US3876498A - Controlled forming wire separation on impervious roll of twin-wire papermaking machine - Google Patents

Controlled forming wire separation on impervious roll of twin-wire papermaking machine Download PDF

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US3876498A
US3876498A US397400A US39740073A US3876498A US 3876498 A US3876498 A US 3876498A US 397400 A US397400 A US 397400A US 39740073 A US39740073 A US 39740073A US 3876498 A US3876498 A US 3876498A
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wire
forming
web
roll
stock
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US397400A
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Edgar J Justus
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Beloit Corp
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Beloit Corp
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US case filed in International Trade Commission litigation Critical https://portal.unifiedpatents.com/litigation/International%20Trade%20Commission/case/337-TA-082 Source: International Trade Commission Jurisdiction: International Trade Commission "Unified Patents Litigation Data" by Unified Patents is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Beloit Corp filed Critical Beloit Corp
Priority to US397400A priority Critical patent/US3876498A/en
Priority to CA200,965A priority patent/CA1010277A/en
Priority to FI1672/74*A priority patent/FI167274A/fi
Priority to FR7428660A priority patent/FR2244049B1/fr
Priority to AR255301A priority patent/AR203761A1/en
Priority to ES429632A priority patent/ES429632A1/en
Priority to GB3904574A priority patent/GB1477049A/en
Priority to DE2442925A priority patent/DE2442925C3/en
Priority to SE7411459A priority patent/SE415111B/en
Priority to BR7615/74A priority patent/BR7407615D0/en
Priority to IT27250/74A priority patent/IT1021344B/en
Publication of US3876498A publication Critical patent/US3876498A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F9/00Complete machines for making continuous webs of paper
    • D21F9/003Complete machines for making continuous webs of paper of the twin-wire type

