US7135446B1 - System for cleaning and protecting windshields - Google Patents
System for cleaning and protecting windshields Download PDFInfo
- Publication number
- US7135446B1 US7135446B1 US10/353,852 US35385203A US7135446B1 US 7135446 B1 US7135446 B1 US 7135446B1 US 35385203 A US35385203 A US 35385203A US 7135446 B1 US7135446 B1 US 7135446B1
- Authority
- US
- United States
- Prior art keywords
- glass
- clay
- composition
- deposits
- cleaner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related, expires
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 13
- 239000011521 glass Substances 0.000 claims abstract description 57
- 239000004927 clay Substances 0.000 claims abstract description 41
- 238000003916 acid precipitation Methods 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 239000007921 spray Substances 0.000 claims abstract description 11
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 22
- 239000000443 aerosol Substances 0.000 claims description 17
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 235000010755 mineral Nutrition 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 239000003380 propellant Substances 0.000 claims description 15
- 239000002738 chelating agent Substances 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 11
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 11
- 238000005187 foaming Methods 0.000 claims description 8
- 239000006260 foam Substances 0.000 claims description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 7
- 238000000151 deposition Methods 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 239000000271 synthetic detergent Substances 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 244000068988 Glycine max Species 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 239000004811 fluoropolymer Substances 0.000 description 12
- 229920002313 fluoropolymer Polymers 0.000 description 12
- 238000000034 method Methods 0.000 description 9
- 238000000576 coating method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 5
- 150000002576 ketones Chemical class 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 229940124447 delivery agent Drugs 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- NGDLSKPZMOTRTR-OAPYJULQSA-N (4z)-4-heptadecylidene-3-hexadecyloxetan-2-one Chemical compound CCCCCCCCCCCCCCCC\C=C1/OC(=O)C1CCCCCCCCCCCCCCCC NGDLSKPZMOTRTR-OAPYJULQSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001272 nitrous oxide Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- -1 nonylphenyl Chemical group 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 241000592335 Agathis australis Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000004446 fluoropolymer coating Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008256 whipped cream Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
-
- C11D2111/18—
Definitions
- the present invention relates to automobile windshields. More particularly, the present invention relates to cleaning and protecting automobile windshields.
- Acid rain causes spots on automobile windows and windshields which are difficult to remove.
- One commercially available method of removing these spots involves rubbing the glass with a piece of clay (see, for example, products sold under the trademark CLAY-MAGIC, U.S. Trademark Registration No. 1,890,761).
- CLAY-MAGIC U.S. Trademark Registration No. 1,890,761
- kaolin clay can remove mineral deposits from painted automotive surfaces if properly applied. This involves dragging a solid block of clay across the paint using a soapy water solution as a lubricant. This prevents scratching and prevents drag. However, the process is somewhat difficult and requires a higher skill level. If the bar is not rotated frequently, the accumulated contaminant will quickly scratch the finish. It is a process that does not lend itself to glass. Kaolin clay by itself will not scratch the glass since the material is softer. The mineral deposits are, however, much harder.
- Kaopolite SF (super fine kaolin clay) has been used for many years in car polishes for painted surfaces.
- a web site sponsored by PPG tells about their product “Aquapel”. It appears to be the same type of chemistry as Fibershield 218. However, it is applied using a special sponge applicator.
- the PPG product is for professional use so the inventors believe that it is the standard water-based product that requires buffing clear. Aquapel makes no claims as scratch resistance. They also make no claims about treating acrylics (either Plexiglas or polycarbonate).
- U.S. Pat. No. 4,687,591 discloses an aerosol cleaning composition with 15–25% by weight kaolin clay for cleaning cymbals.
- U.S. Pat. No. 4,450,151 discloses an aerosol composition which could contain 5–60% by weight kaolin clay.
- U.S. Pat. No. 5,076,952 discloses a liquid dishwasher cleaning agent which can contain clay particles, sodium bicarbonate and sodium tripolyphosphate.
- U.S. Pat. No. 4,395,456 discloses an inorganic foam which can include kaolin clay.
- U.S. Pat. No. 5,034,114 discloses neutralizing acid with a solution containing sodium bicarbonate and a detergent tripolyphosphate.
