WO1991016386A1 - Hot-melt adhesive - Google Patents
Hot-melt adhesive Download PDFInfo
- Publication number
- WO1991016386A1 WO1991016386A1 PCT/JP1991/000508 JP9100508W WO9116386A1 WO 1991016386 A1 WO1991016386 A1 WO 1991016386A1 JP 9100508 W JP9100508 W JP 9100508W WO 9116386 A1 WO9116386 A1 WO 9116386A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- magnesium
- compound
- copolymer
- adhesive
- aluminum
- Prior art date
Links
- 239000004831 Hot glue Substances 0.000 title claims abstract description 23
- 229920005604 random copolymer Polymers 0.000 claims abstract description 34
- 229920001577 copolymer Polymers 0.000 claims abstract description 27
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 25
- 239000000178 monomer Substances 0.000 claims abstract description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 239000000853 adhesive Substances 0.000 claims description 20
- 230000001070 adhesive effect Effects 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 239000004711 α-olefin Substances 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 13
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 12
- 239000000123 paper Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 239000012943 hotmelt Substances 0.000 claims description 2
- 241000353355 Oreosoma atlanticum Species 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 150000004032 porphyrins Chemical class 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 10
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 239000000565 sealant Substances 0.000 abstract description 2
- 238000003878 thermal aging Methods 0.000 abstract 1
- -1 polyethylene Polymers 0.000 description 97
- 239000003054 catalyst Substances 0.000 description 40
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 38
- 239000010936 titanium Substances 0.000 description 35
- 229910052719 titanium Inorganic materials 0.000 description 35
- 150000001875 compounds Chemical class 0.000 description 34
- 229910052782 aluminium Inorganic materials 0.000 description 32
- 150000002681 magnesium compounds Chemical class 0.000 description 32
- 239000007787 solid Substances 0.000 description 31
- 150000002430 hydrocarbons Chemical group 0.000 description 24
- 150000003609 titanium compounds Chemical class 0.000 description 20
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 19
- 239000011777 magnesium Substances 0.000 description 19
- 229910052749 magnesium Inorganic materials 0.000 description 19
- 229930195733 hydrocarbon Natural products 0.000 description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 14
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 13
- 229910052736 halogen Inorganic materials 0.000 description 13
- 150000002367 halogens Chemical class 0.000 description 13
- 229920001221 xylan Polymers 0.000 description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910001629 magnesium chloride Inorganic materials 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 8
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical group O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
- 150000002170 ethers Chemical class 0.000 description 7
- 229940052303 ethers for general anesthesia Drugs 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 7
- 238000007747 plating Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000013032 Hydrocarbon resin Substances 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 150000001733 carboxylic acid esters Chemical class 0.000 description 6
- 229920006270 hydrocarbon resin Polymers 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000005234 alkyl aluminium group Chemical group 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 150000007524 organic acids Chemical class 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 150000004823 xylans Chemical class 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- KZLUHGRPVSRSHI-UHFFFAOYSA-N dimethylmagnesium Chemical compound C[Mg]C KZLUHGRPVSRSHI-UHFFFAOYSA-N 0.000 description 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- UWKKBEQZACDEBT-UHFFFAOYSA-N CCCC[Mg] Chemical compound CCCC[Mg] UWKKBEQZACDEBT-UHFFFAOYSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000004104 aryloxy group Chemical group 0.000 description 3
- 229920005601 base polymer Polymers 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000282472 Canis lupus familiaris Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 241001062472 Stokellia anisodon Species 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 125000001485 cycloalkadienyl group Chemical group 0.000 description 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- OILVSJASOSICMQ-UHFFFAOYSA-N dicyclohexyl(dimethyl)silane Chemical compound C1CCCCC1[Si](C)(C)C1CCCCC1 OILVSJASOSICMQ-UHFFFAOYSA-N 0.000 description 2
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- WJKVFIFBAASZJX-UHFFFAOYSA-N dimethyl(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](C)(C)C1=CC=CC=C1 WJKVFIFBAASZJX-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- TWXDDNPPQUTEOV-FVGYRXGTSA-N methamphetamine hydrochloride Chemical compound Cl.CN[C@@H](C)CC1=CC=CC=C1 TWXDDNPPQUTEOV-FVGYRXGTSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 2
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000005156 substituted alkylene group Chemical group 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 239000003053 toxin Substances 0.000 description 2
- 231100000765 toxin Toxicity 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 229940094989 trimethylsilane Drugs 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 2
- IQBLWPLYPNOTJC-FPLPWBNLSA-N (z)-4-(2-ethylhexoxy)-4-oxobut-2-enoic acid Chemical compound CCCCC(CC)COC(=O)\C=C/C(O)=O IQBLWPLYPNOTJC-FPLPWBNLSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 1
- SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- DEPJZTNLWYQZPA-UHFFFAOYSA-N 1-o-ethyl 2-o-propan-2-yl benzene-1,2-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OC(C)C DEPJZTNLWYQZPA-UHFFFAOYSA-N 0.000 description 1
- AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- WUHHVDQBQZVSJV-UHFFFAOYSA-N 2,2-dibutylpropanedioic acid Chemical compound CCCCC(C(O)=O)(C(O)=O)CCCC WUHHVDQBQZVSJV-UHFFFAOYSA-N 0.000 description 1
- YQNVPNRHJFZONU-UHFFFAOYSA-N 2,3-dimethylbutan-2-amine Chemical compound CC(C)C(C)(C)N YQNVPNRHJFZONU-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- ZPRGNTVUTLXHEJ-UHFFFAOYSA-N 2-hydroxy-2-(2-octoxy-2-oxoethyl)butanedioic acid Chemical compound CCCCCCCCOC(=O)CC(O)(C(O)=O)CC(O)=O ZPRGNTVUTLXHEJ-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- LIRDIZPKBSSVBK-UHFFFAOYSA-N 3-o-ethyl 1-o-methyl propanedioate Chemical compound CCOC(=O)CC(=O)OC LIRDIZPKBSSVBK-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- RTTAGBVNSDJDTE-UHFFFAOYSA-N 4-ethoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCOC(=O)CC(=C)C(O)=O RTTAGBVNSDJDTE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OSJIQLQSJBXTOH-UHFFFAOYSA-N 8-tricyclo[5.2.1.02,6]decanylmethyl prop-2-enoate Chemical compound C12CCCC2C2CC(COC(=O)C=C)C1C2 OSJIQLQSJBXTOH-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- FBDIMPGJZDQPAV-UHFFFAOYSA-N C1CCCC1[SiH](C1CCCC1)C1CCCC1 Chemical compound C1CCCC1[SiH](C1CCCC1)C1CCCC1 FBDIMPGJZDQPAV-UHFFFAOYSA-N 0.000 description 1
- HCQATSUERBUODI-ODZAUARKSA-N CCCC(O)=O.OC(=O)\C=C/C(O)=O Chemical compound CCCC(O)=O.OC(=O)\C=C/C(O)=O HCQATSUERBUODI-ODZAUARKSA-N 0.000 description 1
- RGPSRYWDFHAWOT-UHFFFAOYSA-N CCCCCCCC[Mg]CCCC Chemical compound CCCCCCCC[Mg]CCCC RGPSRYWDFHAWOT-UHFFFAOYSA-N 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical group CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- ZFDIRQKJPRINOQ-HWKANZROSA-N Ethyl crotonate Chemical compound CCOC(=O)\C=C\C ZFDIRQKJPRINOQ-HWKANZROSA-N 0.000 description 1
- ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- FNJSWIPFHMKRAT-UHFFFAOYSA-N Monomethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(O)=O FNJSWIPFHMKRAT-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- CXOFVDLJLONNDW-UHFFFAOYSA-N Phenytoin Chemical group N1C(=O)NC(=O)C1(C=1C=CC=CC=1)C1=CC=CC=C1 CXOFVDLJLONNDW-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 229910010386 TiI4 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
