US2990278A - Method and apparatus for transferring and fixing xerographic images - Google Patents

Method and apparatus for transferring and fixing xerographic images Download PDF

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US2990278A
US2990278A US556326A US55632655A US2990278A US 2990278 A US2990278 A US 2990278A US 556326 A US556326 A US 556326A US 55632655 A US55632655 A US 55632655A US 2990278 A US2990278 A US 2990278A
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image
xerographic
powder
plate
support material
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US556326A
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Chester F Carlson
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Xerox Corp
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Xerox Corp
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00—Apparatus for electrographic processes using a charge pattern
    • G03G15/14—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base
    • G03G15/16—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer
    • G03G15/1605—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer using at least one intermediate support
    • G03G15/161—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer using at least one intermediate support with means for handling the intermediate support, e.g. heating, cleaning, coating with a transfer agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S101/00—Printing
    • Y10S101/37—Printing employing electrostatic force

Definitions

  • This invention relates to the field of xerography and, particularly, to an improved method of and apparatus for transferring and fixing a xerographic powder image on a support.
  • the invention relates to an improved method and apparatus for transferring and fixing xerographic powder images on support surfaces of a type which may be injured by the use of conventional xerographic image fixing techniques, or in applications in which conventional fixing techniques cannot conveniently be employed.
  • the conventional heat fusing or vapor solvent fixing techniques that are widely employed in xerographic installations cannot always be employed in applications in which there is a critical requirement to maintain a predetermined moisture content or the dimensional stability of the support material.
  • Such conditions occur, for example, in the formation of xerographic images on perforated record cards of the type
  • metal layers such as grained zinc or aluminum lithographic plates or electroplated metal layers on plastic insulators which are used as intermediates in printed circuit manufacture
  • the metal layers are not only frequently damaged by heat fusion of the xerographic powder image but are also not well adapted to the electrostatic transfer of the xerographic powder image thereto because of their conductivity or rigidity or both.
  • the powder image may be transferred to smooth-surfaced intermediate support material, tackified while in contact with the intermediate support and, while the powder image is in tackified condition, pressed against the final support surface so that the tackified image is forced into the interstices thereof and forms a firm bond therewith, whereby the powder image remains adhered to the final support surface when it is separated from the intermediate support material.
  • a xerographic plate comprising a photoconductive insulating material on a conductive backing is given a uniform electric charge over its surface and is then exposed to the subject matter to be reproduced, usually by conventional projection techniques. This exposure discharges the plate areas in accordance with the light intensity which reaches them, and thereby creates an electrostatic latent image on or in the plate coating. Development of the image is effected with a finely-divided material such as an electroscopic powder which is brought into contact with the photoconductive insulating material and is held thereon electrostatically in a pattern corresponding to the electrostatic latent image. Thereafter, the developed xerographic image is transferred to a support material to which it may be fixed by any suitable means.
  • the developing material particles are held to the support entirely by electrostatic attraction at this stage or" the process, and, thus, are subject to being smudged during handling. Therefore, whenever an electrostatic image is developed to form a xerographic powder image, and such powder image is then transferred to another support material, it is generally required that the powder image subsequently be fixed to the ultimate support material on which it is formed.
  • the type of fixing technique that is employed depends on the requirements of any given installation. For example, the pigmented resins used for line copy and/or half-tone work are commonly fixed by heat fusing, whereby the powder particles of the image are suificiently tackified to flow into the interstices of the support material and form a firm bond therewith. Upon cooling of the image, the bonded pigment forms a permanent record of the copy to be reproduced.
  • tackified and the several variant forms thereof used throughout the specification, is employed to define the condition of the powder particles that form the copy pattern when treated in a manner such that the individual powder particles soften and coalesce, and in which state they become sticky and readily adhere to other surfaces. Although this condition necessarily requires a flowing-together of the powder particles to effect a thorough fusion thereof, it is to be understood that the extent of such flowing is not sufiicient to extend beyond the boundary of the pattern in which the particles are formed.
  • the principal object of the present invention is to provide an improved method for transferring and heat fixing a xerographic powder image on a support without affecting the dimensional stability or utilization characteristics of such support.
  • a further object is to provide an improved method for transferring and heat fixing a xerographic image on a support without the requirement for specialized support material.
  • a further object is to provide an improved method and apparatus for transferring and heat fixing xerographic powder images on perforated record cards, metal sheets, electroplated metal layers, and similar types of support material.
  • a further object of the invention is to provide an improved apparatus and method for transferring and heat fixing xerographic powder images in a rapid, economical and efficient manner.
  • FIG. 1 is a schematic sectional view of a conventional type of xerographic processing machine adapted to perform the method of the invention and employing a smooth-surfaced continuous belt as the intermediate support surface;
  • FIG. 2 is a schematic sectional view of apparatus similar to that shown in FIG. 1 but employing an expendable smooth-surface paper web as the intermediate support material.
  • the basic process is essentially the same as that disclosed in the above mentioned Carlson patent, but differs in some respects in the several materials and techniques employed, depending upon the type of copy to be reproduced.
  • the xerographic plate currently in commercial use normally has a photoconductive layer of amorphous selenium deposited on a metal backing plate, usually of aluminum, although it also may be made of brass or other materials,
  • a metal backing plate usually of aluminum, although it also may be made of brass or other materials.
  • Such 4 i a plate is usually charged by moving it relatively to a fine wire assembly held at high potential, so that corona current is emitted, whereby a uniform electrostatic charge is applied to the photoconductive surface of the plate.
  • this surface can accept and hold an electrostatic charge but when it is exposed to light or other form of radiation, the charge decays in an amount that is substantially proportional to the radiation.
  • a charge pattern remains on the plate surface in the form of an electrostatic latent image of the subject.
  • the electrostatic image is a mirror image or reverse reading reproduction of the original subject matter.
  • This electrostatic image is then developed by dusting it with a finely divided powder that has been given an electrostatic charge of opposite sign to the charge comprising the electrostatic latent image 011 the zerographic plate.
  • the reverse reading powder image is usually transferred to a sheet of support material, by means of electrostatic transfer techniques, to form a direct reading powder particle image on the support material.
  • This is accomplished by placing the sheet of support material over the powder particle image on the xerographic plate, and by applying corona discharge uniformly to the exposed surface of the support material to charge it to a polarity opposite to that of the charge on the particles forming the powder image. This causes the powder particles to adhere electrostatically to the support material so that, when the support material is separated from the plate, substantially all of the pigmented resin particles remain on the support material.
  • the xerographic powder image is fixed on the support material either by heat fusing or by exposing the powder image to an atmosphere of solvent for the particular type of resin employed.
  • an electrostatic latent image of the subject matter to be reproduced is formed on a xerographic plate, as in general commercial practice.
  • the electrostatic latent image be formed in direct reading position on the xerographic plate instead of in reverse reading position, as in usual practice. This may be accomplished conveniently by placing an optical image reversingv device, such as a prism, in the light path between the subject matter and the xerographic plate, or by turning the film over in the projector.
  • the electrostatic image on the xerographic plate is then developed, in usual manner, preferably by cascading with oppositely charged particles of pigmented powdered resin, whereby the powder particles are electrostatically attracted to the latent image to form a direct reading powder image of the subject matter on the xerographic plate.
  • This powder image is then electrostatically transferred to an intermediate support material which is preferably of such composition that it does not readily or effectively form a mechanical bond with the powdered developing material, either in its dry or tackified state, but readily permits the powder material to be bonded thereto electrostatically.
  • such intermediate support material comprises a relatively heat insensitive plastic sheet such as Teflon or Kel-F, each of which is a fluorinated vinyl carbon material of such physical characteristics that it is substantially adhesive to dry or tackified xerographic developing materials.
  • a relatively heat insensitive plastic sheet such as Teflon or Kel-F
  • fluorinated vinyl carbon material of such physical characteristics that it is substantially adhesive to dry or tackified xerographic developing materials.
  • Other materials that have relatively little affinity for developing material such as silicone treated kraft paper or closely woven glass fiber cloth, may also be employed, if desired.
  • materials having a low bond strength for tackified and/ or hardened powder images are considered more practicable for use with the method of the invention, it should be noted that materials having a higher bond strength for powder image material, such as paper, may
  • the xerographic powder image is electrostatically adhered to the intermediate support material, it is tackified by the application of heat to a degree that it becomes sufficiently sticky readily to adhere to other surfaces. While in this condition, the final support material, e.g., a perforable record card, is superposed on the tackified image and then is uniformly pressed into intimate surface contact with the intermediate support material. In the preferred embodiment of the invention, it is desirable that the intermediate support material have a lower bond strength for tackified and hardened powder images than that of the final support surface for the image material, although, as described below, this condition is not essential to the successful practice of the invention.
