|Publication number||US3868205 A|
|Publication date||25 Feb 1975|
|Filing date||15 Mar 1973|
|Priority date||15 Mar 1973|
|Publication number||US 3868205 A, US 3868205A, US-A-3868205, US3868205 A, US3868205A|
|Inventors||Thomas Gordon D|
|Original Assignee||Kimberly Clark Co|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (6), Referenced by (35), Classifications (17)|
|External Links: USPTO, USPTO Assignment, Espacenet|
[ 1 Feb. 25, 1975 United States tent 1 Thomas 3,571,852 3/1971 Gilbert................;............... 425/369 3,756,884 9/1973 Hagino;..........,.................... 156/471 1 1 EMBOSSED PAPER TOWELING AND METHOD OF PRODUCTION  Inventor: Gordon D. Thomas, Neenah, Wis. Primary Examiner George Lesmes Kimberly-Clark Corporation, Neenah, Wis.
Mar. 15, 1973  Assignee:
Corporation 22] Filed:
 ABSTRACT Absorbent paper sheets in multi-ply web form in Appl. No.: 341,464
which the outer webs of the sheet are creped and consist of a series of ribs and grooves. The webs have their ribs secured together by adhesive dispersed in a pattern consisting of individual adhesive zones. The adhesive zones are obtained by providing in embossing apparatus cooperable rolls each having alternating ribs and grooves, the ribs of one roll being provided with protuberances and the other with recesses. The protu-  References Cited berance; cover a retlativetlly smaltl larea of Ill; total1 rib area an carryawe on e pro u erances roug an UNITED STATES PATENTS adhesive applicator so that a relatively small area of the web receives adhesive for attachment to a second 161/148 Chavannes.......................,.. 161/127 Moone................................ Leonard, Jr.
.h C u S 3446 3366 9999 1111 8497. 3569 73 00 v .3 4404 2550 31 5 Claims, 16 Drawing Figures 3.868.205 SHEET :1 OF 10 PATENTEB FEB 2 51975 III/III!) PATENTED FEBZSIPJS 3' 868 I205 sum c 3 1F 10 FIG. 3
PATENTED #5 SHEET USOF 10 ADHESIVE PATTERN ADHESIVE PATTERN FIG. 8
PATENTEU 3,868,205 SHEET UEUF 10 FIG. 9
PATENTED FEB 2 5 SHEET [UN 10 PATENTED F552 5 SHEET U80F 10 w 0 E ZEPEQ M2812 SHEET user 10 3'868205 PATH-HEB FEB251975 SHEET IOUF 10 P/JENTED F552 5 E 75 EMBOSSED PAPER TOWELING AND METHOD OF PRODUCTION BACKGROUND OF THE INVENTION This invention relates to multi-ply absorbent, soft paper products useful as towels, napkins, wipes and the like. The invention is also concerned with methods and apparatus for attaining such absorbent paper products utilizing an efficient, suitable and generally minimal amount of adhesive to secure attachment of creped tissue webs to form a multi-ply sheet product.
It is known to provide embossed webs and to laminate them into the form of a sheet by adhesive attachment on a commercial basis. This may be done by any of several methods. One common method is to apply adhesive to the embossment surfaces of one of the webs of a sheet product and uniting at the embossment surfaces of the other web. In this instance for a two-ply web, each web is separately embossed and remains in contact with their respective separate embossing rolls. Adhesive is applied in a thin layer to the embossment surfaces of one of the webs with commercially available adhesive applicating equipment and both webs are joined at their embossment surfaces in the nip formed by the mated steel embossing rolls. This method provides a high bulk product having good quality ply attachment and works satisfactorily with discrete peg types of embossing patterns. With other types of embossing patterns, particularly gross patterns consisting of continuous line or embossed line patterns, this method results in application of adhesive to the entire land area of the sheet embossments, even though adhesive attachment may be obtained at a small portion of the total embossed land area, by utilizing for embossing, roll patterns which are in crossing relationship. The result is the use of more total adhesive than necessary for ply attachment purposes, which increases the product cost and also stiffens the product structure.
