WO1988002019A1 - Intumescent material - Google Patents
Intumescent material Download PDFInfo
- Publication number
- WO1988002019A1 WO1988002019A1 PCT/GB1987/000650 GB8700650W WO8802019A1 WO 1988002019 A1 WO1988002019 A1 WO 1988002019A1 GB 8700650 W GB8700650 W GB 8700650W WO 8802019 A1 WO8802019 A1 WO 8802019A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- intumescent material
- material according
- binder
- graphite
- weight
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 95
- 239000011230 binding agent Substances 0.000 claims abstract description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000010439 graphite Substances 0.000 claims abstract description 50
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 50
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 11
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 4
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 claims abstract description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 3
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims abstract description 3
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004202 carbamide Substances 0.000 claims abstract description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 3
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000005011 phenolic resin Substances 0.000 claims abstract description 3
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 3
- 229920000728 polyester Polymers 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000004014 plasticizer Substances 0.000 claims description 8
- 238000004132 cross linking Methods 0.000 claims description 6
- 239000012744 reinforcing agent Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 239000004412 Bulk moulding compound Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 230000001427 coherent effect Effects 0.000 claims description 3
- 238000005345 coagulation Methods 0.000 claims description 2
- 230000015271 coagulation Effects 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 239000003431 cross linking reagent Substances 0.000 claims 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 8
- 229920000126 latex Polymers 0.000 description 8
- 239000004816 latex Substances 0.000 description 7
- 229920001187 thermosetting polymer Polymers 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 229920001084 poly(chloroprene) Polymers 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000004848 polyfunctional curative Substances 0.000 description 5
- 230000009970 fire resistant effect Effects 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 239000012763 reinforcing filler Substances 0.000 description 3
- 229940117958 vinyl acetate Drugs 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 238000009747 press moulding Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 2
- -1 zinc Chemical class 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000008259 solid foam Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
Definitions
- the present invention relates to intumescent material comprising expandible graphite in a polymeric binder.
- an intumescent material comprising expandable graphite in a polymeric binder.
- the intumescent material may further comprise at least one constituent selected from fillers and reinforcing agents.
- the intumescent material may be made by preparing a mixture of the expandible graphite, the polymeric binder and a liquid and causing or allowing the mixture to harden.
- the intumescent material is non-foamed or non-cellular i.e. free of pores or cells.
- the binder is a flexible or elastomeric binder.
- the graphite is preferably present in an amount of 15 to 60% by weight based on the combined weight of the binder and graphite.
- the graphite is present in an amount of at least 20% by weight based on the combined weight of the binder and graphite.
- the graphite is present in an amount not exceeding 55% by weight based on the combined weight of the binder and graphite.
- the binder and the graphite are present in a total amount of at least 70% by weight based on the weight of the intumescent material.
- the intumescent material according to the first aspect of the invention may comprise a plasticizer.
- the amount of the plasticizer preferably does not exceed 15% by weight based on the weight of the intumescent material .
- a suitable plasticizer is dibutyl phthalate.
- the intumescent material according to the first aspect of the invention may be made by preparing a mixture of the expandible graphite, the polymeric binder and water and causing or allowing the mixture to harden. Hardening may occur at least in part due to evaporation of water.
- the mixture may be liquid or formulated as a dough moulding compound.
- the flexible binder may be or comprise a polymer selected from vinyl acetate polymers, styrene polymers, vinyl chloride polymers , acrylic polymers, vinyl butyral polymers, melamine/urea/phenol formaldehyde resins, polyesters and phenolic resins.
- the intumescent material preferably co mprises 40 to 70% by weight of the binder and 25 to 60% by weight of the expandible graphite based on the combined weight of the binder and graphite.
- the intumescent material may be macie by preparing a mixture of the expandible graphite and a liquid emulsion of dispersion of the elastomeric binder and causing or allowing the mixture to cure by coagulation or cross-linking of the elastomeric binder.
