WO1995011470A2 - Novel machining techniques for retroreflective cube corner article and method of manufacture - Google Patents

Novel machining techniques for retroreflective cube corner article and method of manufacture Download PDF

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Publication number
WO1995011470A2
WO1995011470A2 PCT/US1994/012016 US9412016W WO9511470A2 WO 1995011470 A2 WO1995011470 A2 WO 1995011470A2 US 9412016 W US9412016 W US 9412016W WO 9511470 A2 WO9511470 A2 WO 9511470A2
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WO
WIPO (PCT)
Prior art keywords
article
groove
cube corner
grooves
sets
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PCT/US1994/012016
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French (fr)
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WO1995011470A1 (en
Inventor
Gerald M Benson
Kenneth L Smith
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Minnesota Mining & Mfg
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Filing date
Publication date
Application filed by Minnesota Mining & Mfg filed Critical Minnesota Mining & Mfg
Priority to JP51220595A priority Critical patent/JP3590064B2/en
Priority to DE69415991T priority patent/DE69415991T2/en
Priority to EP94931937A priority patent/EP0724736B1/en
Publication of WO1995011470A1 publication Critical patent/WO1995011470A1/en
Publication of WO1995011470A2 publication Critical patent/WO1995011470A2/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/2457Parallel ribs and/or grooves

Abstract

A method of machining a substrate to produce a cube corner element optical array (12). The method includes steps of directly machining a plurality of groove sets (14, 16, 20) into a directly machinable substrate to form an array having a plurality of geometric structures including cube corner elements (24, 26, 30), and machining at least two of the groove sets along the same path in the substrate but at different depths of groove to produce a geometric structure side surface having both an optical portion and a non-optical portion.

Description


  
 



   NOVEL MACHINING TECHNIOUES FOR RETROREFLECTIVE
 CUBE CORNER ARTICLE AND METHOD OF MANUFACTURE
Field of the Invention
 This invention relates to retroreflective cube corner element articles having prismatic retroreflective elements.



  Background of the Invention
 Many types of retroreflective elements are known, including prismatic designs incorporating one or more geometric structures commonly known as cube corners. Retroreflective sheeting which employs cube corner type reflecting elements is well-known. Cube corner reflecting elements are trihedral structures which have three approximately mutually perpendicular lateral faces meeting in a single corner. Light rays are typically reflected at the cube faces due to either total internal reflection or reflective coatings. The manufacture of directly machined arrays comprising retroreflective cube corner elements has many inefficiencies and limitations.

   Percent active aperture, flexibility, and manufacturing ease are adversely affected by these limitations, and overall production costs versus performance are often higher relative to the new class of articles and methods of manufacture taught below.



  Summary of the Invention
 The present invention provides cube corner articles made up of an array of cube corner elements defined by at least two intersecting sets of directly machined parallel grooves. The height of at least one of the structures in the array is adjusted or different from other structures in the array as described below. The invention also provides methods for making such cube corner articles. In brief summary, the method typically comprises machining a series of intersecting sets of parallel grooves as described herein into a substrate and forming one or more generations replicas of the substrate.



   Retroreflective articles of the invention overcome many structural and optical limitations of conventional cube corner retroreflective element  designs. The new class of multiple structure cube corner arrays provided by the invention permit diverse cube corner shaping and permit manufacture of cube corner arrays having highly tailorable optical performance.



  Brief Description of the Drawings
 The invention will be further explained with reference to the drawing, wherein:
 Figure 1 is a plan view of an illustrative directly machined three groove set retroreflective cube corner element array of the invention.



   Figure 2 is a section elevation view taken along line 2-2 of
Figure 1.



   Figure 3 is a plan view of some of the active apertures of the array shown in Figures 1 and 2.



   Figure 4 is a plan view of an illustrative directly machined multiple groove set array of the invention having a   3     relief angle.



   Figure 5 is a section elevation view taken along line 5-5 in
Figure 4.



   Figure 6 is a plan view of some of the active apertures of the array shown in Figure 4.



   Figure 7 is a plan view of an illustrative directly machined retroreflective cube corner element array of the invention.



   Figure 8 is a section elevational view taken along line 8-8 in
Figure 7.



   Figure 9 is a plan view of some of the active apertures of the array shown in Figure 7 and Figure 8.



   Figure 10 is a plan view of an illustrative directly machined canted retroreflective cube corner element array of the invention.



   Figure 11 is a plan view of some of the active apertures of the array shown in Figure 10 at zero entrance angle.



   Figure 12 is a graph depicting percent active aperture versus entrance angle for the arrays shown in Figures 1, 4, and 7.  



   Figure 13 is a graph depicting percent active aperture versus entrance angle for arrays shown in Figures 7 and 10.



   Figure 14 is a section elevational view depicting use of a sealing medium.



   Figure 15 is a section elevational view depicting a retroreflective cube corner element array having a separation surface.



   Figure 16 is a schematic view of a machine tool for grooving directly machined arrays.



   Figure 17 is a plan view of an illustrative composite array of the invention comprising several zones of arrays.



   Figure 18 is a plan view of an illustrative directly machined array of the invention with variable groove spacing.



   These figures, which except for Figures 12 and 13 are idealized and not to scale, are intended to be merely illustrative and non-limiting.



  Detailed Description of Illustrative Embodiments of the Invention
 The invention provides a method of manufacturing a cube corner article comprising the steps of providing a machinable substrate of material suitable for forming reflective surfaces, and creating a plurality of geometric structures including cube corner elements in the substrate by directly machining at least two sets of parallel grooves in the substrate. The direct machining forms at least one geometric structure side surface having both an optical portion and a non-optical portion.



   The invention also provides a method of machining a cube corner article comprising the steps of providing a directly machinable substrate in which a plurality of initial groove sets are machined to produce a plurality of geometric structures including cube corner elements, and adjusting the height of at least one of the geometric structures by directly machining at least one additional groove in at least one groove set.



   The invention also provides a method of machining a cube corner article comprising the steps of providing a directly machinable substrate in which a plurality of groove sets are machined to produce a plurality of  geometric structures including cube corner elements, and machining at least one of the grooves in each of at least two of the groove sets along partially overlapping paths in the substrate but at different depths of groove to form a final groove.



   The invention also provides a retroreflective cube corner article which is a replica of a directly machined substrate in which a plurality of geometric structures including cube corner elements are machined in the substrate. At least one of the geometric structures is height adjusted by directly machining at least one additional groove in at least one groove set.



