US2779066A - Insulated refrigerator wall - Google Patents

Insulated refrigerator wall Download PDF

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Publication number
US2779066A
US2779066A US289482A US28948252A US2779066A US 2779066 A US2779066 A US 2779066A US 289482 A US289482 A US 289482A US 28948252 A US28948252 A US 28948252A US 2779066 A US2779066 A US 2779066A
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Prior art keywords
insulation
bag
walls
wall
air
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US289482A
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Richard S Gaugler
Edmund F Schweller
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Motors Liquidation Co
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Motors Liquidation Co
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Priority to US289482A priority Critical patent/US2779066A/en
Priority to DEG7264U priority patent/DE1717302U/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/13Insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23Sheet including cover or casing
    • Y10T428/231Filled with gas other than air; or under vacuum
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23Sheet including cover or casing
    • Y10T428/237Noninterengaged fibered material encased [e.g., mat, batt, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23Sheet including cover or casing
    • Y10T428/239Complete cover or casing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249962Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
    • Y10T428/249964Fibers of defined composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797Next to addition polymer from unsaturated monomers

Definitions

  • I INVEN TOR Ri ch ard S. Gaugler.
  • This invention relates to refrigerating apparatus and more particularly to an improved arrangement for insulating the walls of refrigerators and the like.
  • Another object of this invention is to provide a material for packaging insulation which will hold up over a long period of years over relatively wide temperature ranges and which will prevent the passing of the insulating gas from the package to the exterior of the package and which will also prevent the passage of air into the package.
  • Another object of this invention is to provide a packaging material which has the necessary ability to prevent the transfer of moisture into the package as a build-up of moisture in the insulation tends to materially reduce the insulating property thereof.
  • Still another object of this invention is to provide a laminated packaging material whereby any pin holes in each of the laminations are sealed by an adjacent lamination.
  • Another object of this invention is to utilize a laminated material wherein the desirable properties of each of the laminae compensate for the undesirable properties of the other laminae and wherein at least one of the laminae may be heat sealed.
  • a further object of this invention is to provide a refrigerator with bag type insulation having means for compensating for differences in atmospheric pressure. More particularly it is an object of this invention to provide insulation which allows for limited expansion and contraction of the bagged insulation without causing bulging of the walls of the refrigerator.
  • Figure 1 is a pictorial view, with parts broken away, showing a conventional household refrigerator provided with insulation constructed in accordance with the invention
  • Figure 2 is a fragmentary sectional view showing a wall section on an enlarged scale
  • Figure 3 is a fragmentary plan view of 'the material used for enclosing the insulation
  • Figure 4 is a fragmentary sectional view on a greatly enlarged scale showing the manner in which the pin holes in one sheet are sealed by the adjacent sheet and showing the manner in which the adhesive used in laminating the sheets further seals the pin holes;
  • Figure 5 is a plan view of a chart showing the thermal 2,779,066 Patented Jan. 29, 1957 ice conductivity of various gases and vapors at various Fahrenheit temperatures.
  • reference numeral 10 designates the outer shell or housing of a conventional household refrigerator.
  • Reference numeral 12 designates the liner or inner wall of the refrigerator. The space between the inner wall and the outer wall is filled with hermetically sealed bags of insulation 14 and slabs 16 of unbagged insulation.
  • the bags 14, as best shown in Figure 2 of the drawbags, are made up of laminations 18 and 20 which are heat sealed at 24 and which are filled with glass fiber insulation 26 and a gas having a low coefficient of conductivity such as difluorodichloromethane, commonly called Freon or F-12. It has been found that by replacing the air with Freon in each bag of insulation it is possible to materially reduce the rate of heat transfer through the insulation. As shown in the chart in Figure 5 of the drawings, the K factor, which is the factor designating the thermal conductivity of gases and vapors in terms of B. t. u. per hour, per square foot, per degree Fahrenheit, per inch thickness, is much less for Freon than for air, with the result that it is possible to approximately double the insulating ability of bagged insulation when Freon is substituted for the air in the bag. 7
  • the big problem in utilizing the insulating properties of Freon or other similar gases is that of providing a bag which will prevent the loss of Freon from the bag during the life of the refrigerator and which will also prevent the ingress of air into the bag.
