US2869967A - Bulky yarn - Google Patents

Bulky yarn Download PDF

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US2869967A
US2869967A US679891A US67989157A US2869967A US 2869967 A US2869967 A US 2869967A US 679891 A US679891 A US 679891A US 67989157 A US67989157 A US 67989157A US 2869967 A US2869967 A US 2869967A
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yarn
jet
fibers
nozzle
staple
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US679891A
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Alvin L Breen
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/16Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam

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  • This invention relates to treatment of yarn, or thread, to produce yarn of greatly increased bulk, and is more particularly concerned with the production of a bulky yarn composed of plurality of individually convoluted fibers and characterized by the presence of a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface.
  • Anobject' of this invention is to provide a yarn'which has a large number of protruding free ends of fiber and,
  • Another object is to provide a spun staple yarn of improved bulk characterized by the'presence of a multitude of ring-likeloo-ps and protruding fiber ends irregularly spaced along the yarn surface.
  • a further object is to provide a process for preparing yarn-of improved bulk from conventional spun staple yarn.
  • An additional object is toprovide a process for treating continuous filament yarn to provide greatly "increased bulk and a covering of projecting fiber ends in'one operation.
  • Figure 1 is a side elevation of suitable apparatus for practicing the process of this invention
  • Figure 2' is a side elevation, partially in section, of
  • Figure 3 is an end View of the nozzle shown in Figure 2
  • Figure 4 is a sideelevation,"partially in section, of another form of nozgle
  • Figure 5 is a side view showing the appearance of untwisted treated yarn prepared from continuous filament yarn (enlarged about ten'ti mes),
  • Figure 6 is a similar enlargedview of untwisted treated yarn prepared'frorntfwo pliesof continuous filament yarn
  • Figure 7 is a similar enlarged view of treated yarn prepared from a ply of continuous'filament yarn anda ply of cotton yarn,
  • Figure 8 is a similar enlarged view of a treated yarn prepared from a single ply spun staple yarn
  • Figure 9 is a similar enlarged View of a treated yarn prepared from a two ply spun staple yarn
  • Figure 10 is a schematic view of the arrangement of the yarn f eed, texturing jet, torque jet, take-up roll and wind up, v
  • Figure 11 is a schematic view of an alternate arrangement similar to' FigurelO' but includes a draw roll with a step rolland a draw pin,
  • Figure 12 is a self-explanatory alternate arrangement of Figure 10, 1
  • Figure 13 is a diagrammatic section of a flocking box provided with a' texturing'jet
  • Figure 14 is' asc hernati c view of an arrangement of yarn feed rolls, flocking box, pinch rolls and wind-up,
  • Figure 15 illustratesdiagrammatically in isolated strands how the staple fibers are caught in'loops introduced by a
  • Figure 16 shows the staple secured in the loops of Figure 15 which have been drawn mimic the staple fiber inplhace, v v l t
  • Figure 17 shows the staple fiber flattened back against tube is used'in place ofthe texturing jet;
  • the T tube may be made of any 'smooth material such as glass, stainless steel, or the like,and may vary in diameter from about A" to /2".
  • a novel yarn'is which has a fuzzyto cashmere-like appearance resulting from a covering of'projecting'fiber ends and unusual bulk, as compared with staple yarns of the prior art, resulting from fibers which are convoluted into coils, loops and whorls at random intervals along their lengths and at irregular spacing on difierent fibers toprovide a lateral interfib'er' spacing?
  • the most obvious characteristics of the yarn are the combination of unusual'bulkiness with'the fuzzy covering providedby protruding fiber "ends, buttlie 'yarn'is'a'lso' characterized by the presence of a multitude of ring-like loops and other convolutions in the fibers'
  • The'convolutions'visible on'the surface contribute desirable properties to the yarn, but the less obvious fiber convolutions within the yarn are even more important in producing bulk andresulting garment warmth of fabrics made from this yarn.
  • the fiber ends and convolutions maybe are held in place by a twist imparted to the yarn.
  • a single ply yarn may have a Z or 8 twist.
  • the individual plies are usually twisted in one direction and the plurality of plies are usually twisted together in the opposite direction, e. g., the plies may have a Z twist and the yarn may have an S twist.
  • the convolutions have been set, as by heating the convoluted yarn, the fibers will resume their original unconvoluted condition when the yarn is untwisted and taken apart; hence initially straight fibers will be recovered in a substantially straight condition.
  • the yarn fibers were initially crimped or wavy or curly, they would resume that condition on being separated from the yarn.
  • the yarn of this invention is prepared by a process which involves feeding yarn through a high velocity fluid jet, under conditions adapted to accomplish the double purpose of imparting bulk-giving convolutions and of providing a multitude of projecting filament ends, and then twisting the filaments together to hold the convolutions and filaments ends in place.
  • the process resembles that of my copending application, Serial No. 261,635, now Patent No. 2,783,609.
  • additional critical conditions must be observed to provide the desired covering of filament ends on the yarn surface.
  • the starting yarn may be composed of substantially continuous filaments or of staple length fibers, which may be natural fibers or artificial filaments cut to staple length, or the yarn may include two or more of these types.
  • the yarn is fed through a jet operated under conditions suchthat the filaments are shattered at random intervals to provide the desired free ends of projecting fiber.
  • the jet must first open up the yarn.
  • the filaments of an untwisted continuous filament yarn are readily separated by the turbulence created by a high velocity jet. Twisted yarn must be untwisted before the filaments can be separated, but this action can also be achieved by the jet; Under proper conditions the jet will apply sufiicient false untwisting to the yarn filaments to permit the jet to open up the yarn, and this is true not only when the yarn is composed of a single twisted ply, but also when it is composed of a plurality of plies which are individually twisted.
  • suitable jet turbulence will whip the filaments about with such rapidity that the flex life of the material is quickly exceeded and some or many of the filaments are broken.
  • the fibers of staple yarn must be held in place by a twist in the yarn, but the yarn must be untwisted while in the jet for the treatment to have appreciable effect.
  • the jet At near sonic velocities the jet has been found to apply a substantial untwisting torque as well as considerable tension to the yarn. If the yarn is permitted to untwist in response to this torque for a distance which exceeds the fiber length, the draft yield strength of the yarn is reduced to such an extent that the accompanying jet tension is sufficient to pull the yarn apart.
  • the untwisting action of the jet is limited to the iength of yarn between the feed and windup devices. In other words, the jet torque applies a false untwist to the yarn.
  • yarn which consists wholly or in part of staple length fibers held in place by a yarn twist can be processed efficiently when feeding the yarn to a high velocity fluid jet operated to apply a false untwist to the yarn, by snubbing the yarn passing to the jet to prevent the untwist from backing up, and again snubbing the yarn leaving the jet to prevent the untwist from carrying forward, the distance between the two snubbing points being less than the length of the staple fibers and preferably being arranged to restrict the false untwist to an effective distance of less than one-half the length of the staple fibers.
  • the required snubbing may be accomplished by dragging the yarn over fixed surfaces, which may be the yarn entrance and exit surfaces of the jet nozzle.
  • the yarn leaving the jet can be snubbed by directing it against a baffle plate which also serves to remove the yarn from the jet stream.
  • the action of the jet in untwisting the yarn may be likened to a combing action.
  • the pull of the jet stream acts to straighten the helically twisted fibers, creating a torque which untwists the yarn.
  • a jet operated at near sonic velocity provides sutficient torque to untwist the yarns usually encountered, but it is sometimes desirable, especially with high twist single ply yarn, to provide a: rotating torque jet which rotates in the opposite direction from that of the yarn twist to accentuate the false untwisting torque of the jet. Purely mechanical means for applying false twist are known in the art, but are not necessary to accomplish the false untwist described.
  • Both staple yarn and continuous filament yarn can therefore be processed in a similar manner with a near sonic velocity jet to produce the desired bulky yarn having a covering of projecting fiber ends.
  • Plied yarn can be processed somewhat more readily than single ply yarn because the plies exert a snubbing action on each other which tends to resist untwisting of the fibers. This effect can supply a part or all of the snubbing action required to prevent the region of false untwist from being so extensive that the yarn is pulled apart. This is most easily seen in the case of a plied staple yarn of the usual type in which the singles twist is in one direction, e. g., a Z twist, and the ply twist is in the opposite direction, e. g., an S twist.
  • An untwisting torque applied to the ply fibers also causes the plies to twist together in the opposite direction, which increase of ply twist opposes the above torque and tends to prevent the fibers from being separated for more than a short distance. If'the twist 'is sufficiently great, as in a high twist yarn, this opposition to fiber separation provides all of the snubbing needed and it is not -necessary to rely on snubbing surfaces before and after the jet. The same assess thing is true to a lesser entent. when the plies fed to the jet are nottw isted together. The plies still provide a snub bing action which opposes forces tending to'untwist the fibe rs of aply.
  • two separate single ply yarns can be fed to a jet together andproce'ss ed into a single yarn in accordance with this invention'with less diflicult'y than a single ply.
  • the continuous filaments also help resist tensions tending to exceed the draft yield strength of the staple ply.
  • Figure "1 shows a suitable arrangement of apparatus for practicing the process of this invention.
  • the starting yarn may be supplied from any convenient source, such as a yarn package, and may come directly-from the spinning process by which it is produced without intermediate wind-up.
  • the yarn is passed between feed rolls 12 and 14, arranged to be driven so as to forward the yarn at the desired speed, which is preferably of the order of 50 to 100 yards per minute but may vary over a wide range. These feed rolls are mounted on a pedestal 16.
  • the yarn passes through guide 18 on support 20 and into a jet nozzle supported by air supply pipe 22.
  • the nozzle is shown in section to clarify the construction.
  • the body Po t on 2 of th nozz s h ll n is p o with a fluid exit 26 which has a venturi-like shape to create the required high velocity jet.
  • a hollow male member 28 is threaded into thebody at 30 and terminates in a cone 32 projecting into the mouth of the jet-forming exit 26.
  • the yarn passes inside the male member, out through a hole in the projecting cone, and is carried out of the nozzle exit 26 by the jet stream created by air entering the nozzle through pipe 22.
  • the flow of air to the jet can be regulated by valve .34 in the supply pipe.
  • the yarn hole in cone '32 should; be of a size which provides a fairly snug fit around the yarn so that the yarn is snubbed sutiiciently to prevent appreeiable untwisting before the jet is reached, unless equivalent snubbing is provided by other means.
  • the yarn leaving the nozzle is deflected at right angles by a baf le plateg36 mounted on the, nozzle close to the exit 26.
  • the balfieplate accomplishes the dual purpose ofterminating the action of the high velocity jet on the yarn and of snubbing the yarn against untwisting beyond this point.
