US5580428A - PVD sputter system having nonplanar target configuration and methods for constructing same - Google Patents

PVD sputter system having nonplanar target configuration and methods for constructing same Download PDF

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US5580428A
US5580428A US08/457,856 US45785695A US5580428A US 5580428 A US5580428 A US 5580428A US 45785695 A US45785695 A US 45785695A US 5580428 A US5580428 A US 5580428A
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target
deposition
nonplanar
substrate
configuration
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US08/457,856
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Zoran Krivokapic
David S. Bang
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Advanced Micro Devices Inc
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Advanced Micro Devices Inc
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target

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  • the invention is generally directed to physical vapor deposition (PVD) sputter systems.
  • the invention is more specifically related to an apparatus and method for PVD sputtering during the fabrication of semiconductor devices wherein it is desirable to obtain a combination of uniform deposition thickness, high deposition rate, and good step coverage.
  • PVD sputtering is used within semiconductor processing and other arts for depositing metal films and the like onto substrate surfaces.
  • the substrate e.g., semiconductor wafer
  • the substrate is typically a planar disk that is positioned, face-down at the top of a vacuum plasma chamber.
  • a planar target is further typically positioned face-up within the chamber, in spaced apart and symmetrical counterfacing relation with the substrate.
  • the target was on top and the substrate on the bottom.
  • the substrate-on-top versus on-bottom orientation has to do with keeping the substrate surface clean and is not directly related to the present invention.
  • the older configuration with the substrate on the bottom will be shown, but it is to be understood that other orientations are fully within the contemplation of this disclosure.
  • the target is made of the material that is to be sputter deposited onto the substrate surface.
  • Examples include, but are not limited to, metals such as aluminum (Al), titanium (Ti), copper (Cu), and alloys or compounds of these materials.
  • Emission-inducing energy is applied to the active face of the target in the form, for example, of a plasma containing accelerated argon ions.
  • the active face of the target emits small particles composed of the target material (e.g. aluminum).
  • the emitted particles follow a generally linear trajectory from their point of emission on the target surface to a collision point on the counterfacing surface of the substrate. Physical adhesion mechanisms cause the target particles to bond to the surface of the substrate.
  • the physical dimensions and positionings of the substrate and target play important roles in determining rate of deposition and the uniformity of the deposited film.
  • the distribution of emission-inducing energy across the target also plays a role.
  • the target should be very wide relative to the substrate so that the target represents an infinite source plane to the particle-receiving face of the substrate.
  • the particle receiving face of the substrate is perfectly planar and parallel to the target, every point on the substrate receiving face will receive the same contribution of deposition particles and film thickness will be uniform across the entire substrate.
  • the target has a finite size that is usually the same order of magnitude as that of the substrate. Non-uniformities develop across the substrate for characteristics such as deposition film thickness and deposition rate due to boundary conditions.
  • the substrate surface is often not perfectly planar.
  • Nonlinear features such as channels and mesas are typically found on the semiconductor substrate. It is often desirable to coat the sidewalls and/or bottoms of each channel or mesa with a layer of deposition material having a prescribed thickness.
  • the linear nature of the trajectories followed by the emitted target particles in PVD systems create shadow effects. Not every portion of the substrate surface receives the same amount of target material at the same rate in the case where the substrate surface includes nonlinearities such as channels or mesas.
  • channel is used herein in a broad sense to include features in semiconductor devices and the like such as contact vias, trenches, and other depressions which are to be fully or partially filled with deposition material.
  • mesa is similarly used herein in a broad sense to include any device feature rising above a surrounding plane where the feature and/or its surrounding plane are to be coated with deposition material.
  • step coverage is used herein in a qualitative sense to refer to the ability to coat one or more sidewalls or bottom of a channel or mesa to a desired thickness.
  • step coverage is further used herein in a quantitative sense to refer to the ratio of film thickness at the bottom of a sidewall relative to film thickness at the top of the same sidewall, where the sidewall has a predefined height.
  • step coverage uniformity is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of step coverage across a given substrate.
  • flat coverage uniformity is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate taking into consideration only substantially planar regions (not step regions) of the substrate surface.
  • film thickness uniformity is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate, taking into consideration all regions (flat and step regions) of the substrate surface.
  • bottom coverage uniformity is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate, taking into consideration only regions at the bottom of channels or mesas.
  • PVD sputter chambers typically need to support ion plasmas at very low pressures, on the order of 2 milliTorr or less, and are thus relatively costly to manufacture. It would be desirable to have a PVD sputter system that can accommodate wafers of different sizes while providing relatively similar uniformities in step coverage and film thickness.
  • a sputter system in accordance with the invention comprises a nonplanar sputter target positioned relative to a to-be-coated substrate such that the maximum angle of particle emission is below a prespecified maximum.
  • power is independently distributed to different parts of the nonplanar target and adjusted to provide substantially uniform rates of deposition across the substrate surface.
  • the nonplanar target is subdivided into isolated target members placed at different heights relative to the substrate surface and energized by independent sources of emission-inducing energy.
  • the amount of emission-inducing energy applied to each portion of the nonplanar target is set according to the travel distance of the particles that are to flow from that portion to the substrate surface.
  • the nonplanar target is configured such that some portions of the target provide a collimation function for particles emitted from other portions of the same nonplanar target.
  • FIG. 1A is a cross sectional view of a hypothetical point-source sputtering system that is used for explaining the principles of operation of the invention
  • FIG. 1B is a cross sectional magnified view showing a central surface portion of the substrate, including a first to-be-coated channel;
  • FIG. 1C is a cross sectional magnified view of a border portion of the substrate surface, including a second to-be-coated channel;
  • FIG. 2 is a cross sectional view of a conventional sputter system having a planar target
  • FIG. 3 is a cross sectional view of a first embodiment in accordance with the invention having a nonplanar target
  • FIG. 4 is a cross sectional view of a second embodiment in accordance with the invention having isolated target members placed at different heights relative to the substrate surface with each target member receiving power from an independent power source;
  • FIG. 5 is a cross sectional view of a third embodiment wherein the nonplanar target has a generally concave shape relative to the substrate;
  • FIG. 6 is a cross sectional view of a fourth embodiment wherein the nonplanar target is comprised of a staggered configuration of independently powered members and has a self-collimating feature;
  • FIG. 7 is a cross sectional view of a first specific configuration having unique deposition attributes
  • FIG. 8 is a cross sectional view of a second specific configuration having unique deposition attributes
  • FIG. 9 is a cross sectional view of a third specific configuration having unique deposition attributes.
  • FIG. 10 is a cross sectional view of a fourth specific configuration having unique deposition attributes.
  • FIG. 1A is a cross sectional view of a hypothetical point-source sputter system 100 that is used for explaining principles of operation of the present invention.
  • a planar, disk-shaped substrate having a width, W S is shown at 110.
  • a central, top surface portion of the substrate is designated as 112.
  • Respective left and right portions of the substrate top surface are designated as 111 and 113.
  • a hypothetical point-source target 120 having a width W T of approximately zero is positioned symmetrically above and spaced away from the central surface portion 112 of the substrate 110.
  • the distance between the point-source target 120 and the substrate center 112 defines a height, H.
  • a power source 140 is coupled by way of means 141 to the point-source target 120 in order to cause the target 120 to emit deposition particles along linear trajectories directed to the substrate surface.
  • the power source 140 can include a source of accelerated argon ions or the like.
  • the power source 140 can further include confinement magnets for confining accelerated particles near the region of the target 120.
  • Trajectory 121 has a particle travel distance of d p1 and carries particles from target 120 to the left surface region 111 of the substrate 110.
  • Trajectory 122 has a travel distance of d p2 equal to height H and carries target particles from the target 120 to the central surface region 112.
  • Trajectory 123 has a particle travel distance of d p3 and carries target particles from the target 120 to the right surface region 113.
  • Each of trajectories 121 and 123 defines an angle of ⁇ between itself and the normal of the substrate surface (the hypothetical perpendicular drawn from the substrate surface). Note that as height H decreases, the trajectory angle ⁇ (or "angle of attack” ⁇ as it will also be called) increases, and vice versa.
  • film deposition rate (r) in sputtering systems is inversely proportional to the particle travel distance (d p ) raised to a power ( ⁇ ) approximately between one and two.
  • ⁇ r f (d p - ⁇ ); where 1 ⁇ 2. ⁇
  • the deposition rates of the left and right trajectories, 121 and 123 are less than that of the central trajectory 122.
  • FIG. 1B is a magnified view showing a first channel 114 formed at the central surface region 112 of substrate 110.
  • the central trajectory 122 deposits target material 132 vertically into the bottom of the channel.
  • the trajectories (not shown) to the left and right of 122 respectively deposit target material for regions 131 and 133. Since the deposition rates of the side trajectories are less than that of the central trajectory 122, the thickness of material deposited at 131 and 133 slopes down as one moves horizontally away from the central trajectory 122. (The slope is exaggerated in FIG.
  • FIG. 1C shows a magnified cross sectional view of right surface region 113, wherein a second channel 116 has been formed. Trajectory 123 approaches second channel 116 with the attack angle ⁇ . The left sidewall 117 of channel 116 casts a shadow on the right sidewall 118 and bottom of the channel. The shadow height increases up along the right sidewall 118 as the attack angle ⁇ increases. As a result of this shadowing effect, only a top portion of the right sidewall 118 is covered with target material 136 contributed by trajectory 123.
  • the entire left sidewall 117, the lower portion of right sidewall 118 and the bottom 119 of the channel do not receive deposition contribution from trajectory 123. In many cases it is desirable to uniformally coat the entire inner surface of channel 116 with the target material 136. However, the shadowing effect of the trajectory angle ⁇ prevents this from occurring.
