US6906131B2 - Cellulose material with improved absorbency - Google Patents
Cellulose material with improved absorbency Download PDFInfo
- Publication number
- US6906131B2 US6906131B2 US09/954,348 US95434801A US6906131B2 US 6906131 B2 US6906131 B2 US 6906131B2 US 95434801 A US95434801 A US 95434801A US 6906131 B2 US6906131 B2 US 6906131B2
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- Prior art keywords
- superabsorbent polymer
- cellulose material
- cellulose
- monomer
- solution
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/28—Polysaccharides or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F2013/530481—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
Definitions
- the present invention relates to cellulose materials that have improved absorbency through the incorporation of polymers that absorb aqueous liquids (such as water, blood and urine).
- the invention relates to cellulose material treated with a pre-superabsorbent polymer that is converted to superabsorbent polymer upon heating of the treated cellulose material.
- the resulting cellulose material has enhanced absorbency over non-treated cellulose material.
- the present invention involves cellulose material and superabsorbent polymers.
- Cellulose material and the art of manufacture of cellulose material are well known to those skilled in the art.
- cellulose material and the process to manufacture are discussed in the book entitled “Handbook for Pulp and Paper Technologist” (Angus Wilde Publications Inc., 1992) by Gary A. Smook.
- Superabsorbent polymers have been used to coat absorbent fibers and drying the coated fibers as disclosed for example see U.S. Pat. No. 4,962,172 (Issued Oct. 9, 1990) to Allen et al; and U.S. Pat. No. 5,160,789 (issued Nov. 3, 1992) to Barcus et al.
- Cellulose fibers have a retention capacity or CRC of about less then 2g/g i.e. cellulose fibers are considered to be a non-absorbent fiber.
- coating fibers with a polymer solution generally adversely affects the fibers other properties such as wicking power and makes the fiber brittle.
- the present invention provides a method for making a treated cellulose material having enhanced absorbency.
- the method comprises first preparing an aqueous solution of pre-superabsorbent polymer, which is formed from at least one monomer, where the pre-superabsorbent polymer is capable upon being subjected to heating of becoming a superabsorbent polymer.
- cellulose material is provided that may be pretreated with a treatment solution comprising an aqueous alkaline solution.
- a slurry is formed made up of the aqueous solution of pre-superabsorbent polymer and the cellulose material. The slurry is then filtered and heat-treated to obtain a treated cellulose material having an enhanced absorbency.
- the present invention provides an absorbent cellulose material comprising a cellulose material having an application of superabsorbent polymer composition adhered to the cellulose material wherein an aqueous solution of pre-superabsorbent polymer is applied to the cellulose material and converted to absorbent polymer upon subjected to heat for a sufficient time wherein the absorbent cellulose material has a fluid retention of greater than 2g/g.
- the present invention provides an absorbent product selected from the group consisting of, agricultural products, fiber optic cables, power cables, water blocking tapes, insulation, hygiene articles, feminine care products, sanitary napkins, tampons, adult incontinence items, baby diapers, paper towels, sealing composites for concrete blocks, bandages, surgical sponges, meat trays, and bath mats, wherein the absorbent product comprises an absorbent cellulose material comprising a cellulose material having an application of superabsorbent polymer composition adhered to the cellulose material wherein an aqueous solution of pre-superabsorbent polymer is applied to the cellulose material and converted to absorbent polymer upon subjected to heat for a sufficient time wherein the absorbent cellulose material has a fluid retention of greater than 2g/g.
- the present invention provides a method for making a treated cellulose material having enhanced absorbency.
- the method includes a first preparation of an aqueous solution of pre-superabsorbent polymer, which is formed from at least one monomer, where the pre-superabsorbent polymer is capable upon being subjected to heating in a later step of the method of becoming a superabsorbent polymer.
- Cellulose material is provided that may be pretreated with a treatment solution comprising an aqueous alkaline solution.
- slurry is formed made up of the aqueous solution of pre-superabsorbent polymer and the cellulose material. The slurry is then filtered and heat-treated to obtain a treated cellulose material having an enhanced absorbency.
- the first preparation of the method includes an aqueous solution of pre-superabsorbent polymer (pre-SAP).
- pre-SAP pre-superabsorbent polymer
- the SAP may be manufactured by any of the prior art polymerization processes for making the SAPs.