- Suitable emulsions or dispersions of the elastomeric binder may comprise Neoprene latex 115 and Neoprene latex 671. These latices are marketed by Du Pent. Neoprene latex 115 is described as a chloroprene copolymer with carboxyl functionality of pH 7 .
- Neoprene latex 671 is described as polychloroprene in anionic colloidal system, pH 12.5.
- organic accelerators such as thiocarbanilide, diphenylguanidine or hexamethylenediamine
- the elastomeric binder may be a rubber.
- the elastomeric binder is preferably fire- or flame-resistant and/or self-extinguishing.
- the binder is a thermosetting formaldehyde resin.
- a resin is normally rigid (i.e. substantially non-flexible and non-elastomeric).
- thermosetting binder may be, for example, melamine formaldehyde resin, urea formaldehyde resin, phenol formaldehyde resin, resorcinol formaldehyde resin or a mixture of two or more of these resins.
- Melamine formaldehyde resin is particularly preferred as the thermosetting binder because it provides an intumescent material which can intumesce smoothly and free of sputtering of graphite particles.
- thermosetting binder may incorporate a minor proportion of one or more of the flexible polymers referred to above in order to improve the flexural properties and to reduce shrinkage of the binder.
- the intumescent material may comprise 20 to 60% by weight of melamine formaldehyde resin as the binder (calculated as uncross-linked resin) and 10 to 50%, more preferably 10 to 40%, by weight of the expandible graphite.
- the amount of the expandible graphite is in the range of 20 to 60% by weight based on the total weight of the binder and graphite.
- the intumescent material may be made by preparing a mixture of the expandible graphite and the binder and causing or allowing the mixture to harden by curing or cross-linking of the binder.
- the intumescent material according to the invention may expand, forming a solid foam or puff, to 8 to 25 times its original volume on heating to elevated temperature.
- the intumescent material according to the invention is fire resistant. Specifically, the solid form or puff formed on heating the material is fire-resistant.
- the intumescent material according to the invention is fire resistant. Specifically, the solid form or puff formed on heating the material is fire-resistant.
- the intumescent material according to the invention may comprise one or more reinforcing agents and/or fillers.
- Such reinforcing agents and fillers may be selected from glass fibre, cellulose-based fibre, chopped tissue, rcckwool, china clay, chalk, gypsum, silicas and mineral silicates e.g. calcium silicate.
- the intumescent material according to the invention may comprise, apart from the graphite, the polymeric binder, any plasticiser, any liquid (such as water or volatile organic liquid) derived from the manufacture of the material, any reinforcing agent, any filler and any catalyst, substantially no other component apart from any incidental impurities which may be present.
- the intumescent material of the invention may be made by a process comprising preparing a mixture of the expandible graphite, the polymeric binder and a liquid and causing or allowing the mixture to harden.
- the liquid may be water or an organic solvent.
- the graphite is dispersed (in particulate form) in the liquid and the polymeric binder is dispersed or dissolved in the liquid.
- the mixture is formulated as a viscous liquid mixture.
- the mixture may alternatively be formulated as a dough moulding compound for press moulding or extrusion.
- One or more reinforcing agents and/or fillers such as described above may be included in the mixture.
- the mixture may be formulated to be almost self-levelling.
- the dough moulding compound may be easily extruded into almost imrnediately handleable strips of the required dimensions, is unexpectedly tough after drying (e.g. carried in an oven at 60°C or by prolonged standing at room temperature), is resistant to creep on heating up to 200°C and does not need reinforcement to be incorporated.
- the mixture may be moulded into sheets of any convenient shape and cured to form the intumescent material or applied as a coating to a substrate and then cured to form the inturrescent material.
- Curing may be effected at ambient temperature particularly where the liquid mixture is in the form of a thin coating or layer. However, it may often be preferable to effect curing at elevated temperature, such as 50 to 60°C, such temperature obviously having to be kept below a temperature at which intumescence of the graphite or rapid dissolution of dissolved air (which would cause bubbles to form in the liquid mixture) would occur.