   The invention also provides a retroreflective cube corner article which is a replica of a directly machined substrate in which a plurality of geometric structures including cube corner elements are machined in the substrate. Each geometric structure is bounded by at least one groove from each of at least two sets of parallel final grooves in the substrate, and at least one geometric structure comprises a side surface having both an optical portion and a non-optical portion.



   The invention also provides a retroreflective cube corner element composite sheeting comprising a plurality of zones of geometric structures including retroreflective cube corner elements. Each zone comprises a replica of a directly machined substrate in which a plurality of initial groove sets are machined to produce a plurality of geometric structures including cube corner elements. The composite sheeting comprises at least one zone with height adjusted geometric structures including cube corner elements formed by directly machining at least one additional groove in at least one groove set.



   The invention also provides a retroreflective cube corner element composite sheeting comprising a plurality of zones of geometric structures including retroreflective cube corner elements. Each zone comprises a replica of a directly machined substrate in which a plurality of cube corner elements are bounded in the substrate by a plurality of grooves from a plurality of groove sets. The composite sheeting comprises at least one zone with at least one geometric structure side surface having both an optical portion and a nonoptical portion.  



   The manufacture of retroreflective cube corner element microcube arrays is accomplished using molds made by different techniques, including those known as pin bundling and direct machining. Molds manufactured using pin bundling are made by assembling together individual pins which each have an end portion shaped with features of a cube corner retroreflective element. Examples of pin bundling include U.S. Patent No.



  3,926,402 (Heenan et   al.)    and United Kingdom Patent Nos. 423,464 and 441,319 (Leray).



   The direct machining technique, also known generally as ruling, comprises cutting portions of a substrate to create a pattern of grooves which intersect to form cube corner elements. The grooved substrate is referred to as a master from which a series of impressions, i.e., replicas, may be formed. In some instances, the master is useful as a retroreflective article, however, replicas, including multigenerational replicas, are more commonly used as a retroreflective article. Direct machining is an excellent method for manufacturing master molds with small micro-cube arrays. Micro-cube arrays are particularly beneficial for producing thin replica arrays with improved flexibility. Micro-cube arrays are also conducive to continuous process manufacturing. The process of manufacturing large arrays is also relatively easier using direct machining methods rather than other techniques.

   Examples of direct machining are shown in U.S. Patent No. 4,588,258 (Hoopman) and
U.S. Patent No. 3,712,706 (Stamm), which disclose single or multiple passes of a machine tool having two opposing cutting surfaces for cutting grooves to form cube corner optical faces in a substrate. An example of direct machining involving only two sets of grooves is shown in U.S. Patent 4,895,428 (Nelson et al.).



   Figure 1 discloses one embodiment of a retroreflective cube corner element array 12 manufactured from a directly machinable substrate 13 by use of at least three groove sets each comprising a plurality of parallel nonoverlapping grooves. Preferably, secondary groove sets consisting of evenly spaced secondary grooves 14, 16, are arranged in non-parallel relation, and a primary groove set consists of a plurality of parallel evenly spaced primary  grooves 20 centered between secondary groove intersections 22. An alternate embodiment groove spacing comprises varied rather than evenly spaced grooves. In the embodiment disclosed in Figure 1, a plurality of raised discontinuous geometric structures including retroreflective cube corner elements are formed.

   In this Figure the intersections of the grooves within two groove sets are not coincident with at least one groove in a third groove set.



  Also, the separation between the intersections of the grooves within two groove sets with at least one groove in a third groove set is preferably greater than about 0.01 millimeters. All of these geometric structures are similar to cube corner elements 24, 26, and 30. Figure 1 illustrates a multiple structure array in which the cube corner elements are shown formed from primary and secondary grooves with a uniform depth of cut. The grooves intersect with included angles of 60'.



   Figure 2 is a cross section elevation view taken along lines 2-2 of
Figure 1. Figure 2 illustrates the difference in heights of cube peaks 34, 36, and 38 corresponding to cube corner elements 24, 26, and 30. Cube peak 38 illustrates a very high point of the directly machined substrate relative to all other surfaces. In addition, formation of the structure depicted in Figure 1 and
Figure 2 results in vertical surfaces 41 which create difficulties during processing of arrays of this type. Vertical surfaces contribute to interlocking of mating faces during replication of these arrays, which in turn results in labor inefficiencies, material waste, and slow down of manufacturing.



   For these arrays, optical performance is conveniently defined by the percent of the surface area that is actually retroreflective, i.e., which comprises an effective area or active aperture. The percent active aperture varies as a function of the amount of canting, refractive index, and the entrance angle. The structure of array 12 shown in Figure 1 and Figure 2 demonstrates an exceptional approximately   91 %    active aperture, as schematically shown in the percent active aperture depiction of Figure 3. Figure 3 also depicts multiple active aperture sizes which result when using the geometric structures and method of manufacturing described above.

   In particular, differently sized apertures 47, 49, and 53, are intermixed and arranged in close proximity, and  correspond to the different types of retroreflective cube corner elements 24, 26, and 30 shown in Figure 1. Array 12 is quite useful in applications requiring high brightness at zero or low entrance angles such as photoelectric sensors, traffic control materials, directional reflectors, and retroreflective markings.



   Figure 4 discloses retroreflective cube corner element array 56 formed using multiple groove sets in similar manner to that shown and described above in relation to Figure 1 to create retroreflective cube corner elements 24, 76, and 77. However, array 56 is formed by machining each of the grooves 94, 95, 96 with a 3 relief angle. As shown in Figure 5, this relief angle results in a less vertical orientation of surface 62 as compared with surface 41, shown in Figure 2. This less vertical orientation of surface 62 enhances ease of manufacturing and permits considerable improvements during the replication process of array 56.



   Use of a relief angle also results in a reduction in percent active aperture corresponding to such arrays. As shown in Figure 6, array 56 comprises multiple differently sized and shaped apertures 47, 79, and 83. As shown in Figure 3, the apertures depicted in Figure 6 are also intermixed and arranged in close proximity to provide relatively high brightness at low entrance angles. However, the maximum percent active aperture of array 56 is reduced to only about 84% due to the use of relief angles eliminating some optical surface area. Increased relief may be utilized to further enhance ease of manufacturing and replication, but it also results in additional reduction in maximum percent active aperture. Sufficiently large relief angles may lower some of the higher structures within arrays.

