US8797258B2 - Highlight color display architecture using enhanced dark state - Google Patents

Highlight color display architecture using enhanced dark state Download PDF

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US8797258B2
US8797258B2 US12/644,861 US64486109A US8797258B2 US 8797258 B2 US8797258 B2 US 8797258B2 US 64486109 A US64486109 A US 64486109A US 8797258 B2 US8797258 B2 US 8797258B2
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color
dark
display device
microcups
black
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Robert A. Sprague
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E Ink Corp
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Sipix Imaging Inc
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/1675Constructional details
    • G02F1/1679Gaskets; Spacers; Sealing of cells; Filling or closing of cells
    • G02F1/1681Gaskets; Spacers; Sealing of cells; Filling or closing of cells having two or more microcells partitioned by walls, e.g. of microcup type
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/1675Constructional details
    • G02F2001/1678Constructional details characterised by the composition or particle type
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2203/00Function characteristic
    • G02F2203/30Gray scale

Definitions

  • the present invention is directed to highlight color display architecture using enhanced dark state.
  • each pixel has two sub-pixels and the two sub-pixels are based on two display cells capable of displaying black and white color states and only one of the sub-pixels has a color filter overlaid on top of a display cell.
  • a color state e.g., red, green or blue
  • the sub-pixel with the color filter is turned on and the sub-pixel without a color filter is turned to the white or black state.
  • the black state is desired, both sub-pixels are turned to the black state.
  • the sub-pixel without a color filter is turned white and the sub-pixel with a color filter is turned black.
  • the disadvantage of such a technique is that the maximum reflectivity of the white state is only 50% since the sub-pixel with the color filter must be turned black for that state. Conversely the color state is of a dark shade (with the black turned on) or a light shade (with the white turned on).
  • the present invention is directed to an alternative design of a highlight color display.
  • One of the key features of the invention is the intense color of the display fluid filled in the microcups, which allows the dark state to appear black.
  • the advantage is that no sub-pixel architecture is required in the active matrix array or the microcup structure. Only one display fluid is needed for all microcups. Furthermore, there is no alignment required between the pixel electrodes and the microcups. In practice, a standard active matrix array may be used to drive the display device.
  • One aspect of the invention is directed to a color display device, which comprises a plurality of microcups wherein
  • the color display further comprises an adhesive layer of a dark color or a color complementary to the color of the solvent.
  • the top surface of the partition walls is of a dark color or a color complementary to the color of the solvent.
  • the partition walls are of a black or dark color. In one embodiment, no more than 10%, preferably no more than 3%, of the light is reflected at the peak transmission of the dark color state.
  • the dark color of the solvent is dark red, dark green or dark blue.
  • the reflectance of the medium color state achieved by driving the white charged pigment particles to an area between the common electrode and the pixel electrode in the microcup has at least five times, preferably at least ten times, the reflectance of the dark color state.
  • the microcups and the pixel electrodes are aligned.
  • the microcups and the pixel electrodes are un-aligned.
  • the medium color state is achieved by driving the white pigment particles to an area between the common electrode and the pixel electrode.
  • the particles are distributed throughout the display fluid.
  • the particles are driven to be at the mid-level in the microcup.
  • each microcup represents a pixel.
  • the device further comprises an active matrix driving system.
  • Another aspect of the invention is directed to a color display device, which comprises a plurality of microcups wherein
  • the colored solvent is red, green or blue respectively.
  • the microcups and the pixel electrodes are aligned. In another embodiment, the microcups and the pixel electrodes are un-aligned.
  • the color state is achieved by driving both the white and black charged pigment particles to an area between the common electrode and the pixel electrode. In one embodiment, the particles are distributed throughout the display fluid. In another embodiment, the particles are driven to be at the mid-level in the microcup. In one embodiment, the color state achieved by driving both the white and black charged pigment particles to an area between the common electrode and the pixel electrode has a reflectance at least five times, preferably at least ten times, the reflectance of the black state. In one embodiment, each microcup represents a pixel. In one embodiment, the device further comprises an active matrix driving system.
  • FIG. 1 a depicts a cross-section view of a color display device of the present invention.
  • FIG. 1 b depicts a top view of microcups.
  • FIGS. 2 a , 2 b and 2 c depict un-aligned designs.
  • FIGS. 3 a - 3 c illustrate how different color states may be displayed.
  • FIG. 4 shows a scale of colors which may be displayed by the color display of the present invention.
  • FIG. 5 shows how different color states may be displayed when the microcups and the pixel electrodes are not aligned.
  • FIGS. 6 a and 6 b are alternative designs to impart a dark color to the partition wall area.
  • FIGS. 7 a - 7 c illustrate how different color states may be displayed with a two particle system.
  • FIG. 8 shows how different color states may be displayed with a two particle system and an un-aligned design.
