US3359206A - Floating soap - Google Patents

Floating soap Download PDF

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US3359206A
US3359206A US369084A US36908464A US3359206A US 3359206 A US3359206 A US 3359206A US 369084 A US369084 A US 369084A US 36908464 A US36908464 A US 36908464A US 3359206 A US3359206 A US 3359206A
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soap
polystyrene
floating
bar
foamed
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Expired - Lifetime
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US369084A
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Steve N Cratsa
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Atlantic Richfield Co
Beazer East Inc
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Koppers Co Inc
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Assigned to ATLANTIC RICHFIELD COMPANY, A CORP. OF PA reassignment ATLANTIC RICHFIELD COMPANY, A CORP. OF PA ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: ARCO POLYMERS, INC., A CORP. OF PA
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/02Floating bodies of detergents or of soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/048Soap or detergent bars or cakes with an inner core consisting of insoluble material

Definitions

  • floating soaps have depended upon entrained air for their buoyancy.
  • This air is usually incorporated into the soap base during the processing of the soap.
  • the molten soap is beat or churned to incorporate air into the molten mass; the mass is then cooled in specially designed equipment and thereafter plodded or continuously extruded in the form of a bar, which is cut into the desired size of cakes, and cooled.
  • An object of this invention is to produce a floating soap which does not depend upon entrained air for its buoyancy.
  • FIGURE 1 illustrates a floating bar of soap which floats as a result of the bar being surrounded by foamed plastic;
  • FIGURE 2 illustrates another embodiment of the invention wherein an insert of foamed plastic renders the soap floatable
  • FIGURE 3 illustrates another embodiment of the invention whereina bar of soap has incorporated therein beads of expandable polystyrene;
  • FIGURE 4 illustrates a further embodiment of the invention wherein soap is incorporated in a block of foamed polystyrene
  • FIGURE 5 illustrates an embodiment of the invention that is in the nature of a film of soap incorporated in foamed polystyrene
  • FIGURE 6 illustrates an embodiment of the invention as a novelty
  • FIGURE 7 illustrates still another embcdirnent of the invention.
  • Soap is made by the action of a caustic solution on fatty oils.
  • the soap usable in accordance with this invention may be a conventional good grade of toilet soap. Soap is usually made in the shape of a bar. The bar of soap is designated 11 in FIG. 1. Since soap is more dense than water, the soap will sink when it is placed in water.
  • the bar 11 of soap is surrounded with a band 13 of foamed polystyrene. This band will so change the weight to volume ratio of the assembly that the assembly will float.
  • Foamed polystyrene is conventionally made by heating expandable polystyrene which is commercially available from several manufacturers. Expandable polystyrene, for example, is sold under the trade name Dylite by Koppers foamed plastic pro- Company, Inc. Generally, expandable polystyrene is polystyrene in which there is incorporated an expanding agent, such as, a low boiling hydrocarbon, for example, pentane, to the extent of 5-15 When the particles are heated to a temperature above the boiling point of the expanding agent but below the softening point of the polystyrene, the particles expand to as much as thirty times their original volume and fuse together to form a structure having closed cells and a foamed characteristic.
  • an expanding agent such as, a low boiling hydrocarbon, for example, pentane
  • the expandable polystyrene is pre-expanded prior to its being foamed; a suitable pre-expander being described, for example, in Rodman Patent No. 3,023,175.
  • the preexpanded particles are then expanded in a mold by subjecting the particles to heat.
  • the band 13 may be molded in accordance with the process in Stastny Patent No. 2,787,809.
  • the band 13 may be made by extruding expand-able polystyrene, for example, as described in Patents Nos. 2,941,964 and 2,941,965, in an extruder as a blown film of substantial thickness.
  • the band 13 is made slightly smaller in inner dimension than the dimension of block 11 of soap. Then the band is expanded and placed over the soap. Thus the band resiliently and frictionally engages the bar of soap. Due to the light weight of the band and the additional bulk which the band provides for the soap, the bar of soap is rendered floatable.
  • the bar of soap 11 may be of one color and the band of foamed plastic 13 may be made another color so as to give the bar of soap an enhanced esthetic apperance. Additionally, band 13 makes the soap easier to grasp. The band has a different feel than that of soap 11 and does not have the slippery nature which causes the soap to be difiicult to handle.
  • FIG. 2 illustrates another embodiment of the invention.
  • an insert 15 of foamed polystyrene in the cake 21 of soap renders the soap floatable.
  • the aperture 17 may be made by molding the soap so as to have an aperture 17 therein for insert 15 to be placed in this aperture or insert 15 may be placed in the soap during the time that the soap is being molded in the form of a cake 21.
