WO1994025746A1 - High efficiency multi-shaft reheat turbine with intercooling and recuperation - Google Patents
High efficiency multi-shaft reheat turbine with intercooling and recuperation Download PDFInfo
- Publication number
- WO1994025746A1 WO1994025746A1 PCT/US1994/003902 US9403902W WO9425746A1 WO 1994025746 A1 WO1994025746 A1 WO 1994025746A1 US 9403902 W US9403902 W US 9403902W WO 9425746 A1 WO9425746 A1 WO 9425746A1
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- Prior art keywords
- shaft assembly
- compressor
- turbine
- power shaft
- additional
- Prior art date
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- 238000002485 combustion reaction Methods 0.000 claims abstract description 47
- 230000008878 coupling Effects 0.000 claims abstract description 6
- 238000010168 coupling process Methods 0.000 claims abstract description 6
- 238000005859 coupling reaction Methods 0.000 claims abstract description 6
- 238000010248 power generation Methods 0.000 claims abstract description 3
- 230000000712 assembly Effects 0.000 claims description 34
- 238000000429 assembly Methods 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 230000006835 compression Effects 0.000 claims description 17
- 238000007906 compression Methods 0.000 claims description 17
- 238000011084 recovery Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 11
- 239000012530 fluid Substances 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 20
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 description 8
- 238000010586 diagram Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 4
- 238000010793 Steam injection (oil industry) Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000135 prohibitive effect Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
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- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K21/00—Steam engine plants not otherwise provided for
- F01K21/04—Steam engine plants not otherwise provided for using mixtures of steam and gas; Plants generating or heating steam by bringing water or steam into direct contact with hot gas
- F01K21/047—Steam engine plants not otherwise provided for using mixtures of steam and gas; Plants generating or heating steam by bringing water or steam into direct contact with hot gas having at least one combustion gas turbine
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/36—Open cycles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
- F02C6/003—Gas-turbine plants with heaters between turbine stages
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2220/00—Application
- F05D2220/60—Application making use of surplus or waste energy
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/20—Heat transfer, e.g. cooling
- F05D2260/211—Heat transfer, e.g. cooling by intercooling, e.g. during a compression cycle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Definitions
- This invention relates to combustion turbine engines with inter cooling, saturation, recuperation and reheat.
- a typical and currently available simple cycle combustion turbine consists of a compressor for compressing the atmospheric air, a combustor for heating the compressed air, a turbine for power production and an electric generator for converting mechanical energy into electrical energy.
- a more sophisticated combustion turbine concept with a number of compressors with intercoolers and with a number of turbines with associated combustors and, also, with a recuperator, has been theoretically known at least since the 1920's.
- the first and the most important engineering problem is that the highest pressure turbine for the prior art combustion turbine concept has the highest inlet temperature. This presents a serious challenge because of high thermal and transient stresses in the high pressure and temperature turbine components, and requires special materials and engineering yet to be developed.
- the second engineering problem is a result of the fact that for a typical prior art concept a plurality of combustion turbines with the same inlet temperatures and equal pressure ratios have very high exhaust gas flow temperatures which are the inlet temperatures for a plurality of downstream combustors. This is yet another serious engineering challenge. 3. Objects of the Invention
- An object of this invention is to develop a new combustion turbine with improved efficiency and economics which embodies a properly integrated plurality of turbines with reheat, a plurality of compressors with intercoolers, a recuperator, saturator, water heaters, duct burners, and a heat recovery steam generator.
- Another object of this invention is to develop a new thermal cycle with reduced inlet temperatures (as compared to the current level of temperatures for industrial expanders) to a plurality of turbines which have inlet pressures exceeding the level of the conventional inlet turbine pressure for simple cycle combustion turbines. This resolves the first and the most important engineering problem: a prohibitive combination of coincidental high pressures and temperatures.
- Still another object of this invention is to reduce the gas flow temperatures entering a plurality of combustors. This resolves the second engineering problem.
