US3737386A - Solvent based detergent - Google Patents
Solvent based detergent Download PDFInfo
- Publication number
- US3737386A US3737386A US00060924A US3737386DA US3737386A US 3737386 A US3737386 A US 3737386A US 00060924 A US00060924 A US 00060924A US 3737386D A US3737386D A US 3737386DA US 3737386 A US3737386 A US 3737386A
- Authority
- US
- United States
- Prior art keywords
- weight
- methylene chloride
- composition
- isopropanol
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
Definitions
- detergents of the known prior art have proved to be insufficient, particularly for cleaning construction units e.g. tiles in service-stations, tunnels, railway stations and similar buildings, soiled concrete areas and other cemented surfaces.
- the dirt on walls and floors of such buildings consists of tars, greases, oils, rosins, resins, asphaltenes, set paints and varnishes as well as of mechanical impurities.
- a detergent composition comprising in combination several solvents which can be applied even at high levels of impurity, i.e. which exhibit good solving properties and which make it possible to wash away the lubricants composed of dirt (tars, greases, oils, rosins, resins, etc.).
- the new detergents are liquid mixtures which can be mixed with water and consist of:
- esters methyl acetate, propyl acetates and butyl acetates, as well as the corresponding propionates and butyrates including ethyl esters; as ketones: diethyl, methyl propyl and isomeric ethyl butyl ketones;
- (D) as anionic surface active agents sulphates and ether sulphates of fatty alcohols, acyl sulphonates, aryl alkyl sulphonates and alkyl aryl sulphonates, ethylene oxide adducts, e.g. sodium lauryl sulphates, lauryl alcohol sulfuric acid ester and triethanolamine salts of ether sulphates of fat alcohols.
- Test l.-Test composition without a surface active substance The test composition had the following ingredients:
- Test 2 composition without chlorinated hydrocarbon The mixture had the following ingredients:
- EXAMPLE 1 The tiles to be cleaned were soiled with the above mentioned lubricant forming dirt composition and submitted to an ageing process of one year. -By means of a cleaning cloth soaked with the above mentioned detergent an area of tiles of 1 m? was cleaned and rinsed with water in '30 sec. time. This detergency power 30 seconds could be considered as very good.
- compositions with considerably changing concentrations of the ingredients were examined, i.e. compositions with a considerably higher or lower amount of methylene chloride, methyl ethyl ketone, ethyl acetate, surface active substances and alcohols according to Examples .1 to 5.
- TEST COMPARISON REPORT (a) varnish of a polyacrylic resin (b) a mixed styrene butadiene polymer (c) a dispersion of polyvinyl acetate (d) lignite tar (e) motor oil recovered from waste oils and fat and submitted to an ageing process, comprising the following steps: for 12 hours the tiles were dryed by infrared light and aerated and then for 12 hours submitted to a relative humidity of 65% at 20 C. The prepared tiles were then treated with each 250 g. of the detergent in the composition of the invention and of the fluid detergent known from the German published patent application 1,200,460. In the examples which follow, after 5 minutes time we tried to remove the impurities with water. Out of the known detergents were applied those of Examples 1 (with perchloroethylene), 2 and 6 of the German published patent 1,200,460.
- Example 1 of the German patent contains parts by weight of carbon tetrachloride or percholorethylene and 20 parts by weight of a 80% technical alkyl benzene sulfonic acid, neutralized with 15 parts by weight of crude pyridine.
- Example 2 of the German patent contains 2320 parts by weight of perchloroethylene, parts by Weight of a sulfated polyglycol ether of fat alcohol and 660 parts by weight of the above mentioned alkylbenzene sulfonic acid neutralized with 330 parts by weight of crude pyridine and parts by weight of morpholine.
- Example -6 of the German patent contains 2600 parts by weight of decylphenolepolyglycolether and 390 parts by Weight of a 80% dibutylnaphthalenesulfonic acid, which was neutralized with 100 parts by Weight of pyridine.
- compositions were capable of solving only oils (e) and tars (d); only these tars and fats could be removed in the form of aqueous emulsions; varnishes i.e. resins (a), (b) and (c) remained, however, unchanged and could not be removed.
- varnishes i.e. resins (a), (b) and (c) remained, however, unchanged and could not be removed.
- the known detergents which were used for comparison are effective at solving oil and fat but have no or only minor solving efficiency to solve varnish, paint and resin.
