US3779924A - Process for preparing electrophotographic liquid developing compositions - Google Patents
Process for preparing electrophotographic liquid developing compositions Download PDFInfo
- Publication number
- US3779924A US3779924A US00130519A US3779924DA US3779924A US 3779924 A US3779924 A US 3779924A US 00130519 A US00130519 A US 00130519A US 3779924D A US3779924D A US 3779924DA US 3779924 A US3779924 A US 3779924A
- Authority
- US
- United States
- Prior art keywords
- dye
- mordant
- binder
- liquid
- liquid carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 187
- 239000000203 mixture Substances 0.000 title claims description 48
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000011230 binding agent Substances 0.000 claims abstract description 124
- 239000002245 particle Substances 0.000 claims abstract description 77
- 239000002904 solvent Substances 0.000 claims abstract description 73
- 238000001556 precipitation Methods 0.000 claims abstract description 68
- 150000003839 salts Chemical class 0.000 claims abstract description 36
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- 239000002244 precipitate Substances 0.000 claims abstract description 15
- 239000000975 dye Substances 0.000 claims description 102
- 238000000034 method Methods 0.000 claims description 55
- -1 di-o-tolylquinidine Chemical compound 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 23
- 239000004094 surface-active agent Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 16
- 239000003960 organic solvent Substances 0.000 claims description 16
- 239000000981 basic dye Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 14
- 239000000980 acid dye Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 11
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 10
- QCGOYKXFFGQDFY-UHFFFAOYSA-M 1,3,3-trimethyl-2-[3-(1,3,3-trimethylindol-1-ium-2-yl)prop-2-enylidene]indole;chloride Chemical compound [Cl-].CC1(C)C2=CC=CC=C2N(C)\C1=C\C=C\C1=[N+](C)C2=CC=CC=C2C1(C)C QCGOYKXFFGQDFY-UHFFFAOYSA-M 0.000 claims description 6
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 5
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 5
- 150000002194 fatty esters Chemical class 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 5
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 5
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 5
- FUPAJKKAHDLPAZ-UHFFFAOYSA-N 1,2,3-triphenylguanidine Chemical compound C=1C=CC=CC=1NC(=NC=1C=CC=CC=1)NC1=CC=CC=C1 FUPAJKKAHDLPAZ-UHFFFAOYSA-N 0.000 claims description 4
- PGWPNHMAKPHTMA-UHFFFAOYSA-N chembl1091601 Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N=NC3=CC=C(C=C3S(O)(=O)=O)NC(=O)NC3=CC=C(C(=C3)S(O)(=O)=O)N=NC3=C4C(O)=CC(=CC4=CC=C3N)S(O)(=O)=O)=C(N)C=CC2=C1 PGWPNHMAKPHTMA-UHFFFAOYSA-N 0.000 claims description 4
- WSALIDVQXCHFEG-UHFFFAOYSA-L disodium;4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulfonate Chemical compound [Na+].[Na+].O=C1C2=C(N)C=C(S([O-])(=O)=O)C(O)=C2C(=O)C2=C1C(O)=C(S([O-])(=O)=O)C=C2N WSALIDVQXCHFEG-UHFFFAOYSA-L 0.000 claims description 4
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 4
- KQSBZNJFKWOQQK-UHFFFAOYSA-N hystazarin Natural products O=C1C2=CC=CC=C2C(=O)C2=C1C=C(O)C(O)=C2 KQSBZNJFKWOQQK-UHFFFAOYSA-N 0.000 claims description 4
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 claims description 4
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- HNONEKILPDHFOL-UHFFFAOYSA-M tolonium chloride Chemical compound [Cl-].C1=C(C)C(N)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 HNONEKILPDHFOL-UHFFFAOYSA-M 0.000 claims description 4
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 3
- 239000001263 FEMA 3042 Substances 0.000 claims description 3
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 3
- DTJAPYHTDACJJX-UHFFFAOYSA-N bis[3-methyl-4-(methylamino)phenyl]methylideneazanium;chloride Chemical compound Cl.C1=C(C)C(NC)=CC=C1C(=N)C1=CC=C(NC)C(C)=C1 DTJAPYHTDACJJX-UHFFFAOYSA-N 0.000 claims description 3
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 claims description 3
- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 claims description 3
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 3
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims description 3
- 229940043267 rhodamine b Drugs 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 229940033123 tannic acid Drugs 0.000 claims description 3
- 235000015523 tannic acid Nutrition 0.000 claims description 3
- 229920002258 tannic acid Polymers 0.000 claims description 3
- 229950003937 tolonium Drugs 0.000 claims description 3
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 claims 2
- VYXSBFYARXAAKO-WTKGSRSZSA-N chembl402140 Chemical compound Cl.C1=2C=C(C)C(NCC)=CC=2OC2=C\C(=N/CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-WTKGSRSZSA-N 0.000 claims 1
- VYXSBFYARXAAKO-UHFFFAOYSA-N ethyl 2-[3-(ethylamino)-6-ethylimino-2,7-dimethylxanthen-9-yl]benzoate;hydron;chloride Chemical compound [Cl-].C1=2C=C(C)C(NCC)=CC=2OC2=CC(=[NH+]CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-UHFFFAOYSA-N 0.000 claims 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 17
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 17
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 15
- 239000003086 colorant Substances 0.000 description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 11
- 229920000180 alkyd Polymers 0.000 description 11
- 238000009835 boiling Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 229920001568 phenolic resin Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 125000002837 carbocyclic group Chemical group 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000012260 resinous material Substances 0.000 description 3
- 239000012905 visible particle Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 2
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- PWATWSYOIIXYMA-UHFFFAOYSA-N Pentylbenzene Chemical compound CCCCCC1=CC=CC=C1 PWATWSYOIIXYMA-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 2
- 229940063655 aluminum stearate Drugs 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 231100000989 no adverse effect Toxicity 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- RYCFRVNAZOREPC-UHFFFAOYSA-N 1,1,2-triphenylguanidine Chemical class C=1C=CC=CC=1N(C=1C=CC=CC=1)C(N)=NC1=CC=CC=C1 RYCFRVNAZOREPC-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- KLVPTMNDLSIOIL-UHFFFAOYSA-N 1-butylanthracene Chemical compound C1=CC=C2C=C3C(CCCC)=CC=CC3=CC2=C1 KLVPTMNDLSIOIL-UHFFFAOYSA-N 0.000 description 1
- URGSMJLDEFDWNX-UHFFFAOYSA-N 1-butylnaphthalene Chemical compound C1=CC=C2C(CCCC)=CC=CC2=C1 URGSMJLDEFDWNX-UHFFFAOYSA-N 0.000 description 1
- LYZJKMDLTZKRML-UHFFFAOYSA-N 1-propylanthracene Chemical compound C1=CC=C2C=C3C(CCC)=CC=CC3=CC2=C1 LYZJKMDLTZKRML-UHFFFAOYSA-N 0.000 description 1
- XXXFZKQPYACQLD-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl acetate Chemical compound CC(=O)OCCOCCO XXXFZKQPYACQLD-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- CWJQQASJVVAXKL-UHFFFAOYSA-N 4-(3-Methyl-5-oxo-4,5-dihydro-1H-pyrazol-1-yl)benzenesulfonic acid Chemical compound O=C1CC(C)=NN1C1=CC=C(S(O)(=O)=O)C=C1 CWJQQASJVVAXKL-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 description 1
- MYAALGBQWWRACC-UHFFFAOYSA-N 6-oxo-6-(oxolan-2-ylmethoxy)hexanoic acid Chemical compound OC(=O)CCCCC(=O)OCC1CCCO1 MYAALGBQWWRACC-UHFFFAOYSA-N 0.000 description 1
- MMNWSHJJPDXKCH-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MMNWSHJJPDXKCH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- NRZVMOKAFOFUAV-UHFFFAOYSA-K CC(C)[Ti+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O Chemical compound CC(C)[Ti+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O NRZVMOKAFOFUAV-UHFFFAOYSA-K 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229940058172 ethylbenzene Drugs 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- VOOLKNUJNPZAHE-UHFFFAOYSA-N formaldehyde;2-methylphenol Chemical compound O=C.CC1=CC=CC=C1O VOOLKNUJNPZAHE-UHFFFAOYSA-N 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- KXUHSQYYJYAXGZ-UHFFFAOYSA-N isobutylbenzene Chemical compound CC(C)CC1=CC=CC=C1 KXUHSQYYJYAXGZ-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- OFUAIAKLWWIPTC-UHFFFAOYSA-L magnesium;naphthalene-2-carboxylate Chemical compound [Mg+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 OFUAIAKLWWIPTC-UHFFFAOYSA-L 0.000 description 1
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- ODNJVAVDJKOYFK-GRVYQHKQSA-L zinc;(9z,12z)-octadeca-9,12-dienoate Chemical compound [Zn+2].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O.CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O ODNJVAVDJKOYFK-GRVYQHKQSA-L 0.000 description 1
- MXODCLTZTIFYDV-UHFFFAOYSA-L zinc;1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Zn+2].C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O.C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O MXODCLTZTIFYDV-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/12—Developers with toner particles in liquid developer mixtures
Definitions
- An electrophotographic liquid developer may be prepared by admixture Of a dye and a mordant therefor in the presence of l) a suitable binder, (2) a solvent for the binder and (3) a liquid precipitation medium; the solvent for the binder is substantially removed; and the resultant dope is added to a suitable liquid carrier to form a dispersion of finely divided toner particles in the liquid carrier.
- the toner particles thus formed contain a dye-mordant salt precipitate dispersed in the binder.
- a particularly useful liquid electrophotographic developer is shown in York, U.S. Pat. No. 3,135,695.
- This patent shows an electrophotographic liquid developer prepared by surrounding or dispersing electrophotographic-type pigment particles with a suitable resinousbinder envelope and treating the pigment-binder combination with a smallamount of an alkylaryl compound before suspending the combination in a liquid aliphatic carrier.
- This type of liquid electrophotographic developer is especially useful due to its relatively high stability.
- lt is therefore, a primary objective of the present invention to provide a process for preparing liquid electrophotographic developers having excellent stability and which contain toner particles requiring relatively short preparation times. Another object of the present invention is to provide novel liquid electrophotographic developers having toner particles of uniformly small particle size. A further object of the invention is to provide a stabilized liquid developer composition having toner particles of a uniformly small size dispersed therein.
- the objects of the present invention are accomplished by a process utilizing a dye and a mordant for said dye to form the colorant contained in the toner particles of a liquid developer
- the dye and mordant therefor are admixed in the presence of (l) a suitable polymeric resinous binder, (2) a solvent for said binder and (3) a liquid precipitation medium which is a solvent or a colloidal dispersive medium for the polymeric binder and which also is miscible with a suitable liquid carrier; the solvent for the binder is substantially removed; and the resultant dope or mixture isadded to the dispersed liquid carrier to form a dispersion of finely divided toner particles in the liquid carrier.