  • a floating soap having an enhanced sales appeal may be made by providing an insert therein of foamed plastic of novel configuration such, for example, as shown in FIG. 6.
  • the cake of soap 61 has a foamed polystyrene article 62 in the shape of a fish inserted in the bar of soap. It is, of course, obvious that other shapes may be utilized to vary the novel effect of the soap.
  • the fish or molded article may be made of any desired color. The additional buoyancy imparted to the soap by the insert enables the soap to float in the water. After the soap has been consumed, the plastic article 62 remains as a toy or novelty.
  • the soap may be used to induce youngsters to bathe.
  • the soap may be molded into the form of a rocket 71.
  • the foamed plastic article, herein illustrated in the form of stars 72, are inserted into the soap during the time of molding. Since the weight ratio can be adjusted, the rocket body can be made to float upright as does a conventional space capsule. The soap thus has floating characteristics.
  • the soap dissolves and is consumed, suspense builds up in the mind of the consumer to discover the surprise article such, for example, as the star 25 that is in the item. Due to the difliculty in cutting soap or otherwise releasing the star 25 before the soap is completely consumed, the mystery of what novelty is embodied in the soap is not readily unlocked. The fact that the novelty cannot be obtained until the soap is consumed aids parents in inducing children to use the soap for washing since the child knows that he will not obtain the novelty 72 until he has used the soap.
  • FIG. 3 Still another embodiment of the invention is illustrated in FIG. 3.
  • the loose expanded particles of foamed polystyrene are incorporated, as beads, in the soap.
  • the beads 31 of expandable polystyrene are pre-expanded, as in the above-described Rodman patent, and then are mixed with the soap prior to the molding of the soap in the shape of cake 11.
  • the additional volume consumed by these beads of foamed polystyrene increases the buoyancy of the soap to provide a floating characteristic for the soap.
  • Beads 31 can also be used to lend a novel effect to the soap to enhance its appeal to the consumer in that the beads may be multi-colored so as to harmonize with or contrast with the color of the main body of the soap itself.
  • FIG. 4 illustrates yet another embodiment of the invention.
  • the soap is mixed with the foamed polystyrene, and the mixture extruded as a block of foamed polystyrene.
  • This block is then cut, for example, as with a hot wire or knife, to provide a bar having the desired dimensions.
  • the foamed polystyrene itself, forms a soft, slightly abrasive cleaner. As the bar is consumed in so abrading, fresh surface of soap and polystyrene is exposed so that the cleaning power of the abrasive enhances the cleaning powerof the soap.
  • an abrasive to enhance still further the cleaning action.
  • Any of the commonly known abrasives which are in the form of grains or particles, may be used.
  • Such abrasives include aluminum oxide, silicon carbide, cryolite, calcium carbonate, diatomaceous earth, jewelers rouge, crocus, and volcanic ash.
  • the size of these particles is a practical matter. However, the particle size generally is in the range of 0.001 to 0.3 inch.
  • the concentration of abrasive should be between 0.1 and of the total volume of polystyrene and abrasive.
  • a cleanser such as a conventional normally solid detergent or surfaceactive agent, such as, an aryl alkyl sulfonate, as an addition to or substitute for the soap.
  • a conventional normally solid detergent or surfaceactive agent such as, an aryl alkyl sulfonate
  • the abrasive should constitute from 250% of the cleanser.
  • the admixture may be readily molded using conventional molding techniques.
  • the resulting foamed polystyrene floats on water.
  • FIG. 5 illustrates yet another embodiment of the invention.
  • the expandable polystyrene is mixed with soap, abrasive, detergent or mixtures thereof and extruded by conventional practice, for example, as illustrated in the Dylite Expandable Polystyrene publication of the Koppers Company, Inc., copyright 1954, page 21, into a blown sheet of foamed polystyrene.
  • This sheet is then split and perforated in a conventional fashion to form a sheet having measured sections. As described before, each section provides not only surface-active cleaner but also enhances this with the abrading power of the polystyrene.
  • in washrooms it is possible, for example, in washrooms to have only a measured amount of cleaner used by each person, which measured amount is formed in one section 51. After cleaning, this section can be disposed of or discarded thereby decreasing the possibility of the spread of germs.
  • the film is floatable so that it does not drop to the bottom of the water but remains on the surface so as to be readily available for use.
  • the foregoing has described a novel floating soap which has both useful hygienic and esthetic value.
  • the soap does not depend upon entrained air for its floatation characteristics.
  • the soap can be made to float to any desired extent.
  • a floating soap consisting essentially of a block of water soluble soap having intimately incorporated and uniformly dispersed therein discrete particles of foam polystyrene having closed cells.