- the detergents of the present invention removed varnish, paint and resin easily.
- the detergents of the present invention are universal cleansing agents.
- a solvent based detergent composition that is miscible with water consisting essentially of (A) 10 to 25% by weight of liquid lower aliphatic chlorinated hydrocarbons,
- (B) is methyl ethyl ketone or ethyl acetate
- (C) is isopropanol, propanol or butanol and (D) is an anionic surface active agent.
- a detergent composition of claim 1 wherein said chlorinated hydrocarbons are selected from the group consisting of monochloromethane, trichloromethane, tetrachloromethane, dichloroethane, trichloroethaue and tetrachloroethane.
- esters (B) are selected from the group consisting of methyl acetate, propyl acetates, butyl acetates, methyl propionates, ethyl propionates, propyl propionates, butyl propionates, methyl butyrates, ethyl butyrates, propyl butyrates and butyl butyrates.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl propyl ketone, (C) is propanol and (D) is ammonium salt of sulphuric acid ester of lauryl alcohol.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is diethyl ketone and ethyl acetate, (C) is butanol and (D) is monoethanolamine salt of the sulphonated coconut fatty alcohols ether.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl ethyl ketone and propyl acetate, (C) is ethanol and (D) is triethanolamine salt of the lauryl alcohol sulphuric acid ester.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl ethyl ketone and ethyl acetate, (C) is isopropanol and (D) is sodium lauryl sulphate.
Abstract
THE INVENTION RELATES TO A DETERGENT USED PARTICULARLY IN INDUSTRY ON THE BASE OF A COMBINATION OF DIFFERENT ORGANIC SOLVENTS IN ADMIXTURE WITH CLEANING INTENSIFIERS.
Description
United States Patent 3,737,386 SOLVENT BASED DETERGENT Richard Geiss, 8875 Lnsshof, Olfingen (Danube), Germany, and Rolf Quarch, St. Johannisstrasse 37, Weissenhorn, Germany No Drawing. Filed Aug. 4, 1970, Ser. No. 60,924 Int. Cl. C09d 9/04; C11d 7/22, 7/50 US. Cl. 252-162 12 Claims ABSTRACT OF THE DISCLOSURE The invention relates to a detergent used particularly in industry on the base of a combination of different organic solvents in admixture with cleansing intensifiers.
It has long been known to utilize a number of different mixtures of solvents for industrial use, in particular combinations of trichloroethylene or perchloroethylene in admixture with benzines or aromatics such as benzene, toluene and xylene. In general these substances are used for removing fat and varnish.
For several cleaning processes, however, detergents of the known prior art have proved to be insufficient, particularly for cleaning construction units e.g. tiles in service-stations, tunnels, railway stations and similar buildings, soiled concrete areas and other cemented surfaces.
The dirt on walls and floors of such buildings consists of tars, greases, oils, rosins, resins, asphaltenes, set paints and varnishes as well as of mechanical impurities.
It is impossible to solve such dirt accumulations and wash them away with water immediately without a long residence time and without applying mechanical power such as scrubbing and rubbing. The same is true with soiled tools, eg brushes.
Accordingly, it is an aim of the present invention to provide a detergent composition comprising in combination several solvents which can be applied even at high levels of impurity, i.e. which exhibit good solving properties and which make it possible to wash away the lubricants composed of dirt (tars, greases, oils, rosins, resins, etc.).
The new detergents are liquid mixtures which can be mixed with water and consist of:
(A) 10 to 25% by weight liquid aliphatic chlorinated hydrocarbons,
(B) 25 to 40% by weight liquid lower aliphatic ketones and/or lower aliphatic esters,
(C) 40 to 50% by weight water-soluble alkanols 2 to carbon atoms and (D) 1 to by weight surface active agents.
Preferred use is made of mixtures of components of the groups consisting of (A) methylene chloride, trichloroethylene, and perchloroethylene,
(B) methyl ethyl ketone and ethyl acetate,
(C) isopropanol, propanol and butanol and (D) an anionic surface active agent.