- the pre-SAP is water soluble
- a solution polymerization process is employed to make the pre-SAP
- the SAPs made this way are called solution polymerization SAPs.
- any of the prior art emulsion or suspension polymerization processes may be employed to make the SAP with the following condition.
- a surfactant would have to be present in order to emulsify the aqueous monomer solution in the oil phase prior to polymerization.
- Suitable surfactants for use in the present invention are well known to those of skill in the art of emulsion polymerization.
- the SAPs made this way are called emulsion polymerization SAPs.
- aqueous solution of the polymer i.e., of the pre-SAP
- aqueous suspension that has present in it a surfactant
- the SAP may be obtained by polymerizing at least about 10%, more preferably about 25%, even more preferably about 55 to about 99.9%, by weight of monomers having olefinically-unsaturated carboxylic and/or sulfonic acid groups.
- acid groups include, but are not limited to, acrylic acid, methacrylic acid, 2-acrylamido-2-methylpropane sulfonic acid, and mixtures thereof.
- the acid groups are present partially as salts, such as sodium, potassium, or ammonium salts.
- the acid groups are typically neutralized to at least about 25 mol %, more preferably at least about 50 mol %. More particularly, the preferred SAP has been formed from X-linked acrylic acid or methacrylic acid, which has been neutralized to an extent of about 50 to about 80 mol %, more preferably about 60 to about 70 mol %.
- Suitable neutralizing agents are hydroxides and/or carbonates of alkaline earth metals and/or alkali metals, for instance, NaOH. Neutralization of acid groups may be performed prior to the polymerization to form the pre-SAP, may be performed on the pre-SAP, or a combination thereof.
- Additional useful monomers for making the SAPs include from about 0 up to about 60% by weight of acrylamide, methacrylamide, maleic acid, maleic anhydride, esters (such as hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, glycidyl methacrylate, dimethyl-aminoalkylacrylate, dimethyl-aminoalkyl-methacrylate, diethylaminoalkyl acrylate,diethylaminoalkyl methacrylate and tertairy butylaminoalkyl methacrylate), dimethyl-aminopropyl acrylamide, N,N-Dimethylacrylamide, N,N-Dimethylmethacrylamide, N,N-Diethylacrylamide, N,N-Diethylmethacrylamide, dimethyldiallylamine, 3-methacrylamidopropyldimethylamine, 2-methacryla
- a preferred amount is from about 1% to about 55%, more preferably from about 2% to about 10% by weight.
- a suitable hydroxypropyl acrylate for use in the present invention is sold under the trade name Mhoromer AM 438 by Creanova, Inc. Such monomers may be present whether or not a network X-linking agent as described in the next paragraph, is present.
- Suitable network X-linking agents that may be used in making the SAPs are those, which have 1 ethylenically unsaturated double bond and 1 functional group reactive toward acid groups, and those, which have several functional groups reactive toward acid groups. Very minor amounts of network X-linking agents which have at least 2 ethylenically unsaturated double bonds may also be used to enhance performance.
- Suitable kinds of network X-linking agents include, but are not limited to, acrylate and methacrylate of polyols (such as butanediol diacrylate, polyglycol diacrylate, hexanediol dimethacrylate, tetrahydrofurfury-2-methacrylate, glycerol dimethacrylate, trimethylolpropane triacrylate, allyloxy polyethylene glycol methacrylate, and ethoxylated trimethylolpropane triacrylate), allyl acrylate, diallyl acrylamide, triallyl amine, diallyl ether, N-methylol acrylamide, methylenebisacrylamide, glycerol dimethacrylate, N,N-dimethylaminoethyl methacrylate, N-dimethylaminopropyl methacryladmide, and N-methylol methacrylamide, two or more valent metal, diglycidyl ether, di
- the diglycidyl ether is very suitable for use in the present invention and is sold under the trade name: DENACOL®EX830 by Nagase Chemicals Ltd.
- DENACOL®EX830 by Nagase Chemicals Ltd.
- one or more of the monomers noted in the previous paragraph may effect network X-linking.
- the SAP is formed by heating the pre-SAP in the last step of the method.
- heating may be conducted in the presence of a diglycidyl ether as a network X-linking agent, which causes functional groups, such as hydroxyl and/or carboxyl present in the pre-SAP to X-link via epoxy groups of X-linking agent and form the SAP.