  • Some materials have been found to be good barriers for Freon but to be relatively poor barriers for air and if one should use such a material the Freon would remain in the bag but air would enter the bag and, consequently, in accordance with the law of partial pressures, the bag would eventually burst or excessively bulge and the insulating value of the bag would be reduced substantially whereas if one were to select a material which would prevent the ingress of air but would not satisfactorily prevent the loss of Freon, the bags would not only lose their insulating value because of the loss of Freon charge, but would also tend to col lapse and compress the solid insulation fibers so as to materially reduce the insulating property of the assembly.
  • Metal foil would meet the above requirements but its thermal conductivity is too high to be useful in making the bags.
  • the density of the fiber glass insulation 16 is preferably about 1.25 pounds per cubic foot whereas the density of the fiber glass insulation 26 in the bags is preferably about 3.75 pounds per cubic foot.
  • the outer layer of the bags is preferably made of Mylar which is a polyester of ethylene glycol and terephth-alic acid and which is about eight times better than Saran as a barrier to the passage of Freon under some conditions. At higher temperatures encountered, Saran tends to become plastic whereas Mylar does not and, therefore, the combination of the two is very ideal.
  • polystyrene As this is a very good barrier for Freon but not for air and therefore must be used in conjunction with a material such as Saran which will prevent the passage of air.
  • the sheets used for making the laminations should preferably be .001 inch or more thick. The thicker the laminations the less is the leakage but for cost purposes the thickness should be kept down within reason.
  • laminated films it is not only intended to include a film product made by bonding two separate sheets of material together but also to include products made by other processes such as spraying a layer or coating of one material upon a sheet or film of the same or a different material.
  • the method of preparing multiple layers may be varied insofar as certain aspects of the invention are concerned.
  • a refrigerator an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material Within said bag means having voids therein, and a gas filling said voids, said gas having a coefiicient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls, and compressible insulation in the space between said bag means and said walls whereby expansion and contraction of said bag means is permitted without distortion of said Walls.
  • a refrigerator an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material within said bag means having voids therein, and a gas filling said voids, said gas having 'a coefiicient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls, and compressible insulation in the space between said bag means and said Walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, said filler material having a density in excess of the density of said compressible insulation.
  • an outer wall an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material Within said bag means having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, and compressible insulation filling the space between the bag means and said walls, said bag means having laminated walls with adjacent laminations thereof bonded together whereby any holes which may exist in the one lamination are sealed by the adjacent lamination.
  • an outer wall an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material within said bag means having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, and compressible insulation filling the space between the bag means and said walls, said bag means having laminated walls with adjacent laminations thereof bonded together whereby any holes which may exist in the one lamination are sealed by the adjacent lamination, said filler material and said compressible insulation comprising glass fibers.
  • an insulated receptacle an outer wall, an inner wall spaced from said outer wall and insulation between said walls, said insulation comprising a laminated bag in which one lamination comprises a copolymer of vinyl chloride and vinylidene chloride and another lamination comprises a polyester of ethylene glycol and terephthalic acid, filler material within said bag having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air.
  • an insulated receptacle an outer wall, an inner wall spaced from said outer Wall and insulation between said walls, said insulation comprising a laminated bag having one layer substantially impervious to the passage of air and having a second layer substantially impervious to the passage of a given gas, filler material within said bag having voids therein and a quantity of said given gas in said voids, said gas having a coeflicient of thermal conductivity less than that of air.
  • a heat insulating material having voids therein, a bag enclosing said material, a gas having a coefiicient of thermal conductivity less than that of air filling said voids, said bag comprising a laminated film having a first layer substantially impervious to the passage of air and having a second layer substantially impervious to the passage of said gas, one of said layers comprising a copolymer of vinyl chloride and vinylidene chloride and another of said layers comprising a polyester of ethylene glycol and terephthalic acid, and bonding material between said layers and sealing any pinholes in either of said layers.

Description

Jan. 29, 1957 R. s. GAUGLER ETAL 2,779,066
INSULATED REFRIGERATOR WALL Filed May 25, 1952 2 Sheets-Sheet 1 Fig. I Fig. 2
INVENTOR.
