US3658663A - Method for effecting partial metal plating - Google Patents
Method for effecting partial metal plating Download PDFInfo
- Publication number
- US3658663A US3658663A US109385A US3658663DA US3658663A US 3658663 A US3658663 A US 3658663A US 109385 A US109385 A US 109385A US 3658663D A US3658663D A US 3658663DA US 3658663 A US3658663 A US 3658663A
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- United States
- Prior art keywords
- article
- base
- plating
- supporting
- partitioning
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- Expired - Lifetime
Links
- 238000007747 plating Methods 0.000 title abstract description 25
- 239000002184 metal Substances 0.000 title abstract description 14
- 229910052751 metal Inorganic materials 0.000 title abstract description 14
- 238000000034 method Methods 0.000 title description 18
- 238000000638 solvent extraction Methods 0.000 abstract description 20
- 239000002245 particle Substances 0.000 abstract description 6
- 239000000843 powder Substances 0.000 abstract description 6
- 239000003792 electrolyte Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000002093 peripheral effect Effects 0.000 abstract description 3
- 238000009713 electroplating Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
Definitions
- ABSTRACT titioning base and not requiring plating via a conductive powder or particles filled on said inner side of the partitioning base, and by immersing that portion of the article protruding on the outer side of said base in the electrolyte, it is possible to accomplish partial metal plating of this article without any complicated steps required in the prior art and to perform mass production at greatly reduced cost.
- the present invention is concerned with a method for effecting partial metal plating, especially electroplating, of articles, and more particularly, it relates to an improved method of accomplishing partial electroplating of articles, especially those having a rounded and non-angled cylindrical circumference with simplified procedure and at much reduced cost.
- FIG. 1 is a vertical cross sectional view of the apparatus which is employed in putting a preferred embodiment of the method of the present invention into practice;
- P16. 2 is a perspective view of an example of the supporting and partitioning base of said apparatus.
- FIG. 3 is a perspective view of a transistor header which is an example of the article to be subjected to partial plating.
- FIGS. 1 and 2 show an example of the plating apparatus for use in putting the method of the present invention into practice.
- like parts are indicated by like reference numerals for the sake of simplicity of explanation.
- reference numeral 1 represents a supporting and partitioning base of a dish-like configuration.
- This supporting and partitioning base 1 com prises a main plate 1' of a dish-like configuration made of a rubber or plastic material having electro-insulating property and an electro-conductive inner lining metal plate 1'' which lines and covers the inner surfaces of said main plate 1 and which serves as the cathode during the plating operation.
- the electrically insulated main plate 1 is provided with a number of openings 4, 4, which are formed through the bottom of said main plate 1 in spaced relations relative to each other at predetermined intervals. Each of these openings 4, 4, is intended for insertion therein of the base portion 3 of a transistor header (article to be plated).
- Each of these openings 4, 4 is of the same V-shaped configuration of the same dimension in its inner peripheral end portion which, when a cylindrical article 2 is inserted in said opening and supported therein, will establish a tight linear contact with the cylindrical circumference of said article.
- said inner lining metal plate I" is provided with as many apertures 5, 5, as said openings 4, 4 one for each opening 4.
- the diameter of each aperture 5 is slightly larger than that of the opening 4 intended for supporting the base portion 3 of the transistor header 2. It s ould be understood that said supporting and partitioning base 1 of a dish-like configuration may be substituted by a partitioning base made of a net.
- the steps of plating operation begin with the insertion of the article 2 in one of said openings 4, 4, through the corresponding aperture 5 in such a fashion that that portion of said article 2 requiring partial plating protrudes from the reverse side of said supporting and partitioning base 1. Then, the dish-like supporting and partitioning base 1 is filled, on the inner side thereof, with a powder or particles 6 having good electro-conductivity so that the filler 6 is brought into good contact with the outer leads 7 and the flange 3' of the article 2.