- U.S. Pat. No. 6,241,579 discloses a surface polishing applicator system and method.
- U.S. Pat. No. 5,928,064 discloses a surface polishing method and system. Both of these patents are assigned to Auto Wax Company, Inc., the maker of Clay Magic brand polish and bars containing abrasive material for removing stains from automobiles.
- U.S. Pat. No. 5,846,650 discloses a protective coating for windshields (see column 1, line 9) that prevents ice build-up and contains a fluoropolymer and a fluorochemical surfactant (see column 2, lines 35–42).
- U.S. Pat. Nos. 5,969,067 and 6,177,196 disclose a coating solution containing a fluoropolymer, which can be applied to a windshield (see column 7, lines 7 and 8).
- U.S. Pat. No. 6,156,389 discloses a protective coating that is applied to windshield and contains a fluoropolymer (see claim 3 in Column 32).
- U.S. Pat. No. 5,712,355 discloses a formulation that contains fluoropolymers, fluorosurfactants and water that is applied to glass microscope slides as a protectant.
- the present invention includes a system for cleaning acid rain marks from automobile glass and a system for more effectively delivering Fibershield 218 and like protectants to glass.
- the present invention includes apparatus for cleaning glass having acid rain deposits and/or mineral deposits, preferably comprising:
- a foaming clay windshield cleaner comprising:
- the present invention includes a method of cleaning glass, comprising spraying the apparatus of the present invention mentioned in the paragraph above on glass;
- the present invention includes a system for more effectively delivering Fibershield 7525 and like protectants to glass comprising a concentrate comprising:
- the concentrate preferably further comprises about 1.0–20 by weight wetting agent.
- the system can comprise about 80% by weight of the concentrate and about 20% by weight of a propellant.
- the present invention includes a system for more effectively delivering Fibershield 218 and like protectants to glass comprising a concentrate comprising:
- the alcohol can comprise isopropyl alcohol, propanol, acetone/ketone, and/or ethanol (specially denatured or fully denatured).
- the present invention includes a kit for cleaning and protecting glass, comprising:
- the cleaning system comprises a clay-based formula including the kaolin clay presently used for this purpose in bar form, but in powder form mixed with lubricants, other cleaners, and delivery agents.
- This formula is preferably delivered to glass by spraying, using an aerosol foaming propellant.
- the foaming clay windshield cleaner of the present invention incorporates kaolin clay, combined with sodium bicarbonate and synthetic detergent to clean away and suspend both mineral deposits and acid rain contaminant on glass.
- the sodium bicarbonate neutralizes the acid rain deposit.
- Chelators such as sodium tripolyphosphate
- the clay frees the mineral deposit.
- the device of the present invention safely and easily removes mineral deposits and acid rain contaminant from glass and auto windshields. It is a mechanism that incorporates chemical and mechanical action. It differs from commercial buffing in that the procedure and device can be applied by the user without special training, machinery or skills.
- the device is an easy-to-use unique inverted aerosol foam that clings to the glass prior to treatment and facilitates clean clay with every application. This is not a clay bar and the present invention pertains only to glass. It does not pertain to painted or other surfaces (several commercially available cleaners/waxes for paint include clay). This is a chemical/mechanical glass cleaner designed to specifically remove mineral and acid rain deposits. And, unlike the clay bar, this is a one-step process.
- Preferred Formula Chemical Function Percentage by Weight Water (preferably deionized Diluent Preferably about 30–70 water or distilled water, More preferably about 60–70 though one could use tap Most Preferably about 62–66 water if an aluminum About 65.34, for example container is used)
- Sodium Benzoate Can preservative Preferably about 1.0–0.10 (optional, could be More preferably about 0.80–0.10 omitted, and more Most Preferably about 0.70–0.10 water could be used) About 0.20, for example A water soluble phosphate, Chelator Preferably about 2.0–0.10 or nitrilo acetic acid More preferably about 1.5–0.25 (NTA)), preferably Sodium Most Preferably about 1.0–0.40 Tripolyphosphate About 0.504, for example Dehydrated Clay, preferably Cleans mineral Preferably about 25–5.0 Dehydrated Kaolin Clay deposits More preferably about 15–6 Most Preferably about 12–7 About 10, for example Neutralizer, preferably Cleans acid deposits
- Oil preferably silicone oil Lubricant, Preferably about 5–0.10 brightener More preferably about 3–0.10 Most Preferably about 2–0.20 About 1.95, for example Hydrocarbon propellant or, Aerosol foaming Preferably about 15–4.0 e.g., CO 2 , Dimethyl ether, propellant More preferably about 13–5 143A or 152A Most Preferably about 12–7 About 10, for example
- the clay-based cleaning product of the present invention is preferably primarily packaged as an inverted whipped cream-like foam (preferably with a valve typically used on whipped cream containers) but can also be sprayed upright with a clog-resistant valve.