- BHMUKYAMTKFLKO-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CCCC1)[Zr+2] Chemical compound [Cl-].[Cl-].C1(=CCCC1)[Zr+2] BHMUKYAMTKFLKO-UHFFFAOYSA-L 0.000 description 1
- UEHLUKOPEIIXIA-UHFFFAOYSA-N [Mg].COCl Chemical compound [Mg].COCl UEHLUKOPEIIXIA-UHFFFAOYSA-N 0.000 description 1
- ZYSISUVVLXHRAH-UHFFFAOYSA-K [Mg].[Al+3].[Cl-].[Cl-].[Cl-] Chemical compound [Mg].[Al+3].[Cl-].[Cl-].[Cl-] ZYSISUVVLXHRAH-UHFFFAOYSA-K 0.000 description 1
- TZSQRHNPVPIZHV-UHFFFAOYSA-M [Mg]OC1=CC=CC=C1 Chemical compound [Mg]OC1=CC=CC=C1 TZSQRHNPVPIZHV-UHFFFAOYSA-M 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- GHIPNDFCSFIXQG-UHFFFAOYSA-K aluminum trichloride hydrobromide Chemical compound Br.[Cl-].[Al+3].[Cl-].[Cl-] GHIPNDFCSFIXQG-UHFFFAOYSA-K 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 1
- 229940116224 behenate Drugs 0.000 description 1
- 229940090012 bentyl Drugs 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical group C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- HMOFGLGHQFZQDS-UHFFFAOYSA-N bis(2-methylpropyl) decanedioate Chemical compound CC(C)COC(=O)CCCCCCCCC(=O)OCC(C)C HMOFGLGHQFZQDS-UHFFFAOYSA-N 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- WHGZNMDFTBSHJR-UHFFFAOYSA-M bromoalumane Chemical compound [AlH2]Br WHGZNMDFTBSHJR-UHFFFAOYSA-M 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical class O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical group CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 1
- GUGRBFQNXVKOGR-UHFFFAOYSA-N butyl hypochlorite Chemical compound CCCCOCl GUGRBFQNXVKOGR-UHFFFAOYSA-N 0.000 description 1
- LYVYUAHSSSHKHC-UHFFFAOYSA-N butyl(trimethyl)silane Chemical compound CCCC[Si](C)(C)C LYVYUAHSSSHKHC-UHFFFAOYSA-N 0.000 description 1
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- SMJYMSAPPGLBAR-UHFFFAOYSA-N chloromethyl acetate Chemical compound CC(=O)OCCl SMJYMSAPPGLBAR-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- CYKLGTUKGYURDP-UHFFFAOYSA-L copper;hydrogen sulfate;hydroxide Chemical compound O.[Cu+2].[O-]S([O-])(=O)=O CYKLGTUKGYURDP-UHFFFAOYSA-L 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- JFDSHJDHYXKJFG-UHFFFAOYSA-N cyclohexyl(dimethyl)silicon Chemical compound C[Si](C)C1CCCCC1 JFDSHJDHYXKJFG-UHFFFAOYSA-N 0.000 description 1
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
- 239000004914 cyclooctane Substances 0.000 description 1
- MGGAITMRMJXXMT-UHFFFAOYSA-N cyclopentyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C1CCCC1 MGGAITMRMJXXMT-UHFFFAOYSA-N 0.000 description 1
- GBBPUQZMSKVZSM-UHFFFAOYSA-N cyclopentyl(trimethyl)silane Chemical compound C[Si](C)(C)C1CCCC1 GBBPUQZMSKVZSM-UHFFFAOYSA-N 0.000 description 1
- MAWOHFOSAIXURX-UHFFFAOYSA-N cyclopentylcyclopentane Chemical group C1CCCC1C1CCCC1 MAWOHFOSAIXURX-UHFFFAOYSA-N 0.000 description 1
- 125000004851 cyclopentylmethyl group Chemical group C1(CCCC1)C* 0.000 description 1
- BAAAEEDPKUHLID-UHFFFAOYSA-N decyl(triethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)OCC BAAAEEDPKUHLID-UHFFFAOYSA-N 0.000 description 1
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- VTZJFPSWNQFPCQ-UHFFFAOYSA-N dibutylaluminum Chemical compound CCCC[Al]CCCC VTZJFPSWNQFPCQ-UHFFFAOYSA-N 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229940120124 dichloroacetate Drugs 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- VQAZCUCWHIIFGE-UHFFFAOYSA-N diethyl 2-ethylpropanedioate Chemical compound CCOC(=O)C(CC)C(=O)OCC VQAZCUCWHIIFGE-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- FGYDHYCFHBSNPE-UHFFFAOYSA-N diethyl phenylmalonate Chemical compound CCOC(=O)C(C(=O)OCC)C1=CC=CC=C1 FGYDHYCFHBSNPE-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical compound C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 125000005678 ethenylene group Chemical group [H]C([*:1])=C([H])[*:2] 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- KIMFKMFUVZLIOO-UHFFFAOYSA-N ethyl benzenecarboperoxoate Chemical compound CCOOC(=O)C1=CC=CC=C1 KIMFKMFUVZLIOO-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- REBFJHPJLSHCAF-UHFFFAOYSA-N ethyl hypochlorite;magnesium Chemical compound [Mg].CCOCl REBFJHPJLSHCAF-UHFFFAOYSA-N 0.000 description 1
- SHADDGFTFXAQEE-UHFFFAOYSA-N ethyl hypochlorite;zirconium Chemical compound [Zr].CCOCl SHADDGFTFXAQEE-UHFFFAOYSA-N 0.000 description 1
- BBIDBFWZMCTRNP-UHFFFAOYSA-N ethylalumane Chemical compound CC[AlH2] BBIDBFWZMCTRNP-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000003983 fluorenyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- DNXDYHALMANNEJ-UHFFFAOYSA-N furan-2,3-dicarboxylic acid Chemical compound OC(=O)C=1C=COC=1C(O)=O DNXDYHALMANNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- XBCBHWAPJGSPNX-UHFFFAOYSA-N hex-1-enyl(trimethyl)silane Chemical compound CCCCC=C[Si](C)(C)C XBCBHWAPJGSPNX-UHFFFAOYSA-N 0.000 description 1
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- AEFLONBTGZFSGQ-UHFFFAOYSA-N isoglutamine Chemical compound NC(=O)C(N)CCC(O)=O AEFLONBTGZFSGQ-UHFFFAOYSA-N 0.000 description 1
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- 229910001641 magnesium iodide Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- BJZBHTNKDCBDNQ-UHFFFAOYSA-L magnesium;dodecanoate Chemical compound [Mg+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BJZBHTNKDCBDNQ-UHFFFAOYSA-L 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 150000002691 malonic acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- NRQNMMBQPIGPTB-UHFFFAOYSA-N methylaluminum Chemical compound [CH3].[Al] NRQNMMBQPIGPTB-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- MXHTZQSKTCCMFG-UHFFFAOYSA-N n,n-dibenzyl-1-phenylmethanamine Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)CC1=CC=CC=C1 MXHTZQSKTCCMFG-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- CLDVQCMGOSGNIW-UHFFFAOYSA-N nickel tin Chemical compound [Ni].[Sn] CLDVQCMGOSGNIW-UHFFFAOYSA-N 0.000 description 1
- LKNLEKUNTUVOML-UHFFFAOYSA-L nickel(2+);sulfate;hydrate Chemical compound O.[Ni+2].[O-]S([O-])(=O)=O LKNLEKUNTUVOML-UHFFFAOYSA-L 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- FTDXCHCAMNRNNY-UHFFFAOYSA-N phenol Chemical class OC1=CC=CC=C1.OC1=CC=CC=C1 FTDXCHCAMNRNNY-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 150000008039 phosphoramides Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- ZHIDJOQMCAERGH-UHFFFAOYSA-N prop-1-enylbenzene prop-2-enylbenzene Chemical compound CC=CC1=CC=CC=C1.C(=C)CC1=CC=CC=C1 ZHIDJOQMCAERGH-UHFFFAOYSA-N 0.000 description 1
- 235000019833 protease Nutrition 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- NAMWXCWEMMLYGZ-UHFFFAOYSA-N s-cyano benzenecarbothioate Chemical compound N#CSC(=O)C1=CC=CC=C1 NAMWXCWEMMLYGZ-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical class [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- DAONBNNRBFCSLS-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 DAONBNNRBFCSLS-UHFFFAOYSA-N 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- ZFDIRQKJPRINOQ-UHFFFAOYSA-N transbutenic acid ethyl ester Natural products CCOC(=O)C=CC ZFDIRQKJPRINOQ-UHFFFAOYSA-N 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- KUOGTDMKRNWKQW-UHFFFAOYSA-H trimagnesium hexachloride Chemical compound [Mg+2].[Mg+2].[Mg+2].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-] KUOGTDMKRNWKQW-UHFFFAOYSA-H 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- KXFSUVJPEQYUGN-UHFFFAOYSA-N trimethyl(phenyl)silane Chemical compound C[Si](C)(C)C1=CC=CC=C1 KXFSUVJPEQYUGN-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31895—Paper or wood
- Y10T428/31899—Addition polymer of hydrocarbon[s] only
- Y10T428/31902—Monoethylenically unsaturated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Definitions
- the present invention relates to a hot-melt adhesive comprising a random copolymer of an alpha-olefin having 4 to 12 carbon atoms and an aromatic vinyl monomer. More specifically, it is excellent in adhesiveness and workability, and is also excellent in environmental aging resistance such as heat aging resistance, and is used for packaging, bookbinding, bag making, woodworking, can making, building construction
- a hot spot consisting of a copolymer of ⁇ -olefins having 4 to 12 carbon atoms and an aromatic vinyl monomer, which can be used in various fields such as sanitary and sanitary applications.