Definitions

  • ABSTRACT A method and mechanism for continuously forming a fibrous web from a slurry of stock including first and second looped permeable woven forming wires positioned to travel over a solid impermeable roll and converge in a throat to travel through a forming run over the roll.
  • a headbox chamber has trailing selfpositionable elements therein and delivers stock to the forming throat. At the end of the forming run.
  • the outer wire is separated from the inner wire at a separation point by a small angle a with the inner wire continuing on the roll for a short distance beyond said separation point.
  • the outer wire will be cleaned at the separation point, and the web will uniquely follow the inner wire despite centrifugal force.
  • the present invention relates to improvements in ftbrous web formation wherein an aqueous fiber suspension is dewatered on a porous forming surface, More particularly, the invention relates to improvements in web forming mechanisms of the type which have become to be known to the art as twin wire formers wherein a slurry of fibrous stock is delivered from a headbox slice opening to a forming throat between a pair of looped traveling forming wires with the web dewatered by being squeezed between the forming wires.
  • twin wire forming machines have met with commercial success offering advantages of requiring less space and improved dewatering at high speeds. As the speed of the papermaking machines are increased. it becomes increasingly difficult to handle and control a high speed traveling fibrous web and to determine with a certainty the continued position of the web and to insure that it will continue to follow a forming wire without leaving the forming wire surface or following an opposing wire.
  • a suction mechanism such as a suction box must be positioned within the wire which the web is to follow to insure that it is stapled or adhered to the wire just before or as the wires are separating.
  • the roll has been provided with a suction box to staple the web to the inner wire.
  • the necessity of providing a suction gland and a hollow roll is undesirable in increasing initial construction cost and increasing power consumption.
  • Another method which has been employed is to keep the wires together, but to pass one of the wires over a suction box to insure transfer of the web to that wire.
  • a feature of the invention is applicants discovery of a combination of elements so constructed and so arranged that it is possible to combine the advantages of a twin wire former with the economics of a plain roll, and the use of two woven mesh wires permitting operation at maximum speed so that the unit is capable of operation at speeds approaching 7,000 feet per minute which is unusually high in the operation of present-day machines. High speeds are accomplishable by utilizing woven wires for both the formation members along the forming run and passing them over a plain solid cylindrical roll which has an absence of suction glands and where the wires do not have to run over suction boxes. Contrary to previous teachings.
  • the outer wire is first led away from the inner wire at a very small angle, and the physical force of the vacuum created as the upper wire is separated from the solid roll, at speed, will cause a flow of air through the outer wire sweeping any water remaining in the outer wire inwardly to help clean the outer wire of fiber and water.
  • the web is held to the inner wire by the dynamically created differential pressure across the web, created by the separation, at speed, of the outer wire from the roll while the inner wire is still wrapped on the roll. This separation, at speed, tends to create a void or vacuum between the two wires which can only be filled from outside the outer wire and cannot be filled from inside the inner wire because of the solid impervious surface of the roll.
  • An object of the present invention is to provide an improved and more economical twin wire forming mechanism and method using two woven wires with positive web control and the capability of having the web follow the inner wire without requiring suction boxes or suction rolls within the wire to effect the transfer of the web.
  • a further object of the invention is to provide an improved twin wire forming mechanism which is particularly well adapted to forming tissue or toweling and which utilizes simple high speed imperforate solid rolls for support of the twin wires.
  • a still further object of the invention is to provide a unique method and mechanism for the positive control of the web traveling in an arcuate path between a pair of forming wires insuring that the web follows the inner forming wire.
  • a further object is to provide a high speed paper forming system utilizing the dynamics of the woven forming wires and supports and without the use of externally powered vacuum devices such as suction rolls or suction boxes.
  • a further object of the invention is to provide a twin wire forming mechanism wherein the wires travel over a curved surface to dewater a web therebetween and dewatering is effected entirely through the outer wire and the outer wire is cleaned of fibers as the wires are separated and the web follows the inner wire.
  • the method and mechanism fine particular advantages in the formation of a paper web from cellulose fibers. but it will be understood that the features may be used to advantage in forming a web from other types of fibers. Also, the mechanism as disclosed is best suited for the handling of a slurry formed of an aqueous suspension but other forms of fluids may be employed.
  • FIG. I is a side elevational view shown in somewhat schematic form of a machanism constructed and operating in accordance with the principles of the present invention.
  • FIG. 2 is an enlarged fragmentary schematic view of a portion of the mechanism of FIG. I shown for the purposes of illustrating certain principles as will become clear from the description;
  • FIG. 3 is another enlarged fragmentary schematic view illustrating an alternate form of operation of a mechanism embodying the principles of the invention.
  • the mechanism includes first and second looped woven permeable forming wires 10 and I2.
  • the wires are trained over rolls so as to approach each other and form a tapered throat 13 into which a jet of stock is delivered, followed by an arcuate forming zone I4.
  • the wires are wrapped over the arcuate outer surface of a plain cylindrical roll 15.
  • the roll has a smooth outer imperforate supporting surface for the wires, and the wires are tensioned so that they apply squeezing force normal to the web being formed therebetween to force the water out through the first or outer wire 10.
  • the second or inner wire 14 be a pervious woven wire so as to provide a web backing or support, which can receive but does not absorb or retain excess water and which does not require elaborate dewatering mechanisms itself for removal of its water, such as would be required for a felts.
  • wires I2 and I0 being substantially similar in openness or weave are particularly well adapted for the formation required for a given web such as tissue and toweling.
  • the solid imperforate roll I5 is particularly well adapted to very high speed operation and eliminates the need for suction glands or suction means and eliminates necessity of rubbing surfaces.
  • the mechanism as is shown which eliminates the need for the wire passing over suction boxes and eliminates the need for suction glands is capable of operating at uniquely high speeds on the order of up to 7,000 ft. per minute with satisfactory long wire life.
  • the first looped outer wire [0 is supported on rolls located within the wire shown at 16, 17, 18, I9, 20, 2] and 22. At least one of the rolls, such as the roll I8 is capable of being moved to an adjusted position to place a predetermined linear tension in the wire to apply the desired squeezing force to the web in the forming zone 14.
  • the second looped inner forming wire 12 is supported on rolls 23, 24 and 25.
  • the wires are both woven and preferably of the same size mesh.
  • a headbox 26 For delivering stock to the throat I3, a headbox 26 is provided.
  • Stock is delivered to the headbox under pressure to flow through the tapered slice chamber 261: of the headbox formed between the converging slice walls 27 and 28.
  • Slice wall 28 is preferably pivotally adjustable so as to controllably regulate the size of the slice opening 29 from which issues a stock jet 30.