Description

Dec. 19, 1967 s. N. CRATSA 3,359,206
FLOATING SOAP Filed May 21, 1964 2 Sheets-Sheet 1 I INVENTOR. STEVEMCPA TSA' WWKM N his 2:;
Dec. 19, 1967 S. N. CRATSA FLOATING SOAP 2 Sheets-Sheet 2 Fild May 21, 1964 INVENTOR. 5'TEVEMCEA7'5A United States Patent 3,359,206 FLOATING SOAP Steve N. Cratsa, Pittsburgh, Pa., assignor to Koppers Company, Inc., a corporation of Delaware Filed May 21, 1964, Ser. No. 369,084 1 Claim. (Cl. 252-92) This invention relates generally to floating soaps.
The density of ordinary soap is greater than the density of water, so soap sinks in water. When this happens as one is bathing, the soap is hard to find in the water and once the soap is found, the inherent slipperyness of the soap makes it difficult to grasp. It is not Surprising, therefore, that floating soaps are the most popular for bath and toilet use.
Heretofore, floating soaps have depended upon entrained air for their buoyancy. This air is usually incorporated into the soap base during the processing of the soap. For example, the molten soap is beat or churned to incorporate air into the molten mass; the mass is then cooled in specially designed equipment and thereafter plodded or continuously extruded in the form of a bar, which is cut into the desired size of cakes, and cooled.
To entrain air in the soap requires elaborate and expensive equipment. It also requires a number of additional processing steps which must be carefully controlled.
An object of this invention, therefore, is to produce a floating soap which does not depend upon entrained air for its buoyancy.
In accordance with this invention, vides the buoyancy for floating soap.
The above and further objects and novel features of the invention will appear more fully from the following detailed description when the same is read in connection with the accompanying drawings. It is to be expressly understood, however, that the drawings are not intended as a definition of the invention but are for the purpose of illustration only.
In the drawings wherein like parts are marked alike:
FIGURE 1 illustrates a floating bar of soap which floats as a result of the bar being surrounded by foamed plastic;
FIGURE 2 illustrates another embodiment of the invention wherein an insert of foamed plastic renders the soap floatable;
FIGURE 3 illustrates another embodiment of the invention whereina bar of soap has incorporated therein beads of expandable polystyrene;
FIGURE 4 illustrates a further embodiment of the invention wherein soap is incorporated in a block of foamed polystyrene;
FIGURE 5 illustrates an embodiment of the invention that is in the nature of a film of soap incorporated in foamed polystyrene;
FIGURE 6 illustrates an embodiment of the invention as a novelty; and
FIGURE 7 illustrates still another embcdirnent of the invention.
Soap is made by the action of a caustic solution on fatty oils. The soap usable in accordance with this invention may be a conventional good grade of toilet soap. Soap is usually made in the shape of a bar. The bar of soap is designated 11 in FIG. 1. Since soap is more dense than water, the soap will sink when it is placed in water.
In accordance wit-h this invention, the bar 11 of soap is surrounded with a band 13 of foamed polystyrene. This band will so change the weight to volume ratio of the assembly that the assembly will float.
Foamed polystyrene is conventionally made by heating expandable polystyrene which is commercially available from several manufacturers. Expandable polystyrene, for example, is sold under the trade name Dylite by Koppers foamed plastic pro- Company, Inc. Generally, expandable polystyrene is polystyrene in which there is incorporated an expanding agent, such as, a low boiling hydrocarbon, for example, pentane, to the extent of 5-15 When the particles are heated to a temperature above the boiling point of the expanding agent but below the softening point of the polystyrene, the particles expand to as much as thirty times their original volume and fuse together to form a structure having closed cells and a foamed characteristic. Usually the expandable polystyrene is pre-expanded prior to its being foamed; a suitable pre-expander being described, for example, in Rodman Patent No. 3,023,175. The preexpanded particles are then expanded in a mold by subjecting the particles to heat. The band 13 may be molded in accordance with the process in Stastny Patent No. 2,787,809.