- melt adhesives is also excellent in adhesiveness and workability, and is also excellent in environmental aging resistance such as heat aging resistance, and is used for packaging, bookbinding, bag making, woodworking, can making, building construction.
- the present invention further relates to a composition comprising the above copolymer and a tackifier, which is useful as a hot melt adhesive or a heat sealant.
- hot-melt adhesives have rapidly expanded their application fields because of their superior high-speed coating properties, safety, work environment, and energy savings compared to conventional solvent-based adhesives. Has been shown.
- Conventional hot-melt adhesives and heat-sealing agents include natural rubber, ethylene-vinyl acetate copolymer, and styrene-butadiene-styrene.
- the present inventors have conducted intensive studies to obtain a resin for adhesives having excellent environmental aging resistance, such as adhesiveness, processability, and heat aging resistance.
- the inventors have found that a random copolymer composed of an aromatic vinyl monomer is excellent in the above properties, and have completed the present invention.
- the present invention is intended to solve the problems associated with the prior art as described above, and has excellent environmental aging resistance such as adhesiveness, workability, and heat aging resistance. (The purpose is to provide a hot melt adhesive comprising a refine-aromatic vinyl random copolymer.)
- the copolymer comprises a random copolymer with an aromatic vinyl, and the ⁇ -olefin is contained in the copolymer in an amount of 50 to 98 mol%.
- the polymer has a melt viscosity at 200 O: in the range of 1000 to 100,000 centigrade and a softening point in the range of 40 to 150.
- a hot-melt adhesive characterized by the following features is provided.
- composition level derived from the age ref is 50-
- a t-olefin having 4 to 12 carbon atoms is randomly copolymerized with an aromatic butyl monomer, and the ⁇ -olefin is also obtained by random copolymerization.
- the softening point is maintained at 40 to 150%, which is suitable for the hot melt adhesive.
- the adhesive strength is significantly improving to various substrates, such as heat aging resistance. --Significant improvement in environmental aging resistance can be achieved.
- the improvement in environmental aging resistance and the like in the present invention is based on the fact that the main chain of the polymer is substantially entirely formed from carbon-carbon single bonds, and not only the main chain but also the side chains. It is recognized that this is due to the fact that it contains a carbon black-carbon double bond.
- an alkyl side chain based on C 4 to C 12 ⁇ -olefin and an aromatic vinyl-based aromatic copolymer are used.
- Reel (phenyl) side chains coexist in a random manner, and the combination of these side chains results in excellent adhesion to the substrate and the hot melt. It is believed to have suitable melt flow properties.
- ⁇ -olefins having 4 to 12 carbon atoms specifically, butene-11, penten-11, hexene-11, hebutene-1 , Octen-11, nonane; I, decene-11, pendecene-11, dodecen-11, and the like.
- butene-11 and bentene-11 are preferably used.
- These alpha one-year-old fins may be used alone or in combination of two or more.
- the aromatic vinyl monomer constituting the aromatic copolymer is, specifically, styrene, ⁇ -methylstyrene , ⁇ — Methyl styrene, m — Methyl styrene, P — Methyl styrene, o — Methyl styrene, m — Methyl styrene, ⁇ — Alkyl-substituted styrenes such as styrene, bromostyrene, butylstyrene, etc., chlorostyrene, and butyl styrene What's the story ⁇ O
- Vinyl naphth such as substituted polystyrene, 1-vinyl naphthalene, 2—vinyl naphthalene, 1-vinyl-4, 4-methyl naphthalene
- turrets are listed.
- styrene and vinyltoluene are preferred.
- the aromatic vinyl monomer that constitutes the refrigerated aromatic vinyl random copolymer may be used alone or in combination of two or more. May be used in combination.
- ethylene is also included in the ⁇ -age-refined aromatic Burlandham copolymer.
- propylene in a range that does not impair the purpose of the present invention, generally in a range of 30 mol% or less, and particularly in a range of 10 mol% or less, based on the total amount of the above-mentioned dimers. It can also be copolymerized.
- the structural unit derived from (X — aged refine having 50 to 9 carbon atoms) has 4 to 12 carbon atoms. It is in the range of 8 mol%, preferably 60 to 96 mol%, and the structural unit derived from the aromatic vinyl monomer is 2 to 50 mol%, preferably. Or in the range of 4 to 40 mol%.
- the intrinsic viscosity [] of this random copolymer measured in decalin at 135 t: is 0.01 to 7 d ns, preferably 0.1 to 5 d s. It is in the range d j2 / / g.
- This characteristic value is a measure of the molecular weight of the ⁇ -olefin-based random copolymer. By combining with other characteristic values, the characteristic value of the above-mentioned excellent property can be obtained.
- the melt viscosity at 200 is 100000 to: 100 centimeters, preferably 200 to 800 centimeters. It is in the range of the noise.
- This characteristic value is a value that is a measure of the coating property when the hot melt adhesive of the present invention is used.
- the softening point (ring and ball method) of the aged refine-aromatic Burlandum copolymer is 50 to 150 t; preferably 70 to 130 t. In the range. This characteristic value is a standard value for the upper limit temperature when the hot melt adhesive of the present invention is used.
- Catalysts for orphan polymerization which are preferably used in the copolymerization include a solid titanium catalyst component (a), an organic aluminum compound catalyst component (b), It is formed from the electron donor component (c) as required.
- the solid titanium catalyst component (a) contains magnesium, titanium,), ⁇ -gen and an electron donor as essential components.
- Nesium titan (atomic ratio) is greater than 1, preferably 3 to 50, particularly preferably 6 to 30. (Atomic ratio) is greater than 1;
- I 00 particularly preferably from 6 to 40, the electron donor / titanium (molar ratio) preferably from 0.1 to 10; Particularly preferred is 0.2 to 6.
- Its specific surface area is preferably at least 3 m 2 Zg, more preferably about 40 to 100 m 2 / g, and more preferably about 100 to 8 0 m 2 g.
- titanium compounds are not desorbed by simple means such as hexane washing at room temperature.
- the X-ray spectrum is fine regardless of the raw material magnesium compound used for the catalyst preparation, and is not related to the magnesium compound. Either shows a crystallized state or has been microcrystallized, preferably when compared to the crystallized state of ordinary magnesium dihalide commercial products Indicates the status. Further, it may contain other elements, metals, functional groups, etc. other than the above essential components. Further organic or is but it may also be diluted with inorganic diluent 0
- the solid titanium catalyst component (a) uses a magnesium compound, a titanium compound, and, if necessary, an electron donor, and brings these compounds into contact with each other. It is prepared by: In the preparation of the solid titanium catalyst component (a), if necessary, other reaction reagents, for example, compounds such as silicon, phosphorus, and aluminum are used. can do .
