US3179550A - Pile surfaced product and method of forming same - Google Patents

Pile surfaced product and method of forming same Download PDF

Info

Publication number
US3179550A
US3179550A US747500A US74750058A US3179550A US 3179550 A US3179550 A US 3179550A US 747500 A US747500 A US 747500A US 74750058 A US74750058 A US 74750058A US 3179550 A US3179550 A US 3179550A
Authority
US
United States
Prior art keywords
sheet
membrane
pile
plastic
matrix
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US747500A
Inventor
Friedman Abraham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US747500A priority Critical patent/US3179550A/en
Application granted granted Critical
Publication of US3179550A publication Critical patent/US3179550A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/022Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
    • B29C59/025Fibrous surfaces with piles or similar fibres substantially perpendicular to the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/22Corrugating
    • B29C53/24Corrugating of plates or sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23979Particular backing structure or composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23993Composition of pile or adhesive

Definitions

  • a plastic material such as a synthetic resin fiber forming polymer
  • Another object of this invention is to provide a method for the formation of a product of the character indicated entirely of plastic materials such as natural or synthetic resins, particularly fiber forming polymers, to be used alone or in combination with or united to other materials; such method being adapted to produce numerous variations as to the fiber or filamentary shape, thickness, length, configuration or color.
  • the fibers or filaments may have imparted thereto other characteristics of a functional or ornamental character.
  • An additional object of this invention is to provide a product of the character indicated and a method for the formation of the same wherein the above characteristics are realized, said product having highly desirable utilitarian, functional and decorative characteristics.
  • FIGURE 1 is a schematic view of an extrusion arrangement employing the method of this invention for the formation of the herein described novel product
  • FIGURES 2 and 3 are cross-sectional views showing a press arrangement employing the method of this invention for the formation of the novel product
  • FIGURE 4- is a cross-sectional view of a pile surfaced sheet in accordance with present invention in the process of removal from the matrix sheet or membrane used in the process of its formation;
  • FIGURE 5 is a cross-sectional view of a product in accordance with this invention wherein the foraminous matrix or membrane remains in position and is incorporated in the filamentary surfaced structure;
  • FIGURE 6 is a view of a calendering arrangement wherein the method of the present invention is employed to form a product in accordance herewith;
  • FIGURE 7 is a cross-sectional view of another form of the product of the present invention.
  • FIGURES 2 and 3 illustrate one form of practicing the instant invention.
  • Said figures illustrate a press ram 10 provided with a horizontal platen 11 having an operative face 12.
  • a matrix sheet or membrane 13 such as a MIC woven wire mesh cloth is suitably supported by conventional means, not shown, in parallel spaced relation with the operative face 12 of platen 11.
  • a mass of plastic material 14, preferably in sheeted form, is disposed between the operative face 12 of the platen and matrix 13.
  • the yield value of the plastic mass 14 is exceeded and the material is rendered sufiiciently mobile so that it is expressed or extruded through the interstices of the matrix.
  • the material thus expressed through each of the apertures or interstices of the matrix and extending through the other side thereof thus comprises a filament or fiber 15 having a cross section determined by the configuration of the interstitial openings and a length determined by the amount of material thus expressed.
  • the multitude of fibers or filaments thus expressed comprise the nap or pile surface 16 of the sheet.
  • the material 18 remaining unexpressed on the upper surface of the matrix comprises a continuous sheet which remains integrally connected with each of the fibers 15 and thus forms a support or backing 18 for the pile surface 16.
  • the pile surface 16 having been formed in the foregoing manner, the plastic material is rendered sufficiently stable to permit its use or further processing if desired. Depending upon the plastic material employed, such stability and permanence of the partially expressed sheet may be achieved with or without further processing. 1
  • the matrix 13 may be left in situ to form a reinforcing structure for the pile surfaced sheet.
  • the stable or set sheet of plastic may be separated or peeled from the matrix.
  • a pile surfaced sheet in the process of such separation is illustrated in FIGURE 4.
  • the pile fibers or filaments 15 are successively withdrawn through the matrix as the backing portion 18 of the sheet is lifted or peeled away therefrom.
  • the sheet thus removed comprises a unitary and homogeneous structure wherein a napped or pile surface is integrally united with the backing material.
  • a plastigel of this type comprises a plastisol to which a suitable thickening or gelling agent has been added to increase the viscosity thereof and produce a material of putty-like consistency.
  • this class of materials comprises a resin such as a high molecular weight polyvinyl chloride in finely divided form.
  • the resin is dispersed in a plasticizer such as .dioctyl phthalate or tricresyl phosphate.
  • Stabilizers and pigments are also advantageously incorporated in the dispersion.
  • Plasticizers of this type do not result in significant swelling at normal ambient temperatures; however, fusion will occur upon the application of elevated temperatures to the dispersion of plastisol.
  • a gelling agent to the plastisol dispersion results in an increase in viscosity and a material of puttylike consistency is thus formed which is dimensionally stable if undisturbed but may be readily deformed upon the application of relatively low pressure.
  • the yield value of the material is readily exceeded even by the ap plication of hand pressure, and the deformation thus achieved is sufficiently permanent to permit further processing as by fusion upon the application of heat in order to set the resin. Fusion of the resin produces dimension interesting and desirable decorative effects.
  • Typical examples of the thickeners or gelling agents useful in the formation of such plastigels are metallic soaps such as aluminum laurate, aluminum stearate, etc.
  • Other useful agents are materials such as colloidal silica or organophylic bentonites.
  • Fillers may also be used such as china clay or copper phthalocyanine pigments which pigment the product and produce a moderate thickening action.
  • a significant characteristic of such pl-astigels is that they are of thick putty-like consistency and require relatively light pressure to exceed the yield value for deformation to the desired configuration. The deformation may therefore be achieved by manual manipulation or by means of many types of equipment used in the handling or processing of plastic materials.
  • Plastigels are cured, set or dimensionally stabilized to the form of useful articles or products by the application of a temperature adequate to produce fusion.
  • This fusion temperature is in the range of 300 to 400 F., a practical fusion temperature in most cases being 350 F.
  • the duration of the bake need only be long enough to achieve the required heat transfer to the interior of the object.
  • the material is fused at 350 to 375 F.
  • Goon 121 is a dispersion grade high molecular weight vinyl chloride polymer product of B. P. Goodrich Chemical Company.
  • Vinylite QYNV is a dispersion grade high molecular weight vinyl chloride polymer product of Bakelite Company. York Whiting is a china clay filler product of R. E. Carrol, Inc.
  • Dyphos is a dibasic lead phosphite stabilizer product of National Lead Company.