  • the distance from the end of the cone '32 to the battle plate must be less than the length of fibers in the treated yarn, and shouldpreferably be such as to limit the false untwisting action of the jet to less than one-half the fiber length.
  • a guide can be used to achieve a similar result. Frequently sufiicient snubbing can be accomplished bypulling the yarn across exit face 38 of the nozzle.
  • the yarn holein cone 32 When sufiicient" back snubbing is not providedbythe yarn holein cone 32 the yarn can be fed into t o e a n a l s th h yarn. is s u be against other parts of the male member 28.
  • Thejetstream is operated at a near sonic velocity to separate-the fibers, form them intobulk-givingconvolutions, and cause ffiber ends to project frornthe yarn, all as described previously.
  • the treated yarn now passes through a guide 40 located below baffie 36, and then to a pair of take-up rolls 44 and 46, which are suitably supported on pedestal QZand are driven at a surface speed somewhat less than that of feed rolls 12,14 to provide an overfeed to the jet.
  • the amount of overfeed is one of the factors controlling the amount of bulking action accomplished in the jet and should generally be in the range of 5% to 50%, depending upon'the effect desired.
  • the percent 7 .overfeed is the percent by which the speed of yarn feed to the jet exceeds the take-up speed.
  • the take-up rolls 44, 46 may feed to any suitable wind-up or, alternatively, one of these rolls can be a wind-up roll.
  • V-nozzles can be used instead of'the one illustrated in Figure :1 to ptovide the required jet.
  • metalblock'50 isdrilled lengthwise to provide axial yarn ssage'JSZ.
  • An-air entrance 54 is drilled ata forward angle of about 45 through one face of the block to intercept the yarn passage.
  • the air entrance may be made of smaller diameter than the yarn passage and be ofi center to intercept the yarn passage at one side as shown in Figure 3.
  • Fitting 56 is soldered over the air entrance; it is threaded at 58 for attachment to the air supply pipe 22 of the apparatus shown in Figure 1.
  • other fluids can be used such as CO steam, or other vapors for special purposes.
  • the nozzle shown in Figure 4 provides advantages over the two forms already described.
  • the housing 60 may be a standard inch plumbers T.
  • the yarn enters through guide member 61, provided with a funnel-shaped portion 62 to receive the yarn end when stringing up.
  • a hypodermic needle 63 of appropriate size provides a passage for conducting the yarn into the nozzle 64.
  • the nozzle has the shape of a conventional venturi tube with the entrance 65 tapering inward so that opposite sides are at about a 20 angle with each other, and the exit 66 diverging more gradually so that opposite sides are at about a 7 angle with each other.
  • the overall length of the venturi tube may suitably be about 1.3 inches with the diverging exit portion about 1.0 inch'long.
  • the arrangement of guide member 61, needle passage 63 and nozzle 64 makes the device self-stringing when a yarn end is fed to it.
  • the needle 63 is adjusted to extend into the entrance of the ve'nturi and stop in the venturi throat 67. This adjustment is important for best performance.
  • the manner of adjustment shown is to thread the outside of the nozzle and provide positioning and locking nuts 68, 69.
  • nozzle slides with a snug fit into the housing do until not 7 68 rests against the housing. It is held in this position by springs, one of which is indicated at 7%.
  • the guide member til likewise slides into the housing with a snug fit until shoulder 71 is positioned against the housing. it may also be held in position by spring 79 and other similar springs. Advantages of this construction are that it can be taken apart easily for cleaning and the parts can be rotated to adjust the needle in the venturi throat. However, either or both parts may be held in position by set screws pass ing through the housing, or the parts may be threaded into the housing.
  • Air is supplied to the nozzle through pipe 72, which is threaded orsoldered into the T housing.
  • the air passes through the venturi around the needle 63, the venturi throat 67 being sufficiently larger than the needle to permit passage of the required volume of air.
  • Gasket material may be placed in groove 73 around member 61 and groove 74 around the nozzle to prevent air leakage.
  • 1 represents a flock chamber provided with an inlet2 and an exit 3 for the yarn. Between the inlet and exit is an open space containing flock 7.
  • the chamber is also provided with an internal air bafiie.
  • the air supplied through the teXturingjet keeps the flock or linters' in a state of violent agitation.
  • the inlet 2 is usually through a texturing jet which is provided with an air supply 4 and an outlet 5 at the base of a venturi chamber 6.
  • the yarn is ledthrough the inlet 2 where it is subjected to a high speed air whorls and loops. As the yarn passes through the suspended flock 7, the fibers find their way into the interstices and loops of the yarn where they are held and entrained as the yarn passes through the exit 3 of the flocking chambet 1. a The yarn then proceeds as shown in Figure 14. i
  • EXAMPLE 2 Using the apparatus shown in Figure 1, two separate plies of yarn were fed to the nozzle. One ply was a 20 cotton count, 15 Z twist (15 turns per inch) cotton yarn. The other ply was a 200 denier, 8O filament, continuous filament acrylo-nitrile yarn. The yarns were fed into the nozzle together at 10 yards per minute. Air was supplied to the nozzle at 90 pounds per square inch gage pressure, which gave a flow, as free air, of 2.7 cubic feet per minute. The appearance of the resulting two-ply yarn after receiving a slight twist is shown in Figure 7.
  • bothplies was markedlyincreased by the formation of crunodal loops and other convolutions, and cotton fibers were caused to project with a great increase in fuzziness.
  • the cotton ply was extended in length by the treatment, so that it wrapped around the continuous filament ply when the yarn was twisted.
  • EXAMPLE 3 A single ply, 18 cotton count, 18 Z twist spun yarn composed of 3-inch staple length, 3 denier, acrylonitriie fibers was processed with an apparatus similar to that shown in Figure 1.
  • the yarn was taken up from the nozzle at yards per minute and the bafile plate was located /4 inch from the snub point provided by the restricted yarn passage into the jet stream. Air was applied to the nozzle at 90 pounds per square inch gage, the nozzle dimensions being such as to give a flow of about 1 cubic foot per minute with an efiective jet stream velocity of slightly above sonic velocity.
  • the appearance of the treated yarn is shown in Figure 8.
  • the yarn was greatly increased in bulk and the surface was covered with ring-like loops and extending fiber ends, giving the yarn a fuzzy or lofty appearance and feel.
  • the changes in the yarn structure comprise a separation and reorientation of the fibers in relation to each other accompanied by intertangling to the extent that the reoriented fibers are stabilized in their new positions.
  • the net result is a peripheral expansion of the central core of the yarn with an accompanying marked increase in the number and length of free fiber ends and the formation of crunodal loops and other convolutions characteristic of the process.
  • Fabric properties EXAMPLE 5 A variety of spun yarns were treated in a similar way with like results. The treated yarns were all taken up from the jet at 100 yards per minute, with other conditions as in Example 4 except as indicated in Table 1.
  • yarn notations such as 50/2 (25 Z, 4' 8 ply) 5 in., 3 d. p. f. in 5(e) refer to a 50 cotton count, 2 ply yarn in which each of the plies has a Z twist of 25 turns per inch and the plies are twisted together in the opposite direction at 4 8 turns per inch, the fibers being 5 inches long and of 3 denier per fiber.
  • Rayon refers to regenerated cellulose yarn made by the viscose process.
  • Dacron and Orlon are trademarks for yarn manufactured by E. I. du Pont de Nemours and Company and refer to polyethylene-terephthalate and polyacrylonitrile yarns, respectively.
  • Nylon refers to polyhexamethyleneadipamide yarn.
  • the appearance of the treated yarns was similar to that shown in Figure 8. However, it was observed that, as the staple length was increased, the amount of loop formation in the yarn bundle increased and, of course, the frequency of protruding ends decreased. The extent of the bulking action could be increased or decreased composed of 4 /2 inch staple length, 3 denier, acrylonitrile fibers was processed at about 100 yards per minby varying the per cent overfeed up or down from the values given in the table, but processing difficulties may be encountered at overfeeds above 15%.
  • EXAMPLE6 1 A 20/1 worsted count 408 its-'1 denierj-bgztwist spun yarn composed of 5 inch, 3 denier, acrylonitrile fibers was processed with the apparatus shown in Fig Qyerage fiber length .of 1%.; vincncs.
  • the treated yarn was characterized by the protrusion of long ends of-fibers from the core of the yarn. These ends projected up to one inch, giving an extremely fuzzy, cashmere-like yarn. In. other respects the yarn was similar to that shown in Figure 8.
  • EXAMPLE 7 A two ply, 27 cotton count, spun polyethylene-terephthalate yarn was processed at 15 yards per minute with apparatus similar to that in Figure l.
  • the plies of this yarn were composed of 1% inch staple length, 3 denier fibers twisted together at 18 2 turns per inch, and the ply twist was 11 S. Air was supplied to the nozzle at 90 pounds per square inch gage, the flow being about 1 cubic foot of free air per minute.
  • the appearance of the yarn is shown in Figure 9 and, except'fo-r the two-ply structure, wassimilar to the yarns described previously inrconnection with Figure 8. In this case the fiber and ply twists were sufiicient to prevent the false untwist imparted by the jet from untwisting the yarn fibers foran undesirable distance, and snubbing against a surface was not necessary.
  • EXAMPLE 8 The previous examples have shown that the jet stream has sufiicient false untwisting action to open up a wide variety of twisted yarns to the extent required by the process of this invention. sirable to accentuate the untwisting action by providing a rotating or torque jet stream. This has been accomplished by cutting oblique or spiralling grooves in the cone-shaped end 32 of the yarn guiding portion of the nozzle in Figure 1.
  • the simple torque nozzle shown in Figures 2 and 3 was used with apparatus similar to that of Figure 1 to process single ply, 18 cotton count, 18 2.
  • EXAMlLE 9 InExample 8 it was observed that the use of a Z torque jet nozzle increased the twist of the Z twist yarn and prevented opening of the yarn, so that bulking did not take place. However, this type of treatment can be com bined with heat-setting of the yarn while in the overtwisted condition to provide a crimp bulking effect.
  • a single ply, 18 cotton count, 15 Z twist spun yarn composed of 4-6 inch, 2.5 denier, polyhexamethyleneadipamide fibers may be processed as in Example 8, using-a torque nozzle which applies a false twist of about 30 turns per inch.
  • the nozzle may be heated to about 240-250 C. to crimp set the yarn while in the false twisted condition. This produces a bulky wool-like yarn having an attractive curly crimp which imparts elasticity to the yarn. The fibers will retain their crimp when separated from the yarn.
  • the yarn guide 18 was spaced at a greater distance from the nozzle than shown in' Figure 1 and a hesttin, surface at 240250 C. was used to crimp set the yarn between the guide and the nozzle. The yarn passed through the torque nozzle without snubbing so that the false twist of'about 30 turns per inch backed up to the yarn guide. With other conditions as described above, a similar crimp bulking effect was: obtained.