- the solid titanium catalyst component (a) for example, JP-A-50-108385, JP-A-50-126590, JP-A-51-20297, Id 51 — 28188 ⁇ O
- a magnesium conjugate may be used, but as the magnesium compound, The magnesium compound having a reducing ability and the magnesium compound having no reducing ability can be mentioned.
- organic magnesium compounds having a reducing ability, specifically,
- magnesium compounds may be used alone, or may form a complex with an organic aluminum compound described below. Further, these magnesium compounds may be liquid or solid.
- magnesium compounds having no reducing ability include:
- Alkoxy magnesium halides such as genuine gum, octokishi shionidani magnesium, etc .;
- Alkoxy magnesium halides such as fenoxin salty magnesium magnesium, methyl fenoxychloride magnesium, etc .
- Tokishimagunesumu Isoprobokishingushimu, Butokishimaguneshimu, n-year-old Tokushimaguneshimu, 2 — Alkoxy magnesium, such as ethylene oxide;
- Aryloxy magnesium such as phenoxy magnesium and dimethyl magnesium
- Magnesium carboxylate such as magnesium laurate and magnesium stearate can be mentioned. .
- magnesium compounds having no reducing ability are prepared by preparing a compound or a catalyst component derived from the magnesium compound having reducing ability described above. It may be a compound induced at that time.
- a magnesium compound having a reducing ability may be used to derive a magnesium compound having no reducing ability from a magnesium compound having a reducing ability.
- the urea compound can be used as a polyxan xan compound, a halogen-containing silane compound, a halogen-containing aluminum conjugate, an ester, an alcohol, or the like. It may be brought into contact with any compound, or a compound having an OH group or an active carbon-oxygen bond.
- the magnesium compound is a magnesium compound having a reducing ability and a magnesium compound having no reducing ability as described above. ,,,,
- the metal compound may be a complex compound of the above magnesium compound and another metal, a complex compound, or a mixture of another metal compound. Further, it may be a mixture of two or more of the above compounds, or may be used in a liquid state or a solid state. When the compound is a solid, it is liquefied using alcohols, carboxylic acids, aldehydes, amines, metal acid esters, and the like. be able to .
- Magnesium conjugates having no reducing ability are preferred, and particularly preferred are Magnesium magnesium containing halogen. It is a daggered product, and among these, magnesium chloride, alcohol salted magnesium salt, and aryloxy salted egg magnesium are also included. Nesium is preferred for use.
- TiO aX -s R is a hydrocarbon group
- X is a halogen atom
- a tetravalent titanium compound represented by 0 ⁇ g ⁇ 4 More specifically, tetranoperogenated titanium such as TiCj £ 4 , TiBr4 and TiI4;
- Tri-Norogeni-Dai-Daru-Kalti Titanium Preferably, the use of a genuine alcoholic titanium is preferred.
- an electron donor can be used if necessary. like this
- Alcohols As electron donors, alcohols, phenols, keto Esters of ethers, aldehydes, carboxylic acids, esters of organic or inorganic acids, ethers, acid amides, acid anhydrides and alkoxysilanes It is possible to use oxygen electron donors, ammonia, amimin, nitrile, nitrogen-containing electron donors such as iso- nates, etc. Wear . More specifically, it is possible to use metal, ethanol, bronze ', pennol, hexanol, octanol, dodeno Canal, Octa desiral call, Benzilla alcohol call, phenyl alcohol call, Cumil alcohol call, A Alcohols having 1 to 18 carbon atoms, such as sodium benzyl alcohol;
- Acids with 2 to 15 carbon atoms such as acetyl chloride, benzoyl chloride lid, trichloric acid chloride, anilic acid chloride, etc. Eids;
- Acid amides ⁇ -dimethyl amides, benzoic acid ,, ⁇ -dimethyl amides, toluene ⁇ , ⁇ -acid amides such as dimethyl amideskind;
- Two trills such as acetonitrile, benzonitrile, and trinitrile;
- Organic phosphorus compounds having a P—0-c bond such as trimethyl phosphite and triethyl phosphite;
- alkoxysilanes such as carboxylate, diphenyl dimethyl xylan, and the like.
- a polyvalent carboxylic acid ester can be mentioned as a particularly preferred example.
- Such a polyvalent carboxylic acid ester is represented by the following general formula:
- R 1 is a substituted or unsubstituted hydrocarbon group
- R 2 , 5, and R 6 are hydrogen or a substituted or unsubstituted hydrocarbon group
- R 3 and R 4 are hydrogen.
- a substituted or unsubstituted hydrocarbon group preferably at least one of which is a substituted or unsubstituted hydrocarbon group
- 3 and R 4 are each other — Lb—
- a hetero atom such as N, 0, S, etc., for example, C 10 -C, COOR, COOH, 0 H, S 0 aH, -C
- polyvalent carboxylic acid esters include succinic acid diethyl, succinic dibutyl, and methyl succinic acid. Diethyl, ⁇ -methyl di-dartal diacid, methyl methyl malonate, methyl ethyl malonate, isopropropyl Dimethyl malonate, Dimethyl butyrate, Diethyl phenylmalonate, Diethylethylmalonate, Dibutylmalonic acid Getyl, monooctyl maleate, dioctyl maleate, dibutyl maleate, dibutyl butyrate maleate, Diethyl butyrate maleate, disobutyl ⁇ -methyldaltalate mouthpiece, diallyl ethyl succinate, dimethyl fumarate 2 — Aliphatic polyester esters such as ethylhexyl, ethyl itaconate, octyl citrate, and 1,2-cyclohexyl (B)
- polyvalent carboxylic acid ester examples include dimethyl adipate, diisobutyrate adipate, and diisobutyl sebacate. Isoprovir, di-eno-senosinate, butyl-, di-eno-senosinate, octyl, di-sebacate, di-2-ethyl, etc. Long-chain dicarboxylic acid esters and the like can be mentioned. Among these compounds, it is preferable to use a carboxylic ester, particularly a polyvalent carboxylic ester, especially a phthalic ester. It is preferred to use acid esters.
- Electron donors that are desired to be contained in (a) in the solid titanium catalyst component include esters of organic or inorganic acids, and alkoxysilanes.
- Compounds having no active hydrogen such as compounds, aryls, ketones, ethers, ketones, tertiary amines, acid halides, and acid anhydrides.
- Particularly preferred are organic acid esters, alkoxysilane conjugates, and lip-mouthed xylan compounds, especially aromatic molybdenum compounds.
- Carboxylic acid substituted succinic acid, maleic acid, substituted maleic acid,
- esters of dicarboxylic acids such as cyclohexyl dicarboxylic acid and phthalic acid and alcohols having 2 or more carbon atoms Is particularly preferred.
- the solid titanium catalyst component uses a carrier compound, a reaction auxiliary agent, etc., in addition to the magnesium compound, the titanium compound, and, if necessary, an electron donor. Alternatively, they may be prepared by contacting them.
- reaction assistant organic and inorganic compounds containing silicon, phosphorus, aluminum, and the like can be used.
- the solid titanium catalyst component (a) comprises a magnesium compound, a titanium compound, an electron donor as needed, and, if necessary, a carrier compound. It is prepared by contact.
- the method for preparing such a solid titanium catalyst component (a) is not particularly limited, but the method will be briefly described below with a few ij.
- each component may be pretreated with an electron donor and a reaction assistant such as an organic aluminum compound or a halogen-containing silicon compound.
- a reaction assistant such as an organic aluminum compound or a halogen-containing silicon compound.
- the method may include a step of grinding the magnesium compound and the titanium compound.
- pretreatment with a reaction aid may be performed, followed by treatment with c, ⁇ -gen, or the like.
- the reaction assistant include an organic aluminum compound and a halogen-containing silicon compound.
- Magnesium salts of organic acids, alkoxy magnesium, aryloxy magnesium, etc. A method of reacting with a body, a titanium compound and a hydrocarbon containing Z or halogen.
- a hydrocarbon solution containing at least a magnesium compound and an alkoxy titan, a titanium compound, an electron donor and, if necessary, a halogen A method for reacting with a halogen-containing compound such as a silicon-containing compound.
