US5055299A - Insecticidal aerosol - Google Patents
Insecticidal aerosol Download PDFInfo
- Publication number
- US5055299A US5055299A US07/281,407 US28140788A US5055299A US 5055299 A US5055299 A US 5055299A US 28140788 A US28140788 A US 28140788A US 5055299 A US5055299 A US 5055299A
- Authority
- US
- United States
- Prior art keywords
- aerosol
- chrysanthemate
- container
- prepared
- phenoxybenzyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Abstract
A mono-layer liquid phase type water-based insecticidal aerosol comprises (A) a base liquid for aerosol containing at least one specific pyrethroidal compound, a specific organic solvent and a buffer solution, which base liquid has a pH of from 7.0 to 9.0 and (B) dimethyl ether as a propellant. The aerosol according to the present invention has a long-term storage stability, as well as an excellent insecticidal activity and causes no degradiation of the container.
Description
The present invention relates to a mono-layer liquid phase type water-based insecticidal aerosol.
Recently, since water-based insecticidal aerosols can be averted from inflammability and toxicity to mammals, and since their manufacturing cost is relatively low, various developments have been forwarded on them.
However, most of the conventionally known water-based aerosols are the so-called two-layer liquid phase type water-based ones, that is, the liquid phase separates in two layers. Consequently, before the use of such aerosols, homogenizing the liquid phase by shaking is not avoidable.
To avoid the inconvenience, the so-called mono-layer liquid phase type water-based insecticidal aerosols have been developed. This type of aerosols can be prepared by dispersing an insecticidally active ingredient such as a pyrethroidal insecticidal compound in water with the aid of ethanol, etc. followed by blending thereto a propellant such as dimethyl ether, etc.
However, this type of insecticidal aerosols, when put to practical use, have serious problems that corrosion occurs on the inner wall of the aerosol container made of tinplate during the storage, which in turn causes the leak of the propellant gas, and that the effect of the aerosols is lowered by the decomposition of the insecticidal compound contained in the aerosols.
The present inventors have extensively studied to develop a mono-layer liquid phase type water-based insecticidal aerosol not causing such the problems, and as a result, have found that a mono-layer liquid phase type water-based insecticidal aerosol which comprises;
(A) a base liquid for aerosol containing as an insecticidally active ingredient at least one pyrethroidal compound selected from the following group I or a mixture of at least one pyrethroidal compound selected from the group I and at least one pyrethroidal compound selected from the following group II, an organic solvent selected from the following group III and a buffer for conditioning the pH of the base liquid from 7.0 to 9.0, and
(B) dimethyl ether as a propellant, can be suited to this object: Group I:
3-allyl-2-methyl-4-oxocyclopent-2-enyl chrysanthemate (allethrin),
2-methyl-4-oxo-3-propargylcyclopent-2-enyl chrysanthemate,
5-propargylfurfuryl chrysanthemate (furamethrin),
α-cyano-3-phenoxybenzyl chrysanthemate,
α-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate (fenpropathrin) and
2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether (ethofenprox);
Group II:
3-phenoxybenzyl 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate (permethrin),
3-phenoxybenzyl chrysanthemate (phenothrin),
5-benzyl-3-furylmethyl chrysanthemate (resmethrin),
1-ethynyl-2-methyl-2-pentenyl chrysanthemate,
2-(4-ethoxyphenyl)-5-(4-fluoro-3-phenoxy)-phenyl-2-methylpentane and
2-[1-methyl-2-(4-phenoxyphenoxy)ethoxy]-pyridine (pyriproxyfen);
Group III:
isopropyl alcohol,
n-propyl alcohol,
ethyl alcohol,
propylene glycol,
propylene glycol methyl ether,
dipropylene glycol methyl ether,
tripropylene glycol methyl ether and acetone.
The present inventors thus attained to the present invention.
The insecticidal aerosol of the present invention can be kept in a homogeneous liquid phase without causing separation in two layers even when it is stored for a long period of time at a relatively high temperature. In addition, there is no generation of rust on the wall of the aerosol container, and the insecticidally active ingredients remain stable.
Accordingly, the insecticidal aerosol of the present invention can be used as they are and requires no previous shaking at the time of application, and also they can exhibit an excellent effect as an insecticide.