  • the movable wall of the headbox is pivoted at 280, and a power means shown schematically at 28b controls the pivotal position of the wall and hence the size of the slice opening 29.
  • the headbox 26 is supported on a pivot 26a and power means shown schematically at 26b and is attached to the headbox to establish its pivotal position.
  • the pivotal position is chosen so that the stock jet 30 will substantially bisect the throat 13, but adjustments can be made so that the jet 30 passes into the throat more or less tangential to either the inner wire 12 or the outer wire 10.
  • a preferred form of headbox construction particularly well adapted to the formation of the web between wires, wherein the deflecting support for the wires is a solid roll, includes a plurality of trailing elements 31 positioned in the tapered slice chamber 30.
  • a fine scale turbulence is generated maintaining uniform fiber dispersion for dewatering through the outer wire.
  • These trailing elements are anchored only at their upstream ends at a perforate wall 32 in the headbox and are positionable responsive solely to forces of the stock flowing through the slice chamber.
  • the trailing elements 3] may be in the form on individual flexible strands of material such as plastic, or may be in the form of continuous or interrupted sheets extending across the headbox. These trailing elements divide the stock flow into a plurality of independent flows having small scale turbu- Ience for intermixing and distribution of the fibers which form the web in the forming run.
  • the web W is formed in the forming zone I4. As the wires are separated from the roll and are separated from each other despite the fact that the outer wire is lifted first from the roll, the web follows the inner second wire 12.
  • the outer wire 10 is separated from the inner wire 12 at a separation point 34, shown in FIGS. 1 and 2.
  • the web W follows the wire 12 and is picked off the upper surface of the wire by pickoff felt 36 brought into close adjacency with the web by pickoff felt roll 37.
  • the web because it is dewatered through the outer wire, is not stapled to the inner wire but is easily removable.
  • the solid arcuate support for the wires in the forming zone is provided preferably by a cylindrical smooth surface roll 15, but because of high attainable speeds and lack of wire to roll friction, it will be understood that other forms of supports may be used such as a curved shoe. It is important in the mechanism and method of the structure that the support be imperforate at the first separation point 34 where the outer wire I0 is separated from the inner wire 12 and at the second separation point 35 where the inner wire is separated from the roll.
  • the web is effectively sealed to the inner wire. It is also essential that the voids of the inner wire be filled with water so that the web will be sealed or pasted onto the inner wire. This is a result of the roll being imperforate and the web being squeezed during the forming run so that water which flows inwardly from the web fills the interstices of the inner wire. This will occur fairly easily in the forming zone and the rest of the water squeezed out of the web will be forced outwardly through the outer wire. Also, since the inner wire is filled with water, fibers will not be forced inwardly to staple themselves to the inner wire.
  • the web will be pasted to the inner wire and when the inner wire is lifted off the roll and the seal which holds the web to the inner wire is broken, the web can easily be lifted off the inner wire.
  • the inner wire reaches the separation points 34 and 35, the surface tension of the water within the inner wire and the sealing effect of the solid roll pastes or holds the web to the inner wire.
  • a vacuum tends to form beneath the inner wire drawing the web down against the inner wire and tending to draw the water out from the inner wire.
  • a separating doctor may be provided, not shown, to help the water separate from the outer surface of the roll 15 to pass into the saveall 15a.
  • the outer wire 10 is separated on a very small distance from the inner wire 15 forming an acute angle a therebetween, as shown in FIG. 2.
  • the angle a should be kept as small as possible so that the distance D is small.
  • the dewatering run along the surface of the roll is of a length so that the web will be dewatered therealong and by the time the web reaches the top of the roll 15, no substantial remaining amount of water is being squeezed therefrom.
  • the amount of water squeezed from the web during the dwatering run is a function of the size of the roll as shown by the radius R of the roll IS in FIG. 2, and the linear tension of the outer wire 10.
  • the supporting roll 16 for the outer wire 10 is adjustable in location so as to be able to selectively control the angle a between the outer and inner wires 10 and 12.
  • the roll 16 is supported on a pivotal arm 16a pivotally supported at 16b and controllable in its position by a power means shown schematically at I60. This permits moving the roll 16 through a range of positions to select an angle shown at a in FIG. 2 and at a in FIG. 3.
  • a saveall 33a is positioned above the wire separation points 34 and 35.
  • the angle a is preferably chosen to be at a minimum size such as in the range of greater than 0 and preferably not greater than 5.
  • This cleaning is augmented by the inward surge of air tending to push forwardly any water present to cause a surge at location 41 to wash and help clean the upper wire removing the fibers stapled to the strands thereof.
  • This surge of air through the outer wire is due to a large part to the inner wire being lifted off the roll with the inward pull on the web at that point.
  • the operation shown in FIG. 3 lends support for this theory of outer wire cleaning because when the mechanism is operated in accordance with the relationship shown in FIG. 3 where the angle 01 is large. the outer wire is not as well cleaned.
  • the inner wire 12 is lifted off the roll a substantially greater distance D after the point of first separation A.
  • the vacuum formed at point 40' does not augment or act substantially simultaneously with, the vacuum formed at location 41' so as to cause the inrush of air.
  • the web will still be pasted to the inner wire [2.
  • the outer wire is lifted off of the roll, the web remains adhered to the inner wire due to the surface tension of the water in the interstices of the wire and due to the vacuum caused as the web tends to lift.
  • the surface tension of the water causes the water in the wire to follow the roll. Because dewatering was substantially completely through the outer wire 10, the web is not stapled to the inner wire 12 and rides lightly thereon making it relatively easy for a pickoff felt to pick the web off the wire.
  • a stock from the headbox 26 is directed in a jet 36 into the throat 13 between the forming wires 10 and [2.
  • the web is dewatered through the outer wire 10 into the saveall 33.
  • the outer wire 10 is first lifted off the roll and the inner wire 12 is almost immediately thereafter lifted off the roll 15, and the physical effects of surface tension and vacuum create the phenomena of overcoming the centrifugal force on the web and cause it to adhere to the inner woven wire with a concurrent cleaning of the outer wire.
  • the web resting on the inner wire is readily picked off the wire by a pickup felt.
  • a mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination:
  • a headbox having an opening positioned to direct a stream of stock into said throat;
  • a first off running guide means for said first wire positioned following the forming run and separating the first wire from the second wire at a first separation point on said curved surface;
  • said curved surface being imperforate at said separation points.
  • said curved surface is the outer surface of a rotatable imperforate cylindrical roll supporting said wires through the forming run.
  • said second offrunning guide means is positioned so that the angle between the wires at the second separation point is in the range of 0 to 5.
  • a tapered slice chamber with a plurality of flexible trailing members anchored only at their upstream ends and being self-positionable responsive to the pressure of stock flowing past said members.
  • a mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination:
  • a slice means having an opening positioned to direct a stream of stock into said throat;
  • first guide means for the outer wire bending the outer wire over said roll throughout the forming run and lifting the outer wire off of the roll