- This product can also be sprayed as a solvent-based aerosol. It could be sprayed on like touch-up paint or it can be packaged as a thick liquid squirted through a flip-top lid. Additionally, it can be applied as a cream or thicker paste.
- the essence is a clay/sodium bicarbonate glass cleaner designed to clean away mineral and acid deposits on glass.
- the glass could be wiped immediately, or the cleaner could be allowed to sit on the glass for 5–15 minutes; the glass is then buffed with a soft cloth for about 10 seconds–10 minutes to remove the stains.
- the stains are removed through a chemical process in which the formula reacts with the stains to cause them to not adhere any more to the glass.
- the present inventors have invented a system for more effectively delivering Fibershield 218 and like protectants to glass. They have developed two formulations, one water-based and the other IPA (isopropyl alcohol) based.
- the system of the present invention for more effectively delivering Fibershield 218 and like protectants to glass preferably sprays on. It is also a fast drying alcohol based system. The alcohol also improves the wetting action.
- the system of the present invention is designed for the “do it yourselfer”.
- Water based Chemical Function Percentage by Weight Water diluent Preferably about 60–98 More preferably about 65–96 Most Preferably about 80–95 90, for example fluoropolymer (such as Preferably about 5–15 Fibershield 218, but More preferably about 6–14 preferably Fibershield Most Preferably about 7–13 7525) 10.00, for example Polar solvent (such as an wetting agent Preferably about 1.0–20 alcohol, a ketone, or a (optional) More preferably about 4–15 glycol ether) Most Preferably about 5–10 About 5, for example If used in a pump, the water-based formula is preferably used as is.
- fluoropolymer such as Preferably about 5–15 Fibershield 218, but More preferably about 6–14 preferably Fibershield Most Preferably about 7–13 7525
- Polar solvent such as an wetting agent Preferably about 1.0–20 alcohol, a ketone, or a (optional) More preferably about 4
- a fluorosurfactant DuPont ISP 100 or equivalent
- a 9–13 mole nonylphenyl surfactant could be used, in an amount of about 0.005 percent by weight. However, preferably no fluorosurfactant is used.
- IPA based Chemical Function Percentage by Weight alcohol, preferably diluent Preferably about 60–90 isopropyl alcohol or ethanol More preferably about 61–80 (specially denatured or fully Most Preferably about 63–70 denatured), but propanol About 63.9, for example and acetone/ketone (and combinations of all of these) could also be used fluoropolymer (preferably Protectant Preferably about 5–15 Fibershield 218) More preferably about 6–14 Most Preferably about 6.5–12 About 8.0, for example A polar solvent, preferably to increase Preferably about 5–30 acetone solubility More preferably about 5–10 Most Preferably about 6–9 About 8.0, for example aerosol propellant A/46 (or propellant Preferably about 14–30 nitrous oxide or dimethyl More preferably about 15–28 ether or CO 2 or nitrogen) Most Preferably about 16–25 20.0, for example
- the IPA based formula could use other alcohols, such as propanol, acetone/ketone, and/or ethanol (specially denatured or fully denatured).
- Fibershield 218 uses hydrogen bonding to bond to the glass; it polymerizes in about 24 hours, providing a thin film which protects the glass. This thin film lasts several weeks at least, and perhaps even several months. Additional coatings can be applied over earlier coatings.
- the method and coating system of the present invention can be used on ceramic tiles and stone containing silicon dioxide (e.g., granite, marble) as well as glass.