   However, the resulting trihedral structures will no longer be cube corner retroreflective elements.



   Figure 7 discloses yet another embodiment of a retroreflective cube corner element array 88 manufactured in similar manner to array 12 and array 56 with a plurality of secondary and primary grooves. Single or multiple passes of a machine tool may be used to produce the shape of the grooves which form geometric structure side surfaces which may include cube corner element optical surfaces. Final grooves form all the geometric structure side surfaces and may be comprised of one or more grooves. Directly machined  array 88 is substantially identically formed as array 56, with the exception of further adjusting the height of at least one of the structures formed in the array.



  This is accomplished in one of several different possible manners. One embodiment comprises machining a plurality of groove sets to produce a plurality of geometric structures including cube corner elements, and machining at least one of the grooves in each of at least two of the groove sets along overlapping or partially overlapping paths in the substrate but at different depths of groove. Another embodiment comprises creating a plurality of geometric structures including cube corner elements by directly machining at least two sets of parallel grooves in the substrate so that groove machining forms a final groove with at least one geometric structure side surface having both an optical portion and a non-optical portion. In this context, "optical portion" refers to a surface which is actually retroreflective at some entrance angle.

   Preferably, these portions intersect along an axis that is parallel to the axis of the groove(s) which form the geometric structure side surface. This may be accomplished using a novel machine tool to form the final groove using only two groove sets, or by simply using more than two groove sets to form the final groove, as described below.



   For example, primary groove 94 shown originally in Figure 5 and also partially in Figure 8, is machined into substrate 13. Then, in a subsequent processing step, an appropriate machine tool forming a subsequent groove 96 is passed through the substrate in an overlapping or partially overlapping manner to the primary groove path or substantially parallel to primary groove 94 at a depth sufficient to reduce the height of cube corner element 76 (Figure 5) but not to a depth which would cut optical surfaces of other previously formed cube corner elements, such as elements 24 and 77. It is recognized that in this subsequent processing step, which comprises a subsequent groove set, a groove 96 is formed in partial overlap of groove 94.



  Groove 96 is likely to be formed only by cutting substrate surfaces on one side of previous groove 94. The included angle of groove 96 may be of any value although it should preferably not cut surfaces of adjacent cube corner elements.



  This results in final groove 97, shown in Figure 8 in side view, which is the  product of the machining operations which form the final surfaces of geometric structures along the groove. Similar additional machining operations may be performed on the surfaces along the secondary groove sets. As shown in Figure 8, the height   Hl    of the cube corner element depicted as cube corner element 76 in Figure 5 and now formed in a new shape as cube corner element 99 with a peak 101 is less than height H2 of cube corner element 76. Final groove 97 forms at least one geometric structure side surface 98 which has both an optical portion and a non-optical portion, i.e., a surface that is not one of the three substantially orthogonal surfaces which form a cube corner.



   Adjustment of the height of at least one of the cube corner elements by use of direct machining techniques provides substantial processing advantages, and improves mechanical and optical performance. A lower height eases the separation of replicates from master arrays during the replication process. Indeed, the replication quality is also greatly improved with a thinner, height reduced array. Reduction of the height also generally results in an overall thinner construction array 88 than those described above in relation to
Figures 1-6. This enhances the ease of manufacturing, processing, and handling.

   In addition, a thinner array, yet one which comprises substantial optical advantages over known arrays, is advantageous in order to reduce the effect of vignetting, which otherwise reduces the amount of light against the optical retroreflective surfaces of the array due to the channel effect of a very long (e.g., high) structure through which the light must travel.



   Another advantage of adjusting the height using the novel cutting methods described above is the increased percent active aperture of resulting arrays, particularly for arrays using non-zero relief angles. These arrays may exhibit up to about a maximum of   9156    active aperture, although this value is reduced when a relief angle is used, for example, as shown in Figure 8. With the relief angle, array 88 has a maximum percent aperture of about   88%.   



  Increased relief angles could decrease the percent active aperture at zero entrance angle, although it is possible to maintain at least about 70% or greater active aperture using these novel cutting methods. Figure 9 shows the active apertures, viewed at zero entrance angle, of array 88. The percent active  aperture of array 88 is represented by multiple differently sized and shaped apertures 47, 79, and 106. These apertures correspond to cube corner elements 24, 77, and 99. Array 88 may be used in a variety of applications, and is particularly useful for those applications requiring high brightness and improved mechanical flexibility.



   Multigenerational replication of cube corner element master arrays is greatly enhanced by use of arrays without vertical surfaces and without deep grooves or high geometric structures. Shorter structures simplify the task of separating a replicate from a master without damaging the optical surfaces. Shorter structures also result in less mechanical interlocking between a replicate and a master. Shorter structures are also less likely to have entrapped bubbles between a replicate and a master, may be processed at lower temperatures than higher structures of the same material, and are compatible with higher speed processing.

   It is recognized that the highest structures referred to may comprise either cube corner elements or other geometric structures, and that substantial advantages during processing occur when the height of the highest structure is reduced to at least about the height of the next highest structure(s). This, of course, recognizes that the plurality of geometric structures may comprise one or more different geometric structures.



   Array 12, array 56, and array 88 are examples of cube corner element retroreflective arrays which comprise non-canted cubes having individual symmetry axes that are perpendicular to a base plane 110. The symmetry axis is a central or optical axis which is a trisector of the internal or dihedral angles defined by the faces of the element. However, in some practical applications it is advantageous to cant or tilt the symmetry axes of the cube corner retroreflective elements to an orientation which is not perpendicular to the base plane. The resulting canted cube corner elements combine to produce an array which retroreflects over a different range of entrance angles.



  Figure 10 discloses a canted retroreflective cube corner element array 116 which comprises a plurality of cube corner elements each formed from primary and secondary grooves intersecting with included angles   58.5--58.5--63*.   



  Each of the primary grooves 118 and each of the secondary grooves 117, 119,  are evenly spaced and have a 3 relief angle. Array 116 has all of the advantages of array 88, but it also exhibits peak brightness at a non-zero entrance angle. This is particularly useful in applications such as highway signage in which a non-zero entrance angle is most likely to occur. The primary grooves 118 are centered between secondary groove intersections 120.