- the toner particles thus suspended in the liquid carrier contain a core of a dye-mordant salt precipitate dispersed in the resinous polymeric binder.
- Suitable polymeric resinous binders include those resins which are soluble in the liquid precipitation medium or which are capable of forming a colloidal dispersion therein and which are insoluble or at least only slightly soluble in the liquid carrier of the developer.
- the liquid precipitation medium utilized in the process of the present invention and which is further described hereinafter may serve both as the solvent for the binder and as the liquid precipitation medium, in which case, however, a portion, but not all, of the liquid precipitation medium is removed prior to dispersal of the dope in the liquid carrier.
- the liquid carrier used can be any of the well-known liquid aliphatic carriers. These liquids have low dielectric constants and a resistivity of greater than about 10 ohm-centimeters to preclude the possibility of discharging the latent electrostatic image.
- the low dielectric constant of the liquid carrier is provided so that the energy in the image field is not dissipated in aligning and moving highly polar molecules. If the admixture of dye, mordant for the dye, polymeric resinous binder and solvent for the binder is dispersed in the liquid carrier without first treating it with the liquid precipitation medium, the system coagulates badly. Where the process of the present invention is utilized to prepare a liquid developer, it is found that the resultant developer exhibits excellent stability. l-lorover, no ball-milling of any sort is needed to prepare liquid developers having finely divided toner particles dispersed therein having a uniform small particle size.
- the admixture of the dye and mordant for the dye is accomplished by dissolving the dye and mordant in separate solutions; that is, the dye is dissolved in a first mixture of polymeric binder and solvent therefor and the mordant for the dye is dissolved in a separate second mixture of polymeric binder and solvent.
- the second mixture containing the mordant is then quickly added with rapid stirring to the first mixture containing the dye in the presence of the liquid precipitation medium.
- the resultant mixture may be washed with water to produce a product containing oily globules dispersed in water.
- the water may be removed by decanting most of it and running the remainder of the product through filter paper.
- the washing step is useful because it generally removes most if not all of the binder solvent, provided a water-miscible solvent has been used.
- the resulting dope contains a very fine dispersion of the dye-mordant salt precipitate in a mixture of the polymeric binder and liquid precipitation medium. Usually no visible particles are present. Any particles that may be present are present in the form of very loose agglomerates which may readily be broken up.
- a developer composition is then formed by dispersing the dope in the liquid aliphatic carrier.
- the admixture of the dye and mordant is accomplished by forming a solution of a dye-mordant salt in an organic solvent for said dye-mordant salt and admixing the dyemordant salt solution with a mixture of the polymeric binder, a solvent for the binder and a liquid precipitation medium.
- a dope without visible particles results.
- the solvent for the polymeric binder may be removed by water-washing as described above or by air-drying such as by placing the dope in an evaporating dish and allowing it to stand until all that remains is a dry powder. This dry powder may then readily be taken up in a small amount of additional liquid precipitation medium.
- the liquid developer composition may then be formed in the same manner as indicated previously by dispersing the resulting dope of particulate dyemordant salt precipitate, polymeric binder and liquid precipitation medium in the liquid carrier vehicle.
- a small quantity of surfactant which is soluble in the liquid carrier may be added prior to or simultaneously with the addition of the liquid precipitation medium and before the dope containing the liquid precipitation medium, binder and dye-mordant salt combination is admixed with the liquid carrier.
- the addition of this small quantity of surfactant provides an even more finely divided suspension of toner particles in the liquid carrier.
- surfactants suitable for use in the present invention include Strodex Super V-8, a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester; Tween 85, polyoxyethylene sorbitan trioleate; Tergitol 3A6, polyoxyethylene tridecylphenol; Sterox DF, polyoxyethylene dodecylphenol; Unamide SOA a fatty alkanolamide; etc.
- an electrostatic latent image can be produced by any of a number of procedures recognized in the art.
- a sensitive element may be produced by coating the support with a suitable photoconductor, such as those described in the Carlson patents cited above, the organicmetallic photoconductors such those described in US. Pat. application Ser. No. 650,664 filed July 3, 1967 now US. Pat. No. 3,647,429 the organic amine" photoconductors described in U.S. Pat. No. 3,240,597 issued Mar. 15, 1966, and the polyarylalkane photoconductors such as those described in US. Pat. No.
- the charged sensitive element is exposed to a pattern of light and shadow illumination whereby the illuminated areas are discharged and a charged image pattern remains which is developed to a visible image by flowing a developer of the present invention over the differentially charged surface.
- the electrostatically attractable particles carried in the insulating liquid carrier of the developer are brough into contact with the electrostatic image which results in the particles being deposited on the charged areas of the sensitive element so that the charged areas are immediately rendered visible because of the optical characteristics of the toner particles. Because of the highly volatile nature of the aliphatic carriers of the developer composition, fast drying results and a visible, permanent image is rapidly obtained.
- the polymeric resinous binder material utilized in the present invention to form an enveloping capsule about the dye-mordant salt colorant is characterized by being soluble in the precipitation medium, but insoluble or only slightly soluble in the liquid carrier of the developer.
- the preferred resinous binders should also be non-chalking should dry to a tought wear-resistant film and should have a refractive index conducive to enhance color or transparency.
- suitable resinous materials should have no adverse effect on particle charge or on developer stability.
- Those resinous materials which have been found to be suitable for use in the process of the present invention can be selected from a number of synthetic resins, modified resins, etc. Examples of suitable resins are given in Table 1 rosin-modified Amberol B/Sl phenol formaldehyde Do.
- LXl-l 403 modified pentaery- Sherwin-Williams Co.
- Suitable resinous materials and mixtures of such materials have been described in such US. Pat. as No. 2,891,011 by lnsalaco issued June 16, 1959, and No. 2,940,934 by Carlson issued June 14, 1963.
- Especially useful types of resins are the alkyd and mofidied alkyd resins, including mofidied alkyds such as soya oilmodified and linseed oil-modified alkyds, phthalic, maleic and stryenated alkyds, etc., and the phenolic resins, including modified phenolic resins such as phenol formaldehyde resins and derivatives thereof such as alkylphenol formaldehyde resins, e.g., methylphenol formaldehyde, xylenol formaldehyde resins, and the like.
- the dyes which can be used in preparing the dye- -mordant salts which serve as colorants in preparing the toner particles for the liquid developers of the present invention can vary widely. Both acid dyes and basic dyes which are mordantable may be used. The principal requirement of the mordantable dyes used in the present invention is that the dye-mordant salt colorant formed from the dye is capable of carrying an electrostatic charge.
- the acid dyes useful in the present invention are strongly acid dyes, and the basic dyes useful herein are strongly basic dyes.
- the strongly acid dye typically contains two or more acid groups and may be further characterized in that a saturated aqueous solution of the free acid form of the dye has a pH less than about 5.
- the strongly basic dye typically contains two or more basic groups and may be characterized in that a saturated aqueous solution of the free base form of the dye has a pH greater than about 8.
- the acid groups of the acid dyes include sulfonic acid or carboxy acid radicals which are capable of forming salts with alkali metals commonly used in the dye trade, such as sodium, potassium and lithium.
- the basic groups of the basic dye include amino or substituted amino radicals.
- the basic dye is typically used as the hydrohalide (e.g., hydrochloride, etc.), sulfate, nitrate, etc.
- Substituents for the amino group can be an alkyl group having from 1 to about 8 carbon atoms and which can be a straight-chain or branched-chain alkyl group, e.g, methyl, ethyl, isopropyl, hexyl, octyl, 2,2,4-trimethy1pentyl, etc., an aryl group, e.g., phenyl, naphthyl, etc., including substituted aryl group bearing such substituents as alkyl as defined above, amino including substituted amino, nitro, halogen and the like, an aralkyl group, eg., methylphenyl, benzyl, dimethylnaphthyl and the like.
- the dyes used as the starting materials in the present invention can be chosen from a wide variety of known dye classes.
- dyes selected from the following classes are useful: nitro, azo, including disazo, etc., arylmethane, including diand tri-arylmethane,
- Useful acidic dyes include Brilliant Alizarine Light Red B, Color Index Acid Red 58; copper phthalocyanine tetrasodium sulfonate, CI. 74220; 4,8- disulfonaphthyl-2-azo-4( 3-methyl- 1 -p-sulfophenyl-5- pyrazolone); anthraquinone Blue B, CI. 73010; Solantine Pink 4 BL, CI. 25380; and the like.
- Useful basic dyes include Astraphloxine FF, CI. 480- Rhodamine B, CI. 45170; Rhodamine 60, CI. 45160; methylene blue, CI. 52015; Toluidine Blue, C.l. 52040; Auramine G, C]. 41005; and the like.
- mordant compounds for use with the dyes of the present invention will depend upon the particular mordantable dye chosen. Naturally, an acid dye will require a basic mordant compound and a basic dye will require an acidic mordant compound. Like the mordantable dyes utilized in the process of the present invention the principal requirement of any mordant, either acid or basic, used in the present process is that these mordants be capable of reacting with the mordantable dye to form colorant particles capable of carrying an electrostatic charge.
- Mordants useful with basic dyes include such materials as phosphomolybdic acid, phosphotungstic acid, tungsto-silicic acid, molybdosilicic acid, naphthalene-l,S-disulfonic acid, tannic acid, 2-sulfoanthraquinone, mixtures thereof, etc.
- Suitable mordants for use with acidic dyes include triphenylguanidine, di-o-tolyguanidine, a-naphthyl-amine, dioctylamine, N,N,-dimethyldodecylamine mixtures thereof, etc.
- the molar ratio of mordant to dye should be within the range of from about 1:1 to about 2.5210, the actual ratio being previously determined by titration. Normally, a slight excess of mordant is preferred.
- the amounts of the dye and dye mordant used in the present invention are generally quite small in comparison with the amount of polymeric binder used. Ordinarily, the ratios of the weight amounts of both the dye and dye mordant to the polymeric binder vary from about 0.05:1 to about O.3:l.0, preferably from about 0.l:1.0 to about 021.0, or smaller or larger amounts of binder could be utilized, if desired.
- the liquid precipitation medium utilized in the process thereof can be characterized as a compound which is capable of dissolving or serving as a colloid-dispersive medium for the polymeric resinous binder and which also is miscible with the liquid carrier of the developer.
