US3607359A - Process for the manufacture of unwoven fabrics bonded with a binding agent and having a smooth surface - Google Patents
Process for the manufacture of unwoven fabrics bonded with a binding agent and having a smooth surface Download PDFInfo
- Publication number
- US3607359A US3607359A US696744A US3607359DA US3607359A US 3607359 A US3607359 A US 3607359A US 696744 A US696744 A US 696744A US 3607359D A US3607359D A US 3607359DA US 3607359 A US3607359 A US 3607359A
- Authority
- US
- United States
- Prior art keywords
- latex
- binding agent
- batting
- manufacture
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/645—Impregnation followed by a solidification process
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2971—Impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
Definitions
- Gwinnell Attorney-Burgess, Dinklage & Sprung ABSTRACT Production of bonded nonwoven fabrics with a latex coagulated at relatively low temperature, where coagu1ation is followed by passing the fabric latex between heated rollers and then subjecting the fabric latex to vulcanization.
- the invention relates to a process for the manufacture of a nonwoven fabric bonded with a binding agent and having a smooth surface, as well as high resistance to wear and tear.
- nonwoven fabric which is commercially available under the name VLlESELlNE, for example. Details on the production of such nonwoven fabrics can be seen in the book entitled, Textilverbundstoffe, by Dr. R. Kroma, VEB-Verlag für, 1963.
- the batting is first impregnated at room temperature and then the latex-wet batting material is heated to at least about 60 C., whereupon the latex coagulates in the form of many small spherules of rubber. Under the microscope, the coagulated binding agent then looks something like caviar, or an agglomeration of shot pellets.
- a binding agent having a caviar structure after coagulation.
- one aspect of this invention resides in a process of binding a nonwoven fabric comprising impregnating the fabric with a rubber latex having the capability of coagulating at up to about 35 C.; coagulating such latex at about 5 to 35 C.; passing said nonwoven fabric containing coagulated latex through the nip of a pair of rolls at about 80 to 120 C., preferably about 100C, at a nip pressure of about 20 to 60 kg./cm. and then simultaneously drying the fabric and vulcanizing the coagulated latex at about 120 to 130 C.
- the latices which are used in the process of this invention are generally known-these being categorized as low temperature sensitized latices.”
- the latex is suitably impregnated into the nonwoven fabric in foam-form by processes which are generally known in the art, for example, German Pat. No. 920,211 and German Auslegeschrift 232,544.
- the wet batting is run through a pair of steel rolls, the temperature on the roll surface preferably amounting to about 100 C.
- the pressure in the roll gap amounts to about 20-60 kg./cm.
- the fiber content of the nonwoven fabric may be any conventional fiber material such as, for example, cellulose acetate, rayon, polyester, polyamide, acrylic, modacrylic, cotton, etc.
- the nonwoven fabric may be made by substantially any technique according to standard practice.
- the so-called low temperature sensitized latex suitably contains a desirable rubber or rubbery polymeric material; a nonionic surfactant, a cationic surfactant and a suitable coagulant.
- the rubbery base material may be exemplified by a product sold under the trade name N4 M by Konverkusen, Germany.
- the nonionic surfactant may be exemplified by a product sold under the trade name réelle LA 140 by Rudolf and Company in Geretsn'ed/Oberbayern (Germany).
- the cationic surfactant may be exemplified by a product sold under the trade name Silastan DG by Schill and Sailacher Stuttgart/Boblingen Germany.
- the coagulant may be exemplified by ammonium chloride and/or formaldehyde.
- a batting l is impregnated with foam-form latex 2 by passing such between a pair of rollers 3 and 4.
- the impregnated batting 5 is passed through heating means 6, which serves to coagulate the binder.
- the batting impregnated with the coagulated binder 7 is then passed through a pair of heat rolls 8 and 9 and then through a drying chamber 10.