Richard S. Gayg/er,
3 ByWZZLJIHd F1 SchweHyeL;
1957 R. s. GAUGLER ET AL 2,779,066
INSULATED REFRIGERATOR WALL Filed May 23, 1952 2 Sheets-Sheet 2 THERMAL CONDUCTIVITY OF GASES a VAPORS TEMP.
.050 .l00 .ISO
.200 K FACTOR F lg. 5
I INVEN TOR. Ri ch ard S. Gaugler.
E imund F. Szhwel/er, By W] r% United States Patent INSULATED REFRIGERATOR WALL Application May 23, 1952, Serial No. 289,482
8 Claims. (Cl. 20-4) This invention relates to refrigerating apparatus and more particularly to an improved arrangement for insulating the walls of refrigerators and the like.
It is an object of this invention to provide an improved and practical insulation in which gas having a low coefficient of thermal conductivity is used in combination with glass fibers or the like.
It is another object of this invention to provide such an insulation which is relatively unaffected in its insulating properties over long periods of years.
Another object of this invention is to provide a material for packaging insulation which will hold up over a long period of years over relatively wide temperature ranges and which will prevent the passing of the insulating gas from the package to the exterior of the package and which will also prevent the passage of air into the package.
Another object of this invention is to provide a packaging material which has the necessary ability to prevent the transfer of moisture into the package as a build-up of moisture in the insulation tends to materially reduce the insulating property thereof.
Still another object of this invention is to provide a laminated packaging material whereby any pin holes in each of the laminations are sealed by an adjacent lamination.
Another object of this invention is to utilize a laminated material wherein the desirable properties of each of the laminae compensate for the undesirable properties of the other laminae and wherein at least one of the laminae may be heat sealed.
A further object of this invention is to provide a refrigerator with bag type insulation having means for compensating for differences in atmospheric pressure. More particularly it is an object of this invention to provide insulation which allows for limited expansion and contraction of the bagged insulation without causing bulging of the walls of the refrigerator.
Further objects and advantages of the present invention will be apparent from the following description, reference being had to the accompanying drawings, wherein a preferred form of the present invention is clearly shown.
In the drawings:
Figure 1 is a pictorial view, with parts broken away, showing a conventional household refrigerator provided with insulation constructed in accordance with the invention;
Figure 2 is a fragmentary sectional view showing a wall section on an enlarged scale;
Figure 3 is a fragmentary plan view of 'the material used for enclosing the insulation;
Figure 4 is a fragmentary sectional view on a greatly enlarged scale showing the manner in which the pin holes in one sheet are sealed by the adjacent sheet and showing the manner in which the adhesive used in laminating the sheets further seals the pin holes; and
Figure 5 is a plan view of a chart showing the thermal 2,779,066 Patented Jan. 29, 1957 ice conductivity of various gases and vapors at various Fahrenheit temperatures.
For purposes of illustrating the invention there is shown in the drawings a household refrigerator whereas certain aspects of the invention are equally applicable to the other types of products wherein it is desired to provide heat insulation for preventing the rapid transfer of heat through a wall section or the like.
Referring now to the drawings wherein a preferred embodiment of the invention is disclosed, reference numeral 10 designates the outer shell or housing of a conventional household refrigerator. Reference numeral 12 designates the liner or inner wall of the refrigerator. The space between the inner wall and the outer wall is filled with hermetically sealed bags of insulation 14 and slabs 16 of unbagged insulation.
The bags 14, as best shown in Figure 2 of the drawbags, are made up of laminations 18 and 20 which are heat sealed at 24 and which are filled with glass fiber insulation 26 and a gas having a low coefficient of conductivity such as difluorodichloromethane, commonly called Freon or F-12. It has been found that by replacing the air with Freon in each bag of insulation it is possible to materially reduce the rate of heat transfer through the insulation. As shown in the chart in Figure 5 of the drawings, the K factor, which is the factor designating the thermal conductivity of gases and vapors in terms of B. t. u. per hour, per square foot, per degree Fahrenheit, per inch thickness, is much less for Freon than for air, with the result that it is possible to approximately double the insulating ability of bagged insulation when Freon is substituted for the air in the bag. 7
The big problem in utilizing the insulating properties of Freon or other similar gases is that of providing a bag which will prevent the loss of Freon from the bag during the life of the refrigerator and which will also prevent the ingress of air into the bag. Some materials have been found to be good barriers for Freon but to be relatively poor barriers for air and if one should use such a material the Freon would remain in the bag but air would enter the bag and, consequently, in accordance with the law of partial pressures, the bag would eventually burst or excessively bulge and the insulating value of the bag would be reduced substantially whereas if one were to select a material which would prevent the ingress of air but would not satisfactorily prevent the loss of Freon, the bags would not only lose their insulating value because of the loss of Freon charge, but would also tend to col lapse and compress the solid insulation fibers so as to materially reduce the insulating property of the assembly. Metal foil would meet the above requirements but its thermal conductivity is too high to be useful in making the bags.