  • Bentone 34 and Bentone 38 are montmorillonite gelling agent products of National Lead Company. Additional formulations are well known to those skilled in the art and are described in the technical literature, such as for example, Plastics Engineering Handbook (Reinhold Publishing Corp, New York, 1954), pages 247-334.
  • the nap or pile surfaced sheet materials produced by the herein disclosed method are subject to considerable variation as to the dimensions and configuration of the individual fibers or filaments. Since the cross-sectional configuration of each individual filament is determined by the matrix aperture configuration, a large range of configurations is available.
  • the matrix material employed may, as heretofore stated, he a membrane such as a wire mesh or textile fabric. Under these circumstances, the weave of the mesh is a determining factor for the fiber configuration and density.
  • the quantity of material expressed through the fabric mesh is determinative of the fiber length and consequently the depth of the nap or pile. By adjusting the rate at which the extrusion of the material takes.
  • curvature or curling of the expressed fibers may be achieved to create
  • perforated or apertured sheets may be employed.
  • textile fabrics ofnatural or synthetic fibers may be employed as the foraminous membrane or matrix material. The employment of the latter type of material is particularly desirable under circumstances wherein such matrix structure is permitted to remain Within the ultimate sheet and is thus incorporated therein. Under such circumstances, the textile fabric sheet is left in situ and becomes part of the ultimate product acting to reinforce the sheet material and to impart other desired physical characteristics thereto.
  • thermoplastic and thermosetting resins may be employed.
  • the resinous material is expressed through a foraminous membrane or matrix so that the expressed material is formed into a relatively dense filamentary mass during the course of its passage through the apertures of the matrix and is supported by a backing of unexpressed residual material or the matrix element itself.
  • the material is brought into contact with the matrix surface under conditions wherein it is rendered mobile, using such heat and pressure as is appropriate for the particular material.
  • the yield value of the material is exceeded as by the application of heat and/or pressure, so that at least a portion of the plastic material is expressed through the matrix thereby forming a multiplicity of closely spaced normally extending fibers or filaments projecting through the matrix.
  • the matrix sheet or membrane may then be separated from the sheet or left in situ as above indicated.
  • resinous materials such as polyethylene, polyvinyl chloride, cellulose acetate, etc.
  • resinous materials such as polyethylene, polyvinyl chloride, cellulose acetate, etc.
  • the resin is disposed in contact with the matrix membrane and is subjected to plastic flow.
  • the yield value of the material is exceeded so that a portion thereof is expressed through the matrix.
  • the densely spaced filaments thus formed are dimensionally stabilized and form the pile surface of the product. Dimensional stabilization may occur by fusion as heretofore described, by cooling, solvent evaporation or by any other means suitable for the particular material employed.
  • the expressed material may be sub jected to a coolant as for example, an air or water stream or bath.
  • FliGURE 1 illustrates a method of practicing the invention based upon the use of an extrusion apparatus.
  • an extruder 19 comprising an extrusion cylinder 20 into which material is fed from a hopper 2i and emerges through a sheeting die 22.
  • a web or belt of foraminous matrix material such as a wire mesh screen is disposed so that a portion thereof traverses the mouth of the sheeting die 22.
  • the foraminous membrane may advantageously bein the form of a belt 28 mounted upon suitable motive means such as rollers 23 which are in turn driven by a motive power source not shown.
  • a roller 26 may be disposed adjacent the die mouth.
  • An extrudable thermoplastic resin is fed into the extruding machine 19 and emerges through the-mouth of the sheeting die at which point a portion of the material is forced and expressed through the openings in the mesh of the belt 28 and projects beyond the undersurface thereof to form a pile of filamentary or fibrous projections 24,.
  • the material remaining upon the upper surface of the foraminous belt comprises a continuous sheet 25 which remains integral with the dense fibrous pile 24 extending through the screen openings. As the expressed material strikes the atmosphere the temperature thereof is sufiiciently reduced to render such materials sufficiently immobile and to prevent coalescence between the individual filaments or fibers.
  • thermoplastic material requires a temperature lower than that of the ambient atmosphere to impart this initial set thereto
  • conventional types of cooling apparatus may be provided in the region of the opening of the sheeting die directed toward the plastic material emerging therefrom.
  • an air stream 50 may be directed at the plastic material or the material belt, as shown in FIGURE 4.
  • prises a backing from which there extend a multiplicity may be immediately passed through a cooling bath.
  • the plastic material upon emerging from the die is caused to be expressed through the moving foraminous belt to the desired degree and is then rendered sufficiently stable so as to retain the individual fiber structure.
  • the matrix or membrane in belt form travels away from the extrusion die, it may be further processed or.
  • ⁇ two component systems such as epoxy or polyester resin systems.
  • a continuous web of fabric or similar sheet foraminous or mesh material may be used in lieu of the endless belt 28.
  • the web as for example of a textile fabric is first wound on the left .hand roller 23 to form a supply roll and is taken up by the right hand roller 23 which thus forms a take-up reel therefor maintaining it in taut condition.
  • the fabric is drawn across the mouth of the sheeting die at which point the plastic material is expressed therethrough in the manner heretofore indicated. After the plastic material is stabilized to a sufficient degree, it may be wound up on the take-up reel in the form of the right hand roller 23.
  • the pile surfaced sheet thus formed incorporates the textile Web as part thereof as exemplified by the pile surfaced sheet shown in FIGURE 5.
  • Said figure illustrates a sheet 44 wherein a multifilament pile surface 41 extends from the backing portion 42 and is additionally supported or reinforced by a foraminous matrix sheet 43.
  • FIGURE 6 An additional arrangement for practicing the instant invention is illustrated in FIGURE 6 wherein a calender 38 is employed for the purpose of forming the pile surfaced sheet.
  • a supply 29 of material is provided such as for example as plasticized resin which may be a vinyl chloride polymer or co-polymer.
  • the supply material 29 is successively passed between rollers 30, 31 and 32 which may be heated in accordance with the requirements of the particular resin for the purpose of achieving the desired plasticity.
  • the material emerges as a uniform layer or sheet 33 on the surface of roller 32.
  • a web of foraminous matrix material, as for example a textile or wire mesh cloth 34 is fed between pinch rollers 36 across the lower surface of roller 32 and is tensioned so that it is pressed toward the surface of said roller so that a portion of the soft plastic mass of sheeted material is forced through the interstices or mesh of the web in filamentary form to thereby form the pile surfaced sheet as shown at 35.
  • Stabilization of the pile surfaced sheet formed of thermoplastic material may, if desired, be assisted by a cooling air stream as shown at 37. On the other hand, if the material employed requires heat for stabilization, it may be passed through a heating zone indicated at 39.