Alternatively, the band 13 may be made by extruding expand-able polystyrene, for example, as described in Patents Nos. 2,941,964 and 2,941,965, in an extruder as a blown film of substantial thickness.
Advantageously, the band 13 is made slightly smaller in inner dimension than the dimension of block 11 of soap. Then the band is expanded and placed over the soap. Thus the band resiliently and frictionally engages the bar of soap. Due to the light weight of the band and the additional bulk which the band provides for the soap, the bar of soap is rendered floatable.
To render the bar of soap more elegant to fit the modern decor of a bathroom, the bar of soap 11 may be of one color and the band of foamed plastic 13 may be made another color so as to give the bar of soap an enhanced esthetic apperance. Additionally, band 13 makes the soap easier to grasp. The band has a different feel than that of soap 11 and does not have the slippery nature which causes the soap to be difiicult to handle.
FIG. 2 illustrates another embodiment of the invention. In this application, an insert 15 of foamed polystyrene in the cake 21 of soap renders the soap floatable.
The aperture 17 may be made by molding the soap so as to have an aperture 17 therein for insert 15 to be placed in this aperture or insert 15 may be placed in the soap during the time that the soap is being molded in the form of a cake 21.
While the cake 21 of soap would normally sink in water, the additional buoyancy imparted by insert 15 renders the soap floatable. Thus the cake of soap will float on the surface of the water. Varying the size of insert 15, it is, of course, possible to impart any desired buoyancy to the soap and thus regulate the extent to which the soap floats.
In accordance with this invention, a floating soap having an enhanced sales appeal may be made by providing an insert therein of foamed plastic of novel configuration such, for example, as shown in FIG. 6. As illustrated therein, the cake of soap 61 has a foamed polystyrene article 62 in the shape of a fish inserted in the bar of soap. It is, of course, obvious that other shapes may be utilized to vary the novel effect of the soap. As is well known in the molding art, the fish or molded article may be made of any desired color. The additional buoyancy imparted to the soap by the insert enables the soap to float in the water. After the soap has been consumed, the plastic article 62 remains as a toy or novelty.
In accordance with the invention, the soap may be used to induce youngsters to bathe. For example, the soap may be molded into the form of a rocket 71. The foamed plastic article, herein illustrated in the form of stars 72, are inserted into the soap during the time of molding. Since the weight ratio can be adjusted, the rocket body can be made to float upright as does a conventional space capsule. The soap thus has floating characteristics. As
the soap dissolves and is consumed, suspense builds up in the mind of the consumer to discover the surprise article such, for example, as the star 25 that is in the item. Due to the difliculty in cutting soap or otherwise releasing the star 25 before the soap is completely consumed, the mystery of what novelty is embodied in the soap is not readily unlocked. The fact that the novelty cannot be obtained until the soap is consumed aids parents in inducing children to use the soap for washing since the child knows that he will not obtain the novelty 72 until he has used the soap.
Still another embodiment of the invention is illustrated in FIG. 3. Here the loose expanded particles of foamed polystyrene are incorporated, as beads, in the soap. The beads 31 of expandable polystyrene are pre-expanded, as in the above-described Rodman patent, and then are mixed with the soap prior to the molding of the soap in the shape of cake 11. The additional volume consumed by these beads of foamed polystyrene increases the buoyancy of the soap to provide a floating characteristic for the soap. Beads 31 can also be used to lend a novel effect to the soap to enhance its appeal to the consumer in that the beads may be multi-colored so as to harmonize with or contrast with the color of the main body of the soap itself.
FIG. 4 illustrates yet another embodiment of the invention. The soap is mixed with the foamed polystyrene, and the mixture extruded as a block of foamed polystyrene. This block is then cut, for example, as with a hot wire or knife, to provide a bar having the desired dimensions.