Additionally, the following substances individually or in admixture with other representatives of the same groups may be used as components of the groups consisting of (A) as chlorinated hydrocarbons: monochloromethane,
trichloromethane and tetrachloromethane, 1,1- and l,
Z-dichloroethanes, 1,1,1- and 1,1,2-trichloroethanes,
and 1,1,1,2- and l,l,2,2-tetrachloroethanes;
(B) as esters: methyl acetate, propyl acetates and butyl acetates, as well as the corresponding propionates and butyrates including ethyl esters; as ketones: diethyl, methyl propyl and isomeric ethyl butyl ketones;
Patented June 5, 1973 (C) as alkanols: ethanol and amyl alcohols;
(D) as anionic surface active agents: sulphates and ether sulphates of fatty alcohols, acyl sulphonates, aryl alkyl sulphonates and alkyl aryl sulphonates, ethylene oxide adducts, e.g. sodium lauryl sulphates, lauryl alcohol sulfuric acid ester and triethanolamine salts of ether sulphates of fat alcohols.
Test l.-Test composition without a surface active substance The test composition had the following ingredients:
Percent Methylene chloride 10 Methyl ethyl ketone 20 Ethyl acetate 20 Isopropanol 50 In the absence of a surface active substance the lubricants formed by dirt and solvent from the test composition could not be washed away with water from the soiled areas or could not be washed away completely. Dirtstripes remained which could be removed only after various applications of the solvent while rubbing or by means of other mechanical powers.
Test 2.-Test composition without chlorinated hydrocarbon The mixture had the following ingredients:
Percent Methyl ethyl ketone 25 Ethyl acetate 25 Isopropanol 40 Surface active substance 10 In the absence of a chlorinated hydrocarbon the mixture of solvents required a prolonged residence time to remove the dirt lubricant, ie the total cleaning of l m? of soiled area required more than 3 minutes time and the application of mechanical power. Thus, it can be stated that the detergency power is rather high but that the dirt lubricant solving time is far too long, especially in view of the great areas to be cleaned.
Further tests showed that aliphatic, lower ketones, from which acetone is known as a solvent for certain resins, exhibit a much stronger and quicker solving efliciency for resins in admixture with the other ingredients (A), (B), and (D) than individual ketones. This synergetic effect was very much surprising and unpresumable.
EXAMPLE 1 The tiles to be cleaned were soiled with the above mentioned lubricant forming dirt composition and submitted to an ageing process of one year. -By means of a cleaning cloth soaked with the above mentioned detergent an area of tiles of 1 m? was cleaned and rinsed with water in '30 sec. time. This detergency power 30 seconds could be considered as very good.
A similar very good detergency power was exhibited by the following combinations according to Examples 2 to 5.
Ammonium salt of the sulphuric acid ester of lauryl alcohol 10 EXAMPLE 3 Percent Methylene chloride 25 Diethyl ketone 12.5 Ethyl acetate 12.5 Butanol 40 Monoethanolamine salt of the sulphonated coconut fatty alcohols ether 10 EXAMPLE 4 Percent Methylene chloride 10 Methyl ethyl ketone 20 Propyl acetate 20 Ethanol 40 Triethanolamine salt of the lauryl alcohol sulphuric acid ester 10 EXAMPLE 5 Percent Methylene chloride l Methyl ethyl ketone 20 Ethyl acetate 20 Isopropanol 40 Sodium lauryl sulphate 10 The results obtained in Examples 1 to could be considered as very good: the joints of the cleaned tiles did not show any changes and the lustre of the tiles remained unchanged. The maximum allowable vapour concentration (in p.p.m. or g./m. of the detergent according to the invention is so high that they can be used without any risk for the operating safety.
In the following Examples 6 and 7 the detergency power of combinations including perchloroethylene or trichloroethylene was examined. For this end methylene chloride from the composition according to Example 5 was substituted by perchloroethylene or trichloroethylene. This composition required a longer residence time, the detergency power of the mixture, however, can be considered as good.
showed a good detergency power, required, however, a much longer residence time than the compositions including methylene chloride according to the Examples 1 to 5.
EXAMPLE 7 A similar composition which had the following ingredients showed the same results:
Percent Perchloroethylene 10 Methyl ethyl ketone 20 Ethyl acetate 20 Isopropanol 40 Sodium lauryl sulphate 10 Finally compositions with considerably changing concentrations of the ingredients were examined, i.e. compositions with a considerably higher or lower amount of methylene chloride, methyl ethyl ketone, ethyl acetate, surface active substances and alcohols according to Examples .1 to 5. It was observed that within a great range dirt lubricant solubility is to be called good or very good, but that theresidence time of the lubricants soaked by the solvent increases with a decreasing amount of methylene chloride, whereas the Wettability of the dirty places increases with a rising amount of surface active substances.
