US4802674A - Golf ball - Google Patents

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Publication number
US4802674A
US4802674A US07/026,888 US2688887A US4802674A US 4802674 A US4802674 A US 4802674A US 2688887 A US2688887 A US 2688887A US 4802674 A US4802674 A US 4802674A
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Prior art keywords
golf ball
paint
enamel
pigment
weight
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Expired - Lifetime
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US07/026,888
Inventor
Katsutoshi Kitaoh
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Sumitomo Rubber Industries Ltd
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Sumitomo Rubber Industries Ltd
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Assigned to SUMITOMO RUBBER INDUSTRIES, LTD., 1-1, TSUTSUI-CHO 1-CHOME, CHUO-KU, KOBE-SHI, HYOGO-KEN, JAPAN reassignment SUMITOMO RUBBER INDUSTRIES, LTD., 1-1, TSUTSUI-CHO 1-CHOME, CHUO-KU, KOBE-SHI, HYOGO-KEN, JAPAN ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: KITAOH, KATSUTOSHI
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    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/12Special coverings, i.e. outer layer material
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/0022Coatings, e.g. paint films; Markings
    • A63B37/00221Coatings, e.g. paint films; Markings characterised by the material
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/007Characteristics of the ball as a whole
    • A63B37/0072Characteristics of the ball as a whole with a specified number of layers
    • A63B37/0074Two piece balls, i.e. cover and core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S273/00Amusement devices: games
    • Y10S273/22Ionomer

Definitions

  • the present invention relates to a golf ball which is coated by paints.
  • the enamaled golf balls are produced by coating its surface once or twice with an enamel paint which contains a pigment which comprises from about 20 to 50% by weight based on the solid content of the paint.
  • the color of the enameled golf balls appear as the color of the enamel paint, because the color of the golf ball is concealed by the enamel paint.
  • the non-enameled golf balls are produced by coating only with a clear paint. The color of the non-enameled golf balls is the same as the color of the golf ball itself.
  • pigments are formulated into a cover composition.
  • This attempt would be unsuccessful if an enamel paint having opacifying properties which are too high is applied to a golf ball in the same manner as applied to the enameled golf balls.
  • it is required to formulate the pigments into a cover composition of the golf balls in a large amount in order to obtain the same color tone as the enameled golf balls.
  • this causes the physical properties of the golf ball to deteriorate.
  • ultraviolet lights are transmitted through the clear coat layer without any barriers so as to lead to a deterioration of surface properties, especially in the adhesion properties.
  • the ionomer resin becomes severely deteriorated by ultraviolet lights which gives rise to a ply separation between the clear paint layer and the ionomer resin cover.
  • an ultraviolet absorber For preventing the deterioration of adhesion properties, it is proposed to formulate an ultraviolet absorber into a clear paint.
  • the formulation of the ultraviolet absorber would decrease the fine view and gloss of the cover. Further, if there are stains on the surface of the golf ball, these stains would be in plain sight and would diminish the commodity quality thereof.
  • An object of the present invention is to provide a golf ball having the desirable properties of both the enameled and non-enameled golf balls.
  • the golf ball is produced by coating its surface with an enamel paint containing a pigment of 1 to 10% by weight based on the solid content of the paint.
  • An enamel paint conventionally used for golf balls contains about 20% by weight of pigments, but the enamel paint employed by the present invention contains 1 to 10% by weight which is less than the conventional one.
  • Another object of the present invention is to provide a two-piece golf ball prepared by coating a golf ball core with a resin composition comprising a pigment of 0.5 to 10% by weight and a cover resin of 0.5 to 10% based on said resin composition, and then coating the coated golf ball core with an enamel paint containing a pigment of 1 to 10% by weight based on a the solid content of said paint.
  • FIG. 1 is a sectional view of a two-piece golf ball of the present embodiment.
  • the enamel paint employed in the present invention includes an epoxy enamel paint, an aqueous urethane enamel paint or a solvent type urethane enamel paint.
