US2690424A - Apparatus for reduction of heavy edge coating in electroplating - Google Patents

Apparatus for reduction of heavy edge coating in electroplating Download PDF

Info

Publication number
US2690424A
US2690424A US196589A US19658950A US2690424A US 2690424 A US2690424 A US 2690424A US 196589 A US196589 A US 196589A US 19658950 A US19658950 A US 19658950A US 2690424 A US2690424 A US 2690424A
Authority
US
United States
Prior art keywords
strip
anode
path
mask
inclined surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US196589A
Inventor
Edward J Hassell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Steel Corp
Original Assignee
National Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Steel Corp filed Critical National Steel Corp
Priority to US196589A priority Critical patent/US2690424A/en
Application granted granted Critical
Publication of US2690424A publication Critical patent/US2690424A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0614Strips or foils
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode

Definitions

  • the present invention relates to improvements in a method of and apparatus for electroplating strip material and more particularly relates to improvements in the electroplating of a conductive surface of elongated strip, such as metal strip, with a protective coating of metal while the strip is being moved continuously and progressively along a predetermined path.
  • the strip When electroplating strip metal, the strip is progressively moved across one or a series of electroplating cells past a soluble anode of electroplatabl metal while the surface to be plated is in contact with an electroplating bath in the cell.
  • the anode is wide enough to extend across the path of the strip from one edge to the opposite edge of the surface being plated.
  • the anode is made up of a series of elongated anode elements or bars arranged side by side with their length parallel to the direction of strip travel. These anode bars are supported on a surface extending across the path of the strip, and this surface is inclined so that the surface is farther away at one side than at the other side of the strip.
  • the anod bars are eroded, and to compensate for this erosion, a fresh anode bar is periodically inserted at the side of the anode which is farther away from the strip.
  • this new anode bar is added, the other bars are pushed up the inclined surface and the anode bar previously adjacent the opposite edge of the strip is pushed out beyond the strip.
  • This last mentioned eroded anode bar is then removed from the electroplating bath and scrapped. With this arrangement, the width of the anode is equal to the total width of the anode bars.
  • the width of the anode being a multiple of the width of the anode bar, it is usually impossible to obtain the exact width of the anode which Will be the correct or best width for the strip being plated.
  • Another problem encountered in practice is that successive lengths of strip vary in width. If this variation in width is relatively large, the width of the anode is varied by increasing or decreasing the number of anode bars in the anode.
  • the anode bars are arranged to provide an anode as wide as or slightly wider than is required for the widest strip and narrower strips will be plated with the same arrangement of anode bars. Accordingly, most if not all, electroplated strip is excessively coated along the edges which is undesirable and which constitutes a waste of valuable metal.
  • Another object of the present invention is to provide a method of and apparatus for continuously electroplating strip material of varying width.
  • Another object of the present invention is to provide an improved method of and apparatus for electroplating strip with a layer of metal of uniform thickness that will not require the carrying in stock of a large number of difierent size of anode elements or bars to obtain an anode having the proper width.
  • the fresh anode bar is positioned along one edge of the anode.
  • a mask interposed between the eroded anode bar and the opposite edge portion of the strip. This mask is positioned so as to reduce the effective width of the anode whereby a more nearly uniform layer of metal is deposited on the strip, particularly along the opposite edge portion of the strip.
  • the eroded anode bar can extend beyond the strip and the mask prevents the depositing of excess metal on the adjacent edge of the strip.
  • the manufacturer of electroplated strip need not carry a large stock of different sizes of anode bars to obtain an anode of the proper -width.
  • the anode when successive lengths of strip of different width are to be plated, the anode is automatically moved laterally of the strip to maintain the fresh anode adjacent the same edge of the successive lengths. This is particularly important as the eroded or partially eroded anode bar at the opposite side has its shape deformed as a result of the mask being present so that when the width of the strip changes, this eroded or partially eroded anode bar that has been partially masked must be discarded. By maintaining the fresh anode bar in the proper electroplating position adjacent the same edge of the strip regardless of the width of the strip, the waste anode metal is greatly reduced.
  • Figure 1 is a plan view with the strip removed of a portion of an electroplating line including an electroplating cell embodying the principles of the present invention
  • Figure 2 is a view in cross-section taken along line 22 of Figure 1;
  • Figure 3 is a view in cross-section taken along line 33 of Figure 2;
  • Figure 4 is a view in cross-section similar to Figure 3 showing a different arrangement of the parts
  • Figure 5 is a fragmentary sectional view taken along 55 of Figure 2 and diagrammatically illustrating an electrical control means
  • Figure 6 is a fragmentary sectional View taken along line 6-E of Figure 4.
  • metal strip after being cleaned and pickled is continuously moved along a path across a series of electroplating cells or a single long electroplating cell with the surface or surfaces to be plated in contact with an electroplating bath in the cell. Both surfaces of the strip may be plated simultaneously or only one surface may be plated at a time.
  • a strip S is progressively moved horizontally across a series of similar electroplating cells Ill and the bottom surface H is plated with anode metal.
  • the strip S may be brought back across a second series of cells (not shown) to electroplate the other surface 12 of the strip.
  • the cells it ⁇ are similar and only one cell will be described in detail, it being understood that one or any number of cells may be used.
  • each pair preferably the upper roll, is a contact roll and is adapted to connect the strip S as a cathode to one side of a source of electric current.