- Yet another object of this invention is an integration of a saturator in the combustion turbine concept to improve the combustion turbine thermal efficiency and to increase the specific production of electric power per pound of air.
- the saturator via heat and mass exchange, preheats the compressed air and saturates it with moisture before entering a recuperator.
- Another object of the invention is to incorporate a recuperator and water heaters into the inventive combustion turbine concept for better utilization of the combustion turbine cycle available heat with associated improvement of the thermal efficiency.
- Still another object of the invention is a maximum utilization of the available prior art simple cycle combustion turbine components with the addition of currently available industrial components properly integrated into the inventive cycle in order to facilitate practical implementation of the inventive concept.
- Yet a further object of this invention is to provide a heat recovery steam generator for the alternative utilization of the exhaust gas heat, for steam use in the bottoming cycle and/or for steam injection into one of the plurality of turbines.
- a further object of the invention is to provide duct burners strategically positioned in locations of the system to improve the efficiency and economics of the system further.
- an electric power generating system which comprises an electric generator and a power shaft assembly including a compressor, an expansion turbine, a combustor feeding heated air to the expansion turbine, and means for coupling the expansion turbine to drive the compressor and the electric generator.
- a power shaft assembly including a compressor, an expansion turbine, a combustor feeding heated air to the expansion turbine, and means for coupling the expansion turbine to drive the compressor and the electric generator.
- at least one -additional shaft assembly is provided.
- Each additional shaft assembly includes a compressor, an intercooler, an expansion turbine, a combustor, and means for coupling the expansion turbine of the additional shaft assembly to drive the compressor of the additional shaft assembly.
- a recuperator and optional duct burners are provided.
- the power shaft assembly, the at least one additional shaft assembly, and the recuperator are connected to define an air and gas path that passes through the compressor of the power shaft assembly, through the intercooler and the compressor of each of the at least one additional shaft assembly in a first predetermined ordered sequence, through the recuperator, through the combustor and the expansion turbine of each of the at least one additional shaft assembly in a second predetermined ordered sequence, through the combustor and expansion turbine of the power shaft assembly, through the recuperator and to the exhaust stack.
- incoming air is alternately compressed and cooled as it passes through the compressors of the power and additional shaft assemblies, is heated in the heat recuperator, and is alternately heated and expanded as its combustion product gas passes through the combustors and the expansion turbines of the additional and power shaft assemblies.
- the water for the inter-coolers is provided from either a cooling tower or other source.
- the major original features of the inventive gas turbine concept are as follows (see FIG. 2) : o
- the inlet temperature to the highest pressure turbine (FIG. 2, point 23) has the lowest inlet temperature at the level of current industrial expander technology (1400° F) .
- the other turbines (point 13) of the additional shaft assemblies (except the lowest pressure turbine) , have the same inlet temperature, or only slightly higher.
- the highest inlet temperature is at the inlet to the lowest pressure turbine (point 3) of the power shaft assembly and presents the current state of the art temperature level for combustion turbines (2300°F to 2500°F) .
- This distribution of turbine inlet temperatures is in contrast with the prior art theoretical cycle as disclosed in U.S. Patent No.
- the compression pressure ratio of the compressor is greater than the expansion pressure ratio of the expansion turbine. Therefore, for total pressure balance the compression pressure ratio of the power shaft assembly compressor is less than the expansion pressure ratio of the power shaft assembly expansion turbine. In effect, the compressor of the power shaft assembly is partially unloaded so that the expansion turbine of the power shaft assembly can supply more of its power to the electric generator.
- exhaust gas from the power shaft assembly expansion turbine is directed to the heat recuperator so as to provide a heat source therefor.
- the multi-shaft arrangement (power shaft and at least one additional shaft assembly) provides for convenient and economical location of inter-coolers. This allows an increase in the pressure ratio of compressors of the power balanced additional shaft assemblies, thus further unloading the compressor of the power shaft assembly, which, in turn, provides additional power for electric power generation and increases efficiency.