  • Example 9 The process of Example 9 is useful with any yarn composed of fibers which can be heat set to stabilize the crimp imparted by the false twist.
  • the treatment is enhanced by fibers which shrink during heat-setting. While the process has been illustrated with spun staple yarn, it
  • a nylon yarn (80/ 68/0) was fed to a jet similar to Figure 8 of U. 8. 2,783,609 at 240 Y. P. M.
  • the jet was mounted so as to exhaust in an enclosure partly filled with cotton linters of about $6 in length ( Figures
  • the pinch rolls as illustrated in Figure 14 were operated at 2G0 Y. P. M. to give an intermediate overfeed of 20%.
  • the wind-up was operated at 230 Y. P. M. to give a net overfeed of 5% and a final denier of 91.
  • 'Since the calculated denier under these condi- 'tions should be 84, the linters increased the yarn weight by about 8%.
  • the yarn sample between the flocking box and the pinch rolls had an appearance illustrated in Cotton yarn also processed excellently under the above conditions with the Storquejet. .Goodresults were ob tained with-a single ply, .18 Ztwist cotton yarn having an Fan Due; to; the short Figure 15. The final yarn showed reduced loop size as shown in Figure 16. Many characteristic random nodes and tangles could be observed under magnification.
  • the short length staple fibers were firmly locked within a continuous filament knot or knot snarlortangle of random configuration and frequently compound in structure; that is, more than one continuous filament and more than one staple fiber involved in a given snarl or tangle. Longer fibers may be used in place of those used to illustrate the invention in this example.
  • the flock or linters may vary in len th from about 0.1 rnillhneter, as is usually found in wood'fiour, up to lengths normally employedfor staple.,fibers;,that is, about 1-5 millimeters, .although for many purposesstaple up'to about 5", may
  • Fiaersotnormal staple lengthin'the'range of 1" to 3" are entangled less readily by the bulked yarn and therefore tend to modify the yarn to a lesser extent in terms of the number of free ends. Longer fibers, however, have the advantage of being more permanent in the final fabric.
  • any process which tends to entangle the longer fibers in the bulked continuous filament yarn may be used to advantage where the staple is long, for example, it may be desirable to pass the bulked yarn through a loosely compacted hat of randomly arranged fibers.
  • the length of contact and compressional load on the yarn being treated should be balanced to avoid undue yarn tension tending to cause breakdowns but may be suflicient to cause filament loops to become locked about the entangled staple fibers and to deform large loops into the flattened configuration shown in Figure l7.
  • irotruding fibers and elongated loops may be held tern porarily in place by a size to improve weaving perform ance and reduce snagging characteristics in the final fabric.
  • short length fibers such as Solka-Floc 1 wood cellulose may be employed with good results.
  • the very short length fibers tend to be fugitive to some extent but increase stability of borderline yarns suificiently to permit improved warping, quilling and weaving or knitting.
  • the bulk of the finished fabrics may be enhanced even after loss of the short fibers due to the unoccupied spaces they leave behind.
  • the bulked yarn may be passed through a liquid fiber slurry.
  • the yarn With well dispersed fibrous material of suitable length and concentration the yarn emerges with much the appearance of a pipe cleaner and increased weight of up to 50% or more. Tension applied to this yarn may again be used to lock most of these fibers in place. Heavily loaded yarns tend, however, to lose a portion of the loosely attached fibers which may be blown, rubbed or shaken off and returned to the slurry.
  • Air under a pressure of 10 p. s. i. g. was directed through the horizontal leg of the T tube to deflect the yarn from its vertical path.
  • the yarn was passed through the tube at abou 60 Y. P. M.
  • a fuzzy yarn having a soft bulky texture was obtained.
  • the air pressure in the tube may be varied from about 10 p. s. i. g. to about 100 p. s. i. g. It is difficult to determine the velocity of the air in the tube, but when the air is under pressure in the higher range, its speed as it contacts the yarn is of the order of sonic velocity.
  • the yarn processed in this manner has fewer loops and whorls and normally very few broken ends as compared with the products of the examples in which a high speed jet is used in conjunction with yarns containing a brittle com po-nent.
  • the free ends project much further from the yarn bundle after treatment than they do in the starting yarn.
  • acetate fibers as the brittle or shatterable component
  • filaments of other materials may be substituted more or less directly in the examples.
  • the suitability of a given filament for the-purpose depends on its tendency to break under the high speed jet action. It has been found that this tendency may be determined by a flex resistance test which consists essentially of bending the filament repeatedly through 180 over a smooth wire under a specified tension. The number of cycles required to cause failure of the specimen is taken as a measure of its flex resistance. The test is carried out by conditioning filaments for at least 16 hours in an atmosphere of 70 F. at 65% relative humidity. Usually 21 filaments are tested together and the number of cycles required to cause failure of 11 filaments is accepted. as the test result.
  • the tension applied to the specimen may be 0.15, 0.3, or 0.6 gram per denier depending upon the brittleness of the sample. It is desirable to select a load factor which will result in a test lasting a minimum of 50 cycles and a maximum of 5,000 cycles. The 0.6 gram per denier load factor is satisfactory for most textile fibers.
  • the order of magnitude of the flex life TABLE II A B C D E F Remarks Example Textnr- Torque Windup O ver- No. Core Ply Fractionable Ply ing Type Jet, Speed, iced, Process Product Jot, p. s. i. Y. P. M. Perp. s. i.
  • e Green implies yarn fresh from spinning unit having 54.0% residual solvent. This yarn is generally much tougher than conditioned" yarn which has been allowed to lose acetone by prolonged storage in fresh air.
  • the tougher fibers may be stabilized by use of lower operating speed on the jet so that the individual increments of fiber length are exposed to the flexing action of the jet for a greater length of time, or by use of higher air pressure in the jet which gives a more violent flexing action in the jet.
  • An example of the former deals with rayon which was processed at 20 Y. P. M. to give a product similar to that obtained with acetate at 200 Y. P. M. (roughly in inverse proportion to the tabulated flex lives).
  • a great range of flex lives may be obtained by changes in orientation and/ or crystallinity.
  • nylon and Dacron are much too tough to be fractured by the action of a texturing jet. If, however, they are prepared in a state of low orientation and high crystallinity the flex lives may be reduced to the range of a few hundred to a few thousand cycles.
  • Molecular weight as indicated by relative viscosity in a suitable solvent also plays an important part in determining fiber toughness.
  • Dacron fibers prepared from polymer with a relative viscosity of about 12 even though oriented and crystallized by normal process steps show flex lives in this same low range (10010,000). Usually a filament having a flex life below about 10,000 may be substituted for the acetate in the examples.
  • a bulky yarn comprising a plurality of discontinuous fibers twisted together, the fibers being convoluted into coils, loops and whorls at random intervals along their lengths, and the yarn surface exhibiting a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface.
  • a bulky yarn comprising a plurality of twisted staplelength fibers which are individually looped upon themselves at random intervals along their lengths and at irregular spacing on different fibers, said yarn exhibiting a fuzzy surface composed of protruding fiber ends and crunodal loops.
  • a bulky twisted staple yarn characterized by having a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface and having a multitude of fiber convolutions irregularly scattered through the yarn structure providing a bulk-giving lateral interfiber spacing.
  • a bulky yarn composed of at least two plies of twisted staple fiber characterized by having a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface and having a multitude of fiber convolutions irregularly scattered through the yarn structure providing a bulk-giving lateral interfiber spacing.
  • a bulky twisted yarn having a multitude of fiber ends protruding from the surface and comprising a plurality of staple-length fibers which are individually looped upon themselves at random intervals along their lengths and irregularly spaced on different fibers, which loops substantially disappear when the yarn is untwisted and pulled apart.

Description

Jan. 20, 1959 A. L. BREEN 2,869,967
BULKY YARN Filed Aug. 25, 195 4 Sheefcs-Sheet 1 IIIH 38 v INVENTOR ALVIN 1.. BREEN ATTORNEY A. L. BREEN Jan. 20, 1959 BULKY YARN 4 Sheets-Sheet 2 Filed Aug. 23,
Big. 10
ACETATE NYLON -RO0STER TAIL DRAW ROLL WITH STEP ROLL TEXTURING JET POSITION FOR 1::
INVENTOR ALVIN L. BREEN ATTORNEY Jan. 20, 1959 A. L. BREEN 2,869,967
BULKY YARN Filed Aug. 25, 1957 4 Sheets-Sheet s iii- .12
SPINNING CELL CONDITIONED ACETATE AIR BAFFLE- FLO0K\ FLOCIIING W 8 TEXTURING 4 INVENTOR ALVIN L.. BREEN ATTORNEY Filed Aug. 25, 1957 Jan. 20, 1959 BREE-N 2,869,967
BULKY YARN 4 Sheets-Sheet 4 Eig.14
Iii .17
Y FLATTENED STAPLE FIBER FLATTENED LO0P INVENTOR ALVIN L. BREEN BY @M 74M ATTORNEY 2,53%? Patented Jan. 2d, 1959 nULrrY YARN Alvin L. Breeu, West Chester, Pa., assignor to E. I. du Pont de Nemours and Company, Wilmington, Del., a corporation ofDelaware Application August 23, 1957, Serial No. 679,891 8 Claims. (Cl. 57l40) This application is a continuation-in-part of my copending application, Serial No. 443,313, filed July 14, i954, now'abandoned.
This invention relates to treatment of yarn, or thread, to produce yarn of greatly increased bulk, and is more particularly concerned with the production of a bulky yarn composed of plurality of individually convoluted fibers and characterized by the presence of a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface.
Inmy copending application, Serial No. 261,635, filed December 14, 1951, now Patent No. 2,783,609 I disclose the production of a 'novel bulky filament yarn having most of the desirable properties of ordinary spun staple yarn, but diifering in being composed of substantially continuous filaments. In that yarn, bulk and an appearance resembling that of staple yarn is provided by a multitude of ring-like loops and other convolutions at random intervals along the filaments and irregularly spaced on different filaments. While this continuous filament structure is a distinct advantage for most purposes, there are textile uses which require a fuzzy,lofty or cashmere-like effect provided by a yarn whi'ch has'a large number of protruding filament ends. A am having the combination ofproperties provided by free ends and bulk-giving filament convolutions would be desirable for such uses.
With the exception of silk, natural animal, vegetable and mineral fibers exist only in relatively short lengths. Yarn prepared from these natural fibers necessarily is composed of staple length fibers. Furthermore, large quantities of artificial continuous filaments are cut into staple before processing into yarn. Treatment of these staple yarns to introduce bulk-giving convo-lutions would be desirable regardless of whether or not free ends are required. When the desired effect requires protruding ends it would be highly desirable to provide a process for treating continuous filament yarn to impart both bulk and a multitude of protruding ends in one operation, thereby avoiding'the expensive operations of cutting continuous filaments into staple and spinning the staple into yarn.