  • the enamel paint contains a pigment in an amount of 1 to 10% by weight, preferably 5 to 10% by weight based on the solid content of the enamel paint.
  • the amounts of the pigment are less than 1% by weight, the surface of the golf ball would be exposed to a high amount of the ultraviolet light as mentioned in the case of the non-enameled golf balls.
  • the amounts of the pigment are more than 10% by weight, the opacifying properties are too high to decrease the transparency and depth in the appearance of the golf ball.
  • the pigment formulated in the enamel paint includes a pigment having high opacifying properties, such as titanium dioxide, zinc oxide and the like; a pigment having transparency, such as micronized barium sulfate, zinc sulfate and the like.
  • the pigment having transparency imparts high transparency to the obtained golf ball with preserving weather resistance.
  • the thickness of the enamel coating layer is generally within the range of 5 to 30 micron, preferably 10 to 25 micron. For obtaining a suitable thickness of the coating layer, a coating process can be repeated. A thickness of more than 30 micron makes meaningless the use of an enamel paint containing less amounts of the pigment than the amounts used in conventional enamel paints. Thus the color of the enameled golf ball does not reflect the basic color of a golf ball. The thickness of less than 5 microns does not impart the technical effects by the enamel coatings of the present invention.
  • a golf ball to be utilized in the present invention includes a one-piece golf ball, a balata covered golf ball or an ionomer covered golf ball. Preferred is the ionomer covered golf ball.
  • the color of the golf ball be the same as the enamel paint to be coated.
  • the golf ball is prepared by covering a core with a resin composition containing a white pigment of 0.5 to 10% by weight and a cover resin of 0.5 to 10% by weight based on the composition. It is more preferred that the resin composition for the golf ball additionally contains a fluorescent whitening agent in an amount of 0.2 to 0.6% by weight.
  • the enamel paint mentioned above is coated once or twice by a conventional method on a golf ball which is prepared by covering core 1 with cover 2 to form enamel layer 3, to which a clear paint is applied to form outermost clear layer 4. If desirable, a clear paint layer may be formed between the golf ball and enamel layer 3.
  • the clear paint includes a urethane type clear paint, an acryl type clear paint, an epoxy type clear paint and the like.

Abstract

A golf ball prepared by covering a golf ball core with an ionomer resin composition comprising 0.5 to 10% by weight of a white pigment and 0.2 to 0.6% by weight of a fluorescent whitening agent, wehrein the % of the pigment and the agent are based on the total weight of the resin composition. The ionomer resin cover is coated with an enamel paint comprising 1 to 10% by weight of a pigment, wherein the % is based on the solid content of said enamel paint. A clear paint may be applied either on the enamel layer or between the enamel layer and the ionomer resin cover.

Description

FIELD OF THE INVENTION
The present invention relates to a golf ball which is coated by paints.
BACKGROUND OF THE INVENTION
There are enameled golf balls and non-enameled golf balls commercially available. The enamaled golf balls are produced by coating its surface once or twice with an enamel paint which contains a pigment which comprises from about 20 to 50% by weight based on the solid content of the paint. The color of the enameled golf balls appear as the color of the enamel paint, because the color of the golf ball is concealed by the enamel paint. The non-enameled golf balls are produced by coating only with a clear paint. The color of the non-enameled golf balls is the same as the color of the golf ball itself.