- elevated temperature such as 50 to 60°C
- curing is effected generally mainly by evaporation of water (or other liquid). However, curing may occur additpenally or alternatively by cross-linking of the polymeric binder.
- the binder is a rubber
- one or more compounds selected from oxides and salts of metals, such as zinc may be used to accelerate hardening of the rubber.
- Zinc borate is a suitable zinc salt for this purpose. It has been found that the intumescent material according to the first aspect of the invention and made by the above-described method is flexible and is not adversely affected by carbon dioxide and moisture. In fact the material is virtually waterproof.
- hardening of the mixture may occur wholly or mainly by cross-linking or curing of the thermosetting resin.
- the mixture may be cured at, e.g. around 60°C, between platens in a heated press.
- the platens may have a covering of e.g. polyethylene sheets, to prevent adhesion of the intumescent material to the platens.
- the liquid mixture may further comprise one or more of: water, a hardener or catalyst, a filler, dicyandiamide (or other polyamido compound), and another polymeric binder.
- the hardener or catalyst or dicyandiamide (or other polyamido compound) may act to cross-link or cure the thermosetting resin.
- the hardener or catalyst may be an acid catalyst or hardener.
- Suitable catalysts or hardeners include hydrochloric acid, sulphuric acid, phosphoric acid, organic acids such as formic acid, acetic acid, maleic acid, malic acid, tartaric acid and citric acid, ammonium phosphates and alkali metal phosphates.
- the invention further provides: a structure defining a gap and including an intumescent material according to the invention, the intjumescent material being arranged so that at elevated temperature as under fire conditions when the material intumesces it closes the gap; an intumescent seal comprising a coherent and self-supporting body of intumescent material according to the invention; the body preferably being shaped to form the seal; and an intumescent seal comprising a holder and intumescent material according to the invention, the intumescent material expanding from the holder at elevated temperature as under fire conditions.
- the material can be manufactured to any required thickness and needs no added protection.
- the material when cured is completely resistant to carbon dioxide, and water and can withstand prolonged exposure to water without its intumescent properties being affected.
- the material can be bent to almost any radius without breaking or fracturing.
- the intumescent material is unexpectedly flexible as compared with the thermoplastic polymer itself. This is perhaps because of an internal lubricating effect of the graphite.
- parts by weight are preferably based on a total of 100 parts by weight of the components listed in the Table.
- the melamine formaldehyde referred to in the Table is substantially uncross-linked initially when incorporated into the liquid mixture.
- the liquid mixture will cure to form the intumescent material within 1 to 2 hours when pumped into a suitable holder of e.g. aluminium or polyvinyl chloride (pvc). It is unnecessary to allow for evaporation of water to effect hardening.
- a suitable holder of e.g. aluminium or polyvinyl chloride (pvc). It is unnecessary to allow for evaporation of water to effect hardening.
- the liquid mixture sets to a hard solid which can be machined to a desired shape.
- the hardened solid intumescent material is substantially completely resistant to carbon dioxide and water vapour and can withstand prolonged exposure to water without its intumescent properties being affected.
- the hardened intumescent material exerts a considerable expansion force on being heated to elevated temperature.
- the intumescent material has an unexpectedly smooth, and hence aesthetically pleasing surface.
- the intumescent material may be moulded, or otherwise shaped, to form an intumescent seal, which may be elongate and of substantially uniform cross-section (or of any other shape), and does not require a holder since the material itself is sufficiently coherent, sufficiently strong and has a sufficient degree of rigidity to form the seal itself and itself provides a suitable, aesthetically acceptable, surface for the seal.
- the seal may itself be shaped, e.g. by the provision of a re-entrant or undercut groove along its length, so that it may itself act as a holder for a smoke seal or other resilient sealing member. 7.
- the hardness of the intumescent material and the lack of need for a holder make it suitable for use in vandal-resistant seals.
- the intumescent material unexpectedly has the property of delayed intumescence. I.e. it does not start to intumesce immediately on being raised to a high temperature. This is of particular advantage in certain circumstances.