- silicon dioxide e.g., granite, marble
- the glass and surface cleaner of the present invention was specifically designed to work with the entire system of the present invention.
- This powerful cleaner has been super-charged with special detergents (sodium bicarbonate and non-ionic surfactant) that target the embedded deposits in the grooves of glass and glass-like surfaces.
- the glass and surface cleaner of the present invention helps users prepare their surface before the application of the spray clay of the present invention and also helps remove the residual clay residue before the shield product of the present invention is applied.
- the foaming action of the glass and surface cleaner of the present invention lets users know it is working and does wipe away clean with no streaks.
- the glass and surface cleaner of the present invention is used.
- a water soluble phosphate, chelator Preferably about 0.1–2 or nitrilo acetic acid More preferably about 0.2–1.5 (NTA)), preferably Sodium Most Preferably about 0.3–0.8 Tripolyphosphate About 0.5, for example Water diluent Preferably about 90–50 More preferably about 85–60 Most Preferably about 85–70 About 83.2, for example a chelator, preferably chelator Preferably about 0.1–2 sodium bicarbonate or More preferably about 0.2–1.5 calcium carbonate Most Preferably about 0.3–0.8 About 0.5, for example Any ethylene or propylene solvent Preferably about .1–5 glycol ether, preferably More preferably about .3–3 Butyl Cellosolve TM brand Most Preferably about .4–2 Ethylene Glycol About 1, for example Mono-n-butyl Ether Non-ionic surfactant with Surfactant Prefer
- the present invention includes a kit including a spray clay (preferably the preferred spray clay of the present invention), a glass and surface cleaner (preferably the preferred glass and surface cleaner of the present invention), and a fluoropolymer delivery agent (preferably the preferred IPA-based formula of the present invention including Fibershield 218).
- a spray clay preferably the preferred spray clay of the present invention
- a glass and surface cleaner preferably the preferred glass and surface cleaner of the present invention
- a fluoropolymer delivery agent preferably the preferred IPA-based formula of the present invention including Fibershield 218
Abstract
Description
-
- clay for freeing mineral deposits;
- sodium bicarbonate for neutralizing acid rain deposits; and
- a chelator to keep the deposits from clinging on the glass and re-depositing. The chelator is preferably sodium tripolyphosphate. The cleaner is preferably formulated as a convenient, effective aerosol foam or as a convenient, effective aerosol spray. The clay is preferably kaolin clay. Preferably, synthetic detergent is included to clean away and suspend both mineral deposits and acid rain deposits. Most preferably, the cleaner includes an aerosol foaming propellant.
-
- a spray clay;
- a glass and surface cleaner;
- a fluoropolymer delivery agent. Preferably, the spray clay comprises a foaming clay windshield cleaner comprising:
- clay for freeing mineral deposits;
- sodium bicarbonate for neutralizing acid rain deposits; and
- a chelator to keep the deposits from clinging on the glass and re-depositing; and the fluoropolymer delivery agent comprises:
- 60–90% by weight alcohol;
- 5–15% by weight fluoropolymer;
- 5–10% by weight acetone; and
- 20–30% by weight aerosol propellant. Preferably, the glass and surface cleaner comprises:
- a chelator, a diluent, a solvent, a surfactant, a pH builder, and a propellant.
