US3668153A - Foamed detergent composition - Google Patents

Foamed detergent composition Download PDF

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US3668153A
US3668153A US624178A US3668153DA US3668153A US 3668153 A US3668153 A US 3668153A US 624178 A US624178 A US 624178A US 3668153D A US3668153D A US 3668153DA US 3668153 A US3668153 A US 3668153A
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carbons
foaming additive
cleaning composition
alkyl
foaming
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Homer E Crotty
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Chemed Corp
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/06—Hydroxides
    • C11D2111/42—

Definitions

  • Highly alkaline detergents for foam cleaning contain, as the foaming additive, sodium salts of fatty acid sulfonates, amine oxides, amido alkyl amine Oxides, substitution derivative of imidazoline alkanoic quaternary ammonium hydroxide, and mixtures thereof.
  • the foam cleaning compositions of this invention contain, as essential ingredients, from to 90 weight percent sodium hydroxide, from 5 to weight percent sodium tripolyphosphate, from 0 to weight percent trisodium phosphate, from 10 to 30 weight percents soda ash, from 0 to 5 weight percent calcium silicate, and from 4 to 10 weight percent of a foaming additive.
  • Suitable foaming additives include sodium salts of fatty acid sulfonates, amine oxides having the formula:
  • R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R, is an alkyl group having from six to 32 carbons; amido alkyl amine oxides having the formula:
  • acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R and R are alkyl radicals having from one to four carbons; amphoteric compounds having the formula:
  • R is a hydrocarbon radical having from four to 18 carbons
  • R is a hydrocarbon radical having from one to four carbons
  • R CO is a acyl radical having from one to four carbons
  • X is H, Na, K, CH COONa, CH,COOK or cn coon
  • Y is H, Na or K; and mixtures of two or more of the above foaming additives.
  • This invention also includes foam cleaning solutions containing from 1.5 to 12 weight percent of the above compositions, formed from a premix of the ingredients or by mixing the individual ingredients with water.
  • Foam cleaning is effected by pumping high foam cleaning solutions in a mechanical system in which compresed air is mixed with the cleaning solution to produce a stable, copious foam, and applying the foam to a soiled surface.
  • the "dry" foam clings to the surface to be cleaned, increases the contact time of the liquid with the soil and prevents rapid drying or run-off of the liquid cleaner, thereby dramatically improving the cleaning.
  • Foam cleaning has several advantages. It reduces the amount of solution required for cleaning. It prevens the splashing experienced in spray cleaning. With foam it is possi- 6 ble to apply cleaning solutions into duct work and pipings, and to the underside and poorly accessible parts of machinery and equipment where spray cleaning is impractical. It prevents the irritating vapors of liquid solutions from into the air.
  • Foam cleaning has been shown to be eflective for cleaning trucks, tractor trailers, aircraft, factory walls, and ceilings. it is efi'ective for alkaline paint stripping and for other applications of solvent-type paint stripping from large surfaces such as storage tanks, walls and ceilings, aircraft and tractor trailers.
  • the foaming additives which can be used in the composition of this invention include sodium salts of fatty acid 10-22 carbons) sulfonates such as fatty acid sulfonates derived from oleic acid, linoleic acid, linolinic acid, eleosteric acid, licanic acid, palmitoleic acid, petroselenic acid, erusic acid and the like.
  • the preferred fatty acid sulfonate is the sodium salt of sulfonated oleic acid.
  • Amine oxides can also be used as the foaming additive in the composition of this invention.
  • Suitable amine oxides include those having the formula:
  • R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R is an alkyl group having from six to 32 carbons.
