US3926547A - Method and apparatus for space dyeing yarn - Google Patents

Method and apparatus for space dyeing yarn Download PDF

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Publication number
US3926547A
US3926547A US429934A US42993474A US3926547A US 3926547 A US3926547 A US 3926547A US 429934 A US429934 A US 429934A US 42993474 A US42993474 A US 42993474A US 3926547 A US3926547 A US 3926547A
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United States
Prior art keywords
skeins
dye bath
bank
color
immersed
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US429934A
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Gerard M O'mahony
James G T Paterson
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INTERDYE Tech CORP
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INTERDYE Tech CORP
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Priority to US429934A priority Critical patent/US3926547A/en
Priority to GB43606/74A priority patent/GB1482957A/en
Priority to AU74195/74A priority patent/AU479266B2/en
Priority to NL7416911A priority patent/NL7416911A/en
Priority to DE19742461598 priority patent/DE2461598A1/en
Priority to JP50001060A priority patent/JPS5095590A/ja
Priority to DK689174A priority patent/DK689174A/da
Priority to SE7416379A priority patent/SE7416379L/xx
Priority to BE152046A priority patent/BE823990A/en
Priority to FR7443317A priority patent/FR2256282B1/fr
Priority to CH781776A priority patent/CH588590A5/xx
Priority to US05/610,315 priority patent/US3986375A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0043Treatment of selected parts of textile materials, e.g. partial dyeing of hanks of yarns
    • D06B11/0046Treatment of selected parts of textile materials, e.g. partial dyeing of hanks of yarns hung on supports
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/929Carpet dyeing