- the saturator saturates the compressed air, thus further reducing the air requirements per kilowatt-hour produced with associated reduction of power consumption by the compressors of the additional shaft assemblies and by the compressor of the power shaft assembly.
- hot water required for the compressed air saturation in the saturator is produced in water heaters (recovering the heat available in the exhaust gas leaving the power shaft assembly turbine after partial heat recovery in the recuperator) and in the intercoolers and aftercooler (recovering the compressed air heat) .
- the steam generated in the heat recovery steam generator produces additional power via steam injection or in the bottoming cycle.
- FIG. 1 is a schematic diagram of a first illustrative embodiment of an electric power generating system according to the present invention
- FIG. 2 is a temperature-entropy diagram for the system of FIG. 1;
- FIG. 3 is a schematic diagram of a second illustrative embodiment of an electric power generating system according to the present invention
- FIG. 4 is a schematic diagram of a third illustrative embodiment of an electric power generating system according to the present invention.
- FIG. 1 is a schematic representation of a first illustrative embodiment of an electric power generating system according to this invention.
- the power shaft assembly represents a conventional heavy duty combustion turbine or an aircraft derivative combustion turbine which includes the compressor 10, the expansion turbine 30, the combustor 20 which feeds heated combustion product gas to the expansion turbine 30, the expansion turbine 30 being coupled to drive the compressor 10 and the electric generator 60.
- air which enters the low pressure compressor 10 at its inlet 1 is compressed thereby and provided at its outlet 2.
- the compressed air is discharged directly to the low pressure combustor 20 and then expanded through the low pressure expansion turbine 30.
- the power output of the turbine 30 is substantially equally divided for driving the compressor 10 and the generator 60.
- At least one additional shaft assembly is provided to modify the conventional power shaft assembly described above.
- two additional shaft assemblies are shown.
- a heat recuperator 50 is provided.
- the first additional shaft assembly includes the intercooler 40, the intermediate pressure compressor 110, the intermediate pressure combustor 120 and the intermediate pressure expansion turbine 130.
- the second additional shaft assembly includes the high pressure intercooler 140, the high pressure compressor 210, the high pressure combustor 220 and the high pressure expansion turbine 230.
- the intercoolers 40 and 140 are cooled by water supplied from a cooling tower.
- the air and gas path extends through the modified compressor of the conventional power shaft assembly, through the intercoolers and compressors of the additional shaft assemblies, through the recuperator, through the combustors and expansion turbines of the additional shaft assemblies, and then through the combustor and expansion turbine of the conventional power shaft assembly.
- the exhaust 2 of the low pressure compressor 10 passes through the intercooler 40 which reduces its temperature at the inlet 11 of the intermediate compressor 110.
- the pressure of the air is then again raised and provided at the exhaust 12 of the compressor 110 to the intercooler 140 which lowers its temperature and provides the cooled intermediate pressure air at the inlet 21 to the high pressure compressor 210.
- the exhaust 22 of the high pressure compressor 210 is provided as an input to the heat recuperator 50.
- the outlet 5 of the heat recuperator 50 is connected to the high pressure combustor 220, whose outlet 23 is provided to the high pressure expansion turbine 230.
- the exhaust 24 of the high pressure expansion turbine 230 is heated in the intermediate pressure combustor 120 and then provided to the inlet 13 of the intermediate pressure expansion turbine 130.
- the exhaust 14 of the intermediate pressure expansion turbine 130 is heated in the low pressure combustor 20 and then provided to the inlet 3 of the low pressure expansion turbine 30, the exhaust 4 of which is utilized as a heat source for the heat recuperator 50, before going to the system exhaust 6.
- the thermodynamic cycle is shown as the temperature- entropy diagram of FIG. 2.
- the compression pressure ratio of the compressor equals the expansion pressure ratio of the turbine, and the output combustion turbine power from the turbine is substantially equally divided for driving the compressor and the electric generator.
- the compression pressure ratio of compressor 10 is substantially reduced so that turbine 30 can supply more of its power for driving generator 60.
