US6726804B2 - RF power delivery for plasma processing using modulated power signal - Google Patents

RF power delivery for plasma processing using modulated power signal Download PDF

Info

Publication number
US6726804B2
US6726804B2 US09/767,282 US76728201A US6726804B2 US 6726804 B2 US6726804 B2 US 6726804B2 US 76728201 A US76728201 A US 76728201A US 6726804 B2 US6726804 B2 US 6726804B2
Authority
US
United States
Prior art keywords
signal
frequency
power
modulated
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US09/767,282
Other versions
US20020096257A1 (en
Inventor
Liang-Guo Wang
Kwok M. Wong
Shamouil Shamouilian
Kartik Ramaswamy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Applied Materials Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US09/767,282 priority Critical patent/US6726804B2/en
Assigned to APPLIED MATERIALS, INC. reassignment APPLIED MATERIALS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: RAMASWAMY, KARTIK, WONG, KWOK M., WANG, LIANG-GUO, SHAMOUILIAN, SHAMOUIL
Publication of US20020096257A1 publication Critical patent/US20020096257A1/en
Application granted granted Critical
Publication of US6726804B2 publication Critical patent/US6726804B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • H01J37/32137Radio frequency generated discharge controlling of the discharge by modulation of energy
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • C23C16/505Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
    • C23C16/507Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges using external electrodes, e.g. in tunnel type reactors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • H01J37/321Radio frequency generated discharge the radio frequency energy being inductively coupled to the plasma