Definitions

  • ABSTRACT A method and apparatus for producing randomly or space dyed skeins of yarn and wherein the skeins are initially arranged to form a bank of side by side, downwardly hanging skeins, and the bank is then completely immersed in a heated aqueous bath to bulk and heat set the yarns. The bank is then removed from the aqueous bath and completely immersed in a first dye bath to apply a first color to the entire skein.
  • the bank When the first dye bath is substantially exhausted, the bank is lifted and a second dyestuff is added directly to the 5 References Cited exhausted first dye bath to form a second dye bath which is adapted to color the yarn a second predeter- UNITED STATES PATENTS mined color.
  • the bank is then partially immersed in 1,906,492 5/1933 Spmdler 8/1552 the second dye h to a predetermined depth and 3:332 llvebber 25 the bank may be tilted so that some of the skeins are 27l6585 8/1955 5 I sll'4 further immersed than others so that the skeins have 31012503 12/1961 whitak'i'1ZifIIIIIIIIIIIIIIIII'ism varyingmb' f abOVe procedure may 3,356,444 12/1967 Haworth et 8/14 x repeated for pp y addmoflal colors to the Y If 3,541,635 11/1970 Crenshaw et a1.
  • the present invention relates to a method for producing randomly or space dyed yarns suitable for use in fabricating multi-colored shag type tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the ability to substantially alleviate visible streaks on the face of the finished carpet caused by a similar repeating color pattern on the yarns.
  • One common process of this type is called the knit de knit" process, and includes the steps of knitting the yam into a knitted prefabric, applying stripes or other patterns of dye on the fabric by a printing operation, heat setting the dye, and then unraveling the fabric to produce a space dyed yarn.
  • the heat setting operation tends to set permanent kinks or curls in the yam due to the loops produced in knitting, and it is common to attempt to subsequently remove these kinks by various processes such as running the kinked yarn over a series of comers.
  • a typical process of this type is further described in the U.S. Patents to Whitaker et al., US. Pat. Nos. 3,012,303 and 3,102,322.
  • Another commonly employed process for producing space dyed yarns involves passing a large number (or warp) of yarns in a parallel arrangement through a series of dye applicators that are charged with dyes of different colors. As the warp of yarns passes through the machine, predetermined portions are pressed into contact with selected applicators to achieve the desired space printing. The yarns are then steamed to fix the dye.
  • a typical process of this type is disclosed in the US. Patent to Farrer et al., US. Pat. No. 3,503,232.
  • the skeins are initially heated in a dry heating apparatus or autoclave to bulk and heat set the yarns. and the skeins are then mounted on a rack and completely immersed in a liquid dye bath which contains a dyestuff adapted to apply the lightest shade of the color selection involved.
  • the temperature of the dye bath when the skeins are immersed is necessarily relatively low, for example about F and the temperature must then be gradually increased at a rate of about 2 per minute to the boiling temperature. which is about 220 F. It is not possible to immerse the skeins in a bath having a temperature above about 120 F., since at an elevated temperature the dye will tend to jump on" the yarn when it is immersed. and thus the dye will not be applied evenly.
  • the skeins After reaching the boiling temperature, the skeins are held immersed for about ten minutes to exhaust the dyestuff. The bath is then dropped, the skeins lifted, and a fresh load of water is run into the vat and its temperature adjusted to about 120 F. A second dyestuff is then added which when overdyed on the previously dyed yarns will give the desired color of the next darkest shade. The skeins are partially immersed in the second bath, and the temperature again slowly raised to the boiling temperature and held for another ten minutes to exhaust the dyestuff. The above procedures are repeated for the third and any subsequent dyeing operations, differing only in that each subsequent skein immersion is less than in the preceeding operation.
  • skein dyeing is able to achieve deep, bright colors in the dyed yarns, this advantage arising from the fact that skein dyeing takes place under optimum conditions of time, temperature, and dye exhaustion which cannot be achieved in a printing operation. Also, skein dyeing results in a high bulk which arises from the relaxed, tension free conditions which exist while the yarn is in skein form and being dyed.
  • skein dyeing has not been extensively employed since as presently practiced it produces a similar long space" repeating color pattern on all of the yarns which has a tendency to produce streaks or chevrons on the face of the finished pile fabric. More particularly, where such a repeating color pattern is present on the yarns, the colors of adjacent yarns in the finished fabric tend to get into and out of phase in a regular sequence, and this produces visible streaks. Such streaks are not as pronounced where a short space" color pattern is achieved, and such short space” pattern is easily produced by the above dye printing operations.
  • the skein dyeing process as presently practiced has a very low production rate as compared to that of the printing processes.
  • skein dyeing possesses recognized advantages, it has not found commercial acceptance because of these overriding disadvantages.
  • a bank of skeins is initially immersed in a heated aqueous bath to bulk and heat set the yarns.
  • the bank is then removed from the aqueous bath and a dyestuff is added thereto so that a first dye bath is formed from the aqueous bath.
  • the bank is then completely immersed in the first dye bath to apply a first color to the entire skeins, and the bank is maintained therein until the dye bath is substantially exhausted.
  • the bank is then lifted from the exhausted first dye bath and a second dyestuff is added to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color.
  • the bank is then partially immersed in the second dye bath so that the second dye bath acts to color only the immersed portions of the skeins.
  • provision is made for tilting the bank of skeins so that some of the skeins are further immersed than others.
  • the bank is again lifted and a third dyestuff is added to the exhausted dye bath, and the bank is then again partially immersed in the third dye bath to a level less than the skeins were immersed in the second dye bath.
  • the bank may be tilted into a somewhat different orientation than was the case when the bank was partially immersed in the second dye bath. The above procedure may be repeated for applying additional colors to the yarns if so desired.
  • FIG. 1 is a schematic flow diagram illustrating the basic steps of a process embodying the present invention
  • FIGS. 2, 2A and 2B illustrate the sequence for applying three colors to the skeins in accordance with the present invention and wherein the bank of skeins is not tilted;
  • FIGS. 3, 3A and 3B are similar to FIGS. 2, 2A and 2B, but illustrate the effect of tilting the bank of yarn skeins during the second and third dyeing operations;
  • FIG. 4 is a perspective view of a skein dyeing apparatus which embodies the features of the present invention.
  • FIG. 5 is a perspective view of one skein rack and a portion of the overhead lifting harness of the apparatus as shown in FIG. 4;
  • FIG. 6 is a fragmentary, exploded, perspective view showing the manner in which the skein rack rests upon the underlying dye tubes of the carriage;
  • FIG. 7 is an end view of arrangement shown in FIG.
  • FIGS. 8-11 are schematic perspective views illustrating the various ways in which the skein rack may be tilted with respect to the dye bath to achieve varying color patterns on the skeins;
  • FIG. 12 is an exploded perspective view of the lifting harness, skein racks, carriage, and dye vat of the apparatus illustrated in FIG. 4;
  • FIG. 13 is a schematic view illustrating the use of power jacks for tilting the bank of skeins along one axis.
  • FIG. 14 is a view similar to FIG. 13 but illustrating the use of fourpower jacks so that the skein rack may be selectively tilted along two axes.
  • FIGS. 4-7 and 12 an apparatus embodying the features of the present invention is illustrated in FIGS. 4-7 and 12.
  • the illustrated apparatus includes an open, rectangular dye vat 20 which is adapted to receive a dye bath 2] or other liquid therein.
  • the vat itself is generally conventional, and includes a suitable inlet and outlet (not shown) for facilitating the filling and emptying of the liquid, and a false bottom wall 22 having a plurality of openings 23 therein and through which the liquid is able to freely pass to the area beneath the wall 22.
  • An external dye bowl 24 is provided for permitting a dyestuff to be added to the liquid in the vat, and a circulation system is provided which includes a pump 25 and a pair of outlet openings 26 in the bottom" wall 22 for the purposes hereinafter set forth.
  • a heating coil (not shown) may be positioned beneath the false bottom wall 22 to provide means for heating the liquid in the vat.
  • a carriage 28 is removably mounted within the vat 20 such that the entire carriage may be vertically translated into the vat to assume an operative position as hereinafter further described.
  • the carriage 28 includes a base 29 which is adapted to rest upon the bottom wall 22 of the vat when the carriage is placed in its operative position within the vat, a plurality of vertical posts 30 extending upwardly from the base 29, and a horizon tally directed tubular manifold 32.
  • the base 29 includes a pair of downwardly facing openings at 31 which are adapted to cooperate with the openings 26 in the bottom wall 22 when the carriage is received in the vat in its operative position so that the liquids pumped upwardly through the openings 26 will enter the openings in the base 29.
  • the base 29 and vertical posts 30 include an internal passageway (not shown) such that the liquid may be directed upwardly from the openings 31 in the base 29 to the manifold 32.
  • Three upwardly directed lifting brackets 33 are fixedly carried on the upper surface of the manifold 32, and a plurality of spaced apart, parallel dye tubes 34 emanate outwardly from each side of the manifold to define two oppositely extending rows of tubes 35 and 36.
  • the tubes extend horizontally, and are designed to be positioned somewhat below the liquid level of the bath 21 when the vat is substantially filled and the carriage 28 is positioned therewithin in its operative position.
  • each dye tube is hollow and communicates with the hollow manifold 32.
  • each dye tube includes a row of spaced apertures 38 extending along the upper surface thereof.
  • the vat 20 and carriage 28 include a cooperating circulation system for continuously circulating the liquid in the vat through the carriage and outwardly through the apertures 28 in the dye tubes 34. More particularly, the liquid in the vat flows through the openings 23 in the false bottom wall 22, and is directed by the pump 25 upwardly through the outlet openings 26. The liquid is then channeled into the manifold 32 and hollow dye tubes 34, and then upwardly through the apertures 28 to return to the vat.
  • the illustrated apparatus further includes a total of four racks which are configured so as to be able to supportingly rest upon the carriage. More particularly, each rack is designed to overlie one-half of the area of each of the rows 35, 36 of tubes as best seen in FIG. 12. Also, each rack 40 comprises a rectangular framework which includes a plurality of transversely spaced apart, parallel arms 42 of substantially equal length. The arms 42 are aligned in the transverse direction such that the ends thereof define a rear edge and a forward edge of the framework, and each arm 42 comprises two transversely spaced apart, parallel rods 44, 45 as best seen in FIGS. 57.
  • an arcuately shaped saddle 46 is carried at each end of each arm to interconnect the two rods, and the saddle at the forward edge of each arm includes an upwardly directed tab 47 which extends between the two rods.
  • An aperture 48 extends transversely through the tab for the purposes hereinafter set forth.
  • a rear brace 49 extends along the rear edge of the rack and is fixedly interconnected to each of the arms.
  • a forward brace 50 extends along the forward edge of the rack and is releasably connected to each of the arms. More particularly, the forward brace 50 includes a transversely extending angle beam 51 having a plurality of slots 52 therein, with each slot being adapted to receive the apertured tab 47 of one of the arms 42.
  • a cylindrical retaining rod 54 is adapted to then extend through the apertures 48 in the tabs 47 of each arm to maintain the assembly of the angle beam 51 and thus the forward brace 50 to the rack.
  • the forward brace 50 may be removed by simply withdrawing the rod 54 and lifting the brace away.
  • Both the rear brace 49 and forward brace 50 include a pair of spaced U-shaped lifting rings 56 for supporting the rack in a manner hereinafter further described.
  • the lifting rings 56 are positioned adjacent the ends of each associated brace, and thus one is positioned adjacent each of the four comers of the rectangular framework of the rack 40.
  • the arms 42 of each rack are arranged to conform to the arrangement of the dye tubes 34 on the carriage 28 such that the rack may be positioned to supportingly rest upon the carriage.
  • the saddles 46 on the arms conform to the curvature of the cylindrical dye tubes to prevent relative shifting movement, and the rods 44, 45 of each arm are positioned to lie along each side of the row of apertures 38 in the underlying dye tube so that the arm does not interfere with the upward flow of the liquid from the apertures in the dye tube.
  • the above structure of the rack and dye tubes permits a plurality of skeins S of textile yarn to be positioned to encircle each arm and its associated dye tube to thereby form a bank of adjacent, side by side, downwardly hanging skeins as best seen in FIG. 4.
  • the skeins may be arranged to form such bank by removing the forward brace 50 in the above described manner, and then sliding the skeins axially along each arm and underlying dye tube.
  • the illustrated apparatus further includes a lifting harness 60 which is adapted to be positioned above the vat for independently supporting all of the racks 40. More particularly, the lifting harness 60 includes a horizontally directed central I-beam 62, and four transversely extending support arms 64 which are fixedly attached to the I-beam in the manner best seen in FIG. 4. In addition, a total of three lifting brackets 65 are fixedly attached to the I-beam and positioned in spaced relation along the length thereof.
  • Each of the support arms 64 includes provision for mounting a pair of spaced cables or chains 66 from each side of the I-beam.
  • the chains 66 extend downwardly from the harness and are attached to the lifting rings 56 of the racks 40 so that the racks may be releasably interconnected to the harness. More particularly, each chain 66 is looped through one of the lifting rings, and a hook 68 is attached at the lower end of each chain so that the chain may be adjusted in effective length by manually adjusting the point at which the hook is interconnected to the chain.