In order to impart a beautiful color to a golf ball, pigments are formulated into a cover composition. This attempt, however, would be unsuccessful if an enamel paint having opacifying properties which are too high is applied to a golf ball in the same manner as applied to the enameled golf balls. In case of the non-enameled golf balls, it is required to formulate the pigments into a cover composition of the golf balls in a large amount in order to obtain the same color tone as the enameled golf balls. However, this causes the physical properties of the golf ball to deteriorate. Also, since the non-enameled golf balls have no enamel layers, ultraviolet lights are transmitted through the clear coat layer without any barriers so as to lead to a deterioration of surface properties, especially in the adhesion properties. Especially, in the case of a golf ball which is covered with an ionomer resin, the ionomer resin becomes severely deteriorated by ultraviolet lights which gives rise to a ply separation between the clear paint layer and the ionomer resin cover. For preventing the deterioration of adhesion properties, it is proposed to formulate an ultraviolet absorber into a clear paint. However, the formulation of the ultraviolet absorber would decrease the fine view and gloss of the cover. Further, if there are stains on the surface of the golf ball, these stains would be in plain sight and would diminish the commodity quality thereof.
It is desirable to develop golf balls having the desirable properties of both the enameled and non-enameled golf balls, as well as having the good appearance of both.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a golf ball having the desirable properties of both the enameled and non-enameled golf balls. The golf ball is produced by coating its surface with an enamel paint containing a pigment of 1 to 10% by weight based on the solid content of the paint. An enamel paint conventionally used for golf balls contains about 20% by weight of pigments, but the enamel paint employed by the present invention contains 1 to 10% by weight which is less than the conventional one.
Another object of the present invention is to provide a two-piece golf ball prepared by coating a golf ball core with a resin composition comprising a pigment of 0.5 to 10% by weight and a cover resin of 0.5 to 10% based on said resin composition, and then coating the coated golf ball core with an enamel paint containing a pigment of 1 to 10% by weight based on a the solid content of said paint.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a sectional view of a two-piece golf ball of the present embodiment.
DETAILED DESCRIPTION OF THE INVENTION
The enamel paint employed in the present invention includes an epoxy enamel paint, an aqueous urethane enamel paint or a solvent type urethane enamel paint. The enamel paint contains a pigment in an amount of 1 to 10% by weight, preferably 5 to 10% by weight based on the solid content of the enamel paint. When the amounts of the pigment are less than 1% by weight, the surface of the golf ball would be exposed to a high amount of the ultraviolet light as mentioned in the case of the non-enameled golf balls. When the amounts of the pigment are more than 10% by weight, the opacifying properties are too high to decrease the transparency and depth in the appearance of the golf ball.
The pigment formulated in the enamel paint includes a pigment having high opacifying properties, such as titanium dioxide, zinc oxide and the like; a pigment having transparency, such as micronized barium sulfate, zinc sulfate and the like. The pigment having transparency imparts high transparency to the obtained golf ball with preserving weather resistance. Preferred are the pigments having high opacifying properties.
The thickness of the enamel coating layer is generally within the range of 5 to 30 micron, preferably 10 to 25 micron. For obtaining a suitable thickness of the coating layer, a coating process can be repeated. A thickness of more than 30 micron makes meaningless the use of an enamel paint containing less amounts of the pigment than the amounts used in conventional enamel paints. Thus the color of the enameled golf ball does not reflect the basic color of a golf ball. The thickness of less than 5 microns does not impart the technical effects by the enamel coatings of the present invention.
A golf ball to be utilized in the present invention includes a one-piece golf ball, a balata covered golf ball or an ionomer covered golf ball. Preferred is the ionomer covered golf ball.
According to the present invention, it is preferred that the color of the golf ball be the same as the enamel paint to be coated. For imparting an excellent appearance to the golf ball, in the case of a white two-piece golf ball, it is preferred that the golf ball is prepared by covering a core with a resin composition containing a white pigment of 0.5 to 10% by weight and a cover resin of 0.5 to 10% by weight based on the composition. It is more preferred that the resin composition for the golf ball additionally contains a fluorescent whitening agent in an amount of 0.2 to 0.6% by weight.
The present invention is further explained with reference to FIG. 1.
The enamel paint mentioned above is coated once or twice by a conventional method on a golf ball which is prepared by covering core 1 with cover 2 to form enamel layer 3, to which a clear paint is applied to form outermost clear layer 4. If desirable, a clear paint layer may be formed between the golf ball and enamel layer 3. The clear paint includes a urethane type clear paint, an acryl type clear paint, an epoxy type clear paint and the like.