  • the other roll of each pair is a back-up roll which holds the strip against the contact roll to grip the strip therebetween.
  • the cell Ill is arranged along the path of the strip S and includes a tray [6 having side walls ll, an entry end wall iii and an exit end wall is.
  • the tank or tray I6 is adapted to confine a body of electroplating solution and bottom surface if of the strip S contacts the bath of solution as the strip moves across the tray.
  • An anode supporting guide 20 provides a pair of shoulders 2i and 22 and has a conductive member ertending above tray it. At the entry end of the tray it, there is an anode support 25 a similar anode support 26 at the exit end of the tray.
  • the upper surfaces of supports 25 and 26 and of shoulders 2i and 22 are parallel and are supporting and guiding surfaces for the anode elements 2?.
  • the upper surfaces of guides 22 and 25 support a series of elongated, parallel anode bars or elements 2'! which together constitute an anode 28.
  • the upper surfaces of shoul-- der 2! and support 23 support a similar series of elongated, anode elements 2? which together constitute a second anode 29.
  • the anodes and 29 are identical.
  • Each shoulder 2i and 2.! is electrically connected to conductive member 23 for connecting each series of anode elements to the opposite side of a source of electroplating current.
  • each anode element extends longitudinally of the strip.
  • the upper anode contacting and supporting surface of support 25 extends transveis across and from one side to the other side of the path of the strip and this surface is inclined from one side of the strip path upwardly toward the path of the strip and the opposite side of the strip path.
  • the anode supporting surfaces of shoulders 2!, 22, 25 and 26 are parallel so that the ends of each anode element are suppor parallel inclined surfaces.
  • the angle of tion is such that the surfaces of the elements facing the path of the strip are locate in common plane that is substantially parallel to the bottom surface of the strip.
  • Zhis last-men tioned plane may be inclined a few degrees so that the upper surface of the anode elet. position 3! and the upper surface of anode element in position sl are slightly differently spaced from strip to compensate for anode sion.
  • the relationship of the anode elements constituting either anode will best be understood from a description of the operation.
  • anode metal for e ample, tin, zinc or other metal
  • metal is being con deposited on the bottom surface of the mevl strip and metal is being continuously dissolved from the anode elements so that the anode elements are continuously eroded.
  • a new anode element corresponding to anode element in position 36 is inserted in this position.
  • the remainder of the anode elements are moved up the inclined supporting surface so that the one previously occupying the position indicated at 3! is moved up inclined supporting surface and out of electrolytic r tion with the strip. This last-mentioned erc anode element is then removed from the electplating cell.
  • a fresh anode element is inserted at 30 each time the previously introduced anode element and the other anode elements have been subjected to a predetermined amount of erosion due to the electrodeposition of anode metal on the bottom surface of the strip. It will be apparent that each anode element as it is moved up the inclined supporting surface by the introduction of a fresh anode element at 30 approaches the position of anode element 3 I. During the time that each anode element is in the cell, erosion reduces the dimensions of the anode element so that by the time the anode element reaches the position at 3i, the anode element has been sufficiently eroded so that it should be removed from the electroplating cell.
  • One of the problems in producing electroplated strip is to deposit a coating that is substantially uniform in thickness across the width of the strip surface. In order to do this, it is necessary to properly position the anode element at 39 adjacent the corresponding edge 32 of strip S and to properly position the anode element at 3! adjacent the corresponding edge 33 of the strip S.
  • the anode elements are formed by casting and produced in one size. An electroplating line requires a large number of anode bars and producing these bars in a variety of sizes would be prohibitive in cost.
  • the width of the anode is determined by widths of all of the anode elements. Thus, the width of the anodes depends on the number of anode elements and the widths of the anode can only be changed by adding or subtracting one or more anode elements. Ac cordingly, it frequently happens that the anode is too wide so that excessive metal is deposited along one or both edges of the strip.
  • the width of the of the anode is infinitely varied in accordance to the width of the strip.
  • the anode element at 30 is correctly positioned adjacent the corresponding edge 32 of the strip so that the coating metal will be substantially uniform in thickness.
  • the anode element 3! is incorrectly positioned and extends beyond the edge of the strip so that normally excessive metal would be deposited along the strip edge portion 33.
  • a mask 35 is mounted adjacent the edge 33 between strip S and anode 3i and edge 33 in position to inhibit the electroplating of anode metal onto the edge portion of the strip.
  • the mask 35 which is made of non-conductive material extends part way into the electrical field between the anode element 3! and the strip so as to reduce the current concentration along the edge portion of the strip.
  • the mask preferably does not prevent the plating of metal along the corresponding edge of the strip but only inhibits the electrodeposition of metal.
  • the anode element adjacent the strip edge is preferably positioned so that the strip extends outwardly beyond the anode a short distance to reduce edge effect.
  • the edge 32 extends beyond anode element 30.
  • the mask 35 preferably extends part way beneath the strip S, although the mask would inhibit electroplating if the edge of the mask did not extend beneath the strip because the mask would reduce the width of the path of the electroplating current.
  • the mask 35 is adjustable transversely of the strip surface.
  • a nut 39 is threaded onto each post 38 and each nut carries a collar 49 engaging the mask 35.
  • the nuts 39 can be adjusted to raise or lower the mask and the members 31 are slidable along the upper surfaces of supports 25 and 26 for adjusting the mask transversely of the path of the strip surface H.