Each of the pyrethroidal compounds belonging to the foregoing groups I and II used as the insecticidally active ingredient has steric and optical isomers. And these isomers and their mixtures may be used in the present invention.
The insecticidally active ingredient is usually blended in the aerosol in an amount of 0.01 to 2% by weight, preferably 0.03 to 1% by weight based on the total weight of the aerosol.
Specific examples of the buffer solutions are:
ammonium benzoate-NaOH buffer solution,
sodium benzoate-benzoic acid buffer solution,
ammonium benzoate-ammonia buffer solution,
ammonium benzoate-benzoic acid buffer solution,
KH2 PO4 -NaOH buffer solution,
NaOH-sodium bimaleate buffer solution,
tris.maleate*-NaOH buffer solution and
* mixture of tris(hydroxymethyl)aminomethane and maleic acid
Na2 CI3 -NaHCO3 buffer solution.
The buffer solution is incorporated in the aerosol in an amount of 10 to 55% by weight, preferably from 20 to 50% by weight based on the total weight of the aerosol.
The amount of dimethyl ether, a propellant, used is usually from 10 to 80% by weight, preferably from 30 to 60% by weight based on the total weight of the aerosol.
The amount of the organic solvent used is usually from 10 to 70% by weight, preferably from 18 to 40% by weight.
In the insecticidal aerosols of the present invention, surface active agents, synergists, perfumes, fungicides, etc. may be used together if necessary.
As the synergists, conventional ones such as piperonyl butoxide, S-421, MGK-264, Synepirin, etc. may be used.
The insecticidal aerosols of the present invention maybe prepared, for example, by the following method: Prescribed amounts of the insecticidally active ingredient, organic solvents and if necesssary, surface active agents, synergists, perfumes, fungicides, etc. are mixed at room temperature or under heating and put in an aerosol container; a prescribed amount of the buffer solution having a prescribed pH value is added, and the base liquid for aerosol thus obtained is conditioned so as to have a pH in a range of from 7.0 to 9.0; and after mounting a valve portion on the aerosol container, dimethyl ether is charged into the container under pressure through the valve portion.
The present invention will be illustrated in more detail with reference to the following examples and comparative examples, but it is not limited to these examples.
In the following examples, parts mean a part by weight.
0.3 Part of allethrin and 24.7 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 30.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 8.5. Thus, a base liquid for aerosol having a pH of 8.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 45.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the mixture was not recognized to be separated, remaining homogeneous and transparent. The content of allethrin in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 95.0%.
The generation of rust on the wall of the aerosol container was not observed.
Apparatus: FID
Column: 2% DEGS [Chromosorb W (AW, DMCS, 100-120 mesh)]. Glass column of 1.1 m×3 mmφ in size.
Column temperature: 190° C.
N2 flow rate: 50 ml/min
Internal standard: Fluoranthene
An aerosol was prepared in the same manner as in Example 1 except that allethrin was replaced by (S)-2-methyl-4-oxo-3-propargylcyclopent-2-enyl (1R)-cis,trans-chrysanthemate (prallethrin).
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol mixture was not recognized to be separated, remaining homogeneous and transparent. The content of prallethrin in the aerosol was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of prallethrin was found to be 96.7%. The generation of rust on the wall of the aerosol container was not observed.
An aerosol was prepared in the same manner as in Example 1 except that fenpropathrin was used in place of allethrin.
The insecticidal aerosol of the present invention thus obtained was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of fenpropathrin in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of fenpropathrin was found to be 95.0%. The generation of rust on the wall of the aerosol container was not observed.
Apparatus: FID .
Column: 3% XE-60 [Chromosorb W (AW, DMCS, 60-80 mesh)]. Glass column of 1.1 m×3 mmφ in size.
Column temperature: 220° C.
N2 flow rate: 50 ml/min
Internal standard: Diphenyl phthalate.
0.3 Part of (RS)-α-cyano-3-phenoxybenzyl (1R)-cis,trans-chrysanthemate (cyphenothrin), 0.5 part of sorbitan monolaurate and 24.2 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 30.0 parts of an ammonium benzoate-NaOH buffer solution, which had been prepared by adding a 10% w/w aqueous NaOH solution to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 8.5. Thus, a base liquid for aerosol having a pH of 8.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 45.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of cyphenothrin in the solution was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of cyphenothrin was found to be 98.2%.