The present invention is an improvement on prior art practices in that adhesive is applied in well spaced adhesive zones, and the adhesive zones define embossments which are superposed on more gross embossments of the web product. This is accomplished by securing the webs together in a combining nip formed by a pair of cooperable embossing rolls having particular characteristics. The embossing rolls for the purpose each have a series of alternating ribs and grooves disposed about its periphery; the ribs of one roll have land areas and projections extending above the land areas separated by the land areas, and the ribs of the other roll have land areas and recesses lying below and separated by these last mentioned land areas of the second roll. The projections of one roll in the rotation of the rolls is receivable in mating recesses of the other said roll. In a further embodiment each of the rolls may have projections which cooperate with the recesses of the other roll.
The projections of the embossing roll support a web for the receipt of adhesive only in the zone of the projection. Since such projections may be conveniently formed by etching, grinding or the like to a very small size. the adhesive application in an adhesive zone may be quite readily limited. Such leads to good flexibility in the webs and final sheet and is conserving of adhesive.
Another advantage for the above embossing and combining method is that it results in a product having tractiveness because of the gross nature of the embossments. By providing the continuous lines embossments of one web with spaced projections and the other with spaced recesses, a more textured or woven type appearance is obtained in the product. The laminated product still has the same general appearance on both sides. However, the embossment line recesses on one of the webs prior to lamination become slightly raised projections as received in the finished product. Similarly, the embossment line raised projections of the other web become slight recesses after lamination in the finished product. These projections and recesses being confined to the continuous line embossments area tend to break up the continuity of the embossments and result in a more pleasing pattern appearance. In fact, the product attains somewhat of a woven fabric appearance.
The invention will be more fully understood by reference to the following detailed description and accompanying drawings wherein:
FIG. 1 is an enlarged and fragmentary view in side elevation illustrating the relationship of the combining rolls of the apparatus with the creped tissue sheets of the sheet material at the combining nip;
FIG. 2 is a fragmentary view in perspective of the combining rolls only illustrating the cooperative relationship of the spirally contoured rolls and their male and female segments;
FIG. 3 is a view in side elevation of embossing apparatus useful in the production of a preferred embodiment of the sheet material and illustrating particularly a four-roll stack having rolls similar to those illustrated in FIGS. 1 and 2;
FIGS. 4 and 5 are respectively fragmentary views on a somewhat enlarged scale of the combining rolls of FIG. 3;
FIG. 6 is a perspective view of the sheet material with the upper web stripped back from the lower web to reveal the adhesive pattern of the sheet;
FIGS. 7 and 8 are views schematically illustrating useful adhesive patterns in the practice of the invention, the view in FIG. 7 being similar to that of the structure shown in FIG. 6;
FIG. 9 is a view similar to that of FIG. 3 but illustrating a roll arrangement for the production of a three-ply sheet product;
FIGS. 10 and 11 are respectively enlarged fragmentary views of the upper and lower combining rolls of the structure of FIG. 9;
FIG. 12 is a view in perspective of a three-ply sheet (with the arrow indicating the direction of travel to the product through the combining rolls of FIG. 9) having the upper and central plies-partially turned back to reveal the adhesive patterns;
FIG. 13 is a schematic view in plan illustrating more specifically the adhesive patterns of the structure of FIG. 12;
FIGS. 14 and 15 are fragmentary views of a further embodiment of the invention illustrating cooperating upper and lower combining rolls having a different form of mating segments; and
FIG. 16 is a fragmentary view in section of a product passing through the type of combining rolls illustrated in FIGS. 14 and 15.
Referring now more in detail to the drawings, the numeral (FIGS. 1-3 inclusive) designates an upper metallic combining roll which cooperates with a similar lower metallic combining roll 11. The composite sheet which issues from the nip between the combining rolls 10,11 is formed of an upper creped paper tissue web 12 and a lower creped paper tissue web 13. The upper web 12, as it approaches the nip between the combining rolls, is provided with an adhesive pattern as is most clearly indicated at 14 in FIGS. 1 and 6.
The upper combining roll 10 is provided with spirally extending ribs 15 (FIG. 2) spaced apart by grooves 16. The ribs 15 are generally rectangular in cross-section, extend at 45 to the direction of sheet travel through the rolls 10,1 1, and are provided over their length with a series of protuberances 17 which extend above land areas 18 separating the protuberances. The protuberances 17, as is most clearly shown in FIGS. 2 and 4, have a generally rectangular configuration as viewed in plan except at the roll ends where the protuberances terminate the roll and have a triangular configuration as indicated at 17a. The land areas 18 are of greater length in the embodiment illustrated than the projections 17.
