WO1994018408A3 - Reinforced thermal protective system - Google Patents

Reinforced thermal protective system Download PDF

Info

Publication number
WO1994018408A3
WO1994018408A3 PCT/US1994/000974 US9400974W WO9418408A3 WO 1994018408 A3 WO1994018408 A3 WO 1994018408A3 US 9400974 W US9400974 W US 9400974W WO 9418408 A3 WO9418408 A3 WO 9418408A3
Authority
WO
WIPO (PCT)
Prior art keywords
reinforced
substrate
protective system
coating compositions
thermal protective
Prior art date
Application number
PCT/US1994/000974
Other languages
French (fr)
Other versions
WO1994018408A2 (en
Inventor
Rubin Feldman
Edward William Taylor
Original Assignee
Thermal Science Inc
Rubin Feldman
Edward William Taylor
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thermal Science Inc, Rubin Feldman, Edward William Taylor filed Critical Thermal Science Inc
Priority to DE69426872T priority Critical patent/DE69426872T2/en
Priority to EP94909502A priority patent/EP0682732B1/en
Priority to CA002155349A priority patent/CA2155349C/en
Priority to KR1019950703281A priority patent/KR0172999B1/en
Priority to AU62328/94A priority patent/AU686136B2/en
Priority to AT94909502T priority patent/ATE199757T1/en
Publication of WO1994018408A2 publication Critical patent/WO1994018408A2/en
Publication of WO1994018408A3 publication Critical patent/WO1994018408A3/en
Priority to NO19953092A priority patent/NO313708B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a general shape other than plane
    • B32B1/08—Tubular products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92—Protection against other undesired influences or dangers
    • E04B1/94—Protection against other undesired influences or dangers against fire
    • E04B1/941—Building elements specially adapted therefor
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92—Protection against other undesired influences or dangers
    • E04B1/94—Protection against other undesired influences or dangers against fire
    • E04B1/941—Building elements specially adapted therefor
    • E04B1/942—Building elements specially adapted therefor slab-shaped
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92—Protection against other undesired influences or dangers
    • E04B1/94—Protection against other undesired influences or dangers against fire
    • E04B1/941—Building elements specially adapted therefor
    • E04B1/943—Building elements specially adapted therefor elongated
    • E04B1/944—Building elements specially adapted therefor elongated covered with fire-proofing material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/38—Meshes, lattices or nets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00—Tubular articles, e.g. hoses, pipes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/902—High modulus filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362—Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362—Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • Y10T428/1366—Textile, fabric, cloth, or pile is sandwiched between two distinct layers of material unlike the textile, fabric, cloth, or pile layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y10T428/24694—Parallel corrugations
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2984—Coated or impregnated carbon or carbonaceous fiber fabric

Abstract

Coating compositions (105, 109, 113, 205, 305, 405, 503) for blocking heat from hyperthermal sources are reinforced with high-temperature, high emissivity, open weave fabrics (107, 111, 207, 307, 407, 507, 508). The coating compositions contain materials which actively respond to excessively high temperatures by undergoing endothermic processes or by swelling, preferably by both. The preferred fabrics (107, 111, 207, 307, 407 507, 508) are made of graphite or cardo-polymer yarns. The reinforced compositions may be applied directly to a substrate (101, 203, 303), or they may be molded into self-supporting shapes (401), which are applied to the substrate or are themselves structural units.
PCT/US1994/000974 1993-02-08 1994-02-01 Reinforced thermal protective system WO1994018408A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE69426872T DE69426872T2 (en) 1993-02-08 1994-02-01 PROVEN HEAT PROTECTION SYSTEM
EP94909502A EP0682732B1 (en) 1993-02-08 1994-02-01 Reinforced thermal protective system
CA002155349A CA2155349C (en) 1993-02-08 1994-02-01 Reinforced thermal protective system
KR1019950703281A KR0172999B1 (en) 1993-02-08 1994-02-01 Reinforced thermal protective system
AU62328/94A AU686136B2 (en) 1993-02-08 1994-02-01 Reinforced thermal protective system
AT94909502T ATE199757T1 (en) 1993-02-08 1994-02-01 REINFORCED HEAT PROTECTION SYSTEM
NO19953092A NO313708B1 (en) 1993-02-08 1995-08-07 System and structure for improved thermal protection

