US3819522A - Anti-fogging window cleaner surfactant mixture - Google Patents
Anti-fogging window cleaner surfactant mixture Download PDFInfo
- Publication number
- US3819522A US3819522A US00291681A US29168172A US3819522A US 3819522 A US3819522 A US 3819522A US 00291681 A US00291681 A US 00291681A US 29168172 A US29168172 A US 29168172A US 3819522 A US3819522 A US 3819522A
- Authority
- US
- United States
- Prior art keywords
- diol
- composition
- surface active
- active agent
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 133
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 74
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 65
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 41
- 238000004140 cleaning Methods 0.000 claims abstract description 33
- 125000000129 anionic group Chemical group 0.000 claims abstract description 28
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 28
- -1 n-decyl diethenoxy sulfate Chemical compound 0.000 claims description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 claims description 17
- 150000002334 glycols Chemical class 0.000 claims description 16
- HCKFFIBKYQSDRD-UHFFFAOYSA-N 4,7-dimethyldec-5-yne-4,7-diol Chemical compound CCCC(C)(O)C#CC(C)(O)CCC HCKFFIBKYQSDRD-UHFFFAOYSA-N 0.000 claims description 13
- FADIFRKKGSXQIQ-UHFFFAOYSA-N 3,6-diethyloct-4-yne-3,6-diol Chemical compound CCC(O)(CC)C#CC(O)(CC)CC FADIFRKKGSXQIQ-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 150000003863 ammonium salts Chemical class 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- CTTGTRXRTUKVEB-UHFFFAOYSA-N 2,3,6,7-tetramethyloct-4-yne-3,6-diol Chemical compound CC(C)C(C)(O)C#CC(C)(O)C(C)C CTTGTRXRTUKVEB-UHFFFAOYSA-N 0.000 claims description 10
- SITNYJAYXKCBFH-UHFFFAOYSA-N 2,5-dicyclopropylhex-3-yne-2,5-diol Chemical compound C1CC1C(O)(C)C#CC(C)(O)C1CC1 SITNYJAYXKCBFH-UHFFFAOYSA-N 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
- NUYADIDKTLPDGG-UHFFFAOYSA-N 3,6-dimethyloct-4-yne-3,6-diol Chemical compound CCC(C)(O)C#CC(C)(O)CC NUYADIDKTLPDGG-UHFFFAOYSA-N 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 9
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 7
- HJVVXZWQDRNQEH-UHFFFAOYSA-N 2,5-diphenylhex-3-yne-2,5-diol Chemical compound C=1C=CC=CC=1C(O)(C)C#CC(C)(O)C1=CC=CC=C1 HJVVXZWQDRNQEH-UHFFFAOYSA-N 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 5
- JTOPSWUULDLBBW-UHFFFAOYSA-N 5,8-dimethyldodec-6-yne-5,8-diol Chemical compound CCCCC(C)(O)C#CC(C)(O)CCCC JTOPSWUULDLBBW-UHFFFAOYSA-N 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- IHJUECRFYCQBMW-UHFFFAOYSA-N 2,5-dimethylhex-3-yne-2,5-diol Chemical compound CC(C)(O)C#CC(C)(C)O IHJUECRFYCQBMW-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 150000001346 alkyl aryl ethers Chemical class 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 26
- 239000007795 chemical reaction product Substances 0.000 abstract description 13
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 13
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 10
- 239000002736 nonionic surfactant Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 235000019441 ethanol Nutrition 0.000 description 17
- 239000011521 glass Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 11
- 239000003599 detergent Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 239000011591 potassium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- HVXRCAWUNAOCTA-UHFFFAOYSA-N 4-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=C(O)C=C1 HVXRCAWUNAOCTA-UHFFFAOYSA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- HTJKZZRXEYJFHE-UHFFFAOYSA-N undec-5-yne-4,7-diol Chemical compound CCCCC(O)C#CC(O)CCC HTJKZZRXEYJFHE-UHFFFAOYSA-N 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- QUYMBZUAFVXGFK-UHFFFAOYSA-N 4,7-dimethyldec-5-yne-4,7-diol 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(CCC)(C#CC(CCC)(O)C)O.CC(C)CC(C#CC(CC(C)C)(O)C)(O)C QUYMBZUAFVXGFK-UHFFFAOYSA-N 0.000 description 1
- 239000005997 Calcium carbide Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000004479 aerosol dispenser Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 239000000551 dentifrice Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- YGMADCGBQRYLND-UHFFFAOYSA-N oct-4-yne-3,6-diol Chemical compound CCC(O)C#CC(O)CC YGMADCGBQRYLND-UHFFFAOYSA-N 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/164—Organic compounds containing a carbon-carbon triple bond
Definitions
- An anti-fogging surfactant mixture for use in a Window cleaning composition consisting essentially of a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting of methyl, ethyl, cyclopropyl, and phenyl or the reaction product of the above glycol and from 2 to 200 moles of ethylene oxide and an anionic or nonionic surfactant in a weight ratio of 1:50 to 1:1.
- a non-fogging window cleaner containing from 0.1 to 3 percent of the above noted anti-fogging surfactant mixture as well as a method for utilizing the same is provided.
- This invention relates to a non-fogging window cleaning composition. More particularly, this invention relates to a synergistic non-fogging surfactant mixture for use in a window cleaning composition.
- Window or mirror fogging is caused at least in part by the condensation of moisture droplets onto the transparent surface. These individual condensed droplets form a whitish fog which renders the glass or mirror opaque and obstructs vision. It has been known to utilize the various surface active agents to reduce the surface tension and thereby enhance the coalescence of these individual water droplets into a larger, more transparent form. Howver, these prior art compositions, although they possess adequate defogging characteristics, possess a series of other undesirable properties, such as high initial film formation, heavy image distortion, streaking, smearing, and smudging of the surface. Obviously, a preferred window cleaner and antifogging composition would possess superior, or at least quite satisfactory, results in each of the above categories as well as possessing adequate anti-fogging properties.
- the antifogging surfactant mixture for window cleaning compositions and window cleaning compositions of the present invention comprises a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting essentially of methyl, ethyl, cyclopropyl, and phenyl or the reaction product of the above glycol and from 2 to 200 moles of ethylene oxide and an anionic surface active agent in a weight ratio of 1:50 to 1:1.
- the window cleaning composition of the present invention comprises from 0.2 to 3 percent by weight of the above synergistic anti-fogging surfactant mixture, from 80 to 93.7 percent water, from 3 to 8 percent by weight of at least one glycol ether, from 3 to 7 percent by weight of a monohydric alcohol and from 0.1 to 2 percent by weight of a hydroxide selected from sodium, potassium and ammonium hydroxide.
- the primary object of the present invention to provide an anti-fogging window cleaner with improved properties.
- the anti-fogging surfactant mixture of the present invention which is for use with a window cleaning composition consists essentially of a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting essentially of methyl, ethyl, cyclopropyl and phenyl or the reactionproduct of the aboveglycol and from 2 to 200 moles of ethylene oxide and an anionic or nonionic surface active agent, especially an anionic surface active agent having the formula R O(C H O,,)SO M wherein R is an alkyl group having from 8 to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from the group consisting of sodium, potassium and ammonium or a nonionic surface active agent having the formula R O(C H O),,H wherein R and n are defined as above in a weight ratio of 1
- the anti-fogging window cleaning composition of the present invention comprises from 0.2 to 3 percent and preferably from 0.3 to 0.5 percent by weight of the above noted synergistic mixture, from 80 to 93.7 percent water, from 3 to 8 percent by weight glycol ether, from 3 to 7 percent lower monohydric alcohol and from 0.1 to 2 percent of an alkali hydroxide selected from sodium, potassium and ammonium hydroxides.
- the acetylenic glycols which comprise one component of the anti-fogging surfactant mixture of the present invention have the following structural formula wherein R is-an alkyl group, either a branched or a straight chain group containing from one to four carbon atoms, such as methyl, ethyl, propyl, isopropyl, nbutyl, isobutyl or t-butyl and wherein R is aradical selected from the group of methyl, ethyl, cyclopropyl and phenyl.