The lower combining roll 11 has ribs 19 which are generally rectangular in cross-section and separated by grooves 20 (FIG. 5). The ribs 19 over their length are provided with a series of recesses 21 also rectangular as viewed in plan spaced apart by land areas 22 of greater length than the recesses. The ribs 19 extend also at 45 to the direction of sheet travel. The roll ends, as indicated in FIG. 2, are terminated in the area of the ribs 19 by recessed portions of triangular shape 21a.
The rolls 10,11 rotate in the direction indicated by the arrows (FIG. 2). The ribs 15,19 extend transversely to each other and. suitably, the ribs have a width of between about 0.015 and 0.050 inch. The grooves 16 and 20 preferably have a somewhat greater length in a direction perpendicular to adjacent ribs and are of about 0.015 to about 0.125 inch. The ribs, while generally rectangular in cross-section, suitably have slightly angled sides to facilitate web movement into the grooves.
Referring now particularly to FIGS. 4 and 5, the projections 17 are designed in the operation of the rolls in the manner illustrated in FIG. 3 to enter into the'recesses 21. The recesses are specifically made quite shallow to minimize distortion at the recess edges of webs forced into the recesses by the action of the projections 17. The projections and recesses need, for example, be only about 0.005 inch. Two plies of the web material each of thickness of about 0.001 inch are slightly compressed by the action of the combining rolls in the manner illustrated in FIG. 1 to insure of good adhesive contact of the webs 12,13.
As will be clear from a consideration of FIGS. 4 and 5, the protuberance b of roll 10, for example, mates with the recess b of roll 11; similarly, the triangular protuberance c cooperates withthe triangular recess 0.
The webs 12,13 (FIG. 3) are directed to the combining rolls 10,11 respectively over rolls 23,24. In the formation of a two-ply sheet the adhesive is applied to the upper traveling web 12 as illustrated in FIG. 3. The liquid adhesive material designated at 25 is fed by a fountain roll 26 to a metering roll 27 in thin film form and transferred to roll 28. The roll 28 engages the traveling web on the combining roll 10 only at the protuberances 17,17a so that only a minor area of adhesive relative to the web area is added to the traveling web 12 (FIG. 6). The pattern of the adhesive in a preferred embodiment is clearly shown in FIG. 6. The lower web 13 in FIG. 6 also shows the presence of adhesive in the stripped back zone for the reason that some adhesive will adhere to the lower ply 13 when the strip back action is effected. Most importantly, however, the adhesive is only applied in well spaced areas where pressure application by the protuberances 17 on material in the re cess 21 is effected and all adhesive employed serves in a bonding action.
Essentially as illustrated in FIG. 7, the sheet may have an area of about 9 percent of the total to which adhesive has been applied. If a more flexible sheet is desired, the adhesive may be reduced and FIG. 8 illustrates a pattern which is generally sinusoidal and suitable for this latter purpose. The adhesive is shown at the cross-over points of the sinusoidal embossments of overlying webs. In the arrangement of FIG. 8 the area having adhesive is about 4 percent of the total area of one sheet.
In order to produce a three-ply product, it is desirable to apply the adhesive to each of the outer plies of the three-ply web in much the same manner as adhesive has been described as applied to the two-ply web of FIG. 6. Thus, as illustrated in FIG. 9, the creped paper web 13' which is combined at the nip between rolls l0 and 11' with the creped paper web 12' is itself adhesively treated. For this purpose a flexographic adhesive printer similar to that described in connection with FIG. 3 is provided; this mechanism includes the pond of adhesive 25', fountain roll 26', metering roll 27, and transfer roll 28. The middle ply of the three-ply web product is indicated at 30 (FIG. 9) and receives adhesive from each of the outer plies as may be clearly seen from FIG. 12. This middle ply may be a strengthening web such as a scrim, an uncreped web or a creped web similar to the outer webs.
The adhesive pattern of the structure of FIG. 12 is, however, quite different than that previously mentioned in connection with FIGS. 6 through 8. The different adhesive pattern is obtained by the provision of engraved'rolls such as indicated in FIGS. 10 and 11. The roll 10 has a series of spirally extending lands and grooves and the lands are configurated as follows. The land portion designated by each numeral 31 provides projections similar to those mentioned in connection with roll 10. An end projection of triangular form is shown at 31a. Each projection 31 lies adjacent a planar portion 32 of the land and a recess 33 of a land also lies adjacent each land portion 32. In the upper roll 10, then, each land has three levels. Thus, each projection 31 of a land is bounded by a planar portion of the land and each recess is also bounded by a planar portion of a land except at roll ends; the projection and recesses at the roll ends alternate around the roll periphery.