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1481693A 1993-02-08 1993-02-08
US08/014,816 1993-02-08

Publications (2)

Publication Number Publication Date
WO1994018408A2 WO1994018408A2 (en) 1994-08-18
WO1994018408A3 true WO1994018408A3 (en) 1994-12-22

Family

ID=21767914

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/000974 WO1994018408A2 (en) 1993-02-08 1994-02-01 Reinforced thermal protective system

Country Status (12)

Country Link
US (1) US5622774A (en)
EP (1) EP0682732B1 (en)
KR (1) KR0172999B1 (en)
AT (1) ATE199757T1 (en)
AU (1) AU686136B2 (en)
CA (1) CA2155349C (en)
DE (1) DE69426872T2 (en)
ES (1) ES2155470T3 (en)
IL (1) IL108529A (en)
NO (1) NO313708B1 (en)
TW (1) TW394727B (en)
WO (1) WO1994018408A2 (en)

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WO2000009362A1 (en) * 1998-08-11 2000-02-24 Daimlerchrysler Ag People mover carshells
US6490828B1 (en) 2000-07-20 2002-12-10 Steelcase Development Corporation Partition wall system
KR20040018321A (en) * 2000-12-22 2004-03-03 누-켐 인코포레이티드 Composite thermal protective system and method
EP1377645A4 (en) * 2001-03-02 2006-05-31 Nu Chem Inc Flexible thermal protective compositions and coatings and structures formed with them
US7232601B2 (en) * 2001-05-31 2007-06-19 Advanced Energy Technology Inc. Method for preparing composite flexible graphite material
US6517648B1 (en) * 2001-11-02 2003-02-11 Appleton Papers Inc. Process for preparing a non-woven fibrous web
US20040147184A1 (en) * 2002-03-01 2004-07-29 Taylor Jr. Edward W. Flexible thermal protective compositions and coatings and structures formed with them
US20050150649A1 (en) * 2004-01-13 2005-07-14 Japan Matex Kabushiki Kaisha (Japan Corporation) Heat release sheet and heat sink
JP2008521646A (en) * 2004-11-24 2008-06-26 ダウ グローバル テクノロジーズ インコーポレイティド Laminated polyisocyanurate foam structure with improved ASTME-84 fire spread index and smoke spread index
US20090094783A1 (en) * 2007-10-11 2009-04-16 Dudderar Raymond P Fiberglass cloth tape laminated fiberboard barrier
WO2013004306A1 (en) * 2011-07-06 2013-01-10 Brabants Gelderse Vastgoed Groep B.V. Fire-resistant laminate
US10815659B1 (en) * 2017-02-10 2020-10-27 Alfred Miller Contracting Company Prefabricated form for fireproofing structural steel and method of use

Citations (13)