- Intumescent material according to the invention may be used as sealing strips for doers and windows, in pipe closures as a pressure and gap filling sealant, as coatings on ventilator grilles or as material from which ventilator grilles are moulded, in penetration seals, in glazing panels and other panels, in hinges, locks and in other situations where conflagration needs holding back.
- the intumescent material according to the invention may have a very low toxicity.
- Examples 1, 4, 5 and 6 relate to the first aspect of the invention.
- Examples 2 and 3 relates to the second aspect of the invention.
- the expandible graphite used in the examples is particulate. It was obtained from Fosecotechnik Limited and was in the form of free-flowing platelets.
- Vinamul 9340 is an aqueous emulsion or dispersion of vinylacetate/ethylene copolymer manufactured by Vinamul Limited of Carshalton, Surrey, England. Vinamul 9340 comprises 60% by weight of polyvinylacetate and 5% by weight dibutyl phthalate as plasticiser.
- the viscous liquid mixture comprised:
- a strip of material prepared in accordance with this example and having a cross section of 2mm x 10mm was heated.
- a force of approximately 1000 Newtons per metre length of the strip was generated. This compares well with Palusol, a proprietary sodium silicate based intumescent product, up to about 320°C and much more favourably at higher temperatures.
- Aqueous formic acid (50% w/w) 6 p.b.w.
- Aerolite 308 is a substantially uncross-linked melamine formaldehyde resin supplied by Ciba-Geigy.
- the mixture was a viscous but virtually self-levelling liquid which, at 20 degrees C, sets to a fairly hard mass within 2 hours. It was found that the rate of hardening could be accelerated by increasing the temperature.
- This formulation is more shrink resistant than the mixture of Example 2, but is also virtually self levelling, setting to a hard mass within 2 hours at 20°C.
- the mixture was then cured.
- the curing is accelerated by increasing the temperature to 60°C.
- the mixture can be thickened with suitable fillers and cured by a two stage pressing process at 60°C, the excess water being allcrwed to evaporate after the first pressing, the partially cured sheet being then layered into small pieces and again pressed.
- the resulting sheet is tough and elastic.
- This mixture was a material of dough-like consistency.
- the material was cured by initially pressing at 60°C for 5 minutes to form a sheet, allowing the sheet to "breathe” for a further 5 minutes to aliow the excess water to evaporate and then reforming the sheet under pressure for a further 5 minutes and allcrwing the sheet to dry.
- MR Revultex latex is a pre-vulcanised natural rubber latex marketed by Revertex Limited of Harlow, England.
- a heat-sensitive coagulant such as polyvinyl methyl ether (e.g. as marketed under the trade name "Lutonal”) could be included in the above-mentioned mixture.
- Vinapol 1080 powder 25 p.b.w. Dibutyl phthalate 2 p.b.w.