Abstract

A method and mechanism for continuously forming a fibrous web from a slurry of stock including first and second looped permeable woven forming wires positioned to travel over a solid impermeable roll and converge in a throat to travel through a forming run over the roll. A headbox chamber has trailing selfpositionable elements therein and delivers stock to the forming throat. At the end of the forming run, the outer wire is separated from the inner wire at a separation point by a small angle .alpha. with the inner wire continuing on the roll for a short distance beyond said separation point. The outer wire will be cleaned at the separation point, and the web will uniquely follow the inner wire despite centrifugal force.

Description

United States Patent Justus Apr. s, 1975 CONTROLLED FORMING WIRE SEPARATION ON IMPERVIOUS ROLL or TWIN-WIRE PAPERMAKING MACHINE Edgar J. Justus, Beloit, Wis.
Assignee: Beloit Corporation, Beloit, Wis
Filed: Sept. 14, 1973 Appl. No.: 397,400
Inventor:
Graham 162/214 X Jordansson et a1. 162/318 X Primary E.\'aminerS. Leon Bashore Assistant Examiner-Richard H. Tushin Attorney, Agent, or Firm-Hill, Gross, Simpson, Van Santen. Steadman, Chiara & Simpson [57] ABSTRACT A method and mechanism for continuously forming a fibrous web from a slurry of stock including first and second looped permeable woven forming wires positioned to travel over a solid impermeable roll and converge in a throat to travel through a forming run over the roll. A headbox chamber has trailing selfpositionable elements therein and delivers stock to the forming throat. At the end of the forming run. the outer wire is separated from the inner wire at a separation point by a small angle a with the inner wire continuing on the roll for a short distance beyond said separation point. The outer wire will be cleaned at the separation point, and the web will uniquely follow the inner wire despite centrifugal force.
14 Claims, 3 Drawing Figures PATENTEUAPR' BIS? SE11 1 BF 2 PATENTEUAPR 8 ms QQBTGASB CZEEET 2 BF 2 CONTROLLED FORMING WIRE SEPARATION ON IMPERVIOUS ROLL OF TWIN-WIRE PAPERMAKING MACHINE BACKGROUND OF THE INVENTION The present invention relates to improvements in ftbrous web formation wherein an aqueous fiber suspension is dewatered on a porous forming surface, More particularly, the invention relates to improvements in web forming mechanisms of the type which have become to be known to the art as twin wire formers wherein a slurry of fibrous stock is delivered from a headbox slice opening to a forming throat between a pair of looped traveling forming wires with the web dewatered by being squeezed between the forming wires.
in relatively recent developments the art of papermaking has undergone a number of significant ad vances in the field of paper web formation using two opposed forming wire runs for web formation therebetween as contrasted to the heretofore more conventional Fourdrinier type papermaking machine employing only a single forming wire. Such twin wire forming machines have met with commercial success offering advantages of requiring less space and improved dewatering at high speeds. As the speed of the papermaking machines are increased. it becomes increasingly difficult to handle and control a high speed traveling fibrous web and to determine with a certainty the continued position of the web and to insure that it will continue to follow a forming wire without leaving the forming wire surface or following an opposing wire. In the manufacture of light weight paper webs, such as tissue, it is increasingly difficult to insure that the paper is not damaged at the point of wire separation due to splitting of the web at that point and the problem is one of insuring that most of the fiber follows one or the other of the two forming wires. These problems are particularly presented in a twin wire forming machine wherein the wires must be separated in order to pick off the web, and the web must follow the exact wire which will carry it to a pickoff device.
Efforts to solve this problem have resulted in teachings of the art that a suction mechanism such as a suction box must be positioned within the wire which the web is to follow to insure that it is stapled or adhered to the wire just before or as the wires are separating. Where the twin wires pass over a roll in an upwardly extending forming run, the roll has been provided with a suction box to staple the web to the inner wire. The necessity of providing a suction gland and a hollow roll is undesirable in increasing initial construction cost and increasing power consumption. Another method which has been employed is to keep the wires together, but to pass one of the wires over a suction box to insure transfer of the web to that wire. An important disadvantage associated with structures of the type described above is that on light weight sanitary grades, such as tissue, the suction box surface damages the sheet even though such suction box is designed with great care. Also, the requirement for the provision of suction boxes or suction rolls requires additional cost and space for pumps and other ancillary parts that wear and require maintenance.
An example of teachings of the prior art is shown in U.S. Pat. No. 3,056,7l9, Webster, wherein the patentee solves the problems of the operation by either employing only a single forming wire with an additional open roll and a suction gland at the end of the forming run to transfer the web to the wire, or, where two wires are used, providing an additional open roll with a suction box therein to assure adherence of the web to one of the wires.
Another teaching of the art is exemplified in U.S. Pat. No. 3,400,045, Graham, wherein the patentee requires that one of the flexible belts between which the web is sandwiched when it is formed be a felt, utilizing the commonly accepted teaching of the art that when two belts separate, the web will follow the belt of greater density, i.e., the felt.
A feature of the invention is applicants discovery of a combination of elements so constructed and so arranged that it is possible to combine the advantages of a twin wire former with the economics of a plain roll, and the use of two woven mesh wires permitting operation at maximum speed so that the unit is capable of operation at speeds approaching 7,000 feet per minute which is unusually high in the operation of present-day machines. High speeds are accomplishable by utilizing woven wires for both the formation members along the forming run and passing them over a plain solid cylindrical roll which has an absence of suction glands and where the wires do not have to run over suction boxes. Contrary to previous teachings. applicant has discovered that by separation of the outer wire from the inner wire by a small angle a while the inside wire is still supported on the plain roll, the web will unerringly follow the inner wire regardless of centrifugal force and contrary to expectation if one follows the teachings of the prior art and as would be expected from observing the obviously high centrifugal forces. The phenomena of physical forces will position the web on the outer surface of the inner wire without it being stapled thereto for each pickoff and the mechanism discovered causes a cleaning of the outer wire removing fibers entrained or intermeshed with the outer wire due to the dewatering being effected through the outer wire during the forming run. At the end of the forming run, the outer wire is first led away from the inner wire at a very small angle, and the physical force of the vacuum created as the upper wire is separated from the solid roll, at speed, will cause a flow of air through the outer wire sweeping any water remaining in the outer wire inwardly to help clean the outer wire of fiber and water. The web is held to the inner wire by the dynamically created differential pressure across the web, created by the separation, at speed, of the outer wire from the roll while the inner wire is still wrapped on the roll. This separation, at speed, tends to create a void or vacuum between the two wires which can only be filled from outside the outer wire and cannot be filled from inside the inner wire because of the solid impervious surface of the roll. It is the filling of this void from the outside which creates the differential pressure which fiushes the web and water from the outside surface of the inside wire. The vacuum or suction formed beneath the inner wire causes an inward flow of air and water through the outer wire so as to clean the outer wire and to help hold the web onto the inner wire. The surface tension of the water filling the interstices of the inner wire also causes the web to adhere to the inner wire, and in effect, the web is pasted onto the inner wire with a force which will completely overcome the centrifugal force on the web which tends to cause the web to lift off the inner wire. Using a woven inner wire and by pressing the web between the wires during the dewatering forming run, the removal of water will be substantially all through the outer wire. However, a small amount of water will travel inwardly to be held in the interstices of the inner wire to perform the sealing function which aids the phenomena of vacuum and surface tension thus insuring that the web will follow the inner wire. Since dewatering has occurred through the outer wire, the web will not be stapled to the inner wire, but will be resting lightly thereon so that it can readily be picked off the inner wire at the pickoff point and reducing the possibility of damage or splitting of the web.
An object of the present invention is to provide an improved and more economical twin wire forming mechanism and method using two woven wires with positive web control and the capability of having the web follow the inner wire without requiring suction boxes or suction rolls within the wire to effect the transfer of the web.
A further object of the invention is to provide an improved twin wire forming mechanism which is particularly well adapted to forming tissue or toweling and which utilizes simple high speed imperforate solid rolls for support of the twin wires.
A still further object of the invention is to provide a unique method and mechanism for the positive control of the web traveling in an arcuate path between a pair of forming wires insuring that the web follows the inner forming wire.