- the amount of magnesium compound, titanium compound and electron donor that is added as necessary is determined by the type, contact conditions, contact Depending on the order and the like, the electron donor is preferably 0.01 to 5 mol, particularly preferably 0.1 to I mol per 1 mol of magnesium.
- the amount of the titanium compound in the liquid state is from 0.1 mol to 0.1 mol.ischen,
- the temperature at which these compounds are brought into contact is usually from 170 t: to 200 :, preferably from 101: to 150 * C.
- the solid titanium catalyst component (a) obtained by the above-mentioned various methods can be purified by thoroughly washing with a liquid inert hydrocarbon.
- Inert hydrocarbons used for this purpose include n-pentane, isopentan, n-hexane, isohexane, n-hexane Tan, n—octane, isooctane, n—decane, n—dodecane, kerosene, aliphatic hydrocarbons such as liquid paraffin;
- Cycloaliphatic hydrocarbons such as cyclopentane, methylcyclopentane, cyclohexane, and methylcyclohexane; benzene Aromatic hydrocarbons such as benzene, toluene, xylene, simene;
- nitrogenogen hydrocarbons such as chlorbenzen and dichlorethane, and mixtures thereof.
- the catalyst for polymerization of olefin used in the production of the ⁇ -year-old random-based copolymer used in the present invention is a solid catalyst as described above. It comprises a tan catalyst component (a) and an organic aluminum compound catalyst component (b).
- organic aluminum compound catalyst component (b) examples include, for example,
- R 1 and R 2 usually have 1 to 15 carbon atoms, It is preferably a hydrocarbon group containing from 1 to 4 which may be the same or different from each other.
- ⁇ 1 is Li, Na, ⁇ , and R 1 is the same as described above.
- organic aluminum compound belonging to the above (1) the following compounds can be exemplified.
- R 1 and R 2 are the same as above, and m is preferably a number of 1.5 ⁇ m ⁇ 3),
- R 1 is the same as above, X is a halogen, and m is preferably 0 ⁇ m ⁇ 3.
- R 1 is the same as above; m is preferably approximately 2 ⁇ m ⁇ 3).
- the aluminum conjugates belonging to (1) include triethyl aluminum, tributyl aluminum and tributyl aluminum.
- Trial alkyl aluminum such as
- Trial kenil aluminum such as trisobrenyl aluminum
- Alkoxy such as ethyl alminum ethoxide, dibutyl alminum, etc. De;
- Alkyl aluminum cesium such as ethyl alminum skeletal toxin and butyl alminum skeletal toxin Kia Koshidid,
- Alkyls such as ethyl aluminum chloride, bromide aluminum chloride, and petroleum zinc chloride Partially hydrogenated alkyl aluminum, such as aluminum zinc oxide; dimethyl aluminum hydride , Such as dibutyl aluminum, hydride, etc. 0 ,
- Alkyl aluminum hydride such as ethyl aluminum hydride, bromo aluminum hydride, etc.
- Other partially hydrogenated alkyl aluminum ethyl aluminum ethoxy chloride, butyluminum Partially alkoxylated and halogenated alloys such as toxyl chloride and ethyl alminium ethoxypromide Can be cited as aluminum.
- Examples of the compound similar to (1) include an organic aluminum compound in which two or more aluminum atoms are bonded via an oxygen atom or a nitrogen atom. And can be done.
- Such compounds include, for example,
- Methyl aluminum quinoxane, etc. can be mentioned.
- the compounds belonging to the above (2) include:
- the olefin polymerization used in the production process of the ⁇ -glutamine-based random copolymer [ ⁇ ] that constitutes the olefin composition according to the present invention is formed from the solid titanium catalyst component (a), the organic aluminum compound catalyst component (b), and, if necessary, the electron donor (c). Yes.
- salts can be formed by the reaction of an organic acid with an organometallic compound.
- the electron donor (c) include, for example, the electron donor used in the preparation of the solid titanium catalyst component (a) described above. . Good results include organic acid esters, alkoxylates (free mouth), silyl conjugates, ethers, ketonic anhydrides, amines, etc. Obtained as the electron donor (c).
- the electron donor in the solid titanium catalyst component (a) is a monocarboxylic acid ester
- the electron donation (c) is performed by converting the aromatic carboxylic acid into an aromatic donor. It is preferable to use an alkyl ester.
- the electron donor in the solid titanium catalyst component (a) may be a dicarboxylic acid and a carbon as exemplified above as preferred.
- R and R ′ are hydrocarbon groups and 0 ⁇ n ⁇ 4)
- organic silicon compound represented by the above general formula examples include trimethyl methoxysilane, trimethyl ethoxysilane, and trimethyl ethoxysilane.
- Cyclopentyl trimethyl silane 2—Methyl smelt Bentyl trimethyl silane, 2, 3—Dimethyl smelt Ventilated triethoxysilane; cyclopentyltriethoxysilane;
- Dicyclopentyl dimethoxysilane bis (2—methylcycloventil) Dimethoxypentyl, bis (2,3—di Methyl cyclobenzoyl) dimethoxy xylan, dicyclopentyl jet xylan;
- the catalyst for olefin polymerization used in the copolymerization is formed from a metallocene component (d) and an aluminum oxane component (e).
- the catalysts used can be listed.
- the meta-sensor component (d) is represented by the general formula:
- M is zirconium, titanium, or nordium
- L is a ligand having a cycloalkadienyl skeleton
- two L's may be linked via an alkylene group, a substituted alkylene group or a silylene group
- X and Y are carbon atoms. 1 to 12 hydrocarbon groups, alkoxy groups, aryloxy groups, nitrogen, or hydrogen).
- Examples of the ligand having a cycloalkenyl skeleton include a cyclopentadienyl group and a methylcyclopentadienyl group.
- Alkyl-substituted cyclopentadienyl, indullu, and fluorene groups such as alkyl group, pentamethylcyclopentagenenyl group, etc. For example, it can be used to illustrate a nitro group.
- alkylene group examples include a methylene group, an ethylene group, a bromoyl group, and the like
- a substituted alkylene group is, for example, an isoalkylene group.
- examples include a propylidene group
- examples of the substituted silylene group include a dimethylsilylene group and a diphenylsilylene group. .
- X and Y are a hydrocarbon group having 1 to 12 carbon atoms, an alkoxy group, an aryloxy group, a nitrogen atom, or hydrogen.
- Examples of the hydrogencarbon group having 1 to 12 carbon atoms include an alkyl group, a cycloalkyl group, an aryl group, and an arylalkyl group.
- -Alkyl groups include, but are not limited to, methyl, ethyl, probyl, isoprobyl, and butyl groups.
- Examples of a cycloalkyl group include a cycloalkyl group and the like, and examples of a cycloalkyl group include a cyclobenzyl group and a cyclohexyl group.
- Examples of the phenyl group and the tolyl group are examples of the radical group, and examples of the aralkyl group are a benzyl group and a neofil group. It is done.
- Examples of the alkoxy group include a methoxy group, an ethoxy group, a butoxy group, and the like. Examples thereof include a group.
- nitrogen examples include fluorine, chlorine, bromine, and iodine.
- the following is a specific example of a transition metal compound containing a ligand having a cycloalkadienyl skeleton in which M is zirconia. Show.
- zirconium compounds a compound in which zirconium metal is replaced with titanium metal or hafnium metal is used. You can also.
- the aluminum oxoxane component (e) can be produced, for example, by the following method.
- Organic compounds such as trialkyl aluminum in media such as benzene, toluene, ethyl ether, tetrahydrofuran, etc.
- the aluminoxane may contain a small amount of an organometallic component.
- the solvent or unreacted organic aluminum compound is removed by distillation from the recovered aluminum oxoxane solution, and then redissolved in the solvent. Is also good.
- the organic aluminum compound used for producing the solution of aluminum oxane includes the organic aluminum compound catalyst component (b) described above.
- the exemplified compounds can be mentioned.
- organic aluminum compounds as described above are used independently or in combination.