- This mixture was of dough like consistency and could be moulded by extrusion or press moulding. After drying the material was tough and flexible.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87905956T ATE86647T1 (en) | 1986-09-17 | 1987-09-17 | INTUMESCING MATERIAL. |
DE19873784727 DE3784727T2 (en) | 1986-09-17 | 1987-09-17 | INTUMESCENT MATERIAL. |
GB8826879A GB2212505B (en) | 1986-09-17 | 1988-11-17 | Intumescent material |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8622341 | 1986-09-17 | ||
GB868622341A GB8622341D0 (en) | 1986-09-17 | 1986-09-17 | Intumescent material |
GB868622823A GB8622823D0 (en) | 1986-09-23 | 1986-09-23 | Intumescent material |
GB8622823 | 1986-09-24 | ||
GB868623157A GB8623157D0 (en) | 1986-09-26 | 1986-09-26 | Intumescent material |
GB8623157 | 1986-09-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1988002019A1 true WO1988002019A1 (en) | 1988-03-24 |
Family
ID=27263152
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1987/000650 WO1988002019A1 (en) | 1986-09-17 | 1987-09-17 | Intumescent material |
Country Status (7)
Country | Link |
---|---|
US (1) | US4945015A (en) |
EP (1) | EP0315649B1 (en) |
AU (1) | AU602008B2 (en) |
CA (1) | CA1295782C (en) |
GB (1) | GB2212505B (en) |
NZ (1) | NZ221842A (en) |
WO (1) | WO1988002019A1 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989009808A1 (en) * | 1988-04-07 | 1989-10-19 | Chemie Linz Gesellschaft M.B.H. | Latex-bound fireproofing material |
US5232976A (en) * | 1988-04-07 | 1993-08-03 | Chemie Linz Gesellschaft M.B.H. | Thermally expandable fire-protection composition comprising expandable graphite, chloroprene latex and compounds forming a paracrystalline carbon skeleton |
WO1994011462A1 (en) * | 1992-11-18 | 1994-05-26 | Environmental Seals Limited | Intumescent products |
EP0835900A2 (en) * | 1996-10-14 | 1998-04-15 | Dr. Wolman GmbH | Elastic articles |
US5847105A (en) * | 1994-03-16 | 1998-12-08 | California Institute Of Technology | Methods for performing multiple sequential reactions on a matrix |
WO1999035196A1 (en) * | 1998-01-02 | 1999-07-15 | Georgia-Pacific Resins, Inc. | Intumescent composition and method |
US5958342A (en) * | 1996-05-17 | 1999-09-28 | Incyte Pharmaceuticals, Inc. | Jet droplet device |
WO1999060074A1 (en) * | 1998-05-15 | 1999-11-25 | Pfc Surechem Limited | Intumescent composition |
GB2359308A (en) * | 2000-02-07 | 2001-08-22 | Graftech Inc | Expandable graphite as a flame retardant in unsaturated polyester resins |
GB2360797A (en) * | 2000-01-19 | 2001-10-03 | James Edward Murray | Fire penetration seal |
CN107349537A (en) * | 2017-07-20 | 2017-11-17 | 合肥安力电力工程有限公司 | A kind of Phase of Electric Power Projects back-fire relief bag and preparation method thereof |
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DE3917518A1 (en) * | 1989-05-30 | 1990-12-06 | Bayer Ag | FIRE PROTECTION ELEMENTS |
DE4007075A1 (en) * | 1990-03-07 | 1991-09-12 | Bayer Ag | INTUMESCENT MOLDED PARTS |
DE4117074A1 (en) * | 1991-05-25 | 1992-11-26 | Bayer Ag | METHOD FOR PRODUCING MOLDED BODIES |
US5498466A (en) * | 1993-03-12 | 1996-03-12 | International Protective Coatings Corp. | Intumescent composite |
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US6641143B2 (en) | 2002-01-18 | 2003-11-04 | The Metraflex Company | Multi-linked seal assembly having material that swells when exposed to fire |
US6809129B2 (en) * | 2002-01-23 | 2004-10-26 | Delphi Technologies, Inc. | Elastomeric intumescent material |