  • the mask 35 can be adjusted back and forth transversely of the strip path in a plane parallel to the strip surface to vary the effective width of the anode.
  • the mask be interposed between the strip and the eroded anode at 3!.
  • metal is removed from that portion of anode bar 3
  • the tank I6 is supported for movement across the path of the strip in a plane parallel to the strip surface so that the relatively fresh anode at 39 can be correctly positioned adjacent the edge or side 32 of strip S and so that the anode 30 can be positioned adjacent the same relative side or edge of successive lengths of strip of different widths.
  • a pair of rails 46 are mounted on the framework t! beneath tank It.
  • Flanged wheels 42 are carried by tank I 6 and mounted on rails 46.
  • a reversible motor 48 is mounted on framework 41 and is connected to along lead screw 49 for rotating the screw in either direction.
  • a bracket 59 is connected to tank is and bracket 50 carries a nut 5! which extends screw 49.
  • control circuit for motor 48 includes means responsive to the strip for energizing motor 13 so as to maintain anode 39 adjacent the side 32 of the strip.
  • a bar is mounted on tank It and extends across the tank above the strip and adjacent the entry end of the tank.
  • a bracket 56 is slidably mounted on bar
  • Thebracket 59 carries alight 5'! connected through wires 58 and 59 to wires 5t and 61 which are in turn connected to a source of electric current.
  • Above the light 5? there is a photoelectric cell 83 mounted on bracket 56 and connected through wires 84 and 55 to amplifiers 66.
  • the amplifiers 66 are connected through wires El, 68 to relays 69.
  • the relays $9 are interposed between the power lines 6!, 99 and wires l0, H and E2 which are connected to the motor 58.
  • the amplifiers and relays 56 and 69 are soarranged that when a predetermined portion of the field of photoelectric cell 63 is covered by strip S, no current is supplied to the motor. If the strip S'moves to the left so that more light from lamp reaches photoelectric cell 63, then the motor is energized to move the tray and the photoelectric cell 63 toward the left until the strip intercepts a portion of the light reaching cell 63. If the strip S moves toward the right so as to further reduce the amount of light reaching the photoelectric cell 63 from the lamp 51, then the motor is energized and rotated in the opposite direction to move the tray and photoelectric cell 63 toward the right so that the strip again intercepts the predetermined amount of light. Thus, if the strip weaves laterally, the photoelectric cell ts automatically moves the tray is along the rails is to maintain the anodes in their correct position relative to the surface of the strip.
  • the tray I6 In operation, and assuming that a relatively wide strip, such as strip S, is to be plated, the tray I6 is moved along the rails into alignment with the path of the strip, and enough anode bars 2? are placed in position so that the anode will have a width sufficient to electroplate the entire bottom surface of the strip.
  • the tray it is so positioned that the anode bar in position is adjacent the edge 32 of the strip and the anode bar 3! is adjacent the opposite edge of the strip 33.
  • the width of the anode should be slightly less than the width of the strip surface to prevent the so-called edge effect.
  • the mask and its holder are adjusted to position the edge of the mask between the edge 33 of the strip and the eroded anode 3
  • the strip S is progressively continuously moved across the cells and anode metal is uniformly deposited on the bottom surface.
  • a new anode bar is inserted at 3%). The insertion of this new anode bar pushes the anodes 21 up the inclined surface of the anode supporting means.
  • a succeeding length of strip is relatively narrow, such as strip S, Figure 4, then some of the anode bars 27 are removed so that the width of the anode is as near to the width of the strip as it is possible to make it.
  • the relatively fresh anode bar 36 is positioned adjacent the same corresponding edge 32' of strip S.
  • is positioned adjacent the opposite edge 33' of the strip.
  • the mask 35 is moved into position so that the effective width of the relatively narrower anode is reduced to the width required for the relatively narrower strip.
  • successive lengths of strip of different widths are moved along a path with the center of the various lengths of strip moving along a common line.
  • bracket 56 is moved along 55 of the strip intercepts part of by lamp 5?.
  • the photoelectric cell is positioned adjacent the edge of the strip so that the motor will not be energized except when the strip moves laterally from its normal position. Then if the strip weaves or moves laterally from this normal position in either direction, the photoelectric cell '53 will automatically energize the motor 48 to move the tray and the anode into alignment with the strip.
  • the present apparatus is primarily intended for electroplating tin onto strip steel, such as black plate.
  • the electrodeposited coating is tin
  • the anode bars are formed of tin and these bars are slowly dissolved or eroded to replenish the electroplating bath with tin.
  • the present invention is not limited to the plating of tin but may be utilized for plating other electrically conductive strip materials with other protective metals.