  • FIGS. 9 a - 9 c show highlight options.
  • FIGS. 10 a - 10 c show photographs taken under a microscope of microcups displaying different color states.
  • FIG. 1 a depicts a cross-section view of a color display device of the present invention.
  • a microcup ( 100 ) is sandwiched between a first layer ( 101 ) and a second layer ( 102 ).
  • the microcup ( 100 ) is surrounded by partition walls ( 107 ).
  • the first layer comprises a common electrode ( 103 ).
  • the second layer comprises multiple pixel electrodes ( 104 ).
  • the microcup ( 100 ) is a micro-container filled with a display fluid ( 105 ). Details of the term “microcup” are given in U.S. Pat. No. 6,930,818, the content of which is incorporated herein by reference in its entirety.
  • microcups are specifically mentioned in the present application, it is understood that any micro-containers (e.g., microcapsules), regardless of their shapes or sizes, are within the scope of the present application, as long as the micro-containers are filled with a display fluid and have the same functions as the microcups.
  • micro-containers e.g., microcapsules
  • the display fluid ( 105 ) is an electrophoretic fluid comprising only one type of charged pigment particles ( 106 ), usually white, dispersed in a colored dielectric solvent or solvent mixture, as shown in FIG. 1 a .
  • the color of the electrophoretic fluid (or the color of the dielectric solvent or solvent mixture) may be a dark red, dark green, dark blue or another dark color.
  • the display fluid in all of the microcups is of the same color.
  • the color of the fluid is dark enough that when the white particles are at the bottom, preferably not more than 10%, more preferably not more than 3%, of the light is reflected at the peak transmission of the dark color state.
  • the electrophoretic fluid may comprise two types of pigment particles of contrasting colors and carrying opposite charge polarities.
  • the pigment particles are also dispersed in a colored solvent and the display fluid in all of the microcups is of the same color.
  • the color of the solvent does not have to be enhanced.
  • the display device may also have an adhesive layer ( 108 ) at the opposite side of the viewing side.
  • the adhesive layer is colored and the first layer, the second layer and the partition walls ( 107 ) are all transparent.
  • the purpose of the colored adhesive layer is to balance the color of the dark color state or enhance the black state.
  • the adhesive layer may be of the black color or a dark color complementary to the color of the display fluid. In the latter case, if the microcups are filled with a display fluid of a dark red color, the dark color state will have a tinge of red. In this case, the adhesive layer may be of a combined color of dark green and dark blue. The dark green and dark blue colors from the adhesive layer through the partition walls and the red color from the display fluid together will provide a neutral dark color.
  • the adhesive layer then may be of a combined color of dark red and dark blue (complementary color). If the microcups are filled with a display fluid of a dark blue color, the adhesive layer then may be of a combined color of dark red and dark green (complementary color). As shown, the adhesive layer has the function of enhancing the dark color state displayed by the display device. Suitable pigments or dyes are added to the adhesive layer to achieve the desired color of the adhesive layer.
  • FIG. 1 b depicts a top view of microcups ( 100 ).
  • the area between the microcups is the wall area ( 107 a ).
  • the total microcup area ( 100 ) takes up a relatively large percentage of the total area, preferably in the range of at least 80%, more preferably in the range of at least 90%.
  • the common electrode ( 103 ) is usually a transparent electrode layer (e.g., ITO), spreading over the entire top of the display device.
  • the pixel electrodes ( 104 ) are described in U.S. Pat. No. 7,046,228, the content of which is incorporated herein by reference in its entirety.
  • active matrix driving electrodes are mentioned as pixel electrodes, the scope of the present invention encompasses other types of electrode addressing as long as the electrodes serve the desired functions.
  • the second layer ( 102 ) comprises multiple pixel electrodes ( 104 ). However, the pixel electrodes and the microcups may be aligned (see FIG. 1 a ). In an aligned design, each pixel electrode corresponds to one microcup.
  • FIG. 2 a shows an un-aligned design.
  • the term “un-aligned” or “non-aligned”, in the context of this invention, is intended to mean that at least one pixel electrode ( 104 ) is permitted to be underneath more than one microcup, as shown in the figure.
  • FIG. 2 b is a top view of an un-aligned design.
  • the microcups (solid lined, 100 ) and the pixel electrodes (dotted lined, 104 ) are un-aligned in only one direction and each pixel electrode is underneath two neighboring microcups.
  • FIG. 2 c is a top view of another un-aligned design.
  • the microcups (solid lined, 100 ) and the pixel electrodes (dotted lined, 104 ) are un-aligned in both directions and each pixel electrode is underneath four neighboring microcups.
  • un-aligned or “non-aligned” is not limited to the examples of FIGS. 2 b and 2 c .