- Suitable compound which have been found useful as the liquid precipitation medium employed in the present invention are the alkylated aromatic-like hydrocarbons, including the alkylated cyclic alkenes, represented by the following general formula:
- R represents at least one straight-chain or branched-chain alkyl group having from 1 to about 12 carbon atoms
- Z represents the nonmetallic atoms necessary to complete a carbocyclic nucleus containing 1 to 3 carbocyclic rings, 5 to 7 carbon atoms being present in each ring.
- Typical examples of useful aromatic-like carbocyclic nuclei comprise benzene, naphthalene, anthracene, etc.
- liquid precipitation media examples include xylene, mesitylene, ethyl-benzene, n-propylbenzene, n-butylbenzene, isobutylbenzene, n-pentylbenzene, n-hexylbenzene, npropylnaphthalene, butylnaph-thalene, propylanthracene, butylanthracene, and the like.
- Useful results are obtained using isomers, as well as the normal aliphatic hydrocarbons and mixtures of each thereof.
- the preferred liquid precipitation media are compounds in which the cyclic nucleus is an aromatic nucleus such as benzene. Especially useful results are obtained where the aromatic substituent is benzene and the alkyl group is selected from those having from 3 to 6 carbon atoms.
- Preparation of any of the liquid precipitation media useful in the present invention can be by any of the well-known methods.
- liquid precipitation medium in the process of the present invention is not entirely understood. Accordingly, it will be understood that the invention should not be limited or restricted to a specific theory of operation. However, it is believed that the liquid precipitation medium aids in the formation of a resinous binder envelope around the particles of dye-mordant salt colorant formed in the process of the invention and also acts to stabilize the resultant liquid developer by effectively preventing the binder envelope from diffusing away from the dye-mordant salt particles.
- finely divider toner particles having particles of the dye-mordant salt colorant dispersed in a coating of the resinous binder are present in the liquid carrier. Moreover, these toner particles remain stable in the liquid carrier over very long periods of time.
- the size of the toner particles prepared according to the present invention may vary within the range of from about 0.05 micron to about microns, preferably within the range of from 0.1 micron to about 2.0 microns.
- a particular advantage of the present invention is that there is provided a process for preparing relatively small toner particles having a uniform size in the order of about 0.5 micron.
- the amounts of the liquid precipitation medium employed may vary over a wide range.
- an amount of the liquid precipitation medium varying from about 0.2 to about 8.0 parts by weight of the liquid precipitation medium for every 1.0 part by weight of the remaining components of the admixture (excluding the weight of the solvents), i.e., the dye, dye mordant and binder components.
- Much larger amounts of liquid precipitation medium may also be used, although it is unnecessary and generally results in simply adding to the expense of the process.
- liquid precipitation medium is also used as the solvent for the polymeric binder
- larger amounts of the liquid precipitation medium than those specified above may be usefully employed.
- the solvents employed in the present invention are removed before dispersal of the admixture of dye, dye-mordant, binder and liquid precipitation medium in the carrier liquid of the developer composition. Accordingly, in those instances where large amounts of the liquid precipitation medium are used because of its dual role as a binder solvent and as a liquid precipitation medium, it is preferable to remove a substantial amount of the liquid precipitation medium prior to dispersal of the admixture in the liquid carrier.
- Suitable liquid carriers for dispersing the toner particles prepared by the present invention comprise liquid possessing a low dielectric constant less than about 3.0.
- the liquid carrier should have a resistivity of greater than about l0 ohm-centimeters.
- Liquids which have been found useful include cyclohexane, carbon tetrachloride, mixed halides such as trichlorotrifluoroethane, sold under the trade name Freon l 13 by E. l.
- du Pont de Nemours & Co. cyclopentane, npentane, n-hexane, paraffinic hydrocarbon such as isoparaffinic hydrocarbon liquids having a boiling point in the range of to C., sold under the trade name Isopar G by the Humble Oil and Refining Co., petroleum distillates, mixtures thereof, etc.
- paraffinic hydrocarbon such as isoparaffinic hydrocarbon liquids having a boiling point in the range of to C., sold under the trade name Isopar G by the Humble Oil and Refining Co., petroleum distillates, mixtures thereof, etc.
- certain other liquid vehicles may be used, such as dimethyl polysiloxane.
- Solvents for the binder materials used in the process of the present invention include a wide variety of materials.
- Generally useful solvents include organic solvents which either are water-soluble or have a low boiling point relative to the boiling point of the liquid precipitation medium, i.e., boiling at least about 25 C. below the boiling point of the liquid precipitation medium. These properties, i.e., water solubility or low boiling point, are desirable because solventshaving these properties may be easily removed from the admixture of dye, dye mordant, liquid precipitation medium, binder material and solvent therefor which is employed in the present invention.
- water-soluble organic solvents may be removed by continuous water-washing of the aforementioned admixture, and low-boiling organic solvents may be easily removed by air-drying the admixture.
- the above-described liquid precipitation medium also functions as the binder solvent, it is desirable to employ a low-boiling liquid so that most of that portion of the liquid serving as a binder solvent may be readily removed by air-drying.
- the particular solvent chosen should be substantially chemically inert with respect to the dye, dye mordant, resinous binder and liquid precipitation at least within the temperature range at which the process of the present invention is carried out.
- the solvent employed should be compatible, i.e., miscible, with the liquid precipitation medium to avoid formation of a multiphase liquid system.
- the solvent utilized should have little or no adverse effect on particle charge or developer stability.
- auxiliary solvents for the dye, dye mordant or dye-mordant salt may be used in the process of the present invention. If so, these solvents should possess properties which are the same as or quite similar to the binder. solvents described immediately above.
- these auxiliary solvents should be compatible, i.e., miscible, with both the liquid precipitation medium and the binder solvents.
- these auxiliary solvents should be compatible with the binder material, i.e., incapable of causing the binder to settle out of admixture with the binder solvent, dye, dye mordant and liquid precipitation medium.
- Preferred solvents useful in the present invention will, of course, vary also depending on the particular binders, dyes, dye mordants, etc., which are employed. Generally, however useful solvents include (1) lowboiling, water-insoluble organic solvents having a boiling point within a range of from about less than 28 C.
- ethyl and butyl acetates such as ethyl and butyl acetates, ethyl propionate, butyl alcohol, ethyl formate, nitroethane, etc.
- water-soluble solvents such as methyl isobutyl ketone, B-ethoxy ethyl acetate, B-butoxy-B- ethoxy ethyl acetate, tetrahydrofurfuryl adipate, diethylene glycol monoacetate, B-methoxymethyl acetate, acetonyl acetone, diacetone alcohol, diethylene glycol monomethyl ether, ethylene glycol, dipropylene glycol, acetone, methanol, ethanol, methylethyl ketone, acetonitrile, dimethylformamide, dioxane, etc.
- the final liquid developer prepared by the process of the present invention ordinarily has a composition as follows: the toner particles, i.e., the particles comprising dye-mordant salt colorant dispersed in the polymeric binder material, are present in concentrations within the range of from about 0.01 to about 10 percent by weight, the liquid precipitation medium is pres.- ent in a concentration within the range of from about 2 to about 35 percent by weight, and the aliphatic liquid carrier can make up from about 45 to about 98 percent by weight.
- the electrostatic-charge polarity of the toner particles of the present invention can be enhanced or altered by the addition of suitable charge control agents, if so desired.
- suitable charge control agents A variety of materials can be used as charge control agents. Illustrative of suitable charge agents would be the polyoxyethylated alkyl surfactants such as polyoxyethylated alkylamine, polyoxyethylene palmitate, polyoxyethylene stearate, etc.
- Other useful materials are magnesium and heavier metal soaps of fatty and aromatic acids as described in Beyer, US. Pat. No. 3,417,019.
- Useful metal soaps include cobalt naphthenate, magnesium naphthenate and manganese naphthenate, zinc resinate, calcium naphthenate, zinc linoleate, aluminum resinate, isopropyltitanium stearate, aluminum stearate, and others, many of which are also described in US. Pat. No. 3,259,581. Typically, the amount of such materials used is less than about 2 percent by weight based on the weight of toner. In certain instances, the resinous binder per se can function as the charge control agent, as can the colorant.
- Beckosol 7 (a soya-modified alkyd resin containing 42 percent phthalic anhydride and 41 percent soya fatty acids, made by the Reichold Chemical Co.) is dissolved in a mixture of 75 ml. of methanol and 75 m1. of methylethyl ketone by stirring the mixture of resins and solvents for 2% hours at room temperature.
- Solution A To a 22-gram quantity of the stock solution (containing 4 grams of resin solids) is added 1.0 gram of a basic magenta dye, Astraphloxine FF (Color lndex 48070, General Dyestuffs Co.) or Calcozine Red BG (Color lndex 48070, American Cyanamid Co.). The dye dissolves readily.
- Astraphloxine FF Color lndex 48070, General Dyestuffs Co.
- Calcozine Red BG Color lndex 48070, American Cyanamid Co.
- Solution B To another 22-gram portion of the stock solution are added the following ingredients:
- Solvesso 100 is an essentially aromatic petroleum hydrocarbon made by Humble Oil and Refining Co.; flash point, F.; boiling range, 315-350 F percent aromatics, 96 percent of total including xylenes 9 percent, monoalkyl benzenes 16 percent, dialkyl benzenes 36 percent, trialkyl benzene 39 percent; aliphatics 4 percent.
- the resultant solution is essentially clear.
- Solution B is quickly added with vigorous stirring to Solution A. There results an excellent dispersion of the precipitated pigment formed by the mordanting of the dye in Solution A by the acid in Solution B. The dispersion is formed in the polymer solution. A 30-gram portion of Solvesso 100 is then stirred in to serve as the liquid precipitation medium.
- the above-described mix ture is dumped into 400 ml. of water. Oily globules result. Most of the water is decanted, and the remaining water is removed by running through a filter paper. The resulting dope contains the liquid precipitation medium and polymeric binder together with colorant particles having an average size of about 0.8 micron, with some very loose agglomerates of up to 6 microns in size. These are readily broken up.
- the developer is then made up by adding dropwise, with stirring in a Polytron blender, 2.5 g. of the dope to 250 ml. of a liquid carrier of lsopar G containing 0.2 g. cobalt naphthenate and 0.45 g. of a 1.5 percent by weight solution of aluminum stearate in xylene and shearing for 3 minutes after addition is complete.
- the resultant liquid developer is found to contain toner particles having an average size of about 0.8 micron. These particles contain the dye-mordant salt colorant dispersed in the Beckosol 7 polymeric binder.
- the toner particles are positively charged.