   Figure 11 discloses the percent active aperture of array 116 at zero entrance angle. Array 116 comprises multiple differently shaped and sized active apertures 122, 125, and 129 corresponding to retroreflective cube corner elements 131, 133, and 137. Figure 11 illustrates the reduction at 0 entrance angle of percent active aperture, as shown by the size of the non-active zones 141, caused by the canting of array 116.



   Figure 12 discloses percent active aperture versus entrance angle for arrays with a refractive index of 1.59 and entrance angles of   0    to + 20' for non-canted arrays. Curve 151 discloses the percent active aperture for a conventional 60'-60'-60' array, such as described in U. S. Patent No.



  3,712,706 to Stamm. Curve 153 discloses the percent active aperture for the   60'-60' -60'    asymmetric array 12 of Figure 1. Curve 155 discloses the percent active aperture for 60'-60'-60' height-adjusted   3    relief array 88 of Figure 7, and curve 159 discloses the percent active aperture for 60'-60'-60' non-height adjusted 3 relief array 56 of Figure 4.



   Figure 12 illustrates a high brightness array having a maximum percent active aperture of about 91%, shown by curve 153, which is achieved in an array formed with grooves having no relief angle. An array with a relief angle improves processability but it also results in a relative reduction of percent active aperture as depicted by curve 159. This reduction in percent active aperture is caused by using grooves with a relief angle without also incorporating any height adjustment to the highest structure(s) in the array.



  However, as shown in curve 155, improved brightness and processability is possible by providing groove relief angles and by reducing the height of the highest structures within the array. These manufacturing techniques yield significant increase in percent active aperture in a range of between about   -15    to about   20    entrance angle for the arrays disclosed above. Additional  processing to reduce the height of the highest structure within an array may be used with arrays having a wide range of relief angles, including zero.



   Figure 13 also discloses percent active aperture versus entrance angle for arrays with a refractive index of 1.59. Curve 155 discloses the percent active aperture for the   60v-60v-60    asymmetric   3    relief angle array 88 shown in Figure 7, which includes a height adjusted groove set, or a controlled depth of cut groove set, either of which produces the novel geometric structure side surface having at least one optical portion and at least one non-optical portion. Curve 163 discloses the percent active aperture for a canted array having retroreflective cube corner elements formed by grooves having included angles of   58.5'-58.5'-63',    corresponding to array 116 shown in Figure 10.

   As shown in Figure 13, curve 163 has substantially identical features to curve 155 except that it achieves peak brightness at a non-zero entrance angle. Both curves 155 and 163 exhibit asymmetric entrance angularity when rotated about an axis within the plane of the substrate. Other amounts of canting may be used advantageously to control the entrance angularity associated with the peak percent active aperture.



   Total light return for retroreflective sheeting is derived from the product of percent active aperture and retroreflected light ray intensity. For some combinations of cube geometries, entrance angles, and refractive index, significant reductions in ray intensity may result in relatively poor total light return even though percent active aperture is relatively high. One example is retroreflective cube corner element arrays which rely on total internal reflection of the retroreflected light rays. Ray intensity is substantially reduced if the critical angle for total internal reflection is exceeded at one of the cube faces.



  Metallized or other reflective coatings on a portion of an array may be utilized advantageously in such situations. For example, a particular portion of an array which has cube surfaces contacting a sealing medium will often be more reflective when the surfaces have a reflective coating. Alternately, a portion may comprise an entire array.



   As shown above, retroreflective directly machined cube corner articles are often designed to receive a sealing film which is applied to the  retroreflective article in order to maintain a low refractive index material, such as air, next to the retroreflective elements for improved performance. In conventional arrays this medium is often placed in direct contact with the cube corner elements in ways which degrade total light return. However, as shown in
Figure 14, a sealing medium 175 may be placed on the highest surfaces 181 of an array without contacting and degrading the optical properties of lower retroreflective cube corner elements, such as elements 24 and 99. The highest surfaces may comprise cube corner elements, non-retroreflective pyramids, frustums, posts, or other structures.

   Although slight height variations may result from slight non-uniformity of groove positions or included angle of cube corner elements due to machining tolerances or intentional inducement of nonorthogonality, these variations are not analogous to the variations disclosed and taught in this invention. When using a sealing medium, the highest surface may be shaped, for example as shown by surface 191 in Figure 15, to both hold the sealing medium and to increase the light transmissivity of the sheeting. Light transmissivity of the sheeting may be increased through use of a transparent or partially transparent sealing medium.



   It is also recognized that reduction of height of the highest structures has a dramatic effect on reducing flexural rigidity particularly for cube sheeting utilizing a sealing medium. Even a moderate reduction in thickness of a sheeting has a significant effect on rigidity since flexural rigidity is proportional to the cube of the thickness for a sheet in bending. For example, a 20% reduction in overall thickness will result in roughly a 50% decrease in flexural rigidity.

 

   Figure 15 is a schematic side view of another embodiment of the invention. This view shows part of an array 200 similar to a portion of array 88 shown in Figure 14 but including the use of a separation surface 206. The side surfaces 210, 213 of geometric structures 218, 219 form the boundary edges 221, 223 for the separation surface. The side surfaces may include cube corner element optical surfaces as well as non-optical surfaces on cube corner and other geometric structures. Separation surface 206 may have flat or curved portions when viewed in cross section. Separation surfaces may be  advantageously utilized to increase light transmission or transparency in sheeting, including flexible sheeting, utilizing the array structures disclosed above.

   Separation surface 206 may be formed using a machine tool with a flat or curved tip, or by further removal of material from a replica of the array master. This construction is particularly useful in applications such as internally illuminated signs and raised pavement markers.



   Suitable materials for retroreflective articles or sheeting of this invention are preferably transparent materials which are dimensionally stable, durable, weatherable, and easily replicated into the desired configuration.



  Examples of suitable materials include glass; acrylics, which have an index of refraction of about 1.5, such as PLEXIGLAS Brand resin manufactured by
Rohm and Haas Company; polycarbonates, which have an index of refraction of about 1.59; reactive materials such as taught in United States Patents Nos.



  4,576,850,   4,582,885,    and   4,668,558;    polyethylene based ionomers, such as those marketed under the brand name of SURLYN by E. I. Dupont de
Nemours and Co., Inc.; polyesters, polyurethanes; and cellulose acetate butyrates. Polycarbonates are particularly suitable because of their toughness and relatively higher refractive index, which generally contributes to improved retroreflective performance over a wider range of entrance angles. These materials may also include dyes, colorants, pigments, UV stabilizers, or other additives. Transparency of the materials ensures that the separation or other shaped surfaces will transmit light through those portions of the article or sheeting.