- the base 3 and the inner leads 8 both of which protrude from the reverse side of the supporting partitioning base 1 are immersed in a metal plating medium liquid or electrolyte by placing this partitioning base 1 on surface of said liquid so as to be set afioaton the liquid which is contained in an electrolyte reservoir 9 to thereby establish electric conduction between an anode made of a conductive metal plate 10 housed within the liquid reservoir 9 and the cathode which, in this example, is composed of the base 3 and the inner leads 8 of the transistor header 2, with the assistance of both the inner lining metal plate I" and the deposited conductive powder or particles 6.
- the partitioning base 1 serves to seal the inner side thereof from the electrolyte.
- electroplating may be performed upon connection of the apparatus to a power source.
- the electro-conductive powder or particles fill into any narrow spaces which exist in the external regions of the article 2 to be plated so that this fact contributes to rendering the article 2 highly conductive, thus insuring unfailing plating of only the required portion of the article 2.
- the method of the present invention completely eliminates the complicated procedure of establishing conduction for each individual article 2 which was required in the prior art; but instead, it allows simultaneouspartial plating of a number of articles very quickly and with great easine'ss, thus markedly increasing the efficiency of the plating operation and reducing the cost. Accordingly, it will be understood by those skilled in the art that the method of the present invention has a further advantage that it can be applied as effectively also to the electroplating of such articles as will require electric conduction at multiple points, which was considered impossible in the prior art.
- An improved method for effecting partial metal plating, especially electroplating, of articles by the use of an apparatus comprising a supporting and partitioning base composed essentially of an electrically insulated dish-like main plate and an electroconductive inner lining metal plate covering the inner surfaces of said base, said base having a plurality of spaced openings formed through the bottom thereof, each opening being of a V-shaped inner peripheral end for tightly linearly fit at the apex of said V-shape to the circumference of the article to be plated when the latter is inserted in place in said opening, said inner lining metal plate having the same number of apertures to correspond to the respective openings of the partitioning base in such a fashion that the diameter of said aperture is slightly greater than that of said opening; and by establishing electric conduction between the conductive portion in that region of the article located on the inner side of said supporting and partitioning base and not requiring plating and the terminal of an electrode located on the outer side of said supporting and partitioning base with the assistance of an electroconductive powder or particles filled on said inner side of the base; and
Abstract
By the use of an apparatus comprising a supporting and partitioning base having a plurality of spaced openings each having an inner peripheral end edge of a V-shaped cross section for tightly linearly contacting the circumference of the article to be plated when the latter is inserted in place in said opening, and by establishing electric conduction between the terminal of an electrode and the conductive portion in that region of the article located on the inner side of said supporting and partitioning base and not requiring plating via a conductive powder or particles filled on said inner side of the partitioning base, and by immersing that portion of the article protruding on the outer side of said base in the electrolyte, it is possible to accomplish partial metal plating of this article without any complicated steps required in the prior art and to perform mass production at greatly reduced cost.
Description
United States Patent Fukanuma et al.
[151 3,658,663 [451 Apr. 25, 1972 [54] METHOD FOR EFFECTING PARTIAL METAL PLATING [72] inventors: l-lirotaka Fukanuma, Tokyo; KenJl Fujlta; Kenji Kashlura, both of Saitama, all of Japan [73] Assignee: Japan Electro Plating Company,
Kawaguchi, Saitama, Japan [22] Filed: Jan. 25, 1971 [21] Appl. No.: 109,385 [30] Foreign Application Priority Data Mar. 3, 1970 Japan ..45/18399 [52] U.S. Cl. ..204/15,204/297R [51] Int. Cl. .C23b 5/48, C23b 5/70 [58] Field of Search ..208/15,297
[56] References Cited UNITED STATES PATENTS 148,409 3/1874 Bush ..204/297 R 258,214 5/1882 Brinckman... .....204/297 R 1,970,459 8/1934 Kelly....- ..204/297 R 2,115,403 4/1938 Verschragen.... ..204/16 3,007,855 1 H1961 Ellwood ..204/15 3,043,767 7/1962 Tobey ..204/297 R 3,223,599 12/1965 Taylor ..204/297R 3,271,280 9/1966 Shroff ..204/297 R FOREIGN PATENTS OR APPLICATIONS 423,442 2/1935 Great Britain .l ..204/15 Primary Examiner-John H. Mack Assistant Examiner-T. Tufariello Attorney-Linton & Linton [57] ABSTRACT titioning base and not requiring plating via a conductive powder or particles filled on said inner side of the partitioning base, and by immersing that portion of the article protruding on the outer side of said base in the electrolyte, it is possible to accomplish partial metal plating of this article without any complicated steps required in the prior art and to perform mass production at greatly reduced cost.