A further object is to provide a high speed paper forming system utilizing the dynamics of the woven forming wires and supports and without the use of externally powered vacuum devices such as suction rolls or suction boxes.
A further object of the invention is to provide a twin wire forming mechanism wherein the wires travel over a curved surface to dewater a web therebetween and dewatering is effected entirely through the outer wire and the outer wire is cleaned of fibers as the wires are separated and the web follows the inner wire.
The method and mechanism fine particular advantages in the formation of a paper web from cellulose fibers. but it will be understood that the features may be used to advantage in forming a web from other types of fibers. Also, the mechanism as disclosed is best suited for the handling of a slurry formed of an aqueous suspension but other forms of fluids may be employed.
Other objects, advantages and features, as well as equivalent structures and methods which are intended to be covered hereby will become more apparent with the disclosure of the preferred embodiment in the specification, claims and drawings in which:
DESCRIPTION OF THE DRAWINGS FIG. I is a side elevational view shown in somewhat schematic form of a machanism constructed and operating in accordance with the principles of the present invention;
FIG. 2 is an enlarged fragmentary schematic view of a portion of the mechanism of FIG. I shown for the purposes of illustrating certain principles as will become clear from the description; and
FIG. 3 is another enlarged fragmentary schematic view illustrating an alternate form of operation of a mechanism embodying the principles of the invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS As shown in FIG. I, the mechanism includes first and second looped woven permeable forming wires 10 and I2. The wires are trained over rolls so as to approach each other and form a tapered throat 13 into which a jet of stock is delivered, followed by an arcuate forming zone I4. For defining the arc of the forming zone, the wires are wrapped over the arcuate outer surface of a plain cylindrical roll 15. The roll has a smooth outer imperforate supporting surface for the wires, and the wires are tensioned so that they apply squeezing force normal to the web being formed therebetween to force the water out through the first or outer wire 10. It is important that the second or inner wire 14 be a pervious woven wire so as to provide a web backing or support, which can receive but does not absorb or retain excess water and which does not require elaborate dewatering mechanisms itself for removal of its water, such as would be required for a felts.
It is also important to provide a wire for the inner support for the web so that its interstices hold water for sealing the underside of the web and pasting it onto the wire at the separation point with the wire providing a substantially noncompressible and nonexpansible web support.
Further, the wires I2 and I0 being substantially similar in openness or weave are particularly well adapted for the formation required for a given web such as tissue and toweling. The solid imperforate roll I5 is particularly well adapted to very high speed operation and eliminates the need for suction glands or suction means and eliminates necessity of rubbing surfaces. The mechanism as is shown which eliminates the need for the wire passing over suction boxes and eliminates the need for suction glands is capable of operating at uniquely high speeds on the order of up to 7,000 ft. per minute with satisfactory long wire life.
The elimination of suction glands and the elimination of the necessity for a hollow roll shell is significant in the ability of the mechanism to achieve unusually high operating speeds. The noise factor would create substantial problems at high speeds if a perforate suction roll were used and problems would vary likely exist providing sealing surfaces that could operate for any length of time at these high speeds. The problems of inertia and pressure waves exist when high speeds are encountered in that the periods of time to which the web or wire is subjected to pressure becomes unusually small. Also, as will be immediately recognized by those versed in the art, the initial cost of a plain roll is considerably lower and the driving power needed for operation is lower. Wire abrasion and wear are reduced and the pressure between wires and roll surface do not create the problems that are present when a perforate roll is used.
The first looped outer wire [0 is supported on rolls located within the wire shown at 16, 17, 18, I9, 20, 2] and 22. At least one of the rolls, such as the roll I8 is capable of being moved to an adjusted position to place a predetermined linear tension in the wire to apply the desired squeezing force to the web in the forming zone 14.
The second looped inner forming wire 12 is supported on rolls 23, 24 and 25. The wires are both woven and preferably of the same size mesh.
As the water is squeezed from the web W which is being formed along the forming zone 14, the water is thrown outwardly from the surface of the outer wire to be caught by a saveall 33. An additional saveall 33a is located when the outer wire is separated from the inner wire.
For delivering stock to the throat I3, a headbox 26 is provided. Stock is delivered to the headbox under pressure to flow through the tapered slice chamber 261: of the headbox formed between the converging slice walls 27 and 28. Slice wall 28 is preferably pivotally adjustable so as to controllably regulate the size of the slice opening 29 from which issues a stock jet 30. The movable wall of the headbox is pivoted at 280, and a power means shown schematically at 28b controls the pivotal position of the wall and hence the size of the slice opening 29. The headbox 26 is supported on a pivot 26a and power means shown schematically at 26b and is attached to the headbox to establish its pivotal position. The pivotal position is chosen so that the stock jet 30 will substantially bisect the throat 13, but adjustments can be made so that the jet 30 passes into the throat more or less tangential to either the inner wire 12 or the outer wire 10.
A preferred form of headbox construction particularly well adapted to the formation of the web between wires, wherein the deflecting support for the wires is a solid roll, includes a plurality of trailing elements 31 positioned in the tapered slice chamber 30. A fine scale turbulence is generated maintaining uniform fiber dispersion for dewatering through the outer wire. These trailing elements are anchored only at their upstream ends at a perforate wall 32 in the headbox and are positionable responsive solely to forces of the stock flowing through the slice chamber. The trailing elements 3] may be in the form on individual flexible strands of material such as plastic, or may be in the form of continuous or interrupted sheets extending across the headbox. These trailing elements divide the stock flow into a plurality of independent flows having small scale turbu- Ience for intermixing and distribution of the fibers which form the web in the forming run.
The web W is formed in the forming zone I4. As the wires are separated from the roll and are separated from each other despite the fact that the outer wire is lifted first from the roll, the web follows the inner second wire 12. The outer wire 10 is separated from the inner wire 12 at a separation point 34, shown in FIGS. 1 and 2.
The web W follows the wire 12 and is picked off the upper surface of the wire by pickoff felt 36 brought into close adjacency with the web by pickoff felt roll 37. The web because it is dewatered through the outer wire, is not stapled to the inner wire but is easily removable.
The solid arcuate support for the wires in the forming zone is provided preferably by a cylindrical smooth surface roll 15, but because of high attainable speeds and lack of wire to roll friction, it will be understood that other forms of supports may be used such as a curved shoe. It is important in the mechanism and method of the structure that the support be imperforate at the first separation point 34 where the outer wire I0 is separated from the inner wire 12 and at the second separation point 35 where the inner wire is separated from the roll.
By providing an imperforate smooth support for the inner wire at the first and second separation points 34 and 35, the web is effectively sealed to the inner wire. It is also essential that the voids of the inner wire be filled with water so that the web will be sealed or pasted onto the inner wire. This is a result of the roll being imperforate and the web being squeezed during the forming run so that water which flows inwardly from the web fills the interstices of the inner wire. This will occur fairly easily in the forming zone and the rest of the water squeezed out of the web will be forced outwardly through the outer wire. Also, since the inner wire is filled with water, fibers will not be forced inwardly to staple themselves to the inner wire. Instead the web will be pasted to the inner wire and when the inner wire is lifted off the roll and the seal which holds the web to the inner wire is broken, the web can easily be lifted off the inner wire. When the inner wire reaches the separation points 34 and 35, the surface tension of the water within the inner wire and the sealing effect of the solid roll pastes or holds the web to the inner wire. At the second separation point 35 when the inner wire is lifted off the roll, a vacuum tends to form beneath the inner wire drawing the web down against the inner wire and tending to draw the water out from the inner wire. This vacuum plus the surface tension between the water and the roll surface, will tend to cause the water in the interstices of the inner wire to follow the surface of the roll 15 when this water is thrown off the roll, it is caught by a saveall 150. A separating doctor may be provided, not shown, to help the water separate from the outer surface of the roll 15 to pass into the saveall 15a.
