WO1995013354A1 - Detergent compositions which provide dye transfer inhibition benefits - Google Patents
Detergent compositions which provide dye transfer inhibition benefits Download PDFInfo
- Publication number
- WO1995013354A1 WO1995013354A1 PCT/US1994/011509 US9411509W WO9513354A1 WO 1995013354 A1 WO1995013354 A1 WO 1995013354A1 US 9411509 W US9411509 W US 9411509W WO 9513354 A1 WO9513354 A1 WO 9513354A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bis
- dye transfer
- hydroxyethyl
- weight
- anilino
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3792—Amine oxide containing polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention is directed to laundry detergent compositions which provide especially effective inhibition of dye transfer between fabrics being laundered in aqueous washing solutions that are formed from these detergent compositions.
- Such detergent compositions comprise from about 1% to 80% by weight of a detersive surfactant, from about 0.01% to 80% by weight of a detergent builder component; from about 0.01% to 10% by weight of certain polymeric dye transfer inhibiting agents and from about 0.005% to 5% by weight of certain hydrophilic optical brightener compounds.
- the polymeric dye transfer inhibiting agents can be polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole or combinations of these polymers and copolymers.
- the hydrophilic optical brighteners used are those having the formula:
- N-2-bis-hydroxyethyl, N-2-hydroxyethyl-2-methylamino, morphilino, chloro or amino and M can be any salt-forming cation.
- anionics and nonionics are preferred and anionics are most preferred.
- Such preferred anionic surfactants can themselves be of several different types.
- water-soluble salts of the higher fatty acids i.e., "soaps"
- alkali metal soaps such as the sodium, potassium, ammonium, and alkylolammonium salts of higher fatty acids containing from about 8 to about 24 carbon atoms, and preferably from about 12 to about 18 carbon atoms.
- Soaps can be made by direct saponification of fats and oils or by the neutralization of free fatty acids.
- Particularly useful are the sodium and potassium salts of the mixtures of fatty acids derived from coconut oil and tallow, i.e., sodium or potassium tallow and coconut soap.
- Additional anionic surfactants which suitable for use herein include the water- soluble .salts, preferably the alkali metal, ammonium and alkylolammonium salts, of organic sulfuric reaction products having in their molecular structure an alkyl group containing from about 10 to about 20 carbon atoms and a sulfonic acid or sulfuric acid ester group.
- nonphosphorus, inorganic builders include the silicates, aluminosilicates, borates and carbonates. Particularly preferred are sodium and potassium carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, and silicates having a weight ratio of S1O2 to alkali metal oxide of from about 0.5 to about 4.0, preferably from about 1.0 to about 2.4. Also preferred are aluminosilicates including zeolites. Such materials and their use as detergent builders are more fully discussed in Corkill et al, U. S. Patent No. 4,605,509, the disclosure of which is incorporated herein by reference. Also, crystalline layered silicates such as those discussed in Corkill et al, U. S. Patent No. 4,605,509, incorporated herein by reference, are suitable for use in the detergent composition of the invention.
- the detergent compositions herein also comprise from about 0.01% to 10% by weight of certain types of polymeric dye transfer inhibiting agents.
- the detergent compositions herein comprise from about 0.05% to 0.5% by weight of these polymeric dye transfer inhibiting materials.
- R wherein P is a polymerizable unit to which a N-O group can be attached or the N-O group can form part of the polymerizable unit or the N-O group can be attached to both units;
- A is one of the following structures: O O
- the N-O group can be represented by the following general structures:
- N-O group can be attached or form part of any of the aforementioned groups.
- the N-O group can be part of the polymerizable unit (P) or can be attached to the polymeric backbone or a combination of both.
- the amine oxide unit of the polyamine N-oxides has a pKa ⁇ 10, preferably pKa ⁇ 7, more preferred pKa ⁇ 6.
- the polyamine oxides can be obtained in almost any degree of polymerization. The degree of polymerization is not critical provided the material has the desired water-solubility and dye-suspending power. Typically, the average molecular weight is within the range of 500 to 1,000,000; more preferred 1,000 to 500,000; most preferred 5,000 to 100,000.
- the most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) which has an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4. This preferred material can be abbreviated as "PVNO".
- the detergent compositions of the present invention may also utilize a copolymer of N-vinylpyrrolidone and N-vinylimidazole (also abbreviated herein as "PVPVI"). It has been found that copolymers of N-vinylpyrrolidone and N- vinylimidazole can provide excellent dye transfer inhibiting performance when utilized in the compositions of this invention.
- the copolymer of N-vinylpyrrolidone and N- vinylimidazole polymers has an average molecular weight range from 5,000 to 1,000,000, more preferably from 5,000 to 200,000.
- the detergent compositions herein also essentially contain from about 0.005% to 5% by weight of a certain type of hydrophilic optical brightener.
- the compositions herein will comprise from about 0.01% to 1% by weight of this optical brightener.