The present invention is illustrated by the following examples, which, however, are not to be construed as limiting the present invention to the details thereof.
Examples 1 to 9 and Comparative Examples 1 to 6
Paints are applied to two piece golf balls which are covered by an ionomer resin composition (an ionomer resin (Surlyn 1605/1706=50/50 blend)/TiO2 =98/2 by weight) as shown in Table 1. Evaluation was made on appearance, paint adhesion after a weather resistance test, yellowing after a weather resistance test, crack resistance of the paint, opacifying properties of stains of the cover. The result of the evaluation is shown in Table 1.
                                  TABLE 1                                 
__________________________________________________________________________
                    Example                                               
                    1   2   3   4   5   6   7   8   9                     
__________________________________________________________________________
Pig- First layer                                                          
            Epoxy paint                                                   
                    5   5   10  0   --  --  --  --   8.0                  
ment        Aqueous --  --  --  --  5   5   10  0   --                    
con-        urethane paint                                                
tent*                                                                     
     Second layer                                                         
            Urethane paint                                                
                    0   5   0   5   0   5   0   5   10.0                  
(%)  Third layer                                                          
            Urethane paint                                                
                    0   0   0   0   0   0   0   0   0                     
Eval-                                                                     
     Appearance (Contribution of the                                      
                    Exist                                                 
                        Exist                                             
                            Exist                                         
                                Exist                                     
                                    Exist                                 
                                        Exist                             
                                            Exist                         
                                                Exist                     
                                                    Exist                 
ua-  color of the cover)                                                  
tion Paint adhession after a weather                                      
                    Fairly                                                
                        Good                                              
                            Good                                          
                                Fairly                                    
                                    Good                                  
                                        Good                              
                                            Good                          
                                                Good                      
                                                    Good                  
     resistance test.sup.1                                                
                    good        good                                      
     Yellowing after a weather                                            
                    Good                                                  
                        Good                                              
                            Good                                          
                                Good                                      
                                    Good                                  
                                        Good                              
                                            Good                          
                                                Good                      
                                                    Good                  
     resistance test.sup.2                                                
     Opacifying properties of the                                         
                    Fairly                                                
                        Good                                              
                            Good                                          
                                Fairly                                    
                                    Good                                  
                                        Good                              
                                            Good                          
                                                Fairly                    
                                                    Good                  
     stains on the cover                                                  
                    good        good            good                      
     Crack resistance of the paint.sup.3                                  
                    Good                                                  
                        Good                                              
                            Good                                          
                                Good                                      
                                    Good                                  
                                        Good                              
                                            Good                          
                                                Good                      
                                                    Good                  
     Total judgement                                                      
                    O   O   O   O   O   O   O   O   O                     
__________________________________________________________________________
                                Comparative Example                       
                                1   2   3   4   5   6                     
__________________________________________________________________________
            Pig- First layer                                              
                        Epoxy paint                                       
                                0   20  20  20  --  --                    
            ment        Aqueous --  --  --  --  0   0                     
            con-        urethane paint                                    
            tent*                                                         
                 Second layer                                             
                        Urethane paint                                    
                                0   0   5   20  0   20                    
            (%)  Third layer                                              
                        Urethane paint                                    
                                0   0   0    0  0   0                     
            Eval-                                                         
                 Appearance (Contribution of the                          
                                No  No  No  No  Exist                     
                                                    No                    
            ua-  color of the cover)                                      
            tion Paint adhession after a weather                          
                                Bad Good                                  
                                        Good                              
                                            Good                          
                                                Bad Good                  
                 resistance test.sup.1                                    
                 Yellowing after a weather                                
                                Good                                      
                                    Good                                  
                                        Good                              
                                            Good                          
                                                Good                      
                                                    Good                  
                 resistance test.sup.2                                    
                 Opacifying properties of the                             
                                Bad Good                                  
                                        Good                              
                                            Good                          
                                                Bad Good                  
                 stains on the cover                                      
                 Crack resistance of the paint.sup.3                      
                                Good                                      
                                    Fairly                                
                                        Fairly                            
                                            Fairly                        
                                                Good                      
                                                    Fairly                
                                    good                                  
                                        good                              
                                            good    good                  
                 Total judgement                                          
                                X   X   X   X   X   X                     
__________________________________________________________________________
 .sup.1 After a golf ball was treated in Sunshine WeatherO-Meter for 60   
 hours and immersed in water for 24 hours, it was collided with a steel   
 board 100 times at a speed of 45 m/sec. After this test, a condition of  
 paint adhesion is observed.                                              
 .sup.2 After a golf ball was treated in Sunshine WeatherO-Meter for 120  
 hours, color difference, i.e. ΔL, Δa, Δb, ΔE     
 values, was measured by a color difference meter, yellowing was evaluated
 by eyes and color difference.                                            
 .sup.3 A crack condition of the paint layer is observed after colliding a
 golf ball with a steel board 100 times at a speed of 45 m/sec.           