  • FIGS. 1A-1C are understood to the hypothetical conditions provided herein for purposes of illustration.
  • the target in an actual sputter system will have some physical width W T greater than zero and hence will act at least as a two-dimensional source rather than a point-source.
  • FIG. 2 shows the cross section of a conventional configuration within a sputter chamber.
  • Like-reference numbers in the "200" number series are used in FIG. 2 to denote elements having like counterparts in FIG. 1A, and as such they will not be again explained in detail.
  • a planar, disk-shaped target 220 having width W T is provided in parallel, spaced apart, and centralized relation to the substrate 210, where the latter has width W S .
  • the target width W T is substantially larger than the substrate width W S .
  • the emission surface of the target 220 generally defines a continuum of point sources distributed across the circular bottom surface area of the target 220. Each target point source contributes partially to the deposition occurring at corresponding receiving points on the top surface of substrate 210.
  • the power output of power source 240 is uniformly distributed to all emission points (target point sources) of the target 220.
  • Deposition at each receiving point on the substrate surface including respective left, center, and right regions, 211, 212, and 213, may be calculated as the summed (or integrated) contribution of particles received from each of the point sources along the emission surface of target 220.
  • the right peripheral region 213 of the substrate receives particles contributed from the left edge of target 220 by way of left trajectory 221.
  • Trajectory 221 has a particle travel distance of d p1 and it forms a first attack angle ⁇ 1 with the substrate surface normal.
  • particles received from the right extreme of target 220 travel along a right-side trajectory 223 for deposition onto substrate region 213.
  • Trajectory 223 has a particle travel distance of d p3 and defines an attack angle of ⁇ 3 relative to the substrate surface normal.
  • film deposition rate (r) at each receiving point on the substrate surface will be inversely proportional to the particle travel distance (d p ) of each target point-source raised to a prespecified power ( ⁇ ).
  • the contribution received at each substrate surface point, from each target point-source has to be summed to determine the accumulated deposition at each receiving point on the substrate surface.
  • ⁇ R i ⁇ f(d p - ⁇ ) ⁇ dx ⁇ dy; for all x and y on the target surface, where R i is the accumulated rate of deposition at a given surface point i on the substrate surface.
  • the specific dimensions of the target width W T , the substrate width W S , and the target-to-substrate separation height H need to be known in order to determine the cumulative deposition rate at each receiving point on the substrate surface.
  • the power source 240 delivers a normalized power of one unit per cm 2 to the emission surface of target 220.
  • the maximum trajectory angle ⁇ 1 of the left-most trajectory path 221 is approximately 59°.
  • the uniformity of step coverage is defined in part by this 59° maximum trajectory angle.
  • the inventors herein recognized that step coverage uniformity could be improved if the maximum trajectory angle ⁇ 1 could be reduced. They also recognized that, if one simply increased the target-to-substrate separation height H uniformly across the target, the deposition rate would then disadvantageously decrease. The solution was to find a compromise between these counterposed attributes.
  • the inventors herein decided to vary target point-to-substrate separation height H at each point of the target as a function of both the allowed maximum trajectory angle ⁇ 1 and desired deposition rate. In other words, they decided to make the target nonplanar relative to the substrate. This produced unexpected advantages.
  • the solution of using a nonplanar target further includes the step of optionally varying the amount of emission-inducing energy applied to each portion of the nonplanar target as a function of that portion's distance from the substrate.
  • FIG. 3 shows a first embodiment 300 in accordance with the invention that is to be compared to scale against the reference system 200 of FIG. 2.
  • Like reference numbers in the "300" numbering system are used in FIG. 3 for elements having corresponding components numbered in the "200" series in FIG. 2.
  • the sputter system 300 of FIG. 3 includes a nonplanar target 320 that is configured to present a generally convex emission surface relative to the deposition surface 311-313 of the substrate 310.
  • the peripheral portions of target 320 are raised to respective left and right heights, H 1 and H 3 , that are each greater than the central height, H 2 .
  • the increase of the peripheral target heights, H 1 on the left and H 3 on the right, works to reduce the trajectory angles of the target particles emitted from those peripheral target sites and thereby improves the uniformity of step coverage across the substrate surface.
  • the top right surface point 313 of substrate 310 receives a first contribution of deposition material from the left edge of the target 320 by way of trajectory 321.
  • the attack angle, ⁇ 31 of trajectory 321 is less than the attack angle ⁇ 1 of previous trajectory 221 in the reference system 200.
  • Surface point 313 further receives a contribution from the right edge of target 320 by way of trajectory 323.
  • the attack angle ⁇ 33 of trajectory 323 is less than the attack angle ⁇ 3 of the previous trajectory 223 in the reference system 200. Since angle ⁇ 31 is less than ⁇ 1 , and angle ⁇ 33 is less than ⁇ 3 , shadowing effects are decreased in magnitude and the uniformity of step coverage is improved across the substrate surface 311-313.
  • the particle travel distances (d p1 and d p3 ) of trajectories 321 and 323 are greater than those of the previous trajectories, 221 and 223 respectively.
  • the overall rate of material deposition suffers as a consequence.
  • a first independent power supply 341 supplies emission-inducing power P 1 to the left periphery of target 320.
  • a second power supply 342 supplies power P 2 to the central portion of target 320.
  • a third independent power supply 343 provides emission-inducing power P 3 to the right peripheral region of target 320.
  • the emission-inducing powers, P 1 and P 3 of the respective first and third power supplies 341 and 343 are preferably set greater than the power P 2 of second power supply 342 so that the peripheral edges of the target 320 have a higher rate of particle emissivity. This compensates for the increased particle travel distance along trajectories 321, 322 and 323 so as to bring the deposition rate at substrate site 313 back to par with that of site 213 in the reference system 200.
  • FIG. 3 shows the nonplanar target 320 as having a unitary construct.
  • a unitary construct does not allow power differentiation to be provided by way of electric voltage difference in cases where the target material 320 is a conductive material such as aluminum, titanium, copper or an alloy of one or more of these metals.
  • One way to provide power differentiation in such a situation is to use independently-driven flux-confining magnets at each of the independently-powered target sites.
  • the magnets may be of the fixed or moving kind.
  • An example of the use of a distributed magnet system for independently powering different parts of a planar target is seen in the Applied Materials Endura 5000TM sputtering chamber which is available from Applied Materials of Santa Clara, Calif.
  • Local magnetic flux strength determines the velocity of emission-inducing particles striking the target surface, and this in turn defines the local surface emissivity. It should be apparent that in the case where the target is symmetrical about its middle axis (H 2 ), the left and right power supplies, 341 and 343, can be merged into a single supply (not shown) whose output may be set differently from that of the central power supply 342.
  • FIG. 4 shows a second embodiment in accordance with the invention wherein the overall target 420 is fragmented into first through third, independent target members 450, 460, and 470 each being adjustable to have a different height relative to the substrate surface 411-413.
  • the multi-member target configuration 400 of FIG. 4 is drawn to the same scale as the reference system 200 of FIG. 2 and to that of the unitary target configuration 300 of FIG. 3 so as to enable simple comparison among these systems (200, 300, 400).
  • Like reference numbers in the "400" numbering system are used in FIG. 4 for elements having corresponding components numbered in the "300" series in FIG. 3.
  • the multi-member target configuration 400 of FIG. 4 includes as its lowest target member 470, a circular disc having an active surface positioned at a height H 3 (equal to reference height H) centrally over substrate 410. Positioned above the lowest target member 470, at a second height H 2 (greater than reference height H) there is the second target member 460 which has an annular shape (ring shape) surrounding the hypothetical upward projection of the lowest target member 470. Positioned above the second target member 460, at a height H 1 (greater than second height H 2 ) there is the first target member 450 which has an annular shape surrounding the hypothetical upward projection of middle ring 460. Target members 450, 460, and 470 are electrically insulated from one another.
  • target members Although a plurality of three target members is shown in FIG. 4, it is to be understood that the number of target members may be reduced to two or increased to any desired number above three.
  • the respective heights of the first through third target members 450, 460, and 470 are arranged in successively decreasing order, H 1 >H 2 >H 3 , it is to be understood that the respective heights of the plural target members can be arranged into any otherwise desired, nonplanar configuration.
  • a first independent power supply 441 supplies a first emission-inducing power P 1 to the first target member 450.
  • a second independent power supply 442 supplies a second emission-inducing power P 2 to the second target member 460.
  • a third power supply 443 similarly applies a third emission-inducing power P 3 to the third target member 470.
  • Power levels P 1 , P 2 , and P 3 may be set independently of one another so as to define different particle emission rates (per cm 2 ) for each of the respective target members, 450, 460, and 470.
  • the combined active width of target members 450, 460, and 470 is substantially equal to the active width W T of the reference target 220 in FIG. 2.
  • the individual active width of each of target members 450, 460, and 470 may be set as desired.
  • the lower target member 470 has an effective width equal to approximately one-fifth of W T while the other two target members 460, 450 each have an effective emissive width equal to two-fifths of W T .
  • the emission inducing power applied to the respective first through third multiple target members 450, 460, and 470 is preferably set such that P 1 >P 2 >P 3 , where the power is measured in terms of Kilowatts per unit area of active target surface or in like terms for determining the per unit area emissivity of each target member, 450, 460, and 470.
  • the top right surface point 413 of substrate 410 receives a first contribution from the left extreme of first target member 450 by way of first trajectory 421.