  • the orientation of each rack 40 may be manually adjusted such that the rack may be tilted along either of two different axes in relation to the liquid level in the vat 20.
  • each rack may be totally released from the harness so that the racks rest upon and are entirely supported by the carriage in the manner described above.
  • An electric hoist 70 or the like is slideably carried by a beam 72 which is fixedly positioned above the vat 20 in the manner best seen in FIG. 4.
  • the hoist 70 includes a downwardly directed cable 74 and hook 75 which may be lowered and elevated in a conventional manner. Also, three cables 77, 78, and 79 extend from the hook 75 to the lifting brackets 65 on the harness 60. By this arrangement, the operator of the apparatus is able to lower or lift the harnessand thus the racks in a selected manner.
  • the hoist and cables 77, 78 and 79 may be attached to the lifting brackets 33 of the carriage 28 so that the entire carriage 28 and supported skein racks 40 may be vertically translated into and out of the vat.
  • a method of randomly dyeing a plurality of skeins of textile yarn employing the above apparatus and in accordance with the present invention will now be described.
  • the method and apparatus of the present invention is particularly suited for space dyeing nylon and polyester yarn, although it is also suitable for processing wool, cotton, acrylic, and other polymeric yarns.
  • the carriage 28 with the racks 40 resting thereon is initially lifted from the vat 20 and placed on a wheeled dolly (not shown) so that the entire assembly may be easily transported to a suitable work area.
  • the front brace 50 of each of the racks 40 is removed after withdrawing the retaining rods 54.
  • the yarns are skeined in a conventional manner, and the individual skeins are loaded onto the assembly by sliding the skeins axially onto each arm and its underlying dye tube so as to encircle the same and form a bank of side by side, downwardly hanging skeins.
  • the front brace 50 is lowered over the tabs 47 and attached to the rack by inserting the rod 54.
  • the loaded carriage is then wheeled back to the vat 20 where the hoist 70 is attached by interconnecting the cables 77, 78, and 79 to 7 the lifting brackets 33 of the carriage.
  • the assembly is then lifted, moved into position over the vat 20, and dropped into the vat so that the carriage assumes its operative position.
  • the vat initially contains boiling water, and the skeins are completely immersed therein for a period of about ten minutes to bulk and heat set the yarn.
  • the circulation system will be directing the water upwardly through the apertures 38 in each of the dye tubes so that the skeins effectively float above the arms and dye tube. Thus there is little or no tension on the yarns to resist the development of bulk.
  • the operator removes the cables 77, 78, and 79 from the carriage and attaches the same to the lifting bracket 65 of the harness 60 which may be positioned immediately adjacent the vat.
  • the harness is then lifted by the hoist 70 to a position immediately above the vat, and the chains 66 are inserted through the lifting rings 56 of the racks and the hooks 68 attached at a predetermined point to form a connection of predetermined length. Normally, at this point in the process, the chains would be connected so that the racks would remain substantially level when the harness is lifted.
  • the harness 60 may be lifted by the hoist 70 so that the skeins are substantially completely withdrawn from the aqueous bath so as to facilitate circulation of the subsequently added dyestuff as described below. Since the dye tubes 34 are normally positioned below the level of the bath, it would be necessary to drop a portion of the bath from the vat if the skeins were to be completely withdrawn therefrom, however, complete withdrawal is not generally necessary.
  • the water in the vat is cooled to about 180 F. by adding cold water, and a concentrated dyestufi' is added to the cooled liquid through the bowl 24.
  • the harness 60 is then lowered so that the bank of skeins is completely immersed in the first dye bath. 'The temperature of the bath is then raised at a rate of about 2 per minute to the boiling temperature of the bath which is about 220 F.
  • the bank of skeins is maintained in the boiling dye bath until the dye bath is substantially exhausted, and this normally takes about ten minutes after the bath reaches the boiling temperature.
  • the circulation system causes the dye bath to be directed upwardly through the apertures 38 in the dye tubes to thereby lift the skeins out of substantial contact with the arms and tubes. This lifting action removes any tension in the yarn, and it insures that there will be no stagnant areas where the skeins contact the arm or tube and which could result in shade variation or stick marking at that point.
  • the initial dye bath may be maintained at a temperature of about l80 F. when the skeins are immersed since the yarn has been partially swelled by the bulking and heat setting operation, and it is in a highly receptive state wherein the dye may be applied in a level fashion at an elevated temperature.
  • This fact serves to substantially reduce the time required to raise the bath to the boiling temperature of 220 F. as compared to the above described conventional skein dyeing process, and thus the production time of the present dyeing operation is substantially reduced.
  • the bank of skeins Upon exhaustion of the first dye bath, the bank of skeins is at least partially withdrawn therefrom, and typically the bank is completely withdrawn from the exhausted dye bath by lifting the harness and dropping a small portion of the bath from the vat so as to achieve maximum circulation.
  • a second dyestuff is then added to the exhausted first dye bath through the bowl 24, and by design, the second dyestuff is adapted to provide the desired color and shade when added to the exhausted first dye bath to color the yarn a second predetermined color.
  • the heated first bath is not dropped and lost, but is utilized in the subsequent dyeing operations to further increase the efficiency of the process.
  • the bank of skeins is then partially immersed in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins.
  • the rack may be oriented or tilted in relation to the liquid level so that some of the skeins are partially immersed in the second dye bath further than others, whereby the skeins have a varying color pattern as illustrated for example in FIG. 3A.
  • This adjustment of die orientation of the rack may be accomplished by manually changing the effective length of the chains 66.
  • the skeins may be initially positioned in the orientation desired for the second dyeing operation while they are partially immersed in the exhausted first dye bath, and the second dyestuff may then be added in the bowl 24. Also, through care ful selection of the second dyestuff, and since the fiber is in a highly receptive state, it is not necessary to cool the bath to 180 F. and heat it slowly to the boiling point in order to get level dyeing as was required in the case of the first dyeing operation. Thus the dye bath may be maintained at the boil and the time requirement for the second dyeing operation is thereby significantly reduced.
  • a third dyeing operation may be performed by repeating the steps of the second operation.
  • the added third dyestuff would be designed to provide the desired third color and shade when added to the exhausted second dye bath.
  • the orientation of the racks may be changed from that employed in the second dyeing operation so that those skeins which were partially immersed further in the second dye bath are not among those which are partially immersed further in the third dye bath. This serves to further vary the color patterns of the skeins, note for example, the skeins illustrated in FIG. 3B.
  • each skein is immersed in the third dye bath to a level less than such skein was immersed in the second bath so that only the lowermost portions of the skeins will be overdyed with the third dyestuff.
  • the arrangement or rotational orientation of the skeins on the racks should not be disturbed between the second and third dyeing operations if the desired color pattern is to be achieved. While three dyeing operations have been described herein, it will be appreciated that additional dyeing operations could be employed where a larger number of colors is desired.
  • the dye bath is dropped from the vat 20, and the harness 60 is removed by disconnecting the chains 66 from the racks 40 and the cables 77, 78, and 79 from the harness.
  • the hoist 70 is then connected to the lifting brackets 33 of the carriage, and the loaded carriage and racks are lifted from the vat and again positioned on the wheeled dolly for transport to a work area.
  • the forward braces 50 are removed from the racks, and the skeins may then be withdrawn from the arms.
  • the skeins are typically then subjected to conventional water extracting and drying operations. In the case of certain fibers such as polyester, it may also be necessary to rinse the skeins prior to water extraction to remove certain carriers and other chemicals before the yarn is dried.
  • the aqueous bath employed in bulking and heat setting the yarns is utilized in the subsequent space dyeing operation.
  • a separate bulking and heat setting bath may be provided which is continuously kept charged with boiling water.
  • a single bulking and heat setting bath would serve several vats filled with the dye bath, and the carriage 28 and racks 40 with the loaded skeins would be transferred from the heat setting bath to the dye vat after the bulking and heat setting operation is completed.
  • FIGS. 8-1 1 schematically illustrate the various ways in which each of the racks 40 may be tilted to achieve varying color patterns in the bank of skeins.
  • the chains 66 to the four comers of the rack are of equal length so that the rack is substantially level. Such orientation would be employed to achieve the similar color patterns in the skeins as shown in FIGS. 2, 2A, and 2B.
  • the two far side chains have been shortened an equal amount so that the rack is tilted along the transverse axis.
  • the two chains along the far end have been shortened to tilt the rack along the longitudinal axis, and in FIG. 11, three of the chains have been shortened to tilt the rack about both the longitudinal and transverse axes.
  • FIG. 13 represents an arrangement for facilitating the orientation of the racks, and includes a pair of power jacks 82, 83 which are adapted to raise and lower the associated connecting rods 82, 83' so that the rack may be rotated about the longitudinal axis.
  • the jacks 82, 83 may be connected to suitable controls to permit the operator to adjust the orientation from a remote location.
  • FIG. 14 shows an arrangement similar to that shown in FIG. 13 but including four power jacks 85, 86, 87 and 88 so that each corner of the rack may be independently raised and lowered to permit rotation about both the longitudinal and transverse axes.
  • the use of a system of power jacks as shown in FIGS. 13 and 14 lends itself to an automated program control to further increase the efiiciency of the process.
  • a yellow dyestuff such as Disperse Yellow 3 may be added to the aqueous bath employed in the bulking and heat setting operation to initially apply a yellow shade as seen at 91 in FIGS. 2 and 3.
  • the second dyestuff may comprise a blue, such as Acid Blue 27. When blue is overdyed upon yellow, a green shade 92 will result as seen in FIGS. 2A and 3A.
  • a red such as Acid Red 57 may be employed. When the red is overdyed upon the green, a brown color 93 will be produced as seen in FIGS. 28 and 3B.
  • the resulting skeins will thus be dyed yellow on the uppermost portions, green along the mid portions, and brown on the lowermost portions.
  • the amount of dyestuff added to the bath will be about 0.25 percent of the weight of the yarn to be dyed for each of the above colors.
  • the dye bath 21 may also include suitable wetting agents, PH control agents, and other chemicals as well known in the art.
  • the above described process and apparatus can also be employed in a resist or indirect space dyeing process.
  • the resist chemicals would be applied as the dyestufi' in the above described process.
  • the skeins will become space sensitized to specific dyestuffs.
  • the space sensitized skeins are immersed in a dye bath containing all of the various colored dyestuffs to which it has been sensitized, and in this way the skeins become space dyed.
  • the process and apparatus of the present invention also lends itself to a related fonn of space dyeing which is termed shade variation or withdrawal dyeing.
  • shade variation or withdrawal dyeing.
  • only one color of the dyestufi is used, and the immersion time of the various portions of the skeins in the bath is varied.
  • a continuous shade variation from near white to the full color development of complete dyeing may be obtained by slowly withdrawing the skeins out of the dye bat as the dyeing proceeds.
  • the top of the skeins will receive little or no dyestuff while the bottom portions will be completely dyed, and there will be a continuous shade variation therebetween.
  • this shade variation may be obtained by a short incremental withdrawal, instead of a continuous withdrawal, and by tilting the rack during the withdrawal operation, some of the skeins will be partially immersed further than others during the withdrawal operation such that the skeins will have varying color patterns.
  • a method of producing space dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the substantial elimination of streaks on the face of the resulting carpet caused by a similar repeating color pattern on the yarns comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a first dye bath to apply a first color to the entire skeins, and then partially immersing the bank in a second dye bath of a color different from that of the first dye bath and so that some of the skeins are partially immersed further than others to thereby apply a second color only to the immersed portions of the skeins and such that the skeins have varying color patterns.
  • step of bulking and heat setting the yarn includes completely immersing the bank of skeins in a heated aqueous bath.
  • a method of producing spaced dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted,
  • a method of producing space dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a heated aqueous bath to bulk and heat set the yarns, then 12 completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted,
  • each skein is immersed to a level less than such skein was immersed in the second dye bath and wherein some of the skeins are partially immersed in the third dye bath further than others to thereby apply a third color only to the immersed portions of the skeins and to further vary the color patterns of the skeins.
  • a method of producing space dyed yarns suitable for use in fabricating tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the substantial elimination of streaks on the face of the resulting carpet caused by a similar repeating color pattern on the yarns comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a dye bath, and