US6706793B2 (en) | 2002-01-23 | 2004-03-16 | Delphi Technologies, Inc. | Intumescent fire retardant composition and method of manufacture thereof |
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US20040123541A1 (en) * | 2002-12-27 | 2004-07-01 | Jewett Scott E. | Reinforced wall structure for blast protection |
JP3945583B2 (en) * | 2004-01-15 | 2007-07-18 | 憲司 中村 | Method for producing cosmetic applicator |
US20060011108A1 (en) * | 2004-07-13 | 2006-01-19 | Abu-Isa Ismat A | Fire resistant plastic pallet |
US7279516B2 (en) * | 2004-11-02 | 2007-10-09 | Solutia Incorporated | Polymer sheets comprising higher order phosphate esters |
US7238427B2 (en) * | 2004-11-02 | 2007-07-03 | Solutia Incorporated | Fire resistant polymer sheets |
US7399525B2 (en) * | 2004-11-02 | 2008-07-15 | Solutia Incorporated | Polymer sheets comprising a fluoropolymer |
GB0507940D0 (en) * | 2005-04-20 | 2005-05-25 | Foseco Int | Seal |
US7547650B2 (en) * | 2006-03-07 | 2009-06-16 | Missing Octave Insights, Inc. | Flame retardant multicomponent articles |
US20090111345A1 (en) | 2007-10-24 | 2009-04-30 | Dattatreya Panse | Thermally protective materials |
US10364527B2 (en) * | 2007-10-24 | 2019-07-30 | W. L. Gore & Associates, Inc. | Burn protective materials |
US20090110919A1 (en) * | 2007-10-24 | 2009-04-30 | Dattatreya Panse | Burn protective materials |
US20100280200A1 (en) * | 2009-03-24 | 2010-11-04 | Poddar Tarun K | Water Permeable Fluoropolymer Articles |
CA2824065C (en) * | 2011-01-28 | 2016-04-05 | W.L. Gore & Associates Gmbh | Laminar structure providing adaptive thermal insulation |
US8808850B2 (en) | 2011-10-25 | 2014-08-19 | Arclin | Water resistant intumescent fire retardant coating |
EP2604363A1 (en) | 2011-12-16 | 2013-06-19 | Vesuvius Crucible Company | intumescent sealing for metal casting apparatus |
US9927061B2 (en) | 2012-07-27 | 2018-03-27 | W. L. Gore & Associates Gmbh | Envelope for a laminar structure providing adaptive thermal insulation |
KR20150034247A (en) | 2012-07-31 | 2015-04-02 | 더블유.엘.고어 앤드 어소시에이츠 게엠베하 | Envelope for a laminar structure providing adaptive thermal insulation |
RU2015106986A (en) | 2012-07-31 | 2016-09-27 | В.Л. Гор Унд Ассошиэйтс Гмбх | SHELL COMBINATION FOR A LAYERED STRUCTURE PROVIDING ADAPTIVE HEAT INSULATION AND HEAT PROTECTION SCREEN |
WO2015054629A2 (en) * | 2013-10-11 | 2015-04-16 | Akrofire, Inc. | Loose fill fire-protective packing media |
PL3094483T3 (en) * | 2014-01-17 | 2024-03-18 | Silcart S.P.A. | Support layer of an insulation panel for construction |
US20150218403A1 (en) * | 2014-02-03 | 2015-08-06 | 3M Innovative Properties Company | Intumescent caulking compositions and methods |
US10487218B2 (en) | 2014-04-10 | 2019-11-26 | Gcp Applied Technologies Inc. | Fire retardant coating composition |
FR3072041B1 (en) | 2017-10-09 | 2019-11-29 | Railtech International | MOLDING ASSEMBLY FOR ALUMINO-THERMAL RAIL SOLDERING AND ALUMINO-THERMAL RAILS SOLDERING PROCESS |
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FR2265838A1 (en) * | 1974-03-29 | 1975-10-24 | Chemie Linz Ag | |
FR2411868A1 (en) * | 1977-12-15 | 1979-07-13 | Chemie Linz Ag | COATING SYSTEM PROVIDING PROTECTION AGAINST FIRE AND PROCESS FOR PROTECTING METAL, CONCRETE OR SIMILAR CONSTRUCTION ELEMENTS IN THE EVENT OF FIRE |
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GB1404822A (en) * | 1972-05-09 | 1975-09-03 | Ici Ltd | Foamed polymers |
GB8432153D0 (en) * | 1984-12-20 | 1985-01-30 | Dunlop Ltd | Polyurethane foams |