  • an electroplating cell including a tank adapted to contain a body of electroplating solu on, rolle means mounted at the ends of the tank for moving the strip progressively along a across the tank from end so that the edge the light emitted to end with the surface of the strip in contact with the electroplating solution, an anode s porting means located in the tank below the pa of the strip and esenting an inclined facing the of the strip, the inclined surface extending transversely across the tank and across the path of the strip with the lower end of the inclined surface at one side of the path of the strip being farther away from the path of the strip than the upper end of the inclined surface at the opposite side of the path of the strip, an anode supported in the tank by the anode supporting means, the anode being below the path of the strip and spaced from the path of the strip, means for connecting the anode to a source of electroplating current, the anode including
  • an electroplating cell including a tank adapted to contain a body of electroplating solution, roller means mounted at the end of the tank for moving the strip progressively along a path across the tank from end to end with the surface of the strip in contact with the electroplating solution, an anode supportin means located in the tank below the path of the strip and presentin an inclined surface facing the path of the strip, the inclined surface extending transversely across the tank and across the path of the strip with the lower end of the inclined surface at the one side of the path of the strip being farther away from the path of the strip than the upper end of the inclined surface at the opposite side of the path of the strip, an anode supported in the tank by the anode supporting means, the anode being below the path of the strip and spaced from the path of the strip, means for connecting the anode -to a source of electroplating current, the anode including a plurality of elongated

Description

Sept. 28, 1954 iled NOV. 20, 1950 E. J. HASSELL APPARATUS FOR REDUCTION OF HEAVY EDGE COATING IN ELECTROPLATING 3 Sheets-Sheet l INVENTOR.
EDWARD J. /M $SZL Afro/MEX Sept. 28, 1954 E. J. HASSELL APPARATUS FOR REDUCTION OF HEAVY EDGE COATING IN ELECTROPLATING 5 Sheets-Sheet 2 iled NOV. 20, 1950 IN VEN TOR.
Q A -H".".". NM. E F w\ 11 8, nm 2. n. Tm hm. o
P 28, 1954 E. J. HASSELL 2,690,424
APPARATUS FOR REDUCTION OF HEAVY EDGE COATING IN ELECTROPLATING iled Nov. 20 1950 3 Sheets-Sheet 3 REL N15 v INVEN TOR.
601741?!) J. HASSZL.
Patented Sept. 28 1954 APPARATUS FOR REDUCTION OF HEAVY EDGE COATING IN ELECTROPLATING Edward J. Hassell, Dayton, Ohio, assignor to National Steel Corporation, a corporation of Delaware Application November 20, 1950, Serial No. 196,589
2 Claims.
The present invention relates to improvements in a method of and apparatus for electroplating strip material and more particularly relates to improvements in the electroplating of a conductive surface of elongated strip, such as metal strip, with a protective coating of metal while the strip is being moved continuously and progressively along a predetermined path.
When electroplating strip metal, the strip is progressively moved across one or a series of electroplating cells past a soluble anode of electroplatabl metal while the surface to be plated is in contact with an electroplating bath in the cell. The anode is wide enough to extend across the path of the strip from one edge to the opposite edge of the surface being plated. In the type of system with which the present invention is concerned the anode is made up of a series of elongated anode elements or bars arranged side by side with their length parallel to the direction of strip travel. These anode bars are supported on a surface extending across the path of the strip, and this surface is inclined so that the surface is farther away at one side than at the other side of the strip. As plating continues, the anod bars are eroded, and to compensate for this erosion, a fresh anode bar is periodically inserted at the side of the anode which is farther away from the strip. When this new anode bar is added, the other bars are pushed up the inclined surface and the anode bar previously adjacent the opposite edge of the strip is pushed out beyond the strip. This last mentioned eroded anode bar is then removed from the electroplating bath and scrapped. With this arrangement, the width of the anode is equal to the total width of the anode bars. In the past, it has been very difiicult, if not impossible, to produce an electrodeposited layer of metal on the surface of the strip that has the same or substantially the same thickness along the edges as the central portion of the strip surface. The coating along the edges tends to be considerably thicker than on the remainder oi the strip. The edge coating can be maintained at or substantially at the same thickness only by accurately positioning the anode bars that define the lateral edges of the anode in the correct positions relative to the corresponding edges of the strip. If the bars along the anode edges extend outwardly beyond such positions, a heavier coating is deposited as a result of the concentration of plating current at the edges of the strip, and this phenomenon is commonly termed edge effect. With the width of the anode being a multiple of the width of the anode bar, it is usually impossible to obtain the exact width of the anode which Will be the correct or best width for the strip being plated. Another problem encountered in practice is that successive lengths of strip vary in width. If this variation in width is relatively large, the width of the anode is varied by increasing or decreasing the number of anode bars in the anode. Here again, it is often impossible to vary the width of the anode by the proper amount as normally only one size of anode bar is carried in stock so that it is only possible to vary the width of the anode by predetermined amounts. These amounts of variation in the anode width quite often do not coincide with the amounts of variation in strip Width. Where the variations in strip width are relatively small, the manufacturer often will not attempt to vary the width of the anode because it is realized that it will be impossible to make a worthwhile improvement. Accordingly, the anode bars are arranged to provide an anode as wide as or slightly wider than is required for the widest strip and narrower strips will be plated with the same arrangement of anode bars. Accordingly, most if not all, electroplated strip is excessively coated along the edges which is undesirable and which constitutes a waste of valuable metal.
Accordingly, it is an object of the present invention to provid an improved method of and apparatus for electroplating a strip with a layer of protective metal that is more nearly uniform in thickness, particularly along the edge portions of the strip.
Another object of the present invention is to provide a method of and apparatus for continuously electroplating strip material of varying width.
Another object of the present invention is to provide an improved method of and apparatus for electroplating strip with a layer of metal of uniform thickness that will not require the carrying in stock of a large number of difierent size of anode elements or bars to obtain an anode having the proper width.