  • the left side trajectory 221 of the reference system is shown as a dashed double-dot line for purposes of comparison. Note that the angle of attack ⁇ 41 of trajectory 421 is substantially less than the angle of attack, ⁇ 1 of reference trajectory 221.
  • trajectory 421 avoids colliding into the second target member 460 by a small distance. If the height H 1 of the first target member 450 were to be raised by an appropriate distance, and/or the height H 2 of the second target member 460 were to be lowered by an appropriate distance, then trajectory 421 would be blocked by the intervening body of the second target member 460. The maximum angle of attack for particles contributing to substrate surface point 413 would then be decreased to less than ⁇ 41 . In such a case, the nonplanar configuration of the target surface would provide a self-collimating function that limits the maximum angle of attack.
  • trajectory 422 receives a further contribution from the right extreme of the middle target member 460 by way of trajectory 422.
  • the particle travel distance (d p2 ) of trajectory 422 is approximately equal to separation height H 2 .
  • Substrate surface point 413 further receives deposition contribution from the right extreme edge of the highest target member 450 by way of trajectory 423.
  • Reference trajectory 223 is drawn as a dashed double-dot line nearby for purposes of comparison. Note that the angle of attack ⁇ 43 of trajectory 423 is substantially less than that the angle of attack ⁇ 3 of reference trajectory 223.
  • the number of variations possible for the multi-target configuration shown in FIG. 4 is quite large. Rather than building a physical embodiment for each possibility, the inventors herein used a computer simulation that calculates the theoretical deposition patterns on a substrate including a plurality of channels for thousands of different target configurations, each having one or more unique settings for target member placement, target member width, target member power, and so forth.
  • SPEEDIE Sand Platform Emulator for Etching and Deposition in IC Engineering
  • Various versions of this simulation package are available from the Stanford Research Center of Stanford University, Palo Alto, Calif.
  • other similarly-suitable simulators may be used for modeling the performance for various target and substrate configurations.
  • FIGS. 7-10 show specific examples of configurations which provided improved performance in one or more areas of measure (e.g., flat coverage uniformity, step coverage, step coverage uniformity, average deposition rate, average bottom coverage and minimum sidewall coverage).
  • a nonplanar target can take on many configurations including, but not limited to: (a) convex, (b) concave, and (c) staggered.
  • the convex configuration has been covered above by the embodiments shown in FIGS. 3 and 4 (continuous and fragmented).
  • FIGS. 5 and 6 respectively show fragmented embodiments of the concave and staggered configurations in a generic sense.
  • Continuous rather than fragmented embodiments of the concave and staggered configurations can be constructed by linking together the fragmented target members of FIGS. 5 and 6 with vertical connections. In the latter continuous-construct cases, independent power to each target section would be provided using magnetic flux intensity rather than electrical voltage as the means for varying applied power.
  • the concave configuration 500 includes first through third target members 550, 560, and 570 respectively arranged and successively higher heights, H 1 , H 2 , and H 3 .
  • Independent power supplies 541, 542, and 543 respectively supply power levels P 1 , P 2 , and P 3 to respective target members 550, 560, and 570.
  • Triangular region 521 in FIG. 5 represents the spread of trajectories contributed from the left side of target member 550 to the surface center point 512 of the substrate 510.
  • Triangular region 522 represents the spread of trajectories contributed by the left side of target member 560 to substrate surface point 512.
  • Triangular region 523 represents the spread of trajectories contributing particles from target member 570 to surface point 512.
  • Triangular region 524 represents a spread of hypothetical trajectories that are "shadowed" or blocked from travelling from the third target member 570 to substrate surface point 513 by the intervening portion of the right side of target member 560.
  • trajectory spread 521 remains substantially unchanged from the corresponding spread in the reference system 200 (FIG. 2).
  • trajectory spread 522 originates from a higher height H 2
  • trajectory 523 originates from an even higher height H 3
  • the attack angles of these latter trajectory spreads, 522 and 523 are less than the corresponding angles of attack for corresponding portions of the planar target 220 in reference system 200. Accordingly, the step coverage for center surface point 512 is improved with respect to the contributions from the second and third target members, 560, and 570.
  • the substrate center point 512 is not uniquely situated to receive particles along the shortest particle travel distances (d p 's) form all emission points on the target 520.
  • the center point 212 of reference system 200 (FIG. 2) is closer in the aggregate to all target source points than any other particle receiving point on the substrate surface.
  • the substrate center point tends to receive the highest cumulative deposition rate (see FIG. 1B) while points spaced horizontally away receive lower rates of deposition. This leads to nonuniformity of deposition film thickness across substrate 210.
  • FIG. 5 a more uniform distribution of film thickness is obtained because the substrate center point 512 is not uniquely advantaged in terms of particle travel distances and aggregate deposition rate.
  • FIG. 6 shows a staggered configuration 600 wherein the first and third target members 650 and 670 are at height H 1 while the second target member 660 is at a greater height H 2 .
  • the third target member 670 acts as a shadow mask for various trajectory spreads emanating from the higher target member 660.
  • the "shadowed" or blocked particle trajectories include a hypothetical first spread 625 emanating from the right side of target member 660 toward the left region 611 of substrate 610 and a hypothetical second spread 626 emanating from the left side of target member 660 towards the right region 613 of the substrate 610.
  • the first and second spreads 625 and 626 are not the only trajectories blocked by target member 670. There are many others. Spreads 625 and 626 are illustrated merely as examples.
  • the trajectory blocking action of the lower target member 670 is referred to herein as "self-collimation" since one portion of the overall target 620 blocks out various trajectories from other portions of the same overall target 620.
  • Self-collimation may be used to provide a variety of advantageous distributions of deposition across the substrate surface in terms of step coverage uniformity and film thickness uniformity.
  • the Staggered target arrangement of FIG. 6 shows only two horizontal layers of target members (at respective heights, H 1 and H 2 ), it should be apparent that the target may have many more layers, each such layer being occupied by one or a plurality of independently powered target members.
  • the organization of the target members in the various layers may be modified and their active surface areas may be resized as desired to provide all sorts of self-collimating and other effects.
  • FIG. 7 is a cross-sectional view showing a first specific implementation similar to the staggered configuration shown in FIG. 6.
  • the diameter W S of semiconductor wafer 710 is 20 cm.
  • the active cross-sectional width of target member 750 is 5 cm on the left and 5 cm. on the right side.
  • the active diameter of target member 770 is 5 cm.
  • the active cross-sectional width of target member 760 is 7.5 cm. on the left and 7.5 cm. on the right.
  • the power densities P 1 and P 2 respectively applied to target members 750 and 760 are approximately equal to one another in terms of kilowatts per cm 2 .
  • the power density P 3 applied to target member 770 is preferably in the range 0.60 P 1 to 1.00 P 1 .
  • staggered configuration 700 Comparing the simulated deposition characteristics of staggered configuration 700 against that of the reference system 200 (FIG. 2), it was found that average deposition rate decreased by 9.9%. However, film thickness uniformity increased by 60%, which is considered a significant improvement. There was no significant change in step coverage. Step coverage uniformity increased by 42%. Accordingly, although the staggered configuration 700 has the drawback of a slightly reduced deposition rate when compared to the reference system 200, the staggered configuration 700 has the advantage of providing a substantially improved uniformity of deposition film thickness and a substantially improved uniformity in step coverage.
  • FIG. 8 shows the cross-sectional view of yet another specific embodiment having a nonplanar target.
  • Like numbers in the "800" number series are used for elements having corresponding components numbered in the "700" number series in FIG. 7.
  • the wafer diameter in FIG. 8 remains unchanged at 20 cm.
  • Left and right sides of target member 860 are each 5 cm. in cross-sectional width.
  • Target member 870 has a diameter of 10 cm. If desired, target members 860 and 870 may be merged into a unitary disk having a diameter of 20 cm.
  • Target member 850 has an effective cross-sectional width of 5 cm. on the left and 5 cm. on the right.
  • the specific configuration 800 of FIG. 8 showed the following deposition characteristics when modeled using SPEEDIE: Deposition rate decreased by 23%. Film thickness uniformity decreased by 2%. Step coverage increased by 23%. And step coverage uniformity increased by the surprising amount of 70%.
  • FIG. 9 shows yet another specific configuration 900.
  • Semiconductor wafer 910 is again 20 cm. in diameter.
  • Power densities P 2 and P 3 are approximately equal to one another while power density P 1 can be equal to or less than P 2 and P 3 .
  • the specific configuration 900 of FIG. 9 exhibited the following deposition characteristics when modeled: deposition rate decreased by 10%, film thickness uniformity increased by 24%, step coverage increased by 5%, and step coverage uniformity increased by 56%.
  • FIG. 10 is a cross-sectional view of yet another specific configuration 1000. Like reference numbers in the "1000" number system are used in FIG. 10 for elements having corresponding components numbered in the "900" number series in FIG. 9.
  • the diameter of wafer 1010 remains at 20 cm.
  • Target member 1060 is positioned at height H 2 32 20 cm. and has an effective cross-sectional width of 5 cm. on the left and 5 cm. on the right.
  • the power density applied to each of the target members 1050, 1060, and 1070 is approximately equal.
  • figure of merit is generally defined as:
  • i represents a deposition attribute selected from the group comprised of, but not limited to: (a) average deposition rate; (b) average bottom coverage; (c) flat coverage uniformity; (d) bottom coverage uniformity; (e) minimum sidewall bottom thickness; (f) step coverage; (g) step coverage uniformity; (h) film thickness uniformity.
  • k represents a particular nonplanar target configuration under consideration
  • f ik represents the modeled ith deposition attribute of nonplanar target configuration k
  • f iR represents the modeled ith deposition attribute of a fixed reference configuration R which is usually a planar target configuration
  • a i represents a predefined weight attached to the ith deposition attribute.