Anobject' of this invention is to provide a yarn'which has a large number of protruding free ends of fiber and,
has an enhanced bulk provided'by filament convolutions of the type characterizedby the pr'esenceof ring-like loops. Another object is to provide a spun staple yarn of improved bulk characterized by the'presence of a multitude of ring-likeloo-ps and protruding fiber ends irregularly spaced along the yarn surface. A further object is to provide a process for preparing yarn-of improved bulk from conventional spun staple yarn. An additional object is toprovide a process for treating continuous filament yarn to provide greatly "increased bulk and a covering of projecting fiber ends in'one operation. Other objects of the invention will become apparent from the"followingdescription'and claims.
In'the drawings, whichillustratefpreferred embodi-' merits of the invention,
Figure 1 is a side elevation of suitable apparatus for practicing the process of this invention,
Figure 2' is a side elevation, partially in section, of
an alternative form of nozzle,
"Figure 3 is an end View of the nozzle shown in Figure 2,
Figure 4 is a sideelevation,"partially in section, of another form of nozgle,
Figure 5 'is a side view showing the appearance of untwisted treated yarn prepared from continuous filament yarn (enlarged about ten'ti mes),
Figure 6 is a similar enlargedview of untwisted treated yarn prepared'frorntfwo pliesof continuous filament yarn,
Figure 7 is a similar enlarged view of treated yarn prepared from a ply of continuous'filament yarn anda ply of cotton yarn,
Figure 8 is a similar enlarged view of a treated yarn prepared from a single ply spun staple yarn,
Figure 9 is a similar enlarged View of a treated yarn prepared from a two ply spun staple yarn,
Figure 10 is a schematic view of the arrangement of the yarn f eed, texturing jet, torque jet, take-up roll and wind up, v
Figure 11 is a schematic view of an alternate arrangement similar to' FigurelO' but includes a draw roll with a step rolland a draw pin,
Figure 12 is a self-explanatory alternate arrangement of Figure 10, 1
Figure 13 is a diagrammatic section of a flocking box provided with a' texturing'jet,
Figure 14 is' asc hernati c view of an arrangement of yarn feed rolls, flocking box, pinch rolls and wind-up,
Figure 15 illustratesdiagrammatically in isolated strands how the staple fibers are caught in'loops introduced by a Figure 16 shows the staple secured in the loops of Figure 15 which have been drawn mimic the staple fiber inplhace, v v l t Figure 17 shows the staple fiber flattened back against tube is used'in place ofthe texturing jet; The T tube may be made of any 'smooth material such as glass, stainless steel, or the like,and may vary in diameter from about A" to /2".
In accordance with this invention a novel yarn'is providedwhich has a fuzzyto cashmere-like appearance resulting from a covering of'projecting'fiber ends and unusual bulk, as compared with staple yarns of the prior art, resulting from fibers which are convoluted into coils, loops and whorls at random intervals along their lengths and at irregular spacing on difierent fibers toprovide a lateral interfib'er' spacing? The most obvious characteristics of the yarn arethe combination of unusual'bulkiness with'the fuzzy covering providedby protruding fiber "ends, buttlie 'yarn'is'a'lso' characterized by the presence of a multitude of ring-like loops and other convolutions in the fibers' The'convolutions'visible on'the surface contribute desirable properties to the yarn, but the less obvious fiber convolutions within the yarn are even more important in producing bulk andresulting garment warmth of fabrics made from this yarn. I a
The characteristic loops in the yarn fibers have been described as ring-like because they are tiny complete loops formed bya fiberdoubling back upon itself, crossing itselfand then proceeding-insubstantially'the original direction. In mathematic's acu'rve o'fjtliis type is said to have a crunode';' "Accordingly the characteristic loops will'bemore"specifically definedas crunod'al'loops, and l loops of. this type are intended" unlessotherwise indi Gated in the followingsp'ecification and'claims: The
aseaeev majority of loops visible on the surface of the yarn are of a roughly circular shape and are properly described as ring-like. The crunodal loops inside of the yarn are not readily studied, but it is evident that pressure of surrounding filaments will tend to cause such loops to assume more complex shapes.
The fiber ends and convolutions maybe are held in place by a twist imparted to the yarn. A single ply yarn may have a Z or 8 twist. In a multiple ply yarn the individual plies are usually twisted in one direction and the plurality of plies are usually twisted together in the opposite direction, e. g., the plies may have a Z twist and the yarn may have an S twist. Unless the convolutions have been set, as by heating the convoluted yarn, the fibers will resume their original unconvoluted condition when the yarn is untwisted and taken apart; hence initially straight fibers will be recovered in a substantially straight condition. Of course, if the yarn fibers were initially crimped or wavy or curly, they would resume that condition on being separated from the yarn.
The yarn of this invention is prepared by a process which involves feeding yarn through a high velocity fluid jet, under conditions adapted to accomplish the double purpose of imparting bulk-giving convolutions and of providing a multitude of projecting filament ends, and then twisting the filaments together to hold the convolutions and filaments ends in place. In some respects the process resembles that of my copending application, Serial No. 261,635, now Patent No. 2,783,609. However, additional critical conditions must be observed to provide the desired covering of filament ends on the yarn surface.
The starting yarn may be composed of substantially continuous filaments or of staple length fibers, which may be natural fibers or artificial filaments cut to staple length, or the yarn may include two or more of these types.
When treating yarn composed of substantially continuous filaments in accordance with this invention, the
yarn is fed through a jet operated under conditions suchthat the filaments are shattered at random intervals to provide the desired free ends of projecting fiber. In order to accomplish this, the jet must first open up the yarn. The filaments of an untwisted continuous filament yarn are readily separated by the turbulence created by a high velocity jet. Twisted yarn must be untwisted before the filaments can be separated, but this action can also be achieved by the jet; Under proper conditions the jet will apply sufiicient false untwisting to the yarn filaments to permit the jet to open up the yarn, and this is true not only when the yarn is composed of a single twisted ply, but also when it is composed of a plurality of plies which are individually twisted. Once the yarn filaments are separated, suitable jet turbulence will whip the filaments about with such rapidity that the flex life of the material is quickly exceeded and some or many of the filaments are broken.
Operation of the jet at approximately sonic velocity, or near sonic velocity, will accomplish these objectives of opening up the yarn and whipping the filaments about sufficiently to shatter them into relatively short lengths. The distance the yarn travels through the jet should be less than the average length of the fibers produced by this shattering of continuous filaments, so that the fibers will not be removed from the yarn to an objectionable extent. After the yarn is withdrawn from the jet it is twisted to hold the resulting fibers and convolutions in place; The severity of the shattering effect will vary with the flex life of the filament material, under otherwise similar'conditions,'but the structure resulting from the treatment can be controlled by the rate at which the yarn is passed through the jet! Preparation of the yarn of this invention from staple yarn is simpler in at least one respect, since filamentshattering' is not required, but'unexpected' difficulties must be overcome or else 'the yarn is either torn to pieces or is substantially unaffected by the treatment.
The fibers of staple yarn must be held in place by a twist in the yarn, but the yarn must be untwisted while in the jet for the treatment to have appreciable effect.
At near sonic velocities the jet has been found to apply a substantial untwisting torque as well as considerable tension to the yarn. If the yarn is permitted to untwist in response to this torque for a distance which exceeds the fiber length, the draft yield strength of the yarn is reduced to such an extent that the accompanying jet tension is sufficient to pull the yarn apart. When the yarn is through the jet to a windup, it has been found that the untwisting action of the jet is limited to the iength of yarn between the feed and windup devices. In other words, the jet torque applies a false untwist to the yarn. The extent of this false untwisting action is inversely proportional to the tension applied to the yarn between feed and windup, since tension imposes a torque which opposes the jet torque. Hence the false untwist can be controlled by increasing the tension, but this does not solve the difficulty because the total of the jet tension and windup tension then exceeds the yarn strength.
In accordance with this invention it has been found that yarn which consists wholly or in part of staple length fibers held in place by a yarn twist can be processed efficiently when feeding the yarn to a high velocity fluid jet operated to apply a false untwist to the yarn, by snubbing the yarn passing to the jet to prevent the untwist from backing up, and again snubbing the yarn leaving the jet to prevent the untwist from carrying forward, the distance between the two snubbing points being less than the length of the staple fibers and preferably being arranged to restrict the false untwist to an effective distance of less than one-half the length of the staple fibers. The required snubbing may be accomplished by dragging the yarn over fixed surfaces, which may be the yarn entrance and exit surfaces of the jet nozzle. The yarn leaving the jet can be snubbed by directing it against a baffle plate which also serves to remove the yarn from the jet stream.
The action of the jet in untwisting the yarn may be likened to a combing action. The pull of the jet stream acts to straighten the helically twisted fibers, creating a torque which untwists the yarn. A jet operated at near sonic velocity provides sutficient torque to untwist the yarns usually encountered, but it is sometimes desirable, especially with high twist single ply yarn, to provide a: rotating torque jet which rotates in the opposite direction from that of the yarn twist to accentuate the false untwisting torque of the jet. Purely mechanical means for applying false twist are known in the art, but are not necessary to accomplish the false untwist described. After the fibers have been untwisted the turbulence of a high velocity jet will act to separate the fibers and form them individually into convolutions with outwardly projecting fiber ends. Both staple yarn and continuous filament yarn can therefore be processed in a similar manner with a near sonic velocity jet to produce the desired bulky yarn having a covering of projecting fiber ends.
Plied yarn can be processed somewhat more readily than single ply yarn because the plies exert a snubbing action on each other which tends to resist untwisting of the fibers. This effect can supply a part or all of the snubbing action required to prevent the region of false untwist from being so extensive that the yarn is pulled apart. This is most easily seen in the case of a plied staple yarn of the usual type in which the singles twist is in one direction, e. g., a Z twist, and the ply twist is in the opposite direction, e. g., an S twist. An untwisting torque applied to the ply fibers also causes the plies to twist together in the opposite direction, which increase of ply twist opposes the above torque and tends to prevent the fibers from being separated for more than a short distance. If'the twist 'is sufficiently great, as in a high twist yarn, this opposition to fiber separation provides all of the snubbing needed and it is not -necessary to rely on snubbing surfaces before and after the jet. The same assess thing is true to a lesser entent. when the plies fed to the jet are nottw isted together. The plies still provide a snub bing action which opposes forces tending to'untwist the fibe rs of aply. Thus two separate single ply yarns can be fed to a jet together andproce'ss ed into a single yarn in accordance with this invention'with less diflicult'y than a single ply. When one ply is composed of continuous filaments and another ply composed of staple-length fibers, the continuous filaments also help resist tensions tending to exceed the draft yield strength of the staple ply.