- EXAMPLE A fiber batting consisting of polyamide fibers of a length of 40 mm. and 3 deniers is impregnated with a mixture of the following composition:
- Silastan DG 1.5 parts formaldehyde 4 parts ammonium chloride as coagulant 200 parts water in such manner that a fiber-to-binding agent ratio of approximately 50:50 is achieved.
- the batting thus impregnated passes beneath infrared radia tors, thereby producing coagulation of the rubber on the fiber. Then the wet batting is passed through a pair of steel rolls, the temperature on the roll surface amounting to about 100. The pressure in the roll gap amounts to 50 kg./cm. Then the material is dried at 130.
- Process of producing a bonded nonwoven fabric which comprises impregnating a nonwoven batting with a latex bonding agent coagulatable at about 5 to 35 C.; rapidly heating said impregnated batting to about 5 to 35 C. to coagulate the latex into small spherules distributed through the interstices of said fabric; passing said batting coagulated latex through the nip of a pair of heated rolls at about to 120 C. which nip exerts a pressure of about 20 to 60 kg./cm. whereby squeezing water and excess binder out of said fabric and simultaneously hot calenderizing such; and then drying said fabric and vulcanizing said binder.
Abstract
Production of bonded nonwoven fabrics with a latex coagulated at relatively low temperature, where coagulation is followed by passing the fabric latex between heated rollers and then subjecting the fabric latex to vulcanization.
Description
United States Patent PROCESS FOR THE MANUFACTURE OF UNWOVEN FABRICS BONDED WITH A BINDING AGENT AND HAVING A SMOOTH SURFACE 3 Claims, 1 Drawing Fig.
US. Cl 117/65.2, 117/140 R, 117/163 Int. Cl B44d l/44, B32b 27/12 Field of Search 1 17/652,
140 R, 163; 260/296 PT [56] References Cited UNITED STATES PATENTS 2,149,750 3/1939 Schwartz 117/163 X 2,261,769 11/1941 Jordan..... 117/163 UX 1,411,593 4/1922 Subers... 117/6512 2,064,360 12/1936 Schur 1. l17/65.2 2,320,536 6/1943 Pollack et a1. l17/65.2 2,715,591 8/1955 Graham ct a1. l17/140X 2,719,795 10/1955 Nottebohm 117/140 X 2,725,309 11/1955 Rodman 117/140 X 3,006,338 10/1961 Davies 117/140 UX 3,034,922 5/1962 Boe 117/140 UX 3,336,183 8/1967 Larner et a1. 117/140 X 3,083,137 3/1963 Fairclough et a1. 117/140 X Primary Examiner-William D. Martin Assistant Examiner-Harry J. Gwinnell Attorney-Burgess, Dinklage & Sprung ABSTRACT: Production of bonded nonwoven fabrics with a latex coagulated at relatively low temperature, where coagu1ation is followed by passing the fabric latex between heated rollers and then subjecting the fabric latex to vulcanization.
PATENTED SEP21 Ian INVENTORS DIETER BIS QHOFF BY HARALD HORDT WWI M x ATTORNEYS.
PROCESS FOR THE MANUFACTURE OF UNWOVEN FABRICS BONDED WITH A BINDING AGENT AND HAVING A SMOOTH SURFACE The invention relates to a process for the manufacture of a nonwoven fabric bonded with a binding agent and having a smooth surface, as well as high resistance to wear and tear.
It is in the prior art to impregnate nonwoven batting with a binding agent, especially a latex, thereafter to dry the wet fibrous sheet material thus produced, and then heat it to temperatures of about 120 C. This vulcanizes the binding agent. in this manner, a nonwoven fabric is obtained which is commercially available under the name VLlESELlNE, for example. Details on the production of such nonwoven fabrics can be seen in the book entitled, Textilverbundstoffe, by Dr. R. Kroma, VEB-Verlag Leipzig, 1963.
It has already been proposed to use sensitized coagulatable latices for the impregnation of fiber batting. According to the prior art, the batting is first impregnated at room temperature and then the latex-wet batting material is heated to at least about 60 C., whereupon the latex coagulates in the form of many small spherules of rubber. Under the microscope, the coagulated binding agent then looks something like caviar, or an agglomeration of shot pellets. One speaks therefore of a binding agent having a caviar structure after coagulation.