The generation of rust on the wall of the aerosol container was not observed.
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: Tetramethrin .
An aerosol was prepared in the same manner as in Example 4 except that furamethrin was used in place of cyphenothrin.
The insecticidal aerosol of the present invention thus obtained was stored at 45° C. for 3 months. Then the aerosol solution in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of furamethrin in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of furamethrin was found to be 92.9%. The generation of rust on the wall of the aerosol container was not observed.
Apparatus and N2 flow rate: Same as in Example 1.
Column: 5% XE-60 [Uniport HP (60-80 mesh)].
Glass column of 1.1 m ×3 mmφ in size.
Column temperature: 160° C.
Internal standard: Dibutyl phthalate.
An aerosol was prepared in the same manner as in Example 4 except that ethofenprox was used in place of cyphenothrin.
The insecticidal aerosol of the present invention thus obtained was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of ethofenprox in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of ethofenprox was found to be 93.7%. The generation of rust on the wall of the aerosol container was not observed.
Apparatus and N2 flow rate: Same as in Example 1.
Column: 5% OV-101 [Uniport HP (100-120 mesh)].
Glass column of 1.1 m×3 mmφ in size.
Column temperature: 260° C.
Internal standard: Triphenyl phosphate.
An aerosol was prepared in the same manner as in Example 1 except that tetramethrin was used in place of allethrin.
The insecticidal aerosol thus obtained was stored at 45° C. for 1 month, and the content of tetramethrin in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of tetramethrin was found to be 50.1%
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: Phenothrin.
An aerosol was prepared in the same manner as in Example 1 except that fenitrothion was used in place of allethrin.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months, and the content of fenitrothion in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of fenitrothion was found to be 50.1%.
Apparatus column and N2 flow rate: Same as in Example 1.
Column temperature: 195° C.
Internal standard: Cyanophos.
An aerosol was prepared in the same manner as in Example 4 except that deltamethrin was used in place of cyphenothrin.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months, and the content of deltamethrin in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of deltamethrin was found to be 44.3%.
Apparatus and N2 flow rate: Same as in Example 1.
Column: 3% OV-101 [Sumikasorb HP (100 120 mesh)].
Glass column of 1.1 m×3 mmφ in size.
Column temperature: 230° C.
Internal standard: Phenylbiphenylyl-1,3,4-oxadiazole
An aerosol was prepared in the same manner as in Example 4 except that propoxur was used in place of cyphenothrin.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months, and the content of propoxur in the aerosol was determined by gas chromatography under the following conditions and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of propoxur was found to be 69.7%.
Apparatus and N2 flow rate: Same as in Example 1.
Column: 2% XE-60 [Chromosorb W (HP, 100-120 mesh)]. Glass column of 1.1 m ×3 mmφ in size.
Column temperature: 170° C.
Internal standard: n-Butyl sebacate
An aerosol was prepared in the same manner as in Example 4 except that deionized water was used in place of the buffer solution.
On storing the insecticidal aerosol thus obtained at 45° C. for 3 months, the generation of rust on the wall of the aerosol container was so remarkable that pin holes were bored through the wall.
0.4 Part of allethrin, 0.1 part of resmethrin, 0.5 part of sorbitan monolaurate and 19.0 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 20.0 parts of an ammonium benzoate-NaOH buffer solution, which had been prepared by adding a 10% w/w aqueous NaOH solution to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 9.5. Thus, a base liquid for aerosol having a pH of 9.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 60.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months, Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The contents of allethrin and resmethrin in the aerosol were determined by gas chromatography under the following conditions and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of allethrin and resmethrin were found to be 94.5% and 99.8%, respectively.
The generation of rust on the wall of the aerosol container was not observed.
(1) Allethrin:
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: Phenothrin.
(2) Resmethrin:
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: Phenothrin
0.1 Part of prallethrin, 0.1 part of cyphenothrin and 39.8 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 20.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the mixed solution to 8.5. Thus, a base liquid for aerosol having a pH of 8.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 40.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The contents of prallethrin and cyphenothrin in the aerosol were determined by gas chromatography in the same manner as in Example 4 and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of prallethrin and cyphenothrin were found to be 94.3% and 95.2%, respectively.