  • the term “un-aligned” or “non-aligned” would broadly encompass all configurations in which at least one pixel electrode is underneath more than one microcup.
  • the “un-aligned” or “non-aligned” would also include configurations with microcups and/or pixel electrodes having irregular shapes, sizes or spatial arrangements.
  • FIGS. 3 a - 3 c illustrate how different color states may be displayed.
  • the display fluid comprises charged white pigment particles dispersed in a dark blue solvent.
  • the display fluid is of the same color in all microcups.
  • the white particles move to be near or at the pixel electrode ( 304 b ). Because the blue dye absorption is strong, the color seen in this case is a very dark blue color. At a high enough level of the blue density, such a pixel will appear black to the viewers. As described previously, if the fluid is not dark enough, the color will appear black if the fluid color is balanced by the complementary colors in the adhesive layer 108 .
  • the particles when the particles are driven to an area between the common electrode and the pixel electrode, the particles may be distributed throughout the display fluid or a substantial amount of the particles may gather at the mid-level in a microcup.
  • the mid-level refers to the area between 20 and 80%, preferably 30 and 70%, more preferably 40 and 60% of the height (h) of a microcup.
  • the reflectance of the medium color achieved by driving the particles to an area between the common and pixel electrodes is at least 5 times, more preferably at least 10 times, the reflectance of the dark color state achieved by driving the particles to be at or near the pixel electrode.
  • the white particles may move to be in an area between the common electrode and the pixel electrode (e.g., at the mid-level of the microcup), as shown in FIG. 3 c .
  • the white particles are distributed in the middle of the microcup and the reflected color appears to be medium blue.
  • a black material e.g., a mixture of red, green and blue dyes
  • a black material e.g., a mixture of red, green and blue dyes
  • FIG. 4 shows a scale of colors which may be displayed by the color display of the present invention.
  • the black state at the right end of the scale is achieved when the white particles are at or near the bottom of a microcup.
  • the white state at the left of the scale is achieved when the white particles are at or near the top of a microcup.
  • the blue color state in the middle of the scale is achieved when the white particles are distributed in an area between the common electrode and the pixel electrode (e.g., the mid-level in a microcup).
  • FIG. 5 shows how different color states may be displayed when the microcups and the pixel electrodes are not aligned.
  • the charged pigment particles are white and the color of the solvent in which the white particles are dispersed is a dark blue color.
  • the white pigment particles may move to be near or at the common electrode, near or at the pixel electrodes or in an area between the common electrode and the pixel electrode (e.g., the mid-level in a microcup).
  • a white color in area marked “A”
  • a dark blue (almost black) color in area marked “B”
  • a medium blue color in area marked “C”
  • the dark colored wall area due to the dark adhesive layer at the bottom of the display device) is negligible when the white or medium blue color is displayed because the wall area is much smaller than the fluid area.
  • an adhesive layer of a black or dark color is added at the bottom of the display device.
  • the dark color seen through the partition walls may also be achieved by alternative designs.
  • the top surface ( 107 b ) of the partition walls ( 107 ) may be colored black or a dark color state, as shown in FIG. 6 a .
  • the black or a dark color may be applied to the top surface of the partition walls by methods as described in U.S. Pat. No. 6,829,078, the content of which is incorporated herein by reference in its entirety.
  • the top surface of the partition walls may be of a dark color complementary to the dark color of the display fluid within the microcups.
  • the top surface may be of a combined color of dark red and dark green, or a combined color of dark green and dark blue or a combined color of dark blue and dark green, depending on the color of the display fluid.
  • Suitable pigments or dyes may be used to achieve the desired color of the top surface layer ( 107 b ).
  • the partition wall ( 107 ) themselves may be of a black or dark color. This can be achieved by forming a microcup structure ( 100 ) in a black or dark color, as shown in FIG. 6 b . In this option, suitable pigments or dyes may be added to the composition for forming the microcup structure.
  • the walls are transparent and the colored adhesive layer is tuned to balance the color of the fluid in the dark state, thus achieving a good black state.
  • the display fluid may comprise two types of pigment particles of contrast color dispersed in a clear and colored solvent.
  • the color of the solvent does not have to be as dark as the color of the solvent in the one particle system.
  • FIGS. 7 a - 7 c illustrate how different color states may be displayed with this two particle system.
  • the pigment particles are black and white and carry charges of opposite polarities.
  • the color of the solvent is a blue color.
  • the white particles are driven to be near or at the common electrode ( 703 ) and the black particles are driven to be near or at the pixel electrode ( 704 a ). As a result, the white color is seen at the viewing side.
  • the black particles are driven to be near or at the common electrode ( 703 ) and the white particles are driven to be near or at the pixel electrode ( 704 b ). As a result, the black color is seen at the viewing side.
