US4923684A - Tripolyphosphate-containing anti-calculus toothpaste - Google Patents
Tripolyphosphate-containing anti-calculus toothpaste Download PDFInfo
- Publication number
- US4923684A US4923684A US07/348,805 US34880589A US4923684A US 4923684 A US4923684 A US 4923684A US 34880589 A US34880589 A US 34880589A US 4923684 A US4923684 A US 4923684A
- Authority
- US
- United States
- Prior art keywords
- toothpaste
- fluoride
- alkali metal
- tripolyphosphate
- toothpaste according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000606 toothpaste Substances 0.000 title claims abstract description 84
- 229940034610 toothpaste Drugs 0.000 title claims abstract description 71
- 235000019832 sodium triphosphate Nutrition 0.000 title claims abstract description 44
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 title claims description 13
- 230000002272 anti-calculus Effects 0.000 title abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 26
- 238000003860 storage Methods 0.000 claims abstract description 19
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 12
- -1 alkali metal tripolyphosphate Chemical class 0.000 claims abstract description 12
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 claims abstract description 9
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 claims abstract description 9
- 229940125532 enzyme inhibitor Drugs 0.000 claims abstract description 7
- 239000002532 enzyme inhibitor Substances 0.000 claims abstract description 7
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical group [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 12
- 208000006558 Dental Calculus Diseases 0.000 claims description 10
- 206010044029 Tooth deposit Diseases 0.000 claims description 10
- 229940122907 Phosphatase inhibitor Drugs 0.000 claims description 7
- 229910001515 alkali metal fluoride Inorganic materials 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011775 sodium fluoride Substances 0.000 claims description 6
- 235000013024 sodium fluoride Nutrition 0.000 claims description 6
- 239000003906 humectant Substances 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 3
- 210000000214 mouth Anatomy 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920000388 Polyphosphate Polymers 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 239000001205 polyphosphate Substances 0.000 description 5
- 235000011176 polyphosphates Nutrition 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003082 abrasive agent Substances 0.000 description 3
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 229940091249 fluoride supplement Drugs 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229960004029 silicic acid Drugs 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000000675 anti-caries Effects 0.000 description 2
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 2
- 229940043256 calcium pyrophosphate Drugs 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000019821 dicalcium diphosphate Nutrition 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013355 food flavoring agent Nutrition 0.000 description 2
- 235000003599 food sweetener Nutrition 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 210000003296 saliva Anatomy 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000003765 sweetening agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002882 anti-plaque Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004075 cariostatic agent Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000551 dentifrice Substances 0.000 description 1
- 239000003975 dentin desensitizing agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 description 1
- 229960002799 stannous fluoride Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/78—Enzyme modulators, e.g. Enzyme agonists
- A61K2800/782—Enzyme inhibitors; Enzyme antagonists
Abstract
Description
TABLE ______________________________________ Percent STP As % Of Initial STP After Toothpaste* 1 year 2 years 3 years 4 years ______________________________________ A (pH 9/4.3% STP) 98 96 94 91 B (pH 7/4.3% STP) 96 93 89 85 C (pH 9/3.0% STP) 90 80 69 59 D (pH 7/2.8% STP) 85 70 55 39 ______________________________________ *The pH's reported are nominal values.
______________________________________ Ingredients % W/W ______________________________________ PEG-8(CTFA) 3.000 Xanthan Gum 0.700 D&C Red #30 Lake 0.017 FD&C Blue #1 (0.2%) 0.168 Yellow #10 (0.02%) 0.137 Deionized Water 24.206 Sodium Fluoride 0.243 Sorbitol (70%) 29.609 Sodium Saccharin 0.214 Hydrated Silica (Thickener) 8.000 Hydrated Silica (Dental Abrasive) 14.000 Titanium Dioxide 0.956 Glycerin 99% 10.000 Sodium Tripolyphosphate (Food Grade)* 5.000 Sodium Hydroxide (25%) 1.800 Flavor 0.800 Sodium Lauryl Sulfate 1.150 TOTAL 100.000% ______________________________________ *Food grade STP has a nominal purity of 92%.