  • the surface of the final support material should be such that the application of pressure causes the tackified powder material to flow into the interstices of the final support material and physically bond therewith, whereas relatively no bonding occurs between the tackified powder material and the surface of the intermediate support material.
  • the final support material with the tackified powder image adhered thereto is separated from the intermediate support material by any suitable means.
  • separation is preferably effected in timed relation to the hardening of the tackified powder image, in accordance with the type of intermediate support material employed, whereby the image forms a permanent bond with the surface of the final support material and provides a direct reading reproduction of the subject matter thereon.
  • xerographic images may be transferred and fixed on final support surfaces of types which heretofore were considered impractical or inconvenient to receive images of this type.
  • the transfer can he performed with extreme rapidity so that there is very little heat transfer between the intermediate support surface and the final support surface whereby even heat-sensitive materials may be used for final support surfaces without danger of damage thereto.
  • relatively rigid material such as a grained zinc or aluminum lithographic plates or electroplated plastic material
  • the flexibility of the intermediate support material allows it to conform closely to the final support surface in order to provide a complete transfer of the xerographic image.
  • pneumatic pressure pads or similar devices may be employed in the final transfer step to obtain close conformity with curved surfaces and even with somewhat irregularly shaped surfaces, as in the ornamentation of metal or china articles, or relatively rough paper or cloth.
  • the final support surface With reference to the separation of the final support surface from the intermediate support surface, it is noted above that this should be effected in timed relation to the hardening of the tackified powder image, in accord ance with the type of intermediate support material employed. As soon as contact is made between the tackified powder image and the relatively cold final support surface, the final support surface begins to absorb heat from the image and from the intermediate support layer whereby the temperature of the fused toner begins to approach its hardening point. When an adhesive intermediate support material is employed it is generally preferred, though not necessary, to maintain contact until the toner solidifies as this permits the transfer of a maximum of the toner material to the final surface.
  • the intermediate support surface is not adhesive, e.g., when plain paper is used, it is usually desirable to bring the surfaces together and then separate them rapidly before the tackified toner adjacent to the intermediate sheet is completely hardened, as it is difficult to obtain a clean separation after bonding is completed.
  • the lat ter method may be employed even though an adhesive intermediate support material is used, although the transfer is not quite as complete. It should be noted that hardening of the toner image begins adjacent to the cool final surface so that, with accurate timing, separation can be effected after some of the toner has hardened against the final surface but before a bond is formed to the still warm intermediate surface.
  • the separation time may be controlled within relatively wide limits, as desired, by suitable selection of toner material components and by variations in the temperature applied to tackify the toner.
  • FIG. 1 A typical apparatus for practicing the method of the invention is disclosed in FIG. 1 which constitutes an adaptation of a xerographic processing machine of the type disclosed in co-pending application S.N. 393,058, filed in the name of Clyde R. Mayo et al. on November 19, 3, and which is currently in extensive commercial use under the name of XeroX Copyflo No. 1 continuous printer, manufactured by The Haloid Company of Rochester, New York.
  • a xerographic plate having a photoconductive surface and a conductive backing is arranged in the form of a cylindrical drum 1 and is mounted for rotation on a shaft 2 that is rotated at a predetermined speed by suitable motive means (not shown).
  • Subject matter that is to be reproduced is represented by successive frames of a microfilm 3 that is fed from a supply reel 4 to a take-up reel 5 by suitable driving mechanism which effects travel of the film at a rate proportional to the speed of the drum and the degree of magnification of the film image projected onto drum 1.
  • a light projection system 6 is pro vided to direct light through microfilm 3 and to project images from the film through an optical system 7, which magnifies the image, and a prism 8 that reverses the image and reflects it through a slit onto a portion of the photoconductive surface of xerographic drum 1.
  • the prism may be eliminated by turning the film over in the projector and projecting it directly on the drum.
  • Drum 1 travels in a counterclockwise direction and, during the course of its rotation, a given portion of its photoconductive surface is first subjected to the operation of a cleaning brush 12 that removes any adhering developing material, following which the cleaned portion of the photoconductive surface may be illuminated by a fluorescent discharge lamp 13 which insures removal of any electrostatic charges remaining on the surface of the drum and which may have been induced by the cleaning brush or other source.
  • a cleaning brush 12 that removes any adhering developing material
  • the cleaned portion of the photoconductive surface may be illuminated by a fluorescent discharge lamp 13 which insures removal of any electrostatic charges remaining on the surface of the drum and which may have been induced by the cleaning brush or other source.
  • the drum surface After passing under discharge lamp 13, the drum surface is next subjected to corona discharge from a charging grid 14 which imposes the required electrostatic charge on the drum surface.
  • the drum surface is next exposed to a light image of the subject matter through slit 9 whereby the photoconductive surface is discharged in accordance with
  • the drum surface passes through a developing chamber consisting of a housing '16, located adjacent the surface of drum 1 and extending from side to side thereof, forming a closed and substantially sealed chamber wherein development of the electrostatic image takes place.
  • Development is eifected by cascading oppositely charged particles of pigmented resin material 17 over the surface of the drum, in transit.
  • the developer particles are projected into contact with the drum by means of a slide 18, and the excess particles fall to the bottom of the developing chamber from which they are elevated by a bucket type conveyor mechanism 19 and returned to the upper end of slide 18 for reuse.
  • Suitable means may be provided to replenish the developing material as it is expended on the drum surface.
  • an endless belt 22 that is mounted for movement over horizontally arranged rollers 23 and 24 and which contacts the surface of Xerographic drum 1 over a portion of its path of travel.
  • belt 22 is preferably formed of a smooth-surfaced adhesive plastic, such as Teflon or Kel-F, to which the powder image does not adhere even though tackified.
  • Suitable motive means are provided to move the belt at a linear rate equal to the peripheral speed of the drum so that pposed surfaces of the drum and belt remain in register throughout their period of contact.
  • any convenient belt tensioning device may be employed to minimize slippage of the belt.
  • a corona discharge electrode 25 is mounted beneath belt 22 in the area in which the belt and drum surface are in contact. Electrode 25 is continuously energized from a suitable power source to emit an electrostatic charge opposite to that on the xerographic image particles, whereby the image particles are electrostatically attracted from the surface of the drum and are transferred to the surface of belt 22 and remain electrostatically bonded thereto.
  • the xerographic powder image on the belt passes into a form of tackifying or heat fusing chamber 28, wherein the powder image is tackified.
  • a tackifier 28 of the heat fusing type wherein resistance wires 29 are energized I to a degree to emit sufficient radiation to cause the powder particles to soften and coalesce to form a sticky surfaced image of the subject matter to be reproduced, in which condition the powder image emerges from the tackifying chamber and begins to pass over horizontal roller 24.
  • the apparatus includes, by way of illustration, a record card feeding apparatus of the type commonly employed in perforated card controlled machines.
  • record cards are placed in a card magazine and are passed seriatim to suitable feed rolls whereby they are advanced to be engaged between belt 22, as it passes over roller 24, and a pressure roll that presses them against the tackified powder image on the belt surface to effect image transfer, after which the cards are passed to a receiving magazine.
  • the record cards 33, or comparable types of final support surface are placed in a magazine 34 in which they are urged into contact with a card feeding mechanism by means of a suitable spring 35.
  • the cards are advanced, one at a time, by a picker knife 36 that is guided for reciprocating movement in suitable ways and is actuated, through a link 37 and pivotally mounted crank 38, by a cyclically operated cam 39 to advance the cards in timed relation to the projection of images on xerographic drum 1.
  • each card 33 is passed from magazine 34 it is gripped by conventional card feed rolls 40 that engage the edges of the card and move it downwardly to a position in which it is pressed against the surface of continuous belt 22 by a pressure roll 42.
  • roll 24 and pressure roll 42 are each provided with a resilient surface whereby the card is pressed into intimate surface contact with the tackified powder image on the surface of continuous belt 22. The pressure applied at this point is such that the tackified powder image is caused to flow into the interstices of the record card surface and bond thereto.
  • suitable ejector rolls 44 that are continuously rotating and serve to pass the card onto a deflecting chute 45 whereby it is fed into a receiving magazine 46.
  • suitable guide means 47 may be provided to assist in separating the card from belt 22 and guiding it into engagement with ejector rolls 44.
  • horizontal pressure roll 22 may be heated, if desired, to insure that the tackified powder image remains in a sufliciently sticky state to permit its adhesion to the record card during the pressure applying step.