- Example 2 The procedure of Example 1 is followed using 0.56 gram of an acid dye, Brilliant Alizarine Light Red B (Sandoz, Color Index acid Red 58), in 22 grams of the stock polymer solution for Solution A, and 0.29 gram of triphenylguanidine as a mordant in 22 grams of the stock solution for Solution B. Recovery and developer preparation are carried out as in Example 1. The toner particles are positively charged.
- an acid dye Brilliant Alizarine Light Red B (Sandoz, Color Index acid Red 58)
- triphenylguanidine as a mordant in 22 grams of the stock solution for Solution B.
- EXAMPLE 3 This is a variation on the procedure of Example 1 which requires no washing step to remove the solvents and recover the dispersion of colorant particles in a dope containing the liquid precipitation medium and the polymeric binder.
- a 0.5 gram quantity of the dye-mordant salt, triphenylguanidine salt of copper phthalocyanine tetrasulfonic acid, is dissolved in ml. of methanol and 10 ml. of methylethyl ketone. To this solution are added 22 grams of the stock polymer solution of Example 1. To the mixture are then added a 10-ml. quantity of S01- vesso 100 as a solvent and a 50 mg. quantity of surfactant (Tween 85). A clear dope without visible particles results. The dope is placed in an evaporating dish and allowed to stand for 24 hours or until all that remains is a dry powder. This is readily taken up in g. of S01- vesso 100, which is now used as the liquid precipitation medium.
- a liquid developer is made in the same manner indicated previously.
- the final toner particles contained therein are under 0.5 micron in size and very uniform.
- the toner particles are positively charged.
- EXAMPLE 4 the same liquid serves both as the binder solvent and as the liquid precipitation medium.
- a stock polymer solution is prepared which contains the following ingredients:
- Beckosol 7 (resinous binder) 27.0 g.
- Solvesso 100 (solvent and precipitation medium)
- a dye solution is prepared by dissolving 0.5 g. of a dye-mordant salt of phosphomolybdic acid complex of Astraphloxine FF in 3.0 ml. of dimethyl sulfoxide.
- the dye solution to which also has been added 0.5 g. of Strodex V-8 as a surfactant, is added to 19.0 g. of the above-described stock polymer solution, with stirring, to yield a dope containing a fine dispersion of the pigment; about 16 g. of excess Solvesso 100 are removed by air-drying the dope.
- the resultant dope is then added to a liquid carrier of Isopar G as described in Example 1 to form a liquid developer composition containing toner particles having the dye-mordant salt dispersed in the Beckosol 7 and Amberol ST137 resin mixture.
- a process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from said mordant, (2) an organic solvent for said binder and (3) an organic liquid precipitation medium which is capable of dissolving or forming a colloidal suspension of the polymeric binder and which is miscible with the liquid carrier; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially unifonn size within the range of from about 0.05 microns to about 20 microns and comprising particulate dye-mordant salt precipitate dispersed in the polymeric binder.
- a process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing an acid dye and a basic mordant for said dye in the presence of (1) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dyemordant salt precipitate dispersed in the polymeric binder; said acid dye being selected from the group consisting of Brilliant Alizarine Light Red B.
- admixture of the acidic dye and basic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- a surfactant selected from the group consisting of a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- a process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a basic dye and an acidic mordant for said dye in the presence of l) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dyemordant salt precipitate dispersed in the polymeric binder; said basic dye being selected from the group consisting of Astraphloxine FF, CI.
- admixture of the basic dye and the acidic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphos'phoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- a surfactant selected from the group consisting of a polyphos'phoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- a process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from sad mordant, (2) an organic solvent for said binder, and (3) a first amount of an organic liquid precipitation medium which is capable of dissolving or forming a colloidal suspension of the polymeric binder and which is miscible with the liquid carrier; removing the solvent for said binder and the liquid precipitation medium to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said organic liquid precipitation medium sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said to
- a process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10" ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from said mordant, (2) an organic solvent for said binder, and (3) a first amount of an alkylated aromatic hydrocarbon; removing the solvent for said binder and the alkylated aromatic hydrocarbon to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said alkylated aromatic hydrocarbon sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.05 microns to about 20 micro
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Abstract
An electrophotographic liquid developer may be prepared by admixture of a dye and a mordant therefor in the presence of (1) a suitable binder, (2) a solvent for the binder and (3) a liquid precipitation medium; the solvent for the binder is substantially removed; and the resultant dope is added to a suitable liquid carrier to form a dispersion of finely divided toner particles in the liquid carrier. The toner particles thus formed contain a dye-mordant salt precipitate dispersed in the binder.
Description
[ Dec. 18,1973
[ 1 PROCESS FOR PREPARING ELECTROPHOTOGRAPHIC LIQUID DEVELOPING COMPOSITIONS [75] Inventor: Jonas J. Chechak, Brockport, NY.
[73] Assignee: Eastman Kodak Company,
Rochester, NY.
[22] Filed: Apr. 1, 1971 [21] Appl. No.: 130,519
[52] US. Cl. 252/62.1 [51] Int. Cl G03g 9/04 [58] Field of Search 252/621; 8/72, 79; 96/97, 84 A [56] References Cited UNITED STATES PATENTS 3,271,148 9/1966 Whitmore 96/29 3,173,878 3/1965 Reyes 252/316 2,671,971 3/1954 Laakse et a1 i 96/84 A 2,118,432 5/1938 Gessler 8/72 2,589,953 3/1952 Miller 8/72 3,078,231 2/1963 Metcalfe et a1 252/62.1
3,135,695 6/1964 York 252/621 3,190,850 6/1965 Burke 260/38 3,336,155 8/1967 Rowe..... 252/316 3,387,916 6/1968 Clarke 8/72 3,391,014 7/1968 Faurer 252/621 Primary ExaminerNorman G. Torchin ,Assistant ExaminerJ. P. Brammer Att0rneyRobert W. Hampton, Paul R. Holmes and Ronald P. Hilst 5 7 ABSTRACT An electrophotographic liquid developer may be prepared by admixture Of a dye and a mordant therefor in the presence of l) a suitable binder, (2) a solvent for the binder and (3) a liquid precipitation medium; the solvent for the binder is substantially removed; and the resultant dope is added to a suitable liquid carrier to form a dispersion of finely divided toner particles in the liquid carrier. The toner particles thus formed contain a dye-mordant salt precipitate dispersed in the binder.
16 Claims, No Drawings PROCESS FOR PREPARING ELECTROPHOTOGRAPl-IIC LIQUID DEVELOPING COMPOSITIONS This invention relates to electrophotography and to liquid compositions containing mordantable dyes which are useful for developing a visible image from a latent electrostatic image existing as a charge pattern on electrophotographic elements.
Processes for producing a visible image from a latent electrostatic image by developing with an electrostatically attracta ble dry powder having optical density are well-known and have been described in numerous U.S. patents including the Carlson U.S. Pat. No. 2,297,691 issued Oct. 6, 1942, and No. 2,357,809 issued Sept. 12, 1944. To develop a latent electrostatic image, the dry granular electroscopic powders have in the past ordinarily been cascaded over latent electroscopic images or brought in the form of powder clouds into intimate contact with the charged image to be rendered visible. Dry developers of this type have been described in such U.S. Pats. as No. 2,618,552 by Wise issued Nov. 18, 1952, and No. 2,753,308 by Landigram issued July 3, 1956. More recently, it has been proposed to develop latent electrostatic images using liquid media rather than the above-described dry process. Straughan in U.S. Pat. No. 2,899,335 issued Aug. 11, 1959, for example, proposed the development of an electrostatic image using a liquid developer in which the charged solid developing particles are carried into contact with the electrostatic image in a liquid medium instead of in air or a gaseous medium as in the aforesaid Carlson patents, for example. Another type of charged pigment suspending liquid developer of electrostatic images has been described by Metcalfe and Wright in Australian Pat. No. 212,315 patented Dec. 6, 1956.
A particularly useful liquid electrophotographic developer is shown in York, U.S. Pat. No. 3,135,695. This patent shows an electrophotographic liquid developer prepared by surrounding or dispersing electrophotographic-type pigment particles with a suitable resinousbinder envelope and treating the pigment-binder combination with a smallamount of an alkylaryl compound before suspending the combination in a liquid aliphatic carrier. This type of liquid electrophotographic developer is especially useful due to its relatively high stability.
One problem associated with most types of liquid developers noted in the patents cited hereinabove is that the time required simply to prepare the toner particles, i.e., particles comprising a combination of colorant and resinous binder, especially finely divided toner particles on the order of about 1 micron, is frequently quite lengthy; for example, a preparation time of several days in not unusual. Usually this is done by a rapid highspeed blending operation, or in cases where very small toner particle size is required by lengthly ball-milling and super ball-milling procedures. The present invention overcomes, quite unexpectedly, such lengthy preparation times by a relatively simple process such that quite small toner particles of colorant and binder having a uniform size on the order of 0.5 micron may be obtained in a matter of minutes or a very few hours.
lt is therefore, a primary objective of the present invention to provide a process for preparing liquid electrophotographic developers having excellent stability and which contain toner particles requiring relatively short preparation times. Another object of the present invention is to provide novel liquid electrophotographic developers having toner particles of uniformly small particle size. A further object of the invention is to provide a stabilized liquid developer composition having toner particles of a uniformly small size dispersed therein. other objects will become apparent on a reading of the specification and appended claims.
The objects of the present invention are accomplished by a process utilizing a dye and a mordant for said dye to form the colorant contained in the toner particles of a liquid developer In this process, the dye and mordant therefor are admixed in the presence of (l) a suitable polymeric resinous binder, (2) a solvent for said binder and (3) a liquid precipitation medium which is a solvent or a colloidal dispersive medium for the polymeric binder and which also is miscible with a suitable liquid carrier; the solvent for the binder is substantially removed; and the resultant dope or mixture isadded to the dispersed liquid carrier to form a dispersion of finely divided toner particles in the liquid carrier. The toner particles thus suspended in the liquid carrier contain a core of a dye-mordant salt precipitate dispersed in the resinous polymeric binder. Suitable polymeric resinous binders include those resins which are soluble in the liquid precipitation medium or which are capable of forming a colloidal dispersion therein and which are insoluble or at least only slightly soluble in the liquid carrier of the developer. lf desired, the liquid precipitation medium utilized in the process of the present invention and which is further described hereinafter may serve both as the solvent for the binder and as the liquid precipitation medium, in which case, however, a portion, but not all, of the liquid precipitation medium is removed prior to dispersal of the dope in the liquid carrier. The liquid carrier used can be any of the well-known liquid aliphatic carriers. These liquids have low dielectric constants and a resistivity of greater than about 10 ohm-centimeters to preclude the possibility of discharging the latent electrostatic image. The low dielectric constant of the liquid carrier is provided so that the energy in the image field is not dissipated in aligning and moving highly polar molecules. If the admixture of dye, mordant for the dye, polymeric resinous binder and solvent for the binder is dispersed in the liquid carrier without first treating it with the liquid precipitation medium, the system coagulates badly. Where the process of the present invention is utilized to prepare a liquid developer, it is found that the resultant developer exhibits excellent stability. l-lorover, no ball-milling of any sort is needed to prepare liquid developers having finely divided toner particles dispersed therein having a uniform small particle size.