  • Amine oxides of this type are disclosed in U.S. Pat. No. 3,270,060 and include acetyl dimethyl amine oxide, myristyl-cetyl dimethyl amine oxide, myristyl dimethyl amine oxide, stearyl dimethyl amine oxide, bis (2 hydroxyethyl) alkyl amine oxide, and the like.
  • foaming additives include amido alkyl amine oxides having the formula:
  • acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R and R are alkyl radicals having from one to four carbons.
  • Foaming agents of this type are disclosed in Canadian Pat. No. 724,663 and include compounds wherein the acyl group is derived from capric, undecanoic, tridecanoic, myristic, pentadecanoic, and palmitic acids, for example.
  • R is a hydrocarbon radical having from four to 18 carbons
  • R is a hydrocarbon radical having from one to four carbons
  • R CO is an acyl radical having from one to four carbons
  • X is Na, K, H, CH COONa, CH COOK or lOlO39 CH,COOH
  • Y is H, Na, or K.
  • Amphoteric foaming additives of this type are disclosed in U.S. Pat. Nos. 2,528,378 and 2,773,068.
  • the preferred amphoteric foaming agents are those according to the formula wherein R, has 8 carbons and R, and R CO each have two carbons; and those compounds according to the formula where R has 11 carbons, R and R CO each have two carbons, and X and Y are Na, K, or H.
  • the foaming additives are mixed with alkali metal (preferably sodium) hydroxides, pyrophosphates, tripolyphosphates, orthophophates, carbonates, silicates, and metasilicates to form compositions of these components having the concentration ranges shown in Table A. 7
  • alkali metal preferably sodium
  • Aqueous solutions containing from 1.5 to 12 and preferably from 3 to 8 weight percent of these compositions are highly effective foam cleaning compositions.
  • the aqueous solutions can be made by mixing water with a previous mix of the foaming additive together with the other ingredients, or it can be formed by sequential addition of the individual ingredients or combinations of ingredients to water.
  • the solution is mixed with sufficient air to form a dry" foam in a foaming device such as described in copending application Ser. No. 534,378 filed Mar. 15, 1966, and is applied to the surface to be cleaned.
  • Dry powder compositions containing 60 percent sodium hydroxide, percent tetrasodium pyrophosphate, 5 percent sodium tripolyphosphate, 2 percent calcium silicate, 13 percent sodium metasilicate, and 4, 6, and percent concentrations of each of the foaming additives shown in Table B were formulated. These compositions are dry, stable powder compositions. Solutions of these compositions in concentrations of from 1.5 to 12 percent produce a dry and copious foam when mixed with air.
  • Aqueous solutions of these dry powder mixtures are mixed with water in amounts sufficient to provide the foaming additive concentrations shown in Table B.
  • Column A lists dilute concentrations
  • Column B lists immediate (preferred) concentrations
  • Column C lists higher concentrations.
  • alkyl amine oxide (Aromox C) ll Dimethyl alkylarninc 0.4% 0.8% 1.6%
  • a powder foam cleaning composition consisting essentially of:
  • a foaming additive selected from the group consisting of: 1. sodium salts of fatty acid sulfonates, 2. amine oxides having the formula wherein R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R is an alkyl group having from six to 32 carbons,
  • amido alkyl amine oxides having the formula is an acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R,and R are alkyl radicals having from one to four carbons, and
  • amphoteric compounds having the formula:
  • R is a hydrocarbon radical having from four to 18 carbons; R is a hydrocarbon radical having from one to four carbons; R CO is an acyl radical having from one to four carbons; X is Na, K, H, CH COONa, CH COOK, or CH,COOH and Y is Na 190; H.
  • R and R,CO each have two carbons.
  • the powder cleaning composition of claim 1 wherein the foaming additive is the amphoteric compound wherein R has 1 l carbons and R andR CO each have two carbons.

Abstract

Highly alkaline detergents for foam cleaning contain, as the foaming additive, sodium salts of fatty acid sulfonates, amine oxides, amido alkyl amine oxides, substitution derivative of imidazoline alkanoic quaternary ammonium hydroxide, and mixtures thereof.