  • both the black and white particles are driven to an area between the common electrode and the pixel electrode (about the mid-level of a microcup). As a result, a blue color is seen at the viewing side.
  • the reflectance of the color state achieved by driving the black and white particles to an area between the common and pixel electrodes is at least 5 times, more preferably at least 10 times, the reflectance of the black color state achieved by driving the white particles to be at or near the pixel electrode.
  • FIG. 8 shows an example.
  • the pigment particles are black and white and the color of the solvent in which the white particles are dispersed is blue.
  • the black and white particles carry charges of opposite polarities.
  • the white pigment particles move to be near or at the common electrode ( 803 ) and the black pigment particles move to be near or at the pixel electrode ( 804 a ) to cause the white color to be seen at the viewing side (in area marked “A”).
  • the black pigment particles move to be near or at the common electrode ( 803 ) and the white pigment particles move to be near or at the pixel electrode ( 804 b ) to cause the black color to be seen at the viewing side (in area marked “B”).
  • both the white and black pigment particles move to be in an area between the common and pixel electrodes (about the mid-level of a microcup) to cause a medium blue color to be seen at the viewing side (in area marked “C”).
  • each microcup defines a pixel as it is capable of displaying three color states, black, white and color (e.g., red, green or blue). No sub-pixels are needed.
  • FIGS. 9 a - 9 c show highlight options of the present invention.
  • FIG. 9 a shows a black image on a white background.
  • the black image is highlighted by the surrounding red color.
  • the image is highlighted by being switched to the red color. Any color can, of course, be used besides the red used to describe the concept in this application.
  • the display device of the present invention may be manufactured by methods known in the art.
  • the microcup layer may be formed on a layer of pixel electrodes followed by laminating a common electrode layer over the microcup layer, as described in U.S. Pat. No. 6,930,818.
  • the non-microcup type display devices they may also be manufactured by methods known in the art.
  • FIGS. 10 a - 10 c show photographs taken under a microscope of microcups displaying the white color ( FIG. 10 a ), a medium blue color ( FIG. 10 b ) and a blue color dark enough to appear black ( FIG. 10 c ).
  • white charged particles are dispersed in a dark blue solvent.
  • the black lines indicate the partition wall area. The black lines are more pronounced in the photographs because these are enlarged images. In practice, the dark lines would not be visually detectable by a viewer.
  • the Dmax of the blue display fluid was 1.43 and the contrast ratio demonstrated by the color display was about 11.8, assuming 35% white.

Abstract

The present invention is directed to a highlight color display. One of the key features of the invention is the dark color of the display fluid filled in the microcups, which allows the dark state to appear black. There is no alignment required between the pixel electrodes and the microcups. In practice, a standard active matrix array may be used to drive the display device.

Description

This application claims priority to U.S. Provisional Application No. 61/141,574, filed Dec. 30, 2008; the content of which is incorporated herein by reference in its entirety.
FIELD OF THE INVENTION
The present invention is directed to highlight color display architecture using enhanced dark state.
BACKGROUND OF THE INVENTION
In order to achieve a highlight color display, color filters are often used. In one of the obvious options, each pixel has two sub-pixels and the two sub-pixels are based on two display cells capable of displaying black and white color states and only one of the sub-pixels has a color filter overlaid on top of a display cell. When a color state (e.g., red, green or blue) is desired, the sub-pixel with the color filter is turned on and the sub-pixel without a color filter is turned to the white or black state. When the black state is desired, both sub-pixels are turned to the black state. When the white state is desired, the sub-pixel without a color filter is turned white and the sub-pixel with a color filter is turned black. It is fairly obvious that the disadvantage of such a technique is that the maximum reflectivity of the white state is only 50% since the sub-pixel with the color filter must be turned black for that state. Conversely the color state is of a dark shade (with the black turned on) or a light shade (with the white turned on).
An alternative technique utilizing a dual switching mode is proposed in U.S. Pat. No. 7,046,228. With the dual switching mode, an extra set of electrodes are added to each microcup so that the microcup can be switched into three states; white (with the particles at top), colored (with the particles at bottom), and black (with the particles moved to the sides). A black background layer is used so when the particles are moved sideways, the black state shows through the microcup. The advantage of this is that high quality white and black states can be achieved. In addition, each microcup defines a pixel and no sub-pixels are required. However, a special electrode structure is needed for this dual mode switching.
SUMMARY OF THE INVENTION
The present invention is directed to an alternative design of a highlight color display. One of the key features of the invention is the intense color of the display fluid filled in the microcups, which allows the dark state to appear black. The advantage is that no sub-pixel architecture is required in the active matrix array or the microcup structure. Only one display fluid is needed for all microcups. Furthermore, there is no alignment required between the pixel electrodes and the microcups. In practice, a standard active matrix array may be used to drive the display device.