Preferably, the outer wire 10 is separated on a very small distance from the inner wire 15 forming an acute angle a therebetween, as shown in FIG. 2. The angle a should be kept as small as possible so that the distance D is small.
The dewatering run along the surface of the roll is of a length so that the web will be dewatered therealong and by the time the web reaches the top of the roll 15, no substantial remaining amount of water is being squeezed therefrom. The amount of water squeezed from the web during the dwatering run is a function of the size of the roll as shown by the radius R of the roll IS in FIG. 2, and the linear tension of the outer wire 10.
As illustrated in FIG. I, the supporting roll 16 for the outer wire 10 is adjustable in location so as to be able to selectively control the angle a between the outer and inner wires 10 and 12. As illustrated somewhat schematically, the roll 16 is supported on a pivotal arm 16a pivotally supported at 16b and controllable in its position by a power means shown schematically at I60. This permits moving the roll 16 through a range of positions to select an angle shown at a in FIG. 2 and at a in FIG. 3. A saveall 33a is positioned above the wire separation points 34 and 35.
The angle a is preferably chosen to be at a minimum size such as in the range of greater than 0 and preferably not greater than 5. With this arrangement. the vac uum formed at location 40, FIG. 2, and the surface tension between the water and roll surface will tend to draw the water from the inner wire 12 and paste the web W onto the wire so that centrifugal force will not lift it. The separation of the web from the outer wire will cause an inrush of air down through the outer wire 10 cleaning the wire. Because during forming dewatering has occurred only through the outer wire 10, the wire has tended to become dirty because the fibers adhering to the wire. The inward flow of air and remaining adhering particles of water through the outer wire 10 cleans the wire. This cleaning is augmented by the inward surge of air tending to push forwardly any water present to cause a surge at location 41 to wash and help clean the upper wire removing the fibers stapled to the strands thereof. This surge of air through the outer wire is due to a large part to the inner wire being lifted off the roll with the inward pull on the web at that point. The operation shown in FIG. 3 lends support for this theory of outer wire cleaning because when the mechanism is operated in accordance with the relationship shown in FIG. 3 where the angle 01 is large. the outer wire is not as well cleaned.
in the operation of FIG. 3, the inner wire 12 is lifted off the roll a substantially greater distance D after the point of first separation A. Thus, the vacuum formed at point 40' does not augment or act substantially simultaneously with, the vacuum formed at location 41' so as to cause the inrush of air. lt has been discovered, however. that some advantages of the invention are still obtainable with the operation of the arrangement of FIG. 3. That is. the web will still be pasted to the inner wire [2. As the outer wire is lifted off of the roll, the web remains adhered to the inner wire due to the surface tension of the water in the interstices of the wire and due to the vacuum caused as the web tends to lift. As the wire 12 is lifted off of the roll from centrifugal force. the surface tension of the water causes the water in the wire to follow the roll. Because dewatering was substantially completely through the outer wire 10, the web is not stapled to the inner wire 12 and rides lightly thereon making it relatively easy for a pickoff felt to pick the web off the wire.
Thus, in operation a stock from the headbox 26 is directed in a jet 36 into the throat 13 between the forming wires 10 and [2. Along the forming run 14, the web is dewatered through the outer wire 10 into the saveall 33. At the end of the forming run, the outer wire 10 is first lifted off the roll and the inner wire 12 is almost immediately thereafter lifted off the roll 15, and the physical effects of surface tension and vacuum create the phenomena of overcoming the centrifugal force on the web and cause it to adhere to the inner woven wire with a concurrent cleaning of the outer wire. The web resting on the inner wire is readily picked off the wire by a pickup felt.
I claim as my invention:
1. A mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination:
a first looped permeable woven outer forming wire;
a second looped permeable woven inner forming wire; said wires positioned to form a converging throat leading to a forming run wherein the wires press against a web being formed therebetween;
a headbox having an opening positioned to direct a stream of stock into said throat;
guide rolls within each of the wire loops holding the loops in tension so that the outer wire applies a pressing force to press the stock between the wires in said forming run;
a convexly curved surface within the second wire with the first and second wires wrapping said surface along said forming run;
a first off running guide means for said first wire positioned following the forming run and separating the first wire from the second wire at a first separation point on said curved surface;
and a second off running guide means for said second wire following said forming zone and separating the second wire from said surface at a second separation point immediately following the first separation point with the web following the second wire;
said curved surface being imperforate at said separation points.
2. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim I:
wherein said curved surface is the outer surface of a rotatable imperforate cylindrical roll supporting said wires through the forming run.
3. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
and including a saveall means positioned within the first wire adjacent the forming zone receiving water expressed from the web in the forming zone and discharged through the first wire.
4. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
wherein said second offrunning guide means is positioned so that the angle between the wires at the second separation point is in the range of 0 to 5.
5. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
wherein said first and second wires each have a mesh of equal size. I
6. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
including within the head box immediately upstream of the opening a tapered slice chamber with a plurality of flexible trailing members anchored only at their upstream ends and being self-positionable responsive to the pressure of stock flowing past said members.
7. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
including a traveling pick-up felt and a pick-up roll within the felt positioned to carry the felt in contact with the web on the second wire following said sec-- ond separation point.
8. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
including means for adjusting the angle between the first and second wire following said separation points.
9. A mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination:
a first looped permeable woven outer forming wire;
a second looped permeable woven inner forming wire with said wires positioned to form a converging throat leading to a forming run wherein a web formed between the wires is pressed and dewatered;
a slice means having an opening positioned to direct a stream of stock into said throat;
a roll having an imperforate outer surface over which the wire loops are wrapped through said forming run;
first guide means for the outer wire bending the outer wire over said roll throughout the forming run and lifting the outer wire off of the roll,
and second guide means for the inner wire training the inner wire on the roll for the forming run and lifting the inner wire off the roll immediately after the outer wire is separated therefrom so that the web will follow the inner wire.
10. The method of continuously forming a fibrous web from a slurry of stock which comprises:
passing a pair of looped perforate woven tensioned forming wires through an arcuate forming run over an arcuate surface to apply a force normal to a web being formed therebetween to dewater the web;
delivering a stream of fibrous stock to the upstream end of said forming run;
separating the outer wire from the inner wire at a first separation point while traveling through said arcuate run and separating the inner wire from said run at a second separation point immediately after said first point;
and blocking the inner surface of the inner wire so that fluid is prevented from flowing outwardly at said separation points so that the web follows said inner wire.
11. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10:
maintaining the wires at an angle of separation between greater than and less than after said separation points.
12. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10:
wherein said blocking of the inner surface of the wire is performed by supporting the inner wire on a ro tatable cylindrical roll.
B. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10:
including the step of subsequently picking the web off of the inner wire after it has traveled a distance on the inner wire of said separation point.
14. The method of continuously forming a fibrous web from a slurry of stock which comprises:
guiding a pair of looped perforate woven forming wires under tension through an arcuate forming run over an imperforate rotating roll to apply a force normal to the web being formed therebetween to press water from the web into the space between the inner wire and the roll within interstices of the wire and through the outer wire so that water is thrown therefrom;
delivering a stream of fibrous stock slurry to the upstream end of the forming run;
and separating the outer wire from the inner wire lifting it off of the curved arcuate path on the roll while maintaining the inner wire on the roll so that the web remains pasted thereto and immediately thereafter lifting the inner wire off the roll so that the separation of the wires from each other and the inner wire from the roll generates an inward surge of air through the outer wire to clean fibers from the outer wire left thereon from dewatering through the outer wire.