Description

United States Patent Crotty 1 June 6, 1972 [541 FOAMED DETERGENT COMPOSITION [72] lnventor:
[73] Assignee: Chelned Corporation, Cincinnati, Ohio [22] Filed: Mar. 20, 1967 21 Appl. No.: 624,178
Homer E. Crotty, Cincinnati, Ohio [52] U.S. Cl ..252/528, 252/525, 252/554 [51] Int. Cl. ..Cl1d 3/066 [58] Field oisearch ..260/583, 561; 252/152, 156,
[56] References Cited UNITED STATES PATENTS 7 2,955,047 10/1960 Terry 106/3 3,037,887 6/1962 Brenner et al.. 252/138 UX 3,247,121 4/1966 Hendricks... ..252/1l7 3,335,092 8/1967 Perry ..252/l58 FOREIGN PATENTS OR APPLICATIONS 656,579 1965 South Africa OTHER PUBLICATIONS C & EN- Aug. 23, 1965 pps. 47- 48 McCutcheon Detergents and Emulsifiers 1963 Annual p. 140
Primary Examiner-Mayer Weinblatt Attorney-William B. Walker and Kenneth E. Prince 57 ABSTRACT Highly alkaline detergents for foam cleaning contain, as the foaming additive, sodium salts of fatty acid sulfonates, amine oxides, amido alkyl amine Oxides, substitution derivative of imidazoline alkanoic quaternary ammonium hydroxide, and mixtures thereof.
8 Claims, No Drawings FOAMED DETERGENT COMPOSITION This invention relates to foam cleaning compositions which are highly alkaline.
In summary, the foam cleaning compositions of this invention contain, as essential ingredients, from to 90 weight percent sodium hydroxide, from 5 to weight percent sodium tripolyphosphate, from 0 to weight percent trisodium phosphate, from 10 to 30 weight percents soda ash, from 0 to 5 weight percent calcium silicate, and from 4 to 10 weight percent of a foaming additive. Suitable foaming additives include sodium salts of fatty acid sulfonates, amine oxides having the formula:
where R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R, is an alkyl group having from six to 32 carbons; amido alkyl amine oxides having the formula:
wherein is an acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R and R are alkyl radicals having from one to four carbons; amphoteric compounds having the formula:
wherein R is a hydrocarbon radical having from four to 18 carbons, R, is a hydrocarbon radical having from one to four carbons, R CO is a acyl radical having from one to four carbons, X is H, Na, K, CH COONa, CH,COOK or cn coon, and Y is H, Na or K; and mixtures of two or more of the above foaming additives. This invention also includes foam cleaning solutions containing from 1.5 to 12 weight percent of the above compositions, formed from a premix of the ingredients or by mixing the individual ingredients with water.
Foam cleaning is effected by pumping high foam cleaning solutions in a mechanical system in which compresed air is mixed with the cleaning solution to produce a stable, copious foam, and applying the foam to a soiled surface. The "dry" foam clings to the surface to be cleaned, increases the contact time of the liquid with the soil and prevents rapid drying or run-off of the liquid cleaner, thereby dramatically improving the cleaning. Foam cleaning has several advantages. It reduces the amount of solution required for cleaning. It prevens the splashing experienced in spray cleaning. With foam it is possi- 6 ble to apply cleaning solutions into duct work and pipings, and to the underside and poorly accessible parts of machinery and equipment where spray cleaning is impractical. It prevents the irritating vapors of liquid solutions from into the air.
It also reduces the cost of labor, time and materials. Foam cleaning has been shown to be eflective for cleaning trucks, tractor trailers, aircraft, factory walls, and ceilings. it is efi'ective for alkaline paint stripping and for other applications of solvent-type paint stripping from large surfaces such as storage tanks, walls and ceilings, aircraft and tractor trailers.