The generation of rust on the wall of the aerosol container was not observed.
0.4 Part of allethrin, 0.1 part of permethrin and 19.5 parts of isopropyl alcohol were well mixed under heating and charged into an aerosol container made of tinplate. To the mixture were added 50.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the mixed solution to 8.5. Thus, a base liquid for aerosol having a pH of 8.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 30.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The contents of allethrin and permethrin in the aerosol were determined by gas chromatography under the following conditions and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of allethrin and permethrin were found to be 94.1% and 98.0%. respectively.
The generation of rust on the wall of the aerosol container was not observed.
(1) Allethrin:
Apparatus, column, N2 flow rate and internal
standard: Same as in Example 1.
Column temperature: 210° C.
(2) Permethrin:
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: tetramethrin.
0.3 Part of furamethrin, 0.1 part of phenothrin, 0.5 part of sorbitan monolaurate and 39.1 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 30.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 8.5. Thus, a base liquid for aerosol having a pH of 8.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 30.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The contents of furamethrin and phenothrin in the aerosol were determined by gas chromatography under the following conditions and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of furamethrin and phenothrin were found to be 93.3% and 94.0%, respectively.
The generation of rust on the wall of the aerosol container was not observed.
(1) Furamethrin:
Apparatus, column, column temperature, N2 flow rate and internal standard: Same as in Example 5.
(2) Phenothrin:
Apparatus, column and N2 flow rate: Same as in Example 1.
Column temperature: 210° C.
Internal standard: Tetramethrin
An aerosol was prepared in the same manner as in Example 8 except that an ammonium benzoate-ammonia buffer solution having a pH of 10.5 was used, and that the pH of the base liquid for aerosol was conditioned to 10.0.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months, and the contents of prallethrin and cyphenothrin in the aerosol were determined by gas chromatography in the same manner as in Example 8 and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of prallethrin and cyphenothrin were found to be 38.7% and 46.7%, respectively.
An aerosol was prepared in the same manner as in Example 8 except that an ammonium benzoate-ammonia buffer solution having a pH of 4.5 was used, and that the pH of the base liquid for aerosol was conditioned to 6.0.
On storing the insecticidal aerosol thus obtained at 45° C. for 3 months, the generation of rust on the wall of the aerosol container was so remarkable that pin holes were bored through the wall.
0.6 Part of allethrin, 0.2 part of phenothrin and 24.2 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 30.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 9.5. Thus, a base liquid for aerosol having a pH of 9.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 45.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The contents of allethrin and phenothrin in the aerosol were determined by gas chromatography under the following conditions and compared with the contents which had been determined immediately after preparation of the aerosol. As a result, the percentages of the remainders of allethrin and phenothrin were found to be 95.6% and 97.8%, respectively.
The generation of rust on the wall of the aerosol container was not observed.
(1) Allethrin:
Apparatus, column, N2 flow rate and internal standard: Same as in Example 1.
Column temperature: 200° C.
(2) Phenothrin:
25 Apparatus, column, N2 flow rate and internal standard: Same as in Example 1.
Column temperature: 200° C.
0.3 Part of allethrin and 24.7 parts of isopropyl alcohol were well mixed under heating and introduced into an aerosol container made of tinplate. To the mixture were added 30.0 parts of an ammonium benzoate-ammonia buffer solution, which had been prepared by adding a 29% aqueous ammonia to a 1.0% w/w aqueous ammonium benzoate solution and then conditioning the pH of the solution to 9.5. Thus, a base liquid for aerosol having a pH of 9.0 was prepared. Thereafter, a valve portion was mounted on the aerosol container, and 45.0 parts of dimethyl ether were charged into the container under pressure through the valve portion.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of allethrin in the solution was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 92 3%.
The generation of rust on the wall of the aerosol container was not observed.
An aerosol was prepared in the same manner as in Example 12 except that ethyl alcohol was used in place of isopropyl alcohol.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of allethrin in the aerosol was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 93.3%.
The generation of rust on the wall of the aerosol container was not observed.
An aerosol was prepared in the same manner as in Example 12 except that propylene glycol was used in place of isopropyl alcohol.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of allethrin in the aerosol was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 90 3%.
The generation of rust on the wall of the aerosol container was not observed.