  • the stabilized sheet is then passed through a tensioning arrangement such as for example under idler roll 44 between pinch rolls 45 before being Thus, a plastigel of the type 6 wound on the take-up roll or other receiving device, not shown.
  • a tensioning arrangement such as for example under idler roll 44 between pinch rolls 45
  • Other forms of plastics processing equipment such as for example knife or other coating equipment may also be adapted for the practice of the instant invention.
  • FIGURE 7 illustrates a modified form of product which may be produced by the instant process.
  • This form of product may advantageously be formed by applying a coating of plastic material 46 to a foraminous membrane such as a woven textile fabric 47 as by means of a knife coater. The coated fabric is then passed under an additional knife or other form of pressure applicator, thereby forcing the plastic coating material 46 through the interstices of the fabric to form the filamentary or pile surface 48. If a very substantial portion of the coating material is thus expressed through the foraminous membrane, an additional reinforcing backing layer 49 is advantageously applied to the back of the pile surfaced sheet.
  • the additional reinforcing backing 49 may be in the form of an additional coating of plastic material, or it may be in the form of an adhesively bonded plastic film or textile fabric.
  • the method of forming a multi-filamentary sheet of material which comprises expressing a filament forming material from one surface of a foraminous membrane through the interstices of said membrane and beyond the other surface thereof, the expressed material extending freely beyond said other surface of said membrane and having portions disposed within the foramens of said membrane and subjecting said material to stabilizing conditions in expressed form while supported within the foramens of said membrane.
  • the method of forming a pile surfaced sheet which comprises disposing a plastic material along one surface of a foraminous membrane, applying pressure to said plastic material so that it is extruded through the interstices of said membrane and extends beyond the opposing surface thereof and continuing the extrusion of said material through said membrane until the desired depth of pile has been achieved and discontinuing said extrusion while portions of said plastic material remainwithin the interstices of said membrane.
  • the method of forming a pile surface-d sheet which comprises disposing a material in plastic state along one surface of a foraminous matrix extruding said material through said matrix, said material in the course of its pastially beyond the other surface of said membrane and constituting a dense filamentary mass having portions thereof disposed within said matrix and subjecting said mass including said portions to stabilizing conditions.
  • the method of forming a sheet of multi-filamentary surface material which comprises rendering said material subject to plastic flow in contact with one surface of a foraminous matrix membrane and expressing at least a portion of said material through said membrane and beyond the other surface thereof whereby said expressed material is formed into a multiplicity of filaments by passage through said matrix and continuing the expression of said material until a desired filamentary length has been achieved, arresting the expression of said material with portions thereof remaining in said matrix membrane and subjecting said material to stabilizing conditions.
  • the method of forming a pile surfaced sheet of plastic material which comprises forming said plastic material into a sheet and contacting said sheet while in plastic state with one side of a foraminous member under pressure so that at least a portion of said plastic material is expressed through the opposing surface of said foraminous membrane in the form of filaments formed solely of said material and subjecting said sheet to stabilizing conditions while supported by said membrane.
  • the method of forming a pile surfaced sheet of polyvinyl chloride resin which comprises forming a dispersion of said resin in a plasticizer disposing said dispersion in contact with a foraminous membrane and applying pressure tov said dispersion whereby it is subjected to plastic flow and at least aportion thereof is expressed through the interstices of said matrix to form a plurality of resin filaments comprising a pile surface, a portion of said dispersion remaining disposed in the interstices of said foraminous membrane, heating said dispersion to fusion temperature to thereby stabilize said resin.
  • a plastic sheet material comprising disposing plastic material against an open mesh fabric sheet having a multitude of closely spaced individual interstices, and continuously moving said sheet under tension while bending said sheet around the surface of a member extending transversely of said sheet to place said plastic material under pressure across said surface to force through said individual interstices of said sheet individual plastic strands integral with said plastic material to form plastic bristles projecting from the sheet material.
  • the method of forming a body of multi-filamentary surfaced material which comprises disposing a synthetic resin plastigel on one surface of a matrix membrane subjecting said plastigel to plastic flow through said matrix, so that a plurality of filaments are formed extending beyond the opposing surface of said matrix having root portions disposed within the interstices of said matrix and stabilizing said plastigel including the root portions there of disposed in said interstices.
  • the method of making a plastic carpet comprising disposing a layer of unfused thixotropic plastic material against an open mesh fabric sheethaving a multitude of closely spaced individual interstices continuously moving said sheet under tension while bending said sheet around the surface of a member extending transversely of said sheet to place said plastic layer under pressure across said surface to force through said individual interstices individual plastic strands integral with said layer of plastic material to form plastic bristles.
  • a pile surfaced sheet comprising a backing sheet, a foraminous sheet disposed in contiguity with saidbacking sheet and a plurality of filaments formed integrally with said backing sheet and extending through the foramens of said foraminous sheet, said filaments having root portions disposed in the foramens of said foraminous sheet.
  • a pile surfaced sheet comprising a foraminous membrane, a plurality of filaments extending from said sheet, the root of each of said filaments being disposed in one of the foramens of said membrane.
  • a plastic sheet material suitable for use as a covering material comprising an open mesh ifabric having a multitude of closely spaced interstices, a coating of organic thermoplastic material on one side. of said sheet; and individual substantially contiguous strands of said thermoplastic material forming a pile and extending through the individual interstices of said sheet and anchored in said coating.
  • a plastic sheet material suitable for use as a carpet comprising an open mesh fabric sheet having a multitude of closely spaced interstices, a smooth coating of plasticized vinyl chloride copolymer on one side of said sheet; and individualsubstantially conti uous strands of plasticized vinyl chloride copolymer extending through the individual interstices of said sheet and anchored in said coating to form a pile comprising plastic projections from the other side of said sheet.
  • a pile surfaced sheet comprising a sheet of Woven material, a plurality of filaments of plasticrnaterial disposed along one surface of said fabric, said filaments having portions extending through the interstices inthe weave of said material and beyond the surface thereof.
  • Apile surfaced sheet comprising a sheet of woven material, a layer of plastic material disposed along 9 one surface of said sheet having integrally formed filaments extending therethrough, said filaments having root portions extending through the interstices of the weave of said material and beyond the other surface thereof forming a pile surface therefor.

