US4627993A - Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer - Google Patents
Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer Download PDFInfo
- Publication number
- US4627993A US4627993A US06/732,089 US73208985A US4627993A US 4627993 A US4627993 A US 4627993A US 73208985 A US73208985 A US 73208985A US 4627993 A US4627993 A US 4627993A
- Authority
- US
- United States
- Prior art keywords
- vinyl
- blend
- polymer
- carbon atoms
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/06—Homopolymers or copolymers of esters of polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Abstract
Description
______________________________________ Component % ______________________________________ Ba/Cd laurates available from 2.5 Argus Chemical Co. as "Mark" WS Epoxidized soy oil available 8.2 from Rohm and Haas Co. as "Paraplex" G62 Liquid phosphite chelator 0.8 available from Argus Chemical Co. as "Mark" 517 Acrylic fusion aid available 2.5 from Rohm and Haas Co. as "Acryloid" K120N Polyethylene wax available from 3.3 Allied Chemical Co. as "Allied" 6A Stearic acid 0.3 ______________________________________
______________________________________ Batch: A B ______________________________________ E.sup.1 /61% MA.sup.2 (MI = 6) 70% 64% PVC ("Geon" 92).sup.3 iv = 1.02 30% 27% Carbon black N-774.sup.4 -- 9.0% Irradiation Dosage (Megarads) 0.9 0.9 ______________________________________ .sup.1 E = ethylene .sup.2 MA = methyl acrylate .sup.3 Sold by B. F. Goodrich Co. .sup.4 ASTM grade designation
______________________________________ Batch: A B ______________________________________ Shore A Hardness.sup.1 52 75 Compression set B (%).sup.2 55 62 (22 hrs at 70° C.) % Volume swell.sup.3 80 78 (7 days at 100° C.) Clash-Berg Temp. °C..sup.4 -25 -23 Tensile at break (psi).sup.5 863 1310 Elongation at break (%).sup.5 440 530 M.sub.100 (psi).sup.5 203 380 M.sub.200 (psi).sup.5 453 603 ______________________________________ .sup.1 ASTM D2240 .sup.2 ASTM D395 .sup.3 ASTM D200 (#3 Oil, 7 days at 100° C.) .sup.4 ASTM D1043 .sup.5 ASTM D412
Claims (18)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/732,089 US4627993A (en) | 1982-07-01 | 1985-05-09 | Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39432982A | 1982-07-01 | 1982-07-01 | |
US06/732,089 US4627993A (en) | 1982-07-01 | 1985-05-09 | Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06572078 Continuation-In-Part | 1984-01-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
US4627993A true US4627993A (en) | 1986-12-09 |
Family
ID=27014690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/732,089 Expired - Lifetime US4627993A (en) | 1982-07-01 | 1985-05-09 | Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer |
Country Status (1)
Country | Link |
---|---|
US (1) | US4627993A (en) |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4806590A (en) * | 1986-05-27 | 1989-02-21 | Imperial Chemical Industries Plc | Aqueous-based sealant compositions |
US4877821A (en) * | 1987-02-26 | 1989-10-31 | The Dow Chemical Company | Stabilizer concentrate |
US4884814A (en) * | 1988-01-15 | 1989-12-05 | Spalding & Evenflo Companies, Inc. | Golf ball |
US4965304A (en) * | 1988-07-05 | 1990-10-23 | The Dow Chemical Company | Extrudable polymeric compositions |
US5037888A (en) * | 1989-11-09 | 1991-08-06 | Eastman Kodak Company | Thermoplastic elastomeric compositions and method for their preparation |
US5075355A (en) * | 1986-08-20 | 1991-12-24 | The Dow Chemical Company | Stabilizer concentrate |
US5270366A (en) * | 1992-12-16 | 1993-12-14 | Vista Chemical Company | Lead stabilized, flexible polymeric blends containing polyvinylchloride |
US5399421A (en) * | 1991-11-12 | 1995-03-21 | Gaska Tape, Inc. | Vinyl film stencil |
US5464903A (en) * | 1994-10-31 | 1995-11-07 | E. I. Du Pont De Nemours And Company | Process for preparing ethylene copolymer plasticized PVC |