Figure "1 shows a suitable arrangement of apparatus for practicing the process of this invention.- The starting yarn may be supplied from any convenient source, such as a yarn package, and may come directly-from the spinning process by which it is produced without intermediate wind-up. The yarn is passed between feed rolls 12 and 14, arranged to be driven so as to forward the yarn at the desired speed, which is preferably of the order of 50 to 100 yards per minute but may vary over a wide range. These feed rolls are mounted on a pedestal 16. The yarn passes through guide 18 on support 20 and into a jet nozzle supported by air supply pipe 22. The nozzle is shown in section to clarify the construction. The body Po t on 2 of th nozz s h ll n is p o with a fluid exit 26 which has a venturi-like shape to create the required high velocity jet. A hollow male member 28 is threaded into thebody at 30 and terminates in a cone 32 projecting into the mouth of the jet-forming exit 26. The yarn passes inside the male member, out through a hole in the projecting cone, and is carried out of the nozzle exit 26 by the jet stream created by air entering the nozzle through pipe 22. The flow of air to the jet can be regulated by valve .34 in the supply pipe. The yarn hole in cone '32 should; be of a size which provides a fairly snug fit around the yarn so that the yarn is snubbed sutiiciently to prevent appreeiable untwisting before the jet is reached, unless equivalent snubbing is provided by other means.
The yarn leaving the nozzle is deflected at right angles by a baf le plateg36 mounted on the, nozzle close to the exit 26. The balfieplate accomplishes the dual purpose ofterminating the action of the high velocity jet on the yarn and of snubbing the yarn against untwisting beyond this point. For reasons previously explained, the distance from the end of the cone '32 to the battle plate must be less than the length of fibers in the treated yarn, and shouldpreferably be such as to limit the false untwisting action of the jet to less than one-half the fiber length. Instead ofthebafileplate, a guide can be used to achieve a similar result. Frequently sufiicient snubbing can be accomplished bypulling the yarn across exit face 38 of the nozzle. When sufiicient" back snubbing is not providedbythe yarn holein cone 32 the yarn can be fed into t o e a n a l s th h yarn. is s u be against other parts of the male member 28. Thejetstreamis operated at a near sonic velocity to separate-the fibers, form them intobulk-givingconvolutions, and cause ffiber ends to project frornthe yarn, all as described previously. The treated yarn now passes through a guide 40 located below baffie 36, and then to a pair of take-up rolls 44 and 46, which are suitably supported on pedestal QZand are driven at a surface speed somewhat less than that of feed rolls 12,14 to provide an overfeed to the jet. The amount of overfeed is one of the factors controlling the amount of bulking action accomplished in the jet and should generally be in the range of 5% to 50%, depending upon'the effect desired. The percent 7 .overfeed is the percent by which the speed of yarn feed to the jet exceeds the take-up speed. The take-up rolls 44, 46 may feed to any suitable wind-up or, alternatively, one of these rolls can be a wind-up roll.
A variety ofv-nozzles can be used instead of'the one illustrated in Figure :1 to ptovide the required jet. A
simple alternative form is shown in Figures 2 and 3. A
metalblock'50 isdrilled lengthwise to provide axial yarn ssage'JSZ. An-air entrance 54 is drilled ata forward angle of about 45 through one face of the block to intercept the yarn passage. When a rotating jet stream is desired the air entrance may be made of smaller diameter than the yarn passage and be ofi center to intercept the yarn passage at one side as shown in Figure 3. Fitting 56 is soldered over the air entrance; it is threaded at 58 for attachment to the air supply pipe 22 of the apparatus shown in Figure 1. In place of air other fluids can be used such as CO steam, or other vapors for special purposes.
The nozzle shown in Figure 4 provides advantages over the two forms already described. The housing 60 may be a standard inch plumbers T. The yarn enters through guide member 61, provided with a funnel-shaped portion 62 to receive the yarn end when stringing up. A hypodermic needle 63 of appropriate size provides a passage for conducting the yarn into the nozzle 64. The nozzle has the shape of a conventional venturi tube with the entrance 65 tapering inward so that opposite sides are at about a 20 angle with each other, and the exit 66 diverging more gradually so that opposite sides are at about a 7 angle with each other. The overall length of the venturi tube may suitably be about 1.3 inches with the diverging exit portion about 1.0 inch'long. The arrangement of guide member 61, needle passage 63 and nozzle 64 makes the device self-stringing when a yarn end is fed to it.
The needle 63 is adjusted to extend into the entrance of the ve'nturi and stop in the venturi throat 67. This adjustment is important for best performance. The manner of adjustment shown is to thread the outside of the nozzle and provide positioning and locking nuts 68, 69. The
nozzle slides with a snug fit into the housing do until not 7 68 rests against the housing. It is held in this position by springs, one of which is indicated at 7%. The guide member til likewise slides into the housing with a snug fit until shoulder 71 is positioned against the housing. it may also be held in position by spring 79 and other similar springs. Advantages of this construction are that it can be taken apart easily for cleaning and the parts can be rotated to adjust the needle in the venturi throat. However, either or both parts may be held in position by set screws pass ing through the housing, or the parts may be threaded into the housing.
Air is supplied to the nozzle through pipe 72, which is threaded orsoldered into the T housing. The air passes through the venturi around the needle 63, the venturi throat 67 being sufficiently larger than the needle to permit passage of the required volume of air. Gasket material may be placed in groove 73 around member 61 and groove 74 around the nozzle to prevent air leakage.
In Figure 13, 1 represents a flock chamber provided with an inlet2 and an exit 3 for the yarn. Between the inlet and exit is an open space containing flock 7. The chamber is also provided with an internal air bafiie. The air supplied through the teXturingjet keeps the flock or linters' in a state of violent agitation. The inlet 2 is usually through a texturing jet which is provided with an air supply 4 and an outlet 5 at the base of a venturi chamber 6.
The yarn is ledthrough the inlet 2 where it is subjected to a high speed air whorls and loops. As the yarn passes through the suspended flock 7, the fibers find their way into the interstices and loops of the yarn where they are held and entrained as the yarn passes through the exit 3 of the flocking chambet 1. a The yarn then proceeds as shown in Figure 14. i
The processand products of the invention will now be illustrated by the following examples, which are not to be jet which textures the yarn forming ment at 40 yards per minute, an overfeed of 50%. Air
was supplied to the nozzle at 90 pounds per square inch gage pressure to give an effective jet velocity of slightly greater than sonic, and an air flow through the nozzle of 2.6 cubic feet per minute measured as free air at atmospheric pressure and temperature. The bafile plate was spaced /s inch from the nozzle exit. The appearance of the untwisted treated yarn is shown in Figure 5. The filaments were convoluted and partially shattered to provide a multitude of filament loops and protruding ends as shown. This yarn was rather weak.
Two plies of the above yarn were fed together to the nozzle at 19 yards per minute and taken up after treatment at 14 yards per minute, an overfeed of 36%. The other conditions were the same as above. Figure 6 shows the appearance of this two-ply yarn after treatment, which exhibited the characteristic fiber loops and ends described above. When twisted the yarn was reasonably strong and processed satisfactorily into fabric.
Qperation of the process as above, but without the bafilc plate, or with the bafile plate spaced one inch or more from the nozzle exit, resulted in the yarn being completely shattered into flock. Operation of the process as above, but at air pressures of 40 pounds per square inch to give air flows of less than 1.0 cubic feet per minute, measured as free air, produced bulk-giving convolutions without appreciable filament shattering, Whereas pressures of 50 or more pounds per square inch produced the multitude of filament loops and ends described above.
EXAMPLE 2 Using the apparatus shown in Figure 1, two separate plies of yarn were fed to the nozzle. One ply was a 20 cotton count, 15 Z twist (15 turns per inch) cotton yarn. The other ply was a 200 denier, 8O filament, continuous filament acrylo-nitrile yarn. The yarns were fed into the nozzle together at 10 yards per minute. Air was supplied to the nozzle at 90 pounds per square inch gage pressure, which gave a flow, as free air, of 2.7 cubic feet per minute. The appearance of the resulting two-ply yarn after receiving a slight twist is shown in Figure 7. The bulk of bothplies was markedlyincreased by the formation of crunodal loops and other convolutions, and cotton fibers were caused to project with a great increase in fuzziness. The cotton ply was extended in length by the treatment, so that it wrapped around the continuous filament ply when the yarn was twisted.
An attempt to treat the cotton yarn alone under similar conditions, but without the baffle plate, resulted in the yarn being completely blown apart and reverted to unspuu staple. The same was true even under such relatively mild conditions as 50 pounds per square inch air pressure and 10% overfeed; the cotton yarn was disintegrated.
EXAMPLE 3 A single ply, 18 cotton count, 18 Z twist spun yarn composed of 3-inch staple length, 3 denier, acrylonitriie fibers was processed with an apparatus similar to that shown in Figure 1. The yarn was taken up from the nozzle at yards per minute and the bafile plate was located /4 inch from the snub point provided by the restricted yarn passage into the jet stream. Air was applied to the nozzle at 90 pounds per square inch gage, the nozzle dimensions being such as to give a flow of about 1 cubic foot per minute with an efiective jet stream velocity of slightly above sonic velocity. The appearance of the treated yarn is shown in Figure 8. The yarn was greatly increased in bulk and the surface was covered with ring-like loops and extending fiber ends, giving the yarn a fuzzy or lofty appearance and feel.
' EXAMPLE 4 A single pl", 18 cotton count, 14 Z twist spun yarn ute and 10% overfeed using an air pressure of 50 pounds per square inch gage. The apparatus was similar to that shown in Figure 1, except that the nozzle shown in Figure 4 was used without a battle plate and yamguide 40 was located beside the nozzle so that the yarn was snubbed across the exit face of the nozzle. The: appearance of the treated yarn was as in Figure 8.. The denier ofthe yarn was increased from 323 to 356.. The effective volume of the yarn was increased to at much greater extent, resulting in a lofty, fuzzy yarnwhich has aesthetic merit, particularly for knitted fabrics. The changes in the yarn structure comprise a separation and reorientation of the fibers in relation to each other accompanied by intertangling to the extent that the reoriented fibers are stabilized in their new positions. The net result is a peripheral expansion of the central core of the yarn with an accompanying marked increase in the number and length of free fiber ends and the formation of crunodal loops and other convolutions characteristic of the process. Some properties of fabrics prepared from the untreated and the treat yarn were as follows:
Fabric properties EXAMPLE 5 A variety of spun yarns were treated in a similar way with like results. The treated yarns were all taken up from the jet at 100 yards per minute, with other conditions as in Example 4 except as indicated in Table 1. In this table, yarn notations such as 50/2 (25 Z, 4' 8 ply) 5 in., 3 d. p. f. in 5(e) refer to a 50 cotton count, 2 ply yarn in which each of the plies has a Z twist of 25 turns per inch and the plies are twisted together in the opposite direction at 4 8 turns per inch, the fibers being 5 inches long and of 3 denier per fiber. Rayon refers to regenerated cellulose yarn made by the viscose process. Dacron and Orlon are trademarks for yarn manufactured by E. I. du Pont de Nemours and Company and refer to polyethylene-terephthalate and polyacrylonitrile yarns, respectively. Nylon refers to polyhexamethyleneadipamide yarn. The appearance of the treated yarns was similar to that shown in Figure 8. However, it was observed that, as the staple length was increased, the amount of loop formation in the yarn bundle increased and, of course, the frequency of protruding ends decreased. The extent of the bulking action could be increased or decreased composed of 4 /2 inch staple length, 3 denier, acrylonitrile fibers was processed at about 100 yards per minby varying the per cent overfeed up or down from the values given in the table, but processing difficulties may be encountered at overfeeds above 15%.