Definitions

  • the present invention relates plasma processing apparatuses and methods, and power systems for plasma processing apparatuses.
  • Plasma processing apparatuses are used to etch and deposit different materials in industries such as the semiconductor industry. For example, in a typical dry etching process, a semiconductor wafer including a layer to be etched is disposed within an etch chamber. A gaseous plasma is created in the chamber using radio frequency (RF) power at a single fixed frequency. The created plasma passes through an etch mask on the layer to etch it and form a desired pattern.
  • RF radio frequency
  • controllable processing parameters it is desirable to increase the number of controllable processing parameters in a plasma processing apparatus. More controllable process parameters provide process engineers with more ways to control the operation of the apparatus to optimize a given process.
  • One way to increase the number of parameters is to use two separate, fixed frequency power sources instead of one fixed frequency power source in the plasma processing apparatus. Power signals at two different fixed frequencies can be applied to a reactant gas in the processing chamber to form a plasma instead of power at one frequency.
  • the duty cycles of the power signals can be modulated. Duty cycle modulation is described in detail below.
  • FIG. 1 shows a conventional plasma reactor apparatus with two, high power, fixed frequency power sources 21 , 24 coupled to a chamber 10 .
  • An upper electrode 12 forms part of the chamber 10 and is grounded.
  • One source 21 generates a high power, high frequency RF signal at, e.g., 13.56 MHz.
  • the other source 24 generates a high power, low frequency RF signal at, e.g., 100 KHz.
  • the high and low frequency signals pass from the power sources 21 , 24 through respective impedance matching networks 23 , 26 , and to central and lower electrodes 13 , 15 .
  • the lower electrode 15 forms part of a wafer chuck which supports a wafer to be processed.
  • a control means 27 controls two modulators 22 , 25 .
  • the two modulators 22 , 25 modulate the RF signals coming from the high and low frequency power sources 21 , 24 before being sent to the electrodes 13 , 15 .
  • RF signals from the respective power sources 21 , 24 are modulated to provide a duty cycle of 100% or less.
  • Duty cycle refers to the fraction, expressed as a percent, per unit time that a signal is “on” or applied to a load. For example, a signal that is applied to a load one-half the time has a fifty percent duty cycle.
  • Duty cycle modulation is a type of “pulse modulation” and can be described in greater detail with reference to FIG. 2 .
  • FIG. 2 illustrates a pair of waveforms representing the control signals from the control means 27 to the modulators 22 , 25 .
  • Waveforms 31 and 32 represent the signals to modulators 22 and 25 , respectively.
  • a process is initiated at a time A and the 13.56 MHz signal from source 21 is continuously applied to electrode 13 until the process is discontinued at time B.
  • the control signal 32 is supplied to the modulator 25 to turn the 100 KHz signal from the source 24 on and off at some suitable rate.
  • the duty cycle of signal 31 is 100% and the duty cycle of signal 32 is approximately 50%.
  • the matching networks 23 , 26 in the apparatus reduce the amount of power reflected back to the RF power sources 21 , 24 .
  • the plasma within the chamber forms an impedance (capacitive reactance) which changes.
  • An RF mismatch arises between the power sources 21 , 24 and the plasma so that some of the RF power is reflected back to the power sources 21 , 24 .
  • the matching networks 23 , 26 compensate for the changing plasma impedance.
  • Each matching network 23 , 26 is adapted to minimize power reflections at the frequencies of the power sources 21 , 24 . For example, a power source providing power at 100 MHz uses a matching network designed to reduce reflections of power at about 100 MHz. If too much power is reflected back to the power sources 21 , 24 , the power sources 21 , 24 may be detrimentally driven into foldback.
  • the apparatus has two different matching networks 23 , 26 for two different high power, fixed frequency power sources 21 , 24 .
  • Each matching network 23 , 26 includes a number of components such as variable capacitors, electric motor servos, and an RF detector circuit.
  • many of the components of the matching networks 23 , 26 are bulky and can fail.
  • an apparatus using two high power sources 21 , 24 is more complex and consumes more energy than an apparatus using one high power, fixed frequency power source. Increased energy consumption leads to increased operating costs.
  • the power sources and matching networks can interfere with each other.
  • two separate different fixed frequency power sources deliver different frequencies of power to the same electrode (e.g., the wafer chuck).
  • the two fixed power source/matching network combinations are electrically coupled to each other.
  • the other power source and its associated matching network can act as a load to the other power source. Consequently, some power can be inadvertently diverted from one power source/matching network combination to another combination instead of to the reactant gas in the chamber.
  • the interference between different power sources and matching networks can be reduced by decoupling electronics.
  • using decoupling electronics in the apparatus further increases the cost and the complexity of the apparatus.
  • Arcing can cause instabilities in the plasma and can cause undesired process variations. Arcing can be avoided by limiting the gas pressure range in the chamber, reducing the total RF power, or reducing the low frequency power applied to the chamber. Although the likelihood of arcing can be reduced by limiting the range of process parameters such as these, it is sometimes desirable to enable broader ranges of such process parameters to be used without inducing arcing.
  • the apparatus can deliver one or two fixed frequency, duty cycle modulated power signals to the chamber
  • the apparatus has a relatively small number of adjustable process parameters.
  • the apparatus only provides for a) one or two fixed frequencies of power to a chamber, and b) the ability to turn the power on and off at some rate. While the ability to modulate the duty cycle of a power signal provides some ability to control the plasma process, the power provided by a duty cycle modulated power signal is still at a single frequency and amplitude. Consequently, the controllable variability of the plasma process is limited.
  • Embodiments of the invention address these and other problems.
  • One embodiment of the invention is directed to a plasma processing apparatus.
  • the apparatus comprises: a single carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; a modulator adapted to modulate the first RF signal with the second RF signal to form an amplitude modulated signal, wherein the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of the peaks of the first RF signal; and a plasma processing chamber coupled to the modulator.
  • the apparatus comprises: a carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; a modulator adapted to modulate the first RF signal with the second RF signal to form a frequency modulated signal; and a plasma processing chamber coupled to the modulator.
  • Another embodiment of the invention is directed to a method of delivering a power signal to a plasma processing chamber.
  • the method comprises: generating a first RF signal at a carrier frequency; generating a second RF signal at a modulating frequency; forming an amplitude modulated (AM) signal by modulating the first RF signal with the second RF signal, wherein the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of peaks of the first RF signal; and delivering only the amplitude modulated signal to a reactant gas within the plasma processing chamber to form a plasma.
  • AM amplitude modulated
  • Another embodiment of the invention is directed to a method of delivering a power signal to a plasma processing chamber.
  • the method comprises: generating a first RF signal at a carrier frequency; generating a second RF signal at a modulation frequency; forming a frequency modulated (FM) signal by modulating the first RF signal with the second RF signal; and generating a plasma within the plasma processing chamber using the frequency modulated signal.
  • FM frequency modulated
  • the power system embodiments may include a carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; and a modulator adapted to modulate the first RF signal with the second RF signal to form a frequency and/or an amplitude modulated signal
  • FIG. 1 illustrates a conventional dual frequency plasma processing apparatus.
  • FIG. 2 illustrates two waveforms of power signals used in the dual frequency plasma processing apparatus in FIG. 1 .
  • FIG. 3 illustrates a plasma processing apparatus according to an embodiment of the invention.
  • FIG. 4 a flowchart illustrating a method according to an embodiment of the invention.
  • FIGS. 5 (A) to 5 (C) respectively show waveforms for a carrier signal, a modulating signal, and an amplitude modulated signal according to embodiments of the invention.
  • FIGS. 6 (A) to 6 (B) respectively illustrate waveforms of a modulating signal, and a waveform for a frequency modulated signal according to embodiments of the invention.
  • a radio-frequency power signal is amplitude, frequency, or amplitude and frequency modulated.
  • the modulated power signal can have a waveform which is simple or complex. When the modulated power signal is applied to a reactant gas in a chamber, it can produce a plasma with unique characteristics.
  • the waveform of the modulated power signal can be modified by adjusting parameters such as the modulation index, the modulation frequency, and the power of the carrier signal. Adjustments such as these can be made without making significant hardware changes to the plasma processing apparatus.
  • more processing parameters are available for a process engineer to adjust to optimize a given process than many conventional plasma processing apparatuses. This increased processing capability is provided while advantageously decreasing the complexity of the apparatus.
  • a modulated RF power signal is transmitted to a plasma processing chamber in a plasma processing apparatus.
  • a first RF signal is generated at a carrier frequency.
  • the first RF signal is modulated by a second RF signal at a modulation frequency.
  • the resulting modulated signal may be an amplitude modulated signal, a frequency modulated signal, or a signal which is both amplitude and frequency modulated.
  • the first RF signal and the second RF signal may also be tuned in frequency.
  • the peaks of the amplitude modulated signals have amplitudes greater or less than the amplitudes of the peaks of the first RF signal.
  • the peak amplitudes of the modulated power signal are different than the peak amplitudes of the carrier signal.
  • a power signal with a unique waveform can be created and used to create a unique plasma tailored for a given process.
  • process variables such as ion energy can be controlled.
  • all signal peaks are at the same amplitude as the carrier signal.
  • a duty cycle modulated power signal a carrier signal is only turned “on” and “off” without modifying the frequency or peak amplitudes of the carrier signal. When the carrier signal is “off”, peaks are not present.
  • Embodiments of the invention provide a number of controllable process parameters for process engineers to change the characteristics of the power signal applied to the reactant gas.
  • the waveform for the power signal can be changed by adjusting parameters such as the modulation frequency, the carrier signal power, and the modulation index (the modulation index is the relative strength of the modulating signal to the carrier signal).
  • the modulation index is the relative strength of the modulating signal to the carrier signal.
  • Each matching network 23 , 26 in the apparatus shown in FIG. 1 is specifically adapted for the frequency of power generated by its corresponding power source 21 , 24 .
  • both the power source 21 , 24 and its matching network 23 , 26 would be changed in some way.
  • Matching networks minimize power reflections from variable, fixed frequency power sources. They typically include variable capacitors and inductors, or banks of fixed value components that are switched in and out. Changing a power source and its matching network to modify the frequency of a power signal delivered to a chamber is undesirable since doing so requires substantial hardware modifications.
  • the nature of the RF power applied to a reactant gas can determine the characteristics of the resulting plasma. For example, higher frequency power is generally more effective than lower frequency power to generate ions from a reactant gas.
  • High frequency power is generally characterized as power which is at a frequency of about 10 MHz or higher.
  • Increasing the amount of generated ions generally increases the ion density of a plasma.
  • the ion density of a plasma can affect processing variables in a deposition or an etching process. For example, a plasma with a high ion density generally etches a material faster than a plasma with a low ion density.
  • Low frequency power generally contributes more to ion energy than higher frequency power.
  • Low frequency power is generally characterized as power having a frequency of less than 1 MHz.
  • the plasma can be optimized for a deposition or an etching process.
  • PECVD plasma-enhanced chemical vapor deposition
  • low frequency power can be used to control the energy of the ions in the plasma to bombard a substrate to deposit a film.
  • the increased ion bombardment control can be used to improve the density, stress, and integrity of the formed film.
  • low frequency power can produce high energy ions that bombard a film to etch very deep profiles in the film in a plasma etch process. Accordingly, the use of low frequency power to generate a plasma is desirable in an anisotropic etch process.
  • the amplitude of the RF power signal may also influence the characteristics of the generated plasma.
  • Amplitude modulated RF power signals are believed to behave like low frequency power signals in that they can be used to control the energy of the ions in the plasma. For example, an amplitude modulated RF signal having a waveform with high peaks can direct ions along longer travel paths than an RF signal having a waveform with small peaks. The ions can accelerate as they travel along the longer paths provided by the amplitude modulated RF signal, thus producing high energy ions.
  • the frequency of a carrier signal can be modulated to form a frequency modulated power signal.