- Ri is selected from anilino, N-2-bis-hydroxyethyl and NH-2-hydroxyethyl
- R2 is selected from N-2-bis-hydroxyethyl, N-2-hydroxyethyl-N-methylamino, morphilino, chloro and amino
- M is a salt-forming cation such as sodium or potassium.
- R2 is N-2-bis-hydroxyethyl and M is a cation such as sodium
- the brightener is 4,4, -bis[(4-anilino-6-(N-2-bis-hydroxyethyl)- s-triazi ⁇ e-2-yl)amino]-2,2 -stilbenedisulfonic acid disodium salt.
- This particular brightener species is commercially marketed under the tradename Tinopal-UNPA- GX by Ciba-Geigy Corporation. Tinopal-UNPA-GX is the preferred hydrophilic optical brightener useful in the detergent compositions herein.
- Rj is anilino
- R2 is morphilino
- M is a cation such as sodium
- the brightener is 4,4,'-bis[(4-anilino-6-mo ⁇ hilino-s-triazine-2- yl)amino]-2,2 -stilbenedisulfonic acid, sodium salt.
- This particular brightener species is commercially marketed under the tradename Tinopal AMS-GX by Ciga-Geigy Corporation.
- proteases are used at an Activity Unit (Anson Unit) level of from about 0.001 to about 0.05, most preferably from about 0.002 to about 0.02, while amylases are used at an amylase unit level of from about 5 to about 5000, most preferably from about 50 to about 500 per gram of detergent composition.
- Activity Unit Asson Unit
- amylases are used at an amylase unit level of from about 5 to about 5000, most preferably from about 50 to about 500 per gram of detergent composition.
- Granular compositions are generally made by combining base granule ingredients (e.g. surfactants, builders, water, etc.) as a slurry, and spray drying the resulting slurry to a low level of residual moisture (5-12%).
- base granule ingredients e.g. surfactants, builders, water, etc.
- the remaining dry ingredients can be admixed in granular powder form with the spray dried ⁇ anules in a rotary mixing drum and the liquid ingredients (e.g. enzymes, binders and perfumes) can be sprayed onto the resulting granules to form the finished detergent composition.
- Granular compositions according to the present invention can also be in "compact form", i.e. they may have a relatively higher density than conventional granular detergents, i.e. from 550 to 950 g 1.
- the granular detergent compositions according to the present invention will contain a lower amount of "inorganic filler salt", compared to conventional granular detergents; typical filler salts are alkaline earth metal salts of sulphates and chlorides, typically sodium sulphate; "compact" detergents typically comprise not more than 10% filler salt.
- Liquid detergent compositions can be prepared by admixing the essential and optional ingredients thereof in any desired order to provide compositions containing components in the requisite concentrations.
- Liquid compositions according to the present invention can also be in "compact form", in such case, the liquid detergent compositions according to the present invention will contain a lower amount of water, compared to conventional liquid detergents.
- the present invention also provides a method for laundering colored fabrics with little or no dye transfer taking place.
- Such a method employs contacting these fabrics with an aqueous washing solution formed from an effective amount of the detergent compositions hereinbefore described. Contacting of fabrics with washing solution will generally occur under conditions of agitation.
- Washing is preferably followed by drying the wet fabric in a conventional clothes dryer.
- An effective amount of the liquid or granular detergent composition in the aqueous wash solution in the washing machine is preferably from about 500 to about
- Tinopal 5BM-GX Brightener 0.21 0.075 Water & minors — up to 100%-
- (2) is a silicone glycol emulsifier available from Dow Corning.
- compositions described in Table I are suitable for laundering colored fabrics in aqueous washing solution while providing excellent dye transfer inhibition benefits.
- Dye transfer inhibition performance provided by the combination of the
- Enzymes protease, lipase, cellulase 2.55 2.27
- PVNO Poly(4-vinylpyridine N-oxide
- compositions described in Table III are suitable for laundering colored fabrics in aqueous solutions while providing excellent dye transfer inhibition benefits.
- Dye transfer inhibition performance provided by the combination of the PVNO or PVPVI and the selected Tinopal brighteners is significantly better than if the dye transfer inhibiting polymers or the optical brighteners were used alone.
- Dye transfer inhibition performance for these compositions is also superior to that which would be provided if other conventional relatively hydrophilic optical brighteners were to be substituted for the Tinopal brighteners employed.