Claims (20)
Priority Applications (22)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/348,805 US4923684A (en) | 1989-05-08 | 1989-05-08 | Tripolyphosphate-containing anti-calculus toothpaste |
US07/407,336 US4985236A (en) | 1989-05-08 | 1989-09-14 | Tripolyphosphate-containing anti-calculus toothpaste |
ZA903439A ZA903439B (en) | 1989-05-08 | 1990-05-07 | Oral hygiene compositions |
GR900100336A GR900100336A (en) | 1989-05-08 | 1990-05-07 | New compositions |
AU54788/90A AU5478890A (en) | 1989-05-08 | 1990-05-07 | Novel compositions |
BE9000478A BE1003125A3 (en) | 1989-05-08 | 1990-05-07 | NEW COMPOSITIONS. |
FR9005722A FR2646601B1 (en) | 1989-05-08 | 1990-05-07 | TOOTHPASTE AND ORAL COMPOSITIONS USEFUL FOR INHIBITING DENTAL CALCULATIONS |
CA002016221A CA2016221C (en) | 1989-05-08 | 1990-05-07 | Compositions |
PT199093969A PT93969A (en) | 1989-05-08 | 1990-05-07 | Process for the preparation of a composition for oral hygiene comprising a tri-phospholiphosphate salt |
JP2116973A JP2802285B2 (en) | 1989-05-08 | 1990-05-08 | Method for stabilizing toothpaste compositions |
ES90304950T ES2060037T3 (en) | 1989-05-08 | 1990-05-08 | COMPOSITIONS OF ANTI-TARE TOOTHPASTS WITH IMPROVED STORAGE STABILITY. |
CY193790A CY1937A (en) | 1989-05-08 | 1990-05-08 | Oral hygiene compositions containing polyphosphate salts |
DK90304950.0T DK0397452T3 (en) | 1989-05-08 | 1990-05-08 | Hitherto unknown preparations |
GB9010258A GB2232591B (en) | 1989-05-08 | 1990-05-08 | Toothpaste composition comprising tripolyphosphate salt |
DE90304950T DE69003585T2 (en) | 1989-05-08 | 1990-05-08 | Anti-tartar toothpastes with increased shelf life. |
CY193890A CY1938A (en) | 1989-05-08 | 1990-05-08 | Anti-calculus oral hygiene compositions |
AT90304950T ATE95054T1 (en) | 1989-05-08 | 1990-05-08 | ANTI-TARTAR TOOTHPASTE WITH EXTENDED SHELF LIFE. |
IT04792490A IT1246991B (en) | 1989-05-08 | 1990-05-08 | COMPOSITION FOR ORAL HYGIENE. |
EP90304950A EP0397452B1 (en) | 1989-05-08 | 1990-05-08 | Anti-calculus toothpaste compositions having improved shelf-life |
GB9303458A GB2262447B (en) | 1989-05-08 | 1993-02-19 | Anti-calculus oral hygiene compositions |
HK218796A HK218796A (en) | 1989-05-08 | 1996-12-24 | Anti-calculus oral hygiene compositions |
HK218896A HK218896A (en) | 1989-05-08 | 1996-12-24 | Toothpaste composition comprising tripolyphosphate salt |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/348,805 US4923684A (en) | 1989-05-08 | 1989-05-08 | Tripolyphosphate-containing anti-calculus toothpaste |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/407,336 Continuation-In-Part US4985236A (en) | 1989-05-08 | 1989-09-14 | Tripolyphosphate-containing anti-calculus toothpaste |
Publications (1)
Publication Number | Publication Date |
---|---|
US4923684A true US4923684A (en) | 1990-05-08 |
Family
ID=23369616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/348,805 Expired - Lifetime US4923684A (en) | 1989-05-08 | 1989-05-08 | Tripolyphosphate-containing anti-calculus toothpaste |
Country Status (2)
Country | Link |
---|---|
US (1) | US4923684A (en) |
ZA (1) | ZA903439B (en) |
Cited By (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4960586A (en) * | 1989-11-15 | 1990-10-02 | Gillette Canada Inc. | Aqueous stannous fluoride non-abrasive home treatment gel compositions |
US4961924A (en) * | 1989-11-15 | 1990-10-09 | Gillette Canada Inc. | Stabilized stannous fluoride toothpaste |
US4970065A (en) * | 1989-11-15 | 1990-11-13 | Gillette Canada Inc. | Stabilized aqueous stannous fluoride mouthwash |
US4985236A (en) * | 1989-05-08 | 1991-01-15 | Beecham Inc. | Tripolyphosphate-containing anti-calculus toothpaste |