- Representative compounds of the above noted acetylenic glycols include the following 2,4,7,9-tetramethyl-5-decyne-4,7-diol 4,7-dimethyl-5-decyne-4,7-diol 2,3,6,7-tetrarnethyl-4-octyne-3,6-diol 3,6-diethyl-4-octyne-3,6-diol prepared by a number of well known techniques, such as by reacting calcium carbide, an alkali metal hydroxide and the corresponding ketone to give the desired glycol as disclosed in US. Pat. No.
- acetylenic glycols have been utilized as non-foaming surface active agents for 2,5-dicyclopropyl-3-hexyne-2,5-diol SOEO 3,6-dimethyl-4-octyne-3,6-diol 2OEO 2,5-diphenyl-3-hexyne-2,5-diol 30EO 2,5-dimethyl-3-hexyne-2,5-diol IOEO 5 ,8-dimethyl-6-dodecyne-5,8-diol, etc.
- any of the above noted reaction products between a great variety of uses such as dentifrices, toilet soaps, ethylene oxide and the acetylenic glycols may be utishampoos, laundry detergents, pigment dispersants in water based paints, viscosity reducers, gel inhibitors and freeze-thaw additives, these materials have not been utilized as a component in an anti-fogging composition.
- reaction products of the above noted acetylenic glycols and ethylene oxide may also be utilized in the anti-fogging window cleaning composition of the present invention. More particularly, this reaction product comprises the reaction product of one mole of the acetylenic glycol having the formula wherein R and R1 are defined as above and from 2 to 200 moles of ethylene oxide. Although any amount of ethylene oxide within the above noted range may be utilized for producing the reaction product utilized in the mixture of the present invention, it is preferred to react the acetylenic glycols with from 2 to 20 moles of ethylene oxide.
- Representative ethoxylated acetylenic glycols include the following wherein the amount of ethylene oxide reacted with the acetylenic glycol is indicated as +NEO wherein N is the number of moles reacted:
- glycolic surface active agents and the nonionic and anionic surfactants within the ratio specified since outside the broad weight ratio, i.e. 1:50 to 1:1 glycolic surfactant to added surface active agent, i.e. anionics or nonio'nics, the anti-fogging properties appreciably disappear. And within the preferred ratio i.e. 1:20 to 1:4 glycolic surfactant to added surfactant and especially within the most preferred range i.e. 1:20 to 1:10, the anti-fog properties are maximized with a concomitent decrease. in adverse films, etc.
- the second component of the anti-fogging mixture is an anionic or nonionic surfactant or mixtures thereof.
- a preferred class of anionic surfactants suitable for use in the synergistic mixture of the present invention has the formula RO(C H O),,SO M wherein R is a fatty alkyl having from eight to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from ammonium, potassium and sodium ions.
- R is a fatty alkyl having from eight to 20 carbon atoms
- n is a number from 2 to 200
- M is a cation selected from ammonium, potassium and sodium ions.
- R is a fatty alkyl having from eight to 20 carbon atoms
- n is a number from 2 to 200
- M is a cation selected from ammonium, potassium and sodium ions.
- the most preferred sulfated anionic utilized in the antifogging window cleaner of the present invention is a mixed C normal primary alkyl'triethanoxy sulfate ammonium salt. This most preferred anionic sulfate salt produces the optimum results in combination with the above noted acetylenic glycol.
- the anionic detergents generally have the fatty alkyl group terminally joined to the polyoxyethylene chain which is of necessity terminally joined to the sulfur of the sulfate group. Although a slight degree of a branching of the higher alkyl group may be tolerated, the detergency of the anionic sulfate is improved if the alkyl group is essentially straight chained. Furthermore, me-
- dial joinder of the alkyl to the ethanoxy chain should be minimized although a small percentage up to about 10 percent of medial joinder near one end of the alkyl chain is acceptable.
- the preferred range of the alkyl is from 10 to 18 carbon atoms and within this range, the mixed alkyls having 12 to 15 carbon atoms are most preferred, these mixtures containing approximately between and 50 percent of each chain length.
- the ethylene oxide content of the anionic detergent is such that n is from 2 to 200 and preferably from 2 to 20 with the most preferred ethylene oxide content being about 3, especially when R is a mixed l2 carbon atom alkyl mixture.
- the value of n or the ethylene oxide content is determined by the desired hydrophobic-hydrophylic balance which may be varied markedly by variations in the ethylene oxide content and the length of the alkyl groups.
- the salt forming cation may be any suitable solubilizing metal; however, the alkali metals, i.e. sodium and potassium and ammonium ions are preferred with the ammonium ion being most preferred.
- Examples of the higher alcohol polyethenoxy sulfates which may be used as the anionic sulfate in the antifogging mixture of the present invention include: mixed C1245 normal primary alkyl triethenoxy sulfate, ammonium salt; myristyl triethenoxy sulfate, potassium salt; n-decyl diethenoxy sulfate, sodium salt; lauryl diethenoxy sulfate, ammonium salt, palmityl tetraethenoxy sulfate, sodium salt; mixed C1245 normal primary alkyl mixed triand tetraethenoxy sulfate, sodium salt; stearyl pentaethenoxy sulfate, ammonium salt and mixed C normal primary alkyl triethenoxy sulfate, potassium salt.
- nonionic detergents having the following formula may also be utilized in conjunction with the acetylenic glycols or ethoxylated acetylenic glycols in the surfactant composition of the present invention:
- R and n are as defined above.
- nonionic detergent should be roughly similar to those described with regard to the anionic detergents, i.e. the nonionic detergents could be formed primarily from straight chained fatty alcohols with the alcohol groups being terminally joined to the alkyl radical. Generally, it is preferred to utilize nonionic compounds wherein the alkyl group has from between eight and carbon atoms with the preferred nonionics having from between 1 l to 16 carbon atoms. Furthermore, with regard to moles of ethylene oxides or length of the ethenoxy chain is generally preferred that from 2 to 20 moles of ethylene oxide be utilized. Furthermore, since these materials are generally formed from mixed alkyl alcohols, the carbon atom chain length would generally be an average chain length with a most preferred nonionic being the reaction product of ethylene oxide with an alkyl alcohol having from 11 to 15 carbon atoms.
- alkaryl polyglycol detergents such as alkylphenol-ethylene oxide condensates (2-20O moles ethylene oxide), such as p-isooctyl phenol polyethylene oxide (10 ethylene oxide units); polyglycerol monolaurate, glycol dioleate, sorbitan monolaurate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monooleate, sorbitan sesquioleate, the condensation products of ethylene oxide with sorbitan esters of long chain fatty acids (Tweens), alkylolamides, amine oxides, phosphine oxides, etc.
- alkaryl polyglycol detergents such as alkylphenol-ethylene oxide condensates (2-20O moles ethylene oxide), such as p-isooctyl phenol polyethylene oxide (10 ethylene oxide units); polyglycerol monolaurate, glycol dioleate, sorbitan monolaurate, sorbitan monoste
- the anti-fogging window cleaner of the present in is the anti-fogging window cleaner of the present in
- vention in addition to the acetylenic glycol and anionic sulfates includes from 80 to 93.7 percent by weight of water, from 3 to 8 percent by weight of at least one glycol ether, from 3 to 7 percent by weight of an alcohol, from 0.1 to 2 percent of ammonium, hydroxide or an alkaline metal hydroxide and from 0.1 to 3 percent by weight of the mixture of anionic or nonionic surfactant and acetylenic glycol.
- glycol ethers which are suitable for use in the window cleaning composition of the present invention are employed primarily for their solvent and additional detersive properties and include monoethers of ethylene glycols, such as the monomethyl, the monoethyl, the monopropyl and the monobutyl ethers of ethylene glycol and the monoethers of propylene glycol, such as the monomethyl, the monoethyl, the monopropyl and the monobutyl ethers of propylene glycol.
- the alcohol utilized is generally a lower alkyl monohydric alcohol, such as methyl alcohol, ethyl alcohol, isopropyl alcohol and butyl alcohol. If ethyl alcohol is utilized, generally such material is utilized as denatured ethyl alcohol.
- the hydroxides are utilized in the window cleaning composition so as to control the pH level of the resultant composition and, generally, the hydroxide corresponding to the anionic sulfate salt is utilized.