TEST COMPARISON REPORT (a) varnish of a polyacrylic resin (b) a mixed styrene butadiene polymer (c) a dispersion of polyvinyl acetate (d) lignite tar (e) motor oil recovered from waste oils and fat and submitted to an ageing process, comprising the following steps: for 12 hours the tiles were dryed by infrared light and aerated and then for 12 hours submitted to a relative humidity of 65% at 20 C. The prepared tiles were then treated with each 250 g. of the detergent in the composition of the invention and of the fluid detergent known from the German published patent application 1,200,460. In the examples which follow, after 5 minutes time we tried to remove the impurities with water. Out of the known detergents were applied those of Examples 1 (with perchloroethylene), 2 and 6 of the German published patent 1,200,460.
The composition of Example 1 of the German patent contains parts by weight of carbon tetrachloride or percholorethylene and 20 parts by weight of a 80% technical alkyl benzene sulfonic acid, neutralized with 15 parts by weight of crude pyridine.
The composition of. Example 2 of the German patent contains 2320 parts by weight of perchloroethylene, parts by Weight of a sulfated polyglycol ether of fat alcohol and 660 parts by weight of the above mentioned alkylbenzene sulfonic acid neutralized with 330 parts by weight of crude pyridine and parts by weight of morpholine.
The composition of Example -6 of the German patent contains 2600 parts by weight of decylphenolepolyglycolether and 390 parts by Weight of a 80% dibutylnaphthalenesulfonic acid, which was neutralized with 100 parts by Weight of pyridine.
These compositions were capable of solving only oils (e) and tars (d); only these tars and fats could be removed in the form of aqueous emulsions; varnishes i.e. resins (a), (b) and (c) remained, however, unchanged and could not be removed. For comparison the following mixtures in the composition of the invention were applied:
G. Penchloroethylene 800 Methylene chloride 80 Methyl ethyl ketone 40 Isopropanol 30 Sodium lauryl sulphate 200 Percent by weight Methylene chloride 25 Ethyl acetate 25 Isopropanol 40 Sodium lauryl sulphate l Percent by weight Methylene chloride 15.5 Butanone 37.5 Isopropanol 40 Sodium lauryl sulphate 7 Percent by weight Methylene chloride 12 Methyl ethyl ketone 25 Isopropanol 50 Sodium lauryl sulphate 13 In the four cases all impurities spread on the tiles could be solved quickly and removed easily with water.
The same results were obtained when cleaning spatulas, brushes etc. soiled with oil, tar, paint and varnish. In most of the cases there was required a residence time of only 1 minute; set residues of resin, varnish and paint required depending on the hardening rate a longer residence time. The detergents of the German patent 1,200,460 and liquid hydrocarbon-based cleansing agents proved to be insufficient.
Therefore it can be seen that in general the known detergents which were used for comparison are effective at solving oil and fat but have no or only minor solving efficiency to solve varnish, paint and resin. In contrast the detergents of the present invention removed varnish, paint and resin easily. Thus, the detergents of the present invention are universal cleansing agents.
What is claimed is:
1. A solvent based detergent composition that is miscible with water consisting essentially of (A) 10 to 25% by weight of liquid lower aliphatic chlorinated hydrocarbons,
(B) 25 to 40% by weight lower aliphatic ketones and/ or lower aliphatic esters,
(C) 40 to 50% by weight water-soluble alkanols having 2 to carbon atoms and (D) 1 to by weight anionic surface active agents.
2. A detergent composition of claim 1 wherein said component (A) is methylene chloride, tn'chloroethylene or perchloroethylene,
(B) is methyl ethyl ketone or ethyl acetate,
(C) is isopropanol, propanol or butanol and (D) is an anionic surface active agent.
3. A detergent composition of claim 1 wherein said chlorinated hydrocarbons are selected from the group consisting of monochloromethane, trichloromethane, tetrachloromethane, dichloroethane, trichloroethaue and tetrachloroethane.
4. A detergent composition of claim 1, wherein said ketone (B) is selected from the group consisting of diethyl ketone, methyl propyl ketone and isomeric ethyl butyl ketones.
5. A detergent composition of claim 1, wherein said esters (B) are selected from the group consisting of methyl acetate, propyl acetates, butyl acetates, methyl propionates, ethyl propionates, propyl propionates, butyl propionates, methyl butyrates, ethyl butyrates, propyl butyrates and butyl butyrates.