- a typical temperature range for the network X-linking to convert the pre-SAP into a SAP is selected based on the equipment and process conditions and may range from about 60° C. to about 140° C., more preferably from about 110 to about 135° C. and most preferably from about 120 to about 130° C.
- the heating to convert the pre-SAP into the SAP may require a higher temperature.
- the time for heating typically is from about 30 seconds to about 60 minutes. A time of about 1 to about 50 minutes is very typical. The specific time and temperature are not critical, as long as they are sufficient to X-link the pre-SAP and convert it into a SAP.
- Cellulose materials used in the present invention are commercial products available from various manufacturers such as Georgia Pacific, Rayonier, etc.
- the cellulose materials may be used by itself with the aqueous solution of the pre-SAP or in the form of a pre-treated aqueous cellulose form.
- a pre-treated aqueous cellulose is formed by pre-treating a cellulose material with a treatment solution comprising aqueous alkaline solution.
- a suitable aqueous alkaline solution is NaOH, preferably in the concentration of about 0.5N.
- the treated cellulose fiber is filtered and washed and optionally dried.
- a slurry is formed made up of the aqueous solution of pre-superabsorbent polymer and the pre-treated aqueous cellulose.
- the slurry is agitated for a sufficient amount of time, then filtered and heat-treated to obtain a treated cellulose material having an enhanced absorbency.
- polymer solution For example to illustrate the preparation of the slurry, about 100 milliliters of approximately 1.5% polymer solution was prepared by diluting the appropriate amount of pre-superabsorbent polymer.
- One gram of freshly prepared 0.23% DENACOL®EX830 (Nagase Chemicals Ltd., Nishi-Ku, Osaka Japan, a polyethylene glycol diglycidyl ether was added to the dilute polymer solution. The mixture was vigorously stirred at room temperature. About 1 gram of dry pre-treated pulp cellulose fiber made in cellulose pre-treatment step was added to the polymer solution. The mixture was stirred at room temperature for 6 hours. The wet pulp was then filtered and allowed to air dry at room temperature. The cellulose fiber was then heated at 120° C. for 30 minutes. The resulting pulp cellulose fiber was shredded in a blender to make a fluff. The fluffed cellulose fiber was then sieved with 100-mesh size screen to remove fine fiber particles.
- SAP fines can be added to the process to enhance the absorbency of the cellulose material.
- SAP fines are commercially available from Stockhausen under the trademark FAVOR®SAP fines.
- the SAP fines are added to the slurry preparation. For example, an aliquot of SAP fines may be added to the fiber slurry and/or to the aqueous solution of the pre-SAP.
- the SAP fines are vigorously stirred into the slurry or the aqueous solution for a few minutes to yield a homogeneous mixture.
- the present invention can be used in the manufacture of pulp and paper or the manufacture of cellulose material.
- the present invention can be used as a part of the manufacturing process that is in line with current pulp, paper and cellulose material manufacturing techniques.
- cellulose material having enhanced absorbency of the present invention include, but are not limited to, agricultural products (i.e., a polymer with herbicide and/or insecticide), fiber optic cables, power cables, water blocking tapes, insulation, hygiene articles, feminine care products (i.e., sanitary napkins and/or tampons), incontinence items for adults, diapers for babies, paper towels, sealing composites between concrete blocks, bandages, surgical sponges, meat trays, bath mats, and the like.
- agricultural products i.e., a polymer with herbicide and/or insecticide
- fiber optic cables i.e., fiber optic cables, power cables, water blocking tapes, insulation, hygiene articles, feminine care products (i.e., sanitary napkins and/or tampons), incontinence items for adults, diapers for babies, paper towels, sealing composites between concrete blocks, bandages, surgical sponges, meat trays, bath mats, and the like.
- CRC Test The test was conducted at ambient conditions of room temperature. Retention of 0.9% saline solution was determined according to the tea bag test method and reported as an average value of 2 measurements. Approximately 100 mg of Cellulosic material particles, were enclosed in a tea bag and immersed in the saline solution for 30 minutes. Next individually hang each teabag up by the corners to drip-dry for 10 minutes. Then, the tea bag was centrifuged at 1400 rpm for 5 minutes and weighed. The diameter of the centrifuge apparatus was about 21 cm. Also, 2 tea bags without particles were used as blanks.