  • the frequency modulated signal may have components with lower and higher frequencies than the carrier signal.
  • the high frequency components can concentrate on the center part of a plasma body and can contribute more to ion density.
  • Lower frequency components can concentrate on the sheath region of the plasma and can contribute more to ion energy.
  • the peaks of the frequency modulated signal may have the same or different amplitudes as the peaks of the carrier signal.
  • the frequency modulated power signal can be adjusted to modify process variables such as the ion density of the plasma or the ion energy.
  • the amplitude of a carrier signal can be modulated to form an amplitude modulated power signal with peaks having higher or lower amplitudes than the peaks of the carrier signal.
  • the frequency of the amplitude modulated power signal may be the same or different than the frequency of the carrier signal.
  • the modulated power signal may have a unique waveform. Process variables such as the ion energy may be controlled by an amplitude modulated carrier signal.
  • a carrier RF signal may be both amplitude and frequency modulated.
  • a carrier signal may be modulated with an amplitude modulating signal and a frequency modulating signal from a modulation source.
  • the modulated power signal can have a unique waveform.
  • the modulated signal may have peaks of higher and lower amplitudes than the carrier signal peaks, and may have components with higher and lower frequency than the carrier signal frequency.
  • the modulated power signal can produce a unique plasma that can be optimized for a given process.
  • a carrier signal can be modulated to have many high frequency components and high peak amplitudes to form a high density plasma with high energy ions.
  • FIG. 3 illustrates an apparatus according to an embodiment of the invention.
  • an inductively coupled RF plasma processing apparatus 110 includes a sealed plasma processing chamber 112 bounded by a generally cylindrical conductive (metal) side wall 114 and a dielectric (e.g., quartz) dome-shaped ceiling 116 .
  • An RF shield 148 covers the ceiling 116 and is grounded.
  • a gas inlet 117 coupled to a gas manifold (not shown) provides an ionizable reactant gas to the interior of the chamber 112 .
  • Ionizable reactant gases supplied through the gas inlet 117 may include gases suitable for an etch process (e.g., CF 4 ) or gases suitable for a deposition process (e.g., silane).
  • a wafer pedestal 118 in the middle of the chamber 112 supports a semiconductor wafer 120 on an isolated conductive top 122 .
  • the wafer pedestal 118 may be a ceramic electrostatic chuck.
  • a vacuum pump (not shown) maintains the interior of the chamber 112 at a desired pressure (e.g., between 0 and 100 milliTorr). Used process gas passes out of a gas outlet (not shown) in communication with the chamber 112 .
  • RF power is coupled to the plasma (not shown) in the chamber 112 by a coiled antenna 124 wound around the exterior of the dome-shaped ceiling 116 .
  • the coil 124 is coupled to a power system 350 that supplies a modulated RF power signal to the chamber 112 .
  • the power system 350 is shown as being coupled to the coiled antenna 124 in FIG. 3, it may be coupled to any suitable part of the substrate processing apparatus.
  • the power system 350 may be coupled to either the lower electrode within the substrate support pedestal or to the gas manifold (upper electrode) of the apparatus.
  • the power system 350 includes a carrier source 302 , a modulation source 304 , a modulator 306 , an amplifier 308 , a transmission line 309 , and a matching network 310 . Each of these components is described in more detail below.
  • the carrier source 302 generates a first signal including a radio frequency (RF) carrier signal (step 402 ).
  • the carrier signal may have any suitable waveform, frequency or amplitude.
  • the frequency of the carrier signal may be from about 1 MHz to about 200 MHz.
  • the first signal may be a sinusoidal signal at a frequency of about 13.56 MHz, the frequency allocated by the Federal Communications Commission of the United States Government.
  • the carrier signal may have any suitable waveform, in some embodiments, the carrier signal is a sinusoidal waveform.
  • the modulation source 304 generates one or more modulating signals (step 404 ) to modulate the carrier signal.
  • the one or more modulating signals may have any suitable waveform, frequency or amplitude.
  • suitable waveforms include triangular, saw-tooth, or sinusoidal waveforms.
  • the one or more modulating signals have a sinusoidal waveform.
  • the modulating signals may be used to modulate the amplitude or frequency of the carrier signal.
  • the modulating signal may be at a lower frequency than the carrier signal.
  • the modulation frequency, ⁇ m may be about one or two orders of magnitude lower than the carrier frequency, ⁇ c .
  • the modulation frequency may be about 0.1 times or less, or about 0.1 to about 0.01 times the carrier frequency when the carrier signal is frequency modulated.
  • the modulation frequency is small compared to the carrier frequency, substantially all of the modulated carrier signal can still pass through the matching network adapted for the carrier frequency. This is true even if the modulated carrier signal includes frequency components which are higher and lower than the carrier frequency.
  • a typical matching network adapted to permit power at 100 MHz to pass to the chamber can also permit a substantial amount of power at frequencies between 98 MHz to 102 MHz to pass to the chamber without being reflected back to the power source.
  • a modulating signal less than about 1 MHz modulates a carrier frequency of 100 MHz, the frequency of the modulated carrier signal fluctuates within the range of 98 MHz to 102 MHz.
  • the modulator 306 receives the carrier signal from the carrier source 302 and the modulating signal from the modulation source 304 and modulates the carrier signal to generate a modulated signal (step 406 ).
  • the carrier signal is modulated to produce a modulated signal with any suitable waveform.
  • the modulated carrier signal may be amplitude modulated, frequency modulated, or may be both amplitude and frequency modulated.
  • the modulated carrier signal may be complex or simple. When the carrier signal is both frequency and amplitude modulated, the carrier signal may be modulated with an amplitude modulating signal and a frequency modulating signal.
  • Many of the modulation techniques used in embodiments of the invention are well known in the TV and radio broadcast industries.
  • FIG. 5 (B) shows an example of a waveform of a sinusoidal modulating signal that modulates the carrier signal shown in FIG. 5 (A). As shown, the modulating signal has a lower frequency than the carrier signal. The resulting modulated signal is amplitude modulated and is shown in FIG. 5 (C).
  • the graph in FIG. 5 (C) shows an amplitude modulated waveform and an envelope corresponding to the modulating signal is shown in FIG. 5 (B).
  • the amplitude modulated waveform has peaks with amplitudes greater than and less than the carrier signal peaks.
  • the carrier signal can be of the form E o sin( ⁇ c t) and the modulating signal may be of the form sin( ⁇ m t).
  • ⁇ c and ⁇ m represent the carrier and modulating frequencies, respectively.
  • E o represents a value for the initial E-field and t is the time.
  • the modulating signal modulates the carrier signal, the corresponding amplitude modulated signal may then be of the form
  • is a modulation index and indicates the relative strengths of the carrier and modulating signals. Generally, ⁇ is less than or equal to one.
  • the modulation index can be varied to adjust the amplitude of the carrier signal and consequently, the power delivered to the chamber.
  • the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of peaks of the first RF signal.
  • the amplitudes of the peaks of the amplitude modulated carrier signal can be increased or decreased by modifying one or more of the carrier signal power, the degree of amplification of the modulated signal, or the modulation index.
  • Increasing or decreasing the peak amplitudes of the modulated signal can increase or decrease the total RF power delivered to the plasma and/or can change the waveform for the modulated RF signal.
  • the amplitudes of the peaks of the carrier signal can be changed without making significant hardware changes.
  • the waveforms for both the carrier signal and the modulating signal may be sinusoidal in the frequency modulated embodiments of the invention.
  • FIG. 6 (A) shows an example of a waveform of a sinusoidal modulating signal that modulates the frequency of a carrier signal (not shown).
  • the resulting frequency modulated carrier signal is shown in FIG. 6 (B).
  • the amplitudes of the peaks of the frequency modulated waveform remain constant in this embodiment.
  • the frequency modulated signal may have components with higher and lower frequencies than the carrier signal frequency.
  • the frequency modulated signal may be of the form:
  • is again a modulation index and indicates the relative strengths of the carrier and modulating signals.
  • ⁇ c and ⁇ m again represent the carrier and modulating frequencies, respectively.
  • the modulation component exp[i ⁇ sin( ⁇ m t)] may be expanded in terms of the Bessel function J n ( ⁇ ) as:
  • the amplifier 308 receives a low power modulated signal and then amplifies it before delivering the modulated signal to the chamber (step 408 ).
  • a lower power carrier source 302 and a low power modulation source 304 can be used to produce the modulated signal.
  • Low power is generally power at about 100 Watts or less.
  • the amplifier 308 amplifies its power to generate a high power modulated power signal.
  • the magnitude of the average power applied to the chamber may vary according to the particular process run on the plasma processing apparatus.
  • the amplified high power modulated power signal may, for example, provide power in excess of 100 Watts to the chamber. For instance, in a typical CVD process, the power may be greater than about 1200 Watts. In a typical etch process, the power maybe greater than about 2000 Watts.
  • the modulated power signal is output by the amplifier 308 via a transmission line 309 and is received by a matching network 310 .
  • the matching network 310 receives the modulated power signal and provides impedance matching from the transmission line 309 to the plasma processing chamber 112 to ensure that substantially all of the power is delivered to the chamber.
  • Any suitable matching network 310 may be used in embodiments of the invention as long as the matching network matches the frequency of the signal from the carrier source 302 .
  • the matching network 310 can be any suitable commercially available matching network designed for this frequency of power.
  • the modulated power signal may be applied to any suitable part of the apparatus 110 (step 410 ).
  • the modulated power signal may pass through the matching network 310 and may be applied to the antennae coil 124 .
  • the antennae coil 124 applies the modulated power signal to reactant gases in the chamber 112 to produce a plasma.
  • the modulated power signal may be provided to the pedestal, the gas manifold (not shown) or any other suitable portion of the apparatus.
  • Embodiments of the invention are not limited to the specific embodiments shown and described with respect to the Figures.
  • the modulator 306 and the amplifier 308 are shown as separate devices, they may be combined in a single device. In another alternative embodiment, an amplifier is not needed.
  • the carrier source 302 may be a high power carrier source which generates a high power RF signal.
  • the modulation source 304 can supply a signal which modulates the high power RF signal before it is applied to the reactant gas in the chamber 312 .
  • Embodiments of the invention provide a number of advantages.
  • the inventive apparatus embodiments can use less hardware than many conventional apparatuses, the apparatus embodiments can have more controllable processing parameters than the conventional apparatuses. For instance, fewer power sources, matching networks, modulators, etc. are used in the inventive apparatus embodiment shown in FIG. 3 than the conventional apparatus shown in FIG. 1 .
  • processing parameters such as the modulation index, the carrier signal power, and the modulation frequency, power signals with simple or complex waveforms can be produced. Consequently, the plasma can be tailored to the particular processing being run in the plasma processing chamber.
  • two power signals at two frequencies and amplitudes are delivered to a reactant gas.
  • the apparatus includes a single matching network and a single high power source. Using a single matching network and a single high power source provides a number of advantages.
  • the resulting apparatus is less complex than a plasma processing apparatus using two matching networks and two high power sources. Eliminating a matching network and a power source also reduces the cost of the manufacturing the apparatus, since less components are needed to make the apparatus. Furthermore, because fewer components are present in the apparatus, the likelihood that the apparatus will become inoperative because of component failure is reduced. Lastly, when using one high power source instead of two power sources, less energy is consumed during operation resulting in lower operating costs.
  • the complexity of an apparatus can be reduced (e.g., as compared to conventional dual frequency apparatuses) while still providing a number of controllable parameters for a process engineer to adjust.
  • high and low frequency signals are combined outside of the processing chamber under controlled conditions.
  • the interference between the carrier and modulating signals can be controlled by a process engineer before delivering the power signal to the chamber.
  • the unintended interference of power signals within the plasma processing chamber can be avoided. Consequently, any unintended problems associated with the unintended interference of power signals are also avoided.
  • Embodiments of the invention may be used with any suitable plasma process and any suitable plasma processing apparatus. Suitable processes include etching processes such as reactive ion etching, and deposition processes such as plasma-assisted chemical vapor deposition (PECVD) and reactive sputtering.
  • PECVD plasma-assisted chemical vapor deposition
  • the plasmas produced according to embodiments of the invention may be of the inductively- or capacitively-coupled type.
  • Embodiments of the invention can be used to deposit or etch any suitable material including silicon containing materials such as silicon nitride, silicon oxide, and amorphous silicon.