6. A detergent composition of claim 1, wherein said alkanols (C) are selected from the group consisting of. ethanol and amyl alcohols.
7. Cleaning surfaces soiled with oils, fats, tars, resins, asphaltenes, pitches, varnishes, paints or mechanical impurities with the composition of claim 1.
8. A detergent composition of claim 1, wherein (A) is methylene chloride, (B) is ethyl acetate, (C) is isopropanol and (D) is a sulphonate of coconut fat alcohols.
9. A detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl propyl ketone, (C) is propanol and (D) is ammonium salt of sulphuric acid ester of lauryl alcohol.
10. A detergent composition of claim 1 wherein (A) is methylene chloride, (B) is diethyl ketone and ethyl acetate, (C) is butanol and (D) is monoethanolamine salt of the sulphonated coconut fatty alcohols ether.
11. A detergent composition of claim 1, wherein (A) is methylene chloride, (B) is methyl ethyl ketone and propyl acetate, (C) is ethanol and (D) is triethanolamine salt of the lauryl alcohol sulphuric acid ester.
12. A detergent composition of claim 1, wherein (A) is methylene chloride, (B) is methyl ethyl ketone and ethyl acetate, (C) is isopropanol and (D) is sodium lauryl sulphate.
References Cited UNITED STATES PATENTS 3,338,756 8/1967 Leon 252171 2,371,647 3/ 1945 Petering et a1 252171 2,630,409 3/ 1953 Bruner 252l7l 3,179,609 4/ 1965 Morison 252-171 3,423,323 1/1969 Hunter et a1 252162 3,475,343 10/1969 Kusawa et al. 252-162 3,535,392 10/ 1970 Cormany et a1 252-171 WILLIAM E. SCHULZ, Primary Examiner US. Cl. X.R.
134-38; 252-171, Dig. 8, Dig. 10
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19691940018 DE1940018A1 (en) | 1969-08-06 | 1969-08-06 | Solvent based detergents |
US6092470A | 1970-08-04 | 1970-08-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3737386A true US3737386A (en) | 1973-06-05 |
Family
ID=25757764
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00060924A Expired - Lifetime US3737386A (en) | 1969-08-06 | 1970-08-04 | Solvent based detergent |
US00350393A Expired - Lifetime US3856695A (en) | 1969-08-06 | 1973-04-12 | Solvent based detergent |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00350393A Expired - Lifetime US3856695A (en) | 1969-08-06 | 1973-04-12 | Solvent based detergent |
Country Status (8)
Country | Link |
---|---|
US (2) | US3737386A (en) |
BE (1) | BE754318A (en) |
CH (1) | CH531561A (en) |
DE (1) | DE1940018A1 (en) |
DK (1) | DK128856A (en) |
FR (1) | FR2057946A5 (en) |
GB (1) | GB1319068A (en) |
NL (1) | NL7011628A (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988256A (en) * | 1974-04-03 | 1976-10-26 | Allied Chemical Corporation | Photoresist stripper rinse |
US4085059A (en) * | 1974-05-02 | 1978-04-18 | Bunker Ramo Corporation | Foam type coating remover |
US4220549A (en) * | 1978-05-04 | 1980-09-02 | Ronnie J. Moore | Method for removing reflective decal |
US4271214A (en) * | 1978-09-07 | 1981-06-02 | Nippon Paint Co., Ltd. | Method for recovering acrylic resin from excess of sprayed powder coating composition by using aromatic solvents |
US4309300A (en) * | 1979-05-04 | 1982-01-05 | Mcdonnell Douglas Corporation | Cleaning solvent and method of cleaning a metal surface |
US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
US4336024A (en) * | 1980-02-22 | 1982-06-22 | Airwick Industries, Inc. | Process for cleaning clothes at home |
US4421665A (en) * | 1980-08-25 | 1983-12-20 | Lloyd Eugene A | Contact lens cleaning composition containing lipid solvent and method of using |
FR2551766A1 (en) * | 1983-09-13 | 1985-03-15 | Elf Aquitaine | AQUEOUS COMPOSITION FOR THE DISPERSION OF HYDROPHOBIC SUBSTANCES APPLICABLE IN PARTICULAR TO THE CLEANING OF OBJECTS SOILED BY A PAINT OR THE LIKE |