Claims (14)

1. A mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination: a first looped permeable woven outer forming wire; a second looped permeable woven inner forming wire; said wires positioned to form a converging throat leading to a forming run wherein the wires press against a web being formed therebetween; a headbox having an opening positioned to direct a stream of stock into said throat; guide rolls within each of the wire loops holding the loops in tension so that the outer wire applies a pressing force to press the stock between the wires in said forming run; a convexly curved surface within the second wire with the first and second wires wrapping said surface along said forming run; a first off running guide means for said first wire positioned following the forming run and separating the first wire from the second wire at a first separation point on said curved surface; and a second off running guide means for said second wire following said forming zone and separating the second wire from said surface at a second separation point immediately following the first separation point with the web following the second wire;
2. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: wherein said curved surface is the outer surface of a rotatable imperforate
3. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: and including a saveall means positioned within the first wire adjacent the forming zone receiving water expressed from the web in the forming zone
4. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: wherein said second offrunning guide means is positioned so that the angle between the wires at the second separation point is in the range of
5. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1:
6. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: including within the head box immediately upstream of the opening a tapered slice chamber with a plurality of flexible trailing members anchored only at their upstream ends and being self-positionable responsive to the
7. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: including a traveling pick-up felt and a pick-up roll within the felt positioned to carry the felt in contact with the web on the second wire
8. A mechanism for continuously forming a fibrous web from a slurry of stock constructed in accordance with claim 1: including means for adjusting the angle between the first and second wire
9. A mechanism for continuously forming a fibrous web from a slurry of stock comprising in combination: a first looped permeable woven outer forming wire; a second looped permeable woven inner forming wire with said wires positioned to form a converging throat leading to a forming run wherein a web formed between the wires is pressed and dewatered; a slice means having an opening positioned to direct a stream of stock into said throat; a roll having an imperforate outer surface over which the wire loops are wrapped through said forming run; first guide means for the outer wire bending the outer wire over said roll throughout the forming run and lifting the outer wire off of the roll, and second guide means for the inner wire training the inner wire on the roll for the forming run and lifting the inner wire off the roll immediately after the outer wire is separated therefrom so that the web
10. THE METHOD OF CONTINUOUSLY FORMING A FIBROUS WEB FROM A SLURRY OF STOCK WHICH COMPRISES: PASSING A PAIR OF LOOPED PERFORATE WOVEN TENSIONED FORMING WIRES THROUGH AN ARCUATE FORMING RUN OVER AN ARCUATE SURFACE TO APPLY A FORCE NORMAL TO A WEB BEING FORMED THEREBETWEEN TO DEWATER THE WEB; DELIBERING A STREAM OF FIBROUS STOCK TO THE UPSTREAM END OF SAID FORMING RUN; SEPARATING THE OUTER WIRE FROM THE INNER WIRE AT A FIRST SEPARATION POINT WHILE TRAVELING THROUGH SAID ACUATE RUN AND SEPARATING THE INNER WIRE FROM THE INNER WIRE FROM SAID RUN SEPARATION POINT IMMEDIATELY AFTER SAID FIRST POINT; AND BLOCKING THE INNER SURFACE OF THE INNER WIRE SO THAT FLUID IS PREVENTED FROM FLOWING OUTWARDLY AT SAID SEPARATION POINT SO THAT THE WEB FOLLOWS SAID INNER WIRE.
11. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10: maintaining the wires at an angle of separation between greater than
12. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10: wherein said blocking of the inner surface of the wire is performed by
13. The method of continuously forming a fibrous web from a slurry of stock in accordance with the steps of claim 10: including the step of subsequently picking the web off of the inner wire after it has traveled a distance on the inner wire of said separation
14. The method of continuously forming a fibrous web from a slurry of stock which comprises: guiding a pair of looped perforate woven forming wires under tension through an arcuate forming run over an imperforate rotating roll to apply a force normal to the web being formed therebetween to press water from the web into the space between the inner wire and the roll within interstices of the wire and through the outer wire so that water is thrown therefrom; delivering a stream of fibrous stock slurry to the upstream end of the forming run; and separating the outer wire from the inner wire lifting it off of the curved arcuate path on the roll while maintaining the inner wire on the roll so that the web remains pasted thereto and immediately thereafter lifting the inner wire off the roll so that the separation of the wires from each other and the inner wire from the roll generates an inward surge of air through the outer wire to clean fibers from the outer wire left thereon from dewatering through the outer wire.
US397400A 1973-09-14 1973-09-14 Controlled forming wire separation on impervious roll of twin-wire papermaking machine Expired - Lifetime US3876498A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
US397400A US3876498A (en) 1973-09-14 1973-09-14 Controlled forming wire separation on impervious roll of twin-wire papermaking machine
CA200,965A CA1010277A (en) 1973-09-14 1974-05-27 Tissue former
FI1672/74*A FI167274A (en) 1973-09-14 1974-05-31
FR7428660A FR2244049B1 (en) 1973-09-14 1974-08-21
AR255301A AR203761A1 (en) 1973-09-14 1974-08-23 APPARATUS FOR THE CONTINUOUS FORMATION OF A FIBROUS SHEET FROM A DILUTED PASTE MATERIAL
ES429632A ES429632A1 (en) 1973-09-14 1974-08-29 Controlled forming wire separation on impervious roll of twin-wire papermaking machine
GB3904574A GB1477049A (en) 1973-09-14 1974-09-06 Method and apparatus for continuously forming a fibrous web
DE2442925A DE2442925C3 (en) 1973-09-14 1974-09-07 Web formation zone of a paper machine with two main belts
SE7411459A SE415111B (en) 1973-09-14 1974-09-11 METHOD AND APPARATUS FOR CONTINUOUS PREPARATION OF A FIBER COAT
BR7615/74A BR7407615D0 (en) 1973-09-14 1974-09-12 PERFECT PROCESS AND APPARATUS TO CONTINUOUSLY FORM A CONTINUOUS FIBROUS STRIP FROM A FLUID FOLDER OF MATERIAL
IT27250/74A IT1021344B (en) 1973-09-14 1974-09-13 METHOD AND APPARATUS FOR THE CONTINUOUS FORMATION OF PAPER FIBER RIBBONS