One example of a prior industrial foam cleaning procedure is described in US. Pat. No. 3,037,887, the entire disclosure of which is incorporated herein by reference for background information.
Although a wide variety of surface active agents are commercially available, many of them identified as foaming agents, most of them will not provide a high foaming action in highly alkaline solutions which are required for cleaning applications.
It is the object of this invention to provide a foam cleaning composition which has a high foam characteristic even though it is very alkaline. It is another object of this invention to provide aqueous solutions of this highly foamable alkaline cleaning composition.
The foaming additives which can be used in the composition of this invention include sodium salts of fatty acid 10-22 carbons) sulfonates such as fatty acid sulfonates derived from oleic acid, linoleic acid, linolinic acid, eleosteric acid, licanic acid, palmitoleic acid, petroselenic acid, erusic acid and the like. The preferred fatty acid sulfonate is the sodium salt of sulfonated oleic acid.
Amine oxides can also be used as the foaming additive in the composition of this invention. Suitable amine oxides include those having the formula:
wherein R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R is an alkyl group having from six to 32 carbons. Amine oxides of this type are disclosed in U.S. Pat. No. 3,270,060 and include acetyl dimethyl amine oxide, myristyl-cetyl dimethyl amine oxide, myristyl dimethyl amine oxide, stearyl dimethyl amine oxide, bis (2 hydroxyethyl) alkyl amine oxide, and the like.
Other useful foaming additives include amido alkyl amine oxides having the formula:
wherein is an acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R and R are alkyl radicals having from one to four carbons. Foaming agents of this type are disclosed in Canadian Pat. No. 724,663 and include compounds wherein the acyl group is derived from capric, undecanoic, tridecanoic, myristic, pentadecanoic, and palmitic acids, for example.
Highly efi'ective foaming additives which can be used in the composition of this invention include amphoteric compounds having the formula:
wherein R is a hydrocarbon radical having from four to 18 carbons, R is a hydrocarbon radical having from one to four carbons, R CO is an acyl radical having from one to four carbons, X is Na, K, H, CH COONa, CH COOK or lOlO39 CH,COOH; and Y is H, Na, or K. Amphoteric foaming additives of this type are disclosed in U.S. Pat. Nos. 2,528,378 and 2,773,068. The preferred amphoteric foaming agents are those according to the formula wherein R, has 8 carbons and R, and R CO each have two carbons; and those compounds according to the formula where R has 11 carbons, R and R CO each have two carbons, and X and Y are Na, K, or H.
The foaming additives are mixed with alkali metal (preferably sodium) hydroxides, pyrophosphates, tripolyphosphates, orthophophates, carbonates, silicates, and metasilicates to form compositions of these components having the concentration ranges shown in Table A. 7
Aqueous solutions containing from 1.5 to 12 and preferably from 3 to 8 weight percent of these compositions are highly effective foam cleaning compositions. The aqueous solutions can be made by mixing water with a previous mix of the foaming additive together with the other ingredients, or it can be formed by sequential addition of the individual ingredients or combinations of ingredients to water.
For cleaning with aqueous solutions of this invention, the solution is mixed with sufficient air to form a dry" foam in a foaming device such as described in copending application Ser. No. 534,378 filed Mar. 15, 1966, and is applied to the surface to be cleaned.