  • height H 3 of the center one of three target members was fixed at 5 cm while heights H 1 and H 2 of the respective outer and middle target members were allowed to vary.
  • Each of the three target members had an effective emissive width of 5 cm.
  • the substrate had a diameter of 15 cm. Power density in terms of kilowatts per cm 2 was the same for each target member.
  • the figure of merit was set to give equal weight to the following five attributes: (a) average deposition rate; (b) average bottom coverage; (c) flat coverage uniformity; (d) bottom coverage uniformity; (e) minimum bottom thickness, while zero weight was given to all other attributes.
  • the resulting figure of merit value for each configuration k of H1 and H2 was plotted as a corresponding color on a two dimensional graph having H1 and H2 as its axes. Different colors were used for each value range, the darker or more pronounced colors being assigned to the higher values of merit.
  • the above configuration optimization method can of course be used to find optimum configurations for other weightings of deposition attributes and other settings of target member geometries and substrate geometries. It is not limited to any particular number of target members.

Abstract

A PVD sputter system having a nonplanar target surface is disclosed. The configuration of the nonplanar target surface is adjusted to provide improved uniformity in deposition film thickness and step coverage at the peripheral boundary regions of the substrate. Emission-inducing power is distributed independently to different portions of the nonplanar target surface so as to modify the deposition profile according to substrate size and other factors.

Description

This application is a division of Ser. No. 08/316,090, filed Sep. 30, 1994.
BACKGROUND
1. Field of the Invention
The invention is generally directed to physical vapor deposition (PVD) sputter systems. The invention is more specifically related to an apparatus and method for PVD sputtering during the fabrication of semiconductor devices wherein it is desirable to obtain a combination of uniform deposition thickness, high deposition rate, and good step coverage.
2. Cross Reference to Related Publications
The following publication(s) is/are believed to be related to the present application and is/are cited here for purposes of reference:
(A) D. S. Bang. et al, "Modeling of Ti Physical Vapor Deposition Systems", IEEE International Workshop on Numerical Modeling of Processes and Devices for Integrated Circuits (NUPAD V, Honolulu) Jun. 1994, pp 41-44;
(B) D. S. Bang. et al, "Profile Modeling of Collimated Ti Physical Vapor Deposition", 10th Symposium on Plasma Processing, Electro Chemical Society, San Francisco, May 1994; and
(C) G. Box and N. Draper, "Empirical Model Building and Response Surfaces", John Wiley & Son, New York 1987.
3. Description of the Related Art
PVD sputtering is used within semiconductor processing and other arts for depositing metal films and the like onto substrate surfaces.
The substrate (e.g., semiconductor wafer) is typically a planar disk that is positioned, face-down at the top of a vacuum plasma chamber.
A planar target is further typically positioned face-up within the chamber, in spaced apart and symmetrical counterfacing relation with the substrate. In older sputter systems the target was on top and the substrate on the bottom. The substrate-on-top versus on-bottom orientation has to do with keeping the substrate surface clean and is not directly related to the present invention. For purposes of consistency, the older configuration with the substrate on the bottom will be shown, but it is to be understood that other orientations are fully within the contemplation of this disclosure.
The target is made of the material that is to be sputter deposited onto the substrate surface. Examples include, but are not limited to, metals such as aluminum (Al), titanium (Ti), copper (Cu), and alloys or compounds of these materials.
Emission-inducing energy is applied to the active face of the target in the form, for example, of a plasma containing accelerated argon ions. In response to such bombardment, the active face of the target emits small particles composed of the target material (e.g. aluminum). The emitted particles follow a generally linear trajectory from their point of emission on the target surface to a collision point on the counterfacing surface of the substrate. Physical adhesion mechanisms cause the target particles to bond to the surface of the substrate.
The physical dimensions and positionings of the substrate and target play important roles in determining rate of deposition and the uniformity of the deposited film. The distribution of emission-inducing energy across the target also plays a role.
Ideally, the target should be very wide relative to the substrate so that the target represents an infinite source plane to the particle-receiving face of the substrate. In a such a situation, if the particle receiving face of the substrate is perfectly planar and parallel to the target, every point on the substrate receiving face will receive the same contribution of deposition particles and film thickness will be uniform across the entire substrate.
Unfortunately, this ideal arrangement is not possible in practical implementations of PVD sputter chambers. The target has a finite size that is usually the same order of magnitude as that of the substrate. Non-uniformities develop across the substrate for characteristics such as deposition film thickness and deposition rate due to boundary conditions.
In the fabrication of semiconductor devices, the substrate surface is often not perfectly planar. Nonlinear features such as channels and mesas are typically found on the semiconductor substrate. It is often desirable to coat the sidewalls and/or bottoms of each channel or mesa with a layer of deposition material having a prescribed thickness. However, the linear nature of the trajectories followed by the emitted target particles in PVD systems create shadow effects. Not every portion of the substrate surface receives the same amount of target material at the same rate in the case where the substrate surface includes nonlinearities such as channels or mesas.
The term, "channel" is used herein in a broad sense to include features in semiconductor devices and the like such as contact vias, trenches, and other depressions which are to be fully or partially filled with deposition material.
The term, "mesa" is similarly used herein in a broad sense to include any device feature rising above a surrounding plane where the feature and/or its surrounding plane are to be coated with deposition material.
The term, "step coverage" is used herein in a qualitative sense to refer to the ability to coat one or more sidewalls or bottom of a channel or mesa to a desired thickness. The term, "step coverage" is further used herein in a quantitative sense to refer to the ratio of film thickness at the bottom of a sidewall relative to film thickness at the top of the same sidewall, where the sidewall has a predefined height.
The term, "step coverage uniformity" is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of step coverage across a given substrate.
The term, "flat coverage uniformity" is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate taking into consideration only substantially planar regions (not step regions) of the substrate surface.
The term, "film thickness uniformity" is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate, taking into consideration all regions (flat and step regions) of the substrate surface.
The term, "bottom coverage uniformity" is used herein in a quantitative sense to mean the statistical standard deviation (sigma) of film thickness across a given substrate, taking into consideration only regions at the bottom of channels or mesas.
It has been common practice in the semiconductor fabrication arts to sputter deposit films to a thickness substantially greater than the desired or minimally acceptable amount in order to make sure that adequate thickness is obtained across the entire substrate despite nonuniformities in step coverage and film thickness. Sometimes, the extra-thick portions of the deposited material have to be polished away or otherwise removed in order to obtain planarity and/or uniform flat coverage across the substrate. Such over-deposition followed by removal of excess material is wasteful of resources, time, and energy.
It has also been common practice in the semiconductor fabrication arts to increase the radius of wafers every so many years in order to obtain higher yield per wafer and/or in order to be able to economically mass produce integrated circuit chips of larger dimensions. Alterations in wafer size have previously required major alterations to production equipment, including making physical vapor deposition sputter chambers of larger size to house larger and larger targets. PVD sputter chambers typically need to support ion plasmas at very low pressures, on the order of 2 milliTorr or less, and are thus relatively costly to manufacture. It would be desirable to have a PVD sputter system that can accommodate wafers of different sizes while providing relatively similar uniformities in step coverage and film thickness.
SUMMARY OF THE INVENTION
It is an object of the invention to provide a sputter apparatus and method that provides an improved combination of deposition thickness uniformity and step coverage uniformity.
It is a further object of the invention to provide a sputter apparatus and method that can be easily modified to accommodate wafers or other substrate surfaces of changing size.
A sputter system in accordance with the invention comprises a nonplanar sputter target positioned relative to a to-be-coated substrate such that the maximum angle of particle emission is below a prespecified maximum.
In accordance with one feature of the invention, power is independently distributed to different parts of the nonplanar target and adjusted to provide substantially uniform rates of deposition across the substrate surface.
In accordance with a second feature of the invention, the nonplanar target is subdivided into isolated target members placed at different heights relative to the substrate surface and energized by independent sources of emission-inducing energy.
In accordance with a third feature of the invention, the amount of emission-inducing energy applied to each portion of the nonplanar target is set according to the travel distance of the particles that are to flow from that portion to the substrate surface.
In accordance with a fourth feature of the invention, the nonplanar target is configured such that some portions of the target provide a collimation function for particles emitted from other portions of the same nonplanar target.
Other aspects of the invention will become apparent from the below detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
The below detailed description makes reference to the accompanying drawings, in which:
FIG. 1A is a cross sectional view of a hypothetical point-source sputtering system that is used for explaining the principles of operation of the invention;
FIG. 1B is a cross sectional magnified view showing a central surface portion of the substrate, including a first to-be-coated channel;
FIG. 1C is a cross sectional magnified view of a border portion of the substrate surface, including a second to-be-coated channel;
FIG. 2 is a cross sectional view of a conventional sputter system having a planar target;
FIG. 3 is a cross sectional view of a first embodiment in accordance with the invention having a nonplanar target;
FIG. 4 is a cross sectional view of a second embodiment in accordance with the invention having isolated target members placed at different heights relative to the substrate surface with each target member receiving power from an independent power source;
FIG. 5 is a cross sectional view of a third embodiment wherein the nonplanar target has a generally concave shape relative to the substrate;
FIG. 6 is a cross sectional view of a fourth embodiment wherein the nonplanar target is comprised of a staggered configuration of independently powered members and has a self-collimating feature;
FIG. 7 is a cross sectional view of a first specific configuration having unique deposition attributes;
FIG. 8 is a cross sectional view of a second specific configuration having unique deposition attributes;
FIG. 9 is a cross sectional view of a third specific configuration having unique deposition attributes; and
FIG. 10 is a cross sectional view of a fourth specific configuration having unique deposition attributes.