GB8611671D0 (en) * | 1986-05-13 | 1986-06-18 | Dunlop Ltd | Flame-retardent latex foams |
-
1987
- 1987-09-17 AU AU79132/87A patent/AU602008B2/en not_active Ceased
- 1987-09-17 CA CA000547195A patent/CA1295782C/en not_active Expired - Fee Related
- 1987-09-17 WO PCT/GB1987/000650 patent/WO1988002019A1/en active IP Right Grant
- 1987-09-17 US US07/340,297 patent/US4945015A/en not_active Expired - Lifetime
- 1987-09-17 NZ NZ221842A patent/NZ221842A/en unknown
- 1987-09-17 EP EP87905956A patent/EP0315649B1/en not_active Expired - Lifetime
-
1988
- 1988-11-17 GB GB8826879A patent/GB2212505B/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2265838A1 (en) * | 1974-03-29 | 1975-10-24 | Chemie Linz Ag | |
FR2411868A1 (en) * | 1977-12-15 | 1979-07-13 | Chemie Linz Ag | COATING SYSTEM PROVIDING PROTECTION AGAINST FIRE AND PROCESS FOR PROTECTING METAL, CONCRETE OR SIMILAR CONSTRUCTION ELEMENTS IN THE EVENT OF FIRE |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989009808A1 (en) * | 1988-04-07 | 1989-10-19 | Chemie Linz Gesellschaft M.B.H. | Latex-bound fireproofing material |
US5232976A (en) * | 1988-04-07 | 1993-08-03 | Chemie Linz Gesellschaft M.B.H. | Thermally expandable fire-protection composition comprising expandable graphite, chloroprene latex and compounds forming a paracrystalline carbon skeleton |
WO1994011462A1 (en) * | 1992-11-18 | 1994-05-26 | Environmental Seals Limited | Intumescent products |
GB2273100A (en) * | 1992-11-18 | 1994-06-08 | Environmental Seals Ltd | Intumescent products |
GB2273100B (en) * | 1992-11-18 | 1997-01-08 | Environmental Seals Ltd | Intumescent products |
US6015880A (en) * | 1994-03-16 | 2000-01-18 | California Institute Of Technology | Method and substrate for performing multiple sequential reactions on a matrix |
US5847105A (en) * | 1994-03-16 | 1998-12-08 | California Institute Of Technology | Methods for performing multiple sequential reactions on a matrix |
US5958342A (en) * | 1996-05-17 | 1999-09-28 | Incyte Pharmaceuticals, Inc. | Jet droplet device |
US6001309A (en) * | 1996-05-17 | 1999-12-14 | Incyte Pharmaceuticals, Inc. | Jet droplet device |
EP0835900A3 (en) * | 1996-10-14 | 1998-07-22 | Dr. Wolman GmbH | Elastic articles |
EP0835900A2 (en) * | 1996-10-14 | 1998-04-15 | Dr. Wolman GmbH | Elastic articles |
WO1999035196A1 (en) * | 1998-01-02 | 1999-07-15 | Georgia-Pacific Resins, Inc. | Intumescent composition and method |
US6228914B1 (en) | 1998-01-02 | 2001-05-08 | Graftech Inc. | Intumescent composition and method |
WO1999060074A1 (en) * | 1998-05-15 | 1999-11-25 | Pfc Surechem Limited | Intumescent composition |
GB2360797A (en) * | 2000-01-19 | 2001-10-03 | James Edward Murray | Fire penetration seal |
GB2360797B (en) * | 2000-01-19 | 2004-03-24 | James Edward Murray | Building services penetration seal |
GB2359308A (en) * | 2000-02-07 | 2001-08-22 | Graftech Inc | Expandable graphite as a flame retardant in unsaturated polyester resins |
CN107349537A (en) * | 2017-07-20 | 2017-11-17 | 合肥安力电力工程有限公司 | A kind of Phase of Electric Power Projects back-fire relief bag and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
US4945015A (en) | 1990-07-31 |
AU602008B2 (en) | 1990-09-27 |
AU7913287A (en) | 1988-04-07 |
GB2212505B (en) | 1990-07-25 |
NZ221842A (en) | 1990-05-28 |
CA1295782C (en) | 1992-02-11 |
GB2212505A (en) | 1989-07-26 |
GB8826879D0 (en) | 1989-03-22 |
EP0315649A1 (en) | 1989-05-17 |
EP0315649B1 (en) | 1993-03-10 |
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