Description

April 20, 1965 A. FRIEDMAN 3, 7
PILE SURFACED PRODUCT AND METHOD OF FORMING SAME Filed July 9, 1958 2 Sheets-Sheet 1 FIG. I.
PlLE SURFACE D MATERIAL HEATING Z ONE 7 FIG. 2. FIG.3.
INVENTOR.
April 20, 1965 A. FRIEDMAN 3,179,550
FILE SURFAGED PRODUCT AND METHOD OF FORMING SAME Filed July 9. 1958 2 Sheets-Sheet 2 PLA s we MA TEE/AL EH 3 8 f 041 E/VDEE IHIHIIII MMMM HHIHM F|G.7. MWAM m IN V EN TOR.
United States Patent D 3,179,550 PILE SURFACED PRODUCT AND METHOD OF FORMING SAME Abraham Friedman, 66 Court St., Brooklyn, N.Y. Filed July 9, 1958, Ser. No. 747,500 21 Claims. (Cl. 161-62) This invention relates to a method for the formation of a pile surfaced product from plastic materials, and to the product of said process.
It is an object of this invention to provide a material of the character indicated wherein the pile backing portions of the sheet material are integrally formed of a plastic material such as a natural or synthetic resin.
It is also an object of this invention to provide a method for the formation of a napped or pile surfaced material wherein a plastic material such as a synthetic resin fiber forming polymer is employed; the fibers or filaments comprising the filamentary projections from the material being formed in situ integrally with, or united to, the backing or support therefor.
It is also an object of this invention to provide a simple, economical and effective process for the formation of mapped or pile material in the form of sheets or the like which is readily adapted for large scale production, and wherein an eflicient method is provided for the formation of fibrous or filamentary projections and for forming or uniting such projections with a suitable backing, support or reinforcement.
Another object of this invention is to provide a method for the formation of a product of the character indicated entirely of plastic materials such as natural or synthetic resins, particularly fiber forming polymers, to be used alone or in combination with or united to other materials; such method being adapted to produce numerous variations as to the fiber or filamentary shape, thickness, length, configuration or color. The fibers or filaments may have imparted thereto other characteristics of a functional or ornamental character.
An additional object of this invention is to provide a product of the character indicated and a method for the formation of the same wherein the above characteristics are realized, said product having highly desirable utilitarian, functional and decorative characteristics.
Other and further objects, benefits and advantages of this invention will be more fully set forth herein and will be apparent from the drawings, specifications and claims forming part thereof.
In the accompanying drawings:
FIGURE 1 is a schematic view of an extrusion arrangement employing the method of this invention for the formation of the herein described novel product;
FIGURES 2 and 3 are cross-sectional views showing a press arrangement employing the method of this invention for the formation of the novel product;
FIGURE 4- is a cross-sectional view of a pile surfaced sheet in accordance with present invention in the process of removal from the matrix sheet or membrane used in the process of its formation;
FIGURE 5 is a cross-sectional view of a product in accordance with this invention wherein the foraminous matrix or membrane remains in position and is incorporated in the filamentary surfaced structure;
FIGURE 6 is a view of a calendering arrangement wherein the method of the present invention is employed to form a product in accordance herewith; and
FIGURE 7 is a cross-sectional view of another form of the product of the present invention.
FIGURES 2 and 3 illustrate one form of practicing the instant invention. Said figures illustrate a press ram 10 provided with a horizontal platen 11 having an operative face 12. A matrix sheet or membrane 13 such as a MIC woven wire mesh cloth is suitably supported by conventional means, not shown, in parallel spaced relation with the operative face 12 of platen 11. A mass of plastic material 14, preferably in sheeted form, is disposed between the operative face 12 of the platen and matrix 13. As shown in FIGURE 3, upon descent of the ram 10 the yield value of the plastic mass 14 is exceeded and the material is rendered sufiiciently mobile so that it is expressed or extruded through the interstices of the matrix. The material thus expressed through each of the apertures or interstices of the matrix and extending through the other side thereof thus comprises a filament or fiber 15 having a cross section determined by the configuration of the interstitial openings and a length determined by the amount of material thus expressed. In the aggregate, the multitude of fibers or filaments thus expressed comprise the nap or pile surface 16 of the sheet. The material 18 remaining unexpressed on the upper surface of the matrix comprises a continuous sheet which remains integrally connected with each of the fibers 15 and thus forms a support or backing 18 for the pile surface 16. The pile surface 16 having been formed in the foregoing manner, the plastic material is rendered sufficiently stable to permit its use or further processing if desired. Depending upon the plastic material employed, such stability and permanence of the partially expressed sheet may be achieved with or without further processing. 1
The matrix 13 may be left in situ to form a reinforcing structure for the pile surfaced sheet. On the other hand, if it is not desired to thus incorporate the matrix element, the stable or set sheet of plastic may be separated or peeled from the matrix. A pile surfaced sheet in the process of such separation is illustrated in FIGURE 4. As appears from said figure, the pile fibers or filaments 15 are successively withdrawn through the matrix as the backing portion 18 of the sheet is lifted or peeled away therefrom. The sheet thus removed comprises a unitary and homogeneous structure wherein a napped or pile surface is integrally united with the backing material.
The method hereinabove described may be used for the formation of napped or pile surfaced sheets from a wide variety of materials. An example of materials which may be readily employed in the practice of the invention as described above, comprise plastigels formed of vinyl chloride polymers or co-polymers thereof predominating in the vinyl chloride ingredient, such as for example vinyl chloride-acetate co-polymers. Plastigels of this type are well known and described in the patented and technical literature and are commercially available. Generally, it may be stated that a plastigel of this type comprises a plastisol to which a suitable thickening or gelling agent has been added to increase the viscosity thereof and produce a material of putty-like consistency. Thus, in their general aspect, this class of materials comprises a resin such as a high molecular weight polyvinyl chloride in finely divided form. The resin is dispersed in a plasticizer such as .dioctyl phthalate or tricresyl phosphate. Stabilizers and pigments are also advantageously incorporated in the dispersion. Plasticizers of this type do not result in significant swelling at normal ambient temperatures; however, fusion will occur upon the application of elevated temperatures to the dispersion of plastisol. The addition of a gelling agent to the plastisol dispersion results in an increase in viscosity and a material of puttylike consistency is thus formed which is dimensionally stable if undisturbed but may be readily deformed upon the application of relatively low pressure. The yield value of the material is readily exceeded even by the ap plication of hand pressure, and the deformation thus achieved is sufficiently permanent to permit further processing as by fusion upon the application of heat in order to set the resin. Fusion of the resin produces dimension interesting and desirable decorative effects.
ally stable permanently set useful end products. Typical examples of the thickeners or gelling agents useful in the formation of such plastigels are metallic soaps such as aluminum laurate, aluminum stearate, etc. Other useful agents are materials such as colloidal silica or organophylic bentonites. Fillers may also be used such as china clay or copper phthalocyanine pigments which pigment the product and produce a moderate thickening action. As heretofore stated, a significant characteristic of such pl-astigels is that they are of thick putty-like consistency and require relatively light pressure to exceed the yield value for deformation to the desired configuration. The deformation may therefore be achieved by manual manipulation or by means of many types of equipment used in the handling or processing of plastic materials. Plastigels are cured, set or dimensionally stabilized to the form of useful articles or products by the application of a temperature adequate to produce fusion. This fusion temperature is in the range of 300 to 400 F., a practical fusion temperature in most cases being 350 F. The duration of the bake need only be long enough to achieve the required heat transfer to the interior of the object.
Examples of plastigel formulations are given below:
Parts by Weight The material is fused at 350 to 375 F.
Goon 121 is a dispersion grade high molecular weight vinyl chloride polymer product of B. P. Goodrich Chemical Company. Vinylite QYNV is a dispersion grade high molecular weight vinyl chloride polymer product of Bakelite Company. York Whiting is a china clay filler product of R. E. Carrol, Inc. Dyphos is a dibasic lead phosphite stabilizer product of National Lead Company. Bentone 34 and Bentone 38 are montmorillonite gelling agent products of National Lead Company. Additional formulations are well known to those skilled in the art and are described in the technical literature, such as for example, Plastics Engineering Handbook (Reinhold Publishing Corp, New York, 1954), pages 247-334.
It will be understood that the foregoing reference to the use of a plastigel is made by way of example onlyand is not intended to limit the scope of this invention.