   The incorporation of either truncated and/or separation surfaces does not eliminate the retroreflectivity of the article, but rather it renders the entire article partially transparent. In some applications requiring partially transparent materials, low indices of refraction of the article will improve the range of light transmitted through the article. In these applications, the increased transmission range of acrylics (refractive index of about 1.5) is desirable. In fully retroreflective articles, materials having high indices of refraction are preferred. In these applications, materials such as polycarbonates, with refractive indices of about 1.59, are used to increase the difference  between the indices of the material and air, thus increasing retroreflection.



  Polycarbonates are also generally preferred for their temperature stability and impact resistance.



   Directly machined arrays according to the invention are formed by adjusting the height of at least one of the structures in the array. As described above, one technique for manufacturing such arrays comprises creating a plurality of geometric structures including cube corner elements by directly machining at least two sets of parallel grooves in the substrate so that groove machining forms at least one geometric structure side surface having both an optical portion and a non-optical portion. This machining may be accomplished using a novel machine tool having groove cutting means for simultaneous cutting of a plurality of different geometric structure surfaces forming multiple side surfaces on at least one side of a final groove.

   One example of this type of tool is shown in Figure 16 in which tool 230 comprises groove cutting means having a first cutting surface 235, a second cutting surface 237, and a third cutting surface 239. In this embodiment, first cutting surface 235 and second cutting surface 237 are configured to form at least one geometric structure side surface having both an optical portion and a nonoptical portion.



   Other embodiments of this invention include creation of an article, or replicas of the article, which further modify the shape of the retroreflected light pattern. These embodiments comprise at least one groove side angle in at least one set of grooves which differs from the angle necessary to produce an orthogonal intersection with other faces of elements defined by the groove sides. Similarly, at least one set of grooves may comprise a repeating pattern of at least two groove side angles that differ from one another.



  Shapes of grooving tools, or other techniques, may create cube corner elements in which at least a significant portion of at least one cube corner element optical face on at least some of the cubes are arcuate. The arcuate face may be concave or convex. The arcuate face, which was initially formed by one of the grooves in one of the groove sets, is flat in a direction substantially parallel to said groove. The arcuate face may be cylindrical, with the axis of the cylinder  parallel to said groove, or may have a varying radius of curvature in a direction perpendicular to said groove.



   Composite tiling is the technique for combining zones of cube corner elements having different orientations. This is used, for example, with conventional arrays to provide sheeting with a uniform appearance at high angles of incidence regardless of orientation. Referring to Figure 17, composite array 244 comprises several zones of arrays 88. Composite arrays may comprise adjacent zones of direct machined cube corner retroreflecting element arrays including either conventional or height adjusted arrays having different configurations, or arrays with at least one geometric structure side surface having both an optical and a non-optical portion. The size of the zones should be selected according to the requirements of particular applications.

   For example, traffic control applications may require zones which are sufficiently small that they are not visually resolvable to the unaided human eye at the minimum expected viewing distance. This provides a composite array with a uniform appearance. Alternatively, channel marking or directional reflector applications may require zones which are sufficiently large that they can be easily resolved by the unaided human eye at maximum required viewing distance.



   Figure 18 discloses array 254 which is similar to array 88 in
Figure 7 but with variable groove spacing. Grooves   257, 258,    and   259    are all in the same groove set. However, as shown in this portion of the array, the spacing of grooves within at least one of the groove sets in the array is varied so that the spacing between a first groove 257 and an adjacent second groove   258    (L,) differs from the spacing between the second groove   258    and an adjacent third groove 259   (by).   



   The process of adjusting the height of geometric structures within a retroreflective cube corner element optical array by either adjusting depth of cut or by conducting an additional height adjustment grooving step results in substantial advantages. These advantages include higher percentage active aperture at various entrance angles, thinner construction of arrays, improved processing, replication, and handling of arrays, improved optical performance  of arrays, improved levels of transparencies of arrays, and improved flexibility of arrays. It is recognized that the above processes may be accomplished using machine tools of various shapes.



   Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention. 