- Alumino silicate (76%) 25.40
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9408024A BR9408024A (en) | 1993-11-10 | 1994-10-11 | Detergent compositions that provide dye transfer inhibition benefits |
EP94930090A EP0728184A1 (en) | 1993-11-10 | 1994-10-11 | Detergent compositions which provide dye transfer inhibition benefits |
AU79319/94A AU7931994A (en) | 1993-11-10 | 1994-10-11 | Detergent compositions which provide dye transfer inhibition benefits |
JP7513823A JPH09505096A (en) | 1993-11-10 | 1994-10-11 | Detergent composition having dye transfer inhibiting effect |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/150,644 US5466802A (en) | 1993-11-10 | 1993-11-10 | Detergent compositions which provide dye transfer inhibition benefits |
US08/150,644 | 1993-11-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995013354A1 true WO1995013354A1 (en) | 1995-05-18 |
Family
ID=22535424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/011509 WO1995013354A1 (en) | 1993-11-10 | 1994-10-11 | Detergent compositions which provide dye transfer inhibition benefits |
Country Status (9)
Country | Link |
---|---|
US (1) | US5466802A (en) |
EP (1) | EP0728184A1 (en) |
JP (1) | JPH09505096A (en) |
CN (1) | CN1139954A (en) |
AU (1) | AU7931994A (en) |
BR (1) | BR9408024A (en) |
CA (1) | CA2174722A1 (en) |
PH (1) | PH31449A (en) |
WO (1) | WO1995013354A1 (en) |
Cited By (12)
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EP0753567A1 (en) * | 1995-07-14 | 1997-01-15 | The Procter & Gamble Company | Softening through the wash compositions |
EP0786517A1 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Detergent composition |
US5726139A (en) * | 1996-03-14 | 1998-03-10 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality |
WO1998023720A1 (en) * | 1996-11-26 | 1998-06-04 | The Procter & Gamble Company | Laundry detergent compositions containing a combination of surfactants and optical brighteners |
WO1998049259A1 (en) * | 1997-04-30 | 1998-11-05 | Unilever Plc | A detergent composition |
WO1999003963A1 (en) * | 1997-07-15 | 1999-01-28 | Unilever Plc | Liquid detergent compositions and process for their preparation |
WO2001059054A1 (en) * | 2000-02-10 | 2001-08-16 | The Procter & Gamble Company | Laundry detergent compositions with a combination of a cyclic amine polymer and a dye transfer inhibitor |
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US5633225A (en) * | 1992-07-15 | 1997-05-27 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
US5560858A (en) * | 1992-07-15 | 1996-10-01 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing a metallocatalyst, a bleach and polyamine N-oxide polymer |
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EP0753567A1 (en) * | 1995-07-14 | 1997-01-15 | The Procter & Gamble Company | Softening through the wash compositions |
EP0786517A1 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Detergent composition |
US5726139A (en) * | 1996-03-14 | 1998-03-10 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality |
WO1998023720A1 (en) * | 1996-11-26 | 1998-06-04 | The Procter & Gamble Company | Laundry detergent compositions containing a combination of surfactants and optical brighteners |
WO1998049259A1 (en) * | 1997-04-30 | 1998-11-05 | Unilever Plc | A detergent composition |
US6121223A (en) * | 1997-04-30 | 2000-09-19 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent composition comprising dye transfer inhibiting polymer and water soluble sunscreen |
WO1999003963A1 (en) * | 1997-07-15 | 1999-01-28 | Unilever Plc | Liquid detergent compositions and process for their preparation |
AU726591B2 (en) * | 1997-07-15 | 2000-11-09 | Unilever Plc | Liquid detergent compositions and process for their preparation |
WO2001059054A1 (en) * | 2000-02-10 | 2001-08-16 | The Procter & Gamble Company | Laundry detergent compositions with a combination of a cyclic amine polymer and a dye transfer inhibitor |
WO2003070870A1 (en) * | 2002-02-25 | 2003-08-28 | Ciba Specialty Chemicals Holding Inc. | Process for the treatment of textile fibre materials |
WO2003070869A1 (en) * | 2002-02-25 | 2003-08-28 | Ciba Specialty Chemicals Holding Inc. | Process for the treatment of textile fibre materials |
EP1715029A2 (en) | 2002-02-25 | 2006-10-25 | Ciba Specialty Chemicals Holding Inc. | Process for the treatment of textile fibre materials |
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WO2004018603A1 (en) * | 2002-08-10 | 2004-03-04 | Unilever Plc | Detergent compositions |
WO2004018602A1 (en) * | 2002-08-10 | 2004-03-04 | Unilever Plc | Detergent compositions |
WO2007019981A1 (en) * | 2005-08-19 | 2007-02-22 | Henkel Kommanditgesellschaft Auf Aktien | Colour protection washing product |
US8263541B2 (en) | 2005-08-19 | 2012-09-11 | Henkel Ag & Co. Kgaa | Triazine derivative dye transfer inhibitors, washing products containing the same and uses therefor |
CN107805960A (en) * | 2017-11-13 | 2018-03-16 | 东莞市古川纺织助剂有限公司 | A kind of fabric short route low temperature active soaping agent |
Also Published As
Publication number | Publication date |
---|---|
JPH09505096A (en) | 1997-05-20 |
PH31449A (en) | 1998-11-03 |
AU7931994A (en) | 1995-05-29 |
CA2174722A1 (en) | 1995-05-18 |
CN1139954A (en) | 1997-01-08 |
BR9408024A (en) | 1996-12-17 |
EP0728184A1 (en) | 1996-08-28 |
US5466802A (en) | 1995-11-14 |
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