  • such heating facilitates the removal of the tackified powder image from the surface of belt 22 in the event belt 22 is formed of a material to which the tackified powder image may have any tendency to adhere.
  • a cleaning brush 48 may be provided to remove any residual portions of the powder image after the transfer to the final support material.
  • suitable means may be employed to discharge the web during each cycle of operation.
  • a pair of grounded alpha particle emitters 49 may be arranged on either side of web 22 for this purpose. Emitters 49 may conveniently be in the form of metal plates coated with polonium or other radioactive material, as described in Carlson Patent No. 2,701,764, issued February 8, 1955.
  • a pair of AC. corona discharge wires supplied from a suitable high voltage source, may also be employed to discharge the web.
  • the apparatus is adapted for use in applications in which it is desired to employ an expendable material as the intermediate support surface.
  • all elements are identical to those shown in FIG. 1 and function as described above, except that the continuous belt 22 is replaced by a paper or glassine web 50 that may be fed from a supply roll 51 and over a guide roll 52 and thence into surface contact with xerographic drum 1, as before.
  • web 50 is passed between pressure rolls 24 and 42, as above, wherein the tackified image is transferred to a record card 33 and the web is then rolled onto a take-up roll 53.
  • the latter arrangement is particularly applicable to installations in which it is permissible to transfer something less than the entire Xerographic powder image to the final support surface.
  • a certain amount of the powder image will, when tackified, soak into the intermediate support material and will not be transferred to the final support surface during the final transfer step.
  • it permits the use of a low-cost intermediate support surface and eliminates the need for cleaning the intermediate support surface after the second transfer step.
  • most paper stock will withstand temperatures up to 325 F. for quite a long period without turning brown and can even be heated to 400 F. without disintegrating during the fusing of an image, such material can readily be used as the expendable web material in conjunction with present xerographic developing materials which normally can be tackified in the range between F. to 300 F.
  • the method and apparatus of the invention may readily be applied to transferring xerographic powder images to photographic film for the purpose of film titling, or to plastic film which may subsequently be covered by laminating on a plastic cover sheet, as for forming unalterable identification badges.
  • the method which comprises transferring a fusible powder image from a xerographic plate to a heat-insensitive transfer sheet, heating said sheet and the powder image supported thereby to a temperature at which said image becomes adhesive, then pressing the face of said sheet carrying said image against a second surface and removing said transfer sheet to leave an image adhering to said second surface.
  • said second surface is the surface of a material which is damaged by heating to the adhesive temperature of said powder image, said second surface being initially at a lower temperature than the adhesive temperature.
  • the method which comprises transferring a fusible powder image to a heat-sensitive transfer sheet, heating said transfer sheet and the transferred powder image above the melting point of said powder, placing the face of said transfer sheet carrying the molten powder image against a second surface and then removing said transfer sheet from said second surface while said powder image is still molten, to leave at least part of said molten image on said second surface.
  • the method of transferring and fixing the powder image to a final support material comprising the steps of transferring the powder image to a smooth-surfaced intermediate support material, heat fusing the powder image in contact with the intermediate support material, superposing the final support material on the fused powder image, pressing the final support material into surface contact with the intermediate support material, and separating the final support material from the intermediate support material.
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, a web of smooth-surface insulating material, a portion of said web being in surface contact with a portion of said xerographic plate, means for transferring a xerographic powder image from the surface of the plate to the surface of the web, means for heat fusing a xerographic powder image supported by the web, means for superposing and pressing a support material on a fused powder image on the web surface, and means for separating the support material from the web surface.
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, means for superposing and pressing a support material on a tackified powder image on the belt surface, and means for separating the support material from the belt surface.
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostaticlly attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for eleotrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for taekifying a xerographic powder image supported by the belt, means for advancing support material into superposing relationship with tackified powder images on said belt, means for pressing support material into surface contact with tackified powder images on the
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surface insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographie powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, means for advancing support material into superposing relationship with tackified powder images on said belt, means for pressing support material into surface contact with tackified powder images on the belt surface, and means
  • An apparatus for transferring and fixing a xerographic powder image to a support surface of the perforable record card type comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically 'attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the sur face of the plate to the surface of the belt, heat fusing means for tackifying a Xerographic powder image supported by the belt, card feeding means for advancing record cards into superposing relationship with tackified powder images on said belt, means for pressing record cards into surface
  • An apparatus for transferring and fixing a xerographic powder image to a support surface of the perforable record card type comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said Xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, card feeding means for advancing record cards into superposing relationship with tackified powder images on said belt, means for pressing record cards into surface contact with t
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subjeot on the plate, a web of insulating material extended between a supply reel and a take-up reel, a portion of said web being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the web, heat fusing means for tackifying a xerographic powder image supported by the web, means for superposing and pressing a support material on a tackified powder image on the web surface, and means for separating the
  • An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, a web of insulating material extended between a supply reel and a take-up reel, portion of said web being in surface contact with a portion of said xerographic plate, means for transferring a xerographic powder image from the surface of the plate to the surface of the web, heat fusing means for taclrifying a xerographic powder image supported by the web, means for advancing support material into superposing relationship with tackified powder images on said web, means for pressing support material into surface contact with tackified powder images on the

Description

June 27, 1961 c. F. CARLSON 2,990,273
METHOD AND APPARATUS FOR TRANSFERRING AND FIXING XEROGRAPHIC IMAGES Filed Dec. 29, 1955 1 looodooooooo INVENTOR. CHESTER F. CARLSON ATmRA/ZY used in punched card tabulating systems.
United States Patent Office Patented June 27, 1961 METHOD AND APPARATUS FOR TRANSFER- RING AND FIXING XEROGRAPHIC llVIAGES Chester F. Carlson, Pittsford, N.Y., assignor, by mesne assignments, to Haloid Xerox Inc., Rochester, N.Y., a
corporation of New York Filed Dec. 29, 1955, 'Ser. No. 556,326 18 Claims. (Cl. 96-1) This invention relates to the field of xerography and, particularly, to an improved method of and apparatus for transferring and fixing a xerographic powder image on a support.
More specifically, the invention relates to an improved method and apparatus for transferring and fixing xerographic powder images on support surfaces of a type which may be injured by the use of conventional xerographic image fixing techniques, or in applications in which conventional fixing techniques cannot conveniently be employed. For example, the conventional heat fusing or vapor solvent fixing techniques that are widely employed in xerographic installations cannot always be employed in applications in which there is a critical requirement to maintain a predetermined moisture content or the dimensional stability of the support material.
Such conditions occur, for example, in the formation of xerographic images on perforated record cards of the type In addition, when xerographic powder images are to be formed on metal layers such as grained zinc or aluminum lithographic plates or electroplated metal layers on plastic insulators which are used as intermediates in printed circuit manufacture, it is found that the metal layers are not only frequently damaged by heat fusion of the xerographic powder image but are also not well adapted to the electrostatic transfer of the xerographic powder image thereto because of their conductivity or rigidity or both. In order to apply xerographic powder images to surfaces of the type mentioned, it has been found that the powder image may be transferred to smooth-surfaced intermediate support material, tackified while in contact with the intermediate support and, while the powder image is in tackified condition, pressed against the final support surface so that the tackified image is forced into the interstices thereof and forms a firm bond therewith, whereby the powder image remains adhered to the final support surface when it is separated from the intermediate support material. In the process of Xerography, for example, as disclosed in Carlson Patent 2,297,691, issued October 6, 1952, a xerographic plate comprising a photoconductive insulating material on a conductive backing is given a uniform electric charge over its surface and is then exposed to the subject matter to be reproduced, usually by conventional projection techniques. This exposure discharges the plate areas in accordance with the light intensity which reaches them, and thereby creates an electrostatic latent image on or in the plate coating. Development of the image is effected with a finely-divided material such as an electroscopic powder which is brought into contact with the photoconductive insulating material and is held thereon electrostatically in a pattern corresponding to the electrostatic latent image. Thereafter, the developed xerographic image is transferred to a support material to which it may be fixed by any suitable means.
The developing material employed may be of any convenient type suitable to the requirements of a particular application. Fore example, in line copy applications, the developing material may be of the type disclosed in Walkup Patent 2,618,551, issued November 18, 1952, wherein a pigmented powdered resin is combined with coated glass bead carriers and is thereby triboelectrically charged to a polarity opposite to that of the electrostatic latent image to be developed. Subsequently, the combined material is cascaded over the latent image whereby the resin particles are caused to adhere electrostatically to the charged portions of the image. Various other pigmented resins, usually having a polystyrene base, are available to suit specific applications. Materials of the type disclosed in Copley Patent No. 2,659,570, issued November 17, 1953, may also be employed.