The foamed polystyrene, itself, forms a soft, slightly abrasive cleaner. As the bar is consumed in so abrading, fresh surface of soap and polystyrene is exposed so that the cleaning power of the abrasive enhances the cleaning powerof the soap.
Along with the soap in this embodiment, there may be added an abrasive to enhance still further the cleaning action. Any of the commonly known abrasives, which are in the form of grains or particles, may be used. Such abrasives, for example, include aluminum oxide, silicon carbide, cryolite, calcium carbonate, diatomaceous earth, jewelers rouge, crocus, and volcanic ash. The size of these particles is a practical matter. However, the particle size generally is in the range of 0.001 to 0.3 inch. The concentration of abrasive should be between 0.1 and of the total volume of polystyrene and abrasive.
With the abrasive, there may be added a cleanser such as a conventional normally solid detergent or surfaceactive agent, such as, an aryl alkyl sulfonate, as an addition to or substitute for the soap. Conveniently, this is done by adding to the polystyrene between about 0.1 to 10% by volume based upon the volume of the polystyrene and abrasive of a commercial cleanser such as mechanics soap, Bab-O, Eon-Ami, etc. In such cleansers, the abrasive should constitute from 250% of the cleanser.
Although it is preferable to extrude the admixture of expandable polystyrene and soap, the admixture may be readily molded using conventional molding techniques. The resulting foamed polystyrene floats on water.
FIG. 5 illustrates yet another embodiment of the invention. The expandable polystyrene is mixed with soap, abrasive, detergent or mixtures thereof and extruded by conventional practice, for example, as illustrated in the Dylite Expandable Polystyrene publication of the Koppers Company, Inc., copyright 1954, page 21, into a blown sheet of foamed polystyrene. This sheet is then split and perforated in a conventional fashion to form a sheet having measured sections. As described before, each section provides not only surface-active cleaner but also enhances this with the abrading power of the polystyrene.
With the foregoing, it is possible, for example, in washrooms to have only a measured amount of cleaner used by each person, which measured amount is formed in one section 51. After cleaning, this section can be disposed of or discarded thereby decreasing the possibility of the spread of germs. On the other hand, the film is floatable so that it does not drop to the bottom of the water but remains on the surface so as to be readily available for use.
The foregoing has described a novel floating soap which has both useful hygienic and esthetic value. The soap does not depend upon entrained air for its floatation characteristics. The soap can be made to float to any desired extent.
I claim:
A floating soap consisting essentially of a block of water soluble soap having intimately incorporated and uniformly dispersed therein discrete particles of foam polystyrene having closed cells.
References Cited UNITED STATES PATENTS 821,245 5/1906 Hutchinson 25292 1,553,775 9/1925 Hertz 252-91 2,083,871 6/1937 Serewicz 25293 2,466,826 4/1949 Romaine 252-91 3,076,298 2/ 1963 Tundermann 252--92 FOREIGN PATENTS 819,701 9/ 1959 Great Britain.
LEON D. ROSDOL, Primary Examiner.
DONALD E. CZAJA, Examiner.
W. E. SCHULZ, Assistant Examiner.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3446893A (en) * 1967-02-23 1969-05-27 Olin Mathieson Solid deodorizing compositions
US3482274A (en) * 1965-08-27 1969-12-09 Samuel M Peck Disposable brush
US3904543A (en) * 1973-08-07 1975-09-09 Morton Norwich Products Inc Detergent film
US3969256A (en) * 1974-01-15 1976-07-13 Hadley Harry A Soap saver
US5183429A (en) * 1991-07-31 1993-02-02 Bitton Mary K Children's toy and bath soap assembly
US5316689A (en) * 1991-04-19 1994-05-31 Farrell Dennis A Toy soap containing compressed sponge which pops out during use
USD428526S (en) * 1999-03-31 2000-07-18 Faith Freeman Soap
WO2001088079A1 (en) * 2000-05-17 2001-11-22 Henkel Kommanditgesellschaft Auf Aktien Washing or cleaning agent shaped bodies
US6896435B1 (en) 2004-06-07 2005-05-24 James W Rink Floating bar soap
US20100125964A1 (en) * 2005-01-26 2010-05-27 Johnsondiversey, Inc. Mop with receptacle