It is an object of this invention to provide a novel latex impregnation process for use with nonwoven fabrics.
It is another object of this invention to produce latex bonded, nonwoven fabrics having a higher tear strength and a smoother surface than those known in the art.
Other and additional objects of this invention will become apparent from a consideration of this entire specification, including the claims and drawing hereof.
In accord with and fulfilling these objects, one aspect of this invention resides in a process of binding a nonwoven fabric comprising impregnating the fabric with a rubber latex having the capability of coagulating at up to about 35 C.; coagulating such latex at about 5 to 35 C.; passing said nonwoven fabric containing coagulated latex through the nip of a pair of rolls at about 80 to 120 C., preferably about 100C, at a nip pressure of about 20 to 60 kg./cm. and then simultaneously drying the fabric and vulcanizing the coagulated latex at about 120 to 130 C.
The latices which are used in the process of this invention are generally known-these being categorized as low temperature sensitized latices."
The latex is suitably impregnated into the nonwoven fabric in foam-form by processes which are generally known in the art, for example, German Pat. No. 920,211 and German Auslegeschrift 232,544.
According to the process described in German Pat. No. 910,960, these latices are first whipped to a foam. This cold form is pressed into a loose fiber batting with the aid of rollers. Then, the wet batting thus impregnated is passed under an infrared radiator, thereby achieving a rapid heating to the coagulation point. Needless to say, an ordinary hot-air drying chamber can be used instead of an infrared radiator, the important thing being that the raising of the temperature to the coagulation point be accomplished as rapidly as possible. After coagulation, it has hitherto been customary to pass the wet batting through cold rolls, thereby squeezing excess binding agent and water out of the batting. According to the invention, however, the wet batting is run through a pair of steel rolls, the temperature on the roll surface preferably amounting to about 100 C. The pressure in the roll gap amounts to about 20-60 kg./cm. These figures, however, can be exceeded. Then, the hot calendered fabric is dried at temperatures of l20130, vulcanization occurring simultaneously.
By the combination of the features of the invention, that is, impregnation with a low temperature sensitized binding agent in the form of foam, rapid coagulation, followed by hot calendering, it is possible to manufacture nonwoven fabrics whose tear strength is 35 to 50 percent higher than the tear strength of nonwoven fabrics manufactured by prior art methods. Furthermore, such fabrics have a smoother surface and are therefore also very resistant to wear.
The fiber content of the nonwoven fabric may be any conventional fiber material such as, for example, cellulose acetate, rayon, polyester, polyamide, acrylic, modacrylic, cotton, etc. The nonwoven fabric may be made by substantially any technique according to standard practice.
The so-called low temperature sensitized latex suitably contains a desirable rubber or rubbery polymeric material; a nonionic surfactant, a cationic surfactant and a suitable coagulant. The rubbery base material may be exemplified by a product sold under the trade name N4 M by Farbenfabriken Bayer in Leverkusen, Deutschland. The nonionic surfactant may be exemplified by a product sold under the trade name Produkt LA 140 by Rudolf and Company in Geretsn'ed/Oberbayern (Germany). The cationic surfactant may be exemplified by a product sold under the trade name Silastan DG by Schill and Sailacher Stuttgart/Boblingen Germany. The coagulant may be exemplified by ammonium chloride and/or formaldehyde.
Understanding of this invention will be facilitated by reference to the drawing, which is a schematic flow sheet of the process described.
Referring now to this drawing, a batting l is impregnated with foam-form latex 2 by passing such between a pair of rollers 3 and 4. The impregnated batting 5 is passed through heating means 6, which serves to coagulate the binder. The batting impregnated with the coagulated binder 7 is then passed through a pair of heat rolls 8 and 9 and then through a drying chamber 10.
The following Example is illustrative of the practice of this invention without being limiting thereon.