Regardless of the type of development, the developing material particles are held to the support entirely by electrostatic attraction at this stage or" the process, and, thus, are subject to being smudged during handling. Therefore, whenever an electrostatic image is developed to form a xerographic powder image, and such powder image is then transferred to another support material, it is generally required that the powder image subsequently be fixed to the ultimate support material on which it is formed. The type of fixing technique that is employed depends on the requirements of any given installation. For example, the pigmented resins used for line copy and/or half-tone work are commonly fixed by heat fusing, whereby the powder particles of the image are suificiently tackified to flow into the interstices of the support material and form a firm bond therewith. Upon cooling of the image, the bonded pigment forms a permanent record of the copy to be reproduced.
The term tackified, and the several variant forms thereof used throughout the specification, is employed to define the condition of the powder particles that form the copy pattern when treated in a manner such that the individual powder particles soften and coalesce, and in which state they become sticky and readily adhere to other surfaces. Although this condition necessarily requires a flowing-together of the powder particles to effect a thorough fusion thereof, it is to be understood that the extent of such flowing is not sufiicient to extend beyond the boundary of the pattern in which the particles are formed.
The technique of heat fixing xerographic images has been found to be highly suitable for many types of applications and is in wide commercial use. However, under certain conditions, the application of heat may adversely affect the dimensional stability or other physical caharacteristics of the support on which the xerographic image is to be formed.
A typical example of such a situation arises in the field of record controlled machines wherein coded perforations representing alphabetic and/or numeric characters are punched in record cards or in tape and serve to control various operations of a wide variety of machines, such as accounting machines, tabulating machines, computers, etc. In this field of endeavor it has been found highly desirable to form visible xerographic images on the record cards to supplement or duplicate the perforated data indications and thereby amplify or facilitate the use of such records in their regular applications. However, it has also been found that the conventional xerographic image heat fixing technique mentioned above cannot conveniently be employed under all conditions without occasionally affecting the dimensional stability and/or moisture content of a record card. For example, the application of excessive heat to fix the image can, under certain conditions, result in differential expansion or contraction of portions of the card to an extent to make it unfit for use in its normally intended operation. Obviously, any change in the physical characteristics of the record cards that would affect their operability during card sensing, card feeding, or card sorting operations cannot be tolerated.
Heretofore, various techniques have been proposed whereby a xerographic powder image is fixed in a manner to form a permanent image on a support such as a perforated record card or similar device without affecting the dimensional stability and/or moisture content thereof, and whereby the normal utilization characteristics of the support remain unimpaired. Although such xerographic powder image fixing techniques are well suited for use in many applications, it has been found that further improvements may be made in the formation of permanent visible images by xerographic techniques whereby the dimensional stability and utilization characteristics of support material may be preserved and, at the same time, may be applied to form xerographic images on support materials of types which, heretofore, were not considered to be conveniently r practically adapted to use in xerographic systems.
The principal object of the present invention is to provide an improved method for transferring and heat fixing a xerographic powder image on a support without affecting the dimensional stability or utilization characteristics of such support. A further object is to provide an improved method for transferring and heat fixing a xerographic image on a support without the requirement for specialized support material. A further object is to provide an improved method and apparatus for transferring and heat fixing xerographic powder images on perforated record cards, metal sheets, electroplated metal layers, and similar types of support material. A further object of the invention is to provide an improved apparatus and method for transferring and heat fixing xerographic powder images in a rapid, economical and efficient manner.
These and other objects are attained, in accordance with the method of the invention, in conjunction with a xerographic process wherein an electrostatically charged xerographic plate is exposed to a projected image to form an electrostatic latent image on the plate corresponding to the projected image and the plate is developed with oppositely charged particles of tackifiable developing material that are attracted to the latent image to form a xerographic powder image corresponding to the projected image, transferring the xerographic powder image to a smooth-surfaced intermediate support material, heat tackifying the powder image while in contact with the intermediate support material, superposing a final support material on the tackified powder image, pressing the final support material into surface contact with the intermediate support material, and separating the final support material from the intermediate support material, whereby, during the separating step, the tackified image material adheres to the surface of the final support material and is fixed thereon as it cools and hardens.
Typical arrangements for carrying out the method of the invention are shown in the accompanying drawings, in which:
FIG. 1 is a schematic sectional view of a conventional type of xerographic processing machine adapted to perform the method of the invention and employing a smooth-surfaced continuous belt as the intermediate support surface; and
FIG. 2 is a schematic sectional view of apparatus similar to that shown in FIG. 1 but employing an expendable smooth-surface paper web as the intermediate support material.
In the various embodiments of xerographic processes currently in general commercial use, the basic process is essentially the same as that disclosed in the above mentioned Carlson patent, but differs in some respects in the several materials and techniques employed, depending upon the type of copy to be reproduced. For example, in the reproduction of line copy, the xerographic plate currently in commercial use normally has a photoconductive layer of amorphous selenium deposited on a metal backing plate, usually of aluminum, although it also may be made of brass or other materials, Such 4 i a plate is usually charged by moving it relatively to a fine wire assembly held at high potential, so that corona current is emitted, whereby a uniform electrostatic charge is applied to the photoconductive surface of the plate. In the dark, this surface can accept and hold an electrostatic charge but when it is exposed to light or other form of radiation, the charge decays in an amount that is substantially proportional to the radiation. Thus, after charging and exposing to the subject matter to be reproduced, a charge pattern remains on the plate surface in the form of an electrostatic latent image of the subject. In most systems, the electrostatic image is a mirror image or reverse reading reproduction of the original subject matter. This electrostatic image is then developed by dusting it with a finely divided powder that has been given an electrostatic charge of opposite sign to the charge comprising the electrostatic latent image 011 the zerographic plate.
After development, the reverse reading powder image is usually transferred to a sheet of support material, by means of electrostatic transfer techniques, to form a direct reading powder particle image on the support material. This is accomplished by placing the sheet of support material over the powder particle image on the xerographic plate, and by applying corona discharge uniformly to the exposed surface of the support material to charge it to a polarity opposite to that of the charge on the particles forming the powder image. This causes the powder particles to adhere electrostatically to the support material so that, when the support material is separated from the plate, substantially all of the pigmented resin particles remain on the support material. Thereafter, in most applications, the xerographic powder image is fixed on the support material either by heat fusing or by exposing the powder image to an atmosphere of solvent for the particular type of resin employed.
In the practice of the method of the present invention, an electrostatic latent image of the subject matter to be reproduced is formed on a xerographic plate, as in general commercial practice. However, in order to obtain a direct reading image on the final support material, it is preferred at this point that the electrostatic latent image be formed in direct reading position on the xerographic plate instead of in reverse reading position, as in usual practice. This may be accomplished conveniently by placing an optical image reversingv device, such as a prism, in the light path between the subject matter and the xerographic plate, or by turning the film over in the projector.
The electrostatic image on the xerographic plate is then developed, in usual manner, preferably by cascading with oppositely charged particles of pigmented powdered resin, whereby the powder particles are electrostatically attracted to the latent image to form a direct reading powder image of the subject matter on the xerographic plate. This powder image is then electrostatically transferred to an intermediate support material which is preferably of such composition that it does not readily or effectively form a mechanical bond with the powdered developing material, either in its dry or tackified state, but readily permits the powder material to be bonded thereto electrostatically. Preferably, such intermediate support material comprises a relatively heat insensitive plastic sheet such as Teflon or Kel-F, each of which is a fluorinated vinyl carbon material of such physical characteristics that it is substantially adhesive to dry or tackified xerographic developing materials. Other materials that have relatively little affinity for developing material, such as silicone treated kraft paper or closely woven glass fiber cloth, may also be employed, if desired. Although materials having a low bond strength for tackified and/ or hardened powder images are considered more practicable for use with the method of the invention, it should be noted that materials having a higher bond strength for powder image material, such as paper, may
also be employed in the form of an expendable web, as described below.
While the xerographic powder image is electrostatically adhered to the intermediate support material, it is tackified by the application of heat to a degree that it becomes sufficiently sticky readily to adhere to other surfaces. While in this condition, the final support material, e.g., a perforable record card, is superposed on the tackified image and then is uniformly pressed into intimate surface contact with the intermediate support material. In the preferred embodiment of the invention, it is desirable that the intermediate support material have a lower bond strength for tackified and hardened powder images than that of the final support surface for the image material, although, as described below, this condition is not essential to the successful practice of the invention. In any event, the surface of the final support material should be such that the application of pressure causes the tackified powder material to flow into the interstices of the final support material and physically bond therewith, whereas relatively no bonding occurs between the tackified powder material and the surface of the intermediate support material.