DETAILED DESCRIPTION
FIG. 1A is a cross sectional view of a hypothetical point-source sputter system 100 that is used for explaining principles of operation of the present invention.
In FIG. 1A, a planar, disk-shaped substrate having a width, WS, is shown at 110. A central, top surface portion of the substrate is designated as 112. Respective left and right portions of the substrate top surface are designated as 111 and 113.
A hypothetical point-source target 120 having a width WT of approximately zero is positioned symmetrically above and spaced away from the central surface portion 112 of the substrate 110. The distance between the point-source target 120 and the substrate center 112 defines a height, H.
A power source 140 is coupled by way of means 141 to the point-source target 120 in order to cause the target 120 to emit deposition particles along linear trajectories directed to the substrate surface. The power source 140 can include a source of accelerated argon ions or the like. The power source 140 can further include confinement magnets for confining accelerated particles near the region of the target 120.
The emission trajectories of the target particles are uniformly distributed about three dimensional space. Three such trajectories are illustrated by way of dashed lines in FIG. 1A and respectively referenced as 121, 122 and 123. Trajectory 121 has a particle travel distance of dp1 and carries particles from target 120 to the left surface region 111 of the substrate 110. Trajectory 122 has a travel distance of dp2 equal to height H and carries target particles from the target 120 to the central surface region 112. Trajectory 123 has a particle travel distance of dp3 and carries target particles from the target 120 to the right surface region 113. Each of trajectories 121 and 123 defines an angle of θ between itself and the normal of the substrate surface (the hypothetical perpendicular drawn from the substrate surface). Note that as height H decreases, the trajectory angle θ (or "angle of attack" θ as it will also be called) increases, and vice versa.
It has been shown that film deposition rate (r) in sputtering systems is inversely proportional to the particle travel distance (dp) raised to a power (α) approximately between one and two. {r=f (dp -α); where 1≦α≦2.} Thus, the deposition rates of the left and right trajectories, 121 and 123, are less than that of the central trajectory 122.
FIG. 1B is a magnified view showing a first channel 114 formed at the central surface region 112 of substrate 110. The central trajectory 122 deposits target material 132 vertically into the bottom of the channel. The trajectories (not shown) to the left and right of 122 respectively deposit target material for regions 131 and 133. Since the deposition rates of the side trajectories are less than that of the central trajectory 122, the thickness of material deposited at 131 and 133 slopes down as one moves horizontally away from the central trajectory 122. (The slope is exaggerated in FIG. 1B for purpose of illustration.) If a desired minimum thickness is to be obtained at the outer portions of depositions 131 and 133, an excess amount of material needs to be deposited at 132 in order to assure that film regions 131 and 133 will have adequate thickness. As explained above, this is disadvantageous because it wastes target material. The target is eroded faster than absolutely necessary and has to be replaced more often. The deposition of excess target material wastes time, energy, and increases the cost of production. In some instances, the excess material near the central portion 112 of the substrate has to be polished away or etched back in order to obtain uniform thickness across the entire width WS of the substrate. This also wastes time, energy and resources.
Referring to FIG. 1C, the maximum trajectory angle θ at which target particles are propelled to the substrate plays an important role in step coverage. FIG. 1C shows a magnified cross sectional view of right surface region 113, wherein a second channel 116 has been formed. Trajectory 123 approaches second channel 116 with the attack angle θ. The left sidewall 117 of channel 116 casts a shadow on the right sidewall 118 and bottom of the channel. The shadow height increases up along the right sidewall 118 as the attack angle θ increases. As a result of this shadowing effect, only a top portion of the right sidewall 118 is covered with target material 136 contributed by trajectory 123. The entire left sidewall 117, the lower portion of right sidewall 118 and the bottom 119 of the channel do not receive deposition contribution from trajectory 123. In many cases it is desirable to uniformally coat the entire inner surface of channel 116 with the target material 136. However, the shadowing effect of the trajectory angle θ prevents this from occurring.
Above FIGS. 1A-1C are understood to the hypothetical conditions provided herein for purposes of illustration. The target in an actual sputter system will have some physical width WT greater than zero and hence will act at least as a two-dimensional source rather than a point-source.
FIG. 2 shows the cross section of a conventional configuration within a sputter chamber. Like-reference numbers in the "200" number series are used in FIG. 2 to denote elements having like counterparts in FIG. 1A, and as such they will not be again explained in detail.
In FIG. 2, a planar, disk-shaped target 220 having width WT is provided in parallel, spaced apart, and centralized relation to the substrate 210, where the latter has width WS. The target width WT is substantially larger than the substrate width WS.
The emission surface of the target 220 generally defines a continuum of point sources distributed across the circular bottom surface area of the target 220. Each target point source contributes partially to the deposition occurring at corresponding receiving points on the top surface of substrate 210. The power output of power source 240 is uniformly distributed to all emission points (target point sources) of the target 220.
Deposition at each receiving point on the substrate surface, including respective left, center, and right regions, 211, 212, and 213, may be calculated as the summed (or integrated) contribution of particles received from each of the point sources along the emission surface of target 220.
By way of example, the right peripheral region 213 of the substrate receives particles contributed from the left edge of target 220 by way of left trajectory 221. Trajectory 221 has a particle travel distance of dp1 and it forms a first attack angle θ1 with the substrate surface normal. Similarly, particles received from the target portion directly above substrate region 213 travel along a middle trajectory 222 which has a travel distance of dp2 and defines an attack angle of θ2 =0 relative to the substrate surface normal. And likewise, particles received from the right extreme of target 220 travel along a right-side trajectory 223 for deposition onto substrate region 213. Trajectory 223 has a particle travel distance of dp3 and defines an attack angle of θ3 relative to the substrate surface normal.
As explained above, film deposition rate (r) at each receiving point on the substrate surface will be inversely proportional to the particle travel distance (dp) of each target point-source raised to a prespecified power (α). The contribution received at each substrate surface point, from each target point-source has to be summed to determine the accumulated deposition at each receiving point on the substrate surface. {Ri =∫f(dp -α)·dx·dy; for all x and y on the target surface, where Ri is the accumulated rate of deposition at a given surface point i on the substrate surface. }
The specific dimensions of the target width WT, the substrate width WS, and the target-to-substrate separation height H need to be known in order to determine the cumulative deposition rate at each receiving point on the substrate surface.
In one specific embodiment, which will be referred to herein as the reference system 200, the substrate 210 is a planar, circular disk having a width of WS =20 cm (twenty centimeters). The target 220 is also a planar, circular disk and has a width of WT =30 cm. The target-to-substrate separation height is H=15 cm. The power source 240 delivers a normalized power of one unit per cm2 to the emission surface of target 220. In this particular situation, the maximum trajectory angle θ1 of the left-most trajectory path 221 is approximately 59°. The uniformity of step coverage is defined in part by this 59° maximum trajectory angle.
The inventors herein recognized that step coverage uniformity could be improved if the maximum trajectory angle θ1 could be reduced. They also recognized that, if one simply increased the target-to-substrate separation height H uniformly across the target, the deposition rate would then disadvantageously decrease. The solution was to find a compromise between these counterposed attributes. The inventors herein decided to vary target point-to-substrate separation height H at each point of the target as a function of both the allowed maximum trajectory angle θ1 and desired deposition rate. In other words, they decided to make the target nonplanar relative to the substrate. This produced unexpected advantages.
The solution of using a nonplanar target further includes the step of optionally varying the amount of emission-inducing energy applied to each portion of the nonplanar target as a function of that portion's distance from the substrate.
FIG. 3 shows a first embodiment 300 in accordance with the invention that is to be compared to scale against the reference system 200 of FIG. 2. Like reference numbers in the "300" numbering system are used in FIG. 3 for elements having corresponding components numbered in the "200" series in FIG. 2.
The sputter system 300 of FIG. 3 includes a nonplanar target 320 that is configured to present a generally convex emission surface relative to the deposition surface 311-313 of the substrate 310. The peripheral portions of target 320 are raised to respective left and right heights, H1 and H3, that are each greater than the central height, H2.
The increase of the peripheral target heights, H1 on the left and H3 on the right, works to reduce the trajectory angles of the target particles emitted from those peripheral target sites and thereby improves the uniformity of step coverage across the substrate surface.
By way of example, note that the top right surface point 313 of substrate 310 receives a first contribution of deposition material from the left edge of the target 320 by way of trajectory 321. The attack angle, θ31 of trajectory 321 is less than the attack angle θ1 of previous trajectory 221 in the reference system 200. Surface point 313 further receives a contribution from the right edge of target 320 by way of trajectory 323. The attack angle θ33 of trajectory 323 is less than the attack angle θ3 of the previous trajectory 223 in the reference system 200. Since angle θ31 is less than θ1, and angle θ33 is less than θ3, shadowing effects are decreased in magnitude and the uniformity of step coverage is improved across the substrate surface 311-313.
Improved step coverage does not come freely, however. The particle travel distances (dp1 and dp3) of trajectories 321 and 323 are greater than those of the previous trajectories, 221 and 223 respectively. The overall rate of material deposition suffers as a consequence.
To overcome this problem, power is distributed to each of the regions of target 320 on an independent region-by-region basis. A first independent power supply 341 supplies emission-inducing power P1 to the left periphery of target 320. A second power supply 342 supplies power P2 to the central portion of target 320. A third independent power supply 343 provides emission-inducing power P3 to the right peripheral region of target 320. The emission-inducing powers, P1 and P3 of the respective first and third power supplies 341 and 343 are preferably set greater than the power P2 of second power supply 342 so that the peripheral edges of the target 320 have a higher rate of particle emissivity. This compensates for the increased particle travel distance along trajectories 321, 322 and 323 so as to bring the deposition rate at substrate site 313 back to par with that of site 213 in the reference system 200.
