US4231982A - Method for the production of tools for deep drawing, moulding, extruding and the like - Google Patents

Method for the production of tools for deep drawing, moulding, extruding and the like Download PDF

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Publication number
US4231982A
US4231982A US05/579,278 US57927875A US4231982A US 4231982 A US4231982 A US 4231982A US 57927875 A US57927875 A US 57927875A US 4231982 A US4231982 A US 4231982A
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United States
Prior art keywords
layer
plastic
easily fusible
tool
metal
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Expired - Lifetime
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US05/579,278
Inventor
Hans B. E. Jansson
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Volvo AB
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Volvo AB
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Priority to US05/579,278 priority Critical patent/US4231982A/en
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Publication of US4231982A publication Critical patent/US4231982A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/565Consisting of shell-like structures supported by backing material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C25/00Profiling tools for metal extruding
    • B21C25/10Making tools by operations not covered by a single other subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C3/00Profiling tools for metal drawing; Combinations of dies and mandrels
    • B21C3/18Making tools by operations not covered by a single other subclass; Repairing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00Tools as parts of machines covered by this subclass
    • B21D37/20Making tools by operations not covered by a single other subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • B23P15/24Making specific metal objects by operations not covered by a single other subclass or a group in this subclass dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/505Screws
    • B29C48/507Screws characterised by the material or their manufacturing process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films

Abstract

An exact replica of a tool for deep drawing, moulding, extruding and the like is manufactured by a method according to the present invention by thermally spraying the wearing surface of the tool to be produced onto a negative replica of the tool to be produced, said last replica being constituted of an easily fusible metal with a lower melting point than the plastic material used for backing up (1) the easily fusible negative replica and (2) the thermally sprayed wearing surface of the tool. According to the method of the invention the wearing surface of the tool can be constituted of steel, carbide or oxide.