The lower roll 11 (FIG. 11) is provided with lands which have either recesses or projections. The numeral 34 designates the land areas of each rib. The recesses from the level 34 are designated at 35 and 35a while projections from level 34 are indicated at 36 and 36a. As is clearly seen from the drawings, the projections of roll 10' cooperate with the recesses of roll 11' in a manner similar to that described in connection with FIGS. 4 and 5. The recess at f, for example, cooperates with the projection f of roll 11'. By this arrangement the projections of roll and the projections 36 of roll 11' receive the adhesive as the sheet 12 and 13' travel to the combining nip (FIG. 9). Much less adhesive is required while yet permitting the attainment of well adhered plies. The adhesive pattern as applied to the upper sheet 12' is illustrated at 40 (FIG. 12) and that retained by the middle ply upon separation is indicated at 40. Similarly, the adhesive zone applied to the lower ply 13 is indicated at 41 and that retained by the middle ply on separation is illustrated at 41'.
FIG. 13 schematically sets forth the adhesive arrangement for a ply of the structure of FIG. 12 and, as is clearly shown, each outer sheet has adhesive on it to the extent of about only 4 5 percent of its surface area.
A further embodiment of the invention is illustrated by the FIGS. 14 through 16 inclusive. The numeral 42 (FIG. 14) designates an upper combining roll of a pair, the lower roll being indicated by the numeral 43. The upper roll has a series of ribs 44 separated by grooves 45 while the lower roll has a series of ribs 46 separated by grooves 47. Projections 48, generally conical in shape, well spaced along the length of the ribs 44, mate with generally conical depressions 49 spaced along the length of the ribs 46. As will be obvious from the foregoing, the function of the projections 48 in the furnishing of a two-ply sheet is to support the upper web as it receives the adhesive in the formingof the two-ply structure in the same manner as has been described in connection with FIGS. 1 through 7. However, in this instance the individual adhesive zones may be small in diameter though preferably the recesses or depressions 49 should be maintained shallow to avoid web distortion in the adhesive areas.
Very pertinent to the practice of this invention is the saving in adhesive which makes for an economical product. Further. the fact that much of the area of the sheets does not require adhesive provides for minimal stiffness of the product. Additionally, the adhesive zones may be spaced well apart on any given land area of the product.
EXAMPLE 1 A toweling material was produced by directing base webs to the equipment arrangement of FIG. 1. Such webs suitably have a dryer basis weight of about 9-12 pounds per 2,880 square feet and a stretch at break in the range of -35 percent. The adhesive supplied to the upper web was polyvinyl alcohol. Other adhesives may, of course, be employed. The spiral pattern of the rolls had lands about 0.030 inch wide and extended continuously at a 45 angle with respect to the axis of the roll. The depth ofthe ribs and the distance between ribs was about 0.070 inch. Engraving the lands into recesses and projections reduced the land area of the sheet containing adhesive. from 30 to 9 percent. This reduces the amount of adhesive applied by a factor of over 3 to 1. Resulting laminated product produced by this method had good bulk characteristics, embossing pattern definition and acceptable ply attachment for towel use. Ply attachment values of 10 gms. per 4 inches and up were possible, depending on the amount ofadhesive applied and the combining nip pressure between the two engraved steel embossing rolls. Ply atouter webs on a portion of the sample, and then placing those 4-inch wide separated web portions in an Instron tester to measure the force required for ply separation.
EXAMPLE 2 Two and three-ply towel weight samples were prepared using the above spiral rib embossing pattern. prior to and after engraving the cross-over points. For the two-ply samples and the outer surface plies of the three-ply samples, a creped tissue web having a dryer basis weight of 10-1 1 pounds per 2,880 square feet and a stretch at break of about 32 percent was employed. For the center web in the three-ply samples, a creped tissue web having a dryer basis weight of about 6-7 pounds per 2,880 square feet and a stretch at break of about percent. The following shows test results on these samples.
Engraved C ross- The Handle-O-Meter values show the improved limpness for the samples produced when the cross-over points were engraved, which is the result of reducing the adhesive coverage on a large portion of the continuous spiral rib lands.