WO1996019536A1 (en) * | 1994-12-21 | 1996-06-27 | Zeneca Resins B.V. | Aqueous polymer emulsions |
US6136923A (en) * | 1997-10-15 | 2000-10-24 | The Dow Chemical Company | Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride |
US6258888B1 (en) | 1994-12-21 | 2001-07-10 | Zeneca Resins Bv | Aqueous polymer emulsions |
US6258308B1 (en) | 1996-07-31 | 2001-07-10 | Exxon Chemical Patents Inc. | Process for adjusting WVTR and other properties of a polyolefin film |
US6287411B1 (en) | 1999-06-18 | 2001-09-11 | Rockwell Automation Technologies, Inc. | Bonding a thermoplastic elastomer to a magnesium based metal |
US6303208B1 (en) | 1996-10-10 | 2001-10-16 | Tredegar Film Products Corporation | Breathable elastic polymeric film laminates |
US20110076502A1 (en) * | 2009-09-30 | 2011-03-31 | Chaudhary Bharat I | Purified acetylated derivatives of castor oil and compostions including same |
US8557139B2 (en) | 2008-02-15 | 2013-10-15 | Dow Global Technologies Llc | Replacement plasticizer system for phthalate-plasticized formulations |
US8697787B2 (en) | 2009-09-30 | 2014-04-15 | Dow Global Technologies Llc | Flexible PVC compositions made with plasticizers derived from renewable sources |
US8802988B2 (en) | 2009-09-30 | 2014-08-12 | Dow Global Technologies Llc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
US8859654B2 (en) | 2009-09-30 | 2014-10-14 | Dow Global Technologies Llc | Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer |
US9228155B2 (en) | 2010-07-28 | 2016-01-05 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
US9394425B2 (en) | 2012-06-22 | 2016-07-19 | Dow Global Technologies Llc | Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions |
US9422418B2 (en) | 2009-09-30 | 2016-08-23 | Dow Global Technologies Llc | Acetylated monoglyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters |
US9499681B2 (en) | 2012-11-12 | 2016-11-22 | Dow Global Technologies Llc | Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers |
US9593091B2 (en) | 2012-11-12 | 2017-03-14 | Dow Global Technologies Llc | Methods for making epoxidized fatty acid alkyl esters |
US9850366B2 (en) | 2012-10-18 | 2017-12-26 | Dow Global Technologies Llc | Epdxidized fatty acid alkyl ester plasticizers and methods for making epdxidized fatty acid alkyl ester plasticizers |
US10077355B2 (en) | 2012-02-08 | 2018-09-18 | Dow Global Technologies Llc | Plasticizer compositions and methods for making plasticizer compositions |
US10100172B2 (en) | 2012-06-26 | 2018-10-16 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3553348A (en) * | 1966-11-02 | 1971-01-05 | Gen Electric | Polymeric blends for insulation composition |
US4340530A (en) * | 1977-12-08 | 1982-07-20 | Sumitomo Bakelite Company Limited | Vinyl chloride type resin composition |
US4379888A (en) * | 1977-10-11 | 1983-04-12 | Asahi-Dow Limited | Composition for drawn film, cold drawn film made of said composition and process for manufacture of said film |
-
1985
- 1985-05-09 US US06/732,089 patent/US4627993A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3553348A (en) * | 1966-11-02 | 1971-01-05 | Gen Electric | Polymeric blends for insulation composition |
US4379888A (en) * | 1977-10-11 | 1983-04-12 | Asahi-Dow Limited | Composition for drawn film, cold drawn film made of said composition and process for manufacture of said film |
US4340530A (en) * | 1977-12-08 | 1982-07-20 | Sumitomo Bakelite Company Limited | Vinyl chloride type resin composition |
Non-Patent Citations (2)
Title |
---|
Chem. Abs. 95 188466 Poly(Vinyl Chloride) Compositions , Japan Kokai 81,100,815 (13 Aug. 1981). * |
Chem. Abs. 95-188466 "Poly(Vinyl Chloride) Compositions", Japan Kokai 81,100,815 (13 Aug. 1981). |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4806590A (en) * | 1986-05-27 | 1989-02-21 | Imperial Chemical Industries Plc | Aqueous-based sealant compositions |