This invention is further illustrated by the following specific but non-limiting examples.
Dry powder compositions containing 60 percent sodium hydroxide, percent tetrasodium pyrophosphate, 5 percent sodium tripolyphosphate, 2 percent calcium silicate, 13 percent sodium metasilicate, and 4, 6, and percent concentrations of each of the foaming additives shown in Table B were formulated. These compositions are dry, stable powder compositions. Solutions of these compositions in concentrations of from 1.5 to 12 percent produce a dry and copious foam when mixed with air.
Aqueous solutions of these dry powder mixtures are mixed with water in amounts sufficient to provide the foaming additive concentrations shown in Table B. Column A lists dilute concentrations, Column B lists immediate (preferred) concentrations and Column C lists higher concentrations.
fatty acid cycloimldate salt cycloimidate (Miranol-C2M) 5 Acetyl dimethylamine 0.3% 0.6% l.3%
oxide (Ammonyx Co) 1 6 Myristyl-cetyl dimethyl 0.3% 0.6% 1.3%
amide oxide (Ammonyx MCO) 7 Myristyl dirnethyl amine 0.3% 0.6% 1.3%
oxide (Ammonyx MO) 8 Stearyl dimethyl amine 0.3% 0.6% 1.3%
oxide (Ammonyx MO) 9 Stearyl dimethyl amine 0.3% 0.6% 1.3%
oxide (Ammonyx SO) 10 Bis (Z-hydroxyethyl) 0.5% 1.0% 2.0%
alkyl amine oxide (Aromox C) ll Dimethyl alkylarninc 0.4% 0.8% 1.6%
oxide (Aromox CD) 12 Alkyl dimethyl amine 0.65% 0.8% 2.60%
oxide (Textamine CA) 13 Amido alkyl amine 0.5% 1.0% 2.0%
oxide (Textamine 1839) 14 Tertiary amine oxide 0.4% 0.8% 2.0%
(Leyco Amine Oxide C-50) The foarnable solutions of Table B form dry and copious foams when mixed with air with a suitable foaming apparatus such as a F OAM-ALL foam generator sold by DuBois Chemicals Division of W. R. Grace & C0.
Obviously, many modifications and variations of the invention as hereinabove set forth can be made without departing from the essence and scope thereof, and only such limitations should be applied as are indicated in the claims.
The invention claimed is:
l. A powder foam cleaning composition consisting essentially of:
a. from 10 to wt. percent sodium hydroxide,
b. from 5 to 25 wt. percent tetrasodium pyrophosphate,
c. from 5 to 25 wt. percent sodium tripolyphosphate,
d. from 0 to 50 wt. percent trisodium phosphate,
e. from 0 to 30 wt. percent soda ash,
f. from 0 to 5 wt. percent calcium silicate,
g. from 0 to 5 wt. percent sodium metasilicate, and
h. from 4 to 10 wt. percent of a foaming additive selected from the group consisting of: 1. sodium salts of fatty acid sulfonates, 2. amine oxides having the formula wherein R and R are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R is an alkyl group having from six to 32 carbons,
3. amido alkyl amine oxides having the formula is an acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R,and R are alkyl radicals having from one to four carbons, and
4. amphoteric compounds having the formula:
wherein R, is a hydrocarbon radical having from four to 18 carbons; R is a hydrocarbon radical having from one to four carbons; R CO is an acyl radical having from one to four carbons; X is Na, K, H, CH COONa, CH COOK, or CH,COOH and Y is Na 190; H.
eight carbons, and R and R,CO each have two carbons.
5. The powder cleaning composition of claim 1 wherein the foaming additive is the amphoteric compound wherein R has 1 l carbons and R andR CO each have two carbons.
6. The powder cleaning composition of claim 1 wherein the foaming additive is the amine oxide (h) (2) wherein R and R, are methyl groups.
7. The powder cleaning composition of claim 1 wherein the foaming additive is the amine oxide (h) (2) wherein R and R are hydroxyethyl groups.
8. The powder cleaning composition of claim 1 wherein the foaming additive is the amido alkyl amine oxide.