Claims

Claims:
1. A method of manufacturing a cube corner article comprising the steps of: a) providing a machinable substrate of material suitable for forming reflective surfaces; and b) creating a plurality of geometric structures including cube corner elements by directly machining at least two sets of parallel final grooves in the substrate so that groove machining forms at least one geometric structure side surface having both an optical portion and a non-optical portion.
2. The method of claim 1 in which the geometric structures are created using three sets of parallel grooves.
3. The method of claim 1 in which the optical and non-optical portions are formed by a single groove comprising a final groove.
4. The method of claim 1 in which the groove machining is accomplished using a machine tool configured for simultaneous cutting of multiple side surfaces on at least one side of a groove.
5. The method of claim 1 in which the optical and non-optical portions of the geometric structure side surface are formed by different grooves along partially overlapping paths, the different grooves forming a combined final groove.
6. The method of claim 1 in which the geometric structure side surface optical portion and non-optical portion intersect along an axis that is parallel to the axis of the groove which forms the geometric structure side surface.
7. An article manufactured according to the method of claim 1.
8. The article of claim 7 in which the geometric structures comprise only non-vertical surfaces relative to a horizontal reference base plane.
9. A cube corner article which is a replica of the article of claim 7.
10. The article of claim 9 in which the article is retroreflective.
11. A retroreflective cube corner article which is a replica of the article of claim 2.
12. A method of machining a cube corner article comprising the steps of: a) providing a directly machinable substrate in which a plurality of initial groove sets are machined to produce a plurality of geometric structures including cube corner elements; and b) adjusting the height of at least one of the geometric structures by directly machining at least one additional groove in at least one groove set.
13. A retroreflective cube corner article which is a replica of a three groove set embodiment of the article of claim 12.
14. The method of claim 12 in which at least one of the additional grooves partially overlaps the path of a groove formed by one of the initial groove sets.
15. The method of claim 12 in which at least one of the additional grooves is substantially parallel to the path of a groove formed by one of the initial groove sets.
16. An article manufactured according to the method of claim 12.
17. A retroreflective cube corner article which is a replica of the article of claim 16.
18. The article of claim 10 or 17 in which at least one of the grooves in at least one groove set defines geometric structure side surfaces which form boundary edges of a separation surface.
19. The article of claim 18 in which the article is partially light transmissive.
20. The article of claim 10 or 17 which is a structure selected from the group of structures including traffic control materials, vehicle markings, photoelectric sensors, directional reflectors, internally illuminated signs, garments, and markings.
21. The article of claim 10 or 17 in which the article is transparent.
22. The article of claim 10 or 17 in which a portion of the article is reflectively coated.
23. The article of claim 10 or 17 which exhibits at least two different active aperture sizes at zero entrance angle.
24. The article of claim 10 or 17 which exhibits at least two different active aperture shapes at zero entrance angle.
25. The article of claim 10 or 17 in which the percent active aperture is greater than 80% at approximately zero entrance angle.
26. The article of claim 10 or 17 in which the percent active aperture is greater than 90% at approximately zero entrance angle.
27. The article of claim 10 or 17 in which the maximum brightness occurs at non-zero entrance angles.
28. The article of claim 10 or 17 in which the article exhibits asymmetric entrance angularity when rotated about an axis within the plane of the substrate.
29. The article of claim 10 or 17 in which the article comprises at least one groove side angle in at least one groove set which differs from the angle that would produce an orthogonal intersection with other faces of elements defined by the groove side surfaces.
30. The article of claim 10 or 17 in which at least one of the sets of grooves includes, in a repeating pattern, at least two groove side angles that differ from one another.
31. The article of claim 10 or 17 in which at least one cube face on at least some of the cube corner elements is arcuate over a significant portion of the cube face to modify the shape of the retroreflected light pattern.
32. The article of claim 10 or 31 in which the shape of the arcuate face is substantially cylindrical, so that the axis of the cylinder is approximately parallel to the groove which bounds the arcuate face.
33. A method of machining an improved performance cube corner article comprising the steps of: a) providing a directly machinable substrate in which a plurality of groove sets are machined to produce a plurality of geometric structures including cube corner elements; and b) machining at least one of the grooves in each of at least two of the groove sets along partially overlapping paths in the substrate but at different depths of groove to form a final groove.
34. A retroreflective cube corner article which is a replica of an article manufactured according to the method of claim 33.
35. The article of claim 34 in which the geometric structures are created using three sets of parallel grooves.
36. A retroreflective cube corner article which is a replica of a directly machined substrate in which a plurality of initial groove sets are machined to produce a plurality of geometric structures including cube corner elements, at least one of the geometric structures is height adjusted by directly machining at least one additional groove in at least one groove set.
37. The article of claim 36 in which the geometric structures are created using three sets of parallel grooves.
38. A retroreflective cube corner article which is a replica of a directly machined substrate in which a plurality of geometric structures including cube corner elements, each geometric structure is bounded by at least one groove from each of at least two sets of parallel final grooves in the substrate, and at least one geometric structure comprises a side surface having both an optical portion and a non-optical portion.
39. The article of claim 38 in which the geometric structures are created using three sets of parallel grooves.
40. The article of claim 10, 17, 34, 36 or 38 which exhibits at least two differently shaped geometric structures.
41. The article of claim 38 in which the geometric structure side surface optical portion and non-optical portion intersect along an axis that is parallel to the axis of the groove which forms the geometric structure side surface.
42. The article of claim 10, 17, 34, 36 or 38 in which the percent active aperture is greater than 70% at approximately zero entrance angle.
43. The article of claim 11, 13, 35, or 39 in which the intersections of the grooves within two groove sets are not coincident with at least one groove in a third groove set.
44. The article of claim 43 in which there is a separation between the intersections of the grooves within two groove sets with at least one groove in a third groove set which is greater than about 0.01 millimeters.
45. The article of claim 10,17, 34, 36 or 38 in which at least two of the geometric structures have different heights above a common reference plane.
46. The article of claim 45 in which a plurality of geometric structures provide support for a sealing medium attached to the article.
47. A retroreflective cube corner element composite sheeting comprising a plurality of zones of retroreflective cube corner elements, each zone comprising a replica of a directly machined substrate in which a plurality of initial groove sets are machined to produce a plurality of geometric structures including cube corner elements, the composite sheeting comprising at least one zone with height adjusted geometric structures including cube corner elements formed by directly machining at least one additional groove in at least one groove set.
48. The sheeting of claim 47 in which at least one of the additional grooves is substantially parallel to the groove formed by one of the initial groove sets.
49. The composite array of claim 47 in which at least one of the additional grooves is machined at a different depth of groove than a corresponding initial groove.
50. The article of claim 47 which exhibits symmetric entrance angularity when rotated about an axis within the plane of the substrate.
51. A retroreflective cube corner element composite sheeting comprising a plurality of zones of geometric structures including retroreflective cube corner elements, each zone comprising a replica of a directly machined substrate in which a plurality of cube corner elements are bounded in the substrate by a plurality of grooves from a plurality of groove sets, the composite sheeting comprising at least one zone with at least one geometric structure side surface having both an optical and a non-optical portion.
52. The article of claim 51 which exhibits symmetric entrance angularity when rotated about an axis within the plane of the substrate.
53. The article of claim 10, 17, 34, 36 or 38 in which the spacing of grooves within at least one of the groove sets is varied so that the spacing between a first groove and an adjacent second groove differs from the spacing between the second groove and an adjacent third groove.
PCT/US1994/012016 1993-10-20 1994-10-20 Novel machining techniques for retroreflective cube corner article and method of manufacture WO1995011470A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP51220595A JP3590064B2 (en) 1993-10-20 1994-10-20 Retroreflective corner cube article and method of making the same
DE69415991T DE69415991T2 (en) 1993-10-20 1994-10-20 NEW PROCESSING TECHNOLOGY FOR RETRORE-REFLECTIVE CUBE-CORNED BODIES AND MANUFACTURING METHODS THEREOF
EP94931937A EP0724736B1 (en) 1993-10-20 1994-10-20 Novel machining techniques for retroreflective cube corner article and method of manufacture

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/139,920 1993-10-20
US08/139,920 US5600484A (en) 1993-10-20 1993-10-20 Machining techniques for retroreflective cube corner article and method of manufacture

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WO1995011470A2 true WO1995011470A2 (en) 1995-04-27