Abstract

A method and apparatus for producing randomly or space dyed skeins of yarn and wherein the skeins are initially arranged to form a bank of side by side, downwardly hanging skeins, and the bank is then completely immersed in a heated aqueous bath to bulk and heat set the yarns. The bank is then removed from the aqueous bath and completely immersed in a first dye bath to apply a first color to the entire skein. When the first dye bath is substantially exhausted, the bank is lifted and a second dyestuff is added directly to the exhausted first dye bath to form a second dye bath which is adapted to color the yarn a second predetermined color. The bank is then partially immersed in the second dye bath to a predetermined depth, and the bank may be tilted so that some of the skeins are further immersed than others so that the skeins have varying color patterns. The above procedure may be repeated for applying additional colors to the yarns if so desired.

Description

United States Patent 1191 OMahony et al.
[ METHOD AND APPARATUS FOR SPACE DYEING YARN [75] Inventors: Gerard M. OMahony, Dalton, Ga.; James G. T. Paterson, Chattanooga, Tenn.
[73] Assignee: Interdye Technology Corporation,
Dalton, Ga.
[22] Filed: Jan. 2, 1974 [21] Appl. No.: 429,934
[52] US. Cl. 8/14; 8/149; 8/1552; 28/75 WT; 68/188; 68/199 [51] Int. Cl." D06B 11/00 [58] Field of Search 8/14, 149, 150, 15, 155.2; 28/75 WT; 68/188, 197, 199, 206, 159, 165,
[ Dec. 16, 1975 Primary Examiner-Harvey C. Homsby Assistant Examiner-Philip R. Coe
Attorney, Agent, or Firm-Parrott, Bell, Seltzer, Park & Gibson [5 7] ABSTRACT A method and apparatus for producing randomly or space dyed skeins of yarn and wherein the skeins are initially arranged to form a bank of side by side, downwardly hanging skeins, and the bank is then completely immersed in a heated aqueous bath to bulk and heat set the yarns. The bank is then removed from the aqueous bath and completely immersed in a first dye bath to apply a first color to the entire skein. When the first dye bath is substantially exhausted, the bank is lifted and a second dyestuff is added directly to the 5 References Cited exhausted first dye bath to form a second dye bath which is adapted to color the yarn a second predeter- UNITED STATES PATENTS mined color. The bank is then partially immersed in 1,906,492 5/1933 Spmdler 8/1552 the second dye h to a predetermined depth and 3:332 llvebber 25 the bank may be tilted so that some of the skeins are 27l6585 8/1955 5 I sll'4 further immersed than others so that the skeins have 31012503 12/1961 whitak'i'1ZifIIIIIIIIIIIIIIIIIIII'ism varyingmb' f abOVe procedure may 3,356,444 12/1967 Haworth et 8/14 x repeated for pp y addmoflal colors to the Y If 3,541,635 11/1970 Crenshaw et a1. s/|ss.2 SO desired- FORElGN PATENTS OR APPLICATIONS 16 Claims 18 Drawing Figures 1,958,649 5/1971 Germany 8/15 B DYE SKEINING ULK AND COMPLETESKElNS HEAT SET WH'H Fnesr Comte OveeoYE EXTRACT PREDETEBMISNED Peer/ens REPEAT Swap 4 DYE- OF KEINS D WITH SECOND (101.012, As REQU'R'ED AN DRYSKENS DYE- COMPLETE SKE NS WITH FIRST COLOR,
BULK AND HEAT SET ExTraAcT DYE AND DEYSKEINS REPEAT STEP 4 As REQUIRED SKEINING OVERDYE PEEDETEENINED DOBTIONS oFSKEms WITH SECOND (101.012
US. Patent Dec. 16,1975 Sheet 2 of4 3,926,547
aw w. s
US. Patent Dec. 16, 1975 Sheet 3 of4 3,926,547
wfiww M r W m METHOD AND APPARATUS FOR SPACE DYEING YARN The present invention relates to a method for producing randomly or space dyed yarns suitable for use in fabricating multi-colored shag type tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the ability to substantially alleviate visible streaks on the face of the finished carpet caused by a similar repeating color pattern on the yarns.
There are several known processes for producing space dyed yarn for use in fabricating multi-colored fabrics. One common process of this type is called the knit de knit" process, and includes the steps of knitting the yam into a knitted prefabric, applying stripes or other patterns of dye on the fabric by a printing operation, heat setting the dye, and then unraveling the fabric to produce a space dyed yarn. The heat setting operation tends to set permanent kinks or curls in the yam due to the loops produced in knitting, and it is common to attempt to subsequently remove these kinks by various processes such as running the kinked yarn over a series of comers. A typical process of this type is further described in the U.S. Patents to Whitaker et al., US. Pat. Nos. 3,012,303 and 3,102,322.
Even where attempts are made to remove as many of the kinks and curls as possible from knit de knit" yarn, the resulting yarn nevertheless possesses a considerable amount of kinking, and such kinking is unsuitable in many applications such as where long shag or plush carpets are to be constructed from the yarn. Further, the attempts to remove the kink tend to draw out the yarn, and thus a considerable portion of the bulk or covering ability of the yarn is lost.
One further disadvantage of the knit de knit" process is the fact that the colors are applied by a printing operation, and such operation by its very nature is unable to achieve thorough penetration of the dye into the yarn. Also, when certain yarns such as nylon are printed, true colors are not achieved due to a "frosting or halo effect which is caused by the printing mechanism.
Another commonly employed process for producing space dyed yarns involves passing a large number (or warp) of yarns in a parallel arrangement through a series of dye applicators that are charged with dyes of different colors. As the warp of yarns passes through the machine, predetermined portions are pressed into contact with selected applicators to achieve the desired space printing. The yarns are then steamed to fix the dye. A typical process of this type is disclosed in the US. Patent to Farrer et al., US. Pat. No. 3,503,232.
While the warp printing operation achieves a straight, non-kinked yarn which is desirable for plush or shag type constructions, the fact that considerable stress is placed on the yarns during the printing and steaming operations results in a significant loss of bulk which cannot be recovered. Also, since a dye printing operation is involved, deep penetration of dye into the yarn cannot be achieved.
It has also been proposed to employ a skein dyeing process for producing space dyed yarns. In the process as presently practiced, the skeins are initially heated in a dry heating apparatus or autoclave to bulk and heat set the yarns. and the skeins are then mounted on a rack and completely immersed in a liquid dye bath which contains a dyestuff adapted to apply the lightest shade of the color selection involved. The temperature of the dye bath when the skeins are immersed is necessarily relatively low, for example about F and the temperature must then be gradually increased at a rate of about 2 per minute to the boiling temperature. which is about 220 F. It is not possible to immerse the skeins in a bath having a temperature above about 120 F., since at an elevated temperature the dye will tend to jump on" the yarn when it is immersed. and thus the dye will not be applied evenly.
After reaching the boiling temperature, the skeins are held immersed for about ten minutes to exhaust the dyestuff. The bath is then dropped, the skeins lifted, and a fresh load of water is run into the vat and its temperature adjusted to about 120 F. A second dyestuff is then added which when overdyed on the previously dyed yarns will give the desired color of the next darkest shade. The skeins are partially immersed in the second bath, and the temperature again slowly raised to the boiling temperature and held for another ten minutes to exhaust the dyestuff. The above procedures are repeated for the third and any subsequent dyeing operations, differing only in that each subsequent skein immersion is less than in the preceeding operation.
It is recognized that skein dyeing is able to achieve deep, bright colors in the dyed yarns, this advantage arising from the fact that skein dyeing takes place under optimum conditions of time, temperature, and dye exhaustion which cannot be achieved in a printing operation. Also, skein dyeing results in a high bulk which arises from the relaxed, tension free conditions which exist while the yarn is in skein form and being dyed.
While the skein dyeing process as presently practiced possesses the above recognized advantages, skein dyeing has not been extensively employed since as presently practiced it produces a similar long space" repeating color pattern on all of the yarns which has a tendency to produce streaks or chevrons on the face of the finished pile fabric. More particularly, where such a repeating color pattern is present on the yarns, the colors of adjacent yarns in the finished fabric tend to get into and out of phase in a regular sequence, and this produces visible streaks. Such streaks are not as pronounced where a short space" color pattern is achieved, and such short space" pattern is easily produced by the above dye printing operations. Also, as will be apparent from the above description, the skein dyeing process as presently practiced has a very low production rate as compared to that of the printing processes. Thus while skein dyeing possesses recognized advantages, it has not found commercial acceptance because of these overriding disadvantages.
It is accordingly an object of the present invention to provide a method for space dyeing a plurality of skeins of textile yarn and wherein the dyed skeins have varying color patterns so that visible streaks or chevrons" on the face of the resulting fabric are substantially eliminated.
It is another object of the present invention to provide a method for space dyeing yarn which is characterized by deep, bright colors. high bulk, and the absence of kinks or curls in the yarn.
it is a further object of the present invention to provide a method for space dyeing skeins of yarn and which is adapted to achieve a high production rate and wherein a large quantity of yarn having the same specifications of color, bulk, and other physical properties 3 can be produced.
It is still another object of the present invention to provide a method for space dyeing skeins of yarn wherein the dye bath is not dropped at the end of each dyeing operation, but rather the exhausted bath is further utilized by adding thereto a preselected dye which has been previously determined will produce the desired color when added to the exhausted dye bath.
It is also an object of the present invention to provide a method for space dyeing skeins of yarn which incorporates a wet heat setting operation in association with the dyeing operations such that the yarns are in a receptive state when immersed in the dye bath.
These and other objects and advantages of the pres ent invention are achieved by a method wherein a bank of skeins is initially immersed in a heated aqueous bath to bulk and heat set the yarns. The bank is then removed from the aqueous bath and a dyestuff is added thereto so that a first dye bath is formed from the aqueous bath. The bank is then completely immersed in the first dye bath to apply a first color to the entire skeins, and the bank is maintained therein until the dye bath is substantially exhausted. The bank is then lifted from the exhausted first dye bath and a second dyestuff is added to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color. The bank is then partially immersed in the second dye bath so that the second dye bath acts to color only the immersed portions of the skeins. In order to achieve a varying color pattern on the skeins, provision is made for tilting the bank of skeins so that some of the skeins are further immersed than others.
If it is desired to apply a third color to the skeins, the bank is again lifted and a third dyestuff is added to the exhausted dye bath, and the bank is then again partially immersed in the third dye bath to a level less than the skeins were immersed in the second dye bath. To further vary the color patterns of the skeins, the bank may be tilted into a somewhat different orientation than was the case when the bank was partially immersed in the second dye bath. The above procedure may be repeated for applying additional colors to the yarns if so desired.
Some of the objects of the invention having been stated, other objects will appear as the description proceeds, when taken in connection with the accompanying drawings, in which FIG. 1 is a schematic flow diagram illustrating the basic steps of a process embodying the present invention;
FIGS. 2, 2A and 2B illustrate the sequence for applying three colors to the skeins in accordance with the present invention and wherein the bank of skeins is not tilted;
FIGS. 3, 3A and 3B are similar to FIGS. 2, 2A and 2B, but illustrate the effect of tilting the bank of yarn skeins during the second and third dyeing operations;
FIG. 4 is a perspective view of a skein dyeing apparatus which embodies the features of the present invention;
FIG. 5 is a perspective view of one skein rack and a portion of the overhead lifting harness of the apparatus as shown in FIG. 4;
FIG. 6 is a fragmentary, exploded, perspective view showing the manner in which the skein rack rests upon the underlying dye tubes of the carriage;
FIG. 7 is an end view of arrangement shown in FIG.
FIGS. 8-11 are schematic perspective views illustrating the various ways in which the skein rack may be tilted with respect to the dye bath to achieve varying color patterns on the skeins;
FIG. 12 is an exploded perspective view of the lifting harness, skein racks, carriage, and dye vat of the apparatus illustrated in FIG. 4;
FIG. 13 is a schematic view illustrating the use of power jacks for tilting the bank of skeins along one axis; and
FIG. 14 is a view similar to FIG. 13 but illustrating the use of fourpower jacks so that the skein rack may be selectively tilted along two axes.