In a preferred embodiment of the process of the present invention, the admixture of the dye and mordant for the dye is accomplished by dissolving the dye and mordant in separate solutions; that is, the dye is dissolved in a first mixture of polymeric binder and solvent therefor and the mordant for the dye is dissolved in a separate second mixture of polymeric binder and solvent. The second mixture containing the mordant is then quickly added with rapid stirring to the first mixture containing the dye in the presence of the liquid precipitation medium. If desired, the resultant mixture may be washed with water to produce a product containing oily globules dispersed in water. The water may be removed by decanting most of it and running the remainder of the product through filter paper. The washing step is useful because it generally removes most if not all of the binder solvent, provided a water-miscible solvent has been used.
The resulting dope contains a very fine dispersion of the dye-mordant salt precipitate in a mixture of the polymeric binder and liquid precipitation medium. Usually no visible particles are present. Any particles that may be present are present in the form of very loose agglomerates which may readily be broken up. A developer composition is then formed by dispersing the dope in the liquid aliphatic carrier.
In a second embodiment of the present invention, the admixture of the dye and mordant is accomplished by forming a solution of a dye-mordant salt in an organic solvent for said dye-mordant salt and admixing the dyemordant salt solution with a mixture of the polymeric binder, a solvent for the binder and a liquid precipitation medium. A dope without visible particles results. The solvent for the polymeric binder may be removed by water-washing as described above or by air-drying such as by placing the dope in an evaporating dish and allowing it to stand until all that remains is a dry powder. This dry powder may then readily be taken up in a small amount of additional liquid precipitation medium. The liquid developer composition may then be formed in the same manner as indicated previously by dispersing the resulting dope of particulate dyemordant salt precipitate, polymeric binder and liquid precipitation medium in the liquid carrier vehicle.
In a variation of either of the above-described embodiments of the present invention, a small quantity of surfactant which is soluble in the liquid carrier may be added prior to or simultaneously with the addition of the liquid precipitation medium and before the dope containing the liquid precipitation medium, binder and dye-mordant salt combination is admixed with the liquid carrier. The addition of this small quantity of surfactant provides an even more finely divided suspension of toner particles in the liquid carrier. Examples of surfactants suitable for use in the present invention include Strodex Super V-8, a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester; Tween 85, polyoxyethylene sorbitan trioleate; Tergitol 3A6, polyoxyethylene tridecylphenol; Sterox DF, polyoxyethylene dodecylphenol; Unamide SOA a fatty alkanolamide; etc.
ln carrying out the present invention, an electrostatic latent image can be produced by any of a number of procedures recognized in the art. For example, a sensitive element may be produced by coating the support with a suitable photoconductor, such as those described in the Carlson patents cited above, the organicmetallic photoconductors such those described in US. Pat. application Ser. No. 650,664 filed July 3, 1967 now US. Pat. No. 3,647,429 the organic amine" photoconductors described in U.S. Pat. No. 3,240,597 issued Mar. 15, 1966, and the polyarylalkane photoconductors such as those described in US. Pat. No. 3,274,000, etc., and imparting a uniform charge to said sensitive element by any of the known means such as corona discharge and by rubbing as also described in the Carlson patents. Fnally, the charged sensitive element is exposed to a pattern of light and shadow illumination whereby the illuminated areas are discharged and a charged image pattern remains which is developed to a visible image by flowing a developer of the present invention over the differentially charged surface. The electrostatically attractable particles carried in the insulating liquid carrier of the developer are brough into contact with the electrostatic image which results in the particles being deposited on the charged areas of the sensitive element so that the charged areas are immediately rendered visible because of the optical characteristics of the toner particles. Because of the highly volatile nature of the aliphatic carriers of the developer composition, fast drying results and a visible, permanent image is rapidly obtained.
The polymeric resinous binder material utilized in the present invention to form an enveloping capsule about the dye-mordant salt colorant is characterized by being soluble in the precipitation medium, but insoluble or only slightly soluble in the liquid carrier of the developer. The preferred resinous binders should also be non-chalking should dry to a tought wear-resistant film and should have a refractive index conducive to enhance color or transparency. On the other hand, suitable resinous materials should have no adverse effect on particle charge or on developer stability. Those resinous materials which have been found to be suitable for use in the process of the present invention can be selected from a number of synthetic resins, modified resins, etc. Examples of suitable resins are given in Table 1 rosin-modified Amberol B/Sl phenol formaldehyde Do.
rosin-modified Amberol F-7 phenol formaldeyhyde Do.
rosin-modified Amberol F-77 phenol form rosin Do.
modified Amberol KlZA phenol form rosin Do.
modified Amberol M-88 phenol form rosin Do.
modified Amberol M-93 phenol form rosin Do.
modified Amberol 800 maleic rosin type Do.
Amberol 801 maleic rosin type Do.
Amberol 801? maleic rosin type Do.
Amberol 808 malcic rosin type Do.
Amberlac D-96 maleic rosin type Do.
Beckosol 7 soya-modified alkyd Reichold Chemical Co.
Ccllolyn 102 modified pentaery- Hercules Powder Co.
thritol ester of rosin Gellolyn I04 modified pentaery- Do.
thritol ester of rosin Lewisol 2L maleic alkyd-modified Do.
rosin ester Lewisol 28 maleic alkyd-modified Do.
rosin ester Neolyn 23 rosin-derived alkyd- Do.
type resin Neolyn 35 rosin-derived alkyd- Do.
type resin Pentalyn B25 phenol-modified Do.
pentaerythritol ester of rosin Pentalyn 802A phenol-modified Do.
pentaerythritol ester of rosin Arochem modified phenolic Archer Daniels Midland Co. Arochem 333 modified phenolic Do. Arochem 335 modified phenolic Do. Arochem 337 modified phenolic Do. Arochem 339 modified phenolic Do. Arochem 365 modified phenolic Do. Arochem 402 modified phenolic Do. Arochem 404 modified phenolic Do. Arochem 520 modified maleic Do. Arochem 533 modified penta ester Do. Arochem 542 modified maleic Do.
Daniels land Arochem 545 modified maleic Do. Arochem 59S modified maleic Do. Arochem 650 lacquer resin Do.
Arofene 753 pure phenolic resin Do.
LXl-l 403 modified pentaery- Sherwin-Williams Co.
thritol.
XLH 504 modified pentaery- Do.
thritol Dymal XLM 110 maleic alkyd Do.
Dymal XLM 101 maleic alkyd Do.
Dymal XLM 103 maleic alkyd Do.
Dymal XLM l06maleic alkyd Do.
Other suitable resinous materials and mixtures of such materials have been described in such US. Pat. as No. 2,891,011 by lnsalaco issued June 16, 1959, and No. 2,940,934 by Carlson issued June 14, 1963. Especially useful types of resins are the alkyd and mofidied alkyd resins, including mofidied alkyds such as soya oilmodified and linseed oil-modified alkyds, phthalic, maleic and stryenated alkyds, etc., and the phenolic resins, including modified phenolic resins such as phenol formaldehyde resins and derivatives thereof such as alkylphenol formaldehyde resins, e.g., methylphenol formaldehyde, xylenol formaldehyde resins, and the like.
The dyes which can be used in preparing the dye- -mordant salts which serve as colorants in preparing the toner particles for the liquid developers of the present invention can vary widely. Both acid dyes and basic dyes which are mordantable may be used. The principal requirement of the mordantable dyes used in the present invention is that the dye-mordant salt colorant formed from the dye is capable of carrying an electrostatic charge.
The acid dyes useful in the present invention are strongly acid dyes, and the basic dyes useful herein are strongly basic dyes. The strongly acid dye typically contains two or more acid groups and may be further characterized in that a saturated aqueous solution of the free acid form of the dye has a pH less than about 5. In a similar manner, the strongly basic dye typically contains two or more basic groups and may be characterized in that a saturated aqueous solution of the free base form of the dye has a pH greater than about 8. Typically, the acid groups of the acid dyes include sulfonic acid or carboxy acid radicals which are capable of forming salts with alkali metals commonly used in the dye trade, such as sodium, potassium and lithium. Typically, the basic groups of the basic dye include amino or substituted amino radicals. The basic dye is typically used as the hydrohalide (e.g., hydrochloride, etc.), sulfate, nitrate, etc. Substituents for the amino group can be an alkyl group having from 1 to about 8 carbon atoms and which can be a straight-chain or branched-chain alkyl group, e.g, methyl, ethyl, isopropyl, hexyl, octyl, 2,2,4-trimethy1pentyl, etc., an aryl group, e.g., phenyl, naphthyl, etc., including substituted aryl group bearing such substituents as alkyl as defined above, amino including substituted amino, nitro, halogen and the like, an aralkyl group, eg., methylphenyl, benzyl, dimethylnaphthyl and the like.
The dyes used as the starting materials in the present invention can be chosen from a wide variety of known dye classes. For example, dyes selected from the following classes are useful: nitro, azo, including disazo, etc., arylmethane, including diand tri-arylmethane,
methine, acridine, thiazole, azine, anthraquinone, phthalocyanine, etc. These and other useful classes of dyes can be found in the Preamble to the Color lndex, Volume 3, Second Edition, 1956.
Useful acidic dyes include Brilliant Alizarine Light Red B, Color Index Acid Red 58; copper phthalocyanine tetrasodium sulfonate, CI. 74220; 4,8- disulfonaphthyl-2-azo-4( 3-methyl- 1 -p-sulfophenyl-5- pyrazolone); anthraquinone Blue B, CI. 73010; Solantine Pink 4 BL, CI. 25380; and the like.
Useful basic dyes include Astraphloxine FF, CI. 480- Rhodamine B, CI. 45170; Rhodamine 60, CI. 45160; methylene blue, CI. 52015; Toluidine Blue, C.l. 52040; Auramine G, C]. 41005; and the like.