- Solvents used in the solution of aluminoxane include aromatic hydrocarbons such as benzene, toluene, xylene, cumene, and simene. Aliphatic hydrocarbons such as, pentane, hexane, hebutane, octane, decane, dodecane, hexadecan, octadecan, etc. , Cyclopentane, cyclohexa nn
- Petroleum fractions such as cycloaliphatic hydrocarbons, cyclooctane, methylcyclobentan, petroleum fractions such as gasoline, kerosene, diesel, etc.
- hydrocarbon solvents such as hydrocarbons, aliphatic hydrocarbons, halogenated alicyclic hydrocarbons, in particular, chlorinated compounds, and brominated compounds.
- other ethers such as ethyl ether and tetrahydrofuran can be used. Of these solvents, aromatic hydrocarbons are particularly preferred.
- the inert hydrocarbon medium used for copolymerization of olefins and aromatic vinyl monomers is, for example, bronopen, bronopen or the like.
- Aliphatic hydrocarbons such as tan, pentane, hexan, hebutane, octane, decane, dodecane, kerosene;
- Alicyclic hydrocarbons such as cyclopentane, cyclohexane, and methylcyclopentane
- Aromatic carbon dioxide such as benzene, toluene, xylene, etc .
- hydrocarbons examples include ethylene chloride, chlorobenzene, and other nitrogen-containing hydrocarbons, and mixtures thereof.
- ⁇ -olefin or aromatic vinyl monomer in liquid form at the polymerization reaction temperature described below is a problem for each catalyst component in the polymerization system.
- the amount of (a) is about 0,0001 to about 1.0 mi in terms of titanium atoms, and (b) is Titanium One one
- the metal atom in the component (b) is set so that the metal atom in the component (b) is about 1 to about 500 mole, and the metal atom in the component (b) is set to be about 1 to about 500 mole.
- Per mole from 0.001 to about 10 moles, preferably from about 0.01 to about 2 moles, and particularly preferably from about 0.05 to about 1 mole. Is preferred.
- the polymerization temperature can be appropriately selected, preferably about 20 to about 200: more preferably about 50 to about 180, and the pressure can be appropriately selected. It is preferable to perform the process under a pressure of about 50 Kg / cm 2 or less at atmospheric pressure.
- the polymerization can be carried out in any of a batch system, a semi-continuous system and a continuous system.
- the molecular weight can be adjusted to some extent by changing the polymerization conditions such as the polymerization temperature and the proportion of the catalyst component used, but the most effective effect is to add hydrogen into the polymerization system. It is a target.
- an ⁇ -year-old refund random copolymer is used as it is as an adhesive.
- the ⁇ -olefin random copolymer is 30 to 90% by weight, preferably 35 to 90% by weight, 40 to 90% by weight, and a tackifier [ ⁇ ] 70 to 10% by weight, preferably 65 to 10% by weight, particularly preferably And S0 to 10% by weight.
- tackifier [ ⁇ ] various tackifier resins usually used for hot-melt adhesives and adhesives are used.
- the following resins can be listed depending on the source of the monomer to be polymerized.
- petroleum Na full c 4 fractions obtained et al is Ru in Tsu by the decomposition of such support, c 5 fractions, this is et al.
- Mixture Oh Ru stomach this is found any fraction of, if example example C 5 Lee Seo-flop les down your good beauty 1 in fractions 3 - Bae te di E emissions, etc.
- Ru by Tsu shall be the main material aromatic hydrocarbon resins; C 4, C 5 fraction any fraction a C 9 fraction copolymerized with fat aliphatic Roh aromatic copolymer hydrocarbon resins; aromatic alicyclic hydrocarbon resins obtained by hydrogenating hydrocarbon resins, aliphatic, Contact alicyclic Synthetic terpenic hydrocarbon resin having a structure containing olefins and aromatics; ⁇ ,) 8 in terrebin oil; terpenic hydrocarbon resin using vinylene as a raw material; Coumarone Indene-based hydrocarbon resin from indene and styrene in natural naphtha: Low-molecular-weight styrene resin; ⁇ Examples include rosin-based resins such as rosin esters.
- additives may be added to the ⁇ -age-refined random copolymer or the composition based on this copolymer.
- Agent can be added.
- Fillers such as metals, calcium carbonate, zinc oxide, titanium oxide, silica, organic compounds of phenol-based or bisphenol-based, metal stone And antioxidants for experiments and the like.
- the hot melt adhesive composition As a method for preparing the hot melt adhesive composition, there are an ⁇ -age-refined random copolymer [A] and, if necessary, a tackifier [B]. Alternatively, a mixture consisting of the above-mentioned various additives is stirred under heating to prepare a homogeneous melt, which is then granulated, flaked, or pelletized according to the intended use. , While cooling into a rod or the like. This hot melt adhesive composition is not melted again and is used for application. For example, when the adhesive is used for bonding, a rod-shaped compound can be applied to a welding gun and used in corner bonding of a formed crystal.
- the method of preparing the pressure-sensitive adhesive is as follows: ct one-year-old refund-based random copolymer [A], tackifier [B] and, if necessary, Conventional methods such as kneading a mixture of various additives on a wool or dissolving in a suitable solvent can be mentioned.
- the present invention is useful as a hot-melt adhesive for various substrates such as metal, plastic, and paper.
- Light metal plates or foils such as various surface-treated steel plates or foils and aluminum sheets are used as the metal base.
- rolled steel plate or foil may be used for zinc plating, tin plating, nickel plating, nickel-tin plating, aluminum plating. ⁇
- plating treatment such as rubber plating and electrolytic chromic acid treatment n
- Chemical treatment, chromic acid, or chemical treatment such as phosphoric acid treatment, zirconia treatment, etc. can be used.
- an aluminum alloy plate or foil is used in addition to a pure aluminum plate or foil.
- Each of them may be coated with a known thermoplastic paint and / or a thermosetting paint.
- plastic substrate molded products of various plastics and films are used.
- polyethylene polylobylene, etc. Olefin tea copolymers, ethylene-propylene copolymers, ethylene-butyl acetate copolymers, ionomers, etc .
- polyethylene resins polyesters such as phthalates, polybutylene phthalates, polyethylene phthalates, neusolates, etc .
- Nylon 6, Nylon 6, 6, Nylon 6 no 6, 6 copolymer polyhexamethylene isophthalamide, telephthalamide, etc.
- Polyamide Polycarbonate; Vinyl chloride resin; Vinylidene chloride resin.
- These plastic substrates may be unstretched or may have been molecularly oriented by uniaxial or biaxial stretching.
- the paper substrate may be glass paper, pure white roll paper, imitation paper, or other wrapping paper or craft paper.
- synthetic paper, synthetic paper and mixed cellulose paper, or mixed paper of these and inorganic fibers may be used.
- the adhesive of the present invention can also be used for bonding.
- the hot-melt adhesive of the present invention utilizes the excellent properties of the hot-melt adhesive to seal the container with the lid by bonding, and to bond a plurality of other members. It can be used for integration or for laminating the above-mentioned plural kinds of substrates.
- the bonding structure can be freely designed.
- the hot-melt adhesive of the present invention can be used to form a non-peelable bonding structure, or other bonding structures can be used. It is possible to mix easily with fin-based resin for easy peeling.
- composition can be applied to one or both surfaces of the above-mentioned various substrates and used for applications such as pressure-sensitive adhesive tapes.
- the composition of the present invention has excellent adhesiveness, excellent heat resistance, heat resistance, weather resistance, and hue, and is useful in the preparation of the composition. It has the advantage of being free of odor during use and being excellent in flavor retention and sanitary properties of the contents as a packaging material.
- the ⁇ -alumina-refined random copolymer used in the following examples was synthesized as follows.
- composition of (a) was 2.5% by weight of titanium, 63.2% by weight of chlorine, 20.7% by weight of magnesium, and 12.5% by weight of disobutyl phthalate.
- Tri-Millimeter Kishiran has been installed. Thereafter, the nitrogen bubbling was stopped, and butene-1 and hydrogen were introduced continuously at a rate of 150 J £ / hour and 150 J / hour, respectively.
- the temperature of this solution was raised to 6 O :, and a titanium catalyst component of D.2 millimol, which was converted into titanium atoms, was added to initiate polymerization.