Referring more specifically to the drawings, an apparatus embodying the features of the present invention is illustrated in FIGS. 4-7 and 12. The illustrated apparatus includes an open, rectangular dye vat 20 which is adapted to receive a dye bath 2] or other liquid therein. The vat itself is generally conventional, and includes a suitable inlet and outlet (not shown) for facilitating the filling and emptying of the liquid, and a false bottom wall 22 having a plurality of openings 23 therein and through which the liquid is able to freely pass to the area beneath the wall 22. An external dye bowl 24 is provided for permitting a dyestuff to be added to the liquid in the vat, and a circulation system is provided which includes a pump 25 and a pair of outlet openings 26 in the bottom" wall 22 for the purposes hereinafter set forth. Also, a heating coil (not shown) may be positioned beneath the false bottom wall 22 to provide means for heating the liquid in the vat.
A carriage 28 is removably mounted within the vat 20 such that the entire carriage may be vertically translated into the vat to assume an operative position as hereinafter further described. The carriage 28 includes a base 29 which is adapted to rest upon the bottom wall 22 of the vat when the carriage is placed in its operative position within the vat, a plurality of vertical posts 30 extending upwardly from the base 29, and a horizon tally directed tubular manifold 32. For the reasons set forth below, the base 29 includes a pair of downwardly facing openings at 31 which are adapted to cooperate with the openings 26 in the bottom wall 22 when the carriage is received in the vat in its operative position so that the liquids pumped upwardly through the openings 26 will enter the openings in the base 29. Also, the base 29 and vertical posts 30 include an internal passageway (not shown) such that the liquid may be directed upwardly from the openings 31 in the base 29 to the manifold 32.
Three upwardly directed lifting brackets 33 are fixedly carried on the upper surface of the manifold 32, and a plurality of spaced apart, parallel dye tubes 34 emanate outwardly from each side of the manifold to define two oppositely extending rows of tubes 35 and 36. The tubes extend horizontally, and are designed to be positioned somewhat below the liquid level of the bath 21 when the vat is substantially filled and the carriage 28 is positioned therewithin in its operative position. As best seen in FIG. 6, each dye tube is hollow and communicates with the hollow manifold 32. Also, each dye tube includes a row of spaced apertures 38 extending along the upper surface thereof.
As will be apparent from the above description, the vat 20 and carriage 28 include a cooperating circulation system for continuously circulating the liquid in the vat through the carriage and outwardly through the apertures 28 in the dye tubes 34. More particularly, the liquid in the vat flows through the openings 23 in the false bottom wall 22, and is directed by the pump 25 upwardly through the outlet openings 26. The liquid is then channeled into the manifold 32 and hollow dye tubes 34, and then upwardly through the apertures 28 to return to the vat.
The illustrated apparatus further includes a total of four racks which are configured so as to be able to supportingly rest upon the carriage. More particularly, each rack is designed to overlie one-half of the area of each of the rows 35, 36 of tubes as best seen in FIG. 12. Also, each rack 40 comprises a rectangular framework which includes a plurality of transversely spaced apart, parallel arms 42 of substantially equal length. The arms 42 are aligned in the transverse direction such that the ends thereof define a rear edge and a forward edge of the framework, and each arm 42 comprises two transversely spaced apart, parallel rods 44, 45 as best seen in FIGS. 57. Also, an arcuately shaped saddle 46 is carried at each end of each arm to interconnect the two rods, and the saddle at the forward edge of each arm includes an upwardly directed tab 47 which extends between the two rods. An aperture 48 extends transversely through the tab for the purposes hereinafter set forth.
A rear brace 49 extends along the rear edge of the rack and is fixedly interconnected to each of the arms. A forward brace 50 extends along the forward edge of the rack and is releasably connected to each of the arms. More particularly, the forward brace 50 includes a transversely extending angle beam 51 having a plurality of slots 52 therein, with each slot being adapted to receive the apertured tab 47 of one of the arms 42. A cylindrical retaining rod 54 is adapted to then extend through the apertures 48 in the tabs 47 of each arm to maintain the assembly of the angle beam 51 and thus the forward brace 50 to the rack. As will be apparent, the forward brace 50 may be removed by simply withdrawing the rod 54 and lifting the brace away.
Both the rear brace 49 and forward brace 50 include a pair of spaced U-shaped lifting rings 56 for supporting the rack in a manner hereinafter further described. The lifting rings 56 are positioned adjacent the ends of each associated brace, and thus one is positioned adjacent each of the four comers of the rectangular framework of the rack 40.
As best seen in FIGS. 6-7, the arms 42 of each rack are arranged to conform to the arrangement of the dye tubes 34 on the carriage 28 such that the rack may be positioned to supportingly rest upon the carriage. In this regard, it will be noted that the saddles 46 on the arms conform to the curvature of the cylindrical dye tubes to prevent relative shifting movement, and the rods 44, 45 of each arm are positioned to lie along each side of the row of apertures 38 in the underlying dye tube so that the arm does not interfere with the upward flow of the liquid from the apertures in the dye tube. As will be hereinafter further described, the above structure of the rack and dye tubes permits a plurality of skeins S of textile yarn to be positioned to encircle each arm and its associated dye tube to thereby form a bank of adjacent, side by side, downwardly hanging skeins as best seen in FIG. 4. The skeins may be arranged to form such bank by removing the forward brace 50 in the above described manner, and then sliding the skeins axially along each arm and underlying dye tube.
The illustrated apparatus further includes a lifting harness 60 which is adapted to be positioned above the vat for independently supporting all of the racks 40. More particularly, the lifting harness 60 includes a horizontally directed central I-beam 62, and four transversely extending support arms 64 which are fixedly attached to the I-beam in the manner best seen in FIG. 4. In addition, a total of three lifting brackets 65 are fixedly attached to the I-beam and positioned in spaced relation along the length thereof.
Each of the support arms 64 includes provision for mounting a pair of spaced cables or chains 66 from each side of the I-beam. The chains 66 extend downwardly from the harness and are attached to the lifting rings 56 of the racks 40 so that the racks may be releasably interconnected to the harness. More particularly, each chain 66 is looped through one of the lifting rings, and a hook 68 is attached at the lower end of each chain so that the chain may be adjusted in effective length by manually adjusting the point at which the hook is interconnected to the chain. By this arrangement, the orientation of each rack 40 may be manually adjusted such that the rack may be tilted along either of two different axes in relation to the liquid level in the vat 20. Also, each rack may be totally released from the harness so that the racks rest upon and are entirely supported by the carriage in the manner described above.
An electric hoist 70 or the like is slideably carried by a beam 72 which is fixedly positioned above the vat 20 in the manner best seen in FIG. 4. The hoist 70 includes a downwardly directed cable 74 and hook 75 which may be lowered and elevated in a conventional manner. Also, three cables 77, 78, and 79 extend from the hook 75 to the lifting brackets 65 on the harness 60. By this arrangement, the operator of the apparatus is able to lower or lift the harnessand thus the racks in a selected manner. Also, when the harness is released from both the hoist 70 and racks 40, the hoist and cables 77, 78 and 79 may be attached to the lifting brackets 33 of the carriage 28 so that the entire carriage 28 and supported skein racks 40 may be vertically translated into and out of the vat.
A method of randomly dyeing a plurality of skeins of textile yarn employing the above apparatus and in accordance with the present invention will now be described. In this regard, it will be noted that the method and apparatus of the present invention is particularly suited for space dyeing nylon and polyester yarn, although it is also suitable for processing wool, cotton, acrylic, and other polymeric yarns.
To prepare the apparatus, the carriage 28 with the racks 40 resting thereon is initially lifted from the vat 20 and placed on a wheeled dolly (not shown) so that the entire assembly may be easily transported to a suitable work area. In addition, the front brace 50 of each of the racks 40 is removed after withdrawing the retaining rods 54.
The yarns are skeined in a conventional manner, and the individual skeins are loaded onto the assembly by sliding the skeins axially onto each arm and its underlying dye tube so as to encircle the same and form a bank of side by side, downwardly hanging skeins. When all of the arms on each rack are fully loaded, the front brace 50 is lowered over the tabs 47 and attached to the rack by inserting the rod 54. The loaded carriage is then wheeled back to the vat 20 where the hoist 70 is attached by interconnecting the cables 77, 78, and 79 to 7 the lifting brackets 33 of the carriage. The assembly is then lifted, moved into position over the vat 20, and dropped into the vat so that the carriage assumes its operative position.
The vat initially contains boiling water, and the skeins are completely immersed therein for a period of about ten minutes to bulk and heat set the yarn. In this regard, the circulation system will be directing the water upwardly through the apertures 38 in each of the dye tubes so that the skeins effectively float above the arms and dye tube. Thus there is little or no tension on the yarns to resist the development of bulk.
During the bulking operation, the operator removes the cables 77, 78, and 79 from the carriage and attaches the same to the lifting bracket 65 of the harness 60 which may be positioned immediately adjacent the vat. The harness is then lifted by the hoist 70 to a position immediately above the vat, and the chains 66 are inserted through the lifting rings 56 of the racks and the hooks 68 attached at a predetermined point to form a connection of predetermined length. Normally, at this point in the process, the chains would be connected so that the racks would remain substantially level when the harness is lifted.
Upon completion of the bulking and heat setting operation, the harness 60 may be lifted by the hoist 70 so that the skeins are substantially completely withdrawn from the aqueous bath so as to facilitate circulation of the subsequently added dyestuff as described below. Since the dye tubes 34 are normally positioned below the level of the bath, it would be necessary to drop a portion of the bath from the vat if the skeins were to be completely withdrawn therefrom, however, complete withdrawal is not generally necessary.
To prepare the first dye bath, the water in the vat is cooled to about 180 F. by adding cold water, and a concentrated dyestufi' is added to the cooled liquid through the bowl 24. The harness 60 is then lowered so that the bank of skeins is completely immersed in the first dye bath. 'The temperature of the bath is then raised at a rate of about 2 per minute to the boiling temperature of the bath which is about 220 F. The bank of skeins is maintained in the boiling dye bath until the dye bath is substantially exhausted, and this normally takes about ten minutes after the bath reaches the boiling temperature. During the dyeing operation, the circulation system causes the dye bath to be directed upwardly through the apertures 38 in the dye tubes to thereby lift the skeins out of substantial contact with the arms and tubes. This lifting action removes any tension in the yarn, and it insures that there will be no stagnant areas where the skeins contact the arm or tube and which could result in shade variation or stick marking at that point.
Where the wet bulking and heat setting operation of the present invention is employed, it has been found that the initial dye bath may be maintained at a temperature of about l80 F. when the skeins are immersed since the yarn has been partially swelled by the bulking and heat setting operation, and it is in a highly receptive state wherein the dye may be applied in a level fashion at an elevated temperature. This fact serves to substantially reduce the time required to raise the bath to the boiling temperature of 220 F. as compared to the above described conventional skein dyeing process, and thus the production time of the present dyeing operation is substantially reduced.
Upon exhaustion of the first dye bath, the bank of skeins is at least partially withdrawn therefrom, and typically the bank is completely withdrawn from the exhausted dye bath by lifting the harness and dropping a small portion of the bath from the vat so as to achieve maximum circulation. A second dyestuff is then added to the exhausted first dye bath through the bowl 24, and by design, the second dyestuff is adapted to provide the desired color and shade when added to the exhausted first dye bath to color the yarn a second predetermined color. Thus the heated first bath is not dropped and lost, but is utilized in the subsequent dyeing operations to further increase the efficiency of the process.