Preferred Formula: |
Chemical | Function | Percentage by Weight |
Water (preferably deionized | Diluent | Preferably about 30–70 |
water or distilled water, | More preferably about 60–70 | |
though one could use tap | Most Preferably about 62–66 | |
water if an aluminum | About 65.34, for example | |
container is used) | ||
Sodium Benzoate | Can preservative | Preferably about 1.0–0.10 |
(optional, could be | More preferably about 0.80–0.10 | |
omitted, and more | Most Preferably about 0.70–0.10 | |
water could be used) | About 0.20, for example | |
A water soluble phosphate, | Chelator | Preferably about 2.0–0.10 |
or nitrilo acetic acid | More preferably about 1.5–0.25 | |
(NTA)), preferably Sodium | Most Preferably about 1.0–0.40 | |
Tripolyphosphate | About 0.504, for example | |
Dehydrated Clay, preferably | Cleans mineral | Preferably about 25–5.0 |
Dehydrated Kaolin Clay | deposits | More preferably about 15–6 |
Most Preferably about 12–7 | ||
About 10, for example | ||
Neutralizer, preferably | Cleans acid deposits | Preferably about 10–0.6 |
sodium bicarbonate (but | More preferably about 9–0.7 | |
calcium carbonate, for | Most Preferably about 7–1.0 | |
example, could be used | About 1.0, for example | |
also) | ||
Synthetic (non-ionic) | Emulsifier and | Preferably about 10–0.20 |
detergent | cleaner | More preferably about 7–0.4 |
Most Preferably about 6–0.5 | ||
About 1.998, for example | ||
Solvent, such as soy bean | Solvent degreaser | Preferably about 30–5.0 |
ester, hydrocarbon solvent | More preferably about 20–7 | |
(napthenic or paraffinic, | Most Preferably about 15–8 | |
glycol ether, vegetable oil, | About 9.990, for example | |
alcohols or any solvent with | ||
a KB (Kauri Butanol value) | ||
low enough to not damage | ||
the glass but high enough to | ||
add cleaning power). | ||
Oil, preferably silicone oil | Lubricant, | Preferably about 5–0.10 |
brightener | More preferably about 3–0.10 | |
Most Preferably about 2–0.20 | ||
About 1.95, for example | ||
Hydrocarbon propellant or, | Aerosol foaming | Preferably about 15–4.0 |
e.g., CO2, Dimethyl ether, | propellant | More preferably about 13–5 |
143A or 152A | Most Preferably about 12–7 | |
About 10, for example | ||
Water based: |
Chemical | Function | Percentage by Weight |
Water | diluent | Preferably about 60–98 |
More preferably about 65–96 | ||
Most Preferably about 80–95 | ||
90, for example | ||
fluoropolymer (such as | Preferably about 5–15 | |
Fibershield 218, but | More preferably about 6–14 | |
preferably Fibershield | Most Preferably about 7–13 | |
7525) | 10.00, for example | |
Polar solvent (such as an | wetting agent | Preferably about 1.0–20 |
alcohol, a ketone, or a | (optional) | More preferably about 4–15 |
glycol ether) | Most Preferably about 5–10 | |
About 5, for example | ||
If used in a pump, the water-based formula is preferably used as is. If used in an aerosol, one could use, e.g., 80% of the water-based formula and 20% of a propellant, such as aerosol propellant A/46 (a propane/isobutane blend). In either event, a fluorosurfactant (DuPont ISP 100 or equivalent) or a 9–13 mole nonylphenyl surfactant could be used, in an amount of about 0.005 percent by weight. However, preferably no fluorosurfactant is used.
IPA based (preferred formulation): |
Chemical | Function | Percentage by Weight |
alcohol, preferably | diluent | Preferably about 60–90 |
isopropyl alcohol or ethanol | More preferably about 61–80 | |
(specially denatured or fully | Most Preferably about 63–70 | |
denatured), but propanol | About 63.9, for example | |
and acetone/ketone (and | ||
combinations of all of | ||
these) could also be used | ||
fluoropolymer (preferably | Protectant | Preferably about 5–15 |
Fibershield 218) | More preferably about 6–14 | |
Most Preferably about 6.5–12 | ||
About 8.0, for example | ||
A polar solvent, preferably | to increase | Preferably about 5–30 |