Description

Tools for deep drawing, moulding, extruding are in general made of steel which in various ways is worked, e.g. by planing, drilling, milling, grinding and polishing. This method of manufacture is rather expensive and time-consuming, particularly for large tools.
In order to provide for less expensive tool manufacture, for example for experiments, testing and for relatively short manufacturing runs, it has been known to employ thermally sprayed metal shells which are stiffened with various materials, e.g. non-shrinking cement or plastic with filling material. Metal especially has been thermally sprayed onto a model so that a metal shell, which is stiffened with cement, gypsum or plastic is obtained and is thereafter removed from the model. The most commonly employed metals have been zinc, tin, bronze and combinations thereof. Steel has also been employed.
The prior art tools suffer, however, from a number of shortcomings due to the fact that, in the case of steel, it has not been possible to spray a layer thicker than 0.2 mm, i.a. because the sprayed metal rises from the foundation or because the true-to-pattern shape is lost in some other way when one attempts to increase the thickness of the metal layer. It can be easily seen that the metal layer is of decisive significance for the longevity of the tool and if the material with which the shell is stiffened is not dimensionally stable, neither satisfactory accuracy to size nor satisfactory longevity are obtained.
Materials which are difficult to spray such as carbides or oxides and certain metallic alloys have not been successfully applied as smooth, true-to-pattern, sufficiently thick wearing surfaces in tools of the type disclosed herein. The thin wearing surfaces thus far produced have often required subsequent treatment in the form of grinding or polishing, for example.
These difficulties have been obviated, on the other hand, in manufacturing a tool according to the invention in that it has been possible to produce tools of a thermally sprayed, true-to-pattern wearing coating of metal, metal alloy, particularly steel, carbide or oxide, having a thickness of 2-5 mm and in intimate mechanical engagement with and stiffened by dimensionally stable, moulded, heat resistant plastic, optionally with added filling and reinforcing material.
To produce a tool according to the invention one begins with a positive or negative working model, for example of plastic, wood, wax or the like, wherein the model is provided with a release agent, is thermally sprayed with a thin layer of an easily fusible metal or metal alloy, to which true-to-pattern layer a wearing coating of another metal or metal alloy or another material is thermally sprayed, the method according to the invention being characterized in that a stiffener of heat resistant plastic is baked onto the easily fusible metal sprayed onto the working model; in that the working model is loosened from the easily fusible metal layer (spray model) which is stiffened with plastic, so that a bright and smooth impression of the working model is obtained; in that the plastic in the spray model is hardened or is so constituted that it withstands a temperature at least 20° C. higher than that required to fuse the easily fusible metal layer; in that the easily fusible metal impression (spray model) is coated by means of thermal spraying on its bright and smooth surface with the wearing coating of the intended tool; in that the tool backing is built up on the thermally sprayed wearing coating which backing consists of a plastic which withstands a temperature sufficiently high to fuse the easily fusible metal layer of the spray model; in that the plastic which comprises the tool backing is heated to the temperature at which the easily fusible metal fuses the the tool or tool member thus obtained and furnished with the wearing coating is separated from the spray model.
According to the invention the thermally sprayed wearing coating may consist of a metal, a metal alloy, particularly steel, carbide or oxide.
In one embodiment of the invention the plastic in the layer nearest the wearing coating of the tool is reinforced with silicon carbide, steel fiber, carbon fiber or similar material and in remaining parts with cheaper filling material, e.g. quartz.
The plastic which is advantageously used for the tool backing should be chosen so that it withstands a temperature which exceeds the fusing point of the easily fusible metal or metal alloy by at least 20° C.
The plastic which is used as stiffener for the wearing coating is a plastic which is thermosetting at room temperature and which undergoes final curing at increased temperature and/or has the property of withstanding the temperature required to fuse the easily fusible metal or metal alloy on the spray model.
The invention will be described in greater detail in connection with the attached drawing in which
FIGS. 1-3 represent various steps in the manufacturing of a tool from a working model according to FIG. 1A where FIG. 3 is an exact copy of the part in FIG. 1A.
The working model 10 shown in FIG. 1A is coated with a release coating 11. This working model is coated in FIG. 1B with a thermally sprayed layer 12 of an easily fusible metal or metal alloy. The upper surface of the sprayed layer as seen in the figure thereby becomes somewhat uneven while its under surface facing the working model 10 is smooth and is a copy of the surface of the working model. The thermally sprayed metal layer 12 is thereafter baked into a thermosetting plastic 13 (FIG. 1C) so that the adhesion between the plastic 13 and the sprayed easily fusible metal layer 12 is exceptionally strong as a result of the irregularity of the metal layer. It can thus be said that the plastic 13 engages the sprayed irregularities of the metal layer.
In FIG. 2A the working model 10 has been separated from the "spray model" 13 consisting of plastic baked onto the easily fusible metal layer. This separation has been possible because of the release agent 11 (FIG. 1A). The sprayed model according to FIG. 2A thus consists of hardened plastic 13 and a thermally sprayed metal layer 12, in intimate contact with the plastic 13 and showing a smooth and even surface corresponding to the original surface of the working model 10.
Onto this smooth surface of the easily fusible alloy is now sprayed a wearing coating 14 of metal, metal alloy, particularly steel, carbide or oxide, having a thickness of 2-5 mm (FIG. 2B). When thermally sprayed the wearing coating adheres in an outstanding manner to the micro pores of the easily fusible alloy layer 12 (FIG. 2B) and the wearing coating thereby receives the exact form which the original working model displayed. When the wearing coating 14 has reached sufficient thickness the thermal spraying is discontinued and thermosetting plastic 15 is baked onto the thermally sprayed wearing coating on its "spray side". An intimate adhesion is effected between the sprayed wearing coating and the plastic 15 applied thereto in this case as well. When the plastic 15 has cured the unit--the spray model 13 and the plastic 15--is heated to a temperature which exceeds the fusing point of the easily fusible alloy 12 by at least 20° C. The layer 12 thereupon fuses and the spray model may be separated from the finished tool or tool member 15 according to FIG. 3. A tool according to FIG. 3 is thereby obtained which is an exact copy of the working model according to FIG. 1A. The tool or tool member according to FIG. 3 may, of course, be mounted by conventional means in suitable carriers or fixtures for use.
The layer thicknesses shown in the drawing figures have, in some cases, been exaggerated for the sake of clarity.
One skilled in the art can, of course, appreciate that various modifications can be carried out without departing from the inventive conception as it is defined in the attached claims.

