USRE32428E - Amorphous antipilferage marker - Google Patents
Amorphous antipilferage marker Download PDFInfo
- Publication number
- USRE32428E USRE32428E US06/740,490 US74049085A USRE32428E US RE32428 E USRE32428 E US RE32428E US 74049085 A US74049085 A US 74049085A US RE32428 E USRE32428 E US RE32428E
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- US
- United States
- Prior art keywords
- marker
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- recited
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B13/00—Burglar, theft or intruder alarms
- G08B13/22—Electrical actuation
- G08B13/24—Electrical actuation by interference with electromagnetic field distribution
- G08B13/2402—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting
- G08B13/2405—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting characterised by the tag technology used
- G08B13/2408—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting characterised by the tag technology used using ferromagnetic tags
- G08B13/2411—Tag deactivation
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/008—Amorphous alloys with Fe, Co or Ni as the major constituent
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- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B13/00—Burglar, theft or intruder alarms
- G08B13/22—Electrical actuation
- G08B13/24—Electrical actuation by interference with electromagnetic field distribution
- G08B13/2402—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting
- G08B13/2428—Tag details
- G08B13/2437—Tag layered structure, processes for making layered tags
- G08B13/2442—Tag materials and material properties thereof, e.g. magnetic material details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
Abstract
Description
TABLE I __________________________________________________________________________ Composition Percent Fe Co Ni Mo B P Si __________________________________________________________________________ Fe--Ni--Mo--B atom % 40 -- 40 2 18 -- -- weight % 45 -- 47 4 4 -- -- Fe--Ni--P--B atom % 39.2 -- 40.2 -- 6.2 14.4 -- weight % 43.23 -- 46.62 -- 1.32 8.83 -- Fe--Ni--B atom % 40 -- 40 -- 20 -- -- weight % 46.6 -- 48.9 -- 4.5 -- -- Fe--B atom % 79.7 -- -- -- 20.3 -- -- weight % 95.38 -- -- -- 4.62 -- -- Fe--Mo--B atom % 77.5 -- -- 2.5 20 -- -- weight % 90.47 -- -- 5.01 4.52 -- -- Co--Fe--Mo--B--Si atom % 5.5 67.5 -- 2 12 -- 13 weight % 6.19 80 -- 3.86 2.61 -- 7.34 __________________________________________________________________________
TABLE II ______________________________________ Composition Percent Example 1 Example 2 ______________________________________ Ni Atom % 71.67 Ni Atom % 65.63 Weight % 84.40 Weight % 76.97 Cr Atom % 5.75 Cr Atom % 11.55 Weight % 6 Weight % 12.0 B Atom % 12.68 B Atom % 11.58 Weight % 2.75 Weight % 2.5 Si Atom % 7.10 Si Atom % 7.13 Weight % 4 Weight % 4 Fe Atom % 2.23 Fe Atom % 3.14 Weight % 2.5 weight % 3.5 C Atom % .25 C Atom % .12 Weight % .06 Weight % .03 P Atom % .032 P Atom % -- Weight % .02 Weight % -- S Atom % .031 S Atom % -- Weight % .02 Weight % -- Al Atom % .093 Al Atom % -- Weight % .05 Weight % -- Ti Atom % .052 Ti Atom % -- Weight % .05 Weight % -- Zr Atom % .027 Zr Atom % -- Weight % .05 Weight % -- Co Atom % .085 Co Atom % .85 Weight % .1 Weight % 1.0 ______________________________________
______________________________________ Strip # Composition (Atom %) Dimensions (Cm) Material ______________________________________ 1 Fe.sub.40 Ni.sub.40 Mo.sub.2 B.sub.18 10.2 × .318 Amorphous 2 (Co.sub.925 Fe.sub.075).sub.73 Mo.sub.2 B.sub.12 Si.sub.13 10.2 × .318 Amorphous 3 Fe.sub.81 C.sub.2 Si.sub.4.5 B.sub.12.5 10.2 × .318 Amorphous 4 Fe.sub.40 Ni.sub.40 B.sub.20 10.2 × .135 Amorphous 5 Conetic Permalloy -- Crystalline ______________________________________
______________________________________ Strip # Condition of Material Activated Alarm ______________________________________ 1 before bending yes after bending yes 2 before bending yes after bending yes 3 before bending yes after bending yes 4 before bending yes after bending yes 5 before bending yes after bending no ______________________________________