 *The pigment was titanium dioxide. Percentage is based on the solid      
 content of a paint.                                                      
Examples 10, 11 and Comparative Example 7
Paints are applied to two-piece golf balls which are coated with an ionomer resin composition (an ionomer resin (Surlyn 1605 made dual ioning by Mg ions [see USP 4,526,375])/TiO2 /a fluorescent whitening agent Whiteflour HCS=97.9/1.8/0.3 by weight) as shown Table 2. Evaluation is made on appearance, paint adhesion after a weather resistance test, yellowing after a weather resistance test, crack resistance of the paint, opacifying properties of stains of the cover. The result of the evaluation is shown in Table 2.
              TABLE 2                                                     
______________________________________                                    
                            Com-                                          
                            parative                                      
                   Example  Example                                       
                   10   11*     7                                         
______________________________________                                    
Fluorescent whitening                                                     
                     0.3    0.3     0.3                                   
agent content (%)                                                         
Pigment                                                                   
       First layer Epoxy paint                                            
                         5      5     0                                   
content                                                                   
       Second layer Urethane paint                                        
                         5      5     0                                   
(%)    Third layer Urethane paint                                         
                         0      0     0                                   
Evalua-                                                                   
       Appearance (Contribution                                           
                         Exist  Exist Exist                               
tion   of the color of the cover)                                         
       Paint adhesion after a                                             
                         Good   Good  Bad                                 
       weather resistance test                                            
       Yellowing after a weather                                          
                         Good   Good  Bad                                 
       resistance test                                                    
       Opacifying properties of the                                       
                         Good   Fairly                                    
                                      Bad                                 
       stains on the cover      good                                      
       Crack resistance of the paint                                      
                         Good   Good  Good                                
       Total judgement   O      O     X                                   
______________________________________                                    
 *This example employs a micronized precipitated barium sulfate, and the  
 other examples employ titanium dioxide.                                  

Claims (13)

What is claimed is:
1. A golf ball prepared by coating a golf ball core with an ionomer resin composition comprising 0.5 to 10% by weight of a pigment and 0.2 to 0.6% by weight of a fluorescent whitening agent, wherein the % of the pigment and the agent are based on the total weight of the resin composition and then coating the ionomer resin composition coated golf ball core with an enamel paint comprising 1 to 10% by weight of a pigment, wherein the % is based on the solid content of said enamel paint.
2. The golf ball according to claim 1 wherein the golf ball is a two-piece golf ball.
3. The two-piece golf ball according to claim 2 wherein the pigment is TiO2.
4. The golf ball according to claim 1 wherein the thickness of the enamel coating is within the range of 10 to 25 microns.
5. The golf ball according to claim 1 wherein the color of the golf ball is the same as the color of the enamel paint.
6. The golf ball according to claim 1, wherein the coating with the ionomer resin composition and enamel paint is followed by coating with a clear paint.