Suitable mordant compounds for use with the dyes of the present invention, of course, will depend upon the particular mordantable dye chosen. Naturally, an acid dye will require a basic mordant compound and a basic dye will require an acidic mordant compound. Like the mordantable dyes utilized in the process of the present invention the principal requirement of any mordant, either acid or basic, used in the present process is that these mordants be capable of reacting with the mordantable dye to form colorant particles capable of carrying an electrostatic charge. Mordants useful with basic dyes include such materials as phosphomolybdic acid, phosphotungstic acid, tungsto-silicic acid, molybdosilicic acid, naphthalene-l,S-disulfonic acid, tannic acid, 2-sulfoanthraquinone, mixtures thereof, etc. Suitable mordants for use with acidic dyes include triphenylguanidine, di-o-tolyguanidine, a-naphthyl-amine, dioctylamine, N,N,-dimethyldodecylamine mixtures thereof, etc. ln general, the molar ratio of mordant to dye should be within the range of from about 1:1 to about 2.5210, the actual ratio being previously determined by titration. Normally, a slight excess of mordant is preferred.
The amounts of the dye and dye mordant used in the present invention are generally quite small in comparison with the amount of polymeric binder used. Ordinarily, the ratios of the weight amounts of both the dye and dye mordant to the polymeric binder vary from about 0.05:1 to about O.3:l.0, preferably from about 0.l:1.0 to about 021.0, or smaller or larger amounts of binder could be utilized, if desired.
According to the present invention, the liquid precipitation medium utilized in the process thereof can be characterized as a compound which is capable of dissolving or serving as a colloid-dispersive medium for the polymeric resinous binder and which also is miscible with the liquid carrier of the developer. Suitable compound which have been found useful as the liquid precipitation medium employed in the present invention are the alkylated aromatic-like hydrocarbons, including the alkylated cyclic alkenes, represented by the following general formula:
Lac
wherein R represents at least one straight-chain or branched-chain alkyl group having from 1 to about 12 carbon atoms, and Z represents the nonmetallic atoms necessary to complete a carbocyclic nucleus containing 1 to 3 carbocyclic rings, 5 to 7 carbon atoms being present in each ring. Typical examples of useful aromatic-like carbocyclic nuclei comprise benzene, naphthalene, anthracene, etc.
Examples of various liquid precipitation media of the type described hereinabove comprise xylene, mesitylene, ethyl-benzene, n-propylbenzene, n-butylbenzene, isobutylbenzene, n-pentylbenzene, n-hexylbenzene, npropylnaphthalene, butylnaph-thalene, propylanthracene, butylanthracene, and the like. Useful results are obtained using isomers, as well as the normal aliphatic hydrocarbons and mixtures of each thereof. The preferred liquid precipitation media are compounds in which the cyclic nucleus is an aromatic nucleus such as benzene. Especially useful results are obtained where the aromatic substituent is benzene and the alkyl group is selected from those having from 3 to 6 carbon atoms. Preparation of any of the liquid precipitation media useful in the present invention can be by any of the well-known methods.
The precise function of the liquid precipitation medium in the process of the present invention is not entirely understood. Accordingly, it will be understood that the invention should not be limited or restricted to a specific theory of operation. However, it is believed that the liquid precipitation medium aids in the formation of a resinous binder envelope around the particles of dye-mordant salt colorant formed in the process of the invention and also acts to stabilize the resultant liquid developer by effectively preventing the binder envelope from diffusing away from the dye-mordant salt particles. It is believed that at some time after removal of the binder solvent and the solvent(s) for the dye, mordant for the dye, and/or dye-mordant salt, if solvents for these latter materials are used, the particles of dye-mordant salt precipitate which are present in the resultant dope containing the liquid precipitation medium begin to act as nucleation sites for the resinous binder. With the addition of the dope to the liquid carrier this phenomenon appears to be enhanced. It is believed that this is caused by the liquid precipitation medium beginning to diffuse into the liquid carrier with which it is miscible and the simultaneous exposure of the resinous binder to the liquid carrier, the resinous binder being insoluble in the liquid carrier. In any case, shortly after addition of the dope to the liquid carrier, finely divider toner particles having particles of the dye-mordant salt colorant dispersed in a coating of the resinous binder are present in the liquid carrier. Moreover, these toner particles remain stable in the liquid carrier over very long periods of time.
Advantageously, the size of the toner particles prepared according to the present invention may vary within the range of from about 0.05 micron to about microns, preferably within the range of from 0.1 micron to about 2.0 microns. A particular advantage of the present invention is that there is provided a process for preparing relatively small toner particles having a uniform size in the order of about 0.5 micron.
In preparing electrostatic developers according to the process of the present invention, the amounts of the liquid precipitation medium employed may vary over a wide range. Ordinarily, in the admixture of dye, dye mordant, binder, various solvents and liquid precipitation medium, there may be present an amount of the liquid precipitation medium varying from about 0.2 to about 8.0 parts by weight of the liquid precipitation medium for every 1.0 part by weight of the remaining components of the admixture (excluding the weight of the solvents), i.e., the dye, dye mordant and binder components. Much larger amounts of liquid precipitation medium may also be used, although it is unnecessary and generally results in simply adding to the expense of the process. Of course, in those embodiments of the invention where the liquid precipitation medium is also used as the solvent for the polymeric binder, larger amounts of the liquid precipitation medium than those specified above may be usefully employed. However, as noted hreinabove, the solvents employed in the present invention are removed before dispersal of the admixture of dye, dye-mordant, binder and liquid precipitation medium in the carrier liquid of the developer composition. Accordingly, in those instances where large amounts of the liquid precipitation medium are used because of its dual role as a binder solvent and as a liquid precipitation medium, it is preferable to remove a substantial amount of the liquid precipitation medium prior to dispersal of the admixture in the liquid carrier.
Suitable liquid carriers for dispersing the toner particles prepared by the present invention comprise liquid possessing a low dielectric constant less than about 3.0. In order to avoid discharge of a latent electrostatic image, the liquid carrier should have a resistivity of greater than about l0 ohm-centimeters. Liquids which have been found useful include cyclohexane, carbon tetrachloride, mixed halides such as trichlorotrifluoroethane, sold under the trade name Freon l 13 by E. l. du Pont de Nemours & Co., cyclopentane, npentane, n-hexane, paraffinic hydrocarbon such as isoparaffinic hydrocarbon liquids having a boiling point in the range of to C., sold under the trade name Isopar G by the Humble Oil and Refining Co., petroleum distillates, mixtures thereof, etc. In addition to these liquids, certain other liquid vehicles may be used, such as dimethyl polysiloxane.
Solvents for the binder materials used in the process of the present invention include a wide variety of materials. Generally useful solvents include organic solvents which either are water-soluble or have a low boiling point relative to the boiling point of the liquid precipitation medium, i.e., boiling at least about 25 C. below the boiling point of the liquid precipitation medium. These properties, i.e., water solubility or low boiling point, are desirable because solventshaving these properties may be easily removed from the admixture of dye, dye mordant, liquid precipitation medium, binder material and solvent therefor which is employed in the present invention. Thus, water-soluble organic solvents may be removed by continuous water-washing of the aforementioned admixture, and low-boiling organic solvents may be easily removed by air-drying the admixture. When the above-described liquid precipitation medium also functions as the binder solvent, it is desirable to employ a low-boiling liquid so that most of that portion of the liquid serving as a binder solvent may be readily removed by air-drying. In addition, the particular solvent chosen should be substantially chemically inert with respect to the dye, dye mordant, resinous binder and liquid precipitation at least within the temperature range at which the process of the present invention is carried out. Also, the solvent employed should be compatible, i.e., miscible, with the liquid precipitation medium to avoid formation of a multiphase liquid system. Advantageously, the solvent utilized should have little or no adverse effect on particle charge or developer stability.
As suggested hereinabove, in addition to the binder solvents, auxiliary solvents for the dye, dye mordant or dye-mordant salt may be used in the process of the present invention. If so, these solvents should possess properties which are the same as or quite similar to the binder. solvents described immediately above. In addition, these auxiliary solvents should be compatible, i.e., miscible, with both the liquid precipitation medium and the binder solvents. Moreover, these auxiliary solvents should be compatible with the binder material, i.e., incapable of causing the binder to settle out of admixture with the binder solvent, dye, dye mordant and liquid precipitation medium.
Preferred solvents useful in the present invention will, of course, vary also depending on the particular binders, dyes, dye mordants, etc., which are employed. Generally, however useful solvents include (1) lowboiling, water-insoluble organic solvents having a boiling point within a range of from about less than 28 C. to about 150 C-., such as ethyl and butyl acetates, ethyl propionate, butyl alcohol, ethyl formate, nitroethane, etc., and (2) water-soluble solvents, such as methyl isobutyl ketone, B-ethoxy ethyl acetate, B-butoxy-B- ethoxy ethyl acetate, tetrahydrofurfuryl adipate, diethylene glycol monoacetate, B-methoxymethyl acetate, acetonyl acetone, diacetone alcohol, diethylene glycol monomethyl ether, ethylene glycol, dipropylene glycol, acetone, methanol, ethanol, methylethyl ketone, acetonitrile, dimethylformamide, dioxane, etc.
The final liquid developer prepared by the process of the present invention ordinarily has a composition as follows: the toner particles, i.e., the particles comprising dye-mordant salt colorant dispersed in the polymeric binder material, are present in concentrations within the range of from about 0.01 to about 10 percent by weight, the liquid precipitation medium is pres.- ent in a concentration within the range of from about 2 to about 35 percent by weight, and the aliphatic liquid carrier can make up from about 45 to about 98 percent by weight.
In addition, the electrostatic-charge polarity of the toner particles of the present invention can be enhanced or altered by the addition of suitable charge control agents, if so desired. A variety of materials can be used as charge control agents. Illustrative of suitable charge agents would be the polyoxyethylated alkyl surfactants such as polyoxyethylated alkylamine, polyoxyethylene palmitate, polyoxyethylene stearate, etc. Other useful materials are magnesium and heavier metal soaps of fatty and aromatic acids as described in Beyer, US. Pat. No. 3,417,019. Useful metal soaps include cobalt naphthenate, magnesium naphthenate and manganese naphthenate, zinc resinate, calcium naphthenate, zinc linoleate, aluminum resinate, isopropyltitanium stearate, aluminum stearate, and others, many of which are also described in US. Pat. No. 3,259,581. Typically, the amount of such materials used is less than about 2 percent by weight based on the weight of toner. In certain instances, the resinous binder per se can function as the charge control agent, as can the colorant.
The following examples further illustrate preferred embodimentsof the invention. I
EXAMPLE 1 A stock solution of polymer is prepared as follows:
A -gram quantity of Beckosol 7 (a soya-modified alkyd resin containing 42 percent phthalic anhydride and 41 percent soya fatty acids, made by the Reichold Chemical Co.) is dissolved in a mixture of 75 ml. of methanol and 75 m1. of methylethyl ketone by stirring the mixture of resins and solvents for 2% hours at room temperature.