TABLE III __________________________________________________________________________ Dimensions Harmonic Signal Sample Wdt. Thk Before After Mandrel After No. Composition Structure mm m Flexure Bend* U-Bend** __________________________________________________________________________ 1 Fe.sub.40 Ni.sub.40 P.sub.14 B.sub.6 Amorphous 0.97 38 44 46 42 2 Fe.sub.85 B.sub.15 Amorphous 1.09 31 86 88 78 3 Fe.sub.40 Ni.sub.40 Mo.sub.2 B.sub.18 Amorphous 1.85 61 140 135 130 4 Co.sub.72 Fe.sub.6 Mo.sub.2 B.sub.15 Si.sub.5 Amorphous 1.91 38 167 167 150 5 Fe.sub.67 Co.sub.18 B.sub.14 Si.sub.1 Amorphous 1.73 46 140 140 115 6 Ni.sub.50 Fe.sub.50 Crystalline 2.26 58 32 7 6 (Deltamax) 7 Ni.sub.80 Fe.sub.15 Mo.sub.5 Crystalline 4.1 25 71 56 56 (Supermalloy) 8 Fe.sub.40 Ni.sub.40 B.sub.20 Amorphous 1.68 51 63 65 63 9 Fe.sub.81 B.sub.13 Si.sub.4 C.sub.2 Amorphous 2.06 31 72 74 76 10 Fe.sub.80 B.sub.20 Amorphous .97 38 44 46 42 11 Fe.sub.30 Ni.sub.50 B.sub.20 Amorphous 1.30 51 37 32 42 12 Fe.sub.80 C.sub.7 P.sub.13 Amorphous 1.02 48 65 64 30 13 Fe.sub.78 Mo.sub.2 B.sub.20 Amorphous 1.45 46 50 50 45 __________________________________________________________________________ *Helical Wrap on a 5.0 mm diameter mandrel **Ubent to a bend diameter of 22 times ribbon thickness
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/740,490 USRE32428E (en) | 1979-04-23 | 1985-06-03 | Amorphous antipilferage marker |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/032,196 US4298862A (en) | 1979-04-23 | 1979-04-23 | Amorphous antipilferage marker |
US06/292,456 US4484184A (en) | 1979-04-23 | 1981-08-13 | Amorphous antipilferage marker |
US06/740,490 USRE32428E (en) | 1979-04-23 | 1985-06-03 | Amorphous antipilferage marker |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/032,196 Continuation-In-Part US4298862A (en) | 1979-04-23 | 1979-04-23 | Amorphous antipilferage marker |
US06/292,456 Reissue US4484184A (en) | 1979-04-23 | 1981-08-13 | Amorphous antipilferage marker |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE32428E true USRE32428E (en) | 1987-05-26 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/740,490 Expired - Lifetime USRE32428E (en) | 1979-04-23 | 1985-06-03 | Amorphous antipilferage marker |
Country Status (1)
Country | Link |
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US (1) | USRE32428E (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0291726A2 (en) * | 1987-05-21 | 1988-11-23 | Vacuumschmelze GmbH | Amorphous alloy for strip-shaped sensor elements |
US5003291A (en) * | 1988-12-27 | 1991-03-26 | Strom Olsen John O | Ferromagnetic fibers having use in electronical article surveillance and method of making same |
US5015992A (en) * | 1989-06-29 | 1991-05-14 | Pitney Bowes Inc. | Cobalt-niobium amorphous ferromagnetic alloys |
US5015993A (en) * | 1989-06-29 | 1991-05-14 | Pitney Bowes Inc. | Ferromagnetic alloys with high nickel content and high permeability |
US5338373A (en) | 1991-08-20 | 1994-08-16 | Vonhoene Robert M | Method of encoding and decoding a glassy alloy strip to be used as an identification marker |
USRE35042E (en) * | 1983-02-04 | 1995-09-26 | Allied Corporation | Amorphous antipilferage marker |
WO1996001910A1 (en) * | 1994-07-08 | 1996-01-25 | Sensormatic Electronics Corporation | High response electronic article surveillance system responders and methods for producing same |
US5745039A (en) * | 1997-02-21 | 1998-04-28 | Minnesota Mining And Manufacturing Company | Remote sterilization monitor |
US20050033544A1 (en) * | 2001-12-10 | 2005-02-10 | Brooks Colin Philip | Detectable components and detection apparatus for detecting such components |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665449A (en) * | 1969-07-11 | 1972-05-23 | Minnesota Mining & Mfg | Method and apparatus for detecting at a distance the status and identity of objects |
US3820104A (en) * | 1972-12-15 | 1974-06-25 | Stop Loss Inc | Method and system for detecting an object within a magnetic field interrogation zone |
US3856513A (en) * | 1972-12-26 | 1974-12-24 | Allied Chem | Novel amorphous metals and amorphous metal articles |