- the pH of the window cleaning compositions of the present invention' is between 8 and 11 with the preferred pH being 10.
- the window cleaning composition of the present invention may be packaged either for dispensing inan aerosol dispenser or utilizing a mechanical pump type valve dispenser.
- the composition includes up to about 10 percent by weight of a suitable propellant, such as any of the well known fluorochloroethanes and similar materials; and the hydrocarbon propellants, such as isobutane, etc.
- the anti-fogging properties of the above noted composition is evaluated by applying the composition to a pane of glass followed by chilling the glass pane and exposing the same to steam.
- the antifog efficacy is judged by observing whether or not the compositions sudsing is proper upon application, the
- Example 2 0.010% TG Fair anti-fog effect. Moderate Example 3 0.025% TG Good anti-fog effect. Good sight.
- Example 4 0.0l0% 2.4,7.9-tetramethvl-5-decvne-4,7-diol 0.250% AAS 7 Good anti-fog effect. Good sight.
- Example 2 'Cl2-l5 alcohol (3E0) Ammonium Sulfate. Same as in Example I fogging when exposed to steam, the clarity of sight through the glass following steaming, the absence of COMPARATIVE EXAMPLES 1 s and EXAMPLES 24 Three commercially available window cleaners plus the window cleaning composition of Example 1 wherein the surfactants are replaced with the surfactants, as shown in Table I with a corresponding reduction or increase in the amount of water present, are applied to a glass surface. These glass surfaces are then Each of the above noted window cleaning compositions performs adequately in the cleaning test, i.e.
- Example I COMPARATIVE EXAMPLES 9-16 and Examples 5-10
- the formulation of Example I is varied utilizing the 45 following surfactants in place of the TG and anionic sulfate with a concomitant change in the water content of the formulation.
- Part l- Liguid Base The above noted formulation is packaged utilizing an aerosol container wherein 98.2 parts by weight of the above noted liquid base is mixed with 1.8 parts by weight of isobutane propellant;
- a window cleaner composition identical to the liquid base for use in the aerosol container is also packaged in a mechanical spray dispenser and the cleaning and anti-fogging effects of each are compared on panes of glass.
- Each of the above noted window cleaning compositions performs adequately with regard to the removal of the mixed kitchen fats which have been previ- ⁇ ously streaked upon the glass panes; and, further, when these glass panes are subjected to steam, the anti fogging properties are rated as good with virtually no image distortion, initial film fonnation, streaking or smearing.
- Example 12 The formulation of Example 1 is utilized except that the surfactant TG mixture is replaced with a similar EXAMPLE 13 The formulation of Example 1 is again utilized with. the exception that the anionic sulfate is replaced with an equivalent amount of the following anionic sulfates:
- G stearyl pentaethenoxy sulfate, ammonium salt
- each of the above noted formulations has satisfactoryanti-fogging properties; however,-the anti-fogging properties of D and G are slightly better than the an- .ionic sulfates utilizing potassium and sodium cations. This appears to be caused by the lower residue of the ammonium sulfates as compared to the sodium and potassium salts.
- Example 14 The formulation of Example 1 is utilized with the exception that the anionic sulfate and the acetylenic glycol are replaced with the following mixtures of acetylenic glycols and anionic sulfates (The glycols are taken from Example 12 and the anionic sulfates are taken from Example 13) with a corresponding increase or decrease in the amount of water present, all other compo nents remaining stable.
- Example 15 The composition of Example 1 is utilized except for that the surfactant TG mixture is replaced with a similar amount of the following ethoxylated acetylenic glycols;
- Example 6 The formulation of Example'l is again utilized except that the anionic sulfate is replaced with an equivalent amount of the following nonionic surfactants:
- An anti-fogging mixture for use in a window cleaning composition consisting essentially of a mixture of a glycolic surface active agent selected from acetylenic glycols having the formula M l n F R-o-o o-p-R OH OH I where R is an alkyl group havingfrom one to four car bon atoms and R, is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl, or the reaction product of an acetylenic glycol having the formula dium, and potassium and nonionic surface agent having the formula R O(C H.,O),,H wherein R and n are as defined in a weight ratio of glycolic to anionic or nonionic surface active agent from 1:50 to 1:1.
- a glycolic surface active agent selected from acetylenic glycols having the formula M l n F R-o-o o-p-R OH OH I where R is an alkyl group havingfrom one to
- composition of claim 1 wherein said anionic surface active agent is selected from the group consisting of mixed C1245 normal primary alkyl triethenoxy sulfate, ammonium salt; myristyl triethenoxy sulfate, potassium salt, n-decyl diethenoxy sulfate, sodim salt; lauryl diethenoxy sulfate, ammonium salt, palmityl tetraethenoxy sulfate, sodium salt; mixed C1245 normal primary alkyl mixed triand tetraethenoxy sulfate, sodium salt, stearyl pentaethenoxy sulfate, ammonium salt and mixed C normal primary alkyl triethenoxy sulfate, potassium salt.
- glycolic surface active agent is selected from the group consisting of 2,4,7,9-tetramethyl-5-decyne-4,7-diol 4,7-dimethyl-5-decyne-4,7-diol 2,3,6,7-tetramethyl-4-octyne-3,6-diol 3,6diethyl-4-octyne-3,6-diol 2,5-dicyclopropyl-3-hexyne-2,5-diol 3,6-dimethyl-4-octyne-3,6-diol 2,5-diphenyl-3hexyne-2,5-diol 2,5-dimethyl-3-hexyne-2,5-diol 5,8-dimethyl-6-dodecyne-5,8-diol 2,4,7,9-tetramethyl-5-decyne-4,7-diol '3.5EO
- glycolic surface active agent is an acetylenic glycol having the formula wherein R is an alkyl group having from one to four carbon atoms, and R, is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl.
- composition of claim 4 wherein said glycolic, surface active agent is 2,4,7,9-tetramethyl-5-decyne- 4,7-diol.
- composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:4.
- composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:10.
- a window cleaning composition comprising from 80 to 93.7 percent water, from 3 to 8 percent by weight of at least one glycol ether selected from the group consisting of monoalkyl ethers of ethylene glycol and propylene glycol from 3 to 7 percent by weight of a lower monohydric alcohol, from 0.1 to 2 percent by weight of an alkali or ammonium hydroxide and from 0.1 to 3 percent by weight of an anti-fogging mixture consisting essentially of a mixture of a glycolic surface active agelnt selected from acetylenic glycols having the formu a wherein R is an alkyl group having from one to four carbon atoms, and R is a radical selected from the 14 group consisting of methyl, ethyl, cyclopropyl and phenyl, or the reaction product of an acetylenic glycol having the formula wherein R is an alkyl group having from on e to four carbon atoms and R is a radical selected from the group consisting of methyl, eth
- a surface active agent selected from anionic surface active agents having the formula R O(C H O),,SO M wherein R is an alkyl group having from 8 to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from the group consisting of ammonium, sodium and potassium and nonionic surface active agent having the formula R O(C H O),,H wherein R and n are as defined in a weight ratio of glycolic to anionic or nonionic surface active agent of from 1:50 to 1:1.
- glycol ether is a mixture of ethylene glycol monobutyl ether and propylene glycol monomethyl ether.
- composition of claim 12 wherein said lower monohydric alcohol is isopropanol.
- composition of claim 12 having a pH between 8 and ll.
- composition of claim 12 arein M is an ammonium ion.
- composition of claim 12 wherein said glycolic surface active agent is an acetylenic glycol having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl.
- glycolic surface active agent is 2,4,7,9-tetramethyl-5- decyne-4,7-diol.
- composition of claim 12 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:10.
Abstract
WHEREIN R is an alkyl group having from one to four carbon atoms and R1 is a radical selected from the group consisting of methyl, ethyl, cyclopropyl, and phenyl or the reaction product of the above glycol and from 2 to 200 moles of ethylene oxide and an anionic or nonionic surfactant in a weight ratio of 1:50 to 1:1. A non-fogging window cleaner containing from 0.1 to 3 percent of the above noted anti-fogging surfactant mixture as well as a method for utilizing the same is provided.