The nap or pile surfaced sheet materials produced by the herein disclosed method are subject to considerable variation as to the dimensions and configuration of the individual fibers or filaments. Since the cross-sectional configuration of each individual filament is determined by the matrix aperture configuration, a large range of configurations is available. The matrix material employed may, as heretofore stated, he a membrane such as a wire mesh or textile fabric. Under these circumstances, the weave of the mesh is a determining factor for the fiber configuration and density. The quantity of material expressed through the fabric mesh is determinative of the fiber length and consequently the depth of the nap or pile. By adjusting the rate at which the extrusion of the material takes. place through the matrix mesh, curvature or curling of the expressed fibers may be achieved to create Instead of using a mesh cloth as a matrix membrane, perforated or apertured sheets may be employed. Similarly, textile fabrics ofnatural or synthetic fibers may be employed as the foraminous membrane or matrix material. The employment of the latter type of material is particularly desirable under circumstances wherein such matrix structure is permitted to remain Within the ultimate sheet and is thus incorporated therein. Under such circumstances, the textile fabric sheet is left in situ and becomes part of the ultimate product acting to reinforce the sheet material and to impart other desired physical characteristics thereto.
The instant process is equally applicable to the production of pile surfaced sheets from a Wide variety of other materials. Thus, thermoplastic and thermosetting resins may be employed. In each case the resinous material is expressed through a foraminous membrane or matrix so that the expressed material is formed into a relatively dense filamentary mass during the course of its passage through the apertures of the matrix and is supported by a backing of unexpressed residual material or the matrix element itself. The material is brought into contact with the matrix surface under conditions wherein it is rendered mobile, using such heat and pressure as is appropriate for the particular material. In any case, the yield value of the material is exceeded as by the application of heat and/or pressure, so that at least a portion of the plastic material is expressed through the matrix thereby forming a multiplicity of closely spaced normally extending fibers or filaments projecting through the matrix. The matrix sheet or membrane may then be separated from the sheet or left in situ as above indicated.
Thus, resinous materials such as polyethylene, polyvinyl chloride, cellulose acetate, etc., may be readily formed into pile surfaced sheets of the character indicatcd by the suitable application of heat and pressure as by means of a press apparatus heretofore described. The resin is disposed in contact with the matrix membrane and is subjected to plastic flow. The yield value of the material is exceeded so that a portion thereof is expressed through the matrix. The densely spaced filaments thus formed are dimensionally stabilized and form the pile surface of the product. Dimensional stabilization may occur by fusion as heretofore described, by cooling, solvent evaporation or by any other means suitable for the particular material employed. In the case of many thermoplastic materials mere exposure to the ambient temperature is adequate. Where lower temperatures are required, the expressed material may be sub jected to a coolant as for example, an air or water stream or bath.
FliGURE 1 illustrates a method of practicing the invention based upon the use of an extrusion apparatus. Thus, as shown in said figure, an extruder 19 is provided comprising an extrusion cylinder 20 into which material is fed from a hopper 2i and emerges through a sheeting die 22. A web or belt of foraminous matrix material such as a wire mesh screen is disposed so that a portion thereof traverses the mouth of the sheeting die 22. The foraminous membrane may advantageously bein the form of a belt 28 mounted upon suitable motive means such as rollers 23 which are in turn driven by a motive power source not shown. A roller 26 may be disposed adjacent the die mouth. An extrudable thermoplastic resin is fed into the extruding machine 19 and emerges through the-mouth of the sheeting die at which point a portion of the material is forced and expressed through the openings in the mesh of the belt 28 and projects beyond the undersurface thereof to form a pile of filamentary or fibrous projections 24,. The material remaining upon the upper surface of the foraminous belt comprises a continuous sheet 25 which remains integral with the dense fibrous pile 24 extending through the screen openings. As the expressed material strikes the atmosphere the temperature thereof is sufiiciently reduced to render such materials sufficiently immobile and to prevent coalescence between the individual filaments or fibers. In the event that the particular thermoplastic material requires a temperature lower than that of the ambient atmosphere to impart this initial set thereto, conventional types of cooling apparatus may be provided in the region of the opening of the sheeting die directed toward the plastic material emerging therefrom. Thus for example, Where such additional cooling is required an air stream 50 may be directed at the plastic material or the material belt, as shown in FIGURE 4. prises a backing from which there extend a multiplicity may be immediately passed through a cooling bath. In each case, the plastic material upon emerging from the die is caused to be expressed through the moving foraminous belt to the desired degree and is then rendered sufficiently stable so as to retain the individual fiber structure. As the matrix or membrane in belt form travels away from the extrusion die, it may be further processed or. cooled until suflicient stability is achieved for the structure to enable it to be further manipulated. As the material is sufficiently cooled or otherwise stabilized, it may be peeled from and withdrawn from the foraminous The resulting sheet comof individual fibers to form a pile surface therefor. The length of the individual fibers is determined by the amount of material which is expressed through the foraminous screen as it passes the die opening. It will be seen that by the foregoing method a sheet of plastic material having a pile surface may be continuously formed in any desired length.
{two component systems, such as epoxy or polyester resin systems.
It will be evident that a continuous web of fabric or similar sheet foraminous or mesh material may be used in lieu of the endless belt 28. In such case, the web as for example of a textile fabric is first wound on the left .hand roller 23 to form a supply roll and is taken up by the right hand roller 23 which thus forms a take-up reel therefor maintaining it in taut condition. The fabric is drawn across the mouth of the sheeting die at which point the plastic material is expressed therethrough in the manner heretofore indicated. After the plastic material is stabilized to a sufficient degree, it may be wound up on the take-up reel in the form of the right hand roller 23.
The pile surfaced sheet thus formed incorporates the textile Web as part thereof as exemplified by the pile surfaced sheet shown in FIGURE 5. Said figure illustrates a sheet 44 wherein a multifilament pile surface 41 extends from the backing portion 42 and is additionally supported or reinforced by a foraminous matrix sheet 43.
An additional arrangement for practicing the instant invention is illustrated in FIGURE 6 wherein a calender 38 is employed for the purpose of forming the pile surfaced sheet. In this arrangement, a supply 29 of material is provided such as for example as plasticized resin which may be a vinyl chloride polymer or co-polymer. The supply material 29 is successively passed between rollers 30, 31 and 32 which may be heated in accordance with the requirements of the particular resin for the purpose of achieving the desired plasticity. The material emerges as a uniform layer or sheet 33 on the surface of roller 32. A web of foraminous matrix material, as for example a textile or wire mesh cloth 34 is fed between pinch rollers 36 across the lower surface of roller 32 and is tensioned so that it is pressed toward the surface of said roller so that a portion of the soft plastic mass of sheeted material is forced through the interstices or mesh of the web in filamentary form to thereby form the pile surfaced sheet as shown at 35. Stabilization of the pile surfaced sheet formed of thermoplastic material may, if desired, be assisted by a cooling air stream as shown at 37. On the other hand, if the material employed requires heat for stabilization, it may be passed through a heating zone indicated at 39. The stabilized sheet is then passed through a tensioning arrangement such as for example under idler roll 44 between pinch rolls 45 before being Thus, a plastigel of the type 6 wound on the take-up roll or other receiving device, not shown. Other forms of plastics processing equipment such as for example knife or other coating equipment may also be adapted for the practice of the instant invention.
FIGURE 7 illustrates a modified form of product which may be produced by the instant process. This form of product may advantageously be formed by applying a coating of plastic material 46 to a foraminous membrane such as a woven textile fabric 47 as by means of a knife coater. The coated fabric is then passed under an additional knife or other form of pressure applicator, thereby forcing the plastic coating material 46 through the interstices of the fabric to form the filamentary or pile surface 48. If a very substantial portion of the coating material is thus expressed through the foraminous membrane, an additional reinforcing backing layer 49 is advantageously applied to the back of the pile surfaced sheet. The additional reinforcing backing 49 may be in the form of an additional coating of plastic material, or it may be in the form of an adhesively bonded plastic film or textile fabric.
I have here shown and described preferred embodiments of my invention. It will be apparent, however, that this invention is not limited to these embodiments, and that many changes, additions and modifications can be made in connection therewith without departing from the spirit and scope of the invention as herein disclosed and hereafter claimed.
Having disclosed my invention, what I claim as new and desire to secure by Letters Patent is:
1. The method of forming a pile surfaced sheet which comprises freely extruding a material in plastic state from one surface of a foraminous membrane through and beyond the other surface until a desired depth of pile extending beyond said other surface of saidmembrane has been achieved while permitting a portion of said material to remain in the foramens of said membrane and allowing said pile including the portions within the foramens of said membrane to achieve dimensional stability.