Thereafter, the final support material with the tackified powder image adhered thereto is separated from the intermediate support material by any suitable means. As described below, separation is preferably effected in timed relation to the hardening of the tackified powder image, in accordance with the type of intermediate support material employed, whereby the image forms a permanent bond with the surface of the final support material and provides a direct reading reproduction of the subject matter thereon.
Thus, there is provided an improved method whereby xerographic images may be transferred and fixed on final support surfaces of types which heretofore were considered impractical or inconvenient to receive images of this type. The transfer can he performed with extreme rapidity so that there is very little heat transfer between the intermediate support surface and the final support surface whereby even heat-sensitive materials may be used for final support surfaces without danger of damage thereto. In the event relatively rigid material, such as a grained zinc or aluminum lithographic plates or electroplated plastic material, is employed as the final support material, the flexibility of the intermediate support material allows it to conform closely to the final support surface in order to provide a complete transfer of the xerographic image. If necessary, pneumatic pressure pads or similar devices may be employed in the final transfer step to obtain close conformity with curved surfaces and even with somewhat irregularly shaped surfaces, as in the ornamentation of metal or china articles, or relatively rough paper or cloth.
With reference to the separation of the final support surface from the intermediate support surface, it is noted above that this should be effected in timed relation to the hardening of the tackified powder image, in accord ance with the type of intermediate support material employed. As soon as contact is made between the tackified powder image and the relatively cold final support surface, the final support surface begins to absorb heat from the image and from the intermediate support layer whereby the temperature of the fused toner begins to approach its hardening point. When an adhesive intermediate support material is employed it is generally preferred, though not necessary, to maintain contact until the toner solidifies as this permits the transfer of a maximum of the toner material to the final surface. When the intermediate support surface is not adhesive, e.g., when plain paper is used, it is usually desirable to bring the surfaces together and then separate them rapidly before the tackified toner adjacent to the intermediate sheet is completely hardened, as it is difficult to obtain a clean separation after bonding is completed. The lat ter method may be employed even though an adhesive intermediate support material is used, although the transfer is not quite as complete. It should be noted that hardening of the toner image begins adjacent to the cool final surface so that, with accurate timing, separation can be effected after some of the toner has hardened against the final surface but before a bond is formed to the still warm intermediate surface. The separation time may be controlled within relatively wide limits, as desired, by suitable selection of toner material components and by variations in the temperature applied to tackify the toner.
A typical apparatus for practicing the method of the invention is disclosed in FIG. 1 which constitutes an adaptation of a xerographic processing machine of the type disclosed in co-pending application S.N. 393,058, filed in the name of Clyde R. Mayo et al. on November 19, 3, and which is currently in extensive commercial use under the name of XeroX Copyflo No. 1 continuous printer, manufactured by The Haloid Company of Rochester, New York. In this arrangement a xerographic plate having a photoconductive surface and a conductive backing is arranged in the form of a cylindrical drum 1 and is mounted for rotation on a shaft 2 that is rotated at a predetermined speed by suitable motive means (not shown). Subject matter that is to be reproduced is represented by successive frames of a microfilm 3 that is fed from a supply reel 4 to a take-up reel 5 by suitable driving mechanism which effects travel of the film at a rate proportional to the speed of the drum and the degree of magnification of the film image projected onto drum 1. A light projection system 6 is pro vided to direct light through microfilm 3 and to project images from the film through an optical system 7, which magnifies the image, and a prism 8 that reverses the image and reflects it through a slit onto a portion of the photoconductive surface of xerographic drum 1. Obviously, the prism may be eliminated by turning the film over in the projector and projecting it directly on the drum.
Drum 1 travels in a counterclockwise direction and, during the course of its rotation, a given portion of its photoconductive surface is first subjected to the operation of a cleaning brush 12 that removes any adhering developing material, following which the cleaned portion of the photoconductive surface may be illuminated by a fluorescent discharge lamp 13 which insures removal of any electrostatic charges remaining on the surface of the drum and which may have been induced by the cleaning brush or other source. After passing under discharge lamp 13, the drum surface is next subjected to corona discharge from a charging grid 14 which imposes the required electrostatic charge on the drum surface. After charging, the drum surface is next exposed to a light image of the subject matter through slit 9 whereby the photoconductive surface is discharged in accordance with the light intensity which reaches it to form an electrostatic latent image of the subject matter to be reproduced,
After exposure, the drum surface passes through a developing chamber consisting of a housing '16, located adjacent the surface of drum 1 and extending from side to side thereof, forming a closed and substantially sealed chamber wherein development of the electrostatic image takes place. Development is eifected by cascading oppositely charged particles of pigmented resin material 17 over the surface of the drum, in transit. The developer particles are projected into contact with the drum by means of a slide 18, and the excess particles fall to the bottom of the developing chamber from which they are elevated by a bucket type conveyor mechanism 19 and returned to the upper end of slide 18 for reuse. Suitable means may be provided to replenish the developing material as it is expended on the drum surface.
In order to provide an intermediate support surface to which the xerographic powder image may be transferred, there is provided an endless belt 22 that is mounted for movement over horizontally arranged rollers 23 and 24 and which contacts the surface of Xerographic drum 1 over a portion of its path of travel. As noted above, belt 22 is preferably formed of a smooth-surfaced adhesive plastic, such as Teflon or Kel-F, to which the powder image does not adhere even though tackified. Suitable motive means are provided to move the belt at a linear rate equal to the peripheral speed of the drum so that pposed surfaces of the drum and belt remain in register throughout their period of contact. If desired, any convenient belt tensioning device may be employed to minimize slippage of the belt.
In order to transfer the xerographic powder image from the drum to the belt surface, a corona discharge electrode 25 is mounted beneath belt 22 in the area in which the belt and drum surface are in contact. Electrode 25 is continuously energized from a suitable power source to emit an electrostatic charge opposite to that on the xerographic image particles, whereby the image particles are electrostatically attracted from the surface of the drum and are transferred to the surface of belt 22 and remain electrostatically bonded thereto.
After transfer, the xerographic powder image on the belt passes into a form of tackifying or heat fusing chamber 28, wherein the powder image is tackified. In the arrangement shown, there is disclosed a tackifier 28 of the heat fusing type wherein resistance wires 29 are energized I to a degree to emit sufficient radiation to cause the powder particles to soften and coalesce to form a sticky surfaced image of the subject matter to be reproduced, in which condition the powder image emerges from the tackifying chamber and begins to pass over horizontal roller 24.
In order to superpose the final support surface on thetackified powder image the apparatus includes, by way of illustration, a record card feeding apparatus of the type commonly employed in perforated card controlled machines. Briefly, in this device record cards are placed in a card magazine and are passed seriatim to suitable feed rolls whereby they are advanced to be engaged between belt 22, as it passes over roller 24, and a pressure roll that presses them against the tackified powder image on the belt surface to effect image transfer, after which the cards are passed to a receiving magazine. Specifically, the record cards 33, or comparable types of final support surface, are placed in a magazine 34 in which they are urged into contact with a card feeding mechanism by means of a suitable spring 35. The cards are advanced, one at a time, by a picker knife 36 that is guided for reciprocating movement in suitable ways and is actuated, through a link 37 and pivotally mounted crank 38, by a cyclically operated cam 39 to advance the cards in timed relation to the projection of images on xerographic drum 1.
As each card 33 is passed from magazine 34 it is gripped by conventional card feed rolls 40 that engage the edges of the card and move it downwardly to a position in which it is pressed against the surface of continuous belt 22 by a pressure roll 42. Preferably, roll 24 and pressure roll 42 are each provided with a resilient surface whereby the card is pressed into intimate surface contact with the tackified powder image on the surface of continuous belt 22. The pressure applied at this point is such that the tackified powder image is caused to flow into the interstices of the record card surface and bond thereto. As each card emerges from engagement with pressure roll 42 and belt 22 it is gripped by suitable ejector rolls 44 that are continuously rotating and serve to pass the card onto a deflecting chute 45 whereby it is fed into a receiving magazine 46. If required, suitable guide means 47 may be provided to assist in separating the card from belt 22 and guiding it into engagement with ejector rolls 44.
