USRE25400E - Adsorbent briquets for combined odor - Google Patents
Adsorbent briquets for combined odor Download PDFInfo
- Publication number
- USRE25400E USRE25400E US25400DE USRE25400E US RE25400 E USRE25400 E US RE25400E US 25400D E US25400D E US 25400DE US RE25400 E USRE25400 E US RE25400E
- Authority
- US
- United States
- Prior art keywords
- briquets
- binder
- adsorbent
- percent
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003463 adsorbent Substances 0.000 title description 12
- 239000011230 binding agent Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- 239000002274 desiccant Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002594 sorbent Substances 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- VZGDMQKNWNREIO-UHFFFAOYSA-N Carbon tetrachloride Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 235000019645 odor Nutrition 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- 239000011118 polyvinyl acetate Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 229920002225 poly(styrene-co-butadiene) Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- XNLICIUVMPYHGG-UHFFFAOYSA-N 2-Pentanone Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229920000126 Latex Polymers 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000000274 adsorptive Effects 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 229940058172 ethylbenzene Drugs 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 206010040003 Sensation of pressure Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229940029983 VITAMINS Drugs 0.000 description 1
- 229940021016 Vitamin IV solution additives Drugs 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drugs Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamins Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
Definitions
- This invention relates to odor-adsorbent and dehydrating briquets, and to a method of producing the same.
- Objectionable odors often develop in packaged food, vitamins and other medicinal products when these are stored for long periods. In some cases moisture destroys the freshness of the stored food or drug, or accelerates the formation of unpleasant odors. Both of these problems are accentuated under certain climatic conditions such as high temperatures and advanced humidity.
- the prime object of this invention is to provide adsorbent briquets for combined odor and moisture removal of such shape and form as to be conveniently and chemically useable for packaging.
- Another object of the invention is the provision of a bonded composite of odor adsorbent and desiccant materials wherein each constituent retains its characteristic properties.
- a further object of this invention is to provide a method for forming such composite briqucts.
- the invention by means of which these objects are achieved consists in briquetting mixtures of pulverized activated carbonaceous particles and a desiccant, combined by a suitable binder carried in a dispersing medium by compressing the mixture in a mold and evaporating the more volatile constituent, thereby causing the mixture to set to a rigid porous solid.
- Carbon which may be any of the conventional types, depending upon the desired adsorptive properties of the end product;
- a desiccant which likewise may be any of the conventional water insoluble types, such as silica gel, activated alumina, zeolite, etc.;
- the characteristics of the formed briquets are a function of the carbon and desiccant characteristics. Thus, in general dense sorbents produce denser and stronger briquets than do low density sorbents.
- the carbon employed may be derived from any available source, and may be activated in any suitable manner. The choice of raw material and activating procedure depends upon the desired properties of the end product. Where the economics of the process are of paramount importance, it is well to note that even inexpensive by-product fines are suitable for forming into briquets.
- the binder must be highly dispersed but not soluble in water. Further, the binding material should add plasticity to the mixture. It must also form a tough film which adheres well to the carbon and desiccant particles when set and must, of course, be permeable to gases and vapors after setting. Suitable binders are [may be divided into three groups]:
- thermoplastic resins such as the latices of polyvinyl acetate, polyvinyl chloride, polystyrene, styrene-butadiene copolymers, etc.
- the vehicle may be any volatile fluid in which carbon, binder and desiccant can be dispersed, but water is the most suitable medium because it is easily and completely removed from the mixture by heat alone, is stable and does not harm the sorbents active surfaces, is not combustible, is inexpensive, and consequently does not have to be recovered.
- water is the most suitable medium because it is easily and completely removed from the mixture by heat alone, is stable and does not harm the sorbents active surfaces, is not combustible, is inexpensive, and consequently does not have to be recovered.
- organic solvents such as acetone, benzene and alcohol can be used in the practice of the invention
- the amount of vehicle used in a mix depends upon the density and porosity of the sorbents, as well as upon the particular properties of the binder. Enough must be used to saturate the sorbents and to distribute the binder uniformly throughout the mixture. Where the vehicle selected is water, the amount thereof required with ditierent sorbents may vary from 50 percent to over
- the first step in the preparation of the briquets is to grind or size the sorbent particles according to the requirements of the desired end product.