US3938125A (en) * | 1974-02-20 | 1976-02-10 | Minnesota Mining And Manufacturing Company | Antipilferage system and marker therefor |
US3990065A (en) * | 1975-02-20 | 1976-11-02 | The Magnavox Company | Theft detection system |
US4030892A (en) * | 1976-03-02 | 1977-06-21 | Allied Chemical Corporation | Flexible electromagnetic shield comprising interlaced glassy alloy filaments |
US4036638A (en) * | 1975-11-13 | 1977-07-19 | Allied Chemical Corporation | Binary amorphous alloys of iron or cobalt and boron |
US4067732A (en) * | 1975-06-26 | 1978-01-10 | Allied Chemical Corporation | Amorphous alloys which include iron group elements and boron |
US4074249A (en) * | 1977-02-04 | 1978-02-14 | Knogo Corporation | Magnetic detection means |
US4075618A (en) * | 1976-07-15 | 1978-02-21 | Minnesota Mining And Manufacturing Company | Magnetic asymmetric antipilferage marker |
US4148973A (en) * | 1976-12-15 | 1979-04-10 | Allied Chemical Corporation | Homogeneous, ductile brazing foils |
US4221257A (en) * | 1978-10-10 | 1980-09-09 | Allied Chemical Corporation | Continuous casting method for metallic amorphous strips |
US4249167A (en) * | 1979-06-05 | 1981-02-03 | Magnavox Government And Industrial Electronics Company | Apparatus and method for theft detection system having different frequencies |
US4257830A (en) * | 1977-12-30 | 1981-03-24 | Noboru Tsuya | Method of manufacturing a thin ribbon of magnetic material |
US4298862A (en) * | 1979-04-23 | 1981-11-03 | Allied Chemical Corporation | Amorphous antipilferage marker |
-
1985
- 1985-06-03 US US06/740,490 patent/USRE32428E/en not_active Expired - Lifetime
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665449A (en) * | 1969-07-11 | 1972-05-23 | Minnesota Mining & Mfg | Method and apparatus for detecting at a distance the status and identity of objects |
US3820104A (en) * | 1972-12-15 | 1974-06-25 | Stop Loss Inc | Method and system for detecting an object within a magnetic field interrogation zone |
US3856513A (en) * | 1972-12-26 | 1974-12-24 | Allied Chem | Novel amorphous metals and amorphous metal articles |
US3938125A (en) * | 1974-02-20 | 1976-02-10 | Minnesota Mining And Manufacturing Company | Antipilferage system and marker therefor |
US3990065A (en) * | 1975-02-20 | 1976-11-02 | The Magnavox Company | Theft detection system |
US4067732A (en) * | 1975-06-26 | 1978-01-10 | Allied Chemical Corporation | Amorphous alloys which include iron group elements and boron |
US4036638A (en) * | 1975-11-13 | 1977-07-19 | Allied Chemical Corporation | Binary amorphous alloys of iron or cobalt and boron |
US4030892A (en) * | 1976-03-02 | 1977-06-21 | Allied Chemical Corporation | Flexible electromagnetic shield comprising interlaced glassy alloy filaments |
US4075618A (en) * | 1976-07-15 | 1978-02-21 | Minnesota Mining And Manufacturing Company | Magnetic asymmetric antipilferage marker |
US4148973A (en) * | 1976-12-15 | 1979-04-10 | Allied Chemical Corporation | Homogeneous, ductile brazing foils |
US4074249A (en) * | 1977-02-04 | 1978-02-14 | Knogo Corporation | Magnetic detection means |
US4257830A (en) * | 1977-12-30 | 1981-03-24 | Noboru Tsuya | Method of manufacturing a thin ribbon of magnetic material |
US4221257A (en) * | 1978-10-10 | 1980-09-09 | Allied Chemical Corporation | Continuous casting method for metallic amorphous strips |
US4298862A (en) * | 1979-04-23 | 1981-11-03 | Allied Chemical Corporation | Amorphous antipilferage marker |
US4249167A (en) * | 1979-06-05 | 1981-02-03 | Magnavox Government And Industrial Electronics Company | Apparatus and method for theft detection system having different frequencies |
Non-Patent Citations (23)
Title |
---|
"Amorphous Ferromagnetic Materials-Magnetic Fundamentals, Properties and Applications," Hilzinger et al., Journal of Magnetism and Magnetic Materials 9 (1978), pp. 191-199. |
"Breakthrough In Magnetic Materials", Solid-State Power Conversion (March/April 1975). |
"Magnetic Circuits and Transformers," Staff of the Department of Electrical Engineering, Massachusetts Institute of Technology (1943), pp. 34-36. |
Allied Chemical Corporation Product Availability Sheet (Dec. 15, 1977). * |