The Handle-O-Meter values were obtained by using a common Thwing-Albert Handle-O-Meter test. For test purposes to obtain the Handle-O-Meter value in the machine direction. 2 /2 inches wide X 6 inches long samples were used, and for cross direction samples were 2% inches wide X 3% inches long. The Handle-O- Meter values give an indication of sheet stiffness and lower values indicate better handle and less stiffness.
In most instances the application of adhesive to the extent of about 5 percent of the sheet area is suitable if the projections of the roll which receive the adhesive are well and uniformly spaced. The pattern and basetissue weight chosen for the final product influence the amount of adhesive applied to the sheet. With heavier weight sheets and more gross patterns usually a greater amount of area of the sheet is occupied by adhesive to insure of good laminate characteristics. The situations found particularly useful are those in which 10 to 50 percent of the rib surface area is constituted by projections for receipt of adhesive.
For a three ply sheet where the projections and recesses alternate on one land of each roll, the same principles are applicable but 5 percent to 25 percent of the rib surface area will be projections but, of course. adhesive is then applied to both outer sheets.
As many apparently widely different embodiments of this invention may be made without departing from the spirit and scope thereof, it is to be understood that I do not limit myself to the specific embodiments thereof except as defined in the appended claims.
1. ln embossing apparatus, a pair of cooperable embossing rolls each having a series of ribs and grooves extending continuously lengthwise of the rolls, the ribs being spaced apart circumferentially by the said grooves disposed about the roll periphery, the ribs of one roll each having a plurality of surface land areas also extending longitudinally on the ribs and projections of these ribs extending above the land areas and separated longitudinally by the land areas and peripherally from projections of adjacent ribs by the said grooves, the ribs of the other roll having surface land areas extending longitudinally on the ribs and recesses of the ribs lying below and separated by these latter mentioned land areas for mating with the said projections, and the projections of the one said roll in the rotation of the cooperable embossing rolls being receivable in the mating recesses of the other said roll, the said recesses being shallow relative to the depth of the ribs. I
2. Embossing apparatus as claimed in claim I in which the land areas of the ribs of the one said roll are of greater length along the ribs than the projections separated by the land areas and the projections have a height of about 0.005 inch.
3. Embossing apparatus as claimed in claim 1 in which the projections and recesses as viewed in plan are rectangular and the projection and recess at each end of a rib is triangular.
4. Embossing apparatus as claimed in claim 1 in which the projections and recesses are generally conical in shape and each lies wholly within the width of the rib which accommodates it.
5. Embossing apparatus as claimed in claim 1 in which each of the ribs of each roll have projections, recesses and land areas, the land areas of each roll separating the projections and recesses of that roll and the projections of each roll being receivable in the recesses of the other.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US1924873 *||1 Nov 1930||29 Aug 1933||Orenda Corp||Machine for making packing material|
|US1954635 *||2 Oct 1929||10 Apr 1934||Orenda Corp||Sheet forming device|
|US3150416 *||29 Jul 1960||29 Sep 1964||Kendall & Co||Method and apparatus for producing apertured non-woven fabrics|
|US3294389 *||29 Jun 1965||27 Dec 1966||Marc A Chavannes||Laminated cellular material|
|US3571852 *||28 Aug 1967||23 Mar 1971||John Harold Gilbert||Apparatus for forming corrugated foamed thermoplastic materials|
|US3756884 *||21 Dec 1971||4 Sep 1973||Mitsui Petrochemical Ind||W closed cells process and apparatus for producing laminanted structure having hollo|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4284465 *||7 Dec 1979||18 Aug 1981||American Can Company||Apparatus for the manufacture of fibrous sheet structure|