An aerosol was prepared in the same manner as in Example 12 except that tripropylene glycol methyl ether was used in place of isopropyl alcohol.
The insecticidal aerosol of the present invention thus prepared was stored at 45° C. for 3 months. Then the aerosol in the container was observed. It was found that the aerosol was not recognized to be separated, remaining homogeneous and transparent. The content of allethrin in the aerosol was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 93.8%.
The generation of rust on the wall of the aerosol container was not observed.
An aerosol was prepared in the same manner as in Example 12 except that hexylene glycol was used in place of isopropyl alcohol.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months. Then the content of allethrin in the aerosol was determined by gas chromatography as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 79.8%.
An aerosol was prepared in the same manner as in Example 12 except that methyl cellosolve was used in place of isopropyl alcohol.
The insecticidal aerosol thus obtained was stored at 45° C. for 3 months. Then the content of allethrin in the aerosol was determined by gas chromatography in the same manner as in Example 1 and compared with the content which had been determined immediately after preparation of the aerosol. As a result, the percentage of the remainder of allethrin was found to be 76.3%.
Claims (5)
1. A mono-layer liquid phase type water-based insecticidal aerosol which comprises
(A) a base liquid for aerosol containing as an insecticidally active ingredient at least one pyrethroidal compound selected from the following group I or a mixture of at least one pyrethroidal compound of the group I and at least one pyrethroidal compound selected from the following group II, an organic solvent selected from the following group III and a buffer solution for conditioning the pH of the base liquid from 7.0 to 9.0, and
(B) dimethyl ether as a propellant. Group I:
3-allyl-2-methyl-4-oxocyclopent-2-enyl chrysanthemate (allethrin),
2-methyl-4-oxo-3-propargylcyclopent-2-enyl chrysanthemate,
5-propargylfurfuryl chrysanthemate (furamethrin),
α-cyano-3-phenoxybenzyl chrysanthemate,
α-cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate (fenpropathrin) and
2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether (ethofenprox); Group II:
3-phenoxybenzyl 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate (permethrin),
3-phenoxybenzyl chrysanthemate (phenothrin),
5-benzyl-3-furylmethyl chrysanthemate (resmethrin),
1-ethynyl-2-methyl-2-pentenyl chrysanthemate,
2-(4-ethoxyphenyl)-5-(4-fluoro-3-phenoxy)-phenyl-2-methylpentane and
2-[1-methyl-2-(4-phenoxyphenoxy)ethoxy]-pyridine (pyriproxyfen);
Group III:
isopropyl alcohol,
n-propyl alcohol,
ethyl alcohol,
propylene glycol,
propylene glycol methyl ether,
dipropylene glycol methyl ether,
tripropylene glycol methyl ether and acetone.
2. An aerosol according to claim 1, wherein dimethyl ether is blended in the aerosol as a propellant in an amount of 10 to 80% by weight based on the total weight of the aerosol.
3. An aerosol according to claim 1, which comprises an organic solvent selected from the group consisting of isopropyl alcohol, n-propyl alcohol, ethyl alcohol, propylene glycol, propylene glycol methyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether and acetone in an amount of from 10 to 70% by weight based on the total weight of the aerosol.
4. An aerosol according to claim 1, which comprises the buffer solution in an amount of from 10 to 55% by weight based on the total weight of the aerosol.