TABLE I.-PREFERRED PROCESS CONDITIONS FOR BULKING SPUN YARNS Over- Alr Pres Ex. Yarn Treated feed, sure,
v Percent lbs/sq. in
5 (11),. 18/104 Z)810in., 3 d. p. f. Rayon 18 50-70 5 (b) 30/109 Z)3.5 in., 3 d. p. f. Rayon- 5 40450 5 (c) 40/102 Z)6-8 in., 3 d. p. f. Rayon 10 60-80 5 (11).- 10/1(1l Z) 51 3 (l. p. f. Dacr0u" 6 60-80 5 (13).--. 50/2O(25 Z, 4 5 ply) 5 in., 3 d. p. f. 6 60-80 in v 5 0).... 18/105 Z) 4-6 in., 2.5 (1. p. f. Nylon- 6 6080 5 (0).... 151104 2) 4 in., 3 d. p. f. blend of 50% 5' 50-70 Dacron, 50% Rayon fibers. V,
EXAMPLE6 1 A 20/1 worsted count 408 its-'1 denierj-bgztwist spun yarn composed of 5 inch, 3 denier, acrylonitrile fibers was processed with the apparatus shown in Fig Qyerage fiber length .of 1%.; vincncs.
square inch gage, the air consumption being 2.44 cubic feet of free air per minute. The treated yarn was characterized by the protrusion of long ends of-fibers from the core of the yarn. These ends projected up to one inch, giving an extremely fuzzy, cashmere-like yarn. In. other respects the yarn was similar to that shown in Figure 8.
EXAMPLE 7 A two ply, 27 cotton count, spun polyethylene-terephthalate yarn was processed at 15 yards per minute with apparatus similar to that in Figure l. The plies of this yarn were composed of 1% inch staple length, 3 denier fibers twisted together at 18 2 turns per inch, and the ply twist was 11 S. Air was supplied to the nozzle at 90 pounds per square inch gage, the flow being about 1 cubic foot of free air per minute. The yarn bulked equally well bothwith and without the baflie plate. The appearance of the yarn is shown in Figure 9 and, except'fo-r the two-ply structure, wassimilar to the yarns described previously inrconnection with Figure 8. In this case the fiber and ply twists were sufiicient to prevent the false untwist imparted by the jet from untwisting the yarn fibers foran undesirable distance, and snubbing against a surface was not necessary.
An attempt was made to process a single ply, 27 cotton count, 18 Z twist yarn composed of 1% inch, 3 denier polyethyleneterephthalate fibers under identical conditions. Without the baflie plate, or other means for snubbing the yarn close to the nozzle exit, the process could not be operated because the air stream pulled the yarn to pieces.
EXAMPLE 8 The previous examples have shown that the jet stream has sufiicient false untwisting action to open up a wide variety of twisted yarns to the extent required by the process of this invention. sirable to accentuate the untwisting action by providing a rotating or torque jet stream. This has been accomplished by cutting oblique or spiralling grooves in the cone-shaped end 32 of the yarn guiding portion of the nozzle in Figure 1. For the purposes of the present example, however, the simple torque nozzle shown in Figures 2 and 3 was used with apparatus similar to that of Figure 1 to process single ply, 18 cotton count, 18 2. twist, spun yarn composed of 3 inch, 3 denier polyacrylonitrile fibers. Air was supplied at 90 pounds per square inch gage to give a flow at near sonic velocity of /2 cubic foot of free air per minute.
Using a nozzle having a A inch yarn passage and arranged to apply an S torque to yarn being treated, with the yarn snubbed A1 inch from the nozzle exit at a distance of 1 inch from the air inlet and then taken up at 15 yards per minute, the Z twist yarn processed excellently to give a multitude of ring-like loops and fuzzy ends. The yarn processed better than the same yarn did the straight-line jet stream of Example 3, even though the air consumption was only one-half as great. This nozzle appeared as in Figure 3 when looking upstream at the nozzle exit. The air inlet 54 was off center to the left,
giving the air stream a-clockwise rotation as it came toward the observer. a 7
An attempt was made to use a. nozzle with the air inlet ofii center to the right, which gave a counterclockwise rotation to the air streamand applied a Z torque to the yarn, but this had no appreciable efiect on the yarn. This 2 torque jet increased the Z twist of the yarn and prevented the opening action necessary for the type of bulking action described. a e 7 However, it is sometimes del3 and 14).
fiber length the bulking effect was somewhat less thanrfor the above 3-inch fiber length polyacrylonitrile yarn. When an attempt was made to treat the cotton yarn with the snubbing point over 1 inch from the nozzle, under otherwise identical conditions, the process was not operable because the yarn pulled apart.
EXAMlLE 9 InExample 8 it was observed that the use of a Z torque jet nozzle increased the twist of the Z twist yarn and prevented opening of the yarn, so that bulking did not take place. However, this type of treatment can be com bined with heat-setting of the yarn while in the overtwisted condition to provide a crimp bulking effect. A single ply, 18 cotton count, 15 Z twist spun yarn composed of 4-6 inch, 2.5 denier, polyhexamethyleneadipamide fibers may be processed as in Example 8, using-a torque nozzle which applies a false twist of about 30 turns per inch. The nozzle may be heated to about 240-250 C. to crimp set the yarn while in the false twisted condition. This produces a bulky wool-like yarn having an attractive curly crimp which imparts elasticity to the yarn. The fibers will retain their crimp when separated from the yarn.
it will often be more convenient to heat the false twisted yarn outside of the nozzle instead of heating the torque nozzle. The yarn guide 18 was spaced at a greater distance from the nozzle than shown in'Figure 1 and a hesttin, surface at 240250 C. was used to crimp set the yarn between the guide and the nozzle. The yarn passed through the torque nozzle without snubbing so that the false twist of'about 30 turns per inch backed up to the yarn guide. With other conditions as described above, a similar crimp bulking effect was: obtained. I
The process of Example 9 is useful with any yarn composed of fibers which can be heat set to stabilize the crimp imparted by the false twist. The treatment is enhanced by fibers which shrink during heat-setting. While the process has been illustrated with spun staple yarn, it
A nylon yarn (80/ 68/0) was fed to a jet similar to Figure 8 of U. 8. 2,783,609 at 240 Y. P. M. The jet was mounted so as to exhaust in an enclosure partly filled with cotton linters of about $6 in length (Figures The pinch rolls as illustrated in Figure 14 were operated at 2G0 Y. P. M. to give an intermediate overfeed of 20%. The wind-up was operated at 230 Y. P. M. to give a net overfeed of 5% and a final denier of 91. 'Since the calculated denier under these condi- 'tions should be 84, the linters increased the yarn weight by about 8%. The yarn sample between the flocking box and the pinch rolls had an appearance illustrated in Cotton yarn also processed excellently under the above conditions with the Storquejet. .Goodresults were ob tained with-a single ply, .18 Ztwist cotton yarn having an Fan Due; to; the short Figure 15. The final yarn showed reduced loop size as shown in Figure 16. Many characteristic random nodes and tangles could be observed under magnification. The short length staple fibers were firmly locked within a continuous filament knot or knot snarlortangle of random configuration and frequently compound in structure; that is, more than one continuous filament and more than one staple fiber involved in a given snarl or tangle. Longer fibers may be used in place of those used to illustrate the invention in this example. In general the flock or linters may vary in len th from about 0.1 rnillhneter, as is usually found in wood'fiour, up to lengths normally employedfor staple.,fibers;,that is, about 1-5 millimeters, .although for many purposesstaple up'to about 5", may
be used. lngeneralthe shorterlengthfibersare loosely bound and have a tendency to be lost in yarn-and fabric Fiaersotnormal staple lengthin'the'range of 1" to 3" are entangled less readily by the bulked yarn and therefore tend to modify the yarn to a lesser extent in terms of the number of free ends. Longer fibers, however, have the advantage of being more permanent in the final fabric.
Any process which tends to entangle the longer fibers in the bulked continuous filament yarn may be used to advantage where the staple is long, for example, it may be desirable to pass the bulked yarn through a loosely compacted hat of randomly arranged fibers. The length of contact and compressional load on the yarn being treated should be balanced to avoid undue yarn tension tending to cause breakdowns but may be suflicient to cause filament loops to become locked about the entangled staple fibers and to deform large loops into the flattened configuration shown in Figure l7. irotruding fibers and elongated loops may be held tern porarily in place by a size to improve weaving perform ance and reduce snagging characteristics in the final fabric.
Where improved yarn stability is the major goal, short length fibers such as Solka-Floc 1 wood cellulose may be employed with good results. The very short length fibers tend to be fugitive to some extent but increase stability of borderline yarns suificiently to permit improved warping, quilling and weaving or knitting. The bulk of the finished fabrics may be enhanced even after loss of the short fibers due to the unoccupied spaces they leave behind.
Similarly, the bulked yarn may be passed through a liquid fiber slurry. With well dispersed fibrous material of suitable length and concentration the yarn emerges with much the appearance of a pipe cleaner and increased weight of up to 50% or more. Tension applied to this yarn may again be used to lock most of these fibers in place. Heavily loaded yarns tend, however, to lose a portion of the loosely attached fibers which may be blown, rubbed or shaken off and returned to the slurry.
The following experiments illustrate embodiments of the invention in which two different yarns are used, one of which is relatively shatterable and the other is relatively unshatterable.