1 Claims, 3 Drawing Figures BACKGROUND OF THE INVENTION 1. Field of the invention The present invention is concerned with a method for effecting partial metal plating, especially electroplating, of articles, and more particularly, it relates to an improved method of accomplishing partial electroplating of articles, especially those having a rounded and non-angled cylindrical circumference with simplified procedure and at much reduced cost.
2. Description of the prior art In the past, it has been the practice to use a specially designed plating apparatus in order to perform partial metal plating of articles, especially in performing electroplating, with gold, of only the base and the inner leads and not the outer leads of transistor headers. In accomplishing this partial electroplating by the use of said'specially designed plating apparatus, it was necessary to render individual articles electroconductive one after another or independently of each other. For this reason, the conventional method had the drawbacks that the plating operation required complicated procedures and that such a method was not suitable for mass production.
SUMMARY OF THE INVENTION lt is, therefore, an object of the present invention to eliminate the drawbacks of the conventional method for effecting partial plating of articles, and to provide an improved method for accomplishing the plating of a large number of articles at greatly reduced cost by establishing electric conduction of articles with a quite simplified procedure.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a vertical cross sectional view of the apparatus which is employed in putting a preferred embodiment of the method of the present invention into practice;
P16. 2 is a perspective view of an example of the supporting and partitioning base of said apparatus; and
FIG. 3 is a perspective view of a transistor header which is an example of the article to be subjected to partial plating.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT The method of the present invention will be understood better by referring to the accompanying drawings, especially FIGS. 1 and 2 which show an example of the plating apparatus for use in putting the method of the present invention into practice. In the drawings, like parts are indicated by like reference numerals for the sake of simplicity of explanation. Now, referring to the drawings, reference numeral 1 represents a supporting and partitioning base of a dish-like configuration. This supporting and partitioning base 1 com prises a main plate 1' of a dish-like configuration made of a rubber or plastic material having electro-insulating property and an electro-conductive inner lining metal plate 1'' which lines and covers the inner surfaces of said main plate 1 and which serves as the cathode during the plating operation. The electrically insulated main plate 1 is provided with a number of openings 4, 4, which are formed through the bottom of said main plate 1 in spaced relations relative to each other at predetermined intervals. Each of these openings 4, 4, is intended for insertion therein of the base portion 3 of a transistor header (article to be plated). Each of these openings 4, 4, is of the same V-shaped configuration of the same dimension in its inner peripheral end portion which, when a cylindrical article 2 is inserted in said opening and supported therein, will establish a tight linear contact with the cylindrical circumference of said article. Also, said inner lining metal plate I" is provided with as many apertures 5, 5, as said openings 4, 4 one for each opening 4. The diameter of each aperture 5 is slightly larger than that of the opening 4 intended for supporting the base portion 3 of the transistor header 2. It s ould be understood that said supporting and partitioning base 1 of a dish-like configuration may be substituted by a partitioning base made of a net.