- the polymerization was carried out at about 60 for 30 minutes.
- the polymerization proceeded in a solution state.
- the polymerization was stopped by adding isobutyl alcohol, and all of the polymer was precipitated in a large amount of methanol, followed by vacuum drying at 120 ° C for 24 hours. g of polymer was obtained.
- the butene-11 content of the polymer was 90.2 mol% and the intrinsic viscosity [7?] Measured in decalin at 135 was 0.45 dg.
- the butene-1 ⁇ styrene random copolymer used in Examples 2, 3, 5, 6, 6 and 7 was prepared as follows: [Synthesis of ⁇ -yearly refin random copolymer] The synthesis was performed by changing the amounts of styrene and butene used in [1].
- butene-1 ⁇ ⁇ -methylstyrene random copolymer used in Examples 4 and 8 was synthesized as [ ⁇ -olefin random copolymer]. In place of styrene, ⁇ -methylstyrene was used in an appropriate amount.
- Polybutene-11 used in Comparative Example 1 was [Synthesis of ⁇ -olefin random copolymer-1] without using styrene. ,.
- the propylene-styrene-random copolymer used in Comparative Example 2 was obtained from [Synthesis of ⁇ -year-old Random Random Copolymer 1]. Instead of propylene, synthesis was performed using propylene and appropriate amounts of styrene and propylene.
- Table 1 shows the test results.
- Example 1 was repeated except that the ⁇ -olefin-aromatic vinyl random copolymer or the adhesive substrate was changed as shown in Table 1 in Example 1. The same operation as was performed. Table 1 shows the results.
- Example 1 the same operation as in Example 1 was carried out except that polybutene-11 was used in place of the ⁇ -year-old ⁇ aromatic aromatic copolymer. went. Table 1 shows the results. Comparative Example 2
- Example 1 the same operation as in Example 1 was performed except that propylene was used instead of butene-11 as an ⁇ -year-old fin. . Table 1 shows the results.
- a biaxially stretched film of polypropylene is stacked on top of this, heat sealed at 3 kg / cm 2 for 10 seconds at 120, and adhesive strength is evaluated.
- a sample for use was obtained. Measured temperature 2 O a T- ⁇ tested to Assess the contact force application of the sample: and Tsu rows ⁇ rate 3 0 cm / / min.
- Example 5 The same operation as in Example 5 was performed except that the content of the aromatic vinyl monomer and the ⁇ -age refin were changed as shown in Table 2.
- Table 2 shows the results. Table 2 Dogs ⁇ -* Dogs / ItH JO / Large IffiCT oa-Orrefin Butene-1 Butene-1 Butene-1 Butene-1 Butene-1 Aromatic vinyl monomer Styrene Styrene Styrene P-Methylstyrene a-a content (mol%) 90.1 87.5 82.3 88.1
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA 2062749 CA2062749C (en) | 1990-04-18 | 1991-04-17 | Hot-melt adhesive |
DE1991611354 DE69111354T2 (de) | 1990-04-18 | 1991-04-17 | Heissschmelzklebstoff. |
KR1019910701899A KR950007714B1 (ko) | 1990-04-18 | 1991-04-17 | 핫멜트 접착제 |
EP91908470A EP0478800B1 (en) | 1990-04-18 | 1991-04-17 | Hot-melt adhesive |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2/102162 | 1990-04-18 | ||
JP10216290 | 1990-04-18 | ||
JP12765590A JP2854088B2 (ja) | 1990-05-17 | 1990-05-17 | ポリオレフィン組成物 |
JP2/127655 | 1990-05-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991016386A1 true WO1991016386A1 (en) | 1991-10-31 |
Family
ID=26442895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1991/000508 WO1991016386A1 (en) | 1990-04-18 | 1991-04-17 | Hot-melt adhesive |
Country Status (7)
Country | Link |
---|---|
US (1) | US5244996A (ja) |
EP (1) | EP0478800B1 (ja) |
KR (1) | KR950007714B1 (ja) |
AT (1) | ATE125285T1 (ja) |
CA (1) | CA2062749C (ja) |
DE (1) | DE69111354T2 (ja) |
WO (1) | WO1991016386A1 (ja) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW408155B (en) * | 1989-08-31 | 2000-10-11 | Dow Chemical Co | Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers |
US5462807A (en) * | 1993-08-20 | 1995-10-31 | Exxon Chemical Patents Inc. | Heat sealable films and articles |
US6111020A (en) * | 1994-09-02 | 2000-08-29 | The Dow Chemical Company | Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers |
US5543484A (en) * | 1994-11-18 | 1996-08-06 | The Penn State Research Foundation | α-olefin/para-alkylstyrene copolymers |
US6015862A (en) * | 1994-11-18 | 2000-01-18 | The Penn State Research Foundation | Functionalized α-olefin/para-alkylstyrene terpolymers |
US6169138B1 (en) | 1994-12-15 | 2001-01-02 | Saint-Gobain Performance Plastics Corporation | Foamed pressure sensitive tapes |
ZA977909B (en) * | 1996-09-04 | 1999-03-03 | Dow Chemical Co | Compositions comprising a substantially random interpolymer of at least one alpha-olefin and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer |
ES2170405T3 (es) | 1996-09-04 | 2002-08-01 | Dow Chemical Co | Cubiertas para suelo, pared o techo. |
US6254956B1 (en) | 1996-09-04 | 2001-07-03 | The Dow Chemical Company | Floor, wall or ceiling covering |
US5739200A (en) * | 1996-12-17 | 1998-04-14 | The Dow Chemical Company | Plasticizied α-olefin/vinylidene aromatic monomer of hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers |
AU733854B2 (en) * | 1997-01-30 | 2001-05-31 | Mitsui Chemicals, Inc. | Hot-melt adhesive composition |
KR100334167B1 (ko) * | 1997-05-08 | 2002-11-22 | 삼성종합화학주식회사 | 알파-올레핀중합방법 |
US6319969B1 (en) | 1997-06-26 | 2001-11-20 | The Dow Chemical Company | Interpolymer compositions for use in sound management |
US6262161B1 (en) | 1997-06-26 | 2001-07-17 | The Dow Chemical Company | Compositions having improved ignition resistance |
US6136923A (en) * | 1997-10-15 | 2000-10-24 | The Dow Chemical Company | Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride |
KR20010024534A (ko) * | 1997-10-17 | 2001-03-26 | 그래햄 이. 테일러 | 1종 이상의 비닐 또는 비닐리덴 방향족 단량체와알파-올레핀 단량체의 상호중합체 조성물 |
CN1143908C (zh) * | 1998-03-11 | 2004-03-31 | 陶氏化学公司 | 由α-烯烃/乙烯基或亚乙烯基芳族单体和/或位阻环脂族或脂族乙烯基或亚乙烯基共聚体制成的纤维 |
WO2000027936A1 (en) * | 1998-11-06 | 2000-05-18 | The Dow Chemical Company | COATINGS COMPOSITIONS CONTAINING α-OLEFIN/VINYL OR VINYLIDENE AROMATIC AND/OR HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE INTERPOLYMERS |
US6187232B1 (en) * | 1998-12-04 | 2001-02-13 | The Dow Chemical Company | Acoustical insulation foams |
US6231795B1 (en) * | 1998-12-04 | 2001-05-15 | The Dow Chemical Company | Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
US6281289B1 (en) | 1998-12-08 | 2001-08-28 | The Dow Chemical Company | Polypropylene/ethylene polymer fiber having improved bond performance and composition for making the same |
KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100546499B1 (ko) * | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
US6331597B1 (en) | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
US6362270B1 (en) | 1999-08-12 | 2002-03-26 | The Dow Chemical Company | Thermoplastic compositions for durable goods applications |
US6524702B1 (en) | 1999-08-12 | 2003-02-25 | Dow Global Technologies Inc. | Electrical devices having polymeric members |