12.. ameter. Air under a pressure of 10 p. s. i. g. was directed through the horizontal leg of the T tube to deflect the yarn from its vertical path. The yarn was passed through the tube at abou 60 Y. P. M. A fuzzy yarn having a soft bulky texture was obtained. The air pressure in the tube may be varied from about 10 p. s. i. g. to about 100 p. s. i. g. It is difficult to determine the velocity of the air in the tube, but when the air is under pressure in the higher range, its speed as it contacts the yarn is of the order of sonic velocity. The yarn processed in this manner has fewer loops and whorls and normally very few broken ends as compared with the products of the examples in which a high speed jet is used in conjunction with yarns containing a brittle com po-nent. The free ends project much further from the yarn bundle after treatment than they do in the starting yarn.
While the examples illustrate the use of acetate fibers as the brittle or shatterable component, it is to be understood that filaments of other materials may be substituted more or less directly in the examples. The suitability of a given filament for the-purpose depends on its tendency to break under the high speed jet action. It has been found that this tendency may be determined by a flex resistance test which consists essentially of bending the filament repeatedly through 180 over a smooth wire under a specified tension. The number of cycles required to cause failure of the specimen is taken as a measure of its flex resistance. The test is carried out by conditioning filaments for at least 16 hours in an atmosphere of 70 F. at 65% relative humidity. Usually 21 filaments are tested together and the number of cycles required to cause failure of 11 filaments is accepted. as the test result. The tension applied to the specimen may be 0.15, 0.3, or 0.6 gram per denier depending upon the brittleness of the sample. It is desirable to select a load factor which will result in a test lasting a minimum of 50 cycles and a maximum of 5,000 cycles. The 0.6 gram per denier load factor is satisfactory for most textile fibers. The order of magnitude of the flex life TABLE II A B C D E F Remarks Example Textnr- Torque Windup O ver- No. Core Ply Fractionable Ply ing Type Jet, Speed, iced, Process Product Jot, p. s. i. Y. P. M. Perp. s. i. cent 11 Dacron 40/27/0 Acetate 55/36/0 e 90 90 204 5 Fig. 10 Many endsiower loops than Fig. 18. Nylon 40/13/1122 Acetate 55/36/0 90 90 204 9 Fig. 10 Fig. 18. Nylon 20/7/1/22 Acetate /24/0 n 100 80 400 3 Fig. 11 Felrver irec curls than lg. 1 Nylon 20/7/1/22 Acetate 30/20/0 a 100 80 409 3 Fig. 12..-- Similar to 13. Green Acetate 150/40/0..- e 100 c 80 410 4 Fig. 12.". Similar to Ex. 13. Green Acetate /36 0-- 100 201 3 Fig Dacron 40/27/0 Acetate 45/24/0 n 100 201 4 Fig Free ends wrap more used in torque completely and projet. trude less from main yarn bundle.
a Fig. 8 U. S.,2.783,609. Torque-jet located at alternate position Fig. 12. d Acetate fibers with Y cross-section.
e Green implies yarn fresh from spinning unit having 54.0% residual solvent. This yarn is generally much tougher than conditioned" yarn which has been allowed to lose acetone by prolonged storage in fresh air.
EXAMPLE 18 Product of the BrownCog Causeway St., Boston 14,
Mass.
commonly used fiber types under a 0.6 g. p. d. load are as follows:
70 Fiber: Flex life Nylon and Dacron 1,000,000 Rayon 3,000 Acetate 300 Polystyrene 10 Glass 1 In general, with other factors held constant, the tougher fibers may be stabilized by use of lower operating speed on the jet so that the individual increments of fiber length are exposed to the flexing action of the jet for a greater length of time, or by use of higher air pressure in the jet which gives a more violent flexing action in the jet. An example of the former deals with rayon which was processed at 20 Y. P. M. to give a product similar to that obtained with acetate at 200 Y. P. M. (roughly in inverse proportion to the tabulated flex lives).
Within a given fiber composition, a great range of flex lives may be obtained by changes in orientation and/ or crystallinity. Normally, nylon and Dacron are much too tough to be fractured by the action of a texturing jet. If, however, they are prepared in a state of low orientation and high crystallinity the flex lives may be reduced to the range of a few hundred to a few thousand cycles. Molecular weight as indicated by relative viscosity in a suitable solvent also plays an important part in determining fiber toughness. Dacron fibers prepared from polymer with a relative viscosity of about 12 even though oriented and crystallized by normal process steps show flex lives in this same low range (10010,000). Usually a filament having a flex life below about 10,000 may be substituted for the acetate in the examples.
Some of the examples and the disclosure illustrate the use of a torque nozzle to process the product of this invention. It is to be understood that this treatment and the torque nozzle per se do not form a part of the present invention since they are disclosed and claimed in copending applications.
Since many dilferent embodiments of the invention may be made without departing from the spirit and scope thereof, it is to be understood that the invention is not limited by the specific illustrations except to the extent defined in the following claims.
I claim:
1. A bulky yarn comprising a plurality of discontinuous fibers twisted together, the fibers being convoluted into coils, loops and whorls at random intervals along their lengths, and the yarn surface exhibiting a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface.
2. A bulky yarn comprising a plurality of twisted staplelength fibers which are individually looped upon themselves at random intervals along their lengths and at irregular spacing on different fibers, said yarn exhibiting a fuzzy surface composed of protruding fiber ends and crunodal loops.
3. A bulky twisted staple yarn characterized by having a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface and having a multitude of fiber convolutions irregularly scattered through the yarn structure providing a bulk-giving lateral interfiber spacing.
4. A bulky yarn composed of at least two plies of twisted staple fiber characterized by having a multitude of ring-like loops and protruding fiber ends irregularly spaced along the yarn surface and having a multitude of fiber convolutions irregularly scattered through the yarn structure providing a bulk-giving lateral interfiber spacing.
5. A bulky yarn having a fuzzy surface formed by a multitude of protruding fiber ends and having a multitude of crunodal loops and other convolutions irregularly scattered through the yarn structure providing a bulk-giving lateral interfiber spacing.
6. A bulky yarn having a fuzzy surface formed by protruding ends of staple fiber and having a core structure comprising substantially continuous filaments which are individually convoluted into coils, loops and whorls at random intervals along their lengths and characterized by the presence of a multitude of crunodal loops.
7. A bulky yarn having a large number of protruding free ends of fiber and an enhanced bulk provided by crunodal loops and other fiber convolutions scattered through the yarn structure, the yarn fibers being twisted together to hold the structure in place.
8. A bulky twisted yarn having a multitude of fiber ends protruding from the surface and comprising a plurality of staple-length fibers which are individually looped upon themselves at random intervals along their lengths and irregularly spaced on different fibers, which loops substantially disappear when the yarn is untwisted and pulled apart.
References Cited in the file of this patent UNITED STATES PATENTS 2,199,400 Geier et a1. May 7, 1940 2,293,003 Hunter Aug. 11, 1942 2,344,892 Modigliani ct al. Mar. 21, 1944 2,581,566 Whitehead et al. Jan. 8, 1952
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US2958919A (en) * 1958-05-14 1960-11-08 Versil Ltd Method and apparatus for producing insulating material
US2982000A (en) * 1956-07-19 1961-05-02 Du Pont Apparatus for bulking yarn
US2985995A (en) * 1960-11-08 1961-05-30 Du Pont Compact interlaced yarn
US2997837A (en) * 1959-12-22 1961-08-29 Du Pont Slub yarn product
US3006137A (en) * 1959-05-04 1961-10-31 Du Pont Fluid twisting apparatus
US3007298A (en) * 1955-05-31 1961-11-07 British Cclanese Ltd Method and apparatus for jet bulking of yarn
US3013379A (en) * 1960-07-05 1961-12-19 Du Pont Process for making elastic bulky composite yarn
US3022563A (en) * 1958-12-02 1962-02-27 Celanese Corp Air jet
US3030690A (en) * 1960-07-20 1962-04-24 Appleton Mills Method of making papermaker's felt
US3034279A (en) * 1957-12-19 1962-05-15 British Celanese Composite textile yarns
US3041816A (en) * 1960-09-29 1962-07-03 Grove Silk Company Method of making sewing thread and product thereof
US3041812A (en) * 1959-12-10 1962-07-03 Kendall & Co Process and apparatus for making novelty yarn
US3053038A (en) * 1957-12-06 1962-09-11 Heberlein Patent Corp Method and apparatus for texturing yarns
US3060674A (en) * 1957-12-19 1962-10-30 Owens Corning Fiberglass Corp Method for producing glass roving
US3069836A (en) * 1958-08-01 1962-12-25 Du Pont Yarn relaxation process using fluid jets
US3079746A (en) * 1961-10-23 1963-03-05 Du Pont Fasciated yarn, process and apparatus for producing the same
US3091913A (en) * 1959-03-13 1963-06-04 Du Pont Variable denier composite yarn
US3098348A (en) * 1954-05-20 1963-07-23 Setar Ag Process for the manufacture of stable single-thread twist-compensated yarns
US3104516A (en) * 1962-05-18 1963-09-24 Du Pont Process for preparing a variable denier composite multifilament yarn
US3110151A (en) * 1961-05-26 1963-11-12 Du Pont Process for producing compact interlaced yarn
US3113413A (en) * 1959-06-08 1963-12-10 Eastman Kodak Co Apparatus and method for producing volumized slub yarn
US3116589A (en) * 1961-12-21 1964-01-07 Du Pont Process for forming a slub yarn
US3118269A (en) * 1964-01-21 Method and apparatus for producing a novelty bulked yarn
US3128527A (en) * 1960-11-23 1964-04-14 Ici Ltd Process for making fabric from bulked yarn
US3137989A (en) * 1959-02-18 1964-06-23 Montedison Spa Dyeable bulky yarns based on polypropylene