It has been found that it is not only necessary to provide a material which will prevent changes in pressure resulting from leakage through the walls of the bag but is also necessary to provide an insulation which is not adversely affected by changes in atmospheric pressures. Since some refrigerators are used at or near sea level, whereas other refrigerators are used or are transported over routes Where the elevation may exceed ten or more thousand feet, it is apparent a bag filled with Freon at atmospheric pressure at sea level would tend to burst or materially bulge in high altitudes. This problem has been solved by providing extra space between the walls of the refrigerator so as to permit limited expansion of the bags.
As indicated in Figures 1 and 2 of the drawings, this extra space is filled with compressible or loose insulation which is not placed in bags and this then allows the necessary expansion and contraction of the bagged insulation without exerting excessive pressures against the walls of the refrigerator. Thus,.if the bags would expand,
the loose insulation 16 would merely compress Without bulging the Walls of the refrigerator. The density of the fiber glass insulation 16 is preferably about 1.25 pounds per cubic foot whereas the density of the fiber glass insulation 26 in the bags is preferably about 3.75 pounds per cubic foot.
It has been found that by making the bags of laminated material the passage of air and/or Freon through the walls of the bag is materially reduced. There are several reasons for this; in the first place, the laminations are secured to one another by means of adhesive material such as vinyl chloride or a rubber base type of adhesive which would tend to seal the pin holes as shown in Figure 4 of the drawings. Furthermore, when one secures one sheet of material having pin holes to another sheet having pin holes the likelihood of two pin holes becoming aligned with one another is extremely remote with the result that each sheet or layer serves to seal the pinhole openings in the adjacent sheet. Figures 3 and 4 are intended to illustrate this point and in these figures the reference numeral 30 has been used to designate the pin holes in the adiacent sheets and the reference numeral 32 has been used to designate the adhesive which bonds the sheets together and seals the pin holes.
it has been found that a copolymer of vinyl chloride and vinylidene chloride such as the product known as Saran has certain properties which make it ideal for the one layer. Thus, one of the advantages of using such a copolymer for the one layer is that it may be heat sealed whereas most other types of plastic or other sheet material cannot be heat sealed. Furthermore Saran seems to be an ideal barrier to the passage of 'both moisture and air and a fairly good barrier to Freon. Still another ad vantage of the use of copo'lymers of this type is that they stand up well at the low temperatures encountered in refrigeration work. The outer layer of the bags is preferably made of Mylar which is a polyester of ethylene glycol and terephth-alic acid and which is about eight times better than Saran as a barrier to the passage of Freon under some conditions. At higher temperatures encountered, Saran tends to become plastic whereas Mylar does not and, therefore, the combination of the two is very ideal.
Another plastic material which may be used as one of the laminations is polystyrene as this is a very good barrier for Freon but not for air and therefore must be used in conjunction with a material such as Saran which will prevent the passage of air.
The sheets used for making the laminations should preferably be .001 inch or more thick. The thicker the laminations the less is the leakage but for cost purposes the thickness should be kept down within reason.
In referring to laminated films it is not only intended to include a film product made by bonding two separate sheets of material together but also to include products made by other processes such as spraying a layer or coating of one material upon a sheet or film of the same or a different material. In other words the method of preparing multiple layers may be varied insofar as certain aspects of the invention are concerned.
By virtue of the particular combination of materials in the laminated sheets and the insulating gas used, a vastly superior type of insulation has been produced which is capable of retaining its insulating properties over long periods of time without being damaged by temperature or pressure fluctuations or other factors such as moisture, oil, etc.