The bank of skeins is then partially immersed in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins. In this regard, the rack may be oriented or tilted in relation to the liquid level so that some of the skeins are partially immersed in the second dye bath further than others, whereby the skeins have a varying color pattern as illustrated for example in FIG. 3A. This adjustment of die orientation of the rack may be accomplished by manually changing the effective length of the chains 66.
In view of the efficiency of the above described circulation system in the vat 20 and carriage 28 of the appa ratus, it is possible to lift the bank of skeins only an incremental distance from the exhausted first dye bath, rather than completely withdrawing the skeins in the manner described above. Thus the skeins may be initially positioned in the orientation desired for the second dyeing operation while they are partially immersed in the exhausted first dye bath, and the second dyestuff may then be added in the bowl 24. Also, through care ful selection of the second dyestuff, and since the fiber is in a highly receptive state, it is not necessary to cool the bath to 180 F. and heat it slowly to the boiling point in order to get level dyeing as was required in the case of the first dyeing operation. Thus the dye bath may be maintained at the boil and the time requirement for the second dyeing operation is thereby significantly reduced.
Upon exhaustion of the second dye bath, a third dyeing operation may be performed by repeating the steps of the second operation. In this case, the added third dyestuff would be designed to provide the desired third color and shade when added to the exhausted second dye bath. In addition, the orientation of the racks may be changed from that employed in the second dyeing operation so that those skeins which were partially immersed further in the second dye bath are not among those which are partially immersed further in the third dye bath. This serves to further vary the color patterns of the skeins, note for example, the skeins illustrated in FIG. 3B. As will be apparent, each skein is immersed in the third dye bath to a level less than such skein was immersed in the second bath so that only the lowermost portions of the skeins will be overdyed with the third dyestuff. Also, the arrangement or rotational orientation of the skeins on the racks should not be disturbed between the second and third dyeing operations if the desired color pattern is to be achieved. While three dyeing operations have been described herein, it will be appreciated that additional dyeing operations could be employed where a larger number of colors is desired.
When the dyeing operations are completed, the dye bath is dropped from the vat 20, and the harness 60 is removed by disconnecting the chains 66 from the racks 40 and the cables 77, 78, and 79 from the harness. The hoist 70 is then connected to the lifting brackets 33 of the carriage, and the loaded carriage and racks are lifted from the vat and again positioned on the wheeled dolly for transport to a work area. The forward braces 50 are removed from the racks, and the skeins may then be withdrawn from the arms. The skeins are typically then subjected to conventional water extracting and drying operations. In the case of certain fibers such as polyester, it may also be necessary to rinse the skeins prior to water extraction to remove certain carriers and other chemicals before the yarn is dried.
In the above described process, the aqueous bath employed in bulking and heat setting the yarns is utilized in the subsequent space dyeing operation. As an alternative to this procedure, a separate bulking and heat setting bath may be provided which is continuously kept charged with boiling water. Thus a single bulking and heat setting bath would serve several vats filled with the dye bath, and the carriage 28 and racks 40 with the loaded skeins would be transferred from the heat setting bath to the dye vat after the bulking and heat setting operation is completed.
FIGS. 8-1 1 schematically illustrate the various ways in which each of the racks 40 may be tilted to achieve varying color patterns in the bank of skeins. In FIG. 8, the chains 66 to the four comers of the rack are of equal length so that the rack is substantially level. Such orientation would be employed to achieve the similar color patterns in the skeins as shown in FIGS. 2, 2A, and 2B.
In FIG. 9, the two far side chains have been shortened an equal amount so that the rack is tilted along the transverse axis. In FIG. 10, the two chains along the far end have been shortened to tilt the rack along the longitudinal axis, and in FIG. 11, three of the chains have been shortened to tilt the rack about both the longitudinal and transverse axes.
FIG. 13 represents an arrangement for facilitating the orientation of the racks, and includes a pair of power jacks 82, 83 which are adapted to raise and lower the associated connecting rods 82, 83' so that the rack may be rotated about the longitudinal axis. The jacks 82, 83 may be connected to suitable controls to permit the operator to adjust the orientation from a remote location.
FIG. 14 shows an arrangement similar to that shown in FIG. 13 but including four power jacks 85, 86, 87 and 88 so that each corner of the rack may be independently raised and lowered to permit rotation about both the longitudinal and transverse axes. As will be apparent, the use of a system of power jacks as shown in FIGS. 13 and 14 lends itself to an automated program control to further increase the efiiciency of the process.
As a typical example of a color combination suitable for use with the present invention, a yellow dyestuff such as Disperse Yellow 3 may be added to the aqueous bath employed in the bulking and heat setting operation to initially apply a yellow shade as seen at 91 in FIGS. 2 and 3. The second dyestuff may comprise a blue, such as Acid Blue 27. When blue is overdyed upon yellow, a green shade 92 will result as seen in FIGS. 2A and 3A. For the third dyestuff, a red such as Acid Red 57 may be employed. When the red is overdyed upon the green, a brown color 93 will be produced as seen in FIGS. 28 and 3B. The resulting skeins will thus be dyed yellow on the uppermost portions, green along the mid portions, and brown on the lowermost portions. Typically, the amount of dyestuff added to the bath will be about 0.25 percent of the weight of the yarn to be dyed for each of the above colors. Also, it will be understood that the dye bath 21 may also include suitable wetting agents, PH control agents, and other chemicals as well known in the art.
The above described process and apparatus can also be employed in a resist or indirect space dyeing process. In such a process, the resist chemicals would be applied as the dyestufi' in the above described process. Thus, by selecting the resist chemicals properly, and by applying them in the same way as in the space dyeing operation described above, the skeins will become space sensitized to specific dyestuffs. Subsequently, the space sensitized skeins are immersed in a dye bath containing all of the various colored dyestuffs to which it has been sensitized, and in this way the skeins become space dyed.
The process and apparatus of the present invention also lends itself to a related fonn of space dyeing which is termed shade variation or withdrawal dyeing. Here, only one color of the dyestufi is used, and the immersion time of the various portions of the skeins in the bath is varied. Thus for example, a continuous shade variation from near white to the full color development of complete dyeing may be obtained by slowly withdrawing the skeins out of the dye bat as the dyeing proceeds. As will be apparent, the top of the skeins will receive little or no dyestuff while the bottom portions will be completely dyed, and there will be a continuous shade variation therebetween. Also, this shade variation may be obtained by a short incremental withdrawal, instead of a continuous withdrawal, and by tilting the rack during the withdrawal operation, some of the skeins will be partially immersed further than others during the withdrawal operation such that the skeins will have varying color patterns.
In the drawings and specification, there has been set forth a preferred embodiment of the invention, and although specific terms are employed, they are used in a generic and descriptive sense only and not for purposes of limitation.
That which is claimed is:
I. A method of producing space dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the substantial elimination of streaks on the face of the resulting carpet caused by a similar repeating color pattern on the yarns, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a first dye bath to apply a first color to the entire skeins, and then partially immersing the bank in a second dye bath of a color different from that of the first dye bath and so that some of the skeins are partially immersed further than others to thereby apply a second color only to the immersed portions of the skeins and such that the skeins have varying color patterns.
2. The method as defined in claim 1 comprising the further subsequent step of partially immersing the bank in a third dye bath of a color different from that of each of the first and second dye baths and so that each skein is immersed to a level less than such skein was partially 1 1 immersed in the second dye bath to thereby apply a third color only to the portions of the skeins immersed in the third dye bath.
3. The method as defined in claim 2 wherein some of the skeins are partially immersed in the third dye bath further than others to additionally vary the color patterns of the skeins.
4. The method as defined in claim 3 wherein at least some of the skeins which were partially immersed further in the second dye bath are not among those skeins which are partially immersed further in the third dye bath.
5. The method as defined in claim 4 wherein the step of bulking and heat setting the yarn includes completely immersing the bank of skeins in a heated aqueous bath.
6. The method as defined in claim 1 comprising the further step of bulking and heat setting the yarn prior to immersing the bank of skeins in the first dye bath.
7. A method of producing spaced dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted,
at least partially removing the bank from the exhausted first dye bath,
adding a dyestuff to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color, and
partially immersing the bank in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins.
8. the method as defined in claim 7 including the further step of bulking and heat setting the yarn prior to immersing the bank of skeins in the first dye bath.
9. The method as defined in claim 8 wherein some of the skeins are partially immersed in the second dye bath further than others such that the skeins have varying color patterns.
10. The method as defined in claim 9 comprising the further subsequent step of partially immersing the bank in a third dye bath of a color different from that of each of the first and second dye baths and so that each skein is immersed to a level less than such skein was immersed in the second dye bath and further wherein some of the skeins are partially immersed in the third dye bath further than others to thereby apply a third color only to the immersed portions of the skeins and to further vary the color patterns of the skeins.
11. A method of producing space dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a heated aqueous bath to bulk and heat set the yarns, then 12 completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted,
at least partially removing the bank from the exhausted first dye bath, adding a second dyestuff to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color, and
partially immersing the bank in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins.
12. The method as defined in claim 11 comprising the further steps of removing the bank from the aqueous bath after the bulking and heat setting has been substantially completed, and then adding a dyestufi' to the aqueous bath so that the first dye bath is formed from the aqueous bath.
I3. The method as defined in claim 12 wherein some of the skeins are partially immersed in the second dye bath further than others such that the skeins have varying color patterns.
14. The method as defined in claim 13 comprising the further subsequent steps of maintaining the bank partially immersed in the second dye bath until such bath is substantially exhausted,
at least partially removing the bank from the exhausted second dye bath,
adding a third dyestuff to the exhausted second dye bath to form a third dye bath adapted to color the yarn a third predetermined color, and
partially immersing the bank in the third dye bath so that each skein is immersed to a level less than such skein was immersed in the second dye bath and wherein some of the skeins are partially immersed in the third dye bath further than others to thereby apply a third color only to the immersed portions of the skeins and to further vary the color patterns of the skeins.
15. A method of producing space dyed yarns suitable for use in fabricating tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the substantial elimination of streaks on the face of the resulting carpet caused by a similar repeating color pattern on the yarns, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a dye bath, and
then
slowly withdrawing the bank from the dye bath during the dyeing operation and while maintaining the bank in a tilted relationship with respect to the dye bath so that some of the skeins will be partially immersed further than others during the withdrawal operation and such that the skeins will have a varying color pattern.
16. The method as defined in claim 15 comprising the further step of completely immersing the bank of skeins in a heated aqueous bath to bulk and heat set the yarn prior to immersing the bank in the dye bath.