- a method of making the cellulose material of the present invention follows the following general procedure:
- the fiber/SAP slurry was then filtered under vacuum (30 inches Hg). The wet pulp was then allowed to air dry at room temperature. The cellulose fiber was then heated at 120° C.—for 30 minutes. The resulting pulp cellulose fiber was shredded in a blender to make a fluff. The fluffed cellulose fiber was then sieved with 100-mesh size screen to remove fine fiber particles.
- Cellulose Fiber/SAP Fines Fluid Retention Sample Composition Process Control Cellulose fiber as received 1.5-2.0 6 2 gram of cellulose fiber as received; First, the cellulose fiber was stirred in polymer/crosslinker 7.1 198 g 1.5% copolymer solution of 50% DN PAA & solution mixture for an hour to obtain an uniform slurry; DMAEA & 2 g of 0.5186% DENACOL EX830 & then SAP fines were added and mixed well and immediateley 1 g FAVOR ® SAP fines. filtered under vacuum. The pad thus obtained was dried at 120° C.
- the pad thus obtained was dried at 120° C. 11 2 gram of dried alkali cellulose fluff, First cellulose fluff was stirred in polymer/crosslinker 8.3 198 g 1.44% copolymer solution of 50% DN PAA & solution mixture for an hour to obtain an uniform slurry; DMAEA & 2 g of 0.5186% DENACOL EX830 & then SAP fines were added and mixed well and immediately 1 g FAVOR ® SAP fines filtered under vacuum. The pad thus obtained was dried at 120° C.
Abstract
Description
Definitions of Abbreviations |
Abbreviations | Definitions | ||
X-linking | cross-linking | ||
SAP | superabsorbent polymer, a polymer | ||
which absorbs over 10 times its weight | |||
in water | |||
pre-SAP | a polymer which is not a SAP and which | ||
is capable upon heating of becoming a | |||
SAP | |||
CRC | centrifuge retention capacity | ||
g | gram | ||
DMAEA | dimethylaminoethyl acrylate | ||
PAA | poly acrylic acid | ||
DN | degree of neutralization | ||
-
- 1. Cut the teabag stock into 3×5-inch rectangles. Fold the strips in half, and seal two of the three open sides so the inside edge of the seals are about ¼ inch from the edge of the teabag.
- 2. For each determination, weigh 0.100+/−0.005 grams of modified cellulosic material into a teabag. Record the initial weight as W1.
- 3. Seal the open side of the teabags using the heat sealer. Store the teabags in a desiccator if the period of time between the initial weighing and the determination is greater than 30 minutes.
- 4. Prepare the two test method blanks by heat-treating two empty teabags without cellulose material sample.
- 5. Fill a dish with 0.9% saline solution to approximately 4 cm high.
- 6. Prepare the sealed teabags for immersion by gently shaking the sample to distribute the cellulosic material evenly across the teabag.
- 7. Immerse the teabags in the 0.9% saline.
- 8. After 30 minutes, remove the teabags from the test liquid.
- 9. Individually hang each teabag up by the corners to drip-dry for 10 minutes.
- 10. Place the teabags into the centrifuge making sure to balance the centrifuge with proper teabag placement. Centrifuge for 3 minutes at 1600 rpm.
- 11. After centrifugation, determine the weights of each sample. Record the weights of the test blanks, without test sample (W2) and the weight of the teabag with test sample accurate to 0.01(W3).