An anti-fogging surfactant mixture for use in a window cleaning composition consisting essentially of a mixture of a nonionic surface active agent having the formula
An anti-fogging surfactant mixture for use in a window cleaning composition consisting essentially of a mixture of a nonionic surface active agent having the formula
Description
United States Patent [191' Zmoda et a1. t
[ June 25, 1974 ANTI-FOGGING WINDOW CLEANER SURFACTANT MIXTURE [75] Inventors: Barney J. Zmoda, Bridgewater;
Raymond S. Brown, lselin, both of NJ.
[73] Assignee: Colgate-Palmolive Company, New
York, NY.
22 Filed: Sept. 25, 1972 21 Appl. No.: 291,681
Primary ExaminerWilliam E. Schultz Attorney, Agent, or Firm-Herbert S. Sylvester; Murray M. Grill; Norman Blumenkopf [57] ABSTRACT An anti-fogging surfactant mixture for use in a Window cleaning composition consisting essentially of a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting of methyl, ethyl, cyclopropyl, and phenyl or the reaction product of the above glycol and from 2 to 200 moles of ethylene oxide and an anionic or nonionic surfactant in a weight ratio of 1:50 to 1:1. A non-fogging window cleaner containing from 0.1 to 3 percent of the above noted anti-fogging surfactant mixture as well as a method for utilizing the same is provided.
20 Claims, N0 Drawings ANTI-FOGGING WINDOW CLEANER SURFACTANT MIXTURE This invention relates to a non-fogging window cleaning composition. More particularly, this invention relates to a synergistic non-fogging surfactant mixture for use in a window cleaning composition.
The formation of fog on glass surfaces with its resultant loss of visibility is a problem which has troubled home owners, drivers, pilots or virtually anyone who depends upon clear visibility through a window or similar glass article. The attention which has been paid to this problem is evidenced by the remarkable number of glass cleaning compositions which are on the market claiming anti-fogging or defogging characteristics.
Window or mirror fogging is caused at least in part by the condensation of moisture droplets onto the transparent surface. These individual condensed droplets form a whitish fog which renders the glass or mirror opaque and obstructs vision. It has been known to utilize the various surface active agents to reduce the surface tension and thereby enhance the coalescence of these individual water droplets into a larger, more transparent form. Howver, these prior art compositions, although they possess adequate defogging characteristics, possess a series of other undesirable properties, such as high initial film formation, heavy image distortion, streaking, smearing, and smudging of the surface. Obviously, a preferred window cleaner and antifogging composition would possess superior, or at least quite satisfactory, results in each of the above categories as well as possessing adequate anti-fogging properties.
It is within the above embodiment that the antifogging surfactant mixture for window cleaning compositions and window cleaning compositions of the present invention were developed. Briefly, such mixture comprises a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting essentially of methyl, ethyl, cyclopropyl, and phenyl or the reaction product of the above glycol and from 2 to 200 moles of ethylene oxide and an anionic surface active agent in a weight ratio of 1:50 to 1:1. The window cleaning composition of the present invention comprises from 0.2 to 3 percent by weight of the above synergistic anti-fogging surfactant mixture, from 80 to 93.7 percent water, from 3 to 8 percent by weight of at least one glycol ether, from 3 to 7 percent by weight of a monohydric alcohol and from 0.1 to 2 percent by weight of a hydroxide selected from sodium, potassium and ammonium hydroxide.
It is, therefore, the primary object of the present invention to provide an anti-fogging window cleaner with improved properties.
It is a further object of the present invention to provide a synergistic anti-fogging surfactant mixture which is effective when used in a small amount in a window cleaning composition.
It is a still further object of the present invention to provide an anti-fogging window cleaning composition which minimizes film formation, sight distortion, smearing, smudging, and streaking.
It is a still further object of the present invention to provide a synergistic anti-fogging surfactant mixture comprising a mixture of a nonionic acetylenic glycol and an anionic sulfate.
Still further objects and advantages of the mixture and window cleaning composition of the present invention will become more apparent from the following, more detailed description thereof.
The foregoing objects and advantages of the present invention are achieved through the anti-fogging surfactant mixture of the present invention which is for use with a window cleaning composition consists essentially of a mixture of a nonionic surface active agent having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting essentially of methyl, ethyl, cyclopropyl and phenyl or the reactionproduct of the aboveglycol and from 2 to 200 moles of ethylene oxide and an anionic or nonionic surface active agent, especially an anionic surface active agent having the formula R O(C H O,,)SO M wherein R is an alkyl group having from 8 to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from the group consisting of sodium, potassium and ammonium or a nonionic surface active agent having the formula R O(C H O),,H wherein R and n are defined as above in a weight ratio of 1:50 to 1:1, preferably 1:20 to 1:4 and most preferably 1:20 to 1:10.
The anti-fogging window cleaning composition of the present invention comprises from 0.2 to 3 percent and preferably from 0.3 to 0.5 percent by weight of the above noted synergistic mixture, from 80 to 93.7 percent water, from 3 to 8 percent by weight glycol ether, from 3 to 7 percent lower monohydric alcohol and from 0.1 to 2 percent of an alkali hydroxide selected from sodium, potassium and ammonium hydroxides.
The acetylenic glycols which comprise one component of the anti-fogging surfactant mixture of the present invention have the following structural formula wherein R is-an alkyl group, either a branched or a straight chain group containing from one to four carbon atoms, such as methyl, ethyl, propyl, isopropyl, nbutyl, isobutyl or t-butyl and wherein R is aradical selected from the group of methyl, ethyl, cyclopropyl and phenyl. Representative compounds of the above noted acetylenic glycols include the following 2,4,7,9-tetramethyl-5-decyne-4,7-diol 4,7-dimethyl-5-decyne-4,7-diol 2,3,6,7-tetrarnethyl-4-octyne-3,6-diol 3,6-diethyl-4-octyne-3,6-diol prepared by a number of well known techniques, such as by reacting calcium carbide, an alkali metal hydroxide and the corresponding ketone to give the desired glycol as disclosed in US. Pat. No. 2,250,445, or by reacting the ketones with an alkali metal acetylide as disclosed in US. Pat. No. 2,106,180, or, lastly, by reacting acetylene with an excess of the ketone in the presence of a solid caustic potash in a solvent medium.
Although the above noted acetylenic glycols have been utilized as non-foaming surface active agents for 2,5-dicyclopropyl-3-hexyne-2,5-diol SOEO 3,6-dimethyl-4-octyne-3,6-diol 2OEO 2,5-diphenyl-3-hexyne-2,5-diol 30EO 2,5-dimethyl-3-hexyne-2,5-diol IOEO 5 ,8-dimethyl-6-dodecyne-5,8-diol, etc. 5E0 2,4,7,9-tetramethyl-5-decyne-4,7-diol 2OEO 4,7-dimethyl-5-decyne-4,7-diol 8E0 2,3,6,7-tetramethyl-4'octyne-3,6-diol l2EO 3,6-diethyl-4-octyne-3,6-diol 15EO 2,5-dicyclopropyl-3-hexyne-2,5-diol IOEO 3,6-dimethyl-4-octyne-3,6-diol SOEO 2,4,7,9-tetramethyl-5-decyne-4,7-diol 30EO 4,7-dimethyl-5-decyne-4,7-diol 10EO 2,3,6,7-tetramethyl-4-octyne-3,6-di0l 5E0 3,6-diethyl-4-octyne-3,6-diol 2E0 2,5-diphenyl-3-hexyne-2,5-diol 5E0 2,5-dimethyl-3-hexyne-2,S-diol 20150 5,8-dimethyl-6-dodecyne-5,8-diol lOEO, etc. Any of the above noted reaction products between a great variety of uses, such as dentifrices, toilet soaps, ethylene oxide and the acetylenic glycols may be utishampoos, laundry detergents, pigment dispersants in water based paints, viscosity reducers, gel inhibitors and freeze-thaw additives, these materials have not been utilized as a component in an anti-fogging composition. This is, of course, due to the fact that the acetylenic glycols themselves without the anionic sulfate do not possess any significant anti-fogging properties and any anti-fogging activity is accompanied by heavy image distortion, streaking, smearing or initial film formation. Accordingly, these materials had been thought to be completely unsuited for utilization in a window cleaning composition in any percentage and, especially unsuited for use in an anti-fogging window cleaning composition.