While the form of embodiment of the invention as herein disclosed constitutes a preferred form, it is to be understood that other forms might be adopted, as may come within the scope of the claims which follow.
What is claimed is as follows:
1. In a refrigerator, an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material Within said bag means having voids therein, and a gas filling said voids, said gas having a coefiicient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls, and compressible insulation in the space between said bag means and said walls whereby expansion and contraction of said bag means is permitted without distortion of said Walls.
2. In a refrigerator, an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material within said bag means having voids therein, and a gas filling said voids, said gas having 'a coefiicient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls, and compressible insulation in the space between said bag means and said Walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, said filler material having a density in excess of the density of said compressible insulation.
3. In a. refrigerator, an outer wall, an inner wall spaced from said outer Wall, insulation between said walls, said insulation comprising outer bag means, filler material within said bag means having voids therein, and a gas filling said voids, said gas having a coeflicient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls, and compressible insulation in the space between said bag means and said walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, said filler material having a density in excess of the density of said compressible insulation, said filler material comprising glass fibers.
4. In a refrigerator, an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material Within said bag means having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, and compressible insulation filling the space between the bag means and said walls, said bag means having laminated walls with adjacent laminations thereof bonded together whereby any holes which may exist in the one lamination are sealed by the adjacent lamination.
5. In a refrigerator, an outer wall, an inner wall spaced from said outer wall, insulation between said walls, said insulation comprising outer bag means, filler material within said bag means having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air, said bag means having a thickness less than the distance between said walls whereby expansion and contraction of said bag means is permitted without distortion of said walls, and compressible insulation filling the space between the bag means and said walls, said bag means having laminated walls with adjacent laminations thereof bonded together whereby any holes which may exist in the one lamination are sealed by the adjacent lamination, said filler material and said compressible insulation comprising glass fibers.
6. In an insulated receptacle, an outer wall, an inner wall spaced from said outer wall and insulation between said walls, said insulation comprising a laminated bag in which one lamination comprises a copolymer of vinyl chloride and vinylidene chloride and another lamination comprises a polyester of ethylene glycol and terephthalic acid, filler material within said bag having voids therein, and a gas filling said voids, said gas having a coefficient of thermal conductivity less than that of air.
7. In an insulated receptacle, an outer wall, an inner wall spaced from said outer Wall and insulation between said walls, said insulation comprising a laminated bag having one layer substantially impervious to the passage of air and having a second layer substantially impervious to the passage of a given gas, filler material within said bag having voids therein and a quantity of said given gas in said voids, said gas having a coeflicient of thermal conductivity less than that of air.
8. In combination, a heat insulating material having voids therein, a bag enclosing said material, a gas having a coefiicient of thermal conductivity less than that of air filling said voids, said bag comprising a laminated film having a first layer substantially impervious to the passage of air and having a second layer substantially impervious to the passage of said gas, one of said layers comprising a copolymer of vinyl chloride and vinylidene chloride and another of said layers comprising a polyester of ethylene glycol and terephthalic acid, and bonding material between said layers and sealing any pinholes in either of said layers.