2. The method of forming a multi-filamentary sheet of material which comprises expressing a filament forming material from one surface of a foraminous membrane through the interstices of said membrane and beyond the other surface thereof, the expressed material extending freely beyond said other surface of said membrane and having portions disposed within the foramens of said membrane and subjecting said material to stabilizing conditions in expressed form while supported within the foramens of said membrane.
3. The method of forming a pile surfaced sheet which comprises disposing a plastic material along one surface of a foraminous membrane, applying pressure to said plastic material so that it is extruded through the interstices of said membrane and extends beyond the opposing surface thereof and continuing the extrusion of said material through said membrane until the desired depth of pile has been achieved and discontinuing said extrusion while portions of said plastic material remainwithin the interstices of said membrane.
4. The method of forming a pile surfaced sheet which comprises expressing a material from one surface .of a foraminous membrane through the interstices of said membrane and beyond the other surface thereof, said material in the course of its passage through said membrane being formed by the mesh of said membrane into a dense filamentary mass, said mass extending beyond the other surface thereof and discontinuing the expression of said material while portions thereof remain within the interstices of said membrane and form a support therefor and subjecting said material to stabilizing conditions.
5. The method of forming a pile surface-d sheet which comprises disposing a material in plastic state along one surface of a foraminous matrix extruding said material through said matrix, said material in the course of its pastially beyond the other surface of said membrane and constituting a dense filamentary mass having portions thereof disposed within said matrix and subjecting said mass including said portions to stabilizing conditions.
6. The method of forming a pile surface on a sheet of woven textile fabric which comprises expressing a pile forming material in plastic state from one surface of said fabric so that said material passes through the interstices of said fabric and extends beyond the other surface thereof, portions of said material remaining disposed in the interstices of said fabric which thus forms a support therefor and subjecting said material including the portions thereof disposed within said interstices to stabilizing conditions.
7. The method of forming a sheet of multi-filamentary surface material which comprises rendering said material subject to plastic flow in contact with one surface of a foraminous matrix membrane and expressing at least a portion of said material through said membrane and beyond the other surface thereof whereby said expressed material is formed into a multiplicity of filaments by passage through said matrix and continuing the expression of said material until a desired filamentary length has been achieved, arresting the expression of said material with portions thereof remaining in said matrix membrane and subjecting said material to stabilizing conditions.
8. The method of forming a pile surfaced textile fab ric. sheet whichcomprises coating one side of a textile fabric sheet with a plastic material, subjecting said plastic material to flow through the interstices and beyond the other surface of said fabric whereby a portion of said coating material is expressed through said fabric sheet and extends beyond the opposing surface thereof in the form of a plurality of filaments formed solely of said plastic material and subjecting said plastic material to stabilizing conditions.
9. The method of forming a pile surfaced sheet of plastic material which comprises forming said plastic material into a sheet and contacting said sheet while in plastic state with one side of a foraminous member under pressure so that at least a portion of said plastic material is expressed through the opposing surface of said foraminous membrane in the form of filaments formed solely of said material and subjecting said sheet to stabilizing conditions while supported by said membrane.
10. The method of forming a pile surfaced sheet of polyvinyl chloride resin which comprises forming a dispersion of said resin in a plasticizer disposing said dispersion in contact with a foraminous membrane and applying pressure tov said dispersion whereby it is subjected to plastic flow and at least aportion thereof is expressed through the interstices of said matrix to form a plurality of resin filaments comprising a pile surface, a portion of said dispersion remaining disposed in the interstices of said foraminous membrane, heating said dispersion to fusion temperature to thereby stabilize said resin.
11. The method of making a plastic sheet material comprising disposing plastic material against an open mesh fabric sheet having a multitude of closely spaced individual interstices, and continuously moving said sheet under tension while bending said sheet around the surface of a member extending transversely of said sheet to place said plastic material under pressure across said surface to force through said individual interstices of said sheet individual plastic strands integral with said plastic material to form plastic bristles projecting from the sheet material.
12. The method of forming a pile surfaced sheet which comprises disposing a mass of plastic material on one side of a foraminous membrane, subjecting said mass to plastic flow and expressing a portion thereof through the interstices and beyond the other side of said membrane,
whereby a continuous sheet of said plastic material is disposed on one surface of said membrane, and a multiplicity of filamentary projections are formed extending from said sheet through said membrane beyond the opposing surface thereof, said filaments being integrally formed with said sheet, allowing said plastic material to be stabilized and upon the stabilization thereof, removing said pilesurfaced sheet from said membrane by Withdrawing the .pile filaments through the membrane foramens.
13. The method of forming a body of multi-filamentary surfaced material which comprises disposing a synthetic resin plastigel on one surface of a matrix membrane subjecting said plastigel to plastic flow through said matrix, so that a plurality of filaments are formed extending beyond the opposing surface of said matrix having root portions disposed within the interstices of said matrix and stabilizing said plastigel including the root portions there of disposed in said interstices.
14. The method of making a plastic carpet comprising disposing a layer of unfused thixotropic plastic material against an open mesh fabric sheethaving a multitude of closely spaced individual interstices continuously moving said sheet under tension while bending said sheet around the surface of a member extending transversely of said sheet to place said plastic layer under pressure across said surface to force through said individual interstices individual plastic strands integral with said layer of plastic material to form plastic bristles.
15. The method of forming a pile surfaced sheet which comprises freely expressing material in plastic state through a foraminous membrane so that a filament is formed by the passage of said plastic material through each of the foramens of said membrane and extends beyond the opposing surface of said membrane, each of said filaments having substantially the crosssectional configuration of said foramens throughout their length and continuing to express said material through said membrane foramens until a desired filament length has been achieved while portions thereof remain disposed in the foramens of said membrane and subjecting said expressed material including the material within said foramens to stabilizing conditions.
16. A pile surfaced sheet comprising a backing sheet, a foraminous sheet disposed in contiguity with saidbacking sheet and a plurality of filaments formed integrally with said backing sheet and extending through the foramens of said foraminous sheet, said filaments having root portions disposed in the foramens of said foraminous sheet.
17. A pile surfaced sheet comprising a foraminous membrane, a plurality of filaments extending from said sheet, the root of each of said filaments being disposed in one of the foramens of said membrane.
18. A plastic sheet material suitable for use as a covering material comprising an open mesh ifabric having a multitude of closely spaced interstices, a coating of organic thermoplastic material on one side. of said sheet; and individual substantially contiguous strands of said thermoplastic material forming a pile and extending through the individual interstices of said sheet and anchored in said coating.
19. A plastic sheet material suitable for use as a carpet comprising an open mesh fabric sheet having a multitude of closely spaced interstices, a smooth coating of plasticized vinyl chloride copolymer on one side of said sheet; and individualsubstantially conti uous strands of plasticized vinyl chloride copolymer extending through the individual interstices of said sheet and anchored in said coating to form a pile comprising plastic projections from the other side of said sheet. 7
20. A pile surfaced sheet comprising a sheet of Woven material, a plurality of filaments of plasticrnaterial disposed along one surface of said fabric, said filaments having portions extending through the interstices inthe weave of said material and beyond the surface thereof.
21. Apile surfaced sheet comprising a sheet of woven material, a layer of plastic material disposed along 9 one surface of said sheet having integrally formed filaments extending therethrough, said filaments having root portions extending through the interstices of the weave of said material and beyond the other surface thereof forming a pile surface therefor.
References Cited by the Examiner UNITED STATES PATENTS 1,925,271 9/33 Miller 154-492 2,032,935 3/36 Hurt 1s-57 1 2,266,368 12/41 Hull et a1. -18-8 2,339,142 1/44 BOdle 61 a1.
2,526,649 10/50 Gaibel 154-76 10 Ewing 117-29 Harrison 154-123 Van Issam 117-119 Morrell et al. 18-8 Esslinger. Salvy 15-176 Mitchell 154-492 Meyers 154-l06 Runton 15452.1
ALEXANDER WYMAN, Primary Examiner.
EARL M. BERGERT, CARL F. KRAFFT,
R. LEBOWITZ, Examiners.