The reaction products of the above noted acetylenic glycols and ethylene oxide may also be utilized in the anti-fogging window cleaning composition of the present invention. More particularly, this reaction product comprises the reaction product of one mole of the acetylenic glycol having the formula wherein R and R1 are defined as above and from 2 to 200 moles of ethylene oxide. Although any amount of ethylene oxide within the above noted range may be utilized for producing the reaction product utilized in the mixture of the present invention, it is preferred to react the acetylenic glycols with from 2 to 20 moles of ethylene oxide. Representative ethoxylated acetylenic glycols include the following wherein the amount of ethylene oxide reacted with the acetylenic glycol is indicated as +NEO wherein N is the number of moles reacted:
2,4,7,9-tetramethyl-S-decyne-4,7-diol 3.5EO 4,7-dimethyl-5-decyne-4,7-diol 20OEO 2,3,6,7-tetramethyl-4-octyne-3,6-diol lOEO 3,6-diethyl-4-octyne-3,6-di0l 9E0 2,5-dicyclopropyl-3-hexyne-2,5-diol 20150 3,6-dimethyl-4-octyne-3,6-diol 30EO 2,4,7,9-tetramethyl-5-decyne-4,7-diol 15EO 4,7-dimethyl-5-decyne-4,7-diol 20EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol 2E0 3,6-diethyl-4-octyne-3,6-diol IOOEO lized, although it is preferred to utilize the reaction products of ethylene oxide and 2,4,7,9-tetramethyl-5- decyne-4,7-diol.
It is important to utilize the glycolic surface active agents and the nonionic and anionic surfactants within the ratio specified since outside the broad weight ratio, i.e. 1:50 to 1:1 glycolic surfactant to added surface active agent, i.e. anionics or nonio'nics, the anti-fogging properties appreciably disappear. And within the preferred ratio i.e. 1:20 to 1:4 glycolic surfactant to added surfactant and especially within the most preferred range i.e. 1:20 to 1:10, the anti-fog properties are maximized with a concomitent decrease. in adverse films, etc.
The second component of the anti-fogging mixture is an anionic or nonionic surfactant or mixtures thereof.
A preferred class of anionic surfactants suitable for use in the synergistic mixture of the present invention has the formula RO(C H O),,SO M wherein R is a fatty alkyl having from eight to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from ammonium, potassium and sodium ions. Although any of the higher fatty acid ethoxylated sulfates may be utilized, it is preferred to utilize a sulfate wherein R is a fatty alkyl from between 10 and 18 carbon atoms, n is a number between two and 20 and M is ammonium. The most preferred sulfated anionic utilized in the antifogging window cleaner of the present invention is a mixed C normal primary alkyl'triethanoxy sulfate ammonium salt. This most preferred anionic sulfate salt produces the optimum results in combination with the above noted acetylenic glycol.
' The anionic detergents generally have the fatty alkyl group terminally joined to the polyoxyethylene chain which is of necessity terminally joined to the sulfur of the sulfate group. Although a slight degree of a branching of the higher alkyl group may be tolerated, the detergency of the anionic sulfate is improved if the alkyl group is essentially straight chained. Furthermore, me-
dial joinder of the alkyl to the ethanoxy chain should be minimized although a small percentage up to about 10 percent of medial joinder near one end of the alkyl chain is acceptable. As noted above, the preferred range of the alkyl is from 10 to 18 carbon atoms and within this range, the mixed alkyls having 12 to 15 carbon atoms are most preferred, these mixtures containing approximately between and 50 percent of each chain length.
The ethylene oxide content of the anionic detergent is such that n is from 2 to 200 and preferably from 2 to 20 with the most preferred ethylene oxide content being about 3, especially when R is a mixed l2 carbon atom alkyl mixture. The value of n or the ethylene oxide content is determined by the desired hydrophobic-hydrophylic balance which may be varied markedly by variations in the ethylene oxide content and the length of the alkyl groups.
The salt forming cation may be any suitable solubilizing metal; however, the alkali metals, i.e. sodium and potassium and ammonium ions are preferred with the ammonium ion being most preferred.
Examples of the higher alcohol polyethenoxy sulfates which may be used as the anionic sulfate in the antifogging mixture of the present invention include: mixed C1245 normal primary alkyl triethenoxy sulfate, ammonium salt; myristyl triethenoxy sulfate, potassium salt; n-decyl diethenoxy sulfate, sodium salt; lauryl diethenoxy sulfate, ammonium salt, palmityl tetraethenoxy sulfate, sodium salt; mixed C1245 normal primary alkyl mixed triand tetraethenoxy sulfate, sodium salt; stearyl pentaethenoxy sulfate, ammonium salt and mixed C normal primary alkyl triethenoxy sulfate, potassium salt.
In addition to the above noted anionic detergents, nonionic detergents having the following formula may also be utilized in conjunction with the acetylenic glycols or ethoxylated acetylenic glycols in the surfactant composition of the present invention:
wherein R and n are as defined above.
The configuration of the nonionic detergent should be roughly similar to those described with regard to the anionic detergents, i.e. the nonionic detergents could be formed primarily from straight chained fatty alcohols with the alcohol groups being terminally joined to the alkyl radical. Generally, it is preferred to utilize nonionic compounds wherein the alkyl group has from between eight and carbon atoms with the preferred nonionics having from between 1 l to 16 carbon atoms. Furthermore, with regard to moles of ethylene oxides or length of the ethenoxy chain is generally preferred that from 2 to 20 moles of ethylene oxide be utilized. Furthermore, since these materials are generally formed from mixed alkyl alcohols, the carbon atom chain length would generally be an average chain length with a most preferred nonionic being the reaction product of ethylene oxide with an alkyl alcohol having from 11 to 15 carbon atoms.
Examples of other suitable non-ionic detergents include alkaryl polyglycol detergents such as alkylphenol-ethylene oxide condensates (2-20O moles ethylene oxide), such as p-isooctyl phenol polyethylene oxide (10 ethylene oxide units); polyglycerol monolaurate, glycol dioleate, sorbitan monolaurate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monooleate, sorbitan sesquioleate, the condensation products of ethylene oxide with sorbitan esters of long chain fatty acids (Tweens), alkylolamides, amine oxides, phosphine oxides, etc.
The anti-fogging window cleaner of the present in;
vention in addition to the acetylenic glycol and anionic sulfates includes from 80 to 93.7 percent by weight of water, from 3 to 8 percent by weight of at least one glycol ether, from 3 to 7 percent by weight of an alcohol, from 0.1 to 2 percent of ammonium, hydroxide or an alkaline metal hydroxide and from 0.1 to 3 percent by weight of the mixture of anionic or nonionic surfactant and acetylenic glycol.
The glycol ethers which are suitable for use in the window cleaning composition of the present invention are employed primarily for their solvent and additional detersive properties and include monoethers of ethylene glycols, such as the monomethyl, the monoethyl, the monopropyl and the monobutyl ethers of ethylene glycol and the monoethers of propylene glycol, such as the monomethyl, the monoethyl, the monopropyl and the monobutyl ethers of propylene glycol.
The alcohol utilized is generally a lower alkyl monohydric alcohol, such as methyl alcohol, ethyl alcohol, isopropyl alcohol and butyl alcohol. If ethyl alcohol is utilized, generally such material is utilized as denatured ethyl alcohol.
The hydroxides are utilized in the window cleaning composition so as to control the pH level of the resultant composition and, generally, the hydroxide corresponding to the anionic sulfate salt is utilized. Generally, the pH of the window cleaning compositions of the present invention'is between 8 and 11 with the preferred pH being 10.
In addition to the above noted ingredients, small amounts of color, perfume and other agents, such as propellants for aerosol dispensing, may be included.
The window cleaning composition of the present invention may be packaged either for dispensing inan aerosol dispenser or utilizing a mechanical pump type valve dispenser. When an aerosol dipensing package is utilized, generally, the composition includes up to about 10 percent by weight of a suitable propellant, such as any of the well known fluorochloroethanes and similar materials; and the hydrocarbon propellants, such as isobutane, etc.