One aspect of the invention is directed to a color display device, which comprises a plurality of microcups wherein
    • a) the microcups are separated by partition walls;
    • b) the microcups are filled with a display fluid comprising white charged pigment particles dispersed in a solvent of a dark color;
    • c) the microcups are sandwiched between a first layer and a second layer wherein the first layer comprises a common electrode and the second layer comprises a plurality of pixel electrodes; and
    • d) each of the microcups is capable of displaying a white color state, a dark color state and a medium color state.
In this aspect of the invention—In one embodiment, the color display further comprises an adhesive layer of a dark color or a color complementary to the color of the solvent. In another embodiment, the top surface of the partition walls is of a dark color or a color complementary to the color of the solvent. In a further embodiment, the partition walls are of a black or dark color. In one embodiment, no more than 10%, preferably no more than 3%, of the light is reflected at the peak transmission of the dark color state. In one embodiment, the dark color of the solvent is dark red, dark green or dark blue. In one embodiment, the reflectance of the medium color state achieved by driving the white charged pigment particles to an area between the common electrode and the pixel electrode in the microcup has at least five times, preferably at least ten times, the reflectance of the dark color state. In one embodiment, the microcups and the pixel electrodes are aligned. In another embodiment, the microcups and the pixel electrodes are un-aligned. In one embodiment, the medium color state is achieved by driving the white pigment particles to an area between the common electrode and the pixel electrode. In one embodiment, the particles are distributed throughout the display fluid. In another embodiment, the particles are driven to be at the mid-level in the microcup. In one embodiment, each microcup represents a pixel. In one embodiment, the device further comprises an active matrix driving system.
Another aspect of the invention is directed to a color display device, which comprises a plurality of microcups wherein
    • a) the microcups are filled with a display fluid comprising black and white charged particles carrying charges of opposite polarities and dispersed in a clear and colored solvent;
    • b) the microcups are sandwiched between a first layer and a second layer wherein the first layer comprises a common electrode and the second layer comprises a plurality of pixel electrodes; and
    • c) each of the microcups is capable of achieving a white state, a black state and a color state.
In this aspect of the invention—In one embodiment, the colored solvent is red, green or blue respectively. In one embodiment, the microcups and the pixel electrodes are aligned. In another embodiment, the microcups and the pixel electrodes are un-aligned. In one embodiment, the color state is achieved by driving both the white and black charged pigment particles to an area between the common electrode and the pixel electrode. In one embodiment, the particles are distributed throughout the display fluid. In another embodiment, the particles are driven to be at the mid-level in the microcup. In one embodiment, the color state achieved by driving both the white and black charged pigment particles to an area between the common electrode and the pixel electrode has a reflectance at least five times, preferably at least ten times, the reflectance of the black state. In one embodiment, each microcup represents a pixel. In one embodiment, the device further comprises an active matrix driving system.
BRIEF DISCUSSION OF THE DRAWINGS
FIG. 1 a depicts a cross-section view of a color display device of the present invention.
FIG. 1 b depicts a top view of microcups.
FIGS. 2 a, 2 b and 2 c depict un-aligned designs.
FIGS. 3 a-3 c illustrate how different color states may be displayed.
FIG. 4 shows a scale of colors which may be displayed by the color display of the present invention.
FIG. 5 shows how different color states may be displayed when the microcups and the pixel electrodes are not aligned.
FIGS. 6 a and 6 b are alternative designs to impart a dark color to the partition wall area.
FIGS. 7 a-7 c illustrate how different color states may be displayed with a two particle system.
FIG. 8 shows how different color states may be displayed with a two particle system and an un-aligned design.
FIGS. 9 a-9 c show highlight options.
FIGS. 10 a-10 c show photographs taken under a microscope of microcups displaying different color states.
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1 a depicts a cross-section view of a color display device of the present invention. A microcup (100) is sandwiched between a first layer (101) and a second layer (102). The microcup (100) is surrounded by partition walls (107). The first layer comprises a common electrode (103). The second layer comprises multiple pixel electrodes (104).
The microcup (100) is a micro-container filled with a display fluid (105). Details of the term “microcup” are given in U.S. Pat. No. 6,930,818, the content of which is incorporated herein by reference in its entirety.
While microcups are specifically mentioned in the present application, it is understood that any micro-containers (e.g., microcapsules), regardless of their shapes or sizes, are within the scope of the present application, as long as the micro-containers are filled with a display fluid and have the same functions as the microcups.
In one embodiment of the invention, the display fluid (105) is an electrophoretic fluid comprising only one type of charged pigment particles (106), usually white, dispersed in a colored dielectric solvent or solvent mixture, as shown in FIG. 1 a. The color of the electrophoretic fluid (or the color of the dielectric solvent or solvent mixture) may be a dark red, dark green, dark blue or another dark color. For a highlight display device, the display fluid in all of the microcups is of the same color. The color of the fluid is dark enough that when the white particles are at the bottom, preferably not more than 10%, more preferably not more than 3%, of the light is reflected at the peak transmission of the dark color state.