- This lowering of the compression pressure ratio of the compressor 10 is accompanied by raising the overall compression pressure ratio of the additional shaft assemblies over the overall expansion pressure ratio of the additional shaft assemblies.
- the intercoolers 40 and 140 the temperature of the air entering the compressors 110 and 210 is reduced, which reduces the power consumed by the compressors 110 and 210, and for the same power consumption by the compressors allows for increased compression pressure ratios.
- FIG. 3 illustrates a modification to the system shown in FIG. 1 which further includes an aftercooler 240 and water saturators 170 and 70 connected between the output of the high pressure compressor 210 and the inlet of the heat recuperator 50.
- the compressed air is cooled in the aftercooler 240 and then directed into the inlet 31 of the saturator 170 and into the inlet 32 of the saturator 70, where the compressed air is saturated with water and preheated before entering the inlet 33 of the heat recuperator 50.
- the remainder of the air and gas path is identical to that of FIG. 1.
- the saturators 170 and 70 are fed by water which has been heated in intercooler 140 and aftercooler 240, and the exhaust gas heat recovering water heaters 65 and 165.
- the water flow paths, including the pumps 80 and 180, are readily apparent from FIG. 3.
- the recuperator 50 and the water heater 65 can be supplementally fired by the installation of duct burners.
- the system shown in FIG. 3 has been shown to have a significantly higher efficiency (up to approximately 53% with state of the art combustion turbines) over the basic system shown in FIG. 1 (approximately 47% efficiency) , but the increased efficiency has some penalties.
- the system shown in FIG. 3 requires a significant amount of make-up water and therefore may have some siting limitations. Further, the system shown in FIG.
- FIG. 4 illustrates another modification to the system of FIG. 1 wherein the exhaust 6 from the heat recuperator 50 is directed to the heat recovery steam generator 90 to produce steam which may be injected into one or more of the combustors 20, 120 and 220.
- the remainder of the system is the same as that shown in FIG. 1.
- the inventive combustion turbine system is a multi-shaft combustion turbine system with a sophisticated thermodynamic cycle and significantly higher efficiency as compared to the state of the art combustion turbine with an estimated specific capital cost, in dollars per kilowatt hour, comparable to that of a simple cycle combustion turbine system.
- the inventive system resolves major engineering problems which until now have prevented an implementation of these sophisticated concepts.
- the system utilizes commercially available components and can be delivered skid mounted, thus shortening the construction time and reducing field construction and cost.
- TABLE 1 presents performance and key point parameters for the inventive system, which are compared to those : for a simple cycle combustion turbine.
- FIG. 3 INJECTION O : (FIG. 4) ⁇ o PERFORMANCE DATA ,
- the performance characteristics presented in TABLE 1 are based on the current level of technology development and on the performance characteristics of estinghouse' s 501F combustion turbine as the source of the power shaft assembly combustion turbine and the performance characteristics of commercial turbo-expanders and compressors for the additional shaft assemblies.
- TABLE 1 shows the advantages of other embodiments of the inventive concepts.
- the second embodiment (FIG 3) , with the addition of a saturator, associated after cooler and waste heat water heaters, has a gross efficiency of 52.8%, as compared to an efficiency of 36.6% for the state of the art combustion turbine.
- TABLE 1 also shows that the third embodiment (FIG. 4) of the inventive concept with use of the heat recovery steam generator shows an efficiency of 48.5%. 19
- the power shaft assembly is a standard commercially available combustion turbine. The modifications required are relatively minor.
- the low pressure compressor 10 pressure ratio has to be reduced to below the pressure ratio of its associated expansion turbine.
- the power-balanced additional shaft assemblies have compression pressure ratios of compressors 110 and 210 which are higher than the corresponding expansion pressure ratios of the turbines 230 and 130. For the same overall compression pressure ratio, this in turn reduces the required compression pressure ratio for the low pressure compressor 10.
- the generator 60 is upgraded for the higher power generating capacity of the plant.
- the power shaft assembly is thrust balanced either by upgrading the existing thrust bearing or by the addition of an external thrust bearing connected to the power shaft assembly.