US4518518A (en) * | 1983-03-30 | 1985-05-21 | Amchem Products, Inc. | Cold paint stripping composition |
US4664721A (en) * | 1981-12-07 | 1987-05-12 | Intercontinental Chemical Corporation | Printing screen cleaning and reclaiming compositions |
US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
EP0320394A2 (en) * | 1987-12-09 | 1989-06-14 | Gérard Grandry | Liquid aid for pulverisation and cleaning of pulverizers |
US4965010A (en) * | 1988-10-27 | 1990-10-23 | Swett Ralph R | Paint stripping composition containing ketones, methanol, and aromatic hydrocarbon |
US5045224A (en) * | 1988-01-12 | 1991-09-03 | Toyota Jidosha Kabushiki Kaisha | Color-change washing solution, suitable for spray coating devices |
US5102573A (en) * | 1987-04-10 | 1992-04-07 | Colgate Palmolive Co. | Detergent composition |
EP0698118A1 (en) * | 1994-03-11 | 1996-02-28 | Biogenex Laboratories | Deparaffinization compositions and methods for their use |
US5676764A (en) * | 1993-02-12 | 1997-10-14 | Mcdonnell Douglas Corporation | Low vapor pressure solvent |
US5690747A (en) * | 1988-05-20 | 1997-11-25 | The Boeing Company | Method for removing photoresist with solvent and ultrasonic agitation |
US6200945B1 (en) | 1999-05-20 | 2001-03-13 | Mcdonnell Douglas Corporation | Environmentally safe solvent composition |
CN106118212A (en) * | 2016-08-18 | 2016-11-16 | 中国航天科技集团公司第九研究院第七七研究所 | Prepared by three anti-coating removal methods of space flight printed circuit board (PCB) and remover and remover |
CN110129813A (en) * | 2019-05-08 | 2019-08-16 | 东莞市杰川电子材料科技有限公司 | Cleaning agent and preparation method thereof for cleaning rare earth |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1058727B (en) * | 1976-04-01 | 1982-05-10 | Rialdi G | COMPOSITION FOR THE TREATMENT OF THE GLASS SURFACE |
US4260509A (en) * | 1980-01-04 | 1981-04-07 | The United States Of America As Represented By The Secretary Of The Navy | Solvent having high flash point |
US4302365A (en) * | 1980-02-11 | 1981-11-24 | American Grease Stick Company | Engine degreaser composition |
FR2486535A1 (en) * | 1980-07-09 | 1982-01-15 | Gottschalk Meinhardt | Compsns. for un-gluing fabric coverings - contg. chlorinated solvent, alcohol(s) and surfactant |
FR2538809B1 (en) * | 1982-12-29 | 1985-07-12 | Lumer Sa Ste Indle Produits Ch | PRODUCT FOR TAKING OFF FLOOR AND WALL COVERINGS BY APPLICATION TO THE UNGONDED SIDE |
US4592856A (en) * | 1983-11-14 | 1986-06-03 | Shin-Etsu Chemical Co., Ltd. | Liquid detergent composition |
US4543206A (en) * | 1984-05-03 | 1985-09-24 | Adams Cornell L | Nail lacquer and enamel remover |
US4741784A (en) * | 1984-11-26 | 1988-05-03 | Kote-Off, Inc. | Composition and method for removing conformal coatings |
NZ224148A (en) * | 1987-04-10 | 1991-02-26 | Colgate Palmolive Co | Pre-spotting composition for food residue removal |
DE3911078A1 (en) * | 1989-01-13 | 1990-10-11 | Kali Chemie Ag | CLEANING COMPOSITIONS |
US5424010A (en) * | 1993-01-06 | 1995-06-13 | Duliba; Edward P. | Light duty liquid detergent composition containing 3-methyl-3-methoxy-butanol |
JP3390245B2 (en) * | 1993-06-01 | 2003-03-24 | 富士通株式会社 | Cleaning liquid and cleaning method |
DE19501661C2 (en) * | 1995-01-20 | 1996-11-21 | Herberts Gmbh | Process for cleaning devices and device cleaners for carrying out the process |
US5827809A (en) * | 1996-10-15 | 1998-10-27 | Vulcan Materials Company | Low-residue macroemulsion cleaner with perchloroethylene |
CA2445375A1 (en) * | 2001-04-24 | 2002-10-31 | Gage Products Company | Water-based purge composition |
EP3170884A1 (en) * | 2015-11-20 | 2017-05-24 | The Procter and Gamble Company | Alcohols in liquid cleaning compositions to remove stains from surfaces |