- Small particles that is those which will pass through a 100 or 200 mesh screen, are advantageous because they produce stronger and denser briquets.
- coarser particles make weaker articles, they increase the porosity and decrease the density.
- the binder seems to have less effect upon the absorptive capacity of coarse particles, because it is confined mainly to the surface of the particles.
- Two methods are available for the mixing of the carbon, desiccant, binder and vehicle.
- Either the binder can be diluted with the vehicle and then mixed with the carbon and desiccant, or the carbon and desiccant can be combined with the binder and the vehicle added to give the desired consistency.
- the wet mix is then either molded under a pres-sure of 1 to 5 tons per square inch, and the briquets dried in an oven to vaporize the vehicle and set the bond, or the mix is dried in a heated mixer and the dry mix is pressed at an elevated temperature.
- a dry powdered resin is mixed with the active materials and molded under pressure at 100 C. to 200 C.
- the briquets are then further heated in an oven at 200 C. to complete the polymerization of the binder, or heated to 950 C. in an inert atmosphere of nitrogen and like gases to carbonize the bond
- 75 grams each of pulverized activated carbon and silica gel were intimately mixed in an internal mixer.
- a second mixture consisting of 27.3 grams polyvinyl acetate latex (55 percent solids and 45 percent water) and 77.7 grams Water was added and the mixing continued for twenty minutes.
- pellets In addition to briquets, pellets, rods, spheres, Raschig rings, etc., are other forms of this invention which are practical and feasible for particular uses.
- An odor and moisture adsorbent composition consisting of a shaped mixture of fragmentary activated carbon particles and a desiccant selected from the group consisting of activated alumina, zeolite and silica gel bonded with a water-dispersible and water-insoluble polymerized binder selected from the group consisting of polyvinyl acetate, polyvinyl chloride, polystyrene, and styrene-butadiene copolymers, said binder being present in an amount ranging between 5 percent and 30 percent by weight of said composition. and a vehicle for said binder, said vehicle being selected from the group consisting of Water, ethyl alcohol, benzene, and acetone] 2.
- An adsorbent unit consisting of equal amounts by weight of activated carbon and silica gel with from 5 percent to 30 percent by weight of a binder selected from the group consisting of polyvinyl acetate, polyvinyl chloride, polystyrene and styrene butadiene copolymers. together with a vehicle for said resin, said vehicle being selected from the group consisting of water, ethyl alcohol, benzene and acetone]
Description
United States Patent 25 400 ADSORBENT BRIQUET FOR COMBINED ODOR AND MOISTURE REMOVAL Ernest G. Doying, Fostoria, Ohio, assignor to Union Carbide Corporation, a corporation of New York No Drawing. Original No. 2,933,455, dated Apr. 19,
1960, Ser. No. 480,287, Jan. 6, 1955. Application for reissue Jan. 17, 1962, Ser. No. 167,479
2 Claims. (Cl. 252-428) Matter enclosed in heavy brackets appears in the original patent but forms no part of this reissue specification; matter printed in italics indicates the additions made by reissue.
This invention relates to odor-adsorbent and dehydrating briquets, and to a method of producing the same.
Objectionable odors often develop in packaged food, vitamins and other medicinal products when these are stored for long periods. In some cases moisture destroys the freshness of the stored food or drug, or accelerates the formation of unpleasant odors. Both of these problems are accentuated under certain climatic conditions such as high temperatures and advanced humidity.
Heretofore, the practice has been generally to find a separate solution for each problem. Thus various sorbent materials, both of the odor-susceptible and dehydrating variety, have been suggested and tried in granular form. While these have performed satisfactorily in particular cases, their wide-spread use, especially with foods, has not been possible, because of the physical form in which they were employed.