Obviously, horizontal pressure roll 22 may be heated, if desired, to insure that the tackified powder image remains in a sufliciently sticky state to permit its adhesion to the record card during the pressure applying step. In
addition, such heating facilitates the removal of the tackified powder image from the surface of belt 22 in the event belt 22 is formed of a material to which the tackified powder image may have any tendency to adhere. In such a case, a cleaning brush 48 may be provided to remove any residual portions of the powder image after the transfer to the final support material. In the event residual electrostatic charge tends to accumulate on web 22, suitable means may be employed to discharge the web during each cycle of operation. For example, a pair of grounded alpha particle emitters 49 may be arranged on either side of web 22 for this purpose. Emitters 49 may conveniently be in the form of metal plates coated with polonium or other radioactive material, as described in Carlson Patent No. 2,701,764, issued February 8, 1955. Alternatively, a pair of AC. corona discharge wires, supplied from a suitable high voltage source, may also be employed to discharge the web.
In the modification of the invention disclosed in FIG. 2, the apparatus is adapted for use in applications in which it is desired to employ an expendable material as the intermediate support surface. In this figure, all elements are identical to those shown in FIG. 1 and function as described above, except that the continuous belt 22 is replaced by a paper or glassine web 50 that may be fed from a supply roll 51 and over a guide roll 52 and thence into surface contact with xerographic drum 1, as before. After the electrostatic transfer of the powder image and the tackification thereof in tackifying chamber 28, web 50 is passed between pressure rolls 24 and 42, as above, wherein the tackified image is transferred to a record card 33 and the web is then rolled onto a take-up roll 53.
The latter arrangement is particularly applicable to installations in which it is permissible to transfer something less than the entire Xerographic powder image to the final support surface. Obviously, in such an arrangement, a certain amount of the powder image will, when tackified, soak into the intermediate support material and will not be transferred to the final support surface during the final transfer step. However, it permits the use of a low-cost intermediate support surface and eliminates the need for cleaning the intermediate support surface after the second transfer step. Inasmuch as most paper stock will withstand temperatures up to 325 F. for quite a long period without turning brown and can even be heated to 400 F. without disintegrating during the fusing of an image, such material can readily be used as the expendable web material in conjunction with present xerographic developing materials which normally can be tackified in the range between F. to 300 F.
Although the method and apparatus of the invention are described, by way of illustration, as applied to the transfer and fixing of fusible xerographic images of line copy to perforated record cards, it is apparent that they are equally applicable for transferring and fixing continuous tone fusible images, and that they may readily be applied for transferring and fixing such types of images to various other types of final support material. For example, by employing a similar type of support surface feeding mechanism Xerographic images may readily be applied to relatively rigid support surfaces such as grained zinc or aluminum lithographic plates, or to electroplated plastic sheets such as are employed in the manufacture of printed circuits. In addition, by employing different types of support surface feeding means, the method and apparatus of the invention may readily be applied to transferring xerographic powder images to photographic film for the purpose of film titling, or to plastic film which may subsequently be covered by laminating on a plastic cover sheet, as for forming unalterable identification badges.
Since many changes could be made in the above construction and many apparently widely different applica tions of the method of the invention could be made without departing from the scope thereof, it is intended that all matter contained in the above description or shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense.
What is claimed is:
1. The method which comprises transferring a fusible powder image from a xerographic plate to a heat-insensitive transfer sheet, heating said sheet and the powder image supported thereby to a temperature at which said image becomes adhesive, then pressing the face of said sheet carrying said image against a second surface and removing said transfer sheet to leave an image adhering to said second surface.
2. The method of claim 1 in which said second surface is the surface of a material which is damaged by heating to the adhesive temperature of said powder image, said second surface being initially at a lower temperature than the adhesive temperature.
3. The method which comprises transferring a fusible powder image to a heat-sensitive transfer sheet, heating said transfer sheet and the transferred powder image above the melting point of said powder, placing the face of said transfer sheet carrying the molten powder image against a second surface and then removing said transfer sheet from said second surface while said powder image is still molten, to leave at least part of said molten image on said second surface.
4. The method of applying an image of fusible material to the surface of a heat-sensitive material, which comprises placing fusible powder on a sheet in the form of an image, heating said sheet and said powder to fuse said powder, then pressing said sheet and fused powder against the surface of said heat-sensitive material and removing said sheet to leave an image of fusible material bonded to said heat-sensitive material.
5. The method as claimed in claim 4 in which said sheet is removed before said fused powder image has completely cooled and solidified.
6. The method of claim 4, in which said sheet is formed of adhesive material and is removed after said fused powder image has solidified.
7. The method of applying an image of fusible material to the surface of a heat-sensitive material, which comprises forming an image of fusible powder on a first surface, transferring said powder image to a sheet material, heating said sheet material and said powder image until said image is fused, then pressing the surface of said sheet material carrying said fused powder image against the substantially unheated surface of said heatsensitive material and separating said surfaces to leave an image on said heat-sensitive material.
8. The method as claimed in claim 7, in which said sheet material is separated from said heat-sensitive material prior to completion of the cooling and solidifying of said fused powder image.
9. The method as claimed in claim 7, in which said sheet material has low bond strength for said fused and solidified powder and said sheet material is separated from said heat-sensitive material after said fused powder image has become solidified by cooling.
10. In the process of xerography wherein an electro statically charged xerographic plate is exposed to projected image to form an electrostatic latent image on the plate corresponding to the projected image and the plate is developed with oppositely charged particles of heat fusible developing material that are attracted to the latent image to form a xerographic powder image corresponding to the projected image, the method of transferring and fixing the powder image to a final support material comprising the steps of transferring the powder image to a smooth-surfaced intermediate support material, heat fusing the powder image in contact with the intermediate support material, superposing the final support material on the fused powder image, pressing the final support material into surface contact with the intermediate support material, and separating the final support material from the intermediate support material.
11. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, a web of smooth-surface insulating material, a portion of said web being in surface contact with a portion of said xerographic plate, means for transferring a xerographic powder image from the surface of the plate to the surface of the web, means for heat fusing a xerographic powder image supported by the web, means for superposing and pressing a support material on a fused powder image on the web surface, and means for separating the support material from the web surface.
12. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, means for superposing and pressing a support material on a tackified powder image on the belt surface, and means for separating the support material from the belt surface.
13. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostaticlly attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for eleotrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for taekifying a xerographic powder image supported by the belt, means for advancing support material into superposing relationship with tackified powder images on said belt, means for pressing support material into surface contact with tackified powder images on the belt surface, and means for separating the support material from the belt surface.
14. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surface insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographie powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, means for advancing support material into superposing relationship with tackified powder images on said belt, means for pressing support material into surface contact with tackified powder images on the belt surface, and means for separating the support material from the belt surface in timed relation to the operation of the pressure applying means.
15. An apparatus for transferring and fixing a xerographic powder image to a support surface of the perforable record card type comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically 'attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the sur face of the plate to the surface of the belt, heat fusing means for tackifying a Xerographic powder image supported by the belt, card feeding means for advancing record cards into superposing relationship with tackified powder images on said belt, means for pressing record cards into surface contact with tackified powder images on the belt surface, and means for separating record cards from the belt surface.
16. An apparatus for transferring and fixing a xerographic powder image to a support surface of the perforable record card type comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, an endless belt of smooth-surfaced insulating material, a portion of said belt being in surface contact with a portion of said Xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the belt, heat fusing means for tackifying a xerographic powder image supported by the belt, card feeding means for advancing record cards into superposing relationship with tackified powder images on said belt, means for pressing record cards into surface contact with tackified powder images on the belt surface, and means for separating record cards from the belt surface in timed relation to the operation of the pressure applying means.
17. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subjeot on the plate, a web of insulating material extended between a supply reel and a take-up reel, a portion of said web being in surface contact with a portion of said xerographic plate, means for electrostatically transferring a xerographic powder image from the surface of the plate to the surface of the web, heat fusing means for tackifying a xerographic powder image supported by the web, means for superposing and pressing a support material on a tackified powder image on the web surface, and means for separating the support material from the web surface.
18. An apparatus for transferring and fixing a xerographic powder image to a support surface comprising, in combination, a cylindrical xerographic plate mounted for rotation about a horizontal axis, means for applying electrostatic charge to the surface of the plate, means for exposing the surface of the plate to a light image of subject matter to be reproduced to form an electrostatic latent image of the subject on the plate, means for developing the latent image with electrostatically attractable powder to form a xerographic powder image of the subject on the plate, a web of insulating material extended between a supply reel and a take-up reel, portion of said web being in surface contact with a portion of said xerographic plate, means for transferring a xerographic powder image from the surface of the plate to the surface of the web, heat fusing means for taclrifying a xerographic powder image supported by the web, means for advancing support material into superposing relationship with tackified powder images on said web, means for pressing support material into surface contact with tackified powder images on the web surface, and means for separating the support material from the web surface in timed relation to the operation of the pressure applying means.