Abstract

A plasma processing apparatus and a method of operating a plasma processing apparatus are disclosed. In one embodiment, a first RF signal at a carrier frequency and a second RF signal at a second frequency are generated. An amplitude modulated signal is formed by modulating the first RF signal with the second RF signal. A plasma is generated within the plasma processing chamber using the amplitude modulated signal. Generating plasma using a frequency modulated signal is also disclosed.

Description

BACKGROUND OF THE INVENTION
The present invention relates plasma processing apparatuses and methods, and power systems for plasma processing apparatuses. Plasma processing apparatuses are used to etch and deposit different materials in industries such as the semiconductor industry. For example, in a typical dry etching process, a semiconductor wafer including a layer to be etched is disposed within an etch chamber. A gaseous plasma is created in the chamber using radio frequency (RF) power at a single fixed frequency. The created plasma passes through an etch mask on the layer to etch it and form a desired pattern.
It is desirable to increase the number of controllable processing parameters in a plasma processing apparatus. More controllable process parameters provide process engineers with more ways to control the operation of the apparatus to optimize a given process. One way to increase the number of parameters is to use two separate, fixed frequency power sources instead of one fixed frequency power source in the plasma processing apparatus. Power signals at two different fixed frequencies can be applied to a reactant gas in the processing chamber to form a plasma instead of power at one frequency. To further increase the number of process parameters, the duty cycles of the power signals can be modulated. Duty cycle modulation is described in detail below.
FIG. 1 shows a conventional plasma reactor apparatus with two, high power, fixed frequency power sources 21, 24 coupled to a chamber 10. An upper electrode 12 forms part of the chamber 10 and is grounded. One source 21 generates a high power, high frequency RF signal at, e.g., 13.56 MHz. The other source 24 generates a high power, low frequency RF signal at, e.g., 100 KHz. The high and low frequency signals pass from the power sources 21, 24 through respective impedance matching networks 23, 26, and to central and lower electrodes 13, 15. The lower electrode 15 forms part of a wafer chuck which supports a wafer to be processed.
In the apparatus, a control means 27 controls two modulators 22, 25. The two modulators 22, 25 modulate the RF signals coming from the high and low frequency power sources 21, 24 before being sent to the electrodes 13, 15. RF signals from the respective power sources 21, 24 are modulated to provide a duty cycle of 100% or less. “Duty cycle” refers to the fraction, expressed as a percent, per unit time that a signal is “on” or applied to a load. For example, a signal that is applied to a load one-half the time has a fifty percent duty cycle.
Duty cycle modulation is a type of “pulse modulation” and can be described in greater detail with reference to FIG. 2. FIG. 2 illustrates a pair of waveforms representing the control signals from the control means 27 to the modulators 22, 25. Waveforms 31 and 32 represent the signals to modulators 22 and 25, respectively. As illustrated in FIG. 2, a process is initiated at a time A and the 13.56 MHz signal from source 21 is continuously applied to electrode 13 until the process is discontinued at time B. Meanwhile, the control signal 32 is supplied to the modulator 25 to turn the 100 KHz signal from the source 24 on and off at some suitable rate. In this example, the duty cycle of signal 31 is 100% and the duty cycle of signal 32 is approximately 50%.
The matching networks 23, 26 in the apparatus reduce the amount of power reflected back to the RF power sources 21, 24. During processing, the plasma within the chamber forms an impedance (capacitive reactance) which changes. An RF mismatch arises between the power sources 21, 24 and the plasma so that some of the RF power is reflected back to the power sources 21, 24. The matching networks 23, 26 compensate for the changing plasma impedance. Each matching network 23, 26 is adapted to minimize power reflections at the frequencies of the power sources 21, 24. For example, a power source providing power at 100 MHz uses a matching network designed to reduce reflections of power at about 100 MHz. If too much power is reflected back to the power sources 21, 24, the power sources 21, 24 may be detrimentally driven into foldback.
While the described apparatus is suitable for some applications, many improvements could be made. For example, it would be desirable if the apparatus was less complex, and consequently less costly to manufacture. The apparatus has two different matching networks 23, 26 for two different high power, fixed frequency power sources 21, 24. Each matching network 23, 26 includes a number of components such as variable capacitors, electric motor servos, and an RF detector circuit. In addition to being complex, many of the components of the matching networks 23, 26 are bulky and can fail. Also, an apparatus using two high power sources 21, 24 is more complex and consumes more energy than an apparatus using one high power, fixed frequency power source. Increased energy consumption leads to increased operating costs.
Also, when using two high power fixed frequency power sources in the apparatus, the power sources and matching networks can interfere with each other. For example, in some conventional apparatuses, two separate different fixed frequency power sources deliver different frequencies of power to the same electrode (e.g., the wafer chuck). In this situation, the two fixed power source/matching network combinations are electrically coupled to each other. When fixed frequency power is applied to the chamber by one power source, the other power source and its associated matching network can act as a load to the other power source. Consequently, some power can be inadvertently diverted from one power source/matching network combination to another combination instead of to the reactant gas in the chamber. The interference between different power sources and matching networks can be reduced by decoupling electronics. However, using decoupling electronics in the apparatus further increases the cost and the complexity of the apparatus.
Also, when two high power, fixed frequency power signals are delivered to a chamber, they can interfere with each other and cause arcing. Arcing can cause instabilities in the plasma and can cause undesired process variations. Arcing can be avoided by limiting the gas pressure range in the chamber, reducing the total RF power, or reducing the low frequency power applied to the chamber. Although the likelihood of arcing can be reduced by limiting the range of process parameters such as these, it is sometimes desirable to enable broader ranges of such process parameters to be used without inducing arcing.
In addition, while the apparatus can deliver one or two fixed frequency, duty cycle modulated power signals to the chamber, the apparatus has a relatively small number of adjustable process parameters. For example, the apparatus only provides for a) one or two fixed frequencies of power to a chamber, and b) the ability to turn the power on and off at some rate. While the ability to modulate the duty cycle of a power signal provides some ability to control the plasma process, the power provided by a duty cycle modulated power signal is still at a single frequency and amplitude. Consequently, the controllable variability of the plasma process is limited.
Embodiments of the invention address these and other problems.
SUMMARY OF THE INVENTION
One embodiment of the invention is directed to a plasma processing apparatus. The apparatus comprises: a single carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; a modulator adapted to modulate the first RF signal with the second RF signal to form an amplitude modulated signal, wherein the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of the peaks of the first RF signal; and a plasma processing chamber coupled to the modulator.
Another embodiment of the invention is directed a plasma processing apparatus. The apparatus comprises: a carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; a modulator adapted to modulate the first RF signal with the second RF signal to form a frequency modulated signal; and a plasma processing chamber coupled to the modulator.
Another embodiment of the invention is directed to a method of delivering a power signal to a plasma processing chamber. The method comprises: generating a first RF signal at a carrier frequency; generating a second RF signal at a modulating frequency; forming an amplitude modulated (AM) signal by modulating the first RF signal with the second RF signal, wherein the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of peaks of the first RF signal; and delivering only the amplitude modulated signal to a reactant gas within the plasma processing chamber to form a plasma.
Another embodiment of the invention is directed to a method of delivering a power signal to a plasma processing chamber. The method comprises: generating a first RF signal at a carrier frequency; generating a second RF signal at a modulation frequency; forming a frequency modulated (FM) signal by modulating the first RF signal with the second RF signal; and generating a plasma within the plasma processing chamber using the frequency modulated signal.
Yet other embodiments of the invention are directed to power systems for plasma processing apparatuses. The power system embodiments may include a carrier source adapted to generate a first RF signal at a carrier frequency; a modulation source adapted to generate a second RF signal at a modulation frequency; and a modulator adapted to modulate the first RF signal with the second RF signal to form a frequency and/or an amplitude modulated signal
These and other embodiments of the invention are discussed in further detail below with reference to the Figures and the Detailed Description.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates a conventional dual frequency plasma processing apparatus.
FIG. 2 illustrates two waveforms of power signals used in the dual frequency plasma processing apparatus in FIG. 1.
FIG. 3 illustrates a plasma processing apparatus according to an embodiment of the invention.
FIG. 4 a flowchart illustrating a method according to an embodiment of the invention.
FIGS. 5(A) to 5(C) respectively show waveforms for a carrier signal, a modulating signal, and an amplitude modulated signal according to embodiments of the invention.
FIGS. 6(A) to 6(B) respectively illustrate waveforms of a modulating signal, and a waveform for a frequency modulated signal according to embodiments of the invention.
DETAILED DESCRIPTION
In embodiments of the invention, a radio-frequency power signal is amplitude, frequency, or amplitude and frequency modulated. The modulated power signal can have a waveform which is simple or complex. When the modulated power signal is applied to a reactant gas in a chamber, it can produce a plasma with unique characteristics. The waveform of the modulated power signal can be modified by adjusting parameters such as the modulation index, the modulation frequency, and the power of the carrier signal. Adjustments such as these can be made without making significant hardware changes to the plasma processing apparatus. In embodiments of the invention, more processing parameters are available for a process engineer to adjust to optimize a given process than many conventional plasma processing apparatuses. This increased processing capability is provided while advantageously decreasing the complexity of the apparatus.