In accordance with my invention, the fresh anode bar is positioned along one edge of the anode. At the opposite edge of the anode, there is a mask interposed between the eroded anode bar and the opposite edge portion of the strip. This mask is positioned so as to reduce the effective width of the anode whereby a more nearly uniform layer of metal is deposited on the strip, particularly along the opposite edge portion of the strip. The eroded anode bar can extend beyond the strip and the mask prevents the depositing of excess metal on the adjacent edge of the strip. The manufacturer of electroplated strip need not carry a large stock of different sizes of anode bars to obtain an anode of the proper -width. V In addition, when successive lengths of strip of different width are to be plated, the anode is automatically moved laterally of the strip to maintain the fresh anode adjacent the same edge of the successive lengths. This is particularly important as the eroded or partially eroded anode bar at the opposite side has its shape deformed as a result of the mask being present so that when the width of the strip changes, this eroded or partially eroded anode bar that has been partially masked must be discarded. By maintaining the fresh anode bar in the proper electroplating position adjacent the same edge of the strip regardless of the width of the strip, the waste anode metal is greatly reduced.
These and other objects and advantages of the present invention will become apparent from the following description, taken with the accompanying drawings, in which:
Figure 1 is a plan view with the strip removed of a portion of an electroplating line including an electroplating cell embodying the principles of the present invention;
Figure 2 is a view in cross-section taken along line 22 of Figure 1;
Figure 3 is a view in cross-section taken along line 33 of Figure 2;
Figure 4 is a view in cross-section similar to Figure 3 showing a different arrangement of the parts;
Figure 5 is a fragmentary sectional view taken along 55 of Figure 2 and diagrammatically illustrating an electrical control means; and,
Figure 6 is a fragmentary sectional View taken along line 6-E of Figure 4.
In electroplating lines of the type in which a preferred embodiment of the present invention is applicable, metal strip after being cleaned and pickled is continuously moved along a path across a series of electroplating cells or a single long electroplating cell with the surface or surfaces to be plated in contact with an electroplating bath in the cell. Both surfaces of the strip may be plated simultaneously or only one surface may be plated at a time. In the system, a part of which is shown in the drawings, a strip S is progressively moved horizontally across a series of similar electroplating cells Ill and the bottom surface H is plated with anode metal. When desirable, the strip S may be brought back across a second series of cells (not shown) to electroplate the other surface 12 of the strip. The cells it} are similar and only one cell will be described in detail, it being understood that one or any number of cells may be used.
Referring to the drawings and more particularly to Figures 1 and 2, adjacent the entry end of cell Hi there are a pair of rolls I3, and adjacent the exit end of cell Ill there are a pair of rolls I4. The rolls l3 and it are rotatable and the strip S passes between the rolls and across the cell. One roll of each pair, preferably the upper roll, is a contact roll and is adapted to connect the strip S as a cathode to one side of a source of electric current. The other roll of each pair is a back-up roll which holds the strip against the contact roll to grip the strip therebetween.
The cell Ill is arranged along the path of the strip S and includes a tray [6 having side walls ll, an entry end wall iii and an exit end wall is. The tank or tray I6 is adapted to confine a body of electroplating solution and bottom surface if of the strip S contacts the bath of solution as the strip moves across the tray. An anode supporting guide 20 provides a pair of shoulders 2i and 22 and has a conductive member ertending above tray it. At the entry end of the tray it, there is an anode support 25 a similar anode support 26 at the exit end of the tray. The upper surfaces of supports 25 and 26 and of shoulders 2i and 22 are parallel and are supporting and guiding surfaces for the anode elements 2?. The upper surfaces of guides 22 and 25 support a series of elongated, parallel anode bars or elements 2'! which together constitute an anode 28. The upper surfaces of shoul-- der 2! and support 23 support a similar series of elongated, anode elements 2? which together constitute a second anode 29. The anodes and 29 are identical. Each shoulder 2i and 2.! is electrically connected to conductive member 23 for connecting each series of anode elements to the opposite side of a source of electroplating current.
Referring to the drawings and particularly Figure 3, the elongated anodes 2'! of anode a arranged side by side in parallel relationship with their length or longitudinal axes extending Si. stantially parallel to the direction of strip travel. Each anode element extends longitudinally of the strip. The upper anode contacting and supporting surface of support 25 extends transveis across and from one side to the other side of the path of the strip and this surface is inclined from one side of the strip path upwardly toward the path of the strip and the opposite side of the strip path. The anode supporting surfaces of shoulders 2!, 22, 25 and 26 are parallel so that the ends of each anode element are suppor parallel inclined surfaces. The angle of tion is such that the surfaces of the elements facing the path of the strip are locate in common plane that is substantially parallel to the bottom surface of the strip. Zhis last-men tioned plane may be inclined a few degrees so that the upper surface of the anode elet. position 3! and the upper surface of anode element in position sl are slightly differently spaced from strip to compensate for anode sion. The relationship of the anode elements constituting either anode will best be understood from a description of the operation.
Assuming that the electroplating line is in continuous operation, anode metal, for e ample, tin, zinc or other metal, is being con deposited on the bottom surface of the mevl strip and metal is being continuously dissolved from the anode elements so that the anode elements are continuously eroded. Periodically, a new anode element corresponding to anode element in position 36 is inserted in this position. In order to place the anode element 39 into this position, the remainder of the anode elements are moved up the inclined supporting surface so that the one previously occupying the position indicated at 3! is moved up inclined supporting surface and out of electrolytic r tion with the strip. This last-mentioned erc anode element is then removed from the electplating cell. A fresh anode element is inserted at 30 each time the previously introduced anode element and the other anode elements have been subjected to a predetermined amount of erosion due to the electrodeposition of anode metal on the bottom surface of the strip. It will be apparent that each anode element as it is moved up the inclined supporting surface by the introduction of a fresh anode element at 30 approaches the position of anode element 3 I. During the time that each anode element is in the cell, erosion reduces the dimensions of the anode element so that by the time the anode element reaches the position at 3i, the anode element has been sufficiently eroded so that it should be removed from the electroplating cell.