References Cited in the file of this patent UNITED STATES PATENTS 2,221,776 Carlson Nov. 19, 1940 2,297,681 Carlson Oct. 6, 1942 2,357,809 Carlson Sept. 12, 1944 2,503,758 Murray Apr. 11, 1950 2,588,675 Walkup et al. Mar. 11, 1952 2,600,580 Sabel et al. June 17, 1952 2,628,929 Persoon et al. Feb. 17, 1953 2,629,671 Murray Feb. 24, 1953 2,637,651 Copley May 5, 1953 2,693,416 Butterfield Nov. 2, 1954 2,726,166 Greaves Dec. 6, 1955 2,756,676 Steinhilper July 31, 1956 2,758,524 Sugarman Aug. 14, 1956 UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No 2,990,278 June 27 196 Chester F. Carlson It is hereby certified that error appears in the above numbered patent requiring correction and that the said Letters Patent should read as corrected below.
Column 4, line 66, column 5 lines 64: 69 and 75 column 1 line 2 and column 9, line 40, for "adhesive", each occurrence read abhesive column 9, line 20 for "heat-sensitive" read heat-insensitive Signed and sealed this 26th day of December 1961 (SEAL) Attest: ERNEST W. SWIDER DAVID L. LADD Attesting Officer Commissioner of Patents USCOMM-DC UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 2 990,278 June 27, 196
Chester Fa Carlson It is hereby certified that error appears in the above numbered patent requiring correction and that the said Letters -Patent. should read as -corrected below Column 4, line 66, column 5 lines 64 69 and 75 column 7 line 2 and column 9 line 4L0, for "adhesive'fl each occurrence read abhesive column 9,, line 20 for "heat-sensitive" read heat-insensitive Signed and sealed this 26th day of December 1961.,
Y (SEAL) Attest:
ERNEST W. SWIDER DAVID L. LADD Attesting Officer Commissioner of Patents USCOMM-DC- UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent, No 2,990 278 June 27 196 Chester FD Carlson It is hereby certified that error appears in the above numbered patent requiring correction and that the said Letters Patent should read as corrected below.
' Column 4, line 66 column 5 lines 64 69 and 75 column 7 line 2 and column 9, line 4O for "adhesivefl each occurrence read abhesive column 9,, line 20 for "heat-sensitive" read heat-insensitive Signed and sealed this 26th day of December 1961.,
' (SEAL) Attest: ERNEST W. SWIDER DAVID L. LADD Attesting Officer I Commissioner of Patents USCOMM-DC-

Claims (1)

10. IN THE PROCESS OF XEROGRAPHY WHEREIN AN ELECTROSTATICALLY CHARGED XEROGRAPHIC PLATE IS EXPOSED TO PROJECTED IMAGE TO FORM AN ELECTROSTATIC LATENT IMAGE ON THE PLATE CORRESPONDING TO THE PROJECTED IMAGE AND THE PLATE IS DEVELOPED WITH OPPOSITELY CHARGED PARTICLES OF HEAT FUSIBLE DEVELOPING MATERIAL THAT ARE ATTACHED TO THE LATENT IMAGE TO FORM A XEROGRAPHIC POWDER IMAGE CORRESPONDING TO THE PROJECTED IMAGE, THE METHOD OF TRANSFERRING AND FIXING THE POWDER IMAGE TO A FINAL SUPPORT MATERIAL COMPRISING THE STEPS OF TRANSFERRING THE POWDER IMAGE TO A SMOOTH-SURFACED INTERMEDIATE SUPPORT MATERIAL, HEAT FUSING THE POWDER IMAGE IN
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US3190264A (en) * 1958-11-28 1965-06-22 Xerox Corp Xerographic developing apparatus
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US3545997A (en) * 1966-01-26 1970-12-08 Pitney Bowes Inc Method for coating on a substrate
US3630615A (en) * 1969-07-24 1971-12-28 Xerox Corp Method and apparatus for transporting support material
US3632372A (en) * 1964-03-24 1972-01-04 Ici Ltd Plastic coating of plasterboards or wood
US3655370A (en) * 1966-04-12 1972-04-11 Xerox Corp Photoelectrophoretic image transfer
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US3862848A (en) * 1971-12-24 1975-01-28 Australia Res Lab Transfer of color images
US3893761A (en) * 1972-11-02 1975-07-08 Itek Corp Electrophotographic toner transfer and fusing apparatus
US3923392A (en) * 1974-01-02 1975-12-02 Itek Corp Electrophotographic copier
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US4006050A (en) * 1974-02-11 1977-02-01 George M. Whiley Limited Method of manufacturing cards and other documents
US4006983A (en) * 1973-10-29 1977-02-08 Electroprint, Inc. Electrostatic color printing systems using modulated ion streams
US4015027A (en) * 1973-10-04 1977-03-29 Itek Corporation Electrophotographic toner transfer and fusing method
US4195927A (en) * 1978-01-30 1980-04-01 Dennison Manufacturing Company Double transfer electrophotography
US4292120A (en) * 1980-04-10 1981-09-29 E. I. Du Pont De Nemours & Company Process of forming a magnetic toner resist using a transfer film
US4338391A (en) * 1979-03-02 1982-07-06 E. I. Du Pont De Nemours And Company Magnetic resist printing process, composition and apparatus
US4369729A (en) * 1980-08-18 1983-01-25 Canon Kabushiki Kaisha Image recording apparatus
US4453820A (en) * 1979-01-25 1984-06-12 Ricoh Company, Ltd. Electrostatographic apparatus
US4497570A (en) * 1983-02-02 1985-02-05 Xerox Corporation Printing machine employing an operator replaceable interposition web and photoconductive member
US4530595A (en) * 1981-08-24 1985-07-23 Konishiroku Photo Industry Co., Ltd. Toner cleaning method and apparatus in which voltage is impressed between electrostatic image holder and a film member
US4533611A (en) * 1982-04-29 1985-08-06 Hoechst Aktiengesellschaft Process for preparing a planographic printing plate
US4690539A (en) * 1986-05-27 1987-09-01 Xerox Corporation Transfer apparatus
US4708460A (en) * 1986-07-25 1987-11-24 Xerox Corporation Simultaneous transfer and fusing in electrophotography
US4992833A (en) * 1989-08-10 1991-02-12 Eastman Kodak Company Fixing method and apparatus having a transfer-fixing chilling drum
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US5150161A (en) * 1991-04-09 1992-09-22 Olin Corporation Color printing apparatus and process using first and second transfer surfaces
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US5233397A (en) * 1992-08-24 1993-08-03 Xerox Corporation Thermal transfer apparatus
US5298956A (en) * 1992-10-07 1994-03-29 Xerox Corporation Reinforced seamless intermediate transfer member
US5361126A (en) * 1992-07-27 1994-11-01 Oce-Nederland, B.V. Toner image transfer apparatus including intermediate transfer medium
US5391247A (en) * 1992-01-24 1995-02-21 Revlon Consumer Products Corporation Hot stamping glass
US5408302A (en) * 1991-02-05 1995-04-18 Siemens Nixdorf Informationssysteme Aktiengesellschaft Printing or copying machine with a belt-type transfer element with associated electrostatic device for transferring toner images from an intermediate image-carrier
US5410384A (en) * 1991-09-03 1995-04-25 Siemens Nixdorf Informationssysteme Aktiengesellschaft Electrophotographic simultaneous double printing system
US5525446A (en) * 1992-10-16 1996-06-11 Xerox Corporation Intermediate transfer member of thermoplastic film forming polymer layer laminated onto a base layer
US5607533A (en) * 1994-06-03 1997-03-04 Fuji Photo Film Co., Ltd. Method for preparation of printing plate by electrophotographic process and apparatus for use therein
US5835830A (en) * 1996-05-10 1998-11-10 Fuji Xerox Co., Ltd. Image forming apparatus
US5890044A (en) * 1997-01-16 1999-03-30 Fuji Xerox Co., Ltd. Image forming apparatus for simultaneous transfer and fixing of images
US5893018A (en) * 1996-07-31 1999-04-06 Xeikon N.V. Single-pass, multi-color electrostatographic printer with continuous path transfer member
US5933694A (en) * 1997-05-07 1999-08-03 Fuji Xerox, Co., Ltd. Image forming method and image forming apparatus for simultaneously transfer-fixing a toner image without creating creases
US6016417A (en) * 1996-11-08 2000-01-18 Fuji Xerox, Co., Ltd Intermediate transfer medium, method for producing the same and image forming device using the same
US6078775A (en) * 1997-07-07 2000-06-20 Fuji Xerox Co., Ltd. Intermediate transfer body and image forming apparatus using the intermediate transfer body