Solution A: To a 22-gram quantity of the stock solution (containing 4 grams of resin solids) is added 1.0 gram of a basic magenta dye, Astraphloxine FF (Color lndex 48070, General Dyestuffs Co.) or Calcozine Red BG (Color lndex 48070, American Cyanamid Co.). The dye dissolves readily.
Solution B: To another 22-gram portion of the stock solution are added the following ingredients:
phosphomolybdic acid (dye mordant) 2.0 g.
methanol (solvent) 10 ml.
methylethyl ketone (solvent) 10 ml.
Solvesso 100 (solvent) 10 ml.
Solvesso 100 is an essentially aromatic petroleum hydrocarbon made by Humble Oil and Refining Co.; flash point, F.; boiling range, 315-350 F percent aromatics, 96 percent of total including xylenes 9 percent, monoalkyl benzenes 16 percent, dialkyl benzenes 36 percent, trialkyl benzene 39 percent; aliphatics 4 percent. The resultant solution is essentially clear.
Solution B is quickly added with vigorous stirring to Solution A. There results an excellent dispersion of the precipitated pigment formed by the mordanting of the dye in Solution A by the acid in Solution B. The dispersion is formed in the polymer solution. A 30-gram portion of Solvesso 100 is then stirred in to serve as the liquid precipitation medium.
To remove most of the above-noted solvents from the pigmented polymer solution, the above-described mix ture is dumped into 400 ml. of water. Oily globules result. Most of the water is decanted, and the remaining water is removed by running through a filter paper. The resulting dope contains the liquid precipitation medium and polymeric binder together with colorant particles having an average size of about 0.8 micron, with some very loose agglomerates of up to 6 microns in size. These are readily broken up.
The developer is then made up by adding dropwise, with stirring in a Polytron blender, 2.5 g. of the dope to 250 ml. of a liquid carrier of lsopar G containing 0.2 g. cobalt naphthenate and 0.45 g. of a 1.5 percent by weight solution of aluminum stearate in xylene and shearing for 3 minutes after addition is complete. The resultant liquid developer is found to contain toner particles having an average size of about 0.8 micron. These particles contain the dye-mordant salt colorant dispersed in the Beckosol 7 polymeric binder.
The toner particles are positively charged.
EXAMPLE 2 The procedure of Example 1 is followed using 0.56 gram of an acid dye, Brilliant Alizarine Light Red B (Sandoz, Color Index acid Red 58), in 22 grams of the stock polymer solution for Solution A, and 0.29 gram of triphenylguanidine as a mordant in 22 grams of the stock solution for Solution B. Recovery and developer preparation are carried out as in Example 1. The toner particles are positively charged.
EXAMPLE 3 This is a variation on the procedure of Example 1 which requires no washing step to remove the solvents and recover the dispersion of colorant particles in a dope containing the liquid precipitation medium and the polymeric binder.
A 0.5 gram quantity of the dye-mordant salt, triphenylguanidine salt of copper phthalocyanine tetrasulfonic acid, is dissolved in ml. of methanol and 10 ml. of methylethyl ketone. To this solution are added 22 grams of the stock polymer solution of Example 1. To the mixture are then added a 10-ml. quantity of S01- vesso 100 as a solvent and a 50 mg. quantity of surfactant (Tween 85). A clear dope without visible particles results. The dope is placed in an evaporating dish and allowed to stand for 24 hours or until all that remains is a dry powder. This is readily taken up in g. of S01- vesso 100, which is now used as the liquid precipitation medium.
A liquid developer is made in the same manner indicated previously. The final toner particles contained therein are under 0.5 micron in size and very uniform. The toner particles are positively charged.
EXAMPLE 4 In this example, the same liquid serves both as the binder solvent and as the liquid precipitation medium. A stock polymer solution is prepared which contains the following ingredients:
Beckosol 7 (resinous binder) 27.0 g.
Amberol STI37 (resinous binder) 81.0 g.
Solvesso 100 (solvent and precipitation medium) A dye solution is prepared by dissolving 0.5 g. of a dye-mordant salt of phosphomolybdic acid complex of Astraphloxine FF in 3.0 ml. of dimethyl sulfoxide. The dye solution, to which also has been added 0.5 g. of Strodex V-8 as a surfactant, is added to 19.0 g. of the above-described stock polymer solution, with stirring, to yield a dope containing a fine dispersion of the pigment; about 16 g. of excess Solvesso 100 are removed by air-drying the dope. The resultant dope is then added to a liquid carrier of Isopar G as described in Example 1 to form a liquid developer composition containing toner particles having the dye-mordant salt dispersed in the Beckosol 7 and Amberol ST137 resin mixture.
Although the invention has been described in considerable detail with particular reference to certain preferred embodiments thereof, variations and modifications can be effected within the spirit and scope of the invention.
1 claim:
1. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from said mordant, (2) an organic solvent for said binder and (3) an organic liquid precipitation medium which is capable of dissolving or forming a colloidal suspension of the polymeric binder and which is miscible with the liquid carrier; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially unifonn size within the range of from about 0.05 microns to about 20 microns and comprising particulate dye-mordant salt precipitate dispersed in the polymeric binder.
2. The process according to claim 1 wherein admixture of the dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquid carrier.
3. The process according to claim 1 wherein the same liquid is employed as the liquid precipitation medium and the binder solvent and wherein only a portion of this liquid is removed during removal of said binder solvent.
4. The process according to claim 1 wherein admixture of the dye and mordant is accomplished by forming a solution of a dye-mordant salt in an organic solvent for said dye-mordant salt and mixing said dyemordant salt solution with a mixture of the polymeric binder, the solvent therefor and the liquid precipitation medium.
5. The process according to claim 4 wherein said mixture of polymeric binder, solvent therefor and liquid precipitation medium also contains a surfactant which is soluble in the liquid carrier.
6. The process according to claim 1 wherein admixture of the dye and mordant is accomplished by dissolving the dye in a first mixture of polymeric binder and solvent therefor, dissolving the mordant for the dye in a second mixture of polymeric binder and a solvent therefor, and mixing said first mixture with said second mixture in the presence of the liquid precipitation medium.
7. The process according to claim 6 wherein the mixture of said first mixture and said second mixture occurs in the presence of the liquid precipitation medium and also in the presence of a surfactant which is soluble in the liquid carrier.
8. The process according to claim 6 wherein said second mixture of polymeric binder and liquid solvent therefor also contains a surfactant which is soluble in the liquid carrier.
9. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing an acid dye and a basic mordant for said dye in the presence of (1) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dyemordant salt precipitate dispersed in the polymeric binder; said acid dye being selected from the group consisting of Brilliant Alizarine Light Red B. C.I. acid Red 58; copper phthalocyanine tetrasodium sulfonate, CI. 74220; 4,8-disu1fonaphthyl-2-azo-4-(3-methyl-1-psulfophenyl-S-pyrazolone); anthraquinone Blue B, CI. 63010; and Solantine Pink 4 BL, C.l. 25380; said basic mordant being selected from the group consisting of triphenylguanidine, di-o-tolylquinidine, a-naphthylamine, dioctylamine and N,N-dimethyldodecylamine.
10. The process according to claim 9 wherein admixture of the acidic dye and basic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
11. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a basic dye and an acidic mordant for said dye in the presence of l) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dyemordant salt precipitate dispersed in the polymeric binder; said basic dye being selected from the group consisting of Astraphloxine FF, CI. 48070; Rhodamine B, C]. 45170; Rhodamine 66, CI. 45160; methylene Blue, CI. 52015; Toluidine Blue, CI. 52040; and Auramine G, C]. 41005; said acidic mordant being se lected from the group consisting of phosphotungstic acid, p'hosphomolybdic acid, tannic acid, tungstosilicic acid and molybdosilicic acid.
12. The process according to claim 11 wherein admixture of the basic dye and the acidic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphos'phoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
13. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from sad mordant, (2) an organic solvent for said binder, and (3) a first amount of an organic liquid precipitation medium which is capable of dissolving or forming a colloidal suspension of the polymeric binder and which is miscible with the liquid carrier; removing the solvent for said binder and the liquid precipitation medium to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said organic liquid precipitation medium sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.05 microns to about 20 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder.
14. The process according to claim 13 wherein admixture of a dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquidcarrier.
15. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 10" ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of l) a polymeric binder comprising a material separate and distinct from said mordant, (2) an organic solvent for said binder, and (3) a first amount of an alkylated aromatic hydrocarbon; removing the solvent for said binder and the alkylated aromatic hydrocarbon to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said alkylated aromatic hydrocarbon sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.05 microns to about 20 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder.
16. The process according to claim 15 wherein admixture of the dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquid carrier.
Claims (15)
- 2. The process according to claim 1 wherein admixture of the dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquid carrier.
- 3. The process according to claim 1 wherein the same liquid is employed as the liquid precipitation medium and the binder solvent and wherein only a portion of this liquid is removed during removal of said binder solvent.
- 4. The process according to claim 1 wherein admixture of the dye and mordant is accomplished by forming a solution of a dye-mordant salt in an organic solvent for said dye-mordant salt and mixing said dye-mordant salt solution with a mixture of the polymeric binder, the solvent therefor and the liquid precipitation medium.
- 5. The process according to claim 4 wherein said mixture of polymeric binder, solvent therefor and liquid precipitation medium also contains a surfactant which is soluble in the liquid carrier.
- 6. The process according to claim 1 wherein admixture of the dye and mordant is accomplished by dissolving the dye in a first mixture of polymeric binder and solvent therefor, dissolving the mordant for the dye in a second mixture of polymeric binder and a solvent therefor, and mixing said first mixture with said second mixture in the presence of the liquid precipitation medium.
- 7. The process according to claim 6 wherein the mixture of said first mixture and said second mixture occurs in the presence of the liquid precipitation medium and also in the presence of a surfactant which is soluble in the liquid carrier.
- 8. The process according to claim 6 wherein said second mixture of polymeric binder and liquid solvent therefor also contains a surfactant which is soluble in the liquid carrier.
- 9. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 1010 ohm-cm. which comprises admixing an acid dye and a basic mordant for said dye in the presence of (1) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder; said acid dye being selected from the group consisting of Brilliant Alizarine Light Red B. C.I. acid Red 58; copper phthalocyanine tetrasodium sulfonate, C.I. 74220; 4,8-disulfonaphthyl-2-azo-4-(3-methyl-1-p-sulfophenyl-5-pyrazolone); anthraquinone Blue B, C.I. 63010; and Solantine Pink 4 BL, C.I. 25380; said basic mordant being selected from the group consisting of triphenylguanidine, di-o-tolylquinidine, Alpha -naphthylamine, dioctylamine and N,N-dimethyldodecylamine.