FIG. 3 shows the nonplanar target 320 as having a unitary construct. Such a unitary construct does not allow power differentiation to be provided by way of electric voltage difference in cases where the target material 320 is a conductive material such as aluminum, titanium, copper or an alloy of one or more of these metals. One way to provide power differentiation in such a situation is to use independently-driven flux-confining magnets at each of the independently-powered target sites. The magnets may be of the fixed or moving kind. An example of the use of a distributed magnet system for independently powering different parts of a planar target is seen in the Applied Materials Endura 5000™ sputtering chamber which is available from Applied Materials of Santa Clara, Calif. Local magnetic flux strength determines the velocity of emission-inducing particles striking the target surface, and this in turn defines the local surface emissivity. It should be apparent that in the case where the target is symmetrical about its middle axis (H2), the left and right power supplies, 341 and 343, can be merged into a single supply (not shown) whose output may be set differently from that of the central power supply 342.
FIG. 4 shows a second embodiment in accordance with the invention wherein the overall target 420 is fragmented into first through third, independent target members 450, 460, and 470 each being adjustable to have a different height relative to the substrate surface 411-413. The multi-member target configuration 400 of FIG. 4 is drawn to the same scale as the reference system 200 of FIG. 2 and to that of the unitary target configuration 300 of FIG. 3 so as to enable simple comparison among these systems (200, 300, 400). Like reference numbers in the "400" numbering system are used in FIG. 4 for elements having corresponding components numbered in the "300" series in FIG. 3.
The multi-member target configuration 400 of FIG. 4 includes as its lowest target member 470, a circular disc having an active surface positioned at a height H3 (equal to reference height H) centrally over substrate 410. Positioned above the lowest target member 470, at a second height H2 (greater than reference height H) there is the second target member 460 which has an annular shape (ring shape) surrounding the hypothetical upward projection of the lowest target member 470. Positioned above the second target member 460, at a height H1 (greater than second height H2) there is the first target member 450 which has an annular shape surrounding the hypothetical upward projection of middle ring 460. Target members 450, 460, and 470 are electrically insulated from one another.
Although a plurality of three target members is shown in FIG. 4, it is to be understood that the number of target members may be reduced to two or increased to any desired number above three.
Although the respective heights of the first through third target members 450, 460, and 470 are arranged in successively decreasing order, H1 >H2 >H3, it is to be understood that the respective heights of the plural target members can be arranged into any otherwise desired, nonplanar configuration.
A first independent power supply 441 supplies a first emission-inducing power P1 to the first target member 450. A second independent power supply 442 supplies a second emission-inducing power P2 to the second target member 460. A third power supply 443 similarly applies a third emission-inducing power P3 to the third target member 470. Power levels P1, P2, and P3 may be set independently of one another so as to define different particle emission rates (per cm2) for each of the respective target members, 450, 460, and 470.
The combined active width of target members 450, 460, and 470 is substantially equal to the active width WT of the reference target 220 in FIG. 2. The individual active width of each of target members 450, 460, and 470 may be set as desired. In the example of FIG. 4, the lower target member 470 has an effective width equal to approximately one-fifth of WT while the other two target members 460, 450 each have an effective emissive width equal to two-fifths of WT. The emission inducing power applied to the respective first through third multiple target members 450, 460, and 470 is preferably set such that P1 >P2 >P3, where the power is measured in terms of Kilowatts per unit area of active target surface or in like terms for determining the per unit area emissivity of each target member, 450, 460, and 470.
As seen, the top right surface point 413 of substrate 410 receives a first contribution from the left extreme of first target member 450 by way of first trajectory 421. The left side trajectory 221 of the reference system is shown as a dashed double-dot line for purposes of comparison. Note that the angle of attack θ41 of trajectory 421 is substantially less than the angle of attack, θ1 of reference trajectory 221.
Note also, by way of an aside whose relevance will be understood below, that trajectory 421 avoids colliding into the second target member 460 by a small distance. If the height H1 of the first target member 450 were to be raised by an appropriate distance, and/or the height H2 of the second target member 460 were to be lowered by an appropriate distance, then trajectory 421 would be blocked by the intervening body of the second target member 460. The maximum angle of attack for particles contributing to substrate surface point 413 would then be decreased to less than θ41. In such a case, the nonplanar configuration of the target surface would provide a self-collimating function that limits the maximum angle of attack.
In addition to the contribution from particle trajectory 421, the right surface point 413 of substrate 410 receives a further contribution from the right extreme of the middle target member 460 by way of trajectory 422. The particle travel distance (dp2) of trajectory 422 is approximately equal to separation height H2.
Substrate surface point 413 further receives deposition contribution from the right extreme edge of the highest target member 450 by way of trajectory 423. Reference trajectory 223 is drawn as a dashed double-dot line nearby for purposes of comparison. Note that the angle of attack θ43 of trajectory 423 is substantially less than that the angle of attack θ3 of reference trajectory 223.
With appropriate adjustment of the heights, effective widths and applied powers of the multiple target members, 450, 460, and 470; it is possible to vary the deposition characteristics of the multi-target sputter system 400 so as to obtain improved step coverage or better film thickness uniformity or compromised improvement in both as will be explained below.
The number of variations possible for the multi-target configuration shown in FIG. 4 is quite large. Rather than building a physical embodiment for each possibility, the inventors herein used a computer simulation that calculates the theoretical deposition patterns on a substrate including a plurality of channels for thousands of different target configurations, each having one or more unique settings for target member placement, target member width, target member power, and so forth.
The computer simulation that was used is generally known as SPEEDIE (Stanford Profile Emulator for Etching and Deposition in IC Engineering). Various versions of this simulation package are available from the Stanford Research Center of Stanford University, Palo Alto, Calif. The particular version used by the inventors included a PVD simulator module operating in accordance with the above cited paper by D. S. Bang et al, "Modeling of Ti Physical Vapor Deposition Systems", NUPAD V, Honolulu June. 1994. Of course, other similarly-suitable simulators may be used for modeling the performance for various target and substrate configurations.
It was found using the SPEEDIE modeler that several nonplanar, staggered arrangements of independently-powered target members provided improved step coverage and/or improved deposition uniformity relative to that of the reference system 200. FIGS. 7-10 show specific examples of configurations which provided improved performance in one or more areas of measure (e.g., flat coverage uniformity, step coverage, step coverage uniformity, average deposition rate, average bottom coverage and minimum sidewall coverage).
In general, a nonplanar target can take on many configurations including, but not limited to: (a) convex, (b) concave, and (c) staggered. The convex configuration has been covered above by the embodiments shown in FIGS. 3 and 4 (continuous and fragmented). FIGS. 5 and 6 respectively show fragmented embodiments of the concave and staggered configurations in a generic sense. (Continuous rather than fragmented embodiments of the concave and staggered configurations can be constructed by linking together the fragmented target members of FIGS. 5 and 6 with vertical connections. In the latter continuous-construct cases, independent power to each target section would be provided using magnetic flux intensity rather than electrical voltage as the means for varying applied power.)
Like reference numbers in the "500" numbering system are used in FIG. 5 and in the "600" numbering system are used in FIG. 6 for elements having corresponding components numbered in the "400" series in FIG. 4.
Referring to FIG. 5, the concave configuration 500 includes first through third target members 550, 560, and 570 respectively arranged and successively higher heights, H1, H2, and H3. Independent power supplies 541, 542, and 543 respectively supply power levels P1, P2, and P3 to respective target members 550, 560, and 570.
Triangular region 521 in FIG. 5 represents the spread of trajectories contributed from the left side of target member 550 to the surface center point 512 of the substrate 510. Triangular region 522 represents the spread of trajectories contributed by the left side of target member 560 to substrate surface point 512. Triangular region 523 represents the spread of trajectories contributing particles from target member 570 to surface point 512. Triangular region 524 represents a spread of hypothetical trajectories that are "shadowed" or blocked from travelling from the third target member 570 to substrate surface point 513 by the intervening portion of the right side of target member 560.
As seen in FIG. 5, the maximum attack angle θ1 of trajectory spread 521 remains substantially unchanged from the corresponding spread in the reference system 200 (FIG. 2). However, because trajectory spread 522 originates from a higher height H2, and trajectory 523 originates from an even higher height H3, the attack angles of these latter trajectory spreads, 522 and 523, are less than the corresponding angles of attack for corresponding portions of the planar target 220 in reference system 200. Accordingly, the step coverage for center surface point 512 is improved with respect to the contributions from the second and third target members, 560, and 570.
Moreover, in FIG. 5 (concave target configuration), the substrate center point 512 is not uniquely situated to receive particles along the shortest particle travel distances (dp 's) form all emission points on the target 520. Note in contrast, that the center point 212 of reference system 200 (FIG. 2) is closer in the aggregate to all target source points than any other particle receiving point on the substrate surface. Thus in FIG. 2, the substrate center point tends to receive the highest cumulative deposition rate (see FIG. 1B) while points spaced horizontally away receive lower rates of deposition. This leads to nonuniformity of deposition film thickness across substrate 210. On the other hand, in FIG. 5, a more uniform distribution of film thickness is obtained because the substrate center point 512 is not uniquely advantaged in terms of particle travel distances and aggregate deposition rate.