CRC=(W 3 −W 2 −W 1)/W 1
where:
-
- CRC=retention after 30 minutes immersion time (g/g)
- W1=initial weight in grams of SAP particles
- W2=average weight in grams of two blanks after centrifugation
- W3=weight in grams of test tea bag after centrifugation
Fluid | |||
Retention | |||
Sample | Treatment | Process | (g/g) |
Control | Cellulose fiber | 1.5-2.0 | |
1 | Cellulose fiber treated | Stirred 6 hours, vacuum | 3.2 |
with DMAEA containing | filtered, dried at room | ||
50% DN PAA solution | temperature then heated | ||
(1.5%) & 0.16% | at 120° C./10 min, | ||
DENACOL ® EX830. | shredded & fluffed by a | ||
blender | |||
2 | Alkali treated cellulose | Stirred 6 hours, vacuum | 4.1 |
fiber treated with | filtered, dried at room | ||
DMAEA containing 50% | temperature then heated | ||
DN PAA solution | at 120° C./10 min, | ||
(2%) & 0.16% | shredded & fluffed by a | ||
DENACOL ® EX830. | blender. | ||
3 | Alkali treated cellulose | Stirred 6 hours, vacuum | 4.9 |
fiber with DMAEA | filtered, dried at room | ||
containing 50% DN PAA | temperature then heated | ||
solution (1.5%) & 0.16% | at 120° C./10 min, | ||
DENACOL ® EX830. | shredded & fluffed by a | ||
blender. | |||
4 | Alkali treated cellulose | Stirred 6 hours, vacuum | 4.9 |
fiber treated with NaOH | filtered, dried at room | ||
treated cellulosic material | temperature then heated | ||
fluff treated with 50% | at 120° C./10 min, | ||
DN PAA solution | shredded & fluffed by a | ||
(1.37%) & 0.2% | blender. | ||
DENACOL ® EX830 | |||
5 | Alkali treated cellulose | Stirred 6 hours, vacuum | 5.8 |
fiber treated with | filtered, dried at room | ||
DMAEA containing 50% | temperature then heated | ||
DN PAA solution | at 120° C./10 min, | ||
(1.6%) & 0.2% | shredded & fluffed by a | ||
DENACOL ® EX830 | blender. | ||
Cellulose Fiber/SAP Fines | Fluid Retention | ||
Sample | Composition | Process | (g/g) |
Control | Cellulose fiber as received | 1.5-2.0 | |
6 | 2 gram of cellulose fiber as received; | First, the cellulose fiber was stirred in polymer/crosslinker | 7.1 |
198 g 1.5% copolymer solution of 50% DN PAA & | solution mixture for an hour to obtain an uniform slurry; | ||
DMAEA & 2 g of 0.5186% DENACOL EX830 & | then SAP fines were added and mixed well and immediateley | ||
1 g FAVOR ® SAP fines. | filtered under vacuum. The pad thus obtained was dried at | ||
120° C. | |||
7 | 2 gram of cellulose fiber as received; | First, SAP fines were stirred in polymer/crosslinker | 7.3 |
198 g 1.5% copolymer solution of 50% DN PAA & | solution mixture to obtain an uniform slurry; then | ||
DMAEA & 2 g of 0.5186% DENACOL EX830 & | cellulose fiber was added and stirred well to obtain | ||
1 g FAVOR ® SAP fines. | an uniform mixture. The mixture was then filtered under | ||
vacuum. The pad thus obtained was dried at 120° C. | |||
8 | 2 gram of dried alkali treated cellulosic; | First, the cellulose fiber was stirred in polymer/crosslinker | 6.3 |
198 g 1.44% copolymer solution of 50% DN PAA & | solution mixture for an hour to obtain an uniform slurry; | ||
DMAEA & 2 g of 0.5186% DENACOL EX830 & | then SAP fines were added and mixed well and immediately | ||
1 g FAVOR ® SAP fines. | filtered under vacuum. The pad thus obtained was dried at | ||
120° C. | |||
9 | 2 gram of dried alkali treated cellulose fiber; | The filtrate was refiltered, made slurry with fiber, | 7.3 |
filtrate from Example 8 & 1 g | then SAP fines were added, mixed well, filtered and | ||
FAVOR ® SAP fines | dried the resulting pad at 120° C. | ||
10 | 2 gram of dried alkali treated cellulose fiber; | First, cellulose fiber was stirred in polymer/crosslinker | 7.1 |
198 g 1.44% copolymer solution of 50% DN | solution mixture for an hour to obtain an uniform slurry; | ||
PAA & DMAEA & 2 g of 0.5186% DENACOL | then SAP fines were added and mixed well and immediately | ||
EX830 & 1 g FAVOR ® SAP fines | filtered under vacuum. The pad thus obtained was dried at | ||
120° C. | |||
11 | 2 gram of dried alkali cellulose fluff, | First cellulose fluff was stirred in polymer/crosslinker | 8.3 |
198 g 1.44% copolymer solution of 50% DN PAA & | solution mixture for an hour to obtain an uniform slurry; | ||
DMAEA & 2 g of 0.5186% DENACOL EX830 & | then SAP fines were added and mixed well and immediately | ||
1 g FAVOR ® SAP fines | filtered under vacuum. The pad thus obtained was dried at | ||
120° C. | |||
12 | 2 gram of dried alkali cellulose fiber, | The filtrate refiltered, made slurry with fiber, then SAP | 8.5 |
filtrate from Example 10 & | fines add, mixed well, filtered, and dried the resulting | ||
1 g FAVOR ® SAP fines. | pad at 120° C. | ||
13 | 2 gram of alkali cellulose fiber, 35 g 1.44% | First, cellulose fluff was mixed with 25 g of polymer/crosslinker | 9.6 |
copolymer solution of 50% DN PAA & DMAEA & | solution, then the paste like mixture was transferred to a blender | ||
2g of 0.5186% DENACOL EX830 & 1 g | and 1 g of SAP fines was added. The content was blended at a | ||
FAVOR ® SAP fines | low speed for a couple of minutes. Then an additional 10 g of | ||
polymer/crosslinker solution was added to the blender and the | |||
whole content was blended at a high speed for 2-3 minutes. | |||
The paste was then vacuum filtered to remove excess fluid (˜5 g). | |||
The pad thus obtained was dried at 120° C. | |||
It will be understood that various details of the invention may be changed without departing from the scope of the invention. Furthermore, the foregoing description is for the purpose of illustration only, and not for the purpose of limitation of the invention being defined by the claims.