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US6226487B1 (en) 1998-10-21 2001-05-01 Fuji Xerox Co., Ltd. Transfer and fixing device having specific nip ratio
US6342273B1 (en) * 1994-11-16 2002-01-29 Dsm N.V. Process for coating a substrate with a powder paint composition
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US3105777A (en) * 1960-04-04 1963-10-01 Xerox Corp Xerographic developing apparatus
US3146687A (en) * 1960-12-05 1964-09-01 Ibm Developing apparatus
US3122454A (en) * 1960-12-30 1964-02-25 Xerox Corp Xerographic developing apparatus
US3268351A (en) * 1961-06-29 1966-08-23 Xerox Corp Xerographing fixing method and apparatus
US3313623A (en) * 1961-09-05 1967-04-11 Xerox Corp Line sequential color xerography
US3132969A (en) * 1961-10-27 1964-05-12 Burroughs Corp Apparatus for electrostatic printing and transferring printed information
US3198648A (en) * 1961-11-30 1965-08-03 Burroughs Corp Electrostatic recording method
US3508823A (en) * 1962-04-04 1970-04-28 Xerox Corp Duplicating apparatus
US3275436A (en) * 1962-07-24 1966-09-27 Xerox Corp Method of image reproduction utilizing a uniform releasable surface film
US3632372A (en) * 1964-03-24 1972-01-04 Ici Ltd Plastic coating of plasterboards or wood
US3441938A (en) * 1964-06-01 1969-04-29 Burroughs Corp Electrostatic and magnetic recording method
US3405682A (en) * 1964-06-08 1968-10-15 Xerox Corp Xerographic development apparatus with web loading means to remove residual developer
US3354804A (en) * 1964-07-23 1967-11-28 Minnesota Mining & Mfg Developing camera
US3350202A (en) * 1964-10-27 1967-10-31 Union Carbide Corp Method of xerographically photosensitizing planographic printing plates
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US3374769A (en) * 1965-12-06 1968-03-26 Xerox Corp Toner fusing apparatus
US3545997A (en) * 1966-01-26 1970-12-08 Pitney Bowes Inc Method for coating on a substrate
US3655370A (en) * 1966-04-12 1972-04-11 Xerox Corp Photoelectrophoretic image transfer
US3404418A (en) * 1967-02-27 1968-10-08 Xerox Corp Sheet transport apparatus
US3515584A (en) * 1967-03-27 1970-06-02 Xerox Corp Xeroprinting master
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DE1811893A1 (en) * 1967-11-30 1969-07-10 Rank Xerox Ltd Method and device for transferring a powder image from an image plate to an image carrier
US3591276A (en) * 1967-11-30 1971-07-06 Xerox Corp Method and apparatus for offset xerographic reproduction
US3795442A (en) * 1968-01-26 1974-03-05 T Kimura Electroprinting device
US3630615A (en) * 1969-07-24 1971-12-28 Xerox Corp Method and apparatus for transporting support material
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US3862848A (en) * 1971-12-24 1975-01-28 Australia Res Lab Transfer of color images
US3893761A (en) * 1972-11-02 1975-07-08 Itek Corp Electrophotographic toner transfer and fusing apparatus
DE2353577A1 (en) * 1972-11-02 1974-05-16 Itek Corp ELECTROPHOTOGRAPHIC SOUND TRANSFER AND MELTING DEVICE AND SOUND TRANSFER AND MELTING METHOD
US3950168A (en) * 1973-02-26 1976-04-13 Xerox Corporation Fixing powder images
US4015027A (en) * 1973-10-04 1977-03-29 Itek Corporation Electrophotographic toner transfer and fusing method
US4006983A (en) * 1973-10-29 1977-02-08 Electroprint, Inc. Electrostatic color printing systems using modulated ion streams
US3923392A (en) * 1974-01-02 1975-12-02 Itek Corp Electrophotographic copier
US4006050A (en) * 1974-02-11 1977-02-01 George M. Whiley Limited Method of manufacturing cards and other documents
US3947113A (en) * 1975-01-20 1976-03-30 Itek Corporation Electrophotographic toner transfer apparatus
US4195927A (en) * 1978-01-30 1980-04-01 Dennison Manufacturing Company Double transfer electrophotography
US4453820A (en) * 1979-01-25 1984-06-12 Ricoh Company, Ltd. Electrostatographic apparatus
US4338391A (en) * 1979-03-02 1982-07-06 E. I. Du Pont De Nemours And Company Magnetic resist printing process, composition and apparatus
US4292120A (en) * 1980-04-10 1981-09-29 E. I. Du Pont De Nemours & Company Process of forming a magnetic toner resist using a transfer film
US4369729A (en) * 1980-08-18 1983-01-25 Canon Kabushiki Kaisha Image recording apparatus
US4530595A (en) * 1981-08-24 1985-07-23 Konishiroku Photo Industry Co., Ltd. Toner cleaning method and apparatus in which voltage is impressed between electrostatic image holder and a film member
US4533611A (en) * 1982-04-29 1985-08-06 Hoechst Aktiengesellschaft Process for preparing a planographic printing plate
US4497570A (en) * 1983-02-02 1985-02-05 Xerox Corporation Printing machine employing an operator replaceable interposition web and photoconductive member
US4690539A (en) * 1986-05-27 1987-09-01 Xerox Corporation Transfer apparatus
US4708460A (en) * 1986-07-25 1987-11-24 Xerox Corporation Simultaneous transfer and fusing in electrophotography
US4992833A (en) * 1989-08-10 1991-02-12 Eastman Kodak Company Fixing method and apparatus having a transfer-fixing chilling drum
WO1991013386A1 (en) * 1990-02-26 1991-09-05 Siemens Nixdorf Informationssysteme Aktiengesellschaft Modular electrophotographic printer
US5258809A (en) * 1990-02-26 1993-11-02 Siemens Nixdorf Informationssysteme Aktiengesellschaft Electrophotographic printer of modular design
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US5150161A (en) * 1991-04-09 1992-09-22 Olin Corporation Color printing apparatus and process using first and second transfer surfaces
US5410384A (en) * 1991-09-03 1995-04-25 Siemens Nixdorf Informationssysteme Aktiengesellschaft Electrophotographic simultaneous double printing system
US5420662A (en) * 1991-10-15 1995-05-30 Siemens Nixdorf Informationssysteme Aktiengesellschaft Printer or copier with an arrangement for printing both sides of a recording medium
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US5391247A (en) * 1992-01-24 1995-02-21 Revlon Consumer Products Corporation Hot stamping glass
US5361126A (en) * 1992-07-27 1994-11-01 Oce-Nederland, B.V. Toner image transfer apparatus including intermediate transfer medium
US5233397A (en) * 1992-08-24 1993-08-03 Xerox Corporation Thermal transfer apparatus
US5298956A (en) * 1992-10-07 1994-03-29 Xerox Corporation Reinforced seamless intermediate transfer member
US5409557A (en) * 1992-10-07 1995-04-25 Xerox Corporation Method of manufacturing a reinforced seamless intermediate transfer member
US5525446A (en) * 1992-10-16 1996-06-11 Xerox Corporation Intermediate transfer member of thermoplastic film forming polymer layer laminated onto a base layer
US5607533A (en) * 1994-06-03 1997-03-04 Fuji Photo Film Co., Ltd. Method for preparation of printing plate by electrophotographic process and apparatus for use therein
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US6342273B1 (en) * 1994-11-16 2002-01-29 Dsm N.V. Process for coating a substrate with a powder paint composition
US5835830A (en) * 1996-05-10 1998-11-10 Fuji Xerox Co., Ltd. Image forming apparatus
US5893018A (en) * 1996-07-31 1999-04-06 Xeikon N.V. Single-pass, multi-color electrostatographic printer with continuous path transfer member
US6016417A (en) * 1996-11-08 2000-01-18 Fuji Xerox, Co., Ltd Intermediate transfer medium, method for producing the same and image forming device using the same
US5890044A (en) * 1997-01-16 1999-03-30 Fuji Xerox Co., Ltd. Image forming apparatus for simultaneous transfer and fixing of images
US5933694A (en) * 1997-05-07 1999-08-03 Fuji Xerox, Co., Ltd. Image forming method and image forming apparatus for simultaneously transfer-fixing a toner image without creating creases
US6078775A (en) * 1997-07-07 2000-06-20 Fuji Xerox Co., Ltd. Intermediate transfer body and image forming apparatus using the intermediate transfer body
US6133927A (en) * 1998-01-07 2000-10-17 Fuji Xerox Co., Ltd. Image forming apparatus
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