acetone | solubility | More preferably about 5–10 |
Most Preferably about 6–9 | ||
About 8.0, for example | ||
aerosol propellant A/46 (or | propellant | Preferably about 14–30 |
nitrous oxide or dimethyl | More preferably about 15–28 | |
ether or CO2 or nitrogen) | Most Preferably about 16–25 | |
20.0, for example | ||
Preferred Glass and Surface Cleaner Formulation |
Chemical | Function | Percentage by Weight |
A water soluble phosphate, | chelator | Preferably about 0.1–2 |
or nitrilo acetic acid | More preferably about 0.2–1.5 | |
(NTA)), preferably Sodium | Most Preferably about 0.3–0.8 | |
Tripolyphosphate | About 0.5, for example | |
Water | diluent | Preferably about 90–50 |
More preferably about 85–60 | ||
Most Preferably about 85–70 | ||
About 83.2, for example | ||
a chelator, preferably | chelator | Preferably about 0.1–2 |
sodium bicarbonate or | More preferably about 0.2–1.5 | |
calcium carbonate | Most Preferably about 0.3–0.8 | |
About 0.5, for example | ||
Any ethylene or propylene | solvent | Preferably about .1–5 |
glycol ether, preferably | More preferably about .3–3 | |
Butyl Cellosolve ™ brand | Most Preferably about .4–2 | |
Ethylene Glycol | About 1, for example | |
Mono-n-butyl Ether | ||
Non-ionic surfactant with | Surfactant | Preferably about 1–.05 |
an HLB (hydrophilic | More preferably about .7–.09 | |
lithophilic balance) of 9– | Most Preferably about .6–.2 | |
13, nonylphenyl surfactant, | About .3, for example | |
9–13 moles of ethylene | ||
oxide | ||
Solvent, preferably | Solvent | Preferably about 5–.1 |
Methylal [Dimethyl | More preferably about 4–.3 | |
Formal] | Most Preferably about 3–.5 | |
About 1, for example | ||
Alcohols or ketones, | solvent | Preferably about 15–.3 |
preferably ethanol or | More preferably about 10–.5 | |
Isopropyl Alcohol (IPA) (or | Most Preferably about 8–.9 | |
combinations of all of | About 7, for example | |
these) | ||
Aqueous ammonia (or any | pH Builder | Preferably about .05–1 |
ammonia bearing amine) | More preferably about .06–.9 | |
Most Preferably about .07–.8 | ||
About 0.2, for example | ||
Hydrocarbon Propellant A- | Propellant | Preferably about .2–12 |
46 (or nitrous oxide or | More preferably about .5–10 | |
dimethyl ether or CO2 or | Most Preferably about .7–9 | |
nitrogen) | About 6, for example | |
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/353,852 US7135446B1 (en) | 2002-01-28 | 2003-01-28 | System for cleaning and protecting windshields |
US10/898,890 US7282100B1 (en) | 2002-01-28 | 2004-07-26 | Method of cleaning automobile painted surfaces and automobile glass surfaces |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35243502P | 2002-01-28 | 2002-01-28 | |
US10/353,852 US7135446B1 (en) | 2002-01-28 | 2003-01-28 | System for cleaning and protecting windshields |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/898,890 Continuation-In-Part US7282100B1 (en) | 2002-01-28 | 2004-07-26 | Method of cleaning automobile painted surfaces and automobile glass surfaces |
Publications (1)
Publication Number | Publication Date |
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US7135446B1 true US7135446B1 (en) | 2006-11-14 |
Family
ID=37397641
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US10/353,852 Expired - Fee Related US7135446B1 (en) | 2002-01-28 | 2003-01-28 | System for cleaning and protecting windshields |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110197915A1 (en) * | 2010-02-12 | 2011-08-18 | Galata Chemicals, Llc | Bio-Based Solvents and Methods for Using Same |
US20110226544A1 (en) * | 2010-03-16 | 2011-09-22 | Rasco Gmbh | Microelectromechanical System Testing Device |
Citations (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3928065A (en) * | 1973-12-19 | 1975-12-23 | Lever Brothers Ltd | Composition for cleaning metal cookware |
US4002571A (en) * | 1972-03-08 | 1977-01-11 | S. C. Johnson & Son, Inc. | Cleaning compositions |