Claims (6)

What I claim is:
1. A method for producing tools for deep drawing, moulding, extruding and the like, comprising forming a working model having a surface the shape of the tool to be produced, coating said surface with a release agent, thermally spraying on said coated surface a thin layer of an easily fusible metal or metal alloy, backing said sprayed layer with a stiffener of heat-resistant plastic, loosening the working model from the sprayed metal layer stiffened with plastic, thermally spraying on said easily fusible layer a wearing layer of the material of the intended tool, to a depth substantially thicker than the depth of said easily fusible layer, backing the wearing layer with a plastic that withstands a temperature sufficiently high to fuse said easily fusible layer, heating the assembly of easily fusible layer and wearing layer and plastic backings to a temperature sufficiently high to fuse said easily fusible layer, and separating the wearing layer and its plastic backing from the easily fusible layer and its plastic backing.
2. A method as claimed in claim 1, said wearing layer consisting of a member selected from the group consisting of a metal, metal alloy, carbide and oxide.
3. A method as claimed in claim 1, in which said wearing layer is steel.
4. A method as claimed in claim 1, and reinforcing said plastic in the layer of plastic nearest said wearing layer with a member selected from the group consisting of silicon carbide, steel fiber, and carbon fiber, and reinforcing the remaining portions of the plastic of the wearing layer backing with quartz.
5. A method as claimed in claim 1, in which both plastic backings resist a temperature at least 20° C. higher than the fusion point of the easily fusible layer.
6. A method as claimed in claim 1, in which the plastic that backs said wearing layer is thermosetting at room temperature.
US05/579,278 1975-05-20 1975-05-20 Method for the production of tools for deep drawing, moulding, extruding and the like Expired - Lifetime US4231982A (en)

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US05/579,278 US4231982A (en) 1975-05-20 1975-05-20 Method for the production of tools for deep drawing, moulding, extruding and the like

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Application Number Priority Date Filing Date Title
US05/579,278 US4231982A (en) 1975-05-20 1975-05-20 Method for the production of tools for deep drawing, moulding, extruding and the like

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Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517027A (en) * 1980-12-16 1985-05-14 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Bulk production of alloys by deposition from the vapor phase and apparatus therefor
US4536364A (en) * 1982-04-30 1985-08-20 Lindskog Kjell J Manufacture of two part mold
US4547941A (en) * 1982-03-18 1985-10-22 Soudbrase-Schweisstechnik Gmbh Method for repairing housings of pumps and the like
US4637907A (en) * 1985-04-05 1987-01-20 Mattel, Inc. Latex dip tooling and method for forming same
US4639345A (en) * 1982-03-24 1987-01-27 Olsen Randolffa Rudolph Interlocking building block system
DE3831192A1 (en) * 1988-09-14 1990-03-22 Hek Gmbh METHOD FOR PRODUCING SHAPES AND SHELLS, FOUNDRY MODELS, CORE SOCKETS AND THE LIKE, WITH STRUCTURED SURFACE