As previously described, the electroplating cell 50 and the anode elements extending longitudinally of the strip are supported and arranged substantially in the same manner as shown and described in Patent No. 2,399,254 which issued on April 30, 1946, to E. W. Rieger et al.
One of the problems in producing electroplated strip is to deposit a coating that is substantially uniform in thickness across the width of the strip surface. In order to do this, it is necessary to properly position the anode element at 39 adjacent the corresponding edge 32 of strip S and to properly position the anode element at 3! adjacent the corresponding edge 33 of the strip S. The anode elements are formed by casting and produced in one size. An electroplating line requires a large number of anode bars and producing these bars in a variety of sizes would be prohibitive in cost. The width of the anode is determined by widths of all of the anode elements. Thus, the width of the anodes depends on the number of anode elements and the widths of the anode can only be changed by adding or subtracting one or more anode elements. Ac cordingly, it frequently happens that the anode is too wide so that excessive metal is deposited along one or both edges of the strip.
In accordance with the present invention, the width of the of the anode is infinitely varied in accordance to the width of the strip. As shown in Figure 3, the anode element at 30 is correctly positioned adjacent the corresponding edge 32 of the strip so that the coating metal will be substantially uniform in thickness. The anode element 3! is incorrectly positioned and extends beyond the edge of the strip so that normally excessive metal would be deposited along the strip edge portion 33. A mask 35 is mounted adjacent the edge 33 between strip S and anode 3i and edge 33 in position to inhibit the electroplating of anode metal onto the edge portion of the strip. The mask 35 which is made of non-conductive material extends part way into the electrical field between the anode element 3! and the strip so as to reduce the current concentration along the edge portion of the strip. The mask preferably does not prevent the plating of metal along the corresponding edge of the strip but only inhibits the electrodeposition of metal. The anode element adjacent the strip edge is preferably positioned so that the strip extends outwardly beyond the anode a short distance to reduce edge effect. The edge 32 extends beyond anode element 30. In order to produce the same effect along the opposite side of the strip, the mask 35 preferably extends part way beneath the strip S, although the mask would inhibit electroplating if the edge of the mask did not extend beneath the strip because the mask would reduce the width of the path of the electroplating current.
The mask 35 is adjustable transversely of the strip surface. On each support 25 and 26, there is mounted a member 31, each carrying a pair of threaded posts 38. A nut 39 is threaded onto each post 38 and each nut carries a collar 49 engaging the mask 35. The nuts 39 can be adjusted to raise or lower the mask and the members 31 are slidable along the upper surfaces of supports 25 and 26 for adjusting the mask transversely of the path of the strip surface H. Thus, the mask 35 can be adjusted back and forth transversely of the strip path in a plane parallel to the strip surface to vary the effective width of the anode.
It is important that the mask be interposed between the strip and the eroded anode at 3!. As electroplating proceeds, metal is removed from that portion of anode bar 3| which is not blanked out or covered by the mask 35 while less metal or no metal is dissolved from that portion of anode bar 3i which is beneath the mask. Accordingly, once the mask is interposed between the anode bar 3| and the edge 33 of the strip and if the mask is subsequently removed, the anode 3! must be discarded as there will be present a raised portion of metal on the anode bar. The raised metal would deposit a streak of heavier metal along the strip surface which is highly undesirable. For this and other reasons, masks have never been used with the present type of anode arrangement. Accordingly, the electroplating operation is carried out in such a manner that a mask can be used and can be used without discarding excessive quantities of partially eroded anode bars.
The tank I6 is supported for movement across the path of the strip in a plane parallel to the strip surface so that the relatively fresh anode at 39 can be correctly positioned adjacent the edge or side 32 of strip S and so that the anode 30 can be positioned adjacent the same relative side or edge of successive lengths of strip of different widths. A pair of rails 46 are mounted on the framework t! beneath tank It. Flanged wheels 42 are carried by tank I 6 and mounted on rails 46. A reversible motor 48 is mounted on framework 41 and is connected to along lead screw 49 for rotating the screw in either direction. A bracket 59 is connected to tank is and bracket 50 carries a nut 5! which extends screw 49. When the motor 48 is energized, tank It and the anode are moved transversely of the strip. The direction of movement depends upon the direction of flow of the current supplied to motor 48.
Preferably, the control circuit for motor 48 includes means responsive to the strip for energizing motor 13 so as to maintain anode 39 adjacent the side 32 of the strip.