7. The golf ball according to claim 6, wherein the clear paint is a urethane clear paint, an acryl clear paint or an epoxy clear paint.
8. The golf ball according to claim 1 wherein the enamel paint is an epoxy enamel paint, an aqueous urethane enamel paint or a solvent type urethane enamel paint.
9. The golf ball according to claim 1 wherein the pigment is titanium dioxide, zinc oxide, micronized barium sulfate, zinc sulfate, a mixture thereof.
10. The golf ball according to claim 1 wherein the thickness of the enamel coating is within the range of 5 to 30 micron.
11. The golf ball according to claim 1 wherein said core is a one-piece construction.
12. A golf ball prepared by coating a golf ball core with an ionomer resin composition comprising 0.5 to 10% by weight of a pigment and 0.2 to 0.6% by weight of a fluorescent whitening agent, wherein the % of the pigment and the agent are based on the total weight of the resin composition, coating the ionomer resin composition coated golf ball with a clear paint which in turn is coated with an enamel paint comprising 1 to 10% by weight of a pigment, wherein the % is based on the solid content of said enamel paint.
13. The golf ball according to claim 12, wherein the clear paint is a urethane clear paint, an acryl clear paint or an epoxy clear paint.
US07/026,888 1986-03-17 1987-03-17 Golf ball Expired - Lifetime US4802674A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP61-39155 1986-03-17
JP3915586 1986-03-17

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Cited By (35)

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Publication number Priority date Publication date Assignee Title
US4871589A (en) * 1987-09-26 1989-10-03 Sumitomo Rubber Industries, Ltd. Method of coating a golf ball
US4991851A (en) * 1990-05-09 1991-02-12 Ruben Melesio Reflective golf ball and method
US5000458A (en) * 1990-04-20 1991-03-19 Wilson Sporting Goods Co. Golf ball with optical brightener in the primer coat
EP0419079A1 (en) * 1989-09-19 1991-03-27 Acushnet Company Painted golf ball
US5007647A (en) * 1989-12-15 1991-04-16 Sports Glow, Inc. Golf ball and method of making same
US5156405A (en) * 1987-09-10 1992-10-20 Sumitomo Rubber Industries, Ltd. Golf ball
GB2254792A (en) * 1991-04-18 1992-10-21 Hogan Ben Co Multiple-coat clear coat with optical brightener for golf ball.
EP0561640A1 (en) * 1992-03-18 1993-09-22 Sumitomo Rubber Industries Limited Coated golf ball
US5300325A (en) * 1993-07-02 1994-04-05 Lisco, Inc. Method of finishing a golf ball or the like
EP0601861A1 (en) * 1992-12-09 1994-06-15 Sumitomo Rubber Industries Ltd. Method of manufacturing a golf ball
US5409974A (en) * 1993-09-22 1995-04-25 Lisco, Inc. Golf ball containing optical brightener blend
US5409233A (en) * 1993-07-16 1995-04-25 Lisco, Inc. Golf ball coating composition
US5506004A (en) * 1993-12-29 1996-04-09 Sumitomo Rubber Industries, Ltd. Method for coating golf balls
DE19506746A1 (en) * 1995-02-27 1996-08-29 Wolfgang Sackmann Luminous golf ball for night-time use
US5552190A (en) * 1992-12-09 1996-09-03 Sumitomo Rubber Industries, Ltd. Golf ball and method of manufacturing the same
US5695414A (en) * 1995-05-31 1997-12-09 Sumitomo Rubber Industries, Ltd. Coated golf ball