US4051056A (en) * | 1974-09-09 | 1977-09-27 | The Procter & Gamble Company | Abrasive scouring compositions |
US4338377A (en) | 1979-10-10 | 1982-07-06 | Minnesota Mining And Manufacturing Company | Sulfonato-organosilanol compounds and aqueous solutions thereof |
US4394179A (en) * | 1979-06-25 | 1983-07-19 | Polymer Technology Corporation | Abrasive-containing contact lens cleaning materials |
US4395456A (en) | 1980-01-10 | 1983-07-26 | Imperial Chemical Industries Limited | Inorganic foam |
US4436637A (en) * | 1982-12-13 | 1984-03-13 | Colgate-Palmolive Company | Fabric softening heavy duty liquid detergent containing a mixture of water insoluble soap and clay |
EP0103466A1 (en) * | 1982-09-09 | 1984-03-21 | R & C PRODUCTS PTY. LIMITED | Oven cleaner |
US4450151A (en) | 1978-08-21 | 1984-05-22 | Toyo Aerosol Industry Co., Ltd. | Powder aerosol composition |
US4687591A (en) | 1986-08-22 | 1987-08-18 | Antonio Castaldo | Cleaning composition for cymbals |
US4830783A (en) * | 1979-06-25 | 1989-05-16 | Polymer Technology, Corp | Abravise-containing contact lens cleaning materials |
US4877691A (en) * | 1985-11-27 | 1989-10-31 | Kay Chemical Company | Soil release agent and method to facilitate the cleaning of ovens used for cooking |
CN1050559A (en) * | 1989-09-30 | 1991-04-10 | 中国科学院地质研究所 | Household utensil detergent and method for making thereof |
US5034114A (en) | 1989-07-28 | 1991-07-23 | Ira Kukin | Acid neutralizing combustion additive with detergent builder |
US5076952A (en) | 1989-04-28 | 1991-12-31 | Ahmed Fahm U | Aqueous liquid automatic dishwasher detergent composition containing a dual bleach system |
US5128027A (en) | 1990-06-07 | 1992-07-07 | Naguib Halaka | Method for removing mineral slimes from kaolin clay |
US5364551A (en) * | 1993-09-17 | 1994-11-15 | Ecolab Inc. | Reduced misting oven cleaner |
US5712355A (en) | 1995-02-03 | 1998-01-27 | E. I. Du Pont De Nemours And Company | Fluoromonomer/functionalized hydrocarbon monomer copolymerization process and copolymer product |
US5779912A (en) | 1997-01-31 | 1998-07-14 | Lynntech, Inc. | Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant |
US5846650A (en) | 1996-05-10 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Anti-reflective, abrasion resistant, anti-fogging coated articles and methods |
US5872111A (en) | 1997-05-19 | 1999-02-16 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising glycosylamide surfactants |
US5928064A (en) | 1995-11-01 | 1999-07-27 | Auto Wax Company, Inc. | Surface polishing method and system |
US5969067A (en) | 1996-09-13 | 1999-10-19 | E.I. Dupont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
US5981459A (en) * | 1995-09-29 | 1999-11-09 | The Procter & Gamble Company | Foam for treating textile fabrics |
US6156389A (en) | 1997-02-03 | 2000-12-05 | Cytonix Corporation | Hydrophobic coating compositions, articles coated with said compositions, and processes for manufacturing same |
US6183872B1 (en) | 1995-08-11 | 2001-02-06 | Daikin Industries, Ltd. | Silicon-containing organic fluoropolymers and use of the same |
US6207780B1 (en) | 1995-05-12 | 2001-03-27 | Rohm & Haas Company | Interpolymers of unsaturated carboxylic acids and unsaturated sulfur acids |
US6241579B1 (en) | 1997-01-10 | 2001-06-05 | Auto Wax Company, Inc. | Surface polishing applicator system and method |
US6310014B1 (en) | 1999-10-05 | 2001-10-30 | Phyzz Inc. | Personal and household care compositions |
US20030027737A1 (en) * | 2000-06-29 | 2003-02-06 | The Procter & Gamble Company | Process of cleaning a hard surface |
-
2003
- 2003-01-28 US US10/353,852 patent/US7135446B1/en not_active Expired - Fee Related
Patent Citations (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4002571A (en) * | 1972-03-08 | 1977-01-11 | S. C. Johnson & Son, Inc. | Cleaning compositions |
US3928065A (en) * | 1973-12-19 | 1975-12-23 | Lever Brothers Ltd | Composition for cleaning metal cookware |
US4051056A (en) * | 1974-09-09 | 1977-09-27 | The Procter & Gamble Company | Abrasive scouring compositions |