In another embodiment, the electrophoretic fluid may comprise two types of pigment particles of contrasting colors and carrying opposite charge polarities. The pigment particles are also dispersed in a colored solvent and the display fluid in all of the microcups is of the same color. However, in the two particle system, the color of the solvent does not have to be enhanced.
The display device may also have an adhesive layer (108) at the opposite side of the viewing side. The adhesive layer is colored and the first layer, the second layer and the partition walls (107) are all transparent. The purpose of the colored adhesive layer is to balance the color of the dark color state or enhance the black state. The adhesive layer may be of the black color or a dark color complementary to the color of the display fluid. In the latter case, if the microcups are filled with a display fluid of a dark red color, the dark color state will have a tinge of red. In this case, the adhesive layer may be of a combined color of dark green and dark blue. The dark green and dark blue colors from the adhesive layer through the partition walls and the red color from the display fluid together will provide a neutral dark color.
Likewise, if the microcups are filled with a display fluid of a dark green color, the adhesive layer then may be of a combined color of dark red and dark blue (complementary color). If the microcups are filled with a display fluid of a dark blue color, the adhesive layer then may be of a combined color of dark red and dark green (complementary color). As shown, the adhesive layer has the function of enhancing the dark color state displayed by the display device. Suitable pigments or dyes are added to the adhesive layer to achieve the desired color of the adhesive layer.
FIG. 1 b depicts a top view of microcups (100). The area between the microcups is the wall area (107 a). In the context of the present invention, the total microcup area (100) takes up a relatively large percentage of the total area, preferably in the range of at least 80%, more preferably in the range of at least 90%.
The common electrode (103) is usually a transparent electrode layer (e.g., ITO), spreading over the entire top of the display device. The pixel electrodes (104) are described in U.S. Pat. No. 7,046,228, the content of which is incorporated herein by reference in its entirety.
It is noted that while active matrix driving electrodes are mentioned as pixel electrodes, the scope of the present invention encompasses other types of electrode addressing as long as the electrodes serve the desired functions.
The second layer (102) comprises multiple pixel electrodes (104). However, the pixel electrodes and the microcups may be aligned (see FIG. 1 a). In an aligned design, each pixel electrode corresponds to one microcup.
FIG. 2 a shows an un-aligned design. The term “un-aligned” or “non-aligned”, in the context of this invention, is intended to mean that at least one pixel electrode (104) is permitted to be underneath more than one microcup, as shown in the figure.
There is no requirement that the shape, size or alignment of pixel electrodes match those of the microcups.
FIG. 2 b is a top view of an un-aligned design. In this figure, the microcups (solid lined, 100) and the pixel electrodes (dotted lined, 104) are un-aligned in only one direction and each pixel electrode is underneath two neighboring microcups.
FIG. 2 c is a top view of another un-aligned design. In this figure, the microcups (solid lined, 100) and the pixel electrodes (dotted lined, 104) are un-aligned in both directions and each pixel electrode is underneath four neighboring microcups.
The term “un-aligned” or “non-aligned” is not limited to the examples of FIGS. 2 b and 2 c. In fact, the term “un-aligned” or “non-aligned” would broadly encompass all configurations in which at least one pixel electrode is underneath more than one microcup. In other words, the “un-aligned” or “non-aligned” would also include configurations with microcups and/or pixel electrodes having irregular shapes, sizes or spatial arrangements.
FIGS. 3 a-3 c illustrate how different color states may be displayed. In this example, the display fluid comprises charged white pigment particles dispersed in a dark blue solvent. The display fluid is of the same color in all microcups.
In FIG. 3 a, by applying appropriate voltages to the common (303) and pixel (304 a) electrodes, the white particles move to be near or at the common electrode (303). As a result, the white color is seen at the viewing side.
In FIG. 3 b, by applying appropriate voltages to the common (303) and pixel (304 b) electrodes, the white particles move to be near or at the pixel electrode (304 b). Because the blue dye absorption is strong, the color seen in this case is a very dark blue color. At a high enough level of the blue density, such a pixel will appear black to the viewers. As described previously, if the fluid is not dark enough, the color will appear black if the fluid color is balanced by the complementary colors in the adhesive layer 108.
In the context of the present invention, when the particles are driven to an area between the common electrode and the pixel electrode, the particles may be distributed throughout the display fluid or a substantial amount of the particles may gather at the mid-level in a microcup. A “substantial amount,” as used herein, refers to at least 60%, preferably 75%, more preferably 90%, of the particles. “The mid-level,” as used herein, refers to the area between 20 and 80%, preferably 30 and 70%, more preferably 40 and 60% of the height (h) of a microcup. In any case, the reflectance of the medium color achieved by driving the particles to an area between the common and pixel electrodes is at least 5 times, more preferably at least 10 times, the reflectance of the dark color state achieved by driving the particles to be at or near the pixel electrode.