ES2570753T3 (es) | 1999-08-17 | 2016-05-20 | Dow Global Technologies Llc | Composición polimérica fluida |
US6689830B1 (en) * | 1999-10-15 | 2004-02-10 | Velsicol Chemical Corporation | Film forming compositions containing benzoic acid esters of 8-carbon alcohols as additives |
CA2388704C (en) | 1999-10-23 | 2005-05-17 | Samsung General Chemicals Co., Ltd. | An improved catalyst for homo- and co-polymerization of olefin |
KR100361224B1 (ko) * | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
AU2731701A (en) | 2000-01-07 | 2001-07-24 | Dow Global Technologies Inc. | Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil |
US6649671B2 (en) | 2000-03-13 | 2003-11-18 | Dow Global Technologies Inc. | Concrete and process to make same |
US6605680B1 (en) | 2000-04-07 | 2003-08-12 | Eastman Chemical Resins, Inc. | Low color, aromatic modified C5 hydrocarbon resins |
KR100359932B1 (ko) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100387734B1 (ko) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | 올레핀 중합용 촉매 및 중합방법 |
EP1305364A1 (en) | 2000-07-20 | 2003-05-02 | Dow Global Technologies Inc. | Foam compositions from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers |
KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
KR100389477B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
US20040072936A1 (en) * | 2000-12-22 | 2004-04-15 | Sok-Won Kim | Polyolefin resin composition |
EP1362079B1 (en) * | 2000-12-22 | 2005-06-08 | Samsung General Chemicals Co., Ltd. | Polypropylene resin composition with improved surface hardness and scratch resistance properties |
JP3921448B2 (ja) * | 2000-12-22 | 2007-05-30 | サムソン ジェネラル ケミカルズ カンパニー リミテッド | 難燃性ポリプロピレン樹脂組成物 |
EP1358223A4 (en) * | 2000-12-22 | 2005-01-05 | Samsung General Chemicals Co | CHELATE CATALYST FOR OLEFIN POLYMERIZATION AND OLEFIN POLYMERIZATION METHOD USED |
KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100496776B1 (ko) * | 2001-06-21 | 2005-06-22 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
KR100530795B1 (ko) * | 2001-12-26 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
US20040106739A1 (en) * | 2002-02-19 | 2004-06-03 | Cheung Yunwa Wilson | Blends of substantially random interpolymers with enhanced thermal performance |
US7165676B2 (en) * | 2002-04-19 | 2007-01-23 | Smurfit-Stone Container Enterprises, Inc. | Heat seal blister package having improved moisture vapor transmission barrier and method for forming same |
US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
EP1558655B1 (en) | 2002-10-15 | 2012-08-29 | ExxonMobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
KR100484604B1 (ko) * | 2002-11-11 | 2005-04-20 | 삼성토탈 주식회사 | 열접착성 폴리프로필렌계 수지 조성물 |
US7204199B2 (en) * | 2004-03-23 | 2007-04-17 | Volk Enterprises, Inc. | Thermopolymeric switching mediums and temperature monitoring devices embodying such mediums |
US7807015B2 (en) * | 2006-09-18 | 2010-10-05 | Xerox Corporation | Adhesion promoter |
US10619081B2 (en) | 2017-05-22 | 2020-04-14 | H.B. Fuller Company | Hot melt adhesive composition |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5030090B1 (ja) * | 1973-12-20 | 1975-09-29 | ||
JPS50158642A (ja) * | 1974-06-13 | 1975-12-22 | ||
JPS5113173B2 (ja) * | 1971-11-10 | 1976-04-26 | ||
JPS5522518B2 (ja) * | 1971-10-15 | 1980-06-17 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3644252A (en) * | 1969-05-13 | 1972-02-22 | Velsicol Chemical Corp | Adhesive compositions containing styrene/isobutylene copolymer |
JPS5281393A (en) * | 1975-12-29 | 1977-07-07 | Chisso Corp | Improved process for preparing polybutene-1 |
US4937138A (en) * | 1988-02-29 | 1990-06-26 | Shell Oil Company | Hot melt polybutylene and poly(butylene/ethylene) adhesives and laminar structures |
CA1338546C (en) * | 1988-05-27 | 1996-08-20 | Kenneth William Powers | Para-alkylstyrene/isoolefin copolymers |
JP2894452B2 (ja) * | 1990-04-18 | 1999-05-24 | 三井化学株式会社 | α‐オレフィン・芳香族ビニルランダム共重合体およびその製造方法 |
-
1991
- 1991-04-17 DE DE1991611354 patent/DE69111354T2/de not_active Expired - Lifetime
- 1991-04-17 KR KR1019910701899A patent/KR950007714B1/ko not_active IP Right Cessation
- 1991-04-17 AT AT91908470T patent/ATE125285T1/de not_active IP Right Cessation
- 1991-04-17 CA CA 2062749 patent/CA2062749C/en not_active Expired - Fee Related
- 1991-04-17 EP EP91908470A patent/EP0478800B1/en not_active Expired - Lifetime
- 1991-04-17 US US07/778,208 patent/US5244996A/en not_active Expired - Lifetime
- 1991-04-17 WO PCT/JP1991/000508 patent/WO1991016386A1/ja active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5522518B2 (ja) * | 1971-10-15 | 1980-06-17 | ||
JPS5113173B2 (ja) * | 1971-11-10 | 1976-04-26 | ||
JPS5030090B1 (ja) * | 1973-12-20 | 1975-09-29 | ||
JPS50158642A (ja) * | 1974-06-13 | 1975-12-22 |
Also Published As
Publication number | Publication date |
---|---|
KR950007714B1 (ko) | 1995-07-14 |
CA2062749C (en) | 2002-07-02 |
EP0478800A1 (en) | 1992-04-08 |
US5244996A (en) | 1993-09-14 |
ATE125285T1 (de) | 1995-08-15 |
KR920702710A (ko) | 1992-10-06 |
DE69111354D1 (de) | 1995-08-24 |
EP0478800A4 (en) | 1992-09-23 |
CA2062749A1 (en) | 1991-10-19 |
EP0478800B1 (en) | 1995-07-19 |
DE69111354T2 (de) | 1995-12-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1991016386A1 (en) | Hot-melt adhesive | |
EP0016617B1 (en) | Laminated multilayer structure | |
TWI571496B (zh) | A coating agent, a decorative film and a molded body | |
WO1997010297A1 (fr) | Composition adhesive de resine polymere ethylenique, et stratifie produit a partir de ladite composition | |
EP0180478B1 (en) | Heat sealable plastics laminate | |
WO2000018815A1 (fr) | Resine de petrole en c9 hydrogenee et procede de production correspondant | |
KR100281851B1 (ko) | 접착성 수지조성물 및 그 조성물을 접착층용으로 사용한 적층체 | |
JPH0725825B2 (ja) | 接着剤用タツキフアイヤ− | |
KR920000013B1 (ko) | 폴리프로필렌 수지조성물 | |
JP2000345098A (ja) | コーティング剤 | |
WO2001005853A1 (fr) | Copolymere d'olefine | |
JP3039792B2 (ja) | ホットメルト接着剤 | |
CN1723253A (zh) | 热熔性粘合剂组合物 | |
JPH0649315A (ja) | 樹脂水性分散液 | |
CN100398591C (zh) | 丁基型橡胶粘合剂配混料 | |
JPH0977923A (ja) | 接着性エチレン系共重合体樹脂組成物およびその組成物を用いた積層体 | |
JP2002019060A (ja) | 積層体、その製造方法およびこの積層体を用いた容器 | |
JP3930515B2 (ja) | 接着性エチレン系共重合体樹脂組成物およびその組成物を用いた積層体 | |
JPS6128508A (ja) | 新規炭化水素樹脂およびそれを用いた接着剤用添加剤 | |
JP2003011301A (ja) | ポリプロピレン樹脂多層フィルム | |
JP2854088B2 (ja) | ポリオレフィン組成物 | |
JP2005213511A (ja) | 接着性エチレン系共重合体樹脂組成物およびその組成物を用いた積層体 | |
JPH0822894B2 (ja) | 変性炭化水素樹脂の製造方法 | |
JP2018039880A (ja) | オレフィン系樹脂組成物、その製造方法、成形体および積層体 | |
JP2000062117A (ja) | 積層フィルム |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): CA KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2062749 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1991908470 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1991908470 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 1991908470 Country of ref document: EP |