Referring more particularly to Figure 5, a bar is mounted on tank It and extends across the tank above the strip and adjacent the entry end of the tank. A bracket 56 is slidably mounted on bar Thebracket 59 carries alight 5'! connected through wires 58 and 59 to wires 5t and 61 which are in turn connected to a source of electric current. Above the light 5? there is a photoelectric cell 83 mounted on bracket 56 and connected through wires 84 and 55 to amplifiers 66. The amplifiers 66 are connected through wires El, 68 to relays 69. The relays $9 are interposed between the power lines 6!, 99 and wires l0, H and E2 which are connected to the motor 58. The amplifiers and relays 56 and 69 are soarranged that when a predetermined portion of the field of photoelectric cell 63 is covered by strip S, no current is supplied to the motor. If the strip S'moves to the left so that more light from lamp reaches photoelectric cell 63, then the motor is energized to move the tray and the photoelectric cell 63 toward the left until the strip intercepts a portion of the light reaching cell 63. If the strip S moves toward the right so as to further reduce the amount of light reaching the photoelectric cell 63 from the lamp 51, then the motor is energized and rotated in the opposite direction to move the tray and photoelectric cell 63 toward the right so that the strip again intercepts the predetermined amount of light. Thus, if the strip weaves laterally, the photoelectric cell ts automatically moves the tray is along the rails is to maintain the anodes in their correct position relative to the surface of the strip.
In operation, and assuming that a relatively wide strip, such as strip S, is to be plated, the tray I6 is moved along the rails into alignment with the path of the strip, and enough anode bars 2? are placed in position so that the anode will have a width sufficient to electroplate the entire bottom surface of the strip. The tray it is so positioned that the anode bar in position is adjacent the edge 32 of the strip and the anode bar 3! is adjacent the opposite edge of the strip 33. Normally, the width of the anode should be slightly less than the width of the strip surface to prevent the so-called edge effect. After the anode bars have been positioned, the mask and its holder are adjusted to position the edge of the mask between the edge 33 of the strip and the eroded anode 3|. The strip S is progressively continuously moved across the cells and anode metal is uniformly deposited on the bottom surface. When the anode bars 2'1 have been sufficiently eroded, a new anode bar is inserted at 3%). The insertion of this new anode bar pushes the anodes 21 up the inclined surface of the anode supporting means. Prior to the insertion of a new anode bar, the mask mounted on the slidable supports 3? is moved up the inclined surface of the anode supporting means out of the way so that the eroded anode bar at position 3i can be pushed out beyond the strip and removed. After this eroded anode bar has been removed, the mask 35 is moved back into position between the edge 33 of the strip and the partially eroded anode bar now in position 3!.
If a succeeding length of strip is relatively narrow, such as strip S, Figure 4, then some of the anode bars 27 are removed so that the width of the anode is as near to the width of the strip as it is possible to make it. The relatively fresh anode bar 36 is positioned adjacent the same corresponding edge 32' of strip S. The eroded anode bar at 3| is positioned adjacent the opposite edge 33' of the strip. After the width of the anode has been varied, the mask 35 is moved into position so that the effective width of the relatively narrower anode is reduced to the width required for the relatively narrower strip. Customarily, successive lengths of strip of different widths are moved along a path with the center of the various lengths of strip moving along a common line. Thus, when a narrower strip is to be plated, it is necessary to en rgize motor 138 to move the tray l6 toward the right to position the anode bar 38 adjacent the edge 32. If a subsequent wider length is to be plated, the tray [6 is moved back toward the left.
Before proceeding to plate the strip and after the tray It has been properly positioned, the
bracket 56 is moved along 55 of the strip intercepts part of by lamp 5?. In other words, the photoelectric cell is positioned adjacent the edge of the strip so that the motor will not be energized except when the strip moves laterally from its normal position. Then if the strip weaves or moves laterally from this normal position in either direction, the photoelectric cell '53 will automatically energize the motor 48 to move the tray and the anode into alignment with the strip.
The present apparatus is primarily intended for electroplating tin onto strip steel, such as black plate. Where the electrodeposited coating is tin, the anode bars are formed of tin and these bars are slowly dissolved or eroded to replenish the electroplating bath with tin. The present invention is not limited to the plating of tin but may be utilized for plating other electrically conductive strip materials with other protective metals.
I claim:
1. In an apparatus for progressively electroplating a surface of an elongated metal strip, the combination comprising an electroplating cell including a tank adapted to contain a body of electroplating solu on, rolle means mounted at the ends of the tank for moving the strip progressively along a across the tank from end so that the edge the light emitted to end with the surface of the strip in contact with the electroplating solution, an anode s porting means located in the tank below the pa of the strip and esenting an inclined facing the of the strip, the inclined surface extending transversely across the tank and across the path of the strip with the lower end of the inclined surface at one side of the path of the strip being farther away from the path of the strip than the upper end of the inclined surface at the opposite side of the path of the strip, an anode supported in the tank by the anode supporting means, the anode being below the path of the strip and spaced from the path of the strip, means for connecting the anode to a source of electroplating current, the anode including a plurality of elon ated soluble anode elements movably mounted side by side on the inclined surface, each element being mounted on the inclined surface with its length dimension parallel to the path of the strip and being movable along the inclined surface laterally of the path of the strip in a direction toward the upper end of the inclined surface to compensate for erosion of the anode elements, one of the anode elements being adjacent the one side of the path of the strip and another anode element being adjacent the opposite side of the path of the strip, means for adjusting the lateral position of the one anode element on the one side of the path of the strip, a mask positioned at the upper end of the inclined surface adjacent the opposite side only of the path of the strip, the mask extending longitudinally of the path of the strip, means for mountin the mask in spaced relation between the path of the strip and the other anode element, the last-named means including a mask supporting member mounted for movement along. the inclined surface laterally of the ath of the strip, and means for mounting the mask on the mask supporting member including means for vertically adjusting the mask with respect topthe mask supporting member.