5. An aerosol according to claim 1, which comprises said insecticidally active ingredient in an amount of from 0.01 to 2% by weight based on the total weight of the aerosol.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31818387 | 1987-12-15 | ||
| JP62-318183 | 1987-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US5055299A true US5055299A (en) | 1991-10-08 |
Family
ID=18096383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US07/281,407 Expired - Fee Related US5055299A (en) | 1987-12-15 | 1988-12-08 | Insecticidal aerosol |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5055299A (en) |
| EP (1) | EP0320909B1 (en) |
| KR (1) | KR960011192B1 (en) |
| AU (1) | AU605939B2 (en) |
| BE (1) | BE1001444A3 (en) |
| BR (1) | BR8806603A (en) |
| CA (1) | CA1308650C (en) |
| CH (1) | CH676907A5 (en) |
| DE (1) | DE3874866T2 (en) |
| ES (1) | ES2009452A6 (en) |
| FR (1) | FR2624344B1 (en) |
| GB (1) | GB2213726B (en) |
| IT (1) | IT1224810B (en) |
| MX (1) | MX14190A (en) |
| MY (1) | MY100350A (en) |
| NZ (1) | NZ227223A (en) |
| ZA (1) | ZA889126B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5620678A (en) * | 1991-04-22 | 1997-04-15 | S. C. Johnson & Son, Inc. | Water-solvent-based aerosol insecticide |
| US5776477A (en) * | 1996-07-08 | 1998-07-07 | Ryder; Kathleen A. | Organic insect repellent |
| US6180088B1 (en) * | 1998-11-17 | 2001-01-30 | Nihon Nohyaku Co., Ltd. | Foamable aerosol agricultural-chemical composition and method of controlling diseases and insect pests |
| WO2002043483A2 (en) * | 2000-11-28 | 2002-06-06 | Avon Products, Inc. | Aerosol insect repellent composition having low voc content and method of applying same to the skin |
| US7226579B1 (en) * | 1999-10-01 | 2007-06-05 | Daizo Co., Ltd. | Aerosol composition |
| CN109258680A (en) * | 2018-11-06 | 2019-01-25 | 成都彩虹电器（集团）中南有限公司 | A kind of water base aerosol of homogeneous phase transparent and preparation method thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3052142B2 (en) * | 1989-09-14 | 2000-06-12 | 住友化学工業株式会社 | Insecticidal and acaricidal compositions |
| WO1994003056A1 (en) * | 1992-07-31 | 1994-02-17 | Ian Alexander Edwin Maccormick | Aerosol insecticide composition |
| CO4750805A1 (en) * | 1995-12-13 | 1999-03-31 | Sumitomo Chemical Co | SHAMPOO COMPOUND |
| JP3855311B2 (en) * | 1996-08-07 | 2006-12-06 | 住友化学株式会社 | Aerosol composition |
| KR100471016B1 (en) * | 1996-08-07 | 2005-07-12 | 스미또모 가가꾸 가부시키가이샤 | Insecticidal aerosol compositions and pesticidal compositions for preparing them |
| KR20080109012A (en) * | 2006-04-05 | 2008-12-16 | 에스.씨. 존슨 앤드 선, 인코포레이티드 | High concentration single phase gycol aerosol air sanitizer with dimethyl ether propellant/solvent |
| BE1027223B1 (en) * | 2019-04-25 | 2020-11-23 | Group Riem | Insecticidal composition |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5495737A (en) * | 1977-02-22 | 1979-07-28 | Dai Ichi Seiyaku Co Ltd | Stabilized composition containing carpronium chloride |
| EP0006212A1 (en) * | 1978-06-20 | 1980-01-09 | Airwick AG | System of pulverisation in the form of an aerosol |
| EP0032779A2 (en) * | 1980-01-21 | 1981-07-29 | Pfw (Nederland) B.V. | Novel method for preparation of homogeneous dimethylether-propelled water-based aerosols |
| EP0069906A2 (en) * | 1981-07-09 | 1983-01-19 | Bayer Ag | Water-based aerosol formulations |
| US4450253A (en) * | 1981-03-03 | 1984-05-22 | Ccl Industries Inc. | Propellant-active carrier system for water-based paints |
| US4518734A (en) * | 1981-06-22 | 1985-05-21 | Rust-Oleum Corporation | Water based aerosol coatings |
| JPS60104003A (en) * | 1983-11-09 | 1985-06-08 | Fumakiraa Kk | Aerosol pesticide composition having low phytotoxicity |