Claims (10)

  1. 2. An aqueous foam cleaning solution of from 1.5 to 12 wt. percent of the powder composition of claim 1.
  2. 2. amine oxides having the formula wherein R and R1 are alkyl groups having from one to 34 carbons or hydroxy alkyl groups having from two to 34 carbons, and R2 is an alkyl group having from six to 32 carbons,
  3. 3. amido alkyl amine oxides having the formula wherein is an acyl radical selected from the group of acyl radicals having from 10 to 16 carbons, and R4and R5 are alkyl radicals having from one to four carbons, and
  4. 3. The powder cleaning composition of claim 1 wherein the foaming additive is sodium oleate sulfonate.
  5. 4. The powder cleaning composition of claim 1 wherein the foaming additive is the amphoteric compound wherein R6 has eight carbons, and R7 and R8CO each have two carbons.
  6. 4. amphoteric compounds having the formula: wherein R6 is a hydrocarbon radical having from four to 18 carbons; R7 is a hydrocarbon radical having from one to four carbons; R8CO is an acyl radical having from one to four carbons; X is Na, K, H, -CH2COONa, -CH2COOK, or -CH2COOH and Y is Na, K or H.
  7. 5. The powder cleaning composition of claim 1 wherein the foaming additive is the amphoteric compound wherein R6 has 11 carbons and R7 and R8CO each have two carbons.
  8. 6. The powder cleaning composition of claim 1 wherein the foaming additive is the amine oxide (h) (2) wherein R and R1 are methyl groups.
  9. 7. The powder cleaning composition of claim 1 wherein the foaming additive is the amine oxide (h) (2) wherein R and R1 are hydroxyethyl groups.
  10. 8. The powder cleaning composition of claim 1 wherein the foaming additive is the amido alkyl amine oxide.
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4741863A (en) * 1984-02-10 1988-05-03 Toyota Jidosha Kabushiki Kaisha Alkaline degreasing solution comprising amine oxides
US5096621A (en) * 1989-04-19 1992-03-17 Kao Corporation Detergent composition containing di-long chain alkyl amine oxides
US5429684A (en) * 1990-12-10 1995-07-04 Henkel Kommanditgesellschaft Auf Aktien Water-based carpet cleaning composition and method
US5888308A (en) * 1997-02-28 1999-03-30 International Business Machines Corporation Process for removing residue from screening masks with alkaline solution
US20040254085A1 (en) * 2003-05-19 2004-12-16 Johnsondiversey, Inc. [high caustic contact cleaner]
US20100016198A1 (en) * 2008-01-22 2010-01-21 Bernhardt Randal J Compositions Comprising Sulfonated Estolides And Alkyl Ester Sulfonates, Methods Of Making Them, And Compositions And Processes Employing Them
US20100017969A1 (en) * 2008-01-22 2010-01-28 Murphy Dennis S Sulfonated Estolide Compositions Containing Magnesium Sulfate and Processes Employing Them
US20100022429A1 (en) * 2008-01-22 2010-01-28 Bernhardt Randal J Mixed Salts of Sulfonated Estolides and Other Derivatives of Fatty Acids, and Methods of Making Them
US20100184632A1 (en) * 2009-01-21 2010-07-22 Bernhardt Randal J Automatic or Machine Dishwashing Compositions of Sulfonated Estolides and Other Derivatives of Fatty Acids and Uses Thereof
US20100184855A1 (en) * 2009-01-21 2010-07-22 Bernhardt Randal J Hard Surface Cleaner Compositions of Sulfonated Estolides and Other Derivatives of Fatty Acids and Uses Thereof
US20100183539A1 (en) * 2009-01-21 2010-07-22 Bernhardt Randal J Personal Care Compositions of Sulfonated Estolides and Other Derivatives of Fatty Acids and Uses Thereof
US20100184633A1 (en) * 2009-01-21 2010-07-22 Bernhardt Randal J Light Duty Liquid Detergent Compositions of Sulfonated Estolides and Other Derivatives of Fatty Acids and Uses Thereof
US7998917B1 (en) * 2009-06-18 2011-08-16 Palmore Joel F Visually enhancing heavy duty degreaser-cleaning composition

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US4087387A (en) 1973-07-10 1978-05-02 Lever Brothers Company Foam cleaning composition
NL1000065C2 (en) * 1995-04-05 1996-10-08 Dija Zeist B V Method and means for cleaning surfaces.

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US3247121A (en) * 1962-04-30 1966-04-19 Procter & Gamble Washing composition
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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4741863A (en) * 1984-02-10 1988-05-03 Toyota Jidosha Kabushiki Kaisha Alkaline degreasing solution comprising amine oxides
US5096621A (en) * 1989-04-19 1992-03-17 Kao Corporation Detergent composition containing di-long chain alkyl amine oxides
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Publication number Publication date
CA817377A (en) 1969-07-08
FR1558761A (en) 1969-02-28
GB1144419A (en) 1969-03-05

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