EXAMPLE A fiber batting consisting of polyamide fibers of a length of 40 mm. and 3 deniers is impregnated with a mixture of the following composition:
100 parts Perbunan N4 M 5 parts zinc oxide 4 parts nonionic wetting agent (commercial name: La 140) 2 parts cation-active wetting agent (commercial name:
Silastan DG) 1.5 parts formaldehyde 4 parts ammonium chloride as coagulant 200 parts water in such manner that a fiber-to-binding agent ratio of approximately 50:50 is achieved.
The batting thus impregnated passes beneath infrared radia tors, thereby producing coagulation of the rubber on the fiber. Then the wet batting is passed through a pair of steel rolls, the temperature on the roll surface amounting to about 100. The pressure in the roll gap amounts to 50 kg./cm. Then the material is dried at 130.
What is claimed is:
1. Process of producing a bonded nonwoven fabric which comprises impregnating a nonwoven batting with a latex bonding agent coagulatable at about 5 to 35 C.; rapidly heating said impregnated batting to about 5 to 35 C. to coagulate the latex into small spherules distributed through the interstices of said fabric; passing said batting coagulated latex through the nip of a pair of heated rolls at about to 120 C. which nip exerts a pressure of about 20 to 60 kg./cm. whereby squeezing water and excess binder out of said fabric and simultaneously hot calenderizing such; and then drying said fabric and vulcanizing said binder.
2. Process as claimed in claim 1 wherein said rolls are at about C.
3. Process as claimed in claim 1 wherein said drying and vulcanizing is carried out at at least about C.
$3 33 I UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. ,359 Dated September 21, 1971 It is certified that error appears in the aboveidentified patent and that said Letters Patent are hereby corrected as shown below:
1'' Column 1, line 49, ,"232,544" should be "1,232,544";
column 1, line 52, "form" should be foam-- Signed and sealed this 21 st day of March 1972.
(SEAL) At test:
EDWARD M.FLETCHER,JR. ROBERT GOTISCHALK Attesting Officer Commissioner of Patents
Claims (2)
- 2. Process as claimed in claim 1 wherein said rolls are at about 100* C.
- 3. Process as claimed in claim 1 wherein said drying and vulcanizing is carried out at at least about 120* C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF0051237 | 1967-01-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3607359A true US3607359A (en) | 1971-09-21 |
Family
ID=7104450
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US696744A Expired - Lifetime US3607359A (en) | 1967-01-12 | 1968-01-10 | Process for the manufacture of unwoven fabrics bonded with a binding agent and having a smooth surface |
Country Status (4)
Country | Link |
---|---|
US (1) | US3607359A (en) |
JP (1) | JPS5545660B1 (en) |
DE (1) | DE1635492A1 (en) |
GB (1) | GB1204582A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5660910A (en) * | 1995-03-31 | 1997-08-26 | Akzo Nobel N.V. | Increased tear strength nonwoven fabric and process for its manufacture |
US6512034B1 (en) * | 1999-09-10 | 2003-01-28 | Sumitomo Rubber Industries, Ltd | Cationic graft-modified natural rubber latex |
US6689242B2 (en) | 2001-03-26 | 2004-02-10 | First Quality Nonwovens, Inc. | Acquisition/distribution layer and method of making same |
US20100105267A1 (en) * | 2005-02-04 | 2010-04-29 | Johns Manville | Method for producing a reinforced polyester non-woven material |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1411593A (en) * | 1919-08-25 | 1922-04-04 | Lawrence A Subers | Process and mechanism for continuously solidifying and vulcanizing coating compounds |