- 10. The process according to clAim 9 wherein admixture of the acidic dye and basic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- 11. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 1010 ohm-cm. which comprises admixing a basic dye and an acidic mordant for said dye in the presence of (1) a polymeric binder, (2) an organic solvent for said binder and (3) an alkylated aromatic hydrocarbon; removing the solvent for said binder; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.1 microns to about 2.0 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder; said basic dye being selected from the group consisting of Astraphloxine FF, C.I. 48070; Rhodamine B, C.I. 45170; Rhodamine 6G, C.I. 45160; methylene Blue, C.I. 52015; Toluidine Blue, C.I. 52040; and Auramine G, C.I. 41005; said acidic mordant being selected from the group consisting of phosphotungstic acid, phosphomolybdic acid, tannic acid, tungstosilicic acid and molybdosilicic acid.
- 12. The process according to claim 11 wherein admixture of the basic dye and the acidic mordant occurs in the presence of a surfactant selected from the group consisting of a polyphosphoric co-ester of an alkylphenol and a polyoxyethylene sorbitan fatty ester, polyoxyethylene sorbitan trioleate, polyoxyethylene tridecylphenol, polyoxyethylene dodecylphenol and a fatty alkanolamide.
- 13. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 1010 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of (1) a polymeric binder comprising a material separate and distinct from sad mordant, (2) an organic solvent for said binder, and (3) a first amount of an organic liquid precipitation medium which is capable of dissolving or forming a colloidal suspension of the polymeric binder and which is miscible with the liquid carrier; removing the solvent for said binder and the liquid precipitation medium to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said organic liquid precipitation medium sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.05 microns to about 20 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder.
- 14. The process according to claim 13 wherein admixture of a dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquid carrier.
- 15. A process for making electrophotographic developers having toner particles dispersed in an organic liquid carrier having a dielectric constant less than about 3.0 and a resistivity greater than about 1010 ohm-cm. which comprises admixing a dye and a mordant for said dye in the presence of (1) a polymeric binder comprising a material separate and distinct from said mordant, (2) an organic solvent for said binder, and (3) a first amount of an alkylated aromatic hyDrocarbon; removing the solvent for said binder and the alkylated aromatic hydrocarbon to form a dry powder admixture of said binder, dye, and mordant for said dye; admixing said dry powder in a second amount of said alkylated aromatic hydrocarbon sufficient to form a dope thereof; and admixing the resultant dope with the liquid carrier to form a substantially stable dispersion of finely-divided toner particles in the liquid carrier, said toner particles having a substantially uniform size within the range of from about 0.05 microns to about 20 microns and comprising a particulate dye-mordant salt precipitate dispersed in the polymeric binder.
- 16. The process according to claim 15 wherein admixture of the dye and mordant for the dye occurs in the presence of a surfactant which is soluble in the liquid carrier.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13051971A | 1971-04-01 | 1971-04-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3779924A true US3779924A (en) | 1973-12-18 |
Family
ID=22445057
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00130519A Expired - Lifetime US3779924A (en) | 1971-04-01 | 1971-04-01 | Process for preparing electrophotographic liquid developing compositions |
Country Status (6)
Country | Link |
---|---|
US (1) | US3779924A (en) |
BE (1) | BE781346A (en) |
CA (1) | CA964094A (en) |
DE (1) | DE2212495B2 (en) |
FR (1) | FR2136065A5 (en) |
GB (1) | GB1348879A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3954640A (en) * | 1973-06-27 | 1976-05-04 | Xerox Corporation | Electrostatic printing inks |
US4363863A (en) * | 1979-12-13 | 1982-12-14 | Nashua Corporation | Liquid negative developer compositions for electrostatic copying containing polymeric charge control agent |
US4374918A (en) * | 1981-09-16 | 1983-02-22 | Nashua Corporation | Thermally stable liquid negative developer |
EP0272649A2 (en) * | 1986-12-23 | 1988-06-29 | Kao Corporation | Spherical fine particulate pigment and process for preparing the same |
US4865937A (en) * | 1988-09-26 | 1989-09-12 | Eastman Kodak Company | Method of making fluorescent toner |
US4879197A (en) * | 1985-04-12 | 1989-11-07 | Mitsubishi Paper Mills, Ltd. | Method of developing electronic photograph with liquid developer and cleaning excess thereof |
US5069995A (en) * | 1989-05-23 | 1991-12-03 | Commtech International Management Corporation | Stain elimination in consecutive color toning |
US5153090A (en) * | 1990-06-28 | 1992-10-06 | Commtech International Management Corporation | Charge directors for use in electrophotographic compositions and processes |
US5952048A (en) * | 1994-06-17 | 1999-09-14 | Ricoh Company, Ltd. | Ink composition and recording method using the same |
US10168629B2 (en) | 2015-01-19 | 2019-01-01 | Hp Indigo B.V. | Liquid electrophotographic varnish composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1155011B (en) * | 1982-01-11 | 1987-01-21 | Savin Corp | METHOD TO INCREASE THE DENSITY OF ELECTROPHOTOGRAPHIC IMAGES DEVELOPED THROUGH LIQUID DEVELOPER WITH IMAGE TRANSFER THROUGH AN AIR SPACE AND DEVELOPMENT COMPOSITION TO BE USED IN SUCH METHOD |
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US2118432A (en) * | 1935-01-14 | 1938-05-24 | Interchem Corp | Coloring medium |
US2589953A (en) * | 1943-06-24 | 1952-03-18 | Calico Printers Ass Ltd | Dyeing of cellulosic textile materials by forming lakes of basic dyes in the fibers |
US2671971A (en) * | 1953-01-28 | 1954-03-16 | Harold T Ackerman | Shoe spinner attachment device |
US3078231A (en) * | 1959-05-13 | 1963-02-19 | Commw Of Australia | Controlled developer for use in electro-photography and electro-radiography |
US3135695A (en) * | 1961-02-20 | 1964-06-02 | Eastman Kodak Co | Liquid developers for electrostatic photography |
US3173878A (en) * | 1960-02-26 | 1965-03-16 | Ibm | Process of making microcapsules |
US3190850A (en) * | 1954-10-15 | 1965-06-22 | Jr Oliver W Burke | Vinylic filler pigments |
US3271148A (en) * | 1962-07-19 | 1966-09-06 | Eastman Kodak Co | Mordanting of acid dyes |
US3336155A (en) * | 1964-01-15 | 1967-08-15 | Ncr Co | Process of coating particles with a polymer |
US3387916A (en) * | 1964-06-23 | 1968-06-11 | Du Pont | Heteropoly acid coloration medium and process |
US3391014A (en) * | 1964-04-27 | 1968-07-02 | Harris Intertype Corp | Liquid development of electrostatic images |
-
1971
- 1971-04-01 US US00130519A patent/US3779924A/en not_active Expired - Lifetime
-
1972
- 1972-03-06 CA CA136,286A patent/CA964094A/en not_active Expired
- 1972-03-15 DE DE19722212495 patent/DE2212495B2/en active Granted
- 1972-03-28 FR FR7210781A patent/FR2136065A5/fr not_active Expired
- 1972-03-28 BE BE781346A patent/BE781346A/en unknown
- 1972-03-30 GB GB1509472A patent/GB1348879A/en not_active Expired
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2118432A (en) * | 1935-01-14 | 1938-05-24 | Interchem Corp | Coloring medium |
US2589953A (en) * | 1943-06-24 | 1952-03-18 | Calico Printers Ass Ltd | Dyeing of cellulosic textile materials by forming lakes of basic dyes in the fibers |
US2671971A (en) * | 1953-01-28 | 1954-03-16 | Harold T Ackerman | Shoe spinner attachment device |
US3190850A (en) * | 1954-10-15 | 1965-06-22 | Jr Oliver W Burke | Vinylic filler pigments |
US3078231A (en) * | 1959-05-13 | 1963-02-19 | Commw Of Australia | Controlled developer for use in electro-photography and electro-radiography |
US3173878A (en) * | 1960-02-26 | 1965-03-16 | Ibm | Process of making microcapsules |
US3135695A (en) * | 1961-02-20 | 1964-06-02 | Eastman Kodak Co | Liquid developers for electrostatic photography |
US3271148A (en) * | 1962-07-19 | 1966-09-06 | Eastman Kodak Co | Mordanting of acid dyes |
US3336155A (en) * | 1964-01-15 | 1967-08-15 | Ncr Co | Process of coating particles with a polymer |
US3391014A (en) * | 1964-04-27 | 1968-07-02 | Harris Intertype Corp | Liquid development of electrostatic images |
US3387916A (en) * | 1964-06-23 | 1968-06-11 | Du Pont | Heteropoly acid coloration medium and process |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3954640A (en) * | 1973-06-27 | 1976-05-04 | Xerox Corporation | Electrostatic printing inks |
US4363863A (en) * | 1979-12-13 | 1982-12-14 | Nashua Corporation | Liquid negative developer compositions for electrostatic copying containing polymeric charge control agent |
US4374918A (en) * | 1981-09-16 | 1983-02-22 | Nashua Corporation | Thermally stable liquid negative developer |
US4879197A (en) * | 1985-04-12 | 1989-11-07 | Mitsubishi Paper Mills, Ltd. | Method of developing electronic photograph with liquid developer and cleaning excess thereof |
EP0272649A2 (en) * | 1986-12-23 | 1988-06-29 | Kao Corporation | Spherical fine particulate pigment and process for preparing the same |
EP0272649A3 (en) * | 1986-12-23 | 1991-11-13 | Kao Corporation | Spherical fine particulate pigment and process for preparing the same |
US4865937A (en) * | 1988-09-26 | 1989-09-12 | Eastman Kodak Company | Method of making fluorescent toner |
US5069995A (en) * | 1989-05-23 | 1991-12-03 | Commtech International Management Corporation | Stain elimination in consecutive color toning |
US5153090A (en) * | 1990-06-28 | 1992-10-06 | Commtech International Management Corporation | Charge directors for use in electrophotographic compositions and processes |
US5952048A (en) * | 1994-06-17 | 1999-09-14 | Ricoh Company, Ltd. | Ink composition and recording method using the same |
US10168629B2 (en) | 2015-01-19 | 2019-01-01 | Hp Indigo B.V. | Liquid electrophotographic varnish composition |
Also Published As
Publication number | Publication date |
---|---|
FR2136065A5 (en) | 1972-12-22 |
GB1348879A (en) | 1974-03-27 |
BE781346A (en) | 1972-07-17 |
DE2212495A1 (en) | 1972-10-12 |
DE2212495B2 (en) | 1976-08-12 |
CA964094A (en) | 1975-03-11 |
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