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Publication number Priority date Publication date Assignee Title
DE2063815A1 (en) * 1970-12-24 1972-07-06 Rosner, Herbert, 8022 Grünwald Flame-protective coatings - with an embedded fabric or fibre layer
US3849178A (en) * 1970-11-11 1974-11-19 Tsi Inc Thermal protective process and article coated with thermal protective composition
US3915777A (en) * 1971-07-22 1975-10-28 Albi Manufacturing Co Inc Method of applying fire-retardant coating materials to a substrate having corners or other sharp edges
GB1497659A (en) * 1974-11-14 1978-01-12 Tsi Inc Thermal protecting process and composition
US4276344A (en) * 1980-08-05 1981-06-30 Varma Indra K Phosphorus-containing bisimide resins
US4324830A (en) * 1980-11-17 1982-04-13 The United States Of America As Represented By The Secretary Of The Air Force Diethynylbenzene-ethylnylpyrene copolymers
US4403075A (en) * 1980-09-25 1983-09-06 Mcdonnell Douglas Corporation Flame resistant composition containing polymeric phosphorylated amides
US4493945A (en) * 1982-08-23 1985-01-15 Thermal Science, Inc. Thermal protective system
WO1985003032A1 (en) * 1984-01-09 1985-07-18 The Boeing Company Composite material structure with integral fire protection
GB2175847A (en) * 1985-05-21 1986-12-10 Charles Romaniec Materials incorporating active carbon
US4687785A (en) * 1985-08-27 1987-08-18 Thermal Science, Inc. Thermally adaptive polymers and prepolymers and methods of making in which an imide is formed from a polyanhydride oligomer and an isocyanate
EP0492248A2 (en) * 1990-12-22 1992-07-01 Bayer Ag Intumescent sheet, its manufacture and use
WO1992015452A1 (en) * 1991-03-05 1992-09-17 Mandoval Limited Composite fire- and blast-resistant panels

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Publication number Priority date Publication date Assignee Title
US3849178A (en) * 1970-11-11 1974-11-19 Tsi Inc Thermal protective process and article coated with thermal protective composition
DE2063815A1 (en) * 1970-12-24 1972-07-06 Rosner, Herbert, 8022 Grünwald Flame-protective coatings - with an embedded fabric or fibre layer
US3915777A (en) * 1971-07-22 1975-10-28 Albi Manufacturing Co Inc Method of applying fire-retardant coating materials to a substrate having corners or other sharp edges
GB1497659A (en) * 1974-11-14 1978-01-12 Tsi Inc Thermal protecting process and composition
US4276344A (en) * 1980-08-05 1981-06-30 Varma Indra K Phosphorus-containing bisimide resins
US4403075A (en) * 1980-09-25 1983-09-06 Mcdonnell Douglas Corporation Flame resistant composition containing polymeric phosphorylated amides
US4324830A (en) * 1980-11-17 1982-04-13 The United States Of America As Represented By The Secretary Of The Air Force Diethynylbenzene-ethylnylpyrene copolymers
US4493945A (en) * 1982-08-23 1985-01-15 Thermal Science, Inc. Thermal protective system
WO1985003032A1 (en) * 1984-01-09 1985-07-18 The Boeing Company Composite material structure with integral fire protection
GB2175847A (en) * 1985-05-21 1986-12-10 Charles Romaniec Materials incorporating active carbon
US4687785A (en) * 1985-08-27 1987-08-18 Thermal Science, Inc. Thermally adaptive polymers and prepolymers and methods of making in which an imide is formed from a polyanhydride oligomer and an isocyanate
EP0492248A2 (en) * 1990-12-22 1992-07-01 Bayer Ag Intumescent sheet, its manufacture and use
WO1992015452A1 (en) * 1991-03-05 1992-09-17 Mandoval Limited Composite fire- and blast-resistant panels

Also Published As

Publication number Publication date
NO953092D0 (en) 1995-08-07
EP0682732A1 (en) 1995-11-22
CA2155349A1 (en) 1994-08-18
IL108529A (en) 1999-04-11
ATE199757T1 (en) 2001-03-15
NO953092L (en) 1995-09-27
DE69426872T2 (en) 2001-10-04
CA2155349C (en) 1999-12-28
US5622774A (en) 1997-04-22
KR0172999B1 (en) 1999-02-18
DE69426872D1 (en) 2001-04-19
ES2155470T3 (en) 2001-05-16
NO313708B1 (en) 2002-11-18
TW394727B (en) 2000-06-21
AU6232894A (en) 1994-08-29
AU686136B2 (en) 1998-02-05
WO1994018408A2 (en) 1994-08-18
EP0682732B1 (en) 2001-03-14

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