More recently attempts have been made to solve the odor-developing and moisture-adsorbing problems simultaneously by adding to the article Whose protection is desired, packets containing odor-adsorbent and desiccant materials. Although this practice is effective and quite satisfactory in particular cases, it would be easier, less expensive and of wider possible application, to simply insert a composite article of such material molded to conveniently useable form, provided the attainment of this form was possible without deleteriously affecting the sorbent characteristics of the constituents. It is known, however, that carbon loses a considerable part of its odor adsorptive capacity when moist, and no known attempts have hitherto been made to combine it with desiccants which by their nature are hygroscopic.
The prime object of this invention, therefore, is to provide adsorbent briquets for combined odor and moisture removal of such shape and form as to be conveniently and chemically useable for packaging.
Another object of the invention is the provision of a bonded composite of odor adsorbent and desiccant materials wherein each constituent retains its characteristic properties.
A further object of this invention is to provide a method for forming such composite briqucts.
The invention by means of which these objects are achieved consists in briquetting mixtures of pulverized activated carbonaceous particles and a desiccant, combined by a suitable binder carried in a dispersing medium by compressing the mixture in a mold and evaporating the more volatile constituent, thereby causing the mixture to set to a rigid porous solid.
The four constituents of such a mixture are these:
(1) Carbon, which may be any of the conventional types, depending upon the desired adsorptive properties of the end product;
(2) A desiccant, which likewise may be any of the conventional water insoluble types, such as silica gel, activated alumina, zeolite, etc.;
(3) A binder which unites adsorbent and desiccant particles in the final product; and
Re. 25,400 Reisaued June 18, 1963 (4) A vehicle medium which serves to distribute the binder and to form a plastic mixture which may be compressed in a mold.
The characteristics of the formed briquets are a function of the carbon and desiccant characteristics. Thus, in general dense sorbents produce denser and stronger briquets than do low density sorbents. The carbon employed may be derived from any available source, and may be activated in any suitable manner. The choice of raw material and activating procedure depends upon the desired properties of the end product. Where the economics of the process are of paramount importance, it is well to note that even inexpensive by-product fines are suitable for forming into briquets.
The binder must be highly dispersed but not soluble in water. Further, the binding material should add plasticity to the mixture. It must also form a tough film which adheres well to the carbon and desiccant particles when set and must, of course, be permeable to gases and vapors after setting. Suitable binders are [may be divided into three groups]:
[Group I.--Polymeric materials which give thick viscous or jelly-like colloidal solutions with water such as methyl cellulose, hydroxy ethyl cellulose, casein and algin, etc.]
[Group II.-] Aqueous dispersions of thermoplastic resins such as the latices of polyvinyl acetate, polyvinyl chloride, polystyrene, styrene-butadiene copolymers, etc.
[Group III.Thermosetting resins which form hard, dense cokes when carbonized, such as phenolic resins] The percentage of binder used ranges between 5 percent and 30 percent.
The vehicle may be any volatile fluid in which carbon, binder and desiccant can be dispersed, but water is the most suitable medium because it is easily and completely removed from the mixture by heat alone, is stable and does not harm the sorbents active surfaces, is not combustible, is inexpensive, and consequently does not have to be recovered. [In addition to water, several organic solvents such as acetone, benzene and alcohol can be used in the practice of the invention] The amount of vehicle used in a mix depends upon the density and porosity of the sorbents, as well as upon the particular properties of the binder. Enough must be used to saturate the sorbents and to distribute the binder uniformly throughout the mixture. Where the vehicle selected is water, the amount thereof required with ditierent sorbents may vary from 50 percent to over percent of the sorbents weight, this being the required amount to saturate the particles, and to produce a damp mixture.