US4450151A (en) | 1978-08-21 | 1984-05-22 | Toyo Aerosol Industry Co., Ltd. | Powder aerosol composition |
US4394179A (en) * | 1979-06-25 | 1983-07-19 | Polymer Technology Corporation | Abrasive-containing contact lens cleaning materials |
US4830783A (en) * | 1979-06-25 | 1989-05-16 | Polymer Technology, Corp | Abravise-containing contact lens cleaning materials |
US4338377A (en) | 1979-10-10 | 1982-07-06 | Minnesota Mining And Manufacturing Company | Sulfonato-organosilanol compounds and aqueous solutions thereof |
US4395456A (en) | 1980-01-10 | 1983-07-26 | Imperial Chemical Industries Limited | Inorganic foam |
EP0103466A1 (en) * | 1982-09-09 | 1984-03-21 | R & C PRODUCTS PTY. LIMITED | Oven cleaner |
US4436637A (en) * | 1982-12-13 | 1984-03-13 | Colgate-Palmolive Company | Fabric softening heavy duty liquid detergent containing a mixture of water insoluble soap and clay |
US4877691A (en) * | 1985-11-27 | 1989-10-31 | Kay Chemical Company | Soil release agent and method to facilitate the cleaning of ovens used for cooking |
US4687591A (en) | 1986-08-22 | 1987-08-18 | Antonio Castaldo | Cleaning composition for cymbals |
US5076952A (en) | 1989-04-28 | 1991-12-31 | Ahmed Fahm U | Aqueous liquid automatic dishwasher detergent composition containing a dual bleach system |
US5034114A (en) | 1989-07-28 | 1991-07-23 | Ira Kukin | Acid neutralizing combustion additive with detergent builder |
CN1050559A (en) * | 1989-09-30 | 1991-04-10 | 中国科学院地质研究所 | Household utensil detergent and method for making thereof |
US5128027A (en) | 1990-06-07 | 1992-07-07 | Naguib Halaka | Method for removing mineral slimes from kaolin clay |
US5364551A (en) * | 1993-09-17 | 1994-11-15 | Ecolab Inc. | Reduced misting oven cleaner |
US5712355A (en) | 1995-02-03 | 1998-01-27 | E. I. Du Pont De Nemours And Company | Fluoromonomer/functionalized hydrocarbon monomer copolymerization process and copolymer product |
US6207780B1 (en) | 1995-05-12 | 2001-03-27 | Rohm & Haas Company | Interpolymers of unsaturated carboxylic acids and unsaturated sulfur acids |
US6183872B1 (en) | 1995-08-11 | 2001-02-06 | Daikin Industries, Ltd. | Silicon-containing organic fluoropolymers and use of the same |
US5981459A (en) * | 1995-09-29 | 1999-11-09 | The Procter & Gamble Company | Foam for treating textile fabrics |
US5928064A (en) | 1995-11-01 | 1999-07-27 | Auto Wax Company, Inc. | Surface polishing method and system |
US5846650A (en) | 1996-05-10 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Anti-reflective, abrasion resistant, anti-fogging coated articles and methods |
US5969067A (en) | 1996-09-13 | 1999-10-19 | E.I. Dupont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
US6177196B1 (en) | 1996-09-13 | 2001-01-23 | E. I. Du Pont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
US6241579B1 (en) | 1997-01-10 | 2001-06-05 | Auto Wax Company, Inc. | Surface polishing applicator system and method |
US5779912A (en) | 1997-01-31 | 1998-07-14 | Lynntech, Inc. | Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant |
US6156389A (en) | 1997-02-03 | 2000-12-05 | Cytonix Corporation | Hydrophobic coating compositions, articles coated with said compositions, and processes for manufacturing same |
US5872111A (en) | 1997-05-19 | 1999-02-16 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising glycosylamide surfactants |
US6310014B1 (en) | 1999-10-05 | 2001-10-30 | Phyzz Inc. | Personal and household care compositions |
US20030027737A1 (en) * | 2000-06-29 | 2003-02-06 | The Procter & Gamble Company | Process of cleaning a hard surface |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110197915A1 (en) * | 2010-02-12 | 2011-08-18 | Galata Chemicals, Llc | Bio-Based Solvents and Methods for Using Same |
US20110226544A1 (en) * | 2010-03-16 | 2011-09-22 | Rasco Gmbh | Microelectromechanical System Testing Device |
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