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999001273A1 (en) * 1997-07-02 1999-01-14 Minnesota Mining And Manufacturing Company Retroreflective cube corner sheeting, molds therefore, and methods of making the same
WO1999015921A1 (en) * 1997-09-25 1999-04-01 Minnesota Mining And Manufacturing Company Dual use reflective article
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US6883921B2 (en) 2001-08-09 2005-04-26 Nippon Carbide Kogyo Kabushiki Kaisha Retroreflection device
US6911486B2 (en) 2000-04-11 2005-06-28 Nippon Carbide Kogyo Kabushiki Kaisha Fluorescent retroreflective sheet
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US7922344B2 (en) 2008-09-02 2011-04-12 Avery Dennison Corporation Metallized retroreflective sheeting with increased daytime brightness

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0724733B1 (en) * 1993-10-20 2001-09-26 Minnesota Mining And Manufacturing Company Multiple structure cube corner article and method of manufacture
US5600484A (en) 1993-10-20 1997-02-04 Minnesota Mining And Manufacturing Company Machining techniques for retroreflective cube corner article and method of manufacture
US5450235A (en) 1993-10-20 1995-09-12 Minnesota Mining And Manufacturing Company Flexible cube-corner retroreflective sheeting
US5696627A (en) * 1993-10-20 1997-12-09 Minnesota Mining And Manufacturing Company Directly machined raised structure retroreflective cube corner article and method of manufacture
US6304364B1 (en) * 1997-06-11 2001-10-16 President & Fellows Of Harvard College Elastomeric light valves
US6461003B1 (en) 1997-06-12 2002-10-08 Purdue Research Foundation Corner cube arrays and manufacture thereof
US5981032A (en) * 1997-07-02 1999-11-09 3M Innovative Properties Company Retroreflective cube corner sheeting mold and sheeting formed therefrom
DE69828070T2 (en) 1997-07-02 2005-12-08 Minnesota Mining And Mfg. Co., St. Paul FORM FOR CUBE TRACKS AND METHOD FOR THE PRODUCTION THEREOF
US5898523A (en) * 1997-07-02 1999-04-27 Minnesota Mining & Manufacturing Company Tiled retroreflective sheeting composed of highly canted cube corner elements
US6253442B1 (en) * 1997-07-02 2001-07-03 3M Innovative Properties Company Retroreflective cube corner sheeting mold and method for making the same
US6050691A (en) * 1998-10-19 2000-04-18 3M Innovative Properties Company Method of making randomly oriented cube-corner articles
US6540367B1 (en) 1999-04-07 2003-04-01 3M Innovative Properties Company Structured surface articles containing geometric structures with compound faces and methods for making same
AU3477399A (en) 1999-04-07 2000-10-23 3M Innovative Properties Company Structured surface articles containing geometric structures with compound faces and methods for making same
US8728610B2 (en) 2000-02-25 2014-05-20 3M Innovative Properties Company Compound mold and structured surface articles containing geometric structures with compound faces and method of making same
US6935756B2 (en) * 2002-06-11 2005-08-30 3M Innovative Properties Company Retroreflective articles having moire-like pattern
JP4308135B2 (en) * 2002-06-11 2009-08-05 スリーエム イノベイティブ プロパティズ カンパニー Manufacturing method of master and its replica
US6843571B2 (en) 2002-06-11 2005-01-18 3M Innovative Properties Company Methods of making a master and replicas thereof
US20040086198A1 (en) * 2002-11-05 2004-05-06 Gerald Brown System and method for bump height measurement
US7142767B2 (en) * 2003-12-31 2006-11-28 3M Innovative Properties Company Scratch-resistant light directing films
KR20130008643A (en) * 2004-12-28 2013-01-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Prismatic retroreflective article with fluorine- or silicon-containing prisms
US7195360B2 (en) * 2004-12-28 2007-03-27 3M Innovative Properties Company Prismatic retroreflective article and method
US7547105B2 (en) * 2007-07-16 2009-06-16 3M Innovative Properties Company Prismatic retroreflective article with cross-linked image layer and method of making same
US9372288B2 (en) 2010-10-29 2016-06-21 Nippon Carbide Industries Co., Inc. Cube-corner retroreflective sheeting
SG195168A1 (en) 2011-05-31 2013-12-30 3M Innovative Properties Co Methods for making differentially pattern cured microstructured articles
WO2012166448A1 (en) 2011-05-31 2012-12-06 3M Innovative Properties Company Retroreflective articles having composite cube-corners and methods of making
US9415539B2 (en) 2011-05-31 2016-08-16 3M Innovative Properties Company Method for making microstructured tools having discontinuous topographies, and articles produced therefrom
WO2014104781A1 (en) * 2012-12-28 2014-07-03 미래나노텍 주식회사 Retro reflection sheet using cube corner having modified structure
CN104133260B (en) * 2014-08-08 2016-09-14 浙江道明光电科技有限公司 A kind of manufacture method of novel micro-prism type reflecting material die
CN106990460B (en) * 2017-04-20 2023-09-26 苏州苏大维格科技集团股份有限公司 Microprism type reflective film and manufacturing method thereof
CN114047568A (en) * 2021-11-03 2022-02-15 江西盛汇光学科技协同创新有限公司 Full-reflection microprism three-dimensional structure array, reflection film and preparation method