The mixture and window cleaning composition of the present invention will now be further illustrated by way of the following examples wherein all parts and percentages are by weight and all temperatures are in degrees centigrade.
EXAMPLE 1 A window cleaner having the following composition is prepared:
9l.0l5% Water, demineralized 2.000 Ethylene glycol monobutyl ether 2.500 Propylene glycol monomethyl ether 3.800 lsopropyl alcohol 0.350 Cl2-l5 alcohol (3 E0) ammonium sulfate 0.035 TG(A commercially available mixture containing 83% 2,4,7,9-tetramethyl- 5-decyne-4,7-diol, ethylene glycol and an alkyl phenyl-ethylene oxide adduct 0.300 26 Be Ammonium Hydroxide The cleaning performance of the above the above noted composition is detemlined by the ability of this composition to flush off from a pane of glass a film of mixed kitchen fats. The anti-fogging properties of the above noted composition is evaluated by applying the composition to a pane of glass followed by chilling the glass pane and exposing the same to steam. The antifog efficacy is judged by observing whether or not the compositions sudsing is proper upon application, the
absence of filming on application, the prevention of TABLE I Example No. Cleaner Characteristics Comp. Ex. 1 Com. Product W Glass fogged on first exposure to steam.
Comp. Ex. 2 Corn. Product EO Poor anti-fog first exposure,
very poor on second.
Comp. Ex. 3 Com. Product A Glass fogged on first exposure.
Comp. Ex. 4 0.6% AAS Fair anti-fog effect, distorted sight.
Comp. Ex. 5 l.0% AAS Excessive sudsing. Good anti-fog.
Moderate sight distortion.
Comp. Ex. 6 1.2% AAS Excessive sudsing. Good anti-fog.
Good sight. Moderate filming, smearing.
Comp. Ex. 7 L47: AAS Excessive sudsing. Good anti fog.
Good sight. Heavy filming, smearing.
CQWPcEJQli. 9.05% 9 N0 g effect.
Example 2 0.010% TG Fair anti-fog effect. Moderate Example 3 0.025% TG Good anti-fog effect. Good sight.
0.250% AAS No filming, no smearing. Example 4 0.0l0% 2.4,7.9-tetramethvl-5-decvne-4,7-diol 0.250% AAS 7 Good anti-fog effect. Good sight.
No filming, no smearing.
'Cl2-l5 alcohol (3E0) Ammonium Sulfate. Same as in Example I fogging when exposed to steam, the clarity of sight through the glass following steaming, the absence of COMPARATIVE EXAMPLES 1 s and EXAMPLES 24 Three commercially available window cleaners plus the window cleaning composition of Example 1 wherein the surfactants are replaced with the surfactants, as shown in Table I with a corresponding reduction or increase in the amount of water present, are applied to a glass surface. These glass surfaces are then Each of the above noted window cleaning compositions performs adequately in the cleaning test, i.e. the ability to flush off a film of mixed kitchen fats; however, as shown in Table I, only those window cleaners of Examples 2-4 which contain the novel synergistic mixture of the present invention provide adequate antifog characteristics with minimal distortion, filming and 5 smearing. The anionic sulfate surfactant used by itself produces fair to good anti-fog effect; however, the distortion, smearing, filming and sudsing characteristics are not acceptable. The acetylenic diol when used by itself produces absolutely no anti-fogging effect what- 40 soever.
COMPARATIVE EXAMPLES 9-16 and Examples 5-10 The formulation of Example I is varied utilizing the 45 following surfactants in place of the TG and anionic sulfate with a concomitant change in the water content of the formulation.
TAELE if 7 Total Window cleaner of Evalua- Glycol/ surfac- Ratio Example product Ex. 1 tion Initial Image dis- AAS, tent, glycol: number c0ntaining surface film Anti-fog tortion Streaking smearing percent percent AAS Comp. Ex. 9 0.200% TG No. AAS Glass 1 Moderate.. Poor Heavy- Slight None... 0. 2/0.0 0. 200 2:
pane Comp. Ex. 10. 0.200% 2,4,7,9-tetra- .do Very None- Complete- None -do 0. 2/0. 0 0. 200 2:0
giietihyl-ii-decyne'iflslight o Comp. Ex. 11 0.200% 3,6-dimethyl- ...do d0 ..do ..do do .do 0. 2/0.0 0. 200 2:0
4-octyne-3,6-diol. Example 5 0.100% 2,4,7,9-tetra- .d0 M0derate.. Fair- Moderate... .do Slight..." 0.1/0. 1 0. 200 1:1
methyl-5-decyne-4J- diol, 0.100% AAS. Example 6 0.050% 2,4,7,9tetra- ...d0 Slight..." Good. Slight .d0 None. 0. 050/0. 210 0. 260 1:4. 2
methy1-5-decyne-4,7- diol, 0.210% AAS. Example 7 0.025% 2,4,7,9-tetra- .d0 None. Fair- Moderate.-...do ..do 0 025/0. 221 0. 246 1:8. 8
methyl-5-decyne-4,7- diol, 0.221% AAS. Example 8 0.010% 2,4,7,9-tetra .do .do Good. None .do .do 0. 010/0. 254 0. 264 1:25. 4
methyl-5-decyne-4,7- diol, 0.254% AAS. Example 9 0.015% 2,4,7,9-tetra- .do Very .do do do Slight. 0. 015/0. 350 0. 365 1:23. 3
methyl-5-decyne-4,7- slight.
01, 0.350% AAS. Example 10. 0.012% 2,4,7,9tetm- Mirror do d0 d0 d0 None 0. 012/0. 300 0. 312 1: 25
methyl-5-decyne-4,7-
diol. 0.300% AAS.
' TABLE ii continued Total Window cleaner o1 Evalua- Glycol/ surlac Ratio Example product Ex. 1 tlon Initial Image dis- AAS, tant, glycol: number contalnlngsurface film Anti-fog tortion Streaking smearing percent percent AAS Compflfii T2... 0.600% AAS only. do Modratcfl Poor-Iairl ll Iilideraw- S1ight..... Moderate KEY/0.00 OLW' '6'500 eavy. Comp. Ex. 13. 0.100% AAS only ..do None..- None Complete- None. None. 0. /0. 0. 100 0:10 Comp. Ex. 14... 1.200% AAS only do Heavy Good. None Heavy... Severe. 0.00:1.20 1.200 0:120
Competitive products Comp. Ex. 15... Commercial product 13.... Glass 1 Slight ..do Slight ..do ..do
pane Comp. Ex. 16." Commerclal product 0 ..do Mgderate- Fair Heavy.-. Moderate... .do
eavy.
1 Same as in Examlglc 1. 1 012- alcohol (3 0) ammonium sulfate.
As is apparent with reference to Table 11 only by the use of the acetylenic glycol and the anionic sulfate are the results regarding film formation, anti-fog, image distortion, streaking and smearing acceptable. When either the acetylenic glycol or the anionic sulfate is utilized singly poor anti-fogging characteristics are ob served or if acceptable anti-fogging characteristics are obtained, other undesirable properties, such as heavy initial film, streaking or smearing, are encountered. Regarding the commercial products B and C which are included for their comparative value, it is noted that they anti-fogging characteristics of these materials are judged fair to good and that these materials are inferior regarding initial film formation, image distortion, streaking and smearing when compared to the products of the present invention.
EXAMPLE 1 1 A window cleaner, having the following formulation,
is prepared:
Part l- Liguid Base The above noted formulation is packaged utilizing an aerosol container wherein 98.2 parts by weight of the above noted liquid base is mixed with 1.8 parts by weight of isobutane propellant;
A window cleaner composition identical to the liquid base for use in the aerosol container is also packaged in a mechanical spray dispenser and the cleaning and anti-fogging effects of each are compared on panes of glass. Each of the above noted window cleaning compositions performs adequately with regard to the removal of the mixed kitchen fats which have been previ-{ ously streaked upon the glass panes; and, further, when these glass panes are subjected to steam, the anti fogging properties are rated as good with virtually no image distortion, initial film fonnation, streaking or smearing.