EP3399013B1 (en) | 2017-05-05 | 2022-08-03 | The Procter & Gamble Company | Laundry detergent compositions with improved grease removal |
EP3399012A1 (en) | 2017-05-05 | 2018-11-07 | The Procter & Gamble Company | Liquid detergent compositions with improved rheology |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2371647A (en) * | 1943-12-28 | 1945-03-20 | Westvaco Chlorine Products Cor | Degreasing process |
US2630409A (en) * | 1949-10-06 | 1953-03-03 | Du Pont | Paint and varnish remover |
US3535392A (en) * | 1958-02-03 | 1970-10-20 | Ppg Industries Inc | Stabilized methylchloroform |
US3179609A (en) * | 1958-09-25 | 1965-04-20 | Union Carbide Corp | Finish removal formulation |
US3338756A (en) * | 1963-10-28 | 1967-08-29 | Hooker Chemical Corp | Method for removing coatings |
US3423323A (en) * | 1964-11-16 | 1969-01-21 | Exxon Research Engineering Co | Process for cleaning olefin separation equipment |
US3475343A (en) * | 1965-03-23 | 1969-10-28 | Chisso Corp | Process for producing solvent for paint and lacquer |
-
0
- DK DK128856D patent/DK128856A/da unknown
- BE BE754318D patent/BE754318A/en unknown
-
1969
- 1969-08-06 DE DE19691940018 patent/DE1940018A1/en active Pending
-
1970
- 1970-07-16 CH CH1080570A patent/CH531561A/en not_active IP Right Cessation
- 1970-07-30 FR FR7028961A patent/FR2057946A5/fr not_active Expired
- 1970-08-04 GB GB3765070A patent/GB1319068A/en not_active Expired
- 1970-08-04 US US00060924A patent/US3737386A/en not_active Expired - Lifetime
- 1970-08-06 NL NL7011628A patent/NL7011628A/xx unknown
-
1973
- 1973-04-12 US US00350393A patent/US3856695A/en not_active Expired - Lifetime
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988256A (en) * | 1974-04-03 | 1976-10-26 | Allied Chemical Corporation | Photoresist stripper rinse |
US4085059A (en) * | 1974-05-02 | 1978-04-18 | Bunker Ramo Corporation | Foam type coating remover |
US4220549A (en) * | 1978-05-04 | 1980-09-02 | Ronnie J. Moore | Method for removing reflective decal |
US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
US4271214A (en) * | 1978-09-07 | 1981-06-02 | Nippon Paint Co., Ltd. | Method for recovering acrylic resin from excess of sprayed powder coating composition by using aromatic solvents |
US4309300A (en) * | 1979-05-04 | 1982-01-05 | Mcdonnell Douglas Corporation | Cleaning solvent and method of cleaning a metal surface |
US4336024A (en) * | 1980-02-22 | 1982-06-22 | Airwick Industries, Inc. | Process for cleaning clothes at home |
US4421665A (en) * | 1980-08-25 | 1983-12-20 | Lloyd Eugene A | Contact lens cleaning composition containing lipid solvent and method of using |
US4664721A (en) * | 1981-12-07 | 1987-05-12 | Intercontinental Chemical Corporation | Printing screen cleaning and reclaiming compositions |
US4518518A (en) * | 1983-03-30 | 1985-05-21 | Amchem Products, Inc. | Cold paint stripping composition |
FR2551766A1 (en) * | 1983-09-13 | 1985-03-15 | Elf Aquitaine | AQUEOUS COMPOSITION FOR THE DISPERSION OF HYDROPHOBIC SUBSTANCES APPLICABLE IN PARTICULAR TO THE CLEANING OF OBJECTS SOILED BY A PAINT OR THE LIKE |
EP0139560A1 (en) * | 1983-09-13 | 1985-05-02 | Societe Nationale Elf Aquitaine | Aqueous composition for dispersing hydrophobic substances,in particular suitable for cleaning objects soiled by paint or the like |
US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
US5102573A (en) * | 1987-04-10 | 1992-04-07 | Colgate Palmolive Co. | Detergent composition |
FR2624518A1 (en) * | 1987-12-09 | 1989-06-16 | Grandry Gerard | ADJUVANT LIQUID FOR SPRAYING, WASHING, DEGREASING, STAIN REMOVAL OR PAINT THINNING |
EP0320394A2 (en) * | 1987-12-09 | 1989-06-14 | Gérard Grandry | Liquid aid for pulverisation and cleaning of pulverizers |