Claims (14)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/954,348 US6906131B2 (en) | 2001-09-17 | 2001-09-17 | Cellulose material with improved absorbency |
DE60238212T DE60238212D1 (en) | 2001-09-17 | 2002-09-12 | CELLULOSE MATERIAL WITH IMPROVED ABSORPTION |
EP02798791A EP1438354B1 (en) | 2001-09-17 | 2002-09-12 | Cellulose material with improved absorbency |
CNB028199510A CN1331930C (en) | 2001-09-17 | 2002-09-12 | Cellulose material with improved absorbency |
PCT/IB2002/003772 WO2003025054A1 (en) | 2001-09-17 | 2002-09-12 | Cellulose material with improved absorbency |
AT02798791T ATE486907T1 (en) | 2001-09-17 | 2002-09-12 | CELLULOSE MATERIAL WITH IMPROVED ABSORBENT CAPACITY |
BR0212575-7A BR0212575A (en) | 2001-09-17 | 2002-09-12 | Enhanced absorbency cellulose material |
CA002460152A CA2460152C (en) | 2001-09-17 | 2002-09-12 | Cellulose material with improved absorbency |
US10/923,194 US7482058B2 (en) | 2001-09-17 | 2004-08-20 | Cellulose material with improved absorbency |
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US09/954,348 US6906131B2 (en) | 2001-09-17 | 2001-09-17 | Cellulose material with improved absorbency |
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US10/923,194 Division US7482058B2 (en) | 2001-09-17 | 2004-08-20 | Cellulose material with improved absorbency |
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US20030055133A1 US20030055133A1 (en) | 2003-03-20 |
US6906131B2 true US6906131B2 (en) | 2005-06-14 |
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US09/954,348 Expired - Lifetime US6906131B2 (en) | 2001-09-17 | 2001-09-17 | Cellulose material with improved absorbency |
US10/923,194 Expired - Lifetime US7482058B2 (en) | 2001-09-17 | 2004-08-20 | Cellulose material with improved absorbency |
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Country Status (8)
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US (2) | US6906131B2 (en) |
EP (1) | EP1438354B1 (en) |
CN (1) | CN1331930C (en) |
AT (1) | ATE486907T1 (en) |
BR (1) | BR0212575A (en) |
CA (1) | CA2460152C (en) |
DE (1) | DE60238212D1 (en) |
WO (1) | WO2003025054A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
US7482058B2 (en) | 2009-01-27 |
US20050020771A1 (en) | 2005-01-27 |
US20030055133A1 (en) | 2003-03-20 |
DE60238212D1 (en) | 2010-12-16 |
ATE486907T1 (en) | 2010-11-15 |
WO2003025054A1 (en) | 2003-03-27 |
CA2460152C (en) | 2009-10-27 |
EP1438354A1 (en) | 2004-07-21 |
BR0212575A (en) | 2004-10-13 |
CN1331930C (en) | 2007-08-15 |
CN1568347A (en) | 2005-01-19 |
EP1438354B1 (en) | 2010-11-03 |
CA2460152A1 (en) | 2003-03-27 |
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