Claims (16)

1. A METHOD OF PRODUCING SPACE DYED YARNS SUITABLE FOR USE IN FABRICATING MULTI-COLORED TUFTED CARPETS AND THE LIKE, AND CHARACTERIZED BY DEEP, BRIGHT COLORS, HIGH BULK, AND THE SUBSTANTIAL ELIMINATION OF STREAKS ON THE FACE OF THE RESULTING CARPET CAUSED BY A SIMILAR REPEATING COLOR PATTERN ON THE YARNS AND COMPRISING THE STEPS OF ARRANGING A PLURALITY OF SKEINS OF TEXTILE YARN TO FORM A BANK OF SIDE BY SIDE, DOWNWARDLY HANGING SKEINS, COMPLETELY IMMERSING THE BANK IN A FIRST DYE BATH TO APPLY A FIRST COLOR TO THE ENTIRE SKEIN, AND THEN PARTIALLY IMMERSING THE BANK IN A SECOND DYE BATH OF A COLOR DIFFERENT FROM THAT OF THE FIRST DYE BATH AND SO THAT SOME OF THE SKEINS ARE PARTIALLY IMMERSED FURTHER THAN OTHER TO THEREBY APPLY A SECOND COLOR ONLY TO THE IMMERSED PORTIONS OF THE SKEINS AND SUCH THAT THE SKEINS HAVE VARYING COLOR PATTERNS.
2. The method as defined in claim 1 comprising the further subsequent step of partially immersing the bank in a third dye bath of a color different from that of each of the first and second dye baths and so that each skein is immersed to a level less than such skein was partially immersed in the second dye bath to thereby apply a third color only to the portions of the skeins immersed in the third dye bath.
3. The method as defined in claim 2 wherein some of the skeins are partially immersed in the third dye bath further than others to additionally vary the color patterns of the skeins.
4. The method as defined in claim 3 wherein at least some of the skeins which were partially immersed further in the second dye bath are not among those skeins which are partially immersed further in the third dye bath.
5. The method as defined in claim 4 wherein the step of bulking and heat setting the yarn includes completely immersing the bank of skeins in a heated aqueous bath.
6. The method as defined in claim 1 comprising the further step of bulking and heat setting the yarn prior to immersing the bank of skeins in the first dye bath.
7. A method of producing spaced dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted, at least partially removing the bank from the exhausted first dye bath, adding a dyestuff to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color, and partially immersing the bank in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins.
8. the method as defined in claim 7 including the further step of bulking and heat setting the yarn prior to immersing the bank of skeins in the first dye bath.
9. The method as defined in claim 8 wherein some of the skeins are partially immersed in the second dye bath further than others such that the skeins have varying color patterns.
10. The method as defined in claim 9 comprising the further subsequent step of partially immersing the bank in a third dye bath of a color different from that of each of the first and second dye baths and so that each skein is immersed to a level less than such skein was immersed in the second dye bath and further wherein some of the skeins are partially immersed in the third dye bath further than others to thereby apply a third color only to the immersed portions of the skeins and to further vary the color patterns of the skeins.
11. A method of producing space dyed yarns suitable for use in fabricating multi-colored tufted carpets and the like, and characterized by deep, bright colors, high bulk, and high production capacity, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hAnging skeins, completely immersing the bank in a heated aqueous bath to bulk and heat set the yarns, then completely immersing the bank in a first dye bath to apply a first color to the entire skeins, maintaining the bank immersed in the first dye bath until such dye bath is substantially exhausted, at least partially removing the bank from the exhausted first dye bath, adding a second dyestuff to the exhausted first dye bath to form a second dye bath adapted to color the yarn a second predetermined color, and partially immersing the bank in the second dye bath such that the second dye bath acts to color only the immersed portions of the skeins.
12. The method as defined in claim 11 comprising the further steps of removing the bank from the aqueous bath after the bulking and heat setting has been substantially completed, and then adding a dyestuff to the aqueous bath so that the first dye bath is formed from the aqueous bath.
13. The method as defined in claim 12 wherein some of the skeins are partially immersed in the second dye bath further than others such that the skeins have varying color patterns.
14. The method as defined in claim 13 comprising the further subsequent steps of maintaining the bank partially immersed in the second dye bath until such bath is substantially exhausted, at least partially removing the bank from the exhausted second dye bath, adding a third dyestuff to the exhausted second dye bath to form a third dye bath adapted to color the yarn a third predetermined color, and partially immersing the bank in the third dye bath so that each skein is immersed to a level less than such skein was immersed in the second dye bath and wherein some of the skeins are partially immersed in the third dye bath further than others to thereby apply a third color only to the immersed portions of the skeins and to further vary the color patterns of the skeins.
15. A method of producing space dyed yarns suitable for use in fabricating tufted carpets and the like, and characterized by deep, bright colors, high bulk, and the substantial elimination of streaks on the face of the resulting carpet caused by a similar repeating color pattern on the yarns, and comprising the steps of arranging a plurality of skeins of textile yarn to form a bank of side by side, downwardly hanging skeins, completely immersing the bank in a dye bath, and then slowly withdrawing the bank from the dye bath during the dyeing operation and while maintaining the bank in a tilted relationship with respect to the dye bath so that some of the skeins will be partially immersed further than others during the withdrawal operation and such that the skeins will have a varying color pattern.
16. The method as defined in claim 15 comprising the further step of completely immersing the bank of skeins in a heated aqueous bath to bulk and heat set the yarn prior to immersing the bank in the dye bath.
US429934A 1974-01-02 1974-01-02 Method and apparatus for space dyeing yarn Expired - Lifetime US3926547A (en)