FIG. 6 shows a staggered configuration 600 wherein the first and third target members 650 and 670 are at height H1 while the second target member 660 is at a greater height H2. Because of this staggered arrangement, the third target member 670 acts as a shadow mask for various trajectory spreads emanating from the higher target member 660. The "shadowed" or blocked particle trajectories include a hypothetical first spread 625 emanating from the right side of target member 660 toward the left region 611 of substrate 610 and a hypothetical second spread 626 emanating from the left side of target member 660 towards the right region 613 of the substrate 610. The first and second spreads 625 and 626 are not the only trajectories blocked by target member 670. There are many others. Spreads 625 and 626 are illustrated merely as examples.
The trajectory blocking action of the lower target member 670 is referred to herein as "self-collimation" since one portion of the overall target 620 blocks out various trajectories from other portions of the same overall target 620. Self-collimation may be used to provide a variety of advantageous distributions of deposition across the substrate surface in terms of step coverage uniformity and film thickness uniformity.
Although the Staggered target arrangement of FIG. 6 shows only two horizontal layers of target members (at respective heights, H1 and H2), it should be apparent that the target may have many more layers, each such layer being occupied by one or a plurality of independently powered target members. The organization of the target members in the various layers may be modified and their active surface areas may be resized as desired to provide all sorts of self-collimating and other effects.
FIG. 7 is a cross-sectional view showing a first specific implementation similar to the staggered configuration shown in FIG. 6. Like reference numbers in the "700" number series are used in FIG. 7 for elements having corresponding components numbered in the "600" number series in FIG. 6. The diameter WS of semiconductor wafer 710 is 20 cm. The active cross-sectional width of target member 750 is 5 cm on the left and 5 cm. on the right side. The active diameter of target member 770 is 5 cm. Target members 750 and 770 are at a height of H1 =10 cm. The active cross-sectional width of target member 760 is 7.5 cm. on the left and 7.5 cm. on the right. Target member 760 is at a height of H2 =20 cm.
The power densities P1 and P2 respectively applied to target members 750 and 760 are approximately equal to one another in terms of kilowatts per cm2. The power density P3 applied to target member 770 is preferably in the range 0.60 P1 to 1.00 P1.
Comparing the simulated deposition characteristics of staggered configuration 700 against that of the reference system 200 (FIG. 2), it was found that average deposition rate decreased by 9.9%. However, film thickness uniformity increased by 60%, which is considered a significant improvement. There was no significant change in step coverage. Step coverage uniformity increased by 42%. Accordingly, although the staggered configuration 700 has the drawback of a slightly reduced deposition rate when compared to the reference system 200, the staggered configuration 700 has the advantage of providing a substantially improved uniformity of deposition film thickness and a substantially improved uniformity in step coverage.
FIG. 8 shows the cross-sectional view of yet another specific embodiment having a nonplanar target. Like numbers in the "800" number series are used for elements having corresponding components numbered in the "700" number series in FIG. 7. The wafer diameter in FIG. 8 remains unchanged at 20 cm. Left and right sides of target member 860 are each 5 cm. in cross-sectional width. Target member 870 has a diameter of 10 cm. If desired, target members 860 and 870 may be merged into a unitary disk having a diameter of 20 cm. The height of target members. 860 and 870 is H1 =10 cm. Target member 850 has an effective cross-sectional width of 5 cm. on the left and 5 cm. on the right. The height of target member 850 is H2 =20 cm. The power density applied to each of the target members, 850, 860, 870 is substantially equal (P1 =P2 =P3).
In comparison to the reference system 200 (FIG. 2) the specific configuration 800 of FIG. 8 showed the following deposition characteristics when modeled using SPEEDIE: Deposition rate decreased by 23%. Film thickness uniformity decreased by 2%. Step coverage increased by 23%. And step coverage uniformity increased by the surprising amount of 70%.
Comparing configuration 800 (FIG. 8) against configuration 700 (FIG. 7), it is seen that significantly improved step coverage and step coverage uniformity may be obtained if one is willing to sacrifice on deposition rate (the latter is measured in terms of microns per minute).
FIG. 9 shows yet another specific configuration 900. Like reference numbers in the "900" number system are used in FIG. 9 for elements having corresponding components in FIG. 8 that are numbered in the "800" number system. Semiconductor wafer 910 is again 20 cm. in diameter. Target member 950 is positioned at height H2 =15 cm. and has a cross-sectional width of 5 cm. on the left side and 5 cm. on the right side. Target member 960 is positioned at height H1 =10 cm. and has a cross-sectional width of 5 cm. on the left side and 5 cm. on the right side. Target member 970 is positioned at height H2 =15 cm. and has a cross-sectional width of 10 cm. Power densities P2 and P3 are approximately equal to one another while power density P1 can be equal to or less than P2 and P3.
In comparison to the reference system 200 (FIG. 2) the specific configuration 900 of FIG. 9 exhibited the following deposition characteristics when modeled: deposition rate decreased by 10%, film thickness uniformity increased by 24%, step coverage increased by 5%, and step coverage uniformity increased by 56%.
In comparison to the deposition characteristics of specific configuration 800 (FIG. 8), it is seen for FIG. 9 that a trade-off may be obtained wherein step coverage and step coverage uniformity are sacrificed in order to obtain an improvement in film thickness uniformity and deposition rate.
FIG. 10 is a cross-sectional view of yet another specific configuration 1000. Like reference numbers in the "1000" number system are used in FIG. 10 for elements having corresponding components numbered in the "900" number series in FIG. 9. The diameter of wafer 1010 remains at 20 cm. Target member 1050 is positioned at height H1 =10 cm. and has an effective cross-sectional width of 5 cm. on the left and 5 cm. on the right. Target member 1060 is positioned at height H2 32 20 cm. and has an effective cross-sectional width of 5 cm. on the left and 5 cm. on the right. Target member 1070 is positioned at height H3 =15 cm. and has an effective cross-sectional width of 10 cm. The power density applied to each of the target members 1050, 1060, and 1070 is approximately equal.
Comparing the specific configuration 1000 of FIG. 10 against the reference system 200 (FIG. 2), the following deposition characteristics were observed through modeling: deposition rate decreased by 9.2%, thickness uniformity increased by 53%, step coverage increased by 4.3%, and step coverage uniformity increased by 26%.
Comparing the results of configuration 1000 (FIG. 10) against those of configuration 900 (FIG. 9), one can see that a further trade-off may be made wherein film thickness uniformity is improved while suffering a loss in step coverage uniformity.
Given the large number of possible trade offs, the inventors herein devised a figure of merit system and a method for identifying the nonplanar configurations having the highest figure of merits under conditions where one or more parameters are varied such as target member heights HX through HY, target member active widths WX through Wy, target member power levels PX through PY, and so forth. The figure of merit is generally defined as:
M.sub.k =Σa.sub.i ·(f.sub.ik /f.sub.iR)
where i represents a deposition attribute selected from the group comprised of, but not limited to: (a) average deposition rate; (b) average bottom coverage; (c) flat coverage uniformity; (d) bottom coverage uniformity; (e) minimum sidewall bottom thickness; (f) step coverage; (g) step coverage uniformity; (h) film thickness uniformity. And further where k represents a particular nonplanar target configuration under consideration, fik represents the modeled ith deposition attribute of nonplanar target configuration k, fiR represents the modeled ith deposition attribute of a fixed reference configuration R which is usually a planar target configuration; and ai represents a predefined weight attached to the ith deposition attribute.
By way of one example, height H3 of the center one of three target members was fixed at 5 cm while heights H1 and H2 of the respective outer and middle target members were allowed to vary. Each of the three target members had an effective emissive width of 5 cm. The substrate had a diameter of 15 cm. Power density in terms of kilowatts per cm2 was the same for each target member. The figure of merit was set to give equal weight to the following five attributes: (a) average deposition rate; (b) average bottom coverage; (c) flat coverage uniformity; (d) bottom coverage uniformity; (e) minimum bottom thickness, while zero weight was given to all other attributes. The resulting figure of merit value for each configuration k of H1 and H2 was plotted as a corresponding color on a two dimensional graph having H1 and H2 as its axes. Different colors were used for each value range, the darker or more pronounced colors being assigned to the higher values of merit. The highest figures of merits were found using this color contour plotting approach to occur at or near the region, H1=2.5 cm and H2=3.5 cm. The planar configuration of H1=H2=H3=5 cm. was found to have one of the lowest figures of merit, thus substantiating the inventors' contention that a nonplanar target in general should give improved performance over a planar target when one takes into account attributes such as bottom coverage uniformity. The optimum configuration for the given fixed parameters and the weights attached to the deposition attributes in the figure of merit calculations is accordingly the concave configuration: H1 =2.5 cm and H2 =3.5 cm. and H3 =5.0 cm.
The above configuration optimization method can of course be used to find optimum configurations for other weightings of deposition attributes and other settings of target member geometries and substrate geometries. It is not limited to any particular number of target members.
The above disclosure is to be taken as illustrative of the invention, not as limiting its scope or spirit. Numerous modifications and variations will become apparent to those skilled in the art after studying the above disclosure.
Given the above disclosure of general concepts and specific embodiments, the scope of protection sought is to be defined by the claims appended hereto.