US5009884A (en) * | 1989-11-15 | 1991-04-23 | Gillette Canada Inc. | Stabilized aqueous stannous fluoride mouthwash |
US5009883A (en) * | 1989-11-15 | 1991-04-23 | Gillette Canada Inc. | Aqueous stannous fluoride non-abrasive home treatment gel compositions |
US5017362A (en) * | 1985-09-13 | 1991-05-21 | Colgate-Palmolive Company | Anticalculus oral composition |
US5017363A (en) * | 1989-11-15 | 1991-05-21 | Gillette Canada, Inc. | Stabilized stannous fluoride toothpaste |
US5096701A (en) * | 1990-12-18 | 1992-03-17 | The Procter & Gamble Company | Oral compositions |
US5139769A (en) * | 1985-09-13 | 1992-08-18 | Colgate-Palmolive Company | Anticalculus oral composition |
US5145667A (en) * | 1990-03-29 | 1992-09-08 | Beecham Inc. | Compositions |
US5176900A (en) * | 1990-12-18 | 1993-01-05 | The Procter & Gamble Company | Compositions for reducing calculus |
US5211559A (en) * | 1991-07-18 | 1993-05-18 | Gillette Canada Inc. | Dental treatment tray for holding medicament gel |
US5283924A (en) * | 1990-09-21 | 1994-02-08 | Gillette Canada, Inc. | Interdental foam brush and treatment gel combination therewith |
US5307954A (en) * | 1991-11-19 | 1994-05-03 | Duncan Enterprises | Multi-color fabric paint product |
US5503842A (en) * | 1989-10-16 | 1996-04-02 | Colgate-Palmolive Company | Polytetrafluoroethylene therapeutic articles |
EP0712624A2 (en) | 1994-11-14 | 1996-05-22 | Colgate-Palmolive Company | Dentifrice compositions having improved anticalculus properties |
EP0735855A1 (en) * | 1993-12-22 | 1996-10-09 | Smithkline Beecham Corporation | Tooth whitening preparations |
US5866101A (en) * | 1997-07-22 | 1999-02-02 | Colgate Palmolive Company | Color stable anticalculus compostion |
WO1999012517A1 (en) * | 1997-09-09 | 1999-03-18 | Smithkline Beecham Corporation | Tooth whitening preparations |
US6447789B1 (en) | 1999-10-13 | 2002-09-10 | Terrie E. Banks | Facial cleanser and method of treating skin conditions |
US6682722B2 (en) | 2001-09-19 | 2004-01-27 | The Procter & Gamble Company | Oral compositions providing enhanced overall cleaning |
US6685916B1 (en) * | 2002-10-31 | 2004-02-03 | Cadbury Adams Usa Llc | Compositions for removing stains from dental surfaces, and methods of making and using the same |
US20050112180A1 (en) * | 2003-11-22 | 2005-05-26 | Chou Belle L. | Antimicrobial elastomeric flexible article and manufacturing method |
US20050260266A1 (en) * | 2003-11-21 | 2005-11-24 | Cadbury Adams Usa, Llc. | Controlled release oral delivery systems |
US20060024245A1 (en) * | 2004-07-29 | 2006-02-02 | Cadbury Adams, Llc. | Tooth whitening compositions and delivery systems therefor |
US20060177517A1 (en) * | 2003-02-26 | 2006-08-10 | Toshikazu Shiba | Antiinflammtory agent and antiinflammatory medical material |
US20060263477A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Edible composition including a delivery system for active components |
US20070053972A1 (en) * | 2005-09-08 | 2007-03-08 | Cadbury Adams Usa Llc. | Gelatin capsules containing actives |
US20070077210A1 (en) * | 2003-07-11 | 2007-04-05 | Petros Gebreselassie | Chewing gum and confectionery compositions containing a stain removing complex, and methods of making and using the same |
US20070178188A1 (en) * | 2006-01-27 | 2007-08-02 | Cadbury Adams Usa Llc | Chewing gum compositions including free neotame sweetener compositions |
US7445769B2 (en) | 2002-10-31 | 2008-11-04 | Cadbury Adams Usa Llc | Compositions for removing stains from dental surfaces and methods of making and using the same |
US20080317681A1 (en) * | 2003-07-11 | 2008-12-25 | Petros Gebreselassie | Compositions containing a stain removing complex, and methods of making and using the same |