According to the method of the present invention, the steps of plating operation begin with the insertion of the article 2 in one of said openings 4, 4, through the corresponding aperture 5 in such a fashion that that portion of said article 2 requiring partial plating protrudes from the reverse side of said supporting and partitioning base 1. Then, the dish-like supporting and partitioning base 1 is filled, on the inner side thereof, with a powder or particles 6 having good electro-conductivity so that the filler 6 is brought into good contact with the outer leads 7 and the flange 3' of the article 2. Thereafter, the base 3 and the inner leads 8 both of which protrude from the reverse side of the supporting partitioning base 1 are immersed in a metal plating medium liquid or electrolyte by placing this partitioning base 1 on surface of said liquid so as to be set afioaton the liquid which is contained in an electrolyte reservoir 9 to thereby establish electric conduction between an anode made of a conductive metal plate 10 housed within the liquid reservoir 9 and the cathode which, in this example, is composed of the base 3 and the inner leads 8 of the transistor header 2, with the assistance of both the inner lining metal plate I" and the deposited conductive powder or particles 6. At the same time, the partitioning base 1 serves to seal the inner side thereof from the electrolyte. Thus, electroplating may be performed upon connection of the apparatus to a power source.
According to the method of the present invention, the electro-conductive powder or particles fill into any narrow spaces which exist in the external regions of the article 2 to be plated so that this fact contributes to rendering the article 2 highly conductive, thus insuring unfailing plating of only the required portion of the article 2. Also, the method of the present invention completely eliminates the complicated procedure of establishing conduction for each individual article 2 which was required in the prior art; but instead, it allows simultaneouspartial plating of a number of articles very quickly and with great easine'ss, thus markedly increasing the efficiency of the plating operation and reducing the cost. Accordingly, it will be understood by those skilled in the art that the method of the present invention has a further advantage that it can be applied as effectively also to the electroplating of such articles as will require electric conduction at multiple points, which was considered impossible in the prior art.
We claim:
1. An improved method for effecting partial metal plating, especially electroplating, of articles by the use of an apparatus comprising a supporting and partitioning base composed essentially of an electrically insulated dish-like main plate and an electroconductive inner lining metal plate covering the inner surfaces of said base, said base having a plurality of spaced openings formed through the bottom thereof, each opening being of a V-shaped inner peripheral end for tightly linearly fit at the apex of said V-shape to the circumference of the article to be plated when the latter is inserted in place in said opening, said inner lining metal plate having the same number of apertures to correspond to the respective openings of the partitioning base in such a fashion that the diameter of said aperture is slightly greater than that of said opening; and by establishing electric conduction between the conductive portion in that region of the article located on the inner side of said supporting and partitioning base and not requiring plating and the terminal of an electrode located on the outer side of said supporting and partitioning base with the assistance of an electroconductive powder or particles filled on said inner side of the base; and by immersing that region of the article protruding from the outer side of said supporting and partitioning base in a plating medium liquid located on said outer side of said partitioning base.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP45018399A JPS4831456B1 (en) | 1970-03-03 | 1970-03-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3658663A true US3658663A (en) | 1972-04-25 |