In embodiments of the invention, a modulated RF power signal is transmitted to a plasma processing chamber in a plasma processing apparatus. A first RF signal is generated at a carrier frequency. The first RF signal is modulated by a second RF signal at a modulation frequency. The resulting modulated signal may be an amplitude modulated signal, a frequency modulated signal, or a signal which is both amplitude and frequency modulated. The first RF signal and the second RF signal may also be tuned in frequency.
In the amplitude modulated signal embodiments, at least some of the peaks of the amplitude modulated signals have amplitudes greater or less than the amplitudes of the peaks of the first RF signal. The peak amplitudes of the modulated power signal are different than the peak amplitudes of the carrier signal. A power signal with a unique waveform can be created and used to create a unique plasma tailored for a given process. As explained in further detail below, by modulating the amplitude of a carrier signal, process variables such as ion energy can be controlled. In comparison, in a duty cycle modulated power signal, all signal peaks are at the same amplitude as the carrier signal. In a duty cycle modulated power signal, a carrier signal is only turned “on” and “off” without modifying the frequency or peak amplitudes of the carrier signal. When the carrier signal is “off”, peaks are not present.
Embodiments of the invention provide a number of controllable process parameters for process engineers to change the characteristics of the power signal applied to the reactant gas. In embodiments of the invention, the waveform for the power signal can be changed by adjusting parameters such as the modulation frequency, the carrier signal power, and the modulation index (the modulation index is the relative strength of the modulating signal to the carrier signal). By changing the waveform of the power signal, the characteristics of the power signal and the formed plasma can also be changed. The plasma can be changed so that it is optimized for a given process. The waveform can be advantageously changed without making significant hardware changes to the plasma processing apparatus and without increasing the complexity of the apparatus.
In comparison, in many conventional apparatuses, it is difficult to produce complex waveforms without making significant hardware changes. For example, it is difficult for one to change the frequency of power in a conventional plasma processing apparatus such as the one shown in FIG. 1 without making significant hardware changes. Each matching network 23, 26 in the apparatus shown in FIG. 1 is specifically adapted for the frequency of power generated by its corresponding power source 21, 24. In order to change the frequency of the power delivered to the chamber 10, both the power source 21, 24 and its matching network 23, 26 would be changed in some way. Matching networks minimize power reflections from variable, fixed frequency power sources. They typically include variable capacitors and inductors, or banks of fixed value components that are switched in and out. Changing a power source and its matching network to modify the frequency of a power signal delivered to a chamber is undesirable since doing so requires substantial hardware modifications.
In a plasma process, the nature of the RF power applied to a reactant gas can determine the characteristics of the resulting plasma. For example, higher frequency power is generally more effective than lower frequency power to generate ions from a reactant gas. High frequency power is generally characterized as power which is at a frequency of about 10 MHz or higher. Increasing the amount of generated ions generally increases the ion density of a plasma. The ion density of a plasma can affect processing variables in a deposition or an etching process. For example, a plasma with a high ion density generally etches a material faster than a plasma with a low ion density.
Lower frequency power, on the other hand, generally contributes more to ion energy than higher frequency power. Low frequency power is generally characterized as power having a frequency of less than 1 MHz. By controlling the energy of the ions formed in the plasma, the plasma can be optimized for a deposition or an etching process. For example, in a plasma-enhanced chemical vapor deposition (PECVD) process, low frequency power can be used to control the energy of the ions in the plasma to bombard a substrate to deposit a film. The increased ion bombardment control can be used to improve the density, stress, and integrity of the formed film. In another example, low frequency power can produce high energy ions that bombard a film to etch very deep profiles in the film in a plasma etch process. Accordingly, the use of low frequency power to generate a plasma is desirable in an anisotropic etch process.
The amplitude of the RF power signal may also influence the characteristics of the generated plasma. Amplitude modulated RF power signals are believed to behave like low frequency power signals in that they can be used to control the energy of the ions in the plasma. For example, an amplitude modulated RF signal having a waveform with high peaks can direct ions along longer travel paths than an RF signal having a waveform with small peaks. The ions can accelerate as they travel along the longer paths provided by the amplitude modulated RF signal, thus producing high energy ions.
In some embodiments of the invention, the frequency of a carrier signal can be modulated to form a frequency modulated power signal. The frequency modulated signal may have components with lower and higher frequencies than the carrier signal. In the plasma, the high frequency components can concentrate on the center part of a plasma body and can contribute more to ion density. Lower frequency components can concentrate on the sheath region of the plasma and can contribute more to ion energy. The peaks of the frequency modulated signal may have the same or different amplitudes as the peaks of the carrier signal. The frequency modulated power signal can be adjusted to modify process variables such as the ion density of the plasma or the ion energy.
In other embodiments of the invention, the amplitude of a carrier signal can be modulated to form an amplitude modulated power signal with peaks having higher or lower amplitudes than the peaks of the carrier signal. The frequency of the amplitude modulated power signal may be the same or different than the frequency of the carrier signal. By modulating the amplitudes of the carrier signal, the modulated power signal may have a unique waveform. Process variables such as the ion energy may be controlled by an amplitude modulated carrier signal.
In yet other embodiments of the invention, a carrier RF signal may be both amplitude and frequency modulated. In these embodiments, a carrier signal may be modulated with an amplitude modulating signal and a frequency modulating signal from a modulation source. By modulating both the frequency and the amplitude of a carrier power signal, the modulated power signal can have a unique waveform. For example, the modulated signal may have peaks of higher and lower amplitudes than the carrier signal peaks, and may have components with higher and lower frequency than the carrier signal frequency. The modulated power signal can produce a unique plasma that can be optimized for a given process. For example, a carrier signal can be modulated to have many high frequency components and high peak amplitudes to form a high density plasma with high energy ions.
FIG. 3 illustrates an apparatus according to an embodiment of the invention. Referring to FIG. 3, an inductively coupled RF plasma processing apparatus 110 includes a sealed plasma processing chamber 112 bounded by a generally cylindrical conductive (metal) side wall 114 and a dielectric (e.g., quartz) dome-shaped ceiling 116. An RF shield 148 covers the ceiling 116 and is grounded. A gas inlet 117 coupled to a gas manifold (not shown) provides an ionizable reactant gas to the interior of the chamber 112. Ionizable reactant gases supplied through the gas inlet 117 may include gases suitable for an etch process (e.g., CF4) or gases suitable for a deposition process (e.g., silane). A wafer pedestal 118 in the middle of the chamber 112 supports a semiconductor wafer 120 on an isolated conductive top 122. The wafer pedestal 118 may be a ceramic electrostatic chuck. A vacuum pump (not shown) maintains the interior of the chamber 112 at a desired pressure (e.g., between 0 and 100 milliTorr). Used process gas passes out of a gas outlet (not shown) in communication with the chamber 112.
RF power is coupled to the plasma (not shown) in the chamber 112 by a coiled antenna 124 wound around the exterior of the dome-shaped ceiling 116. The coil 124 is coupled to a power system 350 that supplies a modulated RF power signal to the chamber 112. Although the power system 350 is shown as being coupled to the coiled antenna 124 in FIG. 3, it may be coupled to any suitable part of the substrate processing apparatus. For example, in a parallel plate capacitively-coupled plasma processing chamber, the power system 350 may be coupled to either the lower electrode within the substrate support pedestal or to the gas manifold (upper electrode) of the apparatus. The power system 350 includes a carrier source 302, a modulation source 304, a modulator 306, an amplifier 308, a transmission line 309, and a matching network 310. Each of these components is described in more detail below.
With reference to both FIGS. 3 and 4, the carrier source 302 generates a first signal including a radio frequency (RF) carrier signal (step 402). The carrier signal may have any suitable waveform, frequency or amplitude. For instance, the frequency of the carrier signal may be from about 1 MHz to about 200 MHz. In a typical example, the first signal may be a sinusoidal signal at a frequency of about 13.56 MHz, the frequency allocated by the Federal Communications Commission of the United States Government. While the carrier signal may have any suitable waveform, in some embodiments, the carrier signal is a sinusoidal waveform.
The modulation source 304 generates one or more modulating signals (step 404) to modulate the carrier signal. The one or more modulating signals may have any suitable waveform, frequency or amplitude. For example, suitable waveforms include triangular, saw-tooth, or sinusoidal waveforms. In some embodiments, the one or more modulating signals have a sinusoidal waveform. The modulating signals may be used to modulate the amplitude or frequency of the carrier signal.
For the frequency modulated embodiments, the modulating signal may be at a lower frequency than the carrier signal. For example, in preferred embodiments, the modulation frequency, ωm, may be about one or two orders of magnitude lower than the carrier frequency, ωc. For example, the modulation frequency may be about 0.1 times or less, or about 0.1 to about 0.01 times the carrier frequency when the carrier signal is frequency modulated.
When the modulation frequency is small compared to the carrier frequency, substantially all of the modulated carrier signal can still pass through the matching network adapted for the carrier frequency. This is true even if the modulated carrier signal includes frequency components which are higher and lower than the carrier frequency. For example, a typical matching network adapted to permit power at 100 MHz to pass to the chamber can also permit a substantial amount of power at frequencies between 98 MHz to 102 MHz to pass to the chamber without being reflected back to the power source. When a modulating signal less than about 1 MHz modulates a carrier frequency of 100 MHz, the frequency of the modulated carrier signal fluctuates within the range of 98 MHz to 102 MHz.