| JPS60104203A (en) * | 1983-11-11 | 1985-06-08 | Canon Inc | Signal processing circuit of semiconductor position detecting element |
| JPS60104004A (en) * | 1983-11-09 | 1985-06-08 | Fumakiraa Kk | Aerosol psticide composition having low toxicity |
| JPS6145601A (en) * | 1984-08-09 | 1986-03-05 | Fujitsu Ltd | Formation of microwave integrated circuit |
| US4604226A (en) * | 1985-03-22 | 1986-08-05 | E. I. Du Pont De Nemours And Company | Aerosol corrosion inhibitors |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU605652B2 (en) * | 1987-12-15 | 1991-01-17 | Sumitomo Chemical Company, Limited | Insecticidal aerosol |
-
1988
- 1988-11-29 AU AU26344/88A patent/AU605939B2/en not_active Ceased
- 1988-12-02 MY MYPI88001403A patent/MY100350A/en unknown
- 1988-12-06 NZ NZ227223A patent/NZ227223A/en unknown
- 1988-12-06 ZA ZA889126A patent/ZA889126B/en unknown
- 1988-12-06 FR FR888815941A patent/FR2624344B1/en not_active Expired - Fee Related
- 1988-12-08 US US07/281,407 patent/US5055299A/en not_active Expired - Fee Related
- 1988-12-09 GB GB8828850A patent/GB2213726B/en not_active Expired - Fee Related
- 1988-12-12 CA CA000585687A patent/CA1308650C/en not_active Expired - Fee Related
- 1988-12-12 CH CH4582/88A patent/CH676907A5/fr not_active IP Right Cessation
- 1988-12-13 IT IT8848646A patent/IT1224810B/en active
- 1988-12-13 ES ES8803781A patent/ES2009452A6/en not_active Expired
- 1988-12-14 DE DE8888120905T patent/DE3874866T2/en not_active Expired - Fee Related
- 1988-12-14 BE BE8801404A patent/BE1001444A3/en not_active IP Right Cessation
- 1988-12-14 BR BR888806603A patent/BR8806603A/en not_active Application Discontinuation
- 1988-12-14 EP EP88120905A patent/EP0320909B1/en not_active Expired - Lifetime
- 1988-12-15 MX MX1419088A patent/MX14190A/en unknown
- 1988-12-15 KR KR1019880016735A patent/KR960011192B1/en active IP Right Grant
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5495737A (en) * | 1977-02-22 | 1979-07-28 | Dai Ichi Seiyaku Co Ltd | Stabilized composition containing carpronium chloride |
| EP0006212A1 (en) * | 1978-06-20 | 1980-01-09 | Airwick AG | System of pulverisation in the form of an aerosol |
| EP0032779A2 (en) * | 1980-01-21 | 1981-07-29 | Pfw (Nederland) B.V. | Novel method for preparation of homogeneous dimethylether-propelled water-based aerosols |
| US4450253A (en) * | 1981-03-03 | 1984-05-22 | Ccl Industries Inc. | Propellant-active carrier system for water-based paints |
| US4518734A (en) * | 1981-06-22 | 1985-05-21 | Rust-Oleum Corporation | Water based aerosol coatings |
| EP0069906A2 (en) * | 1981-07-09 | 1983-01-19 | Bayer Ag | Water-based aerosol formulations |
| JPS60104003A (en) * | 1983-11-09 | 1985-06-08 | Fumakiraa Kk | Aerosol pesticide composition having low phytotoxicity |
| JPS60104004A (en) * | 1983-11-09 | 1985-06-08 | Fumakiraa Kk | Aerosol psticide composition having low toxicity |
| JPS60104203A (en) * | 1983-11-11 | 1985-06-08 | Canon Inc | Signal processing circuit of semiconductor position detecting element |
| JPS6145601A (en) * | 1984-08-09 | 1986-03-05 | Fujitsu Ltd | Formation of microwave integrated circuit |
| US4604226A (en) * | 1985-03-22 | 1986-08-05 | E. I. Du Pont De Nemours And Company | Aerosol corrosion inhibitors |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5620678A (en) * | 1991-04-22 | 1997-04-15 | S. C. Johnson & Son, Inc. | Water-solvent-based aerosol insecticide |
| US5776477A (en) * | 1996-07-08 | 1998-07-07 | Ryder; Kathleen A. | Organic insect repellent |
| US6180088B1 (en) * | 1998-11-17 | 2001-01-30 | Nihon Nohyaku Co., Ltd. | Foamable aerosol agricultural-chemical composition and method of controlling diseases and insect pests |
| US7226579B1 (en) * | 1999-10-01 | 2007-06-05 | Daizo Co., Ltd. | Aerosol composition |