The first step in the preparation of the briquets is to grind or size the sorbent particles according to the requirements of the desired end product. Small particles, that is those which will pass through a 100 or 200 mesh screen, are advantageous because they produce stronger and denser briquets. On the other hand, while coarser particles make weaker articles, they increase the porosity and decrease the density. Furthermore, the binder seems to have less effect upon the absorptive capacity of coarse particles, because it is confined mainly to the surface of the particles. Two methods are available for the mixing of the carbon, desiccant, binder and vehicle. Either the binder can be diluted with the vehicle and then mixed with the carbon and desiccant, or the carbon and desiccant can be combined with the binder and the vehicle added to give the desired consistency. The wet mix is then either molded under a pres-sure of 1 to 5 tons per square inch, and the briquets dried in an oven to vaporize the vehicle and set the bond, or the mix is dried in a heated mixer and the dry mix is pressed at an elevated temperature.
[In a further contemplated embodiment of the invention, a dry powdered resin is mixed with the active materials and molded under pressure at 100 C. to 200 C. In the case of the third group of binders mentioned above, the briquets are then further heated in an oven at 200 C. to complete the polymerization of the binder, or heated to 950 C. in an inert atmosphere of nitrogen and like gases to carbonize the bond] As an example of the practice of the invention, 75 grams each of pulverized activated carbon and silica gel were intimately mixed in an internal mixer. To this, a second mixture consisting of 27.3 grams polyvinyl acetate latex (55 percent solids and 45 percent water) and 77.7 grams Water was added and the mixing continued for twenty minutes. Part of the resulting damp mix was then pressed at room temperature into briquets 1% inches in diameter by 4 inch thick under 3 tons per square inch pressure, while the remainder was air dried overnight and then pressed into briquets under the same pressure, but at 70 C. and 110 C. The briquets were finally dried several hours at 200 C. and then evaluated for the absorption of carbon tetrachloride vapor and moisture. The adsorption tests were run to constant weight in desiccators in a constant temperature room at 70 F. over liquid carbon tetrachloride or dilute sulphuric acid solutions corresponding to 5.7, 37.2 and 60 percent relative humidity at 70 F. The breaking strength of all briquets was also determined with an Izod impact tester. The briquets were held by a special vice and struck across the face at the center by the swinging pendulum. The results of these tests appear in Table I.
TABLE I Mix:
Activated Carbon, pts. 50 50 50 Silica Gel, pts 50 50 50 Binder Solids, pts 10 10 Total Water, (pts 60 60 60 Final Water ontent, pts-.. 50.8 2.0 2. 9 Sorbent Mesh (through) 28 65 65 Molding Conditions:
Pressure, TJsq. in 3 3 3 Temperature, C RT 70 110 Drying Schedule:
Time, hr 3 3 3 Temperature, C 200 200 20(] Finished Brlquet Characteristics:
Diameter, in 1.26 1.26 1. 27 Thickness, in. 11 10 093 \Veight, g 1. 58 1. 63 1. 66 C01 Adsorption, Percent 76. 5 74. 2 70.6 Water Adsorption, Percent at 5.79 R.H .8 1.7 .9 6. 8 9. 3 7. 4 18. 8 17. 3 21. 3 085 055 12 l Pick-up based on weight of sorbents only.
The amount of carbon tetrachloride and moisture adsorbed by the pulverized adsorbents alone under the same conditions as the briquets were tested as shown in Table II.
TABLE II Acti ated Silica Carbon Gel Comparison of these data with the results in Table I shows that the bonding of the two adsorbents into a solid piece does not destroy nor materially alter their ability to adsorb either organic vapors or moisture. The composite adsorbed more carbon tetrachloride than a weighted mixture of the two adsorbents would have, and only percent to percent less moisture.
In addition to briquets, pellets, rods, spheres, Raschig rings, etc., are other forms of this invention which are practical and feasible for particular uses.