EP0320394A3 (en) * | 1987-12-09 | 1990-05-23 | Gérard Grandry | Liquid aid for pulverisation and cleaning of pulverizers |
US5045224A (en) * | 1988-01-12 | 1991-09-03 | Toyota Jidosha Kabushiki Kaisha | Color-change washing solution, suitable for spray coating devices |
US5690747A (en) * | 1988-05-20 | 1997-11-25 | The Boeing Company | Method for removing photoresist with solvent and ultrasonic agitation |
US4965010A (en) * | 1988-10-27 | 1990-10-23 | Swett Ralph R | Paint stripping composition containing ketones, methanol, and aromatic hydrocarbon |
US5676764A (en) * | 1993-02-12 | 1997-10-14 | Mcdonnell Douglas Corporation | Low vapor pressure solvent |
EP0698118A1 (en) * | 1994-03-11 | 1996-02-28 | Biogenex Laboratories | Deparaffinization compositions and methods for their use |
EP0698118A4 (en) * | 1994-03-11 | 1999-06-16 | Biogenex Lab | Deparaffinization compositions and methods for their use |
US6200945B1 (en) | 1999-05-20 | 2001-03-13 | Mcdonnell Douglas Corporation | Environmentally safe solvent composition |
EP1179041B2 (en) † | 1999-05-20 | 2008-02-20 | The Boeing Company | Environmentally safe solvent composition |
CN106118212A (en) * | 2016-08-18 | 2016-11-16 | 中国航天科技集团公司第九研究院第七七研究所 | Prepared by three anti-coating removal methods of space flight printed circuit board (PCB) and remover and remover |
CN106118212B (en) * | 2016-08-18 | 2019-08-20 | 中国航天科技集团公司第九研究院第七七一研究所 | It is prepared by the three proofings coating removal method and remover and remover of space flight printed circuit board |
CN110129813A (en) * | 2019-05-08 | 2019-08-16 | 东莞市杰川电子材料科技有限公司 | Cleaning agent and preparation method thereof for cleaning rare earth |
CN110129813B (en) * | 2019-05-08 | 2023-09-12 | 东莞市杰川电子材料科技有限公司 | Cleaning agent for cleaning rare earth and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
FR2057946A5 (en) | 1971-05-21 |
DE1940018A1 (en) | 1971-02-18 |
CH531561A (en) | 1972-12-15 |
DK128856A (en) | |
US3856695A (en) | 1974-12-24 |
GB1319068A (en) | 1973-05-31 |
NL7011628A (en) | 1971-02-09 |
BE754318A (en) | 1971-01-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3737386A (en) | Solvent based detergent | |
AU2011289224B2 (en) | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof | |
CA2382600C (en) | Environmentally friendly solvent | |
US5503681A (en) | Method of cleaning an object | |
US3832235A (en) | Vapor solvent paint removing method | |
US2396776A (en) | Cleaning composition | |
JP2523111B2 (en) | Demulsifying detergent formulation | |
DE19504192A1 (en) | Thickening aqueous cleaning agents for hard surfaces | |
US3723330A (en) | Detergent composition | |
US5744437A (en) | Single phase liquid composition for cleaning and paint stripping and use thereof | |
US2897104A (en) | Silicone resin remover and method | |
US5472631A (en) | Method of removing oil-based paint from painting articles | |
US2951043A (en) | Cleaner for paint applicators | |
PL71975B1 (en) | Process for removing intaglio ink from a wiping cylinder[US3389656A] | |
DE2505252A1 (en) | PROCEDURE FOR CLEANING AND DEGREASING OBJECTS | |
US3717590A (en) | Liquid water-soluble detergent compositions | |
US2383114A (en) | Detergent composition | |
DE2317135A1 (en) | SOLVENT-BASED CLEANING AGENTS | |
DE4102709C1 (en) | Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants | |
EP0719323A1 (en) | Cleaning composition | |
US3551340A (en) | Liquid additive for alkaline paint strippers | |
RU2190011C2 (en) | Detergent and degreasing agent for cleansing solid surfaces | |
DE3004835C2 (en) | Automatic cleaning fluid | |
JP3375104B2 (en) | How to wash goods | |
US3190836A (en) | Water-soluble liquid detergent compositions |