ExAMPLE 12 The formulation of Example 1 is utilized except that the surfactant TG mixture is replaced with a similar EXAMPLE 13 The formulation of Example 1 is again utilized with. the exception that the anionic sulfate is replaced with an equivalent amount of the following anionic sulfates:
A. mixed C1245 normal primary alkyl triethenoxy sulfate, sodium salt;
B. myristyl triethenoxy sulfate, potassium salt;
C. n-decyl diethenoxy sulfate, sodium salt;
D. lauryl diethenoxy sulfate, ammonium salt;
E. palmityl tetraethenoxy sulfate, sodium salt;
F. mixed C normal primary alkyl mixed triand tetraethenoxy sulfate, sodium salt;
G. stearyl pentaethenoxy sulfate, ammonium salt;
and
H. mixed C1048 normal primary alkyl triethenoxy sulfate, potassium salt.
Each of the above noted formulations has satisfactoryanti-fogging properties; however,-the anti-fogging properties of D and G are slightly better than the an- .ionic sulfates utilizing potassium and sodium cations. This appears to be caused by the lower residue of the ammonium sulfates as compared to the sodium and potassium salts.
EXAMPLE 14 The formulation of Example 1 is utilized with the exception that the anionic sulfate and the acetylenic glycol are replaced with the following mixtures of acetylenic glycols and anionic sulfates (The glycols are taken from Example 12 and the anionic sulfates are taken from Example 13) with a corresponding increase or decrease in the amount of water present, all other compo nents remaining stable.
A. 0.01 Ex. 12(A), 0.19 Ex. 13 (D);
B. 0.06 Ex. 12(C), 2.94 Ex. 13(A);
0.75 Ex. 12(B), 2,25 Ex. 13(0); 0.05 Ex. 12(D), 0.15 Ex. 13(B); 0.02 Ex. 12(F), 0.48 Ex. 13(C);
F. 0.03 Ex. 12(H), 0.97 Ex. 13(H); and
G. 0.10 Ex. 12(E), 1.00 Ex. 13(E).
Each of the above noted formulations has satisfactory anti-fogging properties and performs adequately as regards to cleansing ability.
EXAMPLE 15 The composition of Example 1 is utilized except for that the surfactant TG mixture is replaced with a similar amount of the following ethoxylated acetylenic glycols;
A. 2,4,7,9-tetramethyl-5-decyne-4,7-diol 3.5EO
B. 4,7-dimethyl-5-decyne-4,7-diol 30EO C. 2,3,6,7-tetramethyl-4-octyne-3,6-diol 200EO D. 3,6-diethyl-4-octyne-3,6-diol 10 E E. 2,5-dicyclopropyl-3-hexyne-2,5-diol 20EO F. 3,6-dimethyl-4-octyne-3,6-diol 5E0 G. 2,5-diphenyl-3-hexyne-2,5-diol 15EO H. 2,S-dimethyl-3-hexyne-2,5-diol 2E0 l. 5,8; -dimethyl-6-dodecyne-5,8-diol 7E0 Each of the above noted formulations performs adequately with regard to both cleaning and anti-fogging properties.
C. D. E.
EXAMPLE [6 The formulation of Example'l is again utilized except that the anionic sulfate is replaced with an equivalent amount of the following nonionic surfactants:
A. p-isooctyl phenol polyethylene oxide 10 ethylene oxide units);
B. dodecyl alcohol-polyethylene oxides (6 ethylene oxide units) C. mixed C l 2- l 5 alcohol polyethylene oxide l0 ethylene oxides);
D. sorbitan monolaurate;
E. mixed l l-] 5 alcohol polyethylene oxide having 1 1 ethylene oxide units.
Each of the above noted compositions performs adequately with regard both to cleaning properties and anti-fogging, streaking, and smearing properties. However, when a composition similar to the above noted composition with the exception of the deletion of the acetylenic glycol component is utilized, the antifogging properties are markedly reduced. While the window cleaning composition and antifogging mixture of the present invention and process for utilizing the same have been described with reference to the foregoing specific examples, the same are for the purposes of illustration only and are to be in no way as construed as limiting the present invention which is properly defined by way of the following appended claims.
What is claimed is: 1
1. An anti-fogging mixture for use in a window cleaning composition consisting essentially of a mixture of a glycolic surface active agent selected from acetylenic glycols having the formula M l n F R-o-o o-p-R OH OH I where R is an alkyl group havingfrom one to four car bon atoms and R, is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl, or the reaction product of an acetylenic glycol having the formula dium, and potassium and nonionic surface agent having the formula R O(C H.,O),,H wherein R and n are as defined in a weight ratio of glycolic to anionic or nonionic surface active agent from 1:50 to 1:1.
2. The composition of claim 1 wherein said anionic surface active agent is selected from the group consisting of mixed C1245 normal primary alkyl triethenoxy sulfate, ammonium salt; myristyl triethenoxy sulfate, potassium salt, n-decyl diethenoxy sulfate, sodim salt; lauryl diethenoxy sulfate, ammonium salt, palmityl tetraethenoxy sulfate, sodium salt; mixed C1245 normal primary alkyl mixed triand tetraethenoxy sulfate, sodium salt, stearyl pentaethenoxy sulfate, ammonium salt and mixed C normal primary alkyl triethenoxy sulfate, potassium salt.
3. The composition of claim 1 wherein said glycolic surface active agent is selected from the group consisting of 2,4,7,9-tetramethyl-5-decyne-4,7-diol 4,7-dimethyl-5-decyne-4,7-diol 2,3,6,7-tetramethyl-4-octyne-3,6-diol 3,6diethyl-4-octyne-3,6-diol 2,5-dicyclopropyl-3-hexyne-2,5-diol 3,6-dimethyl-4-octyne-3,6-diol 2,5-diphenyl-3hexyne-2,5-diol 2,5-dimethyl-3-hexyne-2,5-diol 5,8-dimethyl-6-dodecyne-5,8-diol 2,4,7,9-tetramethyl-5-decyne-4,7-diol '3.5EO 4,7-dimethyl-5-decyne-4,7 diol 200EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol l0EO 3,6-diethyl-4-octyne-3,6-diol 9E0 2,5-dicyclopropyl-3-hexyne-2,5-diol 20EO I 3 ,6-dimethyl-4-octyne-3 ,6-diol- 30EO 2,4,7,9 tetramethyl-5-decyne-4,7-diol ISEO 4,7-dimethyl-5-decyne-4,7-diol 20EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol 2E0 3,6-diethyl-4-octyne-3,6-diol EO 2,5-dicyclopropyl-3-hexyne-2,5-diol 50EO 3,6-dimethyl-4-octyne-3,6-diol 20EO 2,5-diphenyl-3-hexyne-2,5diol 30EO 2,5-dimethyl-3-hexyne-2,Sdiol IOEO 5,8-dimethyl-6-dodecyne-5,8-diol, etc. 5E0 2,4,7,9-tetramethyl-5-decyne-4,7-diol 20EO 4,7-dimethyl-5-decyne-4,7-diol 8E0 2,3,6,7-tetramethyl-4-octyne-3,6-diol l2EO 3,6-diethyL4-octyne-3,6-diol l5EO 2,5-dicyclopropyl-3 hexyne-2,5-diol IOEO 3,6-dimethyl-4-octyne-3 ,6-diol 50EO 2,4,7,9-tetramethyl-5-decyne-4,7-diol 30150 4,7-dimethyl-5-decyne-4,-7-diol IOEO anionic surface active agent is C1245 normal primary alkyl triethanoxy sulfate ammonium salt.
7. The composition of claim 1 wherein M is an ammonium ion.
8. The composition of claim 1 wherein said glycolic surface active agent is an acetylenic glycol having the formula wherein R is an alkyl group having from one to four carbon atoms, and R, is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl.