What is claimed is:
1. An odor and moisture adsorbent composition consisting of a shaped mixture of fragmentary activated carbon particles and a desiccant selected from the group consisting of activated alumina, zeolite and silica gel bonded with a water-dispersible and water-insoluble polymerized binder selected from the group consisting of polyvinyl acetate, polyvinyl chloride, polystyrene, and styrene-butadiene copolymers, said binder being present in an amount ranging between 5 percent and 30 percent by weight of said composition. and a vehicle for said binder, said vehicle being selected from the group consisting of Water, ethyl alcohol, benzene, and acetone] 2. An adsorbent unit consisting of equal amounts by weight of activated carbon and silica gel with from 5 percent to 30 percent by weight of a binder selected from the group consisting of polyvinyl acetate, polyvinyl chloride, polystyrene and styrene butadiene copolymers. together with a vehicle for said resin, said vehicle being selected from the group consisting of water, ethyl alcohol, benzene and acetone] References Cited in the file of this patent or the original patent 1,972,368 Alex Sept. 4, 1934 2,209,928 Nowak et a]. July 30, 1940 2,423,702 Hart July 8, 1947 2,428,252 Von Stroh Sept. 30, 1947 OTHER REFERENCES Gregory: Uses and Applications of Chemicals and Related Materials, volume II, pages 262263 (1944).
Publications (1)
Publication Number | Publication Date |
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USRE25400E true USRE25400E (en) | 1963-06-18 |
Family
ID=2094239
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US25400D Expired USRE25400E (en) | Adsorbent briquets for combined odor |
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US (1) | USRE25400E (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3538020A (en) * | 1966-09-23 | 1970-11-03 | Kata Mfg & Filtering Co The | Fluid purification device containing a cartridge of polymer entrapped aggregate particles |
US3557895A (en) * | 1969-01-24 | 1971-01-26 | Frank W Thomas | Battery securing means |
US4677086A (en) | 1984-05-18 | 1987-06-30 | Westvaco Corporation | Shaped wood-based active carbon |
US5914294A (en) | 1996-04-23 | 1999-06-22 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon and method for making said monlith |
US6171373B1 (en) * | 1996-04-23 | 2001-01-09 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon, method for making said monolith, and method for adsorbing chemical agents from fluid streams |
US20060229476A1 (en) * | 2005-04-08 | 2006-10-12 | Mitchell Robert L Sr | Activated carbon monolith catalyst, methods for making same, and uses thereof |
US20080132408A1 (en) * | 2006-10-11 | 2008-06-05 | Applied Technology Limited Partnership | Carbon black monolith, carbon black monolith catalyst, methods for making same, and uses thereof |
-
0
- US US25400D patent/USRE25400E/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3538020A (en) * | 1966-09-23 | 1970-11-03 | Kata Mfg & Filtering Co The | Fluid purification device containing a cartridge of polymer entrapped aggregate particles |
US3557895A (en) * | 1969-01-24 | 1971-01-26 | Frank W Thomas | Battery securing means |
US4677086A (en) | 1984-05-18 | 1987-06-30 | Westvaco Corporation | Shaped wood-based active carbon |
US5914294A (en) | 1996-04-23 | 1999-06-22 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon and method for making said monlith |
US6171373B1 (en) * | 1996-04-23 | 2001-01-09 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon, method for making said monolith, and method for adsorbing chemical agents from fluid streams |
US20060229476A1 (en) * | 2005-04-08 | 2006-10-12 | Mitchell Robert L Sr | Activated carbon monolith catalyst, methods for making same, and uses thereof |
US10265681B2 (en) | 2005-04-08 | 2019-04-23 | Applied Technology Limited Partnership | Activated carbon monolith catalyst, methods for making same, and uses thereof |
US10478804B2 (en) | 2005-04-08 | 2019-11-19 | Applied Technology Limited Partnership | Activated carbon monolith catalyst, methods for making same, and uses thereof |
US10596549B2 (en) | 2005-04-08 | 2020-03-24 | Applied Technology Limited Partnership | Activated carbon monolith catalyst, methods for making same, and uses thereof |
US20080132408A1 (en) * | 2006-10-11 | 2008-06-05 | Applied Technology Limited Partnership | Carbon black monolith, carbon black monolith catalyst, methods for making same, and uses thereof |
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Owner name: WITCO CHEMICAL CORPORATION, 277 PARK AVENUE, NEW Y Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE CORPORATION;REEL/FRAME:003917/0434 Effective date: 19810901 |