- the easiest way of reducing the pressure ratio of the compressor 10 is by de-blading a number of its last stages, which can be performed by a manufacturer or by any packager or any utility.
- the additional shaft assemblies can be supplied by industrial turbo-driven compressor manufacturers, supported by combustor manufacturers.
- the described multi-shaft combustion turbine can be commercially offered by combustion turbine manufacturers, industrial steam turbine and turbo machinery manufacturers and/or by other packagers.
- the system described herein is applicable to all alternative modifications of combustion turbines. Accordingly, there has been disclosed an improved electric power generating system. While illustrative embodiments of the present invention 20 have been disclosed herein, it is understood that various modifications and adaptations to the disclosed embodiments will be apparent to those of ordinary skill in the art and it is only intended that this invention be limited by the scope of the appended claims.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002159104A CA2159104A1 (en) | 1993-04-23 | 1994-04-14 | High efficiency multi-shaft reheat turbine with intercooling and recuperation |
DE69429769T DE69429769T2 (en) | 1993-04-23 | 1994-04-14 | MULTI-SHAFT, INTERMEDIATE GAS TURBINE WITH INTERCOOLING AND HEAT RECOVERY |
AT94914096T ATE212695T1 (en) | 1993-04-23 | 1994-04-14 | MULTI-SHAFT, INTERMEDIATE HEATING GAS TURBINE WITH INTERMEDIATE COOLING AND HEAT RECOVERY |
JP6524297A JPH08510311A (en) | 1993-04-23 | 1994-04-14 | High efficiency multi-axis reheat turbine using intercooling and recuperation |
EP94914096A EP0699272B1 (en) | 1993-04-23 | 1994-04-14 | High efficiency multi-shaft reheat turbine with intercooling and recuperation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/052,948 US5347806A (en) | 1993-04-23 | 1993-04-23 | Cascaded advanced high efficiency multi-shaft reheat turbine with intercooling and recuperation |
US08/052,948 | 1993-04-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994025746A1 true WO1994025746A1 (en) | 1994-11-10 |
Family
ID=21980952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/003902 WO1994025746A1 (en) | 1993-04-23 | 1994-04-14 | High efficiency multi-shaft reheat turbine with intercooling and recuperation |
Country Status (9)
Country | Link |
---|---|
US (2) | US5347806A (en) |
EP (1) | EP0699272B1 (en) |
JP (1) | JPH08510311A (en) |
AT (1) | ATE212695T1 (en) |
CA (1) | CA2159104A1 (en) |
DE (1) | DE69429769T2 (en) |
ES (1) | ES2168296T3 (en) |
IL (1) | IL109352A (en) |
WO (1) | WO1994025746A1 (en) |
Families Citing this family (56)
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WO1995011376A1 (en) * | 1993-10-19 | 1995-04-27 | State Of California Energy Resources Conservation And Development Commission | Performance enhanced gas turbine powerplants |
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US5490377A (en) * | 1993-10-19 | 1996-02-13 | California Energy Commission | Performance enhanced gas turbine powerplants |
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- 1994-04-14 JP JP6524297A patent/JPH08510311A/en not_active Ceased
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- 1994-04-14 ES ES94914096T patent/ES2168296T3/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
---|---|
US5386688A (en) | 1995-02-07 |
EP0699272A1 (en) | 1996-03-06 |
DE69429769T2 (en) | 2002-08-08 |
EP0699272B1 (en) | 2002-01-30 |
EP0699272A4 (en) | 1997-01-22 |
ATE212695T1 (en) | 2002-02-15 |
IL109352A (en) | 1999-09-22 |
IL109352A0 (en) | 1994-07-31 |
DE69429769D1 (en) | 2002-03-14 |
US5347806A (en) | 1994-09-20 |
CA2159104A1 (en) | 1994-11-10 |
JPH08510311A (en) | 1996-10-29 |
ES2168296T3 (en) | 2002-06-16 |
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