2. In an apparatus for progressively electroplating a surface of an elonagted metal strip, the combination comprising an electroplating cell including a tank adapted to contain a body of electroplating solution, roller means mounted at the end of the tank for moving the strip progressively along a path across the tank from end to end with the surface of the strip in contact with the electroplating solution, an anode supportin means located in the tank below the path of the strip and presentin an inclined surface facing the path of the strip, the inclined surface extending transversely across the tank and across the path of the strip with the lower end of the inclined surface at the one side of the path of the strip being farther away from the path of the strip than the upper end of the inclined surface at the opposite side of the path of the strip, an anode supported in the tank by the anode supporting means, the anode being below the path of the strip and spaced from the path of the strip, means for connecting the anode -to a source of electroplating current, the anode including a plurality of elongated soluble anode elements movably mounted side by side on the inclined surface, each element being mounted on the inclined surface with its length dimension parallel to the path of the strip and bein movable along the inclined surface laterally of the path of the strip in a direction toward the op osite side of the path of the strip to compensate for erosion of the anode elements, one of the anode elements being adjacent the one side of the path of the strip and another anode ele- 10 ment being adjacent the opposite side of the path of the strip, means for supporting the tank for movement transversely of the path of the strip for adjusting the lateral position of the one anode element on the one side of the path of the strip, a mask positioned at the upper end of the inclined surface adjacent the opposite side only of the path of the strip, the mask extending longitudinally of the path of the strip, and means for mounting the mask in spaced relation between the path of the strip and the other anode element, the last-named means including a mask supporting member mounted for movement along the inclined surface laterally of the path of the strip, and means for mounting the mask on the mask supporting member including means for vertically adjusting the mask with respect to the mask supporting member.
References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,086,226 Hoff July 6, 1937 2,399,254 Rieger et al Apr. 30, 1946 2,461,556 Lorig Feb. 15, 1949 OTHER REFERENCES Journal of the Electrodepositors Tech. Soc.,
vol. 19 (1943-44), pages to 48.

Claims (1)

1. IN AN APPARATUS FOR PROGRESSIVELY ELECTROPLATING A SURFACE OF AN ELONGATED METAL STRIP, THE COMBINATION COMPRISING AN ELECTROPLATING CELL INCLUDING A TANK ADAPTED TO CONTAIN A BODY OF ELECTROPLATING SOLUTION, ROLLER MEANS MOUNTED AT THE ENDS OF THE TANK FOR MOVING THE STRIP PROGRESSIVELY ALONG A PATH ACROSS THE TANK FROM END TO END WITH THE SURFACE OF THE STRIP IN CONTACT WITH THE ELECTROPLATING SOLUTION, AN ANODE SUPPORTING MEANS LOCATED IN THE TANK BELOW THE PATH OF THE STRIP AND PRESENTING AN INCLINED SURFACE FACING THE PATH OF THE STRIP, THE INCLINED SURFACE EXTENDING TRANSVERSELY ACROSS THE TANK AND ACROSS THE PATH OF THE STRIP WITH THE LOWER END OF THE INCLINED SURFACE AT ONE SIDE OF THE PATH OF THE STRIP BEING FARTHER AWAY FROM THE PATH OF THE STRIP THAN THE UPPER END OF THE INCLINED SURFACE AT THE OPPOSITE SIDE OF THE PATH OF THE STRIP, AN AND SUPPORTED IN THE TANK BY THE ANODE SUPPORTING MEANS, THE ANODE BEING BELOW THE PATH OF THE STRIP AND SPACED FROM THE PATH OF THE STRIP, MEANS CONNECTING THE ANODE TO A SOURCE OF ELECTROPLATING CURRENT, THE ANODE INCLUDING A PLURALITY OF ELONGATED SOLUBLE ANODE ELEMENTS MOVABLY MOUNTED SIDE BY SIDE ON THE INCLINED SURFACE, EACH ELEMENT BEING MOUNTED ON THE INCLINED SURFACE WITH ITS LENGTH DIMENSION PARALLEL TO THE PATH OF THE STRIP AND BEING MOVABLE ALONG THE INCLINED SURFACE LATERALLY OF THE PATH OF THE STRIP IN A DIRECTION TOWARD THE UPPER END OF THE INCLINED SURFACE TO COMPENSATE FOR EROSION OF THE ANODE ELEMENTS, ONE OF THE ANODE ELEMENTS BEING ADJACENT THE ONE SIDE OF THE PATH OF THE STRIP AND ANOTHER ANODE ELEMENT BEING ADJACENT THE OPPOSITE SIDE OF THE PATH OF THE STRIP, MEANS FOR ADJUSTING THE LATERAL POSITION OF THE ONE ANODE ELEMENT ON THE ONE SIDE OF THE PATH OF THE STRIP, A MASK POSITIONED AT THE UPPER END OF THE INCLINED SURFACE ADJACENT THE OPPOSITE SIDE ONLY OF THE PATH OF THE STRIP, THE MASK EXTENDING LONGITUDINALLY OF THE PATH OF THE STRIP, AND MEANS FOR MOUNTING THE MASK IN SPACED RELATION BETWEEN THE PATH OF THE STRIP AND THE OTHER ANODE ELEMENT, THE LAST