Family
ID=11970600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US109385A Expired - Lifetime US3658663A (en) | 1970-03-03 | 1971-01-25 | Method for effecting partial metal plating |
Country Status (2)
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US (1) | US3658663A (en) |
JP (1) | JPS4831456B1 (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3897323A (en) * | 1974-08-05 | 1975-07-29 | Motorola Inc | Apparatus for selective plating |
US4007097A (en) * | 1973-10-04 | 1977-02-08 | Galentan A.G. | Process for selectively applying a metal coating to the metallic parts of elements which pass through an insulator |
US4042480A (en) * | 1973-10-04 | 1977-08-16 | Noz Francis X | Apparatus for selectively applying a metal coating to the metallic parts of elements which pass through an insulator |
US4252630A (en) * | 1978-10-31 | 1981-02-24 | U.S. Philips Corporation | Apparatus for manufacturing cathodes |
EP0107931A2 (en) * | 1982-10-05 | 1984-05-09 | S.G. Owen (Northampton) Limited | Selective plating |
US4454009A (en) * | 1983-05-17 | 1984-06-12 | S.G. Owen Limited | Method of, and a machine for, electroplating |
US4500394A (en) * | 1984-05-16 | 1985-02-19 | At&T Technologies, Inc. | Contacting a surface for plating thereon |
US5516416A (en) * | 1994-12-14 | 1996-05-14 | International Business Machines Corporation | Apparatus and method for electroplating pin grid array packaging modules |
US20020022363A1 (en) * | 1998-02-04 | 2002-02-21 | Thomas L. Ritzdorf | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US20060013961A1 (en) * | 2004-07-19 | 2006-01-19 | Pratt And Whitney Canada Corp. | In situ plating of electrical connector contacts |
US7354336B1 (en) | 2006-10-12 | 2008-04-08 | Pratt & Whitney Canada Corp. | Abrading tool and method for refurbishing electrical connector pin contacts |
US20080257741A1 (en) * | 2007-04-17 | 2008-10-23 | Chiu-Yuea Hung | Metal hand tool and method for manufacturing the same |
US20120164325A1 (en) * | 2010-12-27 | 2012-06-28 | Nhk Spring Co., Ltd. | Method of forming lubricative plated layer on viscous liquid feed nozzle and viscous liquid feed nozzle |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5332271U (en) * | 1976-08-27 | 1978-03-20 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US148409A (en) * | 1874-03-10 | Improvement in devices for plating screws | ||
US258214A (en) * | 1882-05-23 | X x x x x x | ||
US1970459A (en) * | 1932-05-26 | 1934-08-14 | John N Kelly | Plating rack |
GB423442A (en) * | 1933-08-01 | 1935-02-01 | Henderik Van Der Horst | Improvements relating to the electro-deposition of metal on the extremities of pen-nibs |
US2115403A (en) * | 1936-03-19 | 1938-04-26 | American Enka Corp | Repairing spinnerets |
US3007855A (en) * | 1958-12-29 | 1961-11-07 | Bell Telephone Labor Inc | Rhodium plating |
US3043767A (en) * | 1959-05-12 | 1962-07-10 | Alton E Tobey | Electroplating apparatus |
US3223599A (en) * | 1963-04-15 | 1965-12-14 | Beckman Instruments Inc | Holding plate for electroplating a detonator plug |
US3271280A (en) * | 1962-06-29 | 1966-09-06 | Csf | Method for manufacturing coldemission cathodes |
-
1970
- 1970-03-03 JP JP45018399A patent/JPS4831456B1/ja active Pending
-
1971
- 1971-01-25 US US109385A patent/US3658663A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US148409A (en) * | 1874-03-10 | Improvement in devices for plating screws | ||
US258214A (en) * | 1882-05-23 | X x x x x x | ||
US1970459A (en) * | 1932-05-26 | 1934-08-14 | John N Kelly | Plating rack |
GB423442A (en) * | 1933-08-01 | 1935-02-01 | Henderik Van Der Horst | Improvements relating to the electro-deposition of metal on the extremities of pen-nibs |
US2115403A (en) * | 1936-03-19 | 1938-04-26 | American Enka Corp | Repairing spinnerets |
US3007855A (en) * | 1958-12-29 | 1961-11-07 | Bell Telephone Labor Inc | Rhodium plating |
US3043767A (en) * | 1959-05-12 | 1962-07-10 | Alton E Tobey | Electroplating apparatus |
US3271280A (en) * | 1962-06-29 | 1966-09-06 | Csf | Method for manufacturing coldemission cathodes |