US4987799A (en) * 1989-08-18 1991-01-29 Elliott Soth Stamping die replica and method of manufacture thereof
EP0416957A2 (en) * 1989-09-08 1991-03-13 H.P. Chemie Pelzer Research & Development Ltd. A method and apparatus for the removal of moulded parts from a mould
US5079974A (en) * 1991-05-24 1992-01-14 Carnegie-Mellon University Sprayed metal dies
US5096643A (en) * 1989-05-29 1992-03-17 Burkert Gmbh Werk Ingelfingen Method of manufacturing microvalves
EP0535854A1 (en) * 1991-10-04 1993-04-07 Foseco International Limited Moulds
EP0549981A2 (en) * 1991-12-25 1993-07-07 Nippon Shokubai Co., Ltd. Composition having sprayed metal layer, method for producing therof, and mold release agent used in the production method
US5240668A (en) * 1990-05-04 1993-08-31 Vidrio Plano De Mexico, S.A. Method for forming a mold
EP0668136A1 (en) * 1994-02-04 1995-08-23 The Goodyear Tire & Rubber Company Method and apparatus for making a tire mold
GB2294227A (en) * 1994-10-19 1996-04-24 Rover Group The production of an article using a thermal spray technique
WO1998015372A1 (en) * 1996-10-07 1998-04-16 Hek Gmbh Method and device for making moulds and tools
US5817267A (en) * 1995-11-13 1998-10-06 General Magnaplate Corporation Fabrication of tooling by thermal spraying
GB2343396A (en) * 1998-11-04 2000-05-10 Ford Motor Co Method of spray forming metal deposits using a metallic spray forming pattern
US6171091B1 (en) 1999-05-12 2001-01-09 Callaway Golf Company Replaceable mold cavities and mold cavity inserts
WO2001089746A1 (en) * 2000-05-23 2001-11-29 Gmic, Corp. Improvements in thermal-sprayed tooling
WO2001094089A1 (en) * 2000-06-06 2001-12-13 Plastech Thermoset Tectonics Limited Moulding tooling
DE10317797A1 (en) * 2003-04-16 2004-11-11 AHC-Oberflächentechnik GmbH & Co. OHG Production of mold tools for rapid prototyping comprises roughening of the surface without chemical pretreatment, application of an intermediate copper or nickel layer and application of a metallic or ceramic covering by thermal spraying
US20040238146A1 (en) * 2003-05-05 2004-12-02 Huazhong University Of Science & Technology Method of manufacturing dies and molds by melting-spray
US20060188650A1 (en) * 2003-04-16 2006-08-24 Hartmut Sauer Rapid prototyping process
US20060260780A1 (en) * 2003-04-16 2006-11-23 Hartmut Sauer Use of an object as shaping tool
US20070065635A1 (en) * 2003-04-16 2007-03-22 Hartmut Sauer Object with a stratified composite material
US20070087215A1 (en) * 2003-04-16 2007-04-19 Hartmut Sauer Use of an article as electronic structural part
US20110005533A1 (en) * 2009-07-07 2011-01-13 Evans Douglas J Mold For a Smoking Device
DE102016010506A1 (en) 2016-08-30 2018-03-01 Audi Ag Tool
WO2024035366A1 (en) * 2022-08-10 2024-02-15 Coşkunöz Kalip Maki̇na Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ Concrete mold system and production method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2515017A (en) * 1947-11-29 1950-07-11 Nicholson Celtic Process of making wax negative molds
US3228650A (en) * 1963-03-04 1966-01-11 Gen Motors Corp Die and method for its manufacture
US3343430A (en) * 1965-12-15 1967-09-26 Budd Co Method of making metal forming dies
US3405212A (en) * 1966-02-17 1968-10-08 Weyerhaeuser Co Method of making metal clad tools
US3565978A (en) * 1967-09-11 1971-02-23 Xerox Corp Replication of surface deformation images