US5075355A (en) * | 1986-08-20 | 1991-12-24 | The Dow Chemical Company | Stabilizer concentrate |
US4877821A (en) * | 1987-02-26 | 1989-10-31 | The Dow Chemical Company | Stabilizer concentrate |
US4884814A (en) * | 1988-01-15 | 1989-12-05 | Spalding & Evenflo Companies, Inc. | Golf ball |
US4965304A (en) * | 1988-07-05 | 1990-10-23 | The Dow Chemical Company | Extrudable polymeric compositions |
US5037888A (en) * | 1989-11-09 | 1991-08-06 | Eastman Kodak Company | Thermoplastic elastomeric compositions and method for their preparation |
US5399421A (en) * | 1991-11-12 | 1995-03-21 | Gaska Tape, Inc. | Vinyl film stencil |
US5270366A (en) * | 1992-12-16 | 1993-12-14 | Vista Chemical Company | Lead stabilized, flexible polymeric blends containing polyvinylchloride |
US5464903A (en) * | 1994-10-31 | 1995-11-07 | E. I. Du Pont De Nemours And Company | Process for preparing ethylene copolymer plasticized PVC |
WO1996019536A1 (en) * | 1994-12-21 | 1996-06-27 | Zeneca Resins B.V. | Aqueous polymer emulsions |
US6258888B1 (en) | 1994-12-21 | 2001-07-10 | Zeneca Resins Bv | Aqueous polymer emulsions |
US6258308B1 (en) | 1996-07-31 | 2001-07-10 | Exxon Chemical Patents Inc. | Process for adjusting WVTR and other properties of a polyolefin film |
US6303208B1 (en) | 1996-10-10 | 2001-10-16 | Tredegar Film Products Corporation | Breathable elastic polymeric film laminates |
US6136923A (en) * | 1997-10-15 | 2000-10-24 | The Dow Chemical Company | Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride |
US6287411B1 (en) | 1999-06-18 | 2001-09-11 | Rockwell Automation Technologies, Inc. | Bonding a thermoplastic elastomer to a magnesium based metal |
US6517663B1 (en) | 1999-06-18 | 2003-02-11 | Dm Acquisition, Inc. | Bonding a thermoplastic elastomer to a magnesium based metal |
US8557139B2 (en) | 2008-02-15 | 2013-10-15 | Dow Global Technologies Llc | Replacement plasticizer system for phthalate-plasticized formulations |
US20110076502A1 (en) * | 2009-09-30 | 2011-03-31 | Chaudhary Bharat I | Purified acetylated derivatives of castor oil and compostions including same |
US9422418B2 (en) | 2009-09-30 | 2016-08-23 | Dow Global Technologies Llc | Acetylated monoglyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters |
US8697787B2 (en) | 2009-09-30 | 2014-04-15 | Dow Global Technologies Llc | Flexible PVC compositions made with plasticizers derived from renewable sources |
US8802988B2 (en) | 2009-09-30 | 2014-08-12 | Dow Global Technologies Llc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
US8822578B2 (en) | 2009-09-30 | 2014-09-02 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
US8859654B2 (en) | 2009-09-30 | 2014-10-14 | Dow Global Technologies Llc | Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer |
US9181415B2 (en) | 2009-09-30 | 2015-11-10 | Dow Global Technologies Llc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
US8552098B2 (en) | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
US9228155B2 (en) | 2010-07-28 | 2016-01-05 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
US10077355B2 (en) | 2012-02-08 | 2018-09-18 | Dow Global Technologies Llc | Plasticizer compositions and methods for making plasticizer compositions |
US9394425B2 (en) | 2012-06-22 | 2016-07-19 | Dow Global Technologies Llc | Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions |
US10100172B2 (en) | 2012-06-26 | 2018-10-16 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
US9850366B2 (en) | 2012-10-18 | 2017-12-26 | Dow Global Technologies Llc | Epdxidized fatty acid alkyl ester plasticizers and methods for making epdxidized fatty acid alkyl ester plasticizers |
US9499681B2 (en) | 2012-11-12 | 2016-11-22 | Dow Global Technologies Llc | Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers |
US9593091B2 (en) | 2012-11-12 | 2017-03-14 | Dow Global Technologies Llc | Methods for making epoxidized fatty acid alkyl esters |
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