By properly adjusting the timing (i.e., duration) of a driving waveform, the white particles may move to be in an area between the common electrode and the pixel electrode (e.g., at the mid-level of the microcup), as shown in FIG. 3 c. In this scenario, the white particles are distributed in the middle of the microcup and the reflected color appears to be medium blue.
In the white state as shown in FIG. 3 a or the middle level color state as shown in FIG. 3 c, the much brighter color displayed would overwhelm the small amount of the dark color in the wall area to give the desired color appearance.
In another embodiment, it may also be desirable to mix a small amount of a black material (e.g., a mixture of red, green and blue dyes) with the blue color in the fluid in order to more easily achieve a good dark state.
FIG. 4 shows a scale of colors which may be displayed by the color display of the present invention. The black state at the right end of the scale is achieved when the white particles are at or near the bottom of a microcup. The white state at the left of the scale is achieved when the white particles are at or near the top of a microcup. The blue color state in the middle of the scale is achieved when the white particles are distributed in an area between the common electrode and the pixel electrode (e.g., the mid-level in a microcup).
FIG. 5 shows how different color states may be displayed when the microcups and the pixel electrodes are not aligned. In this example, the charged pigment particles are white and the color of the solvent in which the white particles are dispersed is a dark blue color. As shown, when appropriate voltages are applied to the common (503) and pixel electrodes (504 a, 504 b and 504 c), the white pigment particles may move to be near or at the common electrode, near or at the pixel electrodes or in an area between the common electrode and the pixel electrode (e.g., the mid-level in a microcup). As a result, a white color (in area marked “A”), a dark blue (almost black) color (in area marked “B”) or a medium blue color (in area marked “C”) is seen from the viewing side. The dark colored wall area (due to the dark adhesive layer at the bottom of the display device) is negligible when the white or medium blue color is displayed because the wall area is much smaller than the fluid area.
As stated above, in order to achieve a dark level so dark that it appears black, an adhesive layer of a black or dark color is added at the bottom of the display device. The dark color seen through the partition walls may also be achieved by alternative designs. In one embodiment, the top surface (107 b) of the partition walls (107) may be colored black or a dark color state, as shown in FIG. 6 a. The black or a dark color may be applied to the top surface of the partition walls by methods as described in U.S. Pat. No. 6,829,078, the content of which is incorporated herein by reference in its entirety. The top surface of the partition walls may be of a dark color complementary to the dark color of the display fluid within the microcups. In other words, the top surface may be of a combined color of dark red and dark green, or a combined color of dark green and dark blue or a combined color of dark blue and dark green, depending on the color of the display fluid. Suitable pigments or dyes may be used to achieve the desired color of the top surface layer (107 b).
In another embodiment, the partition wall (107) themselves may be of a black or dark color. This can be achieved by forming a microcup structure (100) in a black or dark color, as shown in FIG. 6 b. In this option, suitable pigments or dyes may be added to the composition for forming the microcup structure.
In another embodiment, the walls are transparent and the colored adhesive layer is tuned to balance the color of the fluid in the dark state, thus achieving a good black state.
In another embodiment of the invention, the display fluid may comprise two types of pigment particles of contrast color dispersed in a clear and colored solvent. In this case, the color of the solvent does not have to be as dark as the color of the solvent in the one particle system. In addition, there is less need to balance the dark color in the black level, when one type of the particles is of the black color. In other words, there is less need to have the dark colored adhesive layer at the bottom of the display device, or the dark colored top surface of the partition walls or the dark colored microcup structure.
FIGS. 7 a-7 c illustrate how different color states may be displayed with this two particle system. In this example, the pigment particles are black and white and carry charges of opposite polarities. The color of the solvent is a blue color.
In FIG. 7 a, the white particles are driven to be near or at the common electrode (703) and the black particles are driven to be near or at the pixel electrode (704 a). As a result, the white color is seen at the viewing side.
In FIG. 7 b, the black particles are driven to be near or at the common electrode (703) and the white particles are driven to be near or at the pixel electrode (704 b). As a result, the black color is seen at the viewing side.
In FIG. 7 c, both the black and white particles are driven to an area between the common electrode and the pixel electrode (about the mid-level of a microcup). As a result, a blue color is seen at the viewing side.
In one embodiment, the reflectance of the color state achieved by driving the black and white particles to an area between the common and pixel electrodes is at least 5 times, more preferably at least 10 times, the reflectance of the black color state achieved by driving the white particles to be at or near the pixel electrode.