References Cited in the file of this patent UNITED STATES PATENTS 1,615,801 Elmendorf Ian. 25, 1927 6 Finck July 24, Powell May 7, Munters Jan. 5, Dickson Feb. 23, Roberts Aug. 31, Gould Feb. 1, Leslie Feb. 15, Roberts Apr. 19, Bonsall May 17, Kuenzli Dec. 31., Strauss May 5, Ray Feb. 27, Van Etten Nov. 2, Kleist Jan. 31, Schilling July 4, Bradley July 4, De Sylva Aug. 7, Yung et al May 27, Slatterbeck July 22, Irvine Sept. 16, Pietsch Dec. 16, Sterling Feb. 24,
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Cited By (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2817123A (en) * 1955-03-24 1957-12-24 Gen Motors Corp Refrigerating apparatus
US2834970A (en) * 1957-08-07 1958-05-20 Nappe Moritz Sealed pad
US2863179A (en) * 1955-06-23 1958-12-09 Gen Motors Corp Refrigerating apparatus
US2889078A (en) * 1955-12-16 1959-06-02 Colgate Palmolive Co Dispensing container for pressurepropelled products
US2927626A (en) * 1958-02-03 1960-03-08 Robert G Corwin Insulating blanket for concrete
US2939811A (en) * 1957-03-25 1960-06-07 Gen Electric Heat-insulating units for refrigerator cabinets
US2961030A (en) * 1957-03-15 1960-11-22 Pan American Petroleum Corp Vapor barrier for cold surfaces
US2961342A (en) * 1957-08-15 1960-11-22 Gen Electric Methods of making gas impervious sheet material
US2966229A (en) * 1955-02-15 1960-12-27 Grant E Frezieres Ladder construction
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US5082335A (en) * 1989-12-18 1992-01-21 Whirlpool Corporation Vacuum insulation system for insulating refrigeration cabinets
US5091233A (en) * 1989-12-18 1992-02-25 Whirlpool Corporation Getter structure for vacuum insulation panels
US5330816A (en) * 1992-12-23 1994-07-19 Owens-Corning Fiberglas Technology Inc. High R super insulation panel
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US5408832A (en) * 1992-06-08 1995-04-25 Saes Getters, S.P.A. Thermally insulating jacket and related process
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US5605047A (en) * 1994-01-12 1997-02-25 Owens-Corning Fiberglas Corp. Enclosure for thermoelectric refrigerator and method
US6109712A (en) * 1998-07-16 2000-08-29 Maytag Corporation Integrated vacuum panel insulation for thermal cabinet structures
US6128914A (en) * 1997-04-25 2000-10-10 Sanyo Electric Co., Ltd. Low temperature storage cabinet
US6224179B1 (en) * 1995-05-31 2001-05-01 Bsh Bosch Und Siemens Hausgeraete Gmbh Heat-insulating housing as well as a household oven and a household refrigerator having the housing
US6260377B1 (en) 1999-03-05 2001-07-17 Sanyo Electric Co., Ltd. Refrigerating apparatus
US20020074916A1 (en) * 1999-04-01 2002-06-20 Udo Wenning Thermally insulating wall
US20030157284A1 (en) * 2000-04-21 2003-08-21 Yasuaki Tanimoto Vacuum insulating material and device using the same
US20050235682A1 (en) * 2002-03-13 2005-10-27 Chie Hirai Refrigerator
US20060163395A1 (en) * 2002-08-06 2006-07-27 Akiko Yuasa Method for recycling thermal insulation material, recycled article and refrigerator
US20080000258A1 (en) * 2004-07-29 2008-01-03 Bsh Bosch Und Siemens Hausgerate Gmbh Multi-Part Refrigerator Body and Method for the Production Thereof
US20080174147A1 (en) * 2007-01-24 2008-07-24 Martin Marietta Materials, Inc. Insulated Composite Body Panel Structure for a Refrigerated Truck Body
US20110115355A1 (en) * 2009-11-13 2011-05-19 James Arthur Heckler Appliance door
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WO2018208090A1 (en) * 2017-05-12 2018-11-15 Samsung Electronics Co., Ltd. Heat insulating material and refrigerator having the same
US20190257077A1 (en) * 2011-10-17 2019-08-22 Mark A. Aspenson Building insulation system
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US2966229A (en) * 1955-02-15 1960-12-27 Grant E Frezieres Ladder construction
US2817123A (en) * 1955-03-24 1957-12-24 Gen Motors Corp Refrigerating apparatus