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US821245A (en) * 1905-08-30 1906-05-22 John D Newton Combined sponge and soap cake.
US1553775A (en) * 1924-01-05 1925-09-15 Hertz Maurice Combined sponge and soap
US2083871A (en) * 1935-05-20 1937-06-15 Willis P Wrisley Toilet article and method of making same
US2466826A (en) * 1948-11-10 1949-04-12 Jr William Romaine Detergent rubber compound and process of producing same
GB819701A (en) * 1956-04-14 1959-09-09 Georg Haslinger Improvements to floating soap tablets
US3076298A (en) * 1961-02-03 1963-02-05 Colgate Palmolive Co Attachment of detergent material to synthetic sponge

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US821245A (en) * 1905-08-30 1906-05-22 John D Newton Combined sponge and soap cake.
US1553775A (en) * 1924-01-05 1925-09-15 Hertz Maurice Combined sponge and soap
US2083871A (en) * 1935-05-20 1937-06-15 Willis P Wrisley Toilet article and method of making same
US2466826A (en) * 1948-11-10 1949-04-12 Jr William Romaine Detergent rubber compound and process of producing same
GB819701A (en) * 1956-04-14 1959-09-09 Georg Haslinger Improvements to floating soap tablets
US3076298A (en) * 1961-02-03 1963-02-05 Colgate Palmolive Co Attachment of detergent material to synthetic sponge

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3482274A (en) * 1965-08-27 1969-12-09 Samuel M Peck Disposable brush
US3446893A (en) * 1967-02-23 1969-05-27 Olin Mathieson Solid deodorizing compositions
US3904543A (en) * 1973-08-07 1975-09-09 Morton Norwich Products Inc Detergent film
US3969256A (en) * 1974-01-15 1976-07-13 Hadley Harry A Soap saver
US5316689A (en) * 1991-04-19 1994-05-31 Farrell Dennis A Toy soap containing compressed sponge which pops out during use
USRE38946E1 (en) * 1991-07-31 2006-01-24 Bitton Mary K Children's toy and bath soap assembly
US5183429A (en) * 1991-07-31 1993-02-02 Bitton Mary K Children's toy and bath soap assembly
USD428526S (en) * 1999-03-31 2000-07-18 Faith Freeman Soap
US20040053808A1 (en) * 2000-05-17 2004-03-18 Wilfried Raehse Washing or cleaning agent shaped bodies
WO2001088079A1 (en) * 2000-05-17 2001-11-22 Henkel Kommanditgesellschaft Auf Aktien Washing or cleaning agent shaped bodies
US7256168B2 (en) 2000-05-17 2007-08-14 Henkel Kommanditgesellschaft Auf Aktien Washing or cleaning agent shaped bodies
US6896435B1 (en) 2004-06-07 2005-05-24 James W Rink Floating bar soap
US20100125964A1 (en) * 2005-01-26 2010-05-27 Johnsondiversey, Inc. Mop with receptacle
US8056178B2 (en) 2005-01-26 2011-11-15 Diversey, Inc. Mop with receptacle

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AS Assignment

Owner name: ATLANTIC RICHFIELD COMPANY, 515 FLOWER ST., LOS AN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. EFFECTIVE JULY 1, 1981.;ASSIGNOR:ARCO POLYMERS, INC., A CORP. OF PA;REEL/FRAME:003944/0516

Effective date: 19810630