The two particle system is also applicable to the non-aligned design. FIG. 8 shows an example. In this example, the pigment particles are black and white and the color of the solvent in which the white particles are dispersed is blue. The black and white particles carry charges of opposite polarities. As shown, when appropriate voltages are applied to the common (803) and pixel electrode (804 a), the white pigment particles move to be near or at the common electrode (803) and the black pigment particles move to be near or at the pixel electrode (804 a) to cause the white color to be seen at the viewing side (in area marked “A”). When appropriate voltages are applied to the common (803) and pixel electrode (804 b), the black pigment particles move to be near or at the common electrode (803) and the white pigment particles move to be near or at the pixel electrode (804 b) to cause the black color to be seen at the viewing side (in area marked “B”). When appropriate voltages are applied to the common (803) and pixel electrode (804 c), both the white and black pigment particles move to be in an area between the common and pixel electrodes (about the mid-level of a microcup) to cause a medium blue color to be seen at the viewing side (in area marked “C”).
In a highlight color display of the present invention, each microcup defines a pixel as it is capable of displaying three color states, black, white and color (e.g., red, green or blue). No sub-pixels are needed.
FIGS. 9 a-9 c show highlight options of the present invention. FIG. 9 a shows a black image on a white background. In FIG. 9 b, the black image is highlighted by the surrounding red color. In FIG. 9 c, the image is highlighted by being switched to the red color. Any color can, of course, be used besides the red used to describe the concept in this application.
The display device of the present invention may be manufactured by methods known in the art. For example, the microcup layer may be formed on a layer of pixel electrodes followed by laminating a common electrode layer over the microcup layer, as described in U.S. Pat. No. 6,930,818. For the non-microcup type display devices, they may also be manufactured by methods known in the art.
EXAMPLE
FIGS. 10 a-10 c show photographs taken under a microscope of microcups displaying the white color (FIG. 10 a), a medium blue color (FIG. 10 b) and a blue color dark enough to appear black (FIG. 10 c). In the experiment, white charged particles are dispersed in a dark blue solvent. The black lines indicate the partition wall area. The black lines are more pronounced in the photographs because these are enlarged images. In practice, the dark lines would not be visually detectable by a viewer.
The Dmax of the blue display fluid was 1.43 and the contrast ratio demonstrated by the color display was about 11.8, assuming 35% white.
While the present invention has been described with reference to the specific embodiments thereof, it should be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the true spirit and scope of the invention. In addition, many modifications may be made to adapt a particular situation, materials, compositions, processes, process step or steps, to the objective, spirit and scope of the present invention. All such modifications are intended to be within the scope of the claims appended hereto.

Claims (12)

What is claimed is:
1. A color display device comprising
A) a plurality of microcups, wherein
a) said microcups are separated by transparent partition walls,
b) said microcups are filled with a display fluid comprising white charged pigment particles dispersed in a solvent of a dark color, and the solvent is of the same color in all the microcups, and
c) said microcups are sandwiched between a first layer and a second layer wherein said first layer comprises a common electrode and is on a viewing side and said second layer comprises a plurality of pixel electrodes, and
B) an adhesive layer on the opposite side of the viewing side and the adhesive layer has a black color or a color complementary to the dark color of the solvent,
whereby each area corresponding to a pixel electrode displays a white color state when the white charged pigment particles are driven to be near or at the common electrode, displays a black color state when the white charged pigment particles are driven to be near or at the pixel electrode to cover the pixel electrode, wherein the black color state is the dark color of the solvent enhanced by the color of the adhesive layer seen through the transparent partition walls, and displays a medium color state of the solvent when the white charged pigment particles are driven to an area between the common and pixel electrodes.
2. The color display device of claim 1, further comprising an adhesive layer of a dark color or a color complementary to the color of the solvent, and the adhesive layer is at the opposite side of the viewing side of the display device.
3. The color display device of claim 1, wherein the top surface of the partition walls is of a dark color or a color complementary to the color of the solvent.
4. The color display device of claim 1, wherein the partition walls are of a black or dark color.
5. The color display device of claim 1, wherein no more than 10% of the light is reflected at the peak transmission of the dark color state.
6. The color display device of claim 5, wherein no more than 3% of the light is reflected at the peak transmission of the dark color state.
7. The color display device of claim 1, wherein the medium color of the solvent has a reflectance at least ten times the reflectance of the dark color state.
8. The color display device of claim 1, wherein said microcups and said pixel electrodes are aligned.
9. The color display device of claim 8, wherein each microcup represents a pixel.
10. The color display device of claim 1, wherein said microcups and said pixel electrodes are un-aligned.
11. The color display device of claim 1, wherein said pixel electrodes are active matrix driving electrodes.
12. The color display device of claim 1, wherein the dark color of the solvent is dark red, dark green or dark blue.
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