Claims (2)

1. THE METHOD OF FORMING A PILE SURFACED SHEET WHICH COMPRISES FREELY EXTRUDING A MATERIAL IN PLASTIC STATE FROM ONE SURFACE OF A FORAMINOUS MEMBRANE THROUGH AND BEYOND THE OTHER SURFACE UNTIL A DESIRED DEPTH OF PILE EXTENDING BEYOND SAID OTHER SURFACE OF SAID MEMBRANE HAS BEEN ACHIEVED WHILE PERMITTING A PORTION OF SAID MATERIAL TO REMAIN IN THE FORAMENS OF SAID MEMBRANE AND ALLOWING SAID PILE INCLUDING THE PORTIONS WITHIN THE FORAMENS OF SAID MEMBRANE TO ACHIEVE DIMENSIONAL STABILITY.
17. A PILE SURFACED SHEET COMPRISING A FORAMINOUS MEMBRANE, A PLURALITY OF FILAMENTS EXTENDING FROM SAID SHEET, THE ROOT OF EACH OF SAID FILAMENTS BEING DISPOSED IN ONE OF THE FORAMENS OF SAID MEMBRANE.
US747500A 1958-07-09 1958-07-09 Pile surfaced product and method of forming same Expired - Lifetime US3179550A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US747500A US3179550A (en) 1958-07-09 1958-07-09 Pile surfaced product and method of forming same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US747500A US3179550A (en) 1958-07-09 1958-07-09 Pile surfaced product and method of forming same

Publications (1)

Publication Number Publication Date
US3179550A true US3179550A (en) 1965-04-20

Family

ID=25005317

Family Applications (1)

Application Number Title Priority Date Filing Date
US747500A Expired - Lifetime US3179550A (en) 1958-07-09 1958-07-09 Pile surfaced product and method of forming same

Country Status (1)

Country Link
US (1) US3179550A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3219507A (en) * 1961-02-20 1965-11-23 Magee Carpet Co Method of applying plastic sheet to pile fabric backing
US3273355A (en) * 1962-12-19 1966-09-20 Paul R Hill Heat protection apparatus
US3288663A (en) * 1960-11-21 1966-11-29 Ici Ltd Method of preparing a thermoplastic meterial having pile surface
US3312583A (en) * 1963-10-02 1967-04-04 James J Rochlis Apertured and staggered molded pile product
US3317644A (en) * 1963-06-24 1967-05-02 Takai Unokichi Method for producing a plastic fabric having pile-like projections
US3369949A (en) * 1966-08-08 1968-02-20 Forrest Norman Method of making a flexible mold
US3382122A (en) * 1964-02-25 1968-05-07 George S. Nalle Jr. Method of making plastic rugs of plastic thread loops bonded to a plastic base
US3655497A (en) * 1967-09-28 1972-04-11 Tenneco Chem Synthetic suede
US3696183A (en) * 1969-10-30 1972-10-03 Ici Ltd Forming a pile on an article
US4000230A (en) * 1973-08-21 1976-12-28 Metzeler Schaum Gmbh Process for producing sheeting having fibrous surface
FR2332847A1 (en) * 1975-11-28 1977-06-24 Roehm Gmbh SURFACE PROFILING PROCESS FOR LARGE SURFACE PRODUCTS OF THERMOPLASTIC SYNTHETIC MATERIALS
US4065245A (en) * 1973-08-21 1977-12-27 Metzeler Schaum Gmbh Apparatus for producing sheeting having a fibrous surface
US4240857A (en) * 1978-08-08 1980-12-23 Allied Chemical Corporation Fiber reinforced multi-ply stampable thermoplastic sheet
US5507902A (en) * 1992-06-25 1996-04-16 R.H. Wyner Associates, Inc. Multi-layered sheet
US5874140A (en) * 1994-04-19 1999-02-23 R.H. Wyner Associates, Inc. Sheet material with adhesive
US6605332B2 (en) 1997-07-29 2003-08-12 3M Innovative Properties Company Unitary polymer substrate having napped surface of frayed end microfibers
US8197734B1 (en) * 2007-03-22 2012-06-12 Dynasty Footwear, Ltd. Composite sheet materials and processes for manufacturing same