US5785612A (en) * 1996-04-16 1998-07-28 Wilson Sporting Goods Co. Golf ball
US5789486A (en) * 1994-07-04 1998-08-04 Sumitomo Rubber Industries, Ltd. Coated golf ball
US5840788A (en) * 1997-06-20 1998-11-24 Acushnet Company Ultraviolet light resistant urethane top coat for golf balls
AU701846B2 (en) * 1992-12-09 1999-02-04 Sumitomo Rubber Industries, Ltd. Golf ball and method of manufacturing the same
US6103787A (en) * 1998-03-03 2000-08-15 Acushnet Company Golf ball cover compositions
US6245386B1 (en) 2000-04-26 2001-06-12 Callaway Golf Company Method and system for finishing a golf ball
US6284835B1 (en) 1999-07-09 2001-09-04 Lilly Industries, Inc. High impact coatings
US6340503B1 (en) 1996-03-01 2002-01-22 Spalding Sports Worldwide, Inc. Method of coating a game ball with a solvent-based polyurethane cured with catalyst
US6395861B1 (en) 1996-03-01 2002-05-28 Spalding Sports Worldside, Inc. Quick-cure game ball coating system
US20030050425A1 (en) * 1996-03-01 2003-03-13 Spalding Sports Worldwide, Inc. Quick-cure game ball coating system
US6676543B2 (en) * 2000-10-25 2004-01-13 Sumitomo Rubber Industries, Limited Coated golf ball
US20050037868A1 (en) * 2003-08-15 2005-02-17 Kunihiro Tamura Practice golf ball
US20080302461A1 (en) * 2007-06-08 2008-12-11 E. I. Du Pont De Nemours And Company Transparent Colored High Modulus Interlayers and Laminates Therefrom
US20080318063A1 (en) * 2007-06-22 2008-12-25 Anderson Jerrel C Glass laminates with improved weatherability
US20090155576A1 (en) * 2007-12-18 2009-06-18 E. I. Du Pont De Nemours And Company Glass-less glazing laminates
US20100029413A1 (en) * 2006-09-13 2010-02-04 Gary Matroni Golf Ball
US7717810B2 (en) * 2005-07-14 2010-05-18 Bridgestone Sports Co., Ltd. Golf ball
US20140018193A1 (en) * 2012-07-11 2014-01-16 William E. Morgan Golf ball having multiple different coating layers
US9643059B2 (en) 2015-05-28 2017-05-09 Acushnet Company Golf ball incorporating ultra violet light resistant and light stable layer(s) and method of making

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US5156405A (en) * 1987-09-10 1992-10-20 Sumitomo Rubber Industries, Ltd. Golf ball
US4871589A (en) * 1987-09-26 1989-10-03 Sumitomo Rubber Industries, Ltd. Method of coating a golf ball
AU599265B2 (en) * 1987-09-26 1990-07-12 Sumitomo Rubber Industries, Ltd. Method of coating a golf ball
EP0419079A1 (en) * 1989-09-19 1991-03-27 Acushnet Company Painted golf ball
US5029870A (en) * 1989-09-19 1991-07-09 Acushnet Company Painted golf ball
US5007647A (en) * 1989-12-15 1991-04-16 Sports Glow, Inc. Golf ball and method of making same
WO1991008802A1 (en) * 1989-12-15 1991-06-27 Sports Glow, Inc. Golf ball and method of manufacturing same
US5000458A (en) * 1990-04-20 1991-03-19 Wilson Sporting Goods Co. Golf ball with optical brightener in the primer coat
EP0452794A1 (en) * 1990-04-20 1991-10-23 Wilson Sporting Goods Company Golf ball with optical brightener in the primer coat
US4991851A (en) * 1990-05-09 1991-02-12 Ruben Melesio Reflective golf ball and method
GB2254792A (en) * 1991-04-18 1992-10-21 Hogan Ben Co Multiple-coat clear coat with optical brightener for golf ball.