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US397400A US3876498A (en) 1973-09-14 1973-09-14 Controlled forming wire separation on impervious roll of twin-wire papermaking machine

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AR (1) AR203761A1 (en)
BR (1) BR7407615D0 (en)
CA (1) CA1010277A (en)
DE (1) DE2442925C3 (en)
ES (1) ES429632A1 (en)
FI (1) FI167274A (en)
FR (1) FR2244049B1 (en)
GB (1) GB1477049A (en)
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SE (1) SE415111B (en)

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US3996098A (en) * 1965-08-14 1976-12-07 Valmet Oy Twin-wire paper machine with common wire path controls
US4100018A (en) * 1975-06-23 1978-07-11 Aktiebolaget Karlstads Mekaniska Werkstad Method and apparatus for forming a fibrous web
DE2641714A1 (en) * 1975-09-17 1977-03-24 Valmet Oy TISSUE PAPER MACHINE
DE2647295A1 (en) * 1976-10-20 1978-04-27 Voith Gmbh J M PAPER MACHINE
US4207144A (en) * 1976-10-20 1980-06-10 J. M. Voith, Gmbh Papermaking machines
US4153504A (en) * 1977-01-31 1979-05-08 Beloit Corporation Twin-wire fibrous web former and method
US4234382A (en) * 1977-12-08 1980-11-18 J. M. Voith Gmbh Former for a paper machine
US4176005A (en) * 1978-01-16 1979-11-27 Escher Wyss Gmbh Double filter papermaking machine
US4240872A (en) * 1978-03-17 1980-12-23 Ab Karlstads Mekaniska Werkstad Suspension device for a headbox for paper and pulp machines
US4267017A (en) * 1980-01-09 1981-05-12 Beloit Corporation Drainage roof for twin wire roll former
US4443300A (en) * 1980-03-18 1984-04-17 Escher Wyss Gmbh Paper making machine with a filter cylinder
US4443297A (en) * 1980-08-18 1984-04-17 James River-Dixie/Northern, Inc. Apparatus and method for the manufacture of a non-woven fibrous web
US4443299A (en) * 1980-08-18 1984-04-17 James River-Dixie/Northern, Inc. Apparatus and method for the manufacture of a non-woven fibrous web
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US6500302B2 (en) 1990-10-17 2002-12-31 Fort James Corporation Foam forming method and apparatus
US6413368B1 (en) 1990-10-17 2002-07-02 Fort James Corporation Foam forming method and apparatus
US6017421A (en) * 1997-07-04 2000-01-25 Voith Sulzer Papiermaschinen Gmbh Headbox with baffle
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USD809116S1 (en) 2015-11-02 2018-01-30 Pura Scents Dispenser
USD816506S1 (en) 2015-11-02 2018-05-01 Pura Scents, Inc. Vial for a scent dispenser
USD873142S1 (en) 2015-11-02 2020-01-21 Pura Scents, Inc. Vial for a scent dispenser
US10967091B2 (en) 2015-11-02 2021-04-06 Pura Scents, Inc. Scent dispensation
US11213601B2 (en) 2015-11-02 2022-01-04 Pura Scents, Inc. Fragrance intensity control mechanism with PID control
US11253624B2 (en) 2015-11-02 2022-02-22 Pura Scents, Inc. Data analysis, learning, and analytics generation
US11285233B2 (en) 2015-11-02 2022-03-29 Pura Scents, Inc. Device scent state recovery mechanism with GPS intelligence
US11918710B2 (en) 2015-11-02 2024-03-05 Pura Scents, Inc. Enhanced dispenser control

Also Published As

Publication number Publication date
SE7411459L (en) 1975-03-17
DE2442925B2 (en) 1980-05-22
FR2244049B1 (en) 1979-10-12
CA1010277A (en) 1977-05-17
ES429632A1 (en) 1976-10-01
DE2442925A1 (en) 1975-03-20
SE415111B (en) 1980-09-08
GB1477049A (en) 1977-06-22
IT1021344B (en) 1978-01-30
BR7407615D0 (en) 1975-09-09
DE2442925C3 (en) 1981-02-12
FI167274A (en) 1975-03-15
FR2244049A1 (en) 1975-04-11
AR203761A1 (en) 1975-10-15

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