US3223599A (en) * | 1963-04-15 | 1965-12-14 | Beckman Instruments Inc | Holding plate for electroplating a detonator plug |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4007097A (en) * | 1973-10-04 | 1977-02-08 | Galentan A.G. | Process for selectively applying a metal coating to the metallic parts of elements which pass through an insulator |
US4042480A (en) * | 1973-10-04 | 1977-08-16 | Noz Francis X | Apparatus for selectively applying a metal coating to the metallic parts of elements which pass through an insulator |
US3897323A (en) * | 1974-08-05 | 1975-07-29 | Motorola Inc | Apparatus for selective plating |
US4252630A (en) * | 1978-10-31 | 1981-02-24 | U.S. Philips Corporation | Apparatus for manufacturing cathodes |
EP0107931A2 (en) * | 1982-10-05 | 1984-05-09 | S.G. Owen (Northampton) Limited | Selective plating |
EP0107931A3 (en) * | 1982-10-05 | 1984-08-08 | S.G. Owen Limited | Selective plating |
US4454009A (en) * | 1983-05-17 | 1984-06-12 | S.G. Owen Limited | Method of, and a machine for, electroplating |
US4500394A (en) * | 1984-05-16 | 1985-02-19 | At&T Technologies, Inc. | Contacting a surface for plating thereon |
US5516416A (en) * | 1994-12-14 | 1996-05-14 | International Business Machines Corporation | Apparatus and method for electroplating pin grid array packaging modules |
US6806186B2 (en) | 1998-02-04 | 2004-10-19 | Semitool, Inc. | Submicron metallization using electrochemical deposition |
US7244677B2 (en) | 1998-02-04 | 2007-07-17 | Semitool. Inc. | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US6753251B2 (en) | 1998-02-04 | 2004-06-22 | Semitool, Inc. | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US20020022363A1 (en) * | 1998-02-04 | 2002-02-21 | Thomas L. Ritzdorf | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US20050051436A1 (en) * | 1998-02-04 | 2005-03-10 | Semitool, Inc. | Method of submicron metallization using electrochemical deposition of recesses including a first deposition at a first current density and a second deposition at an increased current density |
US20020102837A1 (en) * | 1998-02-04 | 2002-08-01 | Ritzdorf Thomas L. | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US20060208272A1 (en) * | 1998-02-04 | 2006-09-21 | Semitool, Inc. | Method for filling recessed micro-structures with metallization in the production of a microelectronic device |
US7144805B2 (en) | 1998-02-04 | 2006-12-05 | Semitool, Inc. | Method of submicron metallization using electrochemical deposition of recesses including a first deposition at a first current density and a second deposition at an increased current density |
US20060013961A1 (en) * | 2004-07-19 | 2006-01-19 | Pratt And Whitney Canada Corp. | In situ plating of electrical connector contacts |
US7160427B2 (en) | 2004-07-19 | 2007-01-09 | Pratt & Whitney Canada Corp. | In situ plating of electrical connector contacts |
US7354336B1 (en) | 2006-10-12 | 2008-04-08 | Pratt & Whitney Canada Corp. | Abrading tool and method for refurbishing electrical connector pin contacts |
US20080090494A1 (en) * | 2006-10-12 | 2008-04-17 | Serge Lalancette | Abrading tool and method for refurbishing electrical connector pin contacts |
US20080257741A1 (en) * | 2007-04-17 | 2008-10-23 | Chiu-Yuea Hung | Metal hand tool and method for manufacturing the same |
US7448121B1 (en) * | 2007-04-17 | 2008-11-11 | Jin Xiang Kai Industry Co., Ltd. | Metal hand tool and method for manufacturing the same |
US20120164325A1 (en) * | 2010-12-27 | 2012-06-28 | Nhk Spring Co., Ltd. | Method of forming lubricative plated layer on viscous liquid feed nozzle and viscous liquid feed nozzle |
US8859039B2 (en) * | 2010-12-27 | 2014-10-14 | Nhk Spring Co., Ltd. | Method of forming lubricative plated layer on viscous liquid feed nozzle and viscous liquid feed nozzle |
US9844789B2 (en) | 2010-12-27 | 2017-12-19 | Nhk Spring Co., Ltd. | Method of forming lubricative plated layer on viscous liquid feed nozzle and viscous liquid feed nozzle |
Also Published As
Publication number | Publication date |
---|---|
JPS4831456B1 (en) | 1973-09-29 |
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