9. The composition of claim 4 wherein said glycolic, surface active agent is 2,4,7,9-tetramethyl-5-decyne- 4,7-diol.
10. The composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:4.
11. The composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:10.
12. A window cleaning composition comprising from 80 to 93.7 percent water, from 3 to 8 percent by weight of at least one glycol ether selected from the group consisting of monoalkyl ethers of ethylene glycol and propylene glycol from 3 to 7 percent by weight of a lower monohydric alcohol, from 0.1 to 2 percent by weight of an alkali or ammonium hydroxide and from 0.1 to 3 percent by weight of an anti-fogging mixture consisting essentially of a mixture of a glycolic surface active agelnt selected from acetylenic glycols having the formu a wherein R is an alkyl group having from one to four carbon atoms, and R is a radical selected from the 14 group consisting of methyl, ethyl, cyclopropyl and phenyl, or the reaction product of an acetylenic glycol having the formula wherein R is an alkyl group having from on e to four carbon atoms and R is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl, and from 2 to 200 moles of ethylene oxide, and
a surface active agent selected from anionic surface active agents having the formula R O(C H O),,SO M wherein R is an alkyl group having from 8 to 20 carbon atoms, n is a number from 2 to 200 and M is a cation selected from the group consisting of ammonium, sodium and potassium and nonionic surface active agent having the formula R O(C H O),,H wherein R and n are as defined in a weight ratio of glycolic to anionic or nonionic surface active agent of from 1:50 to 1:1.
13. The composition of claim 12 wherein the glycol ether is a mixture of ethylene glycol monobutyl ether and propylene glycol monomethyl ether.
14. The composition of claim 12 wherein said lower monohydric alcohol is isopropanol.
15. The composition of claim 12 having a pH between 8 and ll.
16. The composition of claim 12 werein M is an ammonium ion.
17. The composition of claim 12 wherein said glycolic surface active agent is an acetylenic glycol having the formula wherein R is an alkyl group having from one to four carbon atoms and R is a radical selected from the group consisting of methyl, ethyl, cyclopropyl and phenyl.
18. The composition of claim 17 wherein said glycolic surface active agent is 2,4,7,9-tetramethyl-5- decyne-4,7-diol.
19. The combination of claim 12 wherein said weight ration of said glycolic surface active agent to said surface active agent is l:20 to 1:4.
20. The composition of claim 12 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:10.
Claims (19)
- 2. The composition of claim 1 wherein said anionic surface active agent is selected from the group consisting of mixed C12-15 normal primary alkyl triethenoxy sulfate, ammonium salt; myristyl triethenoxy sulfate, potassium salt, n-decyl diethenoxy sulfate, sodim salt; lauryl diethenoxy sulfate, ammonium salt, palmityl tetraethenoxy sulfate, sodium salt; mixed C12-15 normal primary alkyl mixed tri- and tetraethenoxy sulfate, sodium salt, stearyl pentaethenoxy sulfate, ammonium salt and mixed C10-18 normal primary alkyl triethenoxy sulfate, potassium salt.
- 3. The composition of claim 1 wherein said glycolic surface active agent is selected from the group consisting of 2,4,7,9-tetramethyl-5-decyne-4,7-diol 4,7-dimethyl-5-decyne-4,7-diol 2,3,6,7-tetramethyl-4-octyne-3,6-diol 3,6-diethyl-4-octyne-3,6-diol 2,5-dicyclopropyl-3-hexyne-2,5-diol 3,6-dimethyl-4-octyne-3,6-diol 2,5-diphenyl-3hexyne-2,5-diol 2,5-dimethyl-3-hexyne-2,5-diol 5,8-dimethyl-6-dodecyne-5,8-diol 2,4,7,9-tetramethyl-5-decyne-4,7-diol + 3.5EO 4,7-dimethyl-5-decyne-4,7-diol + 200EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol + 10EO 3,6-diethyl-4-octyne-3,6-diol + 9EO 2,5-dicyclopropyl-3-hexyne-2,5-diol + 20EO 3,6-dimethyl-4-octyne-3,6-diol + 30EO 2,4,7,9-tetramethyl-5-decyne-4,7-diol + 15EO 4,7-dimethyl-5-decyne-4,7-diol + 20EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol + 2EO 3,6-diethyl-4-octyne-3,6-diol + 100EO 2,5-dicyclopropyl-3-hexyne-2,5-diol + 50EO 3,6-dimethyl-4-octyne-3,6-diol + 20EO 2,5-diphenyl-3-hexyne-2,5diol + 30EO 2,5-dimethyl-3-hexyne-2,5diol + 10EO 5,8-dimethyl-6-dodecyne-5,8-diol, etc. + 5EO 2,4,7,9-tetramethyl-5-decyne-4,7-diol + 20EO 4,7-dimethyl-5-decyne-4,7-diol + 8EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol + 12EO 3,6-diethyl-4-octyne-3,6-diol + 15EO 2,5-dicyclopropyl-3-hexyne-2,5-diol + 10EO 3,6-dimethyl-4-octyne-3,6-diol + 50EO 2,4,7,9-tetramethyl-5-decyne-4,7-diol + 30EO 4,7-dimethyl-5-decyne-4,7-diol + 10EO 2,3,6,7-tetramethyl-4-octyne-3,6-diol + 5EO 3,6-diethyl-4-octyne-3,6-diol + 2EO 2,5-diphenyl-3-hexyne-2,5-diol + 5EO 2,5-dimethyl-3-hexyne-2,5-diol + 20EO 5,8-dimethyl-6-dodecyne-5,5-diol + 10EO, etc.
- 4. The composition of claim 1 wherein said glycolic surface active agent is a mixture of a major amount of 2,4,7,9-tetramethyl-5-decyne-4,7-diol, ethylene glycol and as a minor amount of alkyl phenyl ethylene oxide adduct.
- 5. The composition of claim 1 wherein in said anionic surfactant R2 is mixed alkyl, said alkly containing from 12 to 15 carbon atoms and wherein from about 10 to 50 percent of each alkyl chain length is present.
- 6. The composition according to claim 5 wherein said anionic surface active agent is C12-15 normal primary alkyl triethanoxy sulfate ammonium salt.
- 7. The composition of claim 1 wherein M is an ammonium ion.
- 8. The composition of claim 1 wherein said glycolic surface active agent is an acetylenic glycol having the formula
- 9. The composition of claim 4 wherein said glycolic surface active agent is 2,4,7,9-tetramethyl-5-decyne-4,7-diol.
- 10. The composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1: 20 to 1:4.
- 11. The composition of claim 1 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1: 20 to 1:10.
- 12. A window cleaning composition comprising from 80 to 93.7 percent water, from 3 to 8 percent by weight of at least one glycol ether selected from the group consisting of monoalkyl ethers of ethylene glycol and propylene glycol from 3 to 7 percent by weight of a lower monohydric alcohol, from 0.1 to 2 percent by weight of an alkali or ammonium hydroxide and from 0.1 to 3 percent by weight of an anti-fogging mixture consisting essentially of a mixture of a glycolic surface active agent selected from acetylenic glycols having the formula
- 13. The composition of claim 12 wherein the glycol ether is a mixture of ethylene glycol monobutyl ether and propylene glycol monomethyl ether.
- 14. The composition of claim 12 wherein said lower monohydric alcohol is isopropanol.
- 15. The composition of claim 12 having a pH between 8 and 11.
- 16. The composition of claim 12 werein M is an ammonium ion.
- 17. The composition of claim 12 wherein said glycolic surface active agent is an acetylenic glycol having the formula
- 18. The composition of claim 17 wherein said glycolic surface active agent is 2,4,7,9-tetramethyl-5-decyne-4,7-diol.
- 19. The combination of claim 12 wherein said weight ration of said glycolic surface active agent to said surface active agent is 1:20 to 1:4.
- 20. The composition of claim 12 wherein said weight ratio of said glycolic surface active agent to said surface active agent is 1:20 to 1:10.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00291681A US3819522A (en) | 1972-09-25 | 1972-09-25 | Anti-fogging window cleaner surfactant mixture |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00291681A US3819522A (en) | 1972-09-25 | 1972-09-25 | Anti-fogging window cleaner surfactant mixture |
Publications (1)
Publication Number | Publication Date |
---|---|
US3819522A true US3819522A (en) | 1974-06-25 |
Family
ID=23121365
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00291681A Expired - Lifetime US3819522A (en) | 1972-09-25 | 1972-09-25 | Anti-fogging window cleaner surfactant mixture |
Country Status (1)
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US (1) | US3819522A (en) |
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