The modulator 306 receives the carrier signal from the carrier source 302 and the modulating signal from the modulation source 304 and modulates the carrier signal to generate a modulated signal (step 406). The carrier signal is modulated to produce a modulated signal with any suitable waveform. As noted, the modulated carrier signal may be amplitude modulated, frequency modulated, or may be both amplitude and frequency modulated. The modulated carrier signal may be complex or simple. When the carrier signal is both frequency and amplitude modulated, the carrier signal may be modulated with an amplitude modulating signal and a frequency modulating signal. Many of the modulation techniques used in embodiments of the invention are well known in the TV and radio broadcast industries.
The waveforms of both the modulating signal and the carrier signal are sinusoidal in some amplitude modulated embodiments. For example, FIG. 5(B) shows an example of a waveform of a sinusoidal modulating signal that modulates the carrier signal shown in FIG. 5(A). As shown, the modulating signal has a lower frequency than the carrier signal. The resulting modulated signal is amplitude modulated and is shown in FIG. 5(C). The graph in FIG. 5(C) shows an amplitude modulated waveform and an envelope corresponding to the modulating signal is shown in FIG. 5(B). The amplitude modulated waveform has peaks with amplitudes greater than and less than the carrier signal peaks.
For an amplitude modulated signal embodiments, the carrier signal can be of the form Eosin(ωct) and the modulating signal may be of the form sin(ωmt). ωc and ωm represent the carrier and modulating frequencies, respectively. Eo represents a value for the initial E-field and t is the time. After the modulating signal modulates the carrier signal, the corresponding amplitude modulated signal may then be of the form
Ec ,t)=E o[1+βsin(ωm t)]sin(ωc t)   (1)
In the above equation, β is a modulation index and indicates the relative strengths of the carrier and modulating signals. Generally, β is less than or equal to one. The modulation index can be varied to adjust the amplitude of the carrier signal and consequently, the power delivered to the chamber.
In the amplitude modulated embodiments, the amplitude modulated signal contains peaks with amplitudes greater than or less than amplitudes of peaks of the first RF signal. The amplitudes of the peaks of the amplitude modulated carrier signal can be increased or decreased by modifying one or more of the carrier signal power, the degree of amplification of the modulated signal, or the modulation index. Increasing or decreasing the peak amplitudes of the modulated signal can increase or decrease the total RF power delivered to the plasma and/or can change the waveform for the modulated RF signal. The amplitudes of the peaks of the carrier signal can be changed without making significant hardware changes.
The waveforms for both the carrier signal and the modulating signal may be sinusoidal in the frequency modulated embodiments of the invention. FIG. 6(A) shows an example of a waveform of a sinusoidal modulating signal that modulates the frequency of a carrier signal (not shown). The resulting frequency modulated carrier signal is shown in FIG. 6(B). As shown in FIG. 6(B), the amplitudes of the peaks of the frequency modulated waveform remain constant in this embodiment. Also, the frequency modulated signal may have components with higher and lower frequencies than the carrier signal frequency.
For the frequency modulated signal embodiments, the frequency modulated signal may be of the form:
Ec ,t)=E o[exp( c t)]exp[sin(ωm t)]  (2)
β is again a modulation index and indicates the relative strengths of the carrier and modulating signals. ωc and ωm again represent the carrier and modulating frequencies, respectively. The modulation component exp[iβsin(ωmt)] may be expanded in terms of the Bessel function Jn(β) as:
exp[(iβsin(ωm t)]=ΣJ n(β)exp(inω m t)n=. . . , −2, −1, 0, 1, 2, . . .
Substituting this expression into equation (2) gives:
Ec ,t)=E o Σ{J n(β)exp[ic+nωm)t]}n=. . . , −2, −1, 0, 1, 2, . . .
In preferred embodiments, the amplifier 308 receives a low power modulated signal and then amplifies it before delivering the modulated signal to the chamber (step 408). Prior to being amplified, a lower power carrier source 302 and a low power modulation source 304 can be used to produce the modulated signal. Low power is generally power at about 100 Watts or less. After receiving the low power modulated signal, the amplifier 308 amplifies its power to generate a high power modulated power signal.
The magnitude of the average power applied to the chamber may vary according to the particular process run on the plasma processing apparatus. The amplified high power modulated power signal may, for example, provide power in excess of 100 Watts to the chamber. For instance, in a typical CVD process, the power may be greater than about 1200 Watts. In a typical etch process, the power maybe greater than about 2000 Watts.
The modulated power signal is output by the amplifier 308 via a transmission line 309 and is received by a matching network 310. The matching network 310 receives the modulated power signal and provides impedance matching from the transmission line 309 to the plasma processing chamber 112 to ensure that substantially all of the power is delivered to the chamber. Any suitable matching network 310 may be used in embodiments of the invention as long as the matching network matches the frequency of the signal from the carrier source 302. For example, if the carrier source 302 supplies power at 13.56 MHz, the matching network 310 can be any suitable commercially available matching network designed for this frequency of power.
The modulated power signal may be applied to any suitable part of the apparatus 110 (step 410). For example, as shown in FIG. 3, the modulated power signal may pass through the matching network 310 and may be applied to the antennae coil 124. The antennae coil 124 applies the modulated power signal to reactant gases in the chamber 112 to produce a plasma. Alternatively, in some embodiments (e.g., in a capacitively-coupled plasma processing chamber) the modulated power signal may be provided to the pedestal, the gas manifold (not shown) or any other suitable portion of the apparatus.
Embodiments of the invention are not limited to the specific embodiments shown and described with respect to the Figures. For example, although the modulator 306 and the amplifier 308 are shown as separate devices, they may be combined in a single device. In another alternative embodiment, an amplifier is not needed. For example, the carrier source 302 may be a high power carrier source which generates a high power RF signal. The modulation source 304 can supply a signal which modulates the high power RF signal before it is applied to the reactant gas in the chamber 312.
Embodiments of the invention provide a number of advantages. For example, although the inventive apparatus embodiments can use less hardware than many conventional apparatuses, the apparatus embodiments can have more controllable processing parameters than the conventional apparatuses. For instance, fewer power sources, matching networks, modulators, etc. are used in the inventive apparatus embodiment shown in FIG. 3 than the conventional apparatus shown in FIG. 1. Moreover, in embodiments of the invention, by adjusting processing parameters such as the modulation index, the carrier signal power, and the modulation frequency, power signals with simple or complex waveforms can be produced. Consequently, the plasma can be tailored to the particular processing being run in the plasma processing chamber. In comparison, in the conventional apparatus shown in FIG. 1, two power signals at two frequencies and amplitudes are delivered to a reactant gas.
In preferred embodiments, the apparatus includes a single matching network and a single high power source. Using a single matching network and a single high power source provides a number of advantages.
By using only one matching network and one high power source, the resulting apparatus is less complex than a plasma processing apparatus using two matching networks and two high power sources. Eliminating a matching network and a power source also reduces the cost of the manufacturing the apparatus, since less components are needed to make the apparatus. Furthermore, because fewer components are present in the apparatus, the likelihood that the apparatus will become inoperative because of component failure is reduced. Lastly, when using one high power source instead of two power sources, less energy is consumed during operation resulting in lower operating costs. Advantageously, in embodiments of the invention, the complexity of an apparatus can be reduced (e.g., as compared to conventional dual frequency apparatuses) while still providing a number of controllable parameters for a process engineer to adjust.
Furthermore, when using a single matching network and a single power source, the problems associated with interfering signals can be reduced. As noted above, two power signals can interfere with each other and cause arcing. Because different waveforms are not being applied to the chamber at the same time when a single power source and a single matching network are used, the likelihood of arcing is reduced. Process parameters such as the RF power and the gas pressure need not be limited to reduce the likelihood of potential arcing. Consequently, in embodiments of the invention, processes with even wider gas pressure ranges and power variability can be practiced.
Also, by using a single matching network and a single power source, additional matching networks and power sources are not present and will not divert power away from the reactant gas. Consequently, substantially all of the power from the power source can be delivered to the reactant gas in the chamber. Power is thus delivered efficiently to the chamber in embodiments of the invention. Moreover, since an additional matching network and power source are not present, decoupling electronics are not needed to decouple the different power sources and matching networks. As noted above, the presence of decoupling electronics in a plasma processing apparatus further increases its cost and complexity.
In embodiments of the invention, high and low frequency signals are combined outside of the processing chamber under controlled conditions. Unlike conventional apparatuses, the interference between the carrier and modulating signals can be controlled by a process engineer before delivering the power signal to the chamber. The unintended interference of power signals within the plasma processing chamber can be avoided. Consequently, any unintended problems associated with the unintended interference of power signals are also avoided.
Although an inductively coupled chamber has been shown and described, embodiments of the invention are not limited thereto. Embodiments of the invention may be used with any suitable plasma process and any suitable plasma processing apparatus. Suitable processes include etching processes such as reactive ion etching, and deposition processes such as plasma-assisted chemical vapor deposition (PECVD) and reactive sputtering. The plasmas produced according to embodiments of the invention may be of the inductively- or capacitively-coupled type. Embodiments of the invention can be used to deposit or etch any suitable material including silicon containing materials such as silicon nitride, silicon oxide, and amorphous silicon.
While the foregoing is directed to certain preferred embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope of the invention. Such alternative embodiments are intended to be included within the scope of the present invention. Moreover, the features of one or more embodiments of the invention may be combined with one or more features of other embodiments of the invention without departing from the scope of the invention