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2310790A (en) * 1943-02-09 Optical reflecting material
US1591572A (en) * 1925-02-05 1926-07-06 Jonathan C Stimson Process and apparatus for making central triple reflectors
US2027441A (en) * 1932-11-23 1936-01-14 Landis Aaron Ornamentation for bags
GB423464A (en) * 1932-12-31 1935-02-01 Gustave Leray Improvements in light reflectors
GB441319A (en) * 1933-12-21 1936-01-16 Gustave Leray Improvements in or relating to light reflectors
US2407680A (en) * 1945-03-02 1946-09-17 Minnesota Mining & Mfg Reflex light reflector
US3190178A (en) * 1961-06-29 1965-06-22 Minnesota Mining & Mfg Reflex-reflecting sheeting
US3417959A (en) * 1966-11-14 1968-12-24 Minnesota Mining & Mfg Die for forming retro-reflective article
US3924929A (en) * 1966-11-14 1975-12-09 Minnesota Mining & Mfg Retro-reflective sheet material
US4208090A (en) * 1967-03-24 1980-06-17 Amerace Corporation Reflector structure
US3922065A (en) * 1968-05-31 1975-11-25 Minnesota Mining & Mfg Cube-corner retro-reflective article
US3689346A (en) * 1970-09-29 1972-09-05 Rowland Dev Corp Method for producing retroreflective material
US3810804A (en) * 1970-09-29 1974-05-14 Rowland Dev Corp Method of making retroreflective material
US3684348A (en) * 1970-09-29 1972-08-15 Rowland Dev Corp Retroreflective material
US3712706A (en) * 1971-01-04 1973-01-23 American Cyanamid Co Retroreflective surface
US3811983A (en) * 1972-06-23 1974-05-21 Rowland Dev Corp Method for producing retroreflective sheeting
US3873184A (en) * 1973-02-16 1975-03-25 Amerace Esna Corp Reflector with interspersed angled reflex elements
US3926402A (en) * 1973-04-24 1975-12-16 Amerace Corp Pin having nonaligned cube axis and pin axis and bundle of such pins
US4025159A (en) * 1976-02-17 1977-05-24 Minnesota Mining And Manufacturing Company Cellular retroreflective sheeting
US4349598A (en) * 1976-12-01 1982-09-14 Minnesota Mining And Manufacturing Company High incidence angle retroreflective material
AU4673679A (en) * 1979-05-07 1980-11-13 Ferro Corporation Retroreflective marking tape
US4202600A (en) * 1978-04-24 1980-05-13 Avery International Corporation Diced retroreflective sheeting
US4582885A (en) * 1978-07-20 1986-04-15 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4668558A (en) * 1978-07-20 1987-05-26 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4243618A (en) * 1978-10-23 1981-01-06 Avery International Corporation Method for forming retroreflective sheeting
US4498733A (en) * 1982-07-02 1985-02-12 Amerace Corporation Reflector structure
US4588258A (en) * 1983-09-12 1986-05-13 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles having wide angularity in multiple viewing planes
US4618518A (en) * 1984-08-10 1986-10-21 Amerace Corporation Retroreflective sheeting and methods for making same
US4726706A (en) * 1986-06-02 1988-02-23 Attar Adil H Reflective pavement marker
US4703999A (en) * 1986-06-16 1987-11-03 Minnesota Mining And Manufacturing Company Wide-angle-reflective cube-corner retroreflective sheeting
US4938563A (en) * 1986-11-21 1990-07-03 Minnesota Mining And Manufacturing Company High efficiency cube corner retroflective material
US4775219A (en) * 1986-11-21 1988-10-04 Minnesota Mining & Manufacturing Company Cube-corner retroreflective articles having tailored divergence profiles
US4801193A (en) * 1988-03-04 1989-01-31 Reflexite Corporation Retroreflective sheet material and method of making same
US4952023A (en) * 1988-03-18 1990-08-28 Minnesota Mining And Manufacturing Company Internally illuminated retroreflective sign
US4895428A (en) * 1988-07-26 1990-01-23 Minnesota Mining And Manufacturing Company High efficiency retroreflective material
US5122902A (en) * 1989-03-31 1992-06-16 Minnesota Mining And Manufacturing Company Retroreflective articles having light-transmissive surfaces
US5171624A (en) * 1990-06-01 1992-12-15 Reflexite Corporation Retroreflective microprismatic material and method of making same
US5138488A (en) * 1990-09-10 1992-08-11 Minnesota Mining And Manufacturing Company Retroreflective material with improved angularity
US5237449A (en) * 1991-01-29 1993-08-17 Nelson Optics Company, Inc. Biased lenticular sign system
DE9217179U1 (en) * 1992-12-16 1993-04-22 Gubela Sen., Hans-Erich, 7592 Renchen, De
US5272562A (en) * 1993-02-05 1993-12-21 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles
US5564870A (en) * 1993-10-20 1996-10-15 Minnesota Mining And Manufacturing Company Method of manufacturing an asymmetric cube corner article
EP0724733B1 (en) * 1993-10-20 2001-09-26 Minnesota Mining And Manufacturing Company Multiple structure cube corner article and method of manufacture
US5450235A (en) * 1993-10-20 1995-09-12 Minnesota Mining And Manufacturing Company Flexible cube-corner retroreflective sheeting
US5600484A (en) 1993-10-20 1997-02-04 Minnesota Mining And Manufacturing Company Machining techniques for retroreflective cube corner article and method of manufacture
US5565151A (en) 1994-09-28 1996-10-15 Reflexite Corporation Retroreflective prism structure with windows formed thereon

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Publication number Priority date Publication date Assignee Title
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WO1999015920A1 (en) * 1997-09-25 1999-04-01 Minnesota Mining And Manufacturing Company Reflective article incorporating highly nonorthogonal reflecting surfaces
US6120879A (en) * 1997-09-25 2000-09-19 3M Innovative Properties Company Dual use reflective article
US6685323B1 (en) 1997-11-17 2004-02-03 Nippon Carbide Kogyo Kabushiki Kaisha Triangular-pyramidal cube-corner retroreflective sheeting
US6390629B1 (en) 1998-04-22 2002-05-21 Nippon Carbide Kogyo Kabushiki Kaisha Triangular-pyramidal cube-corner retroreflection sheet
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US6911486B2 (en) 2000-04-11 2005-06-28 Nippon Carbide Kogyo Kabushiki Kaisha Fluorescent retroreflective sheet
US7371339B2 (en) 2001-03-28 2008-05-13 Reflexite Corporation Prismatic retroreflector having a multi-plane facet
US6626544B2 (en) 2001-03-28 2003-09-30 Reflexite Corporation Prismatic retroreflector having a multi-plane facet
US6883921B2 (en) 2001-08-09 2005-04-26 Nippon Carbide Kogyo Kabushiki Kaisha Retroreflection device
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US8231234B2 (en) 2008-09-02 2012-07-31 Avery Dennison Corporation Metallized retroreflective sheeting with increased daytime brightness

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JP3590064B2 (en) 2004-11-17
US6168275B1 (en) 2001-01-02
DE69415991T2 (en) 1999-05-27
EP0724736B1 (en) 1999-01-13
US5600484A (en) 1997-02-04
JPH09504384A (en) 1997-04-28
CN1133637A (en) 1996-10-16
EP0724736A1 (en) 1996-08-07
DE69415991D1 (en) 1999-02-25
CA2173229A1 (en) 1995-04-27
CN1040695C (en) 1998-11-11
US6080340A (en) 2000-06-27

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