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Application Number Priority Date Filing Date Title
US429934A US3926547A (en) 1974-01-02 1974-01-02 Method and apparatus for space dyeing yarn
GB43606/74A GB1482957A (en) 1974-01-02 1974-10-08 Method and apparatus for space dyeing yarn
AU74195/74A AU479266B2 (en) 1974-01-02 1974-10-10 Method and apparatus for space dyeing yarn
NL7416911A NL7416911A (en) 1974-01-02 1974-12-27 METHOD AND DEVICE FOR LOCATION OF YARN.
DE19742461598 DE2461598A1 (en) 1974-01-02 1974-12-27 METHOD AND APPARATUS FOR SECTIONAL DYEING OF YARN
JP50001060A JPS5095590A (en) 1974-01-02 1974-12-28
DK689174A DK689174A (en) 1974-01-02 1974-12-30
SE7416379A SE7416379L (en) 1974-01-02 1974-12-30
BE152046A BE823990A (en) 1974-01-02 1974-12-30 PROCESS AND APPARATUS FOR DYING YARN IN SPACE AND DYED PRODUCTS THUS OBTAINED
FR7443317A FR2256282B1 (en) 1974-01-02 1974-12-30
CH781776A CH588590A5 (en) 1974-01-02 1974-12-31
US05/610,315 US3986375A (en) 1974-01-02 1975-09-04 Apparatus for space dyeing yarn and product

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JP (1) JPS5095590A (en)
BE (1) BE823990A (en)
CH (1) CH588590A5 (en)
DE (1) DE2461598A1 (en)
DK (1) DK689174A (en)
FR (1) FR2256282B1 (en)
GB (1) GB1482957A (en)
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US4047271A (en) * 1976-01-02 1977-09-13 Interdye Technology Corporation Method for space dyeing yarn
US4112714A (en) * 1975-12-17 1978-09-12 Rohm And Haas Company Asymmetric skein dyeing
US4171953A (en) * 1977-10-31 1979-10-23 Cleveland J B Method for randomly coloring textile yarns in a batch system
WO1993006177A1 (en) * 1991-09-17 1993-04-01 Shaw Industries, Inc. Process and composition for dyeing polymeric fibers
US5447539A (en) * 1994-02-10 1995-09-05 Dke Incorporated Method of dyeing polypropylene fiber with more than one color
FR2857988A1 (en) * 2003-07-22 2005-01-28 Teinture Et Appret De Loire Se Textile yarn dyeing procedure consists of winding yarn into skeins or onto perforated tubes and steeping in dye bath in mesh bags and baskets
CN106948110A (en) * 2017-05-12 2017-07-14 厦门大学嘉庚学院 Plant dye processes dyeing apparatus and colouring method

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FR2682130A1 (en) * 1991-10-08 1993-04-09 Gand Teinturerie Apprets Dyeing process for obtaining (gradual) ranges of different colours, and implementation device

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US2043870A (en) * 1934-08-09 1936-06-09 Viscose Co Random skein dyeing
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US2716585A (en) * 1954-11-03 1955-08-30 Jr Sidney Bailey Over-dyeing stockings to produce two-color and ombre effects
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US3356444A (en) * 1963-02-21 1967-12-05 British Nylon Spinners Ltd Varying-tone colour effects in synthetic fibre fabrics
US3541635A (en) * 1968-10-29 1970-11-24 Riegel Textile Corp Apparatus and method for random dyeing skeins of textile yarn

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US1906492A (en) * 1928-06-26 1933-05-02 Firm Sondermann U Co Process for treating hanks or cheeses of yarns with liquids
US2053293A (en) * 1933-08-24 1936-09-08 Viscose Co Method and apparatus for treating yarn with liquid
US2043870A (en) * 1934-08-09 1936-06-09 Viscose Co Random skein dyeing
US2716585A (en) * 1954-11-03 1955-08-30 Jr Sidney Bailey Over-dyeing stockings to produce two-color and ombre effects
US3012303A (en) * 1959-12-24 1961-12-12 Whitaker Co Fred Production of multicolored pile fabric
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Publication number Priority date Publication date Assignee Title
US4112714A (en) * 1975-12-17 1978-09-12 Rohm And Haas Company Asymmetric skein dyeing
US4047271A (en) * 1976-01-02 1977-09-13 Interdye Technology Corporation Method for space dyeing yarn
US4171953A (en) * 1977-10-31 1979-10-23 Cleveland J B Method for randomly coloring textile yarns in a batch system
WO1993006177A1 (en) * 1991-09-17 1993-04-01 Shaw Industries, Inc. Process and composition for dyeing polymeric fibers
US5358537A (en) * 1991-09-17 1994-10-25 Shaw Industries, Inc. Process for dyeing polymeric fibers
US5447539A (en) * 1994-02-10 1995-09-05 Dke Incorporated Method of dyeing polypropylene fiber with more than one color
FR2857988A1 (en) * 2003-07-22 2005-01-28 Teinture Et Appret De Loire Se Textile yarn dyeing procedure consists of winding yarn into skeins or onto perforated tubes and steeping in dye bath in mesh bags and baskets
CN106948110A (en) * 2017-05-12 2017-07-14 厦门大学嘉庚学院 Plant dye processes dyeing apparatus and colouring method
CN106948110B (en) * 2017-05-12 2023-08-04 厦门大学嘉庚学院 Plant dye liquor processing and dyeing device and dyeing method

Also Published As

Publication number Publication date
FR2256282B1 (en) 1979-08-10
FR2256282A1 (en) 1975-07-25
NL7416911A (en) 1975-07-04
BE823990A (en) 1975-06-30
JPS5095590A (en) 1975-07-30
GB1482957A (en) 1977-08-17
DK689174A (en) 1975-09-01
AU7419574A (en) 1976-04-15
CH588590A5 (en) 1977-06-15
DE2461598A1 (en) 1975-07-10
SE7416379L (en) 1975-07-03

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