US7641892B2 (en) | 2004-07-29 | 2010-01-05 | Cadburry Adams USA, LLC | Tooth whitening compositions and delivery systems therefor |
US7727565B2 (en) | 2004-08-25 | 2010-06-01 | Cadbury Adams Usa Llc | Liquid-filled chewing gum composition |
US7851005B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851006B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851000B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and edible confectionery and chewing gum products containing same |
US7955630B2 (en) | 2004-09-30 | 2011-06-07 | Kraft Foods Global Brands Llc | Thermally stable, high tensile strength encapsulated actives |
US20110150789A1 (en) * | 2006-12-22 | 2011-06-23 | Douglas Andersen | Anti-calculus dental composition |
US8389031B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Coated delivery system for active components as part of an edible composition |
US8389032B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Delivery system for active components as part of an edible composition having selected particle size |
US8591974B2 (en) | 2003-11-21 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for two or more active components as part of an edible composition |
US8591972B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for coated active components as part of an edible composition |
US8591973B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition |
US8597703B2 (en) | 2005-05-23 | 2013-12-03 | Kraft Foods Global Brands Llc | Delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
US8828423B2 (en) | 2003-11-21 | 2014-09-09 | Intercontinental Great Brands Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US9011946B2 (en) | 2011-04-29 | 2015-04-21 | Intercontinental Great Brands Llc | Encapsulated acid, method for the preparation thereof, and chewing gum comprising same |
US9198448B2 (en) | 2005-02-07 | 2015-12-01 | Intercontinental Great Brands Llc | Stable tooth whitening gum with reactive ingredients |
JP2017519797A (en) * | 2014-07-10 | 2017-07-20 | ザ プロクター アンド ギャンブル カンパニー | Anti-calculus oral composition |
Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3934002A (en) * | 1972-06-30 | 1976-01-20 | The Procter & Gamble Company | Oral compositions for plaque, caries and calculus retardation with reduced staining tendencies |
US4244931A (en) * | 1979-05-29 | 1981-01-13 | Monsanto Company | Dicalcium phosphate dihydrate with improved stability |
US4247526A (en) * | 1979-05-29 | 1981-01-27 | Monsanto Company | Method for preparing dicalcium phosphate dihydrate with improved stability |
US4267167A (en) * | 1975-10-28 | 1981-05-12 | Cooper Care, Inc. | Thixotropic topical fluoride-phosphate gel compositions useful for the prevention of dental caries |
US4272509A (en) * | 1978-09-19 | 1981-06-09 | J. M. Huber Corporation | Precipitated silicon dioxide cleaning agent and dentifrice composition |
US4340583A (en) * | 1979-05-23 | 1982-07-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4420312A (en) * | 1979-05-23 | 1983-12-13 | J. M. Huber Corporation | Method for production of high fluoride compatibility dentifrice abrasives and compositions |
US4421527A (en) * | 1977-12-20 | 1983-12-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4460565A (en) * | 1981-07-03 | 1984-07-17 | Intradal N.V. | Anticariogenic remineralizing dentifrice |
US4515772A (en) * | 1982-06-22 | 1985-05-07 | The Procter & Gamble Company | Oral compositions |
JPS6136211A (en) * | 1984-07-26 | 1986-02-20 | Lion Corp | Composition for oral cavity application |
US4627977A (en) * | 1985-09-13 | 1986-12-09 | Colgate-Palmolive Company | Anticalculus oral composition |
EP0236290A1 (en) * | 1986-03-05 | 1987-09-09 | Monsanto Company | Anticalculus dentifrices |