Claims (7)

What is claimed is:
1. A plasma processing apparatus comprising:
a carrier source adapted to generate a first RF signal at a carrier frequency;
a modulation source adapted to generate a second RF signal at a modulation frequency;
a modulator adapted to modulate the first RF signal with the second RF signal to form a frequency modulated signal;
a plasma processing chamber coupled to the modulator;
a transmission line for transmitting the frequency modulated signal; and
a single matching network adapted to receive the frequency modulated signal to provide impedance matching from the transmission line to a plasma, and
wherein the modulation frequency is less than about 0.1 times the carrier frequency.
2. The apparatus of claim 1 further comprising:
an amplifier adapted to amplify the frequency modulated signal to generate a high power frequency modulated signal.
3. The apparatus of claim 1 wherein the modulation source is further adapted to generate a third RF signal at an amplitude modulation frequency, and wherein the modulator is further adapted to modulate the first RF signal with the second RF signal and the third RF signal to form an frequency and amplitude modulated signal.
4. The apparatus of claim 1 wherein the second RF signal is in the form of a sine wave.
5. The apparatus of claim 1 wherein the apparatus is an etching apparatus.
6. The apparatus of claim 1 wherein the modulation frequency is from about 0.1 to about 0.01 times the carrier frequency.
7. The apparatus of claim 1 wherein the carrier source is at a frequency of about 13.56 MHz and wherein the single matching network is adapted to transmit power at a frequency of about 13.56 MHz to the plasma processing chamber.
US09/767,282 2001-01-22 2001-01-22 RF power delivery for plasma processing using modulated power signal Expired - Fee Related US6726804B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US09/767,282 US6726804B2 (en) 2001-01-22 2001-01-22 RF power delivery for plasma processing using modulated power signal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/767,282 US6726804B2 (en) 2001-01-22 2001-01-22 RF power delivery for plasma processing using modulated power signal

Publications (2)

Publication Number Publication Date
US20020096257A1 US20020096257A1 (en) 2002-07-25
US6726804B2 true US6726804B2 (en) 2004-04-27

Family

ID=25079019

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/767,282 Expired - Fee Related US6726804B2 (en) 2001-01-22 2001-01-22 RF power delivery for plasma processing using modulated power signal

Country Status (1)

Country Link
US (1) US6726804B2 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050082007A1 (en) * 2003-10-21 2005-04-21 Applied Materials, Inc. Mask etch processing apparatus
US20050133166A1 (en) * 2003-12-19 2005-06-23 Applied Materials, Inc. Tuned potential pedestal for mask etch processing apparatus
US20060278521A1 (en) * 2005-06-14 2006-12-14 Stowell Michael W System and method for controlling ion density and energy using modulated power signals
US20070264791A1 (en) * 2006-05-10 2007-11-15 Jusung Engineering Co., Ltd. Method of gap-filling using amplitude modulation radiofrequency power and apparatus for the same
US20090255800A1 (en) * 2008-03-31 2009-10-15 Tokyo Electron Limited Plasma processing apparatus, plasma processing method, and computer readable storage medium
US20100259107A1 (en) * 2007-11-14 2010-10-14 Peter Kinget Systems and Methods for Providing Power to a Device Under Test
US20110000783A1 (en) * 2008-03-04 2011-01-06 National University Corporation Tohoku University Rotary magnet sputtering apparatus
US20120238073A1 (en) * 2011-03-14 2012-09-20 Chris Johnson Method and Apparatus for Plasma Dicing a Semi-conductor Wafer
US20180185964A1 (en) * 2015-11-09 2018-07-05 Furukawa Electric Co., Ltd. Method of producing semiconductor chip, and mask-integrated surface protective tape used therein
US10763814B2 (en) 2016-08-09 2020-09-01 John Bean Technologies Corporation Radio frequency processing apparatus and method

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7976673B2 (en) 2003-05-06 2011-07-12 Lam Research Corporation RF pulsing of a narrow gap capacitively coupled reactor
US9123508B2 (en) 2004-02-22 2015-09-01 Zond, Llc Apparatus and method for sputtering hard coatings
US20060066248A1 (en) * 2004-09-24 2006-03-30 Zond, Inc. Apparatus for generating high current electrical discharges
US7842355B2 (en) * 2005-11-01 2010-11-30 Applied Materials, Inc. System and method for modulation of power and power related functions of PECVD discharge sources to achieve new film properties
US20070095281A1 (en) * 2005-11-01 2007-05-03 Stowell Michael W System and method for power function ramping of microwave liner discharge sources
US9011633B2 (en) * 2005-11-17 2015-04-21 Mks Instruments, Inc. Broadband techniques to reduce the effects of impedance mismatch in plasma chambers
DE102009016701A1 (en) * 2009-04-06 2010-10-14 Forschungsverbund Berlin E.V. Process chamber with modulated plasma supply
US8501631B2 (en) * 2009-11-19 2013-08-06 Lam Research Corporation Plasma processing system control based on RF voltage
US10128090B2 (en) 2012-02-22 2018-11-13 Lam Research Corporation RF impedance model based fault detection
US10157729B2 (en) 2012-02-22 2018-12-18 Lam Research Corporation Soft pulsing
US9114666B2 (en) 2012-02-22 2015-08-25 Lam Research Corporation Methods and apparatus for controlling plasma in a plasma processing system
US9462672B2 (en) 2012-02-22 2016-10-04 Lam Research Corporation Adjustment of power and frequency based on three or more states
US9320126B2 (en) 2012-12-17 2016-04-19 Lam Research Corporation Determining a value of a variable on an RF transmission model
US9842725B2 (en) 2013-01-31 2017-12-12 Lam Research Corporation Using modeling to determine ion energy associated with a plasma system
US9197196B2 (en) 2012-02-22 2015-11-24 Lam Research Corporation State-based adjustment of power and frequency
US9145607B2 (en) * 2013-10-22 2015-09-29 Lam Research Corporation Tandem source activation for cyclical deposition of films
US9594105B2 (en) 2014-01-10 2017-03-14 Lam Research Corporation Cable power loss determination for virtual metrology
US10950421B2 (en) 2014-04-21 2021-03-16 Lam Research Corporation Using modeling for identifying a location of a fault in an RF transmission system for a plasma system
TWI690972B (en) * 2015-05-12 2020-04-11 日商東京威力科創股份有限公司 Plasma processing device and plasma processing method
US20180308667A1 (en) * 2017-04-24 2018-10-25 Kenneth S. Collins Plasma reactor with groups of electrodes
WO2022163535A1 (en) * 2021-01-29 2022-08-04 東京エレクトロン株式会社 Plasma processing device, and method for controlling source frequency of source high-frequency electric power