Claims (7)

What is claimed is:
1. A method for constructing a sputter deposition apparatus having a nonplanar target configuration, comprising the steps of:
(a) defining a figure of merit having the general form:
M.sub.k =Σa.sub.i ·(f.sub.ik /f.sub.iR)
wherein i designates an ith deposition attribute selected from a plurality of predefined deposition attributes, wherein k designates a kth nonplanar target configuration selected from a plurality of predefined different nonplanar target configurations under consideration, fik defines a modeled ith deposition attribute of nonplanar target configuration k, fir defines a modeled ith deposition attribute of a fixed reference configuration R, and ai is a predefined weight attached to the ith deposition attribute, at least one of weights ai for a respective value of i being other than zero;
(b) determining Mk for each of said plurality of predefined nonplanar target configurations;
(c) identifying one or more of said configurations having the relatively highest figures of merit; and
(d) configuring the nonplanar target in accordance with one of the one or more configurations identified as having the relatively highest figures of merit;
wherein each of said plurality of predefined deposition attributes provides a quantitative measure corresponding to:
(d.1) a rate of deposition;
(d.2) a thickness of deposition; or
(d.3) a uniformity of deposition.
2. The construction method of claim 1 wherein the plurality of predefined deposition attributes is selected from the group consisting of: (a) average deposition rate; (b) average bottom coverage; (c) flat coverage uniformity; (d) bottom coverage uniformity; (e) minimum sidewall bottom thickness; (f) step coverage; and (g) step coverage uniformity; (h) film thickness uniformity.
3. The construction method of claim 1 wherein:
said plurality of predefined nonplanar target configurations under consideration each contain multiple target members disposed at respective heights relative to a deposition receiving surface;
each target member has a respective active width;
each target member has a respective power level; and
said plurality of predefined nonplanar target configurations differ from one another with respect to at least one configuration parameter in the group consisting of:
(a.1) target member heights;
(a.2) target member active widths;
(a.3) target member power levels;
(a.4) number of target members; and
(a.5) geometry of each target member.
4. The construction method of claim 3 wherein said step of identifying one or more of said configurations having the relatively highest figures of merit includes:
(c.1) assigning one of different colors to each value of merit, where darker or otherwise more pronounced colors are assigned to respectively higher values of merit;
(c.2) in a plotting space having at least two axes each representing a different one of said configuration parameters, for each determined figure of merit Mk, plotting the correspondingly assigned color at a point in the plotting space corresponding to the respective target configuration k; and
(c.3) after said plotting, locating regions within the plotting space having the darkest or otherwise more pronounced colors; and
(c.4) identifying the respective target configurations of the located regions.
5. The construction method of claim 3 wherein said fixed reference configuration R constitutes a planar target having an effective emission width equal to the combined active emission widths of said multiple targets.
6. The construction method of claim 1 wherein the number of considered nonplanar target configurations is at least a thousand.
7. The construction method of claim 1 wherein at least two of weights ai for a respective two values of i are other than zero.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5751607A (en) * 1995-03-30 1998-05-12 Nec Corporation Method of sputter deposition simulation by inverse trajectory calculation
US5914018A (en) * 1996-08-23 1999-06-22 Applied Materials, Inc. Sputter target for eliminating redeposition on the target sidewall
US6009255A (en) * 1996-08-21 1999-12-28 Nec Corporation Method of deposition profile simulation
US6168690B1 (en) * 1997-09-29 2001-01-02 Lam Research Corporation Methods and apparatus for physical vapor deposition
US6419803B1 (en) 2001-03-16 2002-07-16 4Wave, Inc. System and method for making thin-film structures using a stepped profile mask
US6500321B1 (en) * 1999-05-26 2002-12-31 Novellus Systems, Inc. Control of erosion profile and process characteristics in magnetron sputtering by geometrical shaping of the sputtering target
US6596598B1 (en) 2000-02-23 2003-07-22 Advanced Micro Devices, Inc. T-shaped gate device and method for making
US6750126B1 (en) 2003-01-08 2004-06-15 Texas Instruments Incorporated Methods for sputter deposition of high-k dielectric films
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Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0704878A1 (en) * 1994-09-27 1996-04-03 Applied Materials, Inc. Uniform film thickness deposition of sputtered materials
JP3403550B2 (en) * 1995-06-29 2003-05-06 松下電器産業株式会社 Sputtering apparatus and sputtering method
US6042706A (en) * 1997-01-14 2000-03-28 Applied Materials, Inc. Ionized PVD source to produce uniform low-particle deposition
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DE19813075A1 (en) * 1998-03-25 1999-09-30 Leybold Ag Device for coating a substrate
US6585870B1 (en) 2000-04-28 2003-07-01 Honeywell International Inc. Physical vapor deposition targets having crystallographic orientations
US20060207872A1 (en) * 2005-03-21 2006-09-21 Sergey Mishin Dual magnetron thin film deposition system
US9194036B2 (en) * 2007-09-06 2015-11-24 Infineon Technologies Ag Plasma vapor deposition
KR101299755B1 (en) * 2008-10-16 2013-08-23 가부시키가이샤 아루박 Sputtering apparatus, thin film forming method and method for manufacturing field effect transistor
US9869013B2 (en) * 2014-04-25 2018-01-16 Applied Materials, Inc. Ion assisted deposition top coat of rare-earth oxide

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4604180A (en) * 1984-01-20 1986-08-05 Anelva Corporation Target assembly capable of attaining a high step coverage ratio in a magnetron-type sputtering device
US4606806A (en) * 1984-05-17 1986-08-19 Varian Associates, Inc. Magnetron sputter device having planar and curved targets
US4747926A (en) * 1985-02-08 1988-05-31 Hitachi, Ltd. Conical-frustum sputtering target and magnetron sputtering apparatus
US4957605A (en) * 1989-04-17 1990-09-18 Materials Research Corporation Method and apparatus for sputter coating stepped wafers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1595037A (en) * 1968-02-12 1970-06-08
US3669871A (en) * 1969-09-10 1972-06-13 Ibm Sputtering apparatus having a concave source cathode
US3988232A (en) * 1974-06-25 1976-10-26 Matsushita Electric Industrial Co., Ltd. Method of making crystal films
US4595482A (en) * 1984-05-17 1986-06-17 Varian Associates, Inc. Apparatus for and the method of controlling magnetron sputter device having separate confining magnetic fields to separate targets subject to separate discharges
US4834856A (en) * 1988-01-21 1989-05-30 Wehner Gottfried K Method and apparatus for sputtering a superconductor onto a substrate
JPH01268869A (en) * 1988-04-20 1989-10-26 Fuji Photo Film Co Ltd Sputtering device
JPH0452276A (en) * 1990-06-20 1992-02-20 Hitachi Nakaseiki Ltd Ion sputtering device and method
JP2902822B2 (en) * 1991-08-28 1999-06-07 株式会社日立製作所 Planar magnetron sputter electrode
JP3269834B2 (en) * 1991-11-26 2002-04-02 旭硝子株式会社 Sputtering apparatus and sputtering method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4604180A (en) * 1984-01-20 1986-08-05 Anelva Corporation Target assembly capable of attaining a high step coverage ratio in a magnetron-type sputtering device
US4606806A (en) * 1984-05-17 1986-08-19 Varian Associates, Inc. Magnetron sputter device having planar and curved targets
US4747926A (en) * 1985-02-08 1988-05-31 Hitachi, Ltd. Conical-frustum sputtering target and magnetron sputtering apparatus
US4957605A (en) * 1989-04-17 1990-09-18 Materials Research Corporation Method and apparatus for sputter coating stepped wafers

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5751607A (en) * 1995-03-30 1998-05-12 Nec Corporation Method of sputter deposition simulation by inverse trajectory calculation
US6009255A (en) * 1996-08-21 1999-12-28 Nec Corporation Method of deposition profile simulation
US5914018A (en) * 1996-08-23 1999-06-22 Applied Materials, Inc. Sputter target for eliminating redeposition on the target sidewall
US6059945A (en) * 1996-08-23 2000-05-09 Applied Materials, Inc. Sputter target for eliminating redeposition on the target sidewall
US6168690B1 (en) * 1997-09-29 2001-01-02 Lam Research Corporation Methods and apparatus for physical vapor deposition
US6500321B1 (en) * 1999-05-26 2002-12-31 Novellus Systems, Inc. Control of erosion profile and process characteristics in magnetron sputtering by geometrical shaping of the sputtering target
US6596598B1 (en) 2000-02-23 2003-07-22 Advanced Micro Devices, Inc. T-shaped gate device and method for making
US6419803B1 (en) 2001-03-16 2002-07-16 4Wave, Inc. System and method for making thin-film structures using a stepped profile mask
US6689255B2 (en) 2001-03-16 2004-02-10 4 Wave, Inc. System and method for making thin-film structures using a stepped profile mask
US6750126B1 (en) 2003-01-08 2004-06-15 Texas Instruments Incorporated Methods for sputter deposition of high-k dielectric films
US20100252416A1 (en) * 2009-04-03 2010-10-07 Applied Materials, Inc. Sputtering Target for PVD Chamber
US9752228B2 (en) * 2009-04-03 2017-09-05 Applied Materials, Inc. Sputtering target for PVD chamber
US10060024B2 (en) 2009-04-03 2018-08-28 Applied Materials, Inc. Sputtering target for PVD chamber
US8821701B2 (en) 2010-06-02 2014-09-02 Clifton Higdon Ion beam sputter target and method of manufacture
US20130309599A1 (en) * 2012-05-16 2013-11-21 Shin-Etsu Chemical Co., Ltd. Photomask blank manufacturing method, photomask blank, photomask, and pattern transfer method
US9689066B2 (en) * 2012-05-16 2017-06-27 Shin-Etsu Chemical Co., Ltd. Photomask blank manufacturing method, photomask blank, photomask, and pattern transfer method
US9911583B1 (en) * 2015-03-13 2018-03-06 HIA, Inc. Apparatus for enhanced physical vapor deposition
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US20210230739A1 (en) * 2020-01-27 2021-07-29 Applied Materials, Inc. Physical Vapor Deposition Apparatus And Methods With Gradient Thickness Target

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