US3142147A (en) * 1959-03-09 1964-07-28 Monsanto Co Voluminous yarn from synthetic continuous thermoplastic filaments
US3144747A (en) * 1959-05-05 1964-08-18 Celanese Corp Apparatus for producing a composite novelty slub yarn
US3144687A (en) * 1960-04-06 1964-08-18 Owens Corning Fiberglass Corp Method for forming and processing textile fibers and filamentary materials
US3150481A (en) * 1959-08-05 1964-09-29 Celanese Corp Loopy, gas jet bulked yarn and method
US3153315A (en) * 1960-12-12 1964-10-20 Celanese Corp Kasha-type yarn
US3153316A (en) * 1958-07-15 1964-10-20 Celanese Corp Bulky yarn and method of producing the yarn
US3153895A (en) * 1960-09-01 1964-10-27 Coats & Clark Process of producing a textured sewing thread and a textured sewing thread made thereby
US3167845A (en) * 1960-07-19 1965-02-02 Du Pont Bulk yarn process and apparatus
US3194000A (en) * 1960-02-02 1965-07-13 Celanese Corp Apparatus and method for bulking yarn
US3199284A (en) * 1962-07-26 1965-08-10 Ernest Seragg & Sons Ltd Process for making yarn from a thermoplastic strip
US3200576A (en) * 1963-07-12 1965-08-17 Du Pont Bulky continuous filament yarn of distinct plies having different shrinkage characteristics
US3206922A (en) * 1961-06-19 1965-09-21 Teikokn Jinzo Kenshi Kabushiki Nozzle for producing crimped yarn by the twisting method
US3208125A (en) * 1963-07-17 1965-09-28 Bancroft & Sons Co J Apparatus for making bulked yarn
US3242035A (en) * 1963-10-28 1966-03-22 Du Pont Fibrillated product
US3248274A (en) * 1960-03-30 1966-04-26 Fmc Corp Weftless tape
US3253396A (en) * 1959-06-01 1966-05-31 Beaunit Corp Method and apparatus for making textured yarn and product
US3262177A (en) * 1961-11-01 1966-07-26 Owens Corning Fiberglass Corp Apparatus for producing novelty bulked yarn
US3273328A (en) * 1965-02-04 1966-09-20 Bloch Godfrey Process and apparatus for making bulked filament yarns
US3309855A (en) * 1961-06-09 1967-03-21 Celanese Corp Process and apparatus for producing bulked plied yarn
US3317296A (en) * 1962-12-26 1967-05-02 Pittsburgh Plate Glass Co Process of making fibrous product
US3329757A (en) * 1963-12-26 1967-07-04 Monsanto Co Method of texturing filament yarn
US3336174A (en) * 1965-04-06 1967-08-15 Eastman Kodak Co Method of making a fibrous filter product
US3380242A (en) * 1957-03-01 1968-04-30 American Enka Corp Yarn and method of making same
US3410076A (en) * 1955-11-04 1968-11-12 Eastman Kodak Co Volumized yarn of large denier
US3430427A (en) * 1966-02-17 1969-03-04 Ici Ltd Apparatus and method for forming cohesive filamentary tows
DE1290293B (en) * 1963-02-15 1969-03-06 Du Pont Process for the production of a loop yarn with knob-like thickenings
US3447302A (en) * 1959-01-30 1969-06-03 Du Pont Yarn processing
US3543358A (en) * 1967-10-24 1970-12-01 Du Pont Process for increasing the bulk of multifilament yarn
US3593514A (en) * 1968-10-22 1971-07-20 Techniservice Corp Strand treatment
US3662440A (en) * 1970-08-17 1972-05-16 Du Pont Process for controlling yarn tension and threadline stability during high speed heat treating of the yarn
US3688358A (en) * 1969-05-09 1972-09-05 Asahi Chemical Ind Process for producing bulky yarn from multifilament yarn
JPS5025838A (en) * 1973-07-12 1975-03-18
US3881232A (en) * 1974-06-26 1975-05-06 Enterprise Machine & Dev Resonant baffle for yarn texturing air jet
JPS5076359A (en) * 1973-11-10 1975-06-23
JPS5123614B1 (en) * 1970-01-14 1976-07-17
JPS5134019B1 (en) * 1971-04-28 1976-09-24
US4054025A (en) * 1975-07-23 1977-10-18 Bayer Aktiengesellschaft Process for the production of filament yarns with statistically distributed, broken individual filaments
US4303724A (en) * 1980-09-04 1981-12-01 The Kendall Co. Adhesive tapes containing texturized yarns
US4406310A (en) * 1980-03-12 1983-09-27 Reader A M Secondary carpet backing fabrics
US4519200A (en) * 1983-08-22 1985-05-28 Eastman Kodak Company Textile yarns with loops and free protruding ends
US5613285A (en) * 1994-11-01 1997-03-25 Basf Corporation Process for making multicolor multifilament non commingled yarn

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US3118269A (en) * 1964-01-21 Method and apparatus for producing a novelty bulked yarn
US3098348A (en) * 1954-05-20 1963-07-23 Setar Ag Process for the manufacture of stable single-thread twist-compensated yarns
US3007298A (en) * 1955-05-31 1961-11-07 British Cclanese Ltd Method and apparatus for jet bulking of yarn
US3410076A (en) * 1955-11-04 1968-11-12 Eastman Kodak Co Volumized yarn of large denier
US2982000A (en) * 1956-07-19 1961-05-02 Du Pont Apparatus for bulking yarn
US3380242A (en) * 1957-03-01 1968-04-30 American Enka Corp Yarn and method of making same
US3053038A (en) * 1957-12-06 1962-09-11 Heberlein Patent Corp Method and apparatus for texturing yarns
US3034279A (en) * 1957-12-19 1962-05-15 British Celanese Composite textile yarns
US3060674A (en) * 1957-12-19 1962-10-30 Owens Corning Fiberglass Corp Method for producing glass roving
US2958919A (en) * 1958-05-14 1960-11-08 Versil Ltd Method and apparatus for producing insulating material
US3153316A (en) * 1958-07-15 1964-10-20 Celanese Corp Bulky yarn and method of producing the yarn
US3069836A (en) * 1958-08-01 1962-12-25 Du Pont Yarn relaxation process using fluid jets
US3022563A (en) * 1958-12-02 1962-02-27 Celanese Corp Air jet
US3447302A (en) * 1959-01-30 1969-06-03 Du Pont Yarn processing
US3137989A (en) * 1959-02-18 1964-06-23 Montedison Spa Dyeable bulky yarns based on polypropylene
US3142147A (en) * 1959-03-09 1964-07-28 Monsanto Co Voluminous yarn from synthetic continuous thermoplastic filaments
US3091913A (en) * 1959-03-13 1963-06-04 Du Pont Variable denier composite yarn
US3006137A (en) * 1959-05-04 1961-10-31 Du Pont Fluid twisting apparatus
US3144747A (en) * 1959-05-05 1964-08-18 Celanese Corp Apparatus for producing a composite novelty slub yarn
US3253396A (en) * 1959-06-01 1966-05-31 Beaunit Corp Method and apparatus for making textured yarn and product
US3113413A (en) * 1959-06-08 1963-12-10 Eastman Kodak Co Apparatus and method for producing volumized slub yarn
US3150481A (en) * 1959-08-05 1964-09-29 Celanese Corp Loopy, gas jet bulked yarn and method
US3041812A (en) * 1959-12-10 1962-07-03 Kendall & Co Process and apparatus for making novelty yarn
US2997837A (en) * 1959-12-22 1961-08-29 Du Pont Slub yarn product
US3194000A (en) * 1960-02-02 1965-07-13 Celanese Corp Apparatus and method for bulking yarn
DE1291849B (en) * 1960-03-30 1969-04-03 Fmc Corp Process for the production of a tape which consists of a multiplicity of parallel threads held together by a layer of plastic or the like
US3248274A (en) * 1960-03-30 1966-04-26 Fmc Corp Weftless tape
US3144687A (en) * 1960-04-06 1964-08-18 Owens Corning Fiberglass Corp Method for forming and processing textile fibers and filamentary materials
US3013379A (en) * 1960-07-05 1961-12-19 Du Pont Process for making elastic bulky composite yarn
US3167845A (en) * 1960-07-19 1965-02-02 Du Pont Bulk yarn process and apparatus
US3030690A (en) * 1960-07-20 1962-04-24 Appleton Mills Method of making papermaker's felt
US3153895A (en) * 1960-09-01 1964-10-27 Coats & Clark Process of producing a textured sewing thread and a textured sewing thread made thereby
US3041816A (en) * 1960-09-29 1962-07-03 Grove Silk Company Method of making sewing thread and product thereof
US2985995A (en) * 1960-11-08 1961-05-30 Du Pont Compact interlaced yarn
US3128527A (en) * 1960-11-23 1964-04-14 Ici Ltd Process for making fabric from bulked yarn
US3153315A (en) * 1960-12-12 1964-10-20 Celanese Corp Kasha-type yarn
US3110151A (en) * 1961-05-26 1963-11-12 Du Pont Process for producing compact interlaced yarn
US3309855A (en) * 1961-06-09 1967-03-21 Celanese Corp Process and apparatus for producing bulked plied yarn
US3206922A (en) * 1961-06-19 1965-09-21 Teikokn Jinzo Kenshi Kabushiki Nozzle for producing crimped yarn by the twisting method
US3079746A (en) * 1961-10-23 1963-03-05 Du Pont Fasciated yarn, process and apparatus for producing the same
US3262177A (en) * 1961-11-01 1966-07-26 Owens Corning Fiberglass Corp Apparatus for producing novelty bulked yarn
US3116589A (en) * 1961-12-21 1964-01-07 Du Pont Process for forming a slub yarn
US3104516A (en) * 1962-05-18 1963-09-24 Du Pont Process for preparing a variable denier composite multifilament yarn
US3199284A (en) * 1962-07-26 1965-08-10 Ernest Seragg & Sons Ltd Process for making yarn from a thermoplastic strip
US3317296A (en) * 1962-12-26 1967-05-02 Pittsburgh Plate Glass Co Process of making fibrous product
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US3200576A (en) * 1963-07-12 1965-08-17 Du Pont Bulky continuous filament yarn of distinct plies having different shrinkage characteristics
US3208125A (en) * 1963-07-17 1965-09-28 Bancroft & Sons Co J Apparatus for making bulked yarn
US3242035A (en) * 1963-10-28 1966-03-22 Du Pont Fibrillated product
US3329757A (en) * 1963-12-26 1967-07-04 Monsanto Co Method of texturing filament yarn
US3273328A (en) * 1965-02-04 1966-09-20 Bloch Godfrey Process and apparatus for making bulked filament yarns
US3336174A (en) * 1965-04-06 1967-08-15 Eastman Kodak Co Method of making a fibrous filter product
US3430427A (en) * 1966-02-17 1969-03-04 Ici Ltd Apparatus and method for forming cohesive filamentary tows
US3543358A (en) * 1967-10-24 1970-12-01 Du Pont Process for increasing the bulk of multifilament yarn
US3593514A (en) * 1968-10-22 1971-07-20 Techniservice Corp Strand treatment
US3688358A (en) * 1969-05-09 1972-09-05 Asahi Chemical Ind Process for producing bulky yarn from multifilament yarn
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US3662440A (en) * 1970-08-17 1972-05-16 Du Pont Process for controlling yarn tension and threadline stability during high speed heat treating of the yarn
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US3881232A (en) * 1974-06-26 1975-05-06 Enterprise Machine & Dev Resonant baffle for yarn texturing air jet
US4054025A (en) * 1975-07-23 1977-10-18 Bayer Aktiengesellschaft Process for the production of filament yarns with statistically distributed, broken individual filaments
US4406310A (en) * 1980-03-12 1983-09-27 Reader A M Secondary carpet backing fabrics
US4303724A (en) * 1980-09-04 1981-12-01 The Kendall Co. Adhesive tapes containing texturized yarns
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