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1925271A (en) * 1932-03-31 1933-09-05 Aviat Patent And Res Corp Composite floor construction
US2032935A (en) * 1934-11-28 1936-03-03 Us Rubber Co Rubber film or sheet
US2266368A (en) * 1938-11-10 1941-12-16 Du Pont Apparatus for the production of artificial structures
US2339142A (en) * 1940-08-03 1944-01-11 Mishawaka Rubber Carpet underlay or the like and method of making same
US2526649A (en) * 1946-11-13 1950-10-24 Gaibel Hyman Preparation of piled webs
US2567327A (en) * 1947-02-21 1951-09-11 Celanese Corp Process of making pile fabric
US2622040A (en) * 1948-09-07 1952-12-16 Nat Automotive Fibres Inc Method of making stretchable suede material
US2707158A (en) * 1951-07-24 1955-04-26 Carola Van Issum Method of making pile fabric
US2730758A (en) * 1954-07-21 1956-01-17 Firestone Tire & Rubber Co Method and apparatus for the production of crimped filaments
US2782461A (en) * 1955-10-06 1957-02-26 Us Rubber Co Method and apparatus for molding conveyor belts
US2795807A (en) * 1952-08-25 1957-06-18 Salvy Leger Brushes
US2807564A (en) * 1954-07-02 1957-09-24 Robert L Mitchell Multi-colored rubber mats and apparatus for formation thereof
US2816853A (en) * 1954-02-01 1957-12-17 Eagle Picher Co Method of forming plastic protuberances
US2841515A (en) * 1956-05-18 1958-07-01 Russell Mfg Co Conveyor belts

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1925271A (en) * 1932-03-31 1933-09-05 Aviat Patent And Res Corp Composite floor construction
US2032935A (en) * 1934-11-28 1936-03-03 Us Rubber Co Rubber film or sheet
US2266368A (en) * 1938-11-10 1941-12-16 Du Pont Apparatus for the production of artificial structures
US2339142A (en) * 1940-08-03 1944-01-11 Mishawaka Rubber Carpet underlay or the like and method of making same
US2526649A (en) * 1946-11-13 1950-10-24 Gaibel Hyman Preparation of piled webs
US2567327A (en) * 1947-02-21 1951-09-11 Celanese Corp Process of making pile fabric
US2622040A (en) * 1948-09-07 1952-12-16 Nat Automotive Fibres Inc Method of making stretchable suede material
US2707158A (en) * 1951-07-24 1955-04-26 Carola Van Issum Method of making pile fabric
US2795807A (en) * 1952-08-25 1957-06-18 Salvy Leger Brushes
US2816853A (en) * 1954-02-01 1957-12-17 Eagle Picher Co Method of forming plastic protuberances
US2807564A (en) * 1954-07-02 1957-09-24 Robert L Mitchell Multi-colored rubber mats and apparatus for formation thereof
US2730758A (en) * 1954-07-21 1956-01-17 Firestone Tire & Rubber Co Method and apparatus for the production of crimped filaments
US2782461A (en) * 1955-10-06 1957-02-26 Us Rubber Co Method and apparatus for molding conveyor belts
US2841515A (en) * 1956-05-18 1958-07-01 Russell Mfg Co Conveyor belts

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3288663A (en) * 1960-11-21 1966-11-29 Ici Ltd Method of preparing a thermoplastic meterial having pile surface
US3219507A (en) * 1961-02-20 1965-11-23 Magee Carpet Co Method of applying plastic sheet to pile fabric backing
US3273355A (en) * 1962-12-19 1966-09-20 Paul R Hill Heat protection apparatus
US3317644A (en) * 1963-06-24 1967-05-02 Takai Unokichi Method for producing a plastic fabric having pile-like projections
US3312583A (en) * 1963-10-02 1967-04-04 James J Rochlis Apertured and staggered molded pile product
US3382122A (en) * 1964-02-25 1968-05-07 George S. Nalle Jr. Method of making plastic rugs of plastic thread loops bonded to a plastic base
US3369949A (en) * 1966-08-08 1968-02-20 Forrest Norman Method of making a flexible mold
US3655497A (en) * 1967-09-28 1972-04-11 Tenneco Chem Synthetic suede
US3696183A (en) * 1969-10-30 1972-10-03 Ici Ltd Forming a pile on an article
US4065245A (en) * 1973-08-21 1977-12-27 Metzeler Schaum Gmbh Apparatus for producing sheeting having a fibrous surface
US4000230A (en) * 1973-08-21 1976-12-28 Metzeler Schaum Gmbh Process for producing sheeting having fibrous surface
FR2332847A1 (en) * 1975-11-28 1977-06-24 Roehm Gmbh SURFACE PROFILING PROCESS FOR LARGE SURFACE PRODUCTS OF THERMOPLASTIC SYNTHETIC MATERIALS
US4240857A (en) * 1978-08-08 1980-12-23 Allied Chemical Corporation Fiber reinforced multi-ply stampable thermoplastic sheet
US5507902A (en) * 1992-06-25 1996-04-16 R.H. Wyner Associates, Inc. Multi-layered sheet
US5874140A (en) * 1994-04-19 1999-02-23 R.H. Wyner Associates, Inc. Sheet material with adhesive
US6605332B2 (en) 1997-07-29 2003-08-12 3M Innovative Properties Company Unitary polymer substrate having napped surface of frayed end microfibers
US20040005434A1 (en) * 1997-07-29 2004-01-08 3M Innovative Properties Company Microstructured polymer substrate
US7070727B2 (en) 1997-07-29 2006-07-04 3M Innovative Properties Company Methods for making microstructured polymer substrates
US8197734B1 (en) * 2007-03-22 2012-06-12 Dynasty Footwear, Ltd. Composite sheet materials and processes for manufacturing same
US8414810B1 (en) 2007-03-22 2013-04-09 Dynasty Footwear, Ltd. Composite sheet materials and processes for manufacturing same
US8608996B2 (en) 2007-03-22 2013-12-17 Dynasty Footwear, Ltd. Composite sheet materials and processes for manufacturing same

Similar Documents

Publication Publication Date Title
US3179550A (en) Pile surfaced product and method of forming same
US4258093A (en) Molding nonwoven, needle punched fabrics into three dimensional shapes
US2500282A (en) Fibrous products and process for making them
US4351683A (en) Method of forming web material
US3436442A (en) Process and apparatus for manufacturing flocked fabric
DE2053408A1 (en) Method and device for Her provide an object with a plush-like surface
US4276346A (en) Thermoplastics articles having a surface fused to cloth
US2823156A (en) Vinyl coated knit fabric
US3230127A (en) Process for forming plastic coated articles
US3390403A (en) Oriented pile structure
US3694873A (en) Method of preparing a tufted rug with cellular fibers
DE1812358B2 (en) Process for the production of tufted carpets
DE2745032A1 (en) TREATMENT PROCESS FOR A PLUSH SURFACE PRODUCT
US2994940A (en) Plastic coated fabric and method of making same
US4186235A (en) Thermoplastics articles having a surface fused to cloth
US3127306A (en) Stretch type fabrics having temporary stability
DE19812097C1 (en) Semi-finished thermoplastic film material with fine hair piles on one surface
US4362774A (en) Drapery fabric foam backing
US3746608A (en) Shaped article of synthetic resin having mechanically disordered orientation
DE1753695A1 (en) Plastic material of artificial leather-like nature, as well as a method for producing such a material and device for carrying out such a method
DE2359565A1 (en) METHOD AND DEVICE FOR THE MANUFACTURING OF OBJECTS WITH PLUG-IN SURFACE
US3307961A (en) Method of producing air permeable sheet material
DE2538851A1 (en) PRODUCTS WITH PLUSH SURFACE
US2926100A (en) Method of producing decorative sheet material
US3622428A (en) Staple fiber reinforced thermoplastic film