|US4320162 *||15 May 1980||16 Mar 1982||American Can Company||Multi-ply fibrous sheet structure and its manufacture|
|US4376671 *||5 Oct 1981||15 Mar 1983||American Can Company||Multi-ply fibrous web structure and its manufacture|
|US5269983 *||9 Jan 1992||14 Dec 1993||James River Corporation Of Virginia||Rubber-to-steel mated embossing|
|US5490902 *||18 Oct 1994||13 Feb 1996||James River Corporation Of Virginia||Strength control embossing and paper product produced thereby|
|US5693403 *||27 Mar 1995||2 Dec 1997||Kimberly-Clark Worldwide, Inc.||Embossing with reduced element height|
|US5900114 *||3 Jul 1997||4 May 1999||Kimberly-Clark Worldwide, Inc.||Embossing with reduced element height|
|US5913765 *||2 Mar 1995||22 Jun 1999||Kimberly-Clark Worldwide, Inc.||System and method for embossing a pattern on a consumer paper product|
|US6247914 *||28 Dec 1995||19 Jun 2001||Sca Hygiene Products Ab||Casing material and a method and apparatus for its manufacture|
|US6251207||24 Mar 1999||26 Jun 2001||Kimberly-Clark Worldwide, Inc.||Embossing and laminating irregular bonding patterns|
|US6287676 *||10 Feb 1993||11 Sep 2001||Georgia-Pacific France||Compound sheets made of absorbent paper|
|US6458447||16 Apr 1998||1 Oct 2002||The Proctor & Gamble Company||Extensible paper web and method of forming|
|US6589634||13 Mar 2001||8 Jul 2003||Kimberly-Clark Worldwide, Inc.||Embossing and laminating irregular bonding patterns|
|US6602577||3 Oct 2000||5 Aug 2003||The Procter & Gamble Company||Embossed cellulosic fibrous structure|
|US6723203 *||11 May 2001||20 Apr 2004||Georgia-Pacific France||Absorbent paper product with asymmetric structure|
|US7771566 *||11 Jun 2008||10 Aug 2010||The Procter + Gamble Company||Embossed multi-ply tissue having a softening lotion|
|US7799169||21 Sep 2010||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US8025764||31 Aug 2010||27 Sep 2011||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US8216424||13 Nov 2009||10 Jul 2012||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US8287986||16 Oct 2012||Georgia-Pacific Consumer Products Lp||Ultra premium bath tissue|
|US8506756||4 Mar 2009||13 Aug 2013||Sca Tissue France||Embossed sheet comprising a ply of water-soluble material and method for manufacturing such a sheet|
|US8771466||2 Jul 2013||8 Jul 2014||Sca Tissue France||Method for manufacturing an embossed sheet comprising a ply of water-soluble material|
|US20060042767 *||22 Nov 2004||2 Mar 2006||Fort James Corporation||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US20070131368 *||14 Dec 2005||14 Jun 2007||Sonoco Development, Inc.||Paperboard with discrete densified regions, process for making same, and laminate incorporating same|
|US20080264275 *||30 Apr 2007||30 Oct 2008||Lee Delson Wilhelm||Embossing apparatus|
|US20080314535 *||11 Jun 2008||25 Dec 2008||The Procter & Gamble Company||Embossed multi-ply tissue having a softening lotion|
|US20090297781 *||27 May 2009||3 Dec 2009||Georgia-Pacific Consumer Products Lp||Ultra premium bath tissue|
|US20100116451 *||13 Nov 2009||13 May 2010||Georgia-Pacific Consumer Products Lp||Multi-Ply Paper Product with Moisture Strike Through Resistance and Method of Making the Same|
|US20100319864 *||31 Aug 2010||23 Dec 2010||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US20100326613 *||4 Mar 2009||30 Dec 2010||Yoann Denis||Embossed sheet comprising a ply of water-soluble material and method for manufacturing such a sheet|
|EP1101866A1 †||21 Nov 2000||23 May 2001||Fort James France||Creped and embossed absorbant paper sheet, embossing roll and embossing process|
|WO1993011929A1 *||7 Dec 1992||24 Jun 1993||Kaysersberg||Process and machine for the manufacture of embossed laminated film|
|WO1994012343A1 *||22 Nov 1993||9 Jun 1994||Kaysersberg||Laminated product made of cellulose wad|
|WO2008132612A1 *||19 Feb 2008||6 Nov 2008||Kimberly-Clark Worldwide, Inc.||Embossing apparatus|
|WO2014181389A1 *||7 May 2013||13 Nov 2014||Kikuo Yamada||Water-disintegrable paper manufacturing method|
|U.S. Classification||425/363, 425/500, 156/555|
|International Classification||B31F1/00, D21H27/30, B31F1/07, D21H27/40|
|Cooperative Classification||B31F2201/0728, B31F2201/0738, B31F2201/0787, B31F1/07, D21H27/40, B31F2201/0735, B31F2201/0761, B31F2201/0766|
|European Classification||B31F1/07, D21H27/40|