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585516A (en) 1985-03-04 1986-04-29 Tegal Corporation Variable duty cycle, multiple frequency, plasma reactor
US4808258A (en) * 1983-10-19 1989-02-28 Hitachi, Ltd. Plasma processing method and apparatus for carrying out the same
US5057185A (en) 1990-09-27 1991-10-15 Consortium For Surface Processing, Inc. Triode plasma reactor with phase modulated plasma control
US5513765A (en) 1993-12-08 1996-05-07 Fujitsu Limited Plasma generating apparatus and method
US5556549A (en) 1994-05-02 1996-09-17 Lsi Logic Corporation Power control and delivery in plasma processing equipment
US5562952A (en) 1993-11-11 1996-10-08 Nissin Electric Co., Ltd. Plasma-CVD method and apparatus
US5643364A (en) 1994-11-30 1997-07-01 Applied Materials, Inc. Plasma chamber with fixed RF matching
US5688357A (en) 1995-02-15 1997-11-18 Applied Materials, Inc. Automatic frequency tuning of an RF power source of an inductively coupled plasma reactor
JPH10150025A (en) * 1996-11-20 1998-06-02 Mitsubishi Electric Corp Plasma reactor
US5824606A (en) 1996-03-29 1998-10-20 Lam Research Corporation Methods and apparatuses for controlling phase difference in plasma processing systems
US5866985A (en) 1996-12-03 1999-02-02 International Business Machines Corporation Stable matching networks for plasma tools
US5981899A (en) 1997-01-17 1999-11-09 Balzers Aktiengesellschaft Capacitively coupled RF-plasma reactor
US6106737A (en) 1994-04-20 2000-08-22 Tokyo Electron Limited Plasma treatment method utilizing an amplitude-modulated high frequency power

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808258A (en) * 1983-10-19 1989-02-28 Hitachi, Ltd. Plasma processing method and apparatus for carrying out the same
US4585516A (en) 1985-03-04 1986-04-29 Tegal Corporation Variable duty cycle, multiple frequency, plasma reactor
US5057185A (en) 1990-09-27 1991-10-15 Consortium For Surface Processing, Inc. Triode plasma reactor with phase modulated plasma control
US5562952A (en) 1993-11-11 1996-10-08 Nissin Electric Co., Ltd. Plasma-CVD method and apparatus
US5513765A (en) 1993-12-08 1996-05-07 Fujitsu Limited Plasma generating apparatus and method
US6106737A (en) 1994-04-20 2000-08-22 Tokyo Electron Limited Plasma treatment method utilizing an amplitude-modulated high frequency power
US5556549A (en) 1994-05-02 1996-09-17 Lsi Logic Corporation Power control and delivery in plasma processing equipment
US5643364A (en) 1994-11-30 1997-07-01 Applied Materials, Inc. Plasma chamber with fixed RF matching
US5688357A (en) 1995-02-15 1997-11-18 Applied Materials, Inc. Automatic frequency tuning of an RF power source of an inductively coupled plasma reactor
US5824606A (en) 1996-03-29 1998-10-20 Lam Research Corporation Methods and apparatuses for controlling phase difference in plasma processing systems
JPH10150025A (en) * 1996-11-20 1998-06-02 Mitsubishi Electric Corp Plasma reactor
US20020066537A1 (en) * 1996-11-20 2002-06-06 Satoshi Ogino Plasma reactor
US6471821B2 (en) * 1996-11-20 2002-10-29 Mitsubishi Denki Kabushiki Kaisha Plasma reactor and method
US20030000646A1 (en) * 1996-11-20 2003-01-02 Mitsubishi Denki Kabushiki Kaisha Plasma reactor
US5866985A (en) 1996-12-03 1999-02-02 International Business Machines Corporation Stable matching networks for plasma tools
US5981899A (en) 1997-01-17 1999-11-09 Balzers Aktiengesellschaft Capacitively coupled RF-plasma reactor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Rex Miller and Mark R. Miller "Modulation and Demodulation"; Electronics The Easy Way, (1995) pp. 207-226.

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7879151B2 (en) 2003-10-21 2011-02-01 Applied Materials, Inc. Mask etch processing apparatus
US7128806B2 (en) 2003-10-21 2006-10-31 Applied Materials, Inc. Mask etch processing apparatus
US20050082007A1 (en) * 2003-10-21 2005-04-21 Applied Materials, Inc. Mask etch processing apparatus
US20050133166A1 (en) * 2003-12-19 2005-06-23 Applied Materials, Inc. Tuned potential pedestal for mask etch processing apparatus
US20060278521A1 (en) * 2005-06-14 2006-12-14 Stowell Michael W System and method for controlling ion density and energy using modulated power signals
TWI415175B (en) * 2006-05-10 2013-11-11 Jusung Eng Co Ltd Method of gap-filling using amplitude modulation radiofrequency power and apparatus for the same
US20100031886A1 (en) * 2006-05-10 2010-02-11 Jusung Engineering Co., Ltd. Method of gap-filling using amplitude modulation radiofrequency power and apparatus for the same
US7605084B2 (en) * 2006-05-10 2009-10-20 Jusung Engineering Co., Ltd. Method of gap-filling using amplitude modulation radio frequency power
US8039406B2 (en) 2006-05-10 2011-10-18 Jusung Engineering Co., Ltd. Method of gap-filling using amplitude modulation radiofrequency power and apparatus for the same
KR101170597B1 (en) 2006-05-10 2012-08-02 주성엔지니어링(주) Gap-fill method using amplitude modulated RF power and gap-fill apparatus for the same
US20070264791A1 (en) * 2006-05-10 2007-11-15 Jusung Engineering Co., Ltd. Method of gap-filling using amplitude modulation radiofrequency power and apparatus for the same
US20100259107A1 (en) * 2007-11-14 2010-10-14 Peter Kinget Systems and Methods for Providing Power to a Device Under Test
US8535494B2 (en) * 2008-03-04 2013-09-17 National University Corporation Tohoku University Rotary magnet sputtering apparatus
US20110000783A1 (en) * 2008-03-04 2011-01-06 National University Corporation Tohoku University Rotary magnet sputtering apparatus
US20090255800A1 (en) * 2008-03-31 2009-10-15 Tokyo Electron Limited Plasma processing apparatus, plasma processing method, and computer readable storage medium
US8741095B2 (en) * 2008-03-31 2014-06-03 Tokyo Electron Limited Plasma processing apparatus, plasma processing method, and computer readable storage medium
US20120238073A1 (en) * 2011-03-14 2012-09-20 Chris Johnson Method and Apparatus for Plasma Dicing a Semi-conductor Wafer
US8778806B2 (en) * 2011-03-14 2014-07-15 Plasma-Therm Llc Method and apparatus for plasma dicing a semi-conductor wafer
US20180185964A1 (en) * 2015-11-09 2018-07-05 Furukawa Electric Co., Ltd. Method of producing semiconductor chip, and mask-integrated surface protective tape used therein
US10307866B2 (en) * 2015-11-09 2019-06-04 Furukawa Electric Co., Ltd. Method of producing semiconductor chip, and mask-integrated surface protective tape used therein
US10763814B2 (en) 2016-08-09 2020-09-01 John Bean Technologies Corporation Radio frequency processing apparatus and method
US11489507B2 (en) 2016-08-09 2022-11-01 John Bean Technologies Corporation Radio frequency processing apparatus and method

Also Published As

Publication number Publication date
US20020096257A1 (en) 2002-07-25

Similar Documents

Publication Publication Date Title
US6726804B2 (en) RF power delivery for plasma processing using modulated power signal
US7431857B2 (en) Plasma generation and control using a dual frequency RF source
TWI689986B (en) Plasma processing method and plasma processing device
US10340123B2 (en) Multi-frequency power modulation for etching high aspect ratio features
US7510665B2 (en) Plasma generation and control using dual frequency RF signals
US6288493B1 (en) Antenna device for generating inductively coupled plasma
EP1323180B1 (en) System, apparatus, and method for processing wafer using single frequency rf power in plasma processing chamber
JP3776856B2 (en) Plasma processing apparatus and plasma processing method
US20100252199A1 (en) Multifrequency capacitively coupled plasma etch chamber
US20040194890A1 (en) Hybrid plasma processing apparatus
JPH03171623A (en) Plasma treatment for semiconductor wafer manufacture and device therefor
EP1119033A1 (en) Plasma processing method
CN107452589B (en) Plasma processing apparatus and plasma processing method
US11031213B2 (en) Microwave output device and plasma processing device
US10381238B2 (en) Process for performing self-limited etching of organic materials
JPH07288196A (en) Plasma generating apparatus
WO2023199766A1 (en) Plasma processing device
US20240038498A1 (en) Film deposition apparatus
US20220115208A1 (en) Plasma processing apparatus and plasma processing method
KR20050019628A (en) Radio frequency power supplier for generating large-size plasma and method of power supply thereof
JPH11241189A (en) Inductive coupling discharge etching device

Legal Events

Date Code Title Description
AS Assignment

Owner name: APPLIED MATERIALS, INC., CALIFORNIA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WANG, LIANG-GUO;WONG, KWOK M.;SHAMOUILIAN, SHAMOUIL;AND OTHERS;REEL/FRAME:011498/0218;SIGNING DATES FROM 20010112 TO 20010120

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20160427