US2064360A (en) * | 1934-07-25 | 1936-12-15 | Brown Co | Manufacture of smooth-faced webs of interfelted fiber |
US2149750A (en) * | 1935-11-15 | 1939-03-07 | American Ecla Corp | Process for the production of waterproof fabrics permeable to air |
US2261769A (en) * | 1939-08-22 | 1941-11-04 | Us Rubber Co | Process of manufacturing rubber articles |
US2320536A (en) * | 1939-12-19 | 1943-06-01 | Pittsburgh Plate Glass Co | Method of coating |
US2715591A (en) * | 1952-12-16 | 1955-08-16 | Du Pont | Sheet material |
US2719795A (en) * | 1948-10-01 | 1955-10-04 | Pellon Corp | Absorbent fibrous sheet material and process of manufacturing the same |
US2725309A (en) * | 1951-06-18 | 1955-11-29 | Du Pont | Coated non-woven fabric and method of making |
US3006338A (en) * | 1953-10-12 | 1961-10-31 | Johnson & Johnson | Non-adherent surgical dressing |
US3034922A (en) * | 1958-08-01 | 1962-05-15 | Freudenberg Carl Kg | Water-soluble paper and method of making it |
US3083137A (en) * | 1961-04-13 | 1963-03-26 | Hooker Chemical Corp | 3, 5-diisopropylphenyl n-methylcarbamate, a low toxicity insecticide |
US3336183A (en) * | 1962-12-19 | 1967-08-15 | Goodrich Co B F | Leather-like composition |
-
1967
- 1967-01-12 DE DE19671635492 patent/DE1635492A1/en active Pending
-
1968
- 1968-01-10 US US696744A patent/US3607359A/en not_active Expired - Lifetime
- 1968-01-12 JP JP137868A patent/JPS5545660B1/ja active Pending
- 1968-01-12 GB GB0831/68A patent/GB1204582A/en not_active Expired
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1411593A (en) * | 1919-08-25 | 1922-04-04 | Lawrence A Subers | Process and mechanism for continuously solidifying and vulcanizing coating compounds |
US2064360A (en) * | 1934-07-25 | 1936-12-15 | Brown Co | Manufacture of smooth-faced webs of interfelted fiber |
US2149750A (en) * | 1935-11-15 | 1939-03-07 | American Ecla Corp | Process for the production of waterproof fabrics permeable to air |
US2261769A (en) * | 1939-08-22 | 1941-11-04 | Us Rubber Co | Process of manufacturing rubber articles |
US2320536A (en) * | 1939-12-19 | 1943-06-01 | Pittsburgh Plate Glass Co | Method of coating |
US2719795A (en) * | 1948-10-01 | 1955-10-04 | Pellon Corp | Absorbent fibrous sheet material and process of manufacturing the same |
US2725309A (en) * | 1951-06-18 | 1955-11-29 | Du Pont | Coated non-woven fabric and method of making |
US2715591A (en) * | 1952-12-16 | 1955-08-16 | Du Pont | Sheet material |
US3006338A (en) * | 1953-10-12 | 1961-10-31 | Johnson & Johnson | Non-adherent surgical dressing |
US3034922A (en) * | 1958-08-01 | 1962-05-15 | Freudenberg Carl Kg | Water-soluble paper and method of making it |
US3083137A (en) * | 1961-04-13 | 1963-03-26 | Hooker Chemical Corp | 3, 5-diisopropylphenyl n-methylcarbamate, a low toxicity insecticide |
US3336183A (en) * | 1962-12-19 | 1967-08-15 | Goodrich Co B F | Leather-like composition |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5660910A (en) * | 1995-03-31 | 1997-08-26 | Akzo Nobel N.V. | Increased tear strength nonwoven fabric and process for its manufacture |
US6512034B1 (en) * | 1999-09-10 | 2003-01-28 | Sumitomo Rubber Industries, Ltd | Cationic graft-modified natural rubber latex |
US6689242B2 (en) | 2001-03-26 | 2004-02-10 | First Quality Nonwovens, Inc. | Acquisition/distribution layer and method of making same |
US20100105267A1 (en) * | 2005-02-04 | 2010-04-29 | Johns Manville | Method for producing a reinforced polyester non-woven material |
Also Published As
Publication number | Publication date |
---|---|
JPS5545660B1 (en) | 1980-11-19 |
GB1204582A (en) | 1970-09-09 |
DE1635492A1 (en) | 1971-10-14 |
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