US2863179A (en) * 1955-06-23 1958-12-09 Gen Motors Corp Refrigerating apparatus
US2889078A (en) * 1955-12-16 1959-06-02 Colgate Palmolive Co Dispensing container for pressurepropelled products
US2961030A (en) * 1957-03-15 1960-11-22 Pan American Petroleum Corp Vapor barrier for cold surfaces
US2939811A (en) * 1957-03-25 1960-06-07 Gen Electric Heat-insulating units for refrigerator cabinets
US3039849A (en) * 1957-06-05 1962-06-19 Du Pont Aluminum oxide production
US2834970A (en) * 1957-08-07 1958-05-20 Nappe Moritz Sealed pad
US2961342A (en) * 1957-08-15 1960-11-22 Gen Electric Methods of making gas impervious sheet material
US2927626A (en) * 1958-02-03 1960-03-08 Robert G Corwin Insulating blanket for concrete
US3020183A (en) * 1959-05-13 1962-02-06 Calvaresi Archie Protective insulating mat
US3092530A (en) * 1959-09-21 1963-06-04 Walter A Plummer Heat protective sheathing
US3103042A (en) * 1959-09-28 1963-09-10 Maquinas Fabricacion Sa De Structural building element
US3040539A (en) * 1960-04-27 1962-06-26 Gen Motors Corp Refrigerating apparatus
US3032772A (en) * 1960-08-02 1962-05-08 Raymond L Fonash Protective garment for astronauts employing sublimating salts
US3106307A (en) * 1960-08-03 1963-10-08 Liquefreeze Company Inc Insulated container
US3162566A (en) * 1962-09-04 1964-12-22 Isadore H Katz Thermal insulating blanket for concrete curing
US3357585A (en) * 1963-01-24 1967-12-12 Union Stock Yard & Transit Co Chicago Foamed plastic insulation
US3240029A (en) * 1964-05-04 1966-03-15 Gen Motors Corp Refrigerator cabinets and insulation thereof
US3392864A (en) * 1965-02-03 1968-07-16 Nasa Usa Insulation system
US3722971A (en) * 1969-11-06 1973-03-27 Hefendehl H Plastic box furniture
US3695483A (en) * 1970-11-27 1972-10-03 Louis A Pogorski Thermal insulation and thermally insulated device
US4139024A (en) * 1971-07-29 1979-02-13 General Electric Company Thermal insulation structure
US3804481A (en) * 1972-12-27 1974-04-16 Whirlpool Co Refrigerator cabinet structure
US3910658A (en) * 1974-01-14 1975-10-07 Whirlpool Co Refrigeration apparatus enclosure structure
US3913996A (en) * 1974-01-14 1975-10-21 Whirlpool Co Refrigeration apparatus enclosure structure
US3933398A (en) * 1974-01-14 1976-01-20 Whirlpool Corporation Refrigeration apparatus enclosure structure
US3989329A (en) * 1974-01-14 1976-11-02 Whirlpool Corporation Refrigeration apparatus enclosure structure
US3960631A (en) * 1974-08-30 1976-06-01 Whirlpool Corporation Method of making a liner construction
US4050145A (en) * 1975-08-04 1977-09-27 Whirlpool Corporation Method of making refrigeration apparatus enclosure structure
US4194329A (en) * 1976-01-20 1980-03-25 Wendt Alan C Sound absorbing panels
US4172915A (en) * 1978-07-31 1979-10-30 American Can Company Thermal insulation
US4340630A (en) * 1980-04-04 1982-07-20 Doty Francis D Low conductivity gas sealed building insulation
US4399645A (en) * 1980-12-15 1983-08-23 Lou Weitz Bladder insulation
US4636415A (en) * 1985-02-08 1987-01-13 General Electric Company Precipitated silica insulation
US4675225A (en) * 1985-04-05 1987-06-23 J.M.J. Technologies Inc. Thermal insulating blanket
US4681788A (en) * 1986-07-31 1987-07-21 General Electric Company Insulation formed of precipitated silica and fly ash
EP0263511A2 (en) * 1986-10-08 1988-04-13 Union Carbide Corporation Vacuum insulation panel
US4726974A (en) * 1986-10-08 1988-02-23 Union Carbide Corporation Vacuum insulation panel
EP0263511A3 (en) * 1986-10-08 1988-08-24 Union Carbide Corporation Vacuum insulation panel
US5044705A (en) * 1986-11-17 1991-09-03 Soltech, Inc. Insulation structure for appliances
US5056279A (en) * 1987-09-29 1991-10-15 Veldhoen George G Flat panel and method for fabricating it
US4974382A (en) * 1989-01-06 1990-12-04 Constructonika, Inc. Infiltration and energy barrier