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2515017A (en) * 1947-11-29 1950-07-11 Nicholson Celtic Process of making wax negative molds
US3228650A (en) * 1963-03-04 1966-01-11 Gen Motors Corp Die and method for its manufacture
US3343430A (en) * 1965-12-15 1967-09-26 Budd Co Method of making metal forming dies
US3405212A (en) * 1966-02-17 1968-10-08 Weyerhaeuser Co Method of making metal clad tools
US3565978A (en) * 1967-09-11 1971-02-23 Xerox Corp Replication of surface deformation images

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517027A (en) * 1980-12-16 1985-05-14 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Bulk production of alloys by deposition from the vapor phase and apparatus therefor
US4547941A (en) * 1982-03-18 1985-10-22 Soudbrase-Schweisstechnik Gmbh Method for repairing housings of pumps and the like
US4639345A (en) * 1982-03-24 1987-01-27 Olsen Randolffa Rudolph Interlocking building block system
US4536364A (en) * 1982-04-30 1985-08-20 Lindskog Kjell J Manufacture of two part mold
US4637907A (en) * 1985-04-05 1987-01-20 Mattel, Inc. Latex dip tooling and method for forming same
EP0423390A1 (en) * 1988-09-14 1991-04-24 HEK GmbH Process for fabricating moulds, shell-moulds, foundry patterns, core boxes etc., having a structured surface
DE3831192A1 (en) * 1988-09-14 1990-03-22 Hek Gmbh METHOD FOR PRODUCING SHAPES AND SHELLS, FOUNDRY MODELS, CORE SOCKETS AND THE LIKE, WITH STRUCTURED SURFACE
US5096643A (en) * 1989-05-29 1992-03-17 Burkert Gmbh Werk Ingelfingen Method of manufacturing microvalves
US4987799A (en) * 1989-08-18 1991-01-29 Elliott Soth Stamping die replica and method of manufacture thereof
EP0416957A2 (en) * 1989-09-08 1991-03-13 H.P. Chemie Pelzer Research & Development Ltd. A method and apparatus for the removal of moulded parts from a mould
EP0416957A3 (en) * 1989-09-08 1991-08-28 H.P. Chemie Pelzer Research & Development Ltd. A method and apparatus for the removal of moulded parts from a mould
US5240668A (en) * 1990-05-04 1993-08-31 Vidrio Plano De Mexico, S.A. Method for forming a mold
US5079974A (en) * 1991-05-24 1992-01-14 Carnegie-Mellon University Sprayed metal dies
EP0535854A1 (en) * 1991-10-04 1993-04-07 Foseco International Limited Moulds
EP0549981A2 (en) * 1991-12-25 1993-07-07 Nippon Shokubai Co., Ltd. Composition having sprayed metal layer, method for producing therof, and mold release agent used in the production method
EP0549981A3 (en) * 1991-12-25 1994-02-23 Chugoku Kako Co Ltd
US5296178A (en) * 1991-12-25 1994-03-22 Chugoku Kako Co., Ltd. Method of making a mold by spraying metal using a particulate mold release agent
EP0668136A1 (en) * 1994-02-04 1995-08-23 The Goodyear Tire & Rubber Company Method and apparatus for making a tire mold
GB2294227B (en) * 1994-10-19 1998-05-27 Rover Group The production of an article using a thermal spray technique
GB2294227A (en) * 1994-10-19 1996-04-24 Rover Group The production of an article using a thermal spray technique
US5817267A (en) * 1995-11-13 1998-10-06 General Magnaplate Corporation Fabrication of tooling by thermal spraying
WO1998015372A1 (en) * 1996-10-07 1998-04-16 Hek Gmbh Method and device for making moulds and tools
GB2343396A (en) * 1998-11-04 2000-05-10 Ford Motor Co Method of spray forming metal deposits using a metallic spray forming pattern
US6155330A (en) * 1998-11-04 2000-12-05 Visteon Global Technologies, Inc. Method of spray forming metal deposits using a metallic spray forming pattern
US6171091B1 (en) 1999-05-12 2001-01-09 Callaway Golf Company Replaceable mold cavities and mold cavity inserts
WO2001089746A1 (en) * 2000-05-23 2001-11-29 Gmic, Corp. Improvements in thermal-sprayed tooling
US6447704B1 (en) 2000-05-23 2002-09-10 Gmic, Corp. Thermal-sprayed tooling
US20020150645A1 (en) * 2000-05-23 2002-10-17 Gmic, Corp. Thermal-sprayed tooling
US20050127562A1 (en) * 2000-05-23 2005-06-16 Gmic Corp. Forming a molded article using improved thermal-sprayed tooling
US7311870B2 (en) 2000-05-23 2007-12-25 Gmic, Corp. Forming a molded article using improved thermal-sprayed tooling
US6871830B2 (en) 2000-05-23 2005-03-29 Gmic, Corp. Thermal-sprayed tooling
WO2001094089A1 (en) * 2000-06-06 2001-12-13 Plastech Thermoset Tectonics Limited Moulding tooling
DE10317797A1 (en) * 2003-04-16 2004-11-11 AHC-Oberflächentechnik GmbH & Co. OHG Production of mold tools for rapid prototyping comprises roughening of the surface without chemical pretreatment, application of an intermediate copper or nickel layer and application of a metallic or ceramic covering by thermal spraying
DE10317797B4 (en) * 2003-04-16 2005-06-30 AHC-Oberflächentechnik GmbH & Co. OHG Rapid prototyping process
US20060188650A1 (en) * 2003-04-16 2006-08-24 Hartmut Sauer Rapid prototyping process
US20060260780A1 (en) * 2003-04-16 2006-11-23 Hartmut Sauer Use of an object as shaping tool
US20070065635A1 (en) * 2003-04-16 2007-03-22 Hartmut Sauer Object with a stratified composite material
US20070087215A1 (en) * 2003-04-16 2007-04-19 Hartmut Sauer Use of an article as electronic structural part
US20040238146A1 (en) * 2003-05-05 2004-12-02 Huazhong University Of Science & Technology Method of manufacturing dies and molds by melting-spray
US20110005533A1 (en) * 2009-07-07 2011-01-13 Evans Douglas J Mold For a Smoking Device
DE102016010506A1 (en) 2016-08-30 2018-03-01 Audi Ag Tool
WO2024035366A1 (en) * 2022-08-10 2024-02-15 Coşkunöz Kalip Maki̇na Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ Concrete mold system and production method

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