EP0561640A1 (en) * 1992-03-18 1993-09-22 Sumitomo Rubber Industries Limited Coated golf ball
EP0601861A1 (en) * 1992-12-09 1994-06-15 Sumitomo Rubber Industries Ltd. Method of manufacturing a golf ball
US5552190A (en) * 1992-12-09 1996-09-03 Sumitomo Rubber Industries, Ltd. Golf ball and method of manufacturing the same
AU676216B2 (en) * 1992-12-09 1997-03-06 Sumitomo Rubber Industries, Ltd. Golf ball and method of manufacturing the same
US5743818A (en) * 1992-12-09 1998-04-28 Sumitomo Rubber Industries, Ltd. Golf ball
AU701846B2 (en) * 1992-12-09 1999-02-04 Sumitomo Rubber Industries, Ltd. Golf ball and method of manufacturing the same
US5300325A (en) * 1993-07-02 1994-04-05 Lisco, Inc. Method of finishing a golf ball or the like
US5409233A (en) * 1993-07-16 1995-04-25 Lisco, Inc. Golf ball coating composition
US5409974A (en) * 1993-09-22 1995-04-25 Lisco, Inc. Golf ball containing optical brightener blend
US5506004A (en) * 1993-12-29 1996-04-09 Sumitomo Rubber Industries, Ltd. Method for coating golf balls
US5789486A (en) * 1994-07-04 1998-08-04 Sumitomo Rubber Industries, Ltd. Coated golf ball
DE19506746A1 (en) * 1995-02-27 1996-08-29 Wolfgang Sackmann Luminous golf ball for night-time use
US5695414A (en) * 1995-05-31 1997-12-09 Sumitomo Rubber Industries, Ltd. Coated golf ball
AU702110B2 (en) * 1995-05-31 1999-02-11 Sumitomo Rubber Industries, Ltd. Coated golf ball
US6639024B2 (en) 1996-03-01 2003-10-28 The Top-Flite Golf Company Coating a ball with two-part polyester polyol-catalyst/polyisocyanate system
US6340503B1 (en) 1996-03-01 2002-01-22 Spalding Sports Worldwide, Inc. Method of coating a game ball with a solvent-based polyurethane cured with catalyst
US6395861B1 (en) 1996-03-01 2002-05-28 Spalding Sports Worldside, Inc. Quick-cure game ball coating system
US20030050425A1 (en) * 1996-03-01 2003-03-13 Spalding Sports Worldwide, Inc. Quick-cure game ball coating system
US5785612A (en) * 1996-04-16 1998-07-28 Wilson Sporting Goods Co. Golf ball
US5840788A (en) * 1997-06-20 1998-11-24 Acushnet Company Ultraviolet light resistant urethane top coat for golf balls
US6103787A (en) * 1998-03-03 2000-08-15 Acushnet Company Golf ball cover compositions
US6284835B1 (en) 1999-07-09 2001-09-04 Lilly Industries, Inc. High impact coatings
US6245386B1 (en) 2000-04-26 2001-06-12 Callaway Golf Company Method and system for finishing a golf ball
US6676543B2 (en) * 2000-10-25 2004-01-13 Sumitomo Rubber Industries, Limited Coated golf ball
US20050037868A1 (en) * 2003-08-15 2005-02-17 Kunihiro Tamura Practice golf ball
US7717810B2 (en) * 2005-07-14 2010-05-18 Bridgestone Sports Co., Ltd. Golf ball
US20100029413A1 (en) * 2006-09-13 2010-02-04 Gary Matroni Golf Ball
US20080302461A1 (en) * 2007-06-08 2008-12-11 E. I. Du Pont De Nemours And Company Transparent Colored High Modulus Interlayers and Laminates Therefrom
US20080318063A1 (en) * 2007-06-22 2008-12-25 Anderson Jerrel C Glass laminates with improved weatherability
US20090155576A1 (en) * 2007-12-18 2009-06-18 E. I. Du Pont De Nemours And Company Glass-less glazing laminates
US20140018193A1 (en) * 2012-07-11 2014-01-16 William E. Morgan Golf ball having multiple different coating layers
US9643059B2 (en) 2015-05-28 2017-05-09 Acushnet Company Golf ball incorporating ultra violet light resistant and light stable layer(s) and method of making

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