US5018328A (en) * 1989-12-18 1991-05-28 Whirlpool Corporation Multi-compartment vacuum insulation panels
US5082335A (en) * 1989-12-18 1992-01-21 Whirlpool Corporation Vacuum insulation system for insulating refrigeration cabinets
US5091233A (en) * 1989-12-18 1992-02-25 Whirlpool Corporation Getter structure for vacuum insulation panels
US5379568A (en) * 1992-04-13 1995-01-10 Murray; Earl W. Method and apparatus for providing cellulose-filled insulation batts
USRE42467E1 (en) 1992-06-08 2011-06-21 Saes Getters S.P.A. Thermally insulating jacket and related process
US5408832A (en) * 1992-06-08 1995-04-25 Saes Getters, S.P.A. Thermally insulating jacket and related process
US5330816A (en) * 1992-12-23 1994-07-19 Owens-Corning Fiberglas Technology Inc. High R super insulation panel
US5522216A (en) * 1994-01-12 1996-06-04 Marlow Industries, Inc. Thermoelectric refrigerator
US5605047A (en) * 1994-01-12 1997-02-25 Owens-Corning Fiberglas Corp. Enclosure for thermoelectric refrigerator and method
US5505046A (en) * 1994-01-12 1996-04-09 Marlow Industrie, Inc. Control system for thermoelectric refrigerator
US6224179B1 (en) * 1995-05-31 2001-05-01 Bsh Bosch Und Siemens Hausgeraete Gmbh Heat-insulating housing as well as a household oven and a household refrigerator having the housing
US6128914A (en) * 1997-04-25 2000-10-10 Sanyo Electric Co., Ltd. Low temperature storage cabinet
US6109712A (en) * 1998-07-16 2000-08-29 Maytag Corporation Integrated vacuum panel insulation for thermal cabinet structures
US6260377B1 (en) 1999-03-05 2001-07-17 Sanyo Electric Co., Ltd. Refrigerating apparatus
US20020074916A1 (en) * 1999-04-01 2002-06-20 Udo Wenning Thermally insulating wall
US7645003B2 (en) * 1999-04-01 2010-01-12 Bsh Bosch Und Siemens Hausgeraete Gmbh Thermally insulating wall
US6938968B2 (en) * 2000-04-21 2005-09-06 Matsushita Refrigeration Company Vacuum insulating material and device using the same
US20030157284A1 (en) * 2000-04-21 2003-08-21 Yasuaki Tanimoto Vacuum insulating material and device using the same
US20050235682A1 (en) * 2002-03-13 2005-10-27 Chie Hirai Refrigerator
US7278279B2 (en) * 2002-03-13 2007-10-09 Matsushita Refrigeration Co. Refrigerator
US20060163395A1 (en) * 2002-08-06 2006-07-27 Akiko Yuasa Method for recycling thermal insulation material, recycled article and refrigerator
US20080000258A1 (en) * 2004-07-29 2008-01-03 Bsh Bosch Und Siemens Hausgerate Gmbh Multi-Part Refrigerator Body and Method for the Production Thereof
US20080174147A1 (en) * 2007-01-24 2008-07-24 Martin Marietta Materials, Inc. Insulated Composite Body Panel Structure for a Refrigerated Truck Body
US8342588B2 (en) * 2007-01-24 2013-01-01 Martin Marietta Materials, Inc. Insulated composite body panel structure for a refrigerated truck body
US20110315693A1 (en) * 2009-05-15 2011-12-29 Whirlpool Corporation Insulation panels applied to or as a feature module
US8726690B2 (en) * 2009-05-15 2014-05-20 Whirlpool Corporation Insulation panels applied to or as a feature module
US20110115355A1 (en) * 2009-11-13 2011-05-19 James Arthur Heckler Appliance door
US8714672B2 (en) * 2009-11-13 2014-05-06 Fisher & Paykel Appliances Limited Appliance door
US20190257077A1 (en) * 2011-10-17 2019-08-22 Mark A. Aspenson Building insulation system
US20140329042A1 (en) * 2011-12-05 2014-11-06 Dow Corning Corporation Wall Insulation Panel
US20170096284A1 (en) * 2014-06-03 2017-04-06 Panasonic Intellectual Property Management Co., Ltd. Vacuum heat insulating body, and heat insulating container and heat insulating wall employing same
US10501931B2 (en) 2015-12-17 2019-12-10 Rockwool International A/S Method of producing an insulation product and a product obtained by said method
WO2018208090A1 (en) * 2017-05-12 2018-11-15 Samsung Electronics Co., Ltd. Heat insulating material and refrigerator having the same

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