GB2188548A (en) * | 1986-04-05 | 1987-10-07 | Beecham Group Plc | Oral hygiene compositions |
EP0254452A2 (en) * | 1986-07-24 | 1988-01-27 | Lion Corporation | Oral composition |
GB2200551A (en) * | 1987-01-30 | 1988-08-10 | Colgate Palmolive Co | Antibacterial antiplaque, anticalculus oral composition |
EP0295116A1 (en) * | 1987-06-12 | 1988-12-14 | Unilever Plc | Oral compositions |
US4806342A (en) * | 1985-09-13 | 1989-02-21 | Colgate-Palmolive Company | Anticalculus oral composition |
US4808400A (en) * | 1985-09-13 | 1989-02-28 | Colgate-Palmolive Company | Anticalculus oral composition |
US4808401A (en) * | 1985-09-13 | 1989-02-28 | Colgate-Palmolive Company | Anticalculus oral composition |
US4842847A (en) * | 1987-12-21 | 1989-06-27 | The B. F. Goodrich Company | Dental calculus inhibiting compositions |
-
1989
- 1989-05-08 US US07/348,805 patent/US4923684A/en not_active Expired - Lifetime
-
1990
- 1990-05-07 ZA ZA903439A patent/ZA903439B/en unknown
Patent Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3934002A (en) * | 1972-06-30 | 1976-01-20 | The Procter & Gamble Company | Oral compositions for plaque, caries and calculus retardation with reduced staining tendencies |
US4267167A (en) * | 1975-10-28 | 1981-05-12 | Cooper Care, Inc. | Thixotropic topical fluoride-phosphate gel compositions useful for the prevention of dental caries |
US4421527A (en) * | 1977-12-20 | 1983-12-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4272509A (en) * | 1978-09-19 | 1981-06-09 | J. M. Huber Corporation | Precipitated silicon dioxide cleaning agent and dentifrice composition |
US4340583A (en) * | 1979-05-23 | 1982-07-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4420312A (en) * | 1979-05-23 | 1983-12-13 | J. M. Huber Corporation | Method for production of high fluoride compatibility dentifrice abrasives and compositions |
US4244931A (en) * | 1979-05-29 | 1981-01-13 | Monsanto Company | Dicalcium phosphate dihydrate with improved stability |
US4247526A (en) * | 1979-05-29 | 1981-01-27 | Monsanto Company | Method for preparing dicalcium phosphate dihydrate with improved stability |
US4460565A (en) * | 1981-07-03 | 1984-07-17 | Intradal N.V. | Anticariogenic remineralizing dentifrice |
US4515772A (en) * | 1982-06-22 | 1985-05-07 | The Procter & Gamble Company | Oral compositions |
JPS6136211A (en) * | 1984-07-26 | 1986-02-20 | Lion Corp | Composition for oral cavity application |
US4627977A (en) * | 1985-09-13 | 1986-12-09 | Colgate-Palmolive Company | Anticalculus oral composition |
US4806342A (en) * | 1985-09-13 | 1989-02-21 | Colgate-Palmolive Company | Anticalculus oral composition |
US4808400A (en) * | 1985-09-13 | 1989-02-28 | Colgate-Palmolive Company | Anticalculus oral composition |
US4808401A (en) * | 1985-09-13 | 1989-02-28 | Colgate-Palmolive Company | Anticalculus oral composition |
EP0236290A1 (en) * | 1986-03-05 | 1987-09-09 | Monsanto Company | Anticalculus dentifrices |
GB2188548A (en) * | 1986-04-05 | 1987-10-07 | Beecham Group Plc | Oral hygiene compositions |
EP0254452A2 (en) * | 1986-07-24 | 1988-01-27 | Lion Corporation | Oral composition |
GB2200551A (en) * | 1987-01-30 | 1988-08-10 | Colgate Palmolive Co | Antibacterial antiplaque, anticalculus oral composition |
EP0295116A1 (en) * | 1987-06-12 | 1988-12-14 | Unilever Plc | Oral compositions |
US4842847A (en) * | 1987-12-21 | 1989-06-27 | The B. F. Goodrich Company | Dental calculus inhibiting compositions |
Non-Patent Citations (2)
Title |
---|
Briner and Francis, Calc. Tiss. Res., 11, pp. 10 22 (1973). * |
Briner and Francis, Calc. Tiss. Res., 11, pp. 10-22 (1973). |
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