Allied Chemical Corporation Product Availability Sheet (Dec. 2, 1974). * |
Allied Chemical Corporation Product Availability Sheet (Nov. 7, 1977). * |
Amorphous Ferromagnetic Materials Magnetic Fundamentals, Properties and Applications, Hilzinger et al., Journal of Magnetism and Magnetic Materials 9 (1978), pp. 191 199. * |
Breakthrough In Magnetic Materials , Solid State Power Conversion (March/April 1975). * |
Egami et al., "Amorphous Alloys as Soft Magnetic Materials", AIP Conference Proceedings (1975). |
Egami et al., Amorphous Alloys as Soft Magnetic Materials , AIP Conference Proceedings (1975). * |
Fahlenbrach, "Techn Mitt. Krupp-Werksber., 30, 149 (1972). |
Fahlenbrach, Techn Mitt. Krupp Werksber., 30, 149 (1972). * |
Hilzinger, H. R. et al., "Amorphous Ferromagnetic Materials-Magnetic Fundamentals, Properties and Applications," Journal of Magnetism and Magnetic Materials IX (1978), pp. 191-199. |
Hilzinger, H. R. et al., Amorphous Ferromagnetic Materials Magnetic Fundamentals, Properties and Applications, Journal of Magnetism and Magnetic Materials IX (1978), pp. 191 199. * |
Luborsky et al., "Magnetic Annealing of Amorphous Alloys", IEEE Trans. on Magnetics, vol. Mag-11, No. 6, pp. 1644-1649 (Nov. 1975). |
Luborsky et al., Magnetic Annealing of Amorphous Alloys , IEEE Trans. on Magnetics, vol. Mag 11, No. 6, pp. 1644 1649 (Nov. 1975). * |
Magnetic Circuits and Transformers, Staff of the Department of Electrical Engineering, Massachusetts Institute of Technology (1943), pp. 34 36. * |
Mendelsohn et al., "Glassy Metal Fabric: A Unique Magnetic Shield", IEEE Trans. on Magnetic, vol. Mag-12, No. 6, pp. 924-926 (Nov. 1976). |
Mendelsohn et al., Glassy Metal Fabric: A Unique Magnetic Shield , IEEE Trans. on Magnetic, vol. Mag 12, No. 6, pp. 924 926 (Nov. 1976). * |
O Handley, R. C., et al. Ferromagnetic Properties of Some New Metallic Glasses, Applied Physics Letters, XXIX, 6, pp. 230 232, XXXIX, 6, pp. 330 332. * |
O'Handley, R. C., et al. "Ferromagnetic Properties of Some New Metallic Glasses," Applied Physics Letters, XXIX, 6, pp. 230-232, XXXIX, 6, pp. 330-332. |
Sellers, "METGLAS® Alloys: An Answer to Low Frequency Magnetic Shielding", IEEE 1977 International Symposium on Electromagnetic Compatibility, Seattle, Washington (Aug. 24, 1977). |
Sellers, METGLAS Alloys: An Answer to Low Frequency Magnetic Shielding , IEEE 1977 International Symposium on Electromagnetic Compatibility, Seattle, Washington (Aug. 24, 1977). * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE35042E (en) * | 1983-02-04 | 1995-09-26 | Allied Corporation | Amorphous antipilferage marker |
EP0291726A2 (en) * | 1987-05-21 | 1988-11-23 | Vacuumschmelze GmbH | Amorphous alloy for strip-shaped sensor elements |
EP0291726A3 (en) * | 1987-05-21 | 1989-07-05 | Vacuumschmelze Gmbh | Amorphous alloy for strip-shaped sensor elements |
US5003291A (en) * | 1988-12-27 | 1991-03-26 | Strom Olsen John O | Ferromagnetic fibers having use in electronical article surveillance and method of making same |
US5015992A (en) * | 1989-06-29 | 1991-05-14 | Pitney Bowes Inc. | Cobalt-niobium amorphous ferromagnetic alloys |
US5015993A (en) * | 1989-06-29 | 1991-05-14 | Pitney Bowes Inc. | Ferromagnetic alloys with high nickel content and high permeability |
US5338373A (en) | 1991-08-20 | 1994-08-16 | Vonhoene Robert M | Method of encoding and decoding a glassy alloy strip to be used as an identification marker |
WO1996001910A1 (en) * | 1994-07-08 | 1996-01-25 | Sensormatic Electronics Corporation | High response electronic article surveillance system responders and methods for producing same |
US5745039A (en) * | 1997-02-21 | 1998-04-28 | Minnesota Mining And Manufacturing Company | Remote sterilization monitor |
US20050033544A1 (en) * | 2001-12-10 | 2005-02-10 | Brooks Colin Philip | Detectable components and detection apparatus for detecting such components |
US7469838B2 (en) | 2001-12-10 | 2008-12-30 | Brewster Kaleidoscope Llc | Detectable components and detection apparatus for detecting such components |
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