| WO2002043483A2 (en) * | 2000-11-28 | 2002-06-06 | Avon Products, Inc. | Aerosol insect repellent composition having low voc content and method of applying same to the skin |
| WO2002043483A3 (en) * | 2000-11-28 | 2002-08-22 | Avon Prod Inc | Aerosol insect repellent composition having low voc content and method of applying same to the skin |
| US6969521B1 (en) * | 2000-11-28 | 2005-11-29 | Avon Products, Inc. | Aerosol insect repellent composition having low VOC content and method of applying same to the skin |
| CN109258680A (en) * | 2018-11-06 | 2019-01-25 | 成都彩虹电器（集团）中南有限公司 | A kind of water base aerosol of homogeneous phase transparent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2009452A6 (en) | 1989-09-16 |
| AU605939B2 (en) | 1991-01-24 |
| MX14190A (en) | 1993-10-01 |
| GB8828850D0 (en) | 1989-01-18 |
| NZ227223A (en) | 1990-05-28 |
| EP0320909A1 (en) | 1989-06-21 |
| MY100350A (en) | 1990-10-28 |
| BE1001444A3 (en) | 1989-10-31 |
| KR960011192B1 (en) | 1996-08-21 |
| EP0320909B1 (en) | 1992-09-23 |
| FR2624344A1 (en) | 1989-06-16 |
| GB2213726A (en) | 1989-08-23 |
| DE3874866T2 (en) | 1993-03-11 |
| IT1224810B (en) | 1990-10-24 |
| AU2634488A (en) | 1989-06-15 |
| ZA889126B (en) | 1989-08-30 |
| BR8806603A (en) | 1989-08-22 |
| CH676907A5 (en) | 1991-03-28 |
| KR890009264A (en) | 1989-08-01 |
| GB2213726B (en) | 1991-07-10 |
| DE3874866D1 (en) | 1992-10-29 |
| IT8848646A0 (en) | 1988-12-13 |
| CA1308650C (en) | 1992-10-13 |
| FR2624344B1 (en) | 1990-06-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5064639A (en) | Insecticidal aerosol | |
| US5055299A (en) | Insecticidal aerosol | |
| US5028623A (en) | Insecticidal transparent emulsion | |
| US5192793A (en) | Plant protective microemulsion composition comprising pyrethroids | |
| EP0823213B1 (en) | Insecticidal aerosol composition and insecticidal composition for preparation of same | |
| US5190745A (en) | Insecticidal compositions | |
| Barlow et al. | Some laboratory investigations relevant to the possible use of new pyrethroids in control of mosquitoes and tsetse flies | |
| JP3008603B2 (en) | Insecticidal composition | |
| EP0064803B1 (en) | Insecticidal compositions | |
| JPH0768092B2 (en) | Aerosol insecticide | |
| US5846997A (en) | Liquid formulations | |
| JPH07121848B2 (en) | Aerosol insecticide | |
| JP2000080006A (en) | Insecticidal aerosol composition | |
| JPS6054928B2 (en) | water-based insecticide | |
| KR0161534B1 (en) | Insecticidal compositions | |
| 堂原一伸 et al. | Water-based aerosol insecticides containing dimethyl ether as a propellant | |
| CN113518556A (en) | One-pack aqueous aerosol composition | |
| MXPA97006012A (en) | Insecticide composition in aerosol and compositioninsecticide for the preparation of the | |
| HU189820B (en) | Arthropocide preparations with improved duration of effect containing 4-amino-benzoic acid-ester-derivatives as photostabilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: SUMITOMO CHEMICAL COMPANY, LIMITED, A CORP. OF JAP Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:DOHARA, KAZUNOBU;MATSUNAGA, TADAHIRO;SHIRAISHI, MOTOMITSU;AND OTHERS;SIGNING DATES FROM 19881124 TO 19881130;REEL/FRAME:004981/0780 Owner name: SUMITOMO CHEMICAL COMPANY, LIMITED, 15, KITAHAMA-5 Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:DOHARA, KAZUNOBU;MATSUNAGA, TADAHIRO;SHIRAISHI, MOTOMITSU;AND OTHERS;REEL/FRAME:004981/0780;SIGNING DATES FROM 19881124 TO 19881130 |
|
| FPAY | Fee payment |
Year of fee payment: 4 |
|
| REMI | Maintenance fee reminder mailed | ||
| LAPS | Lapse for failure to pay maintenance fees | ||
| FP | Lapsed due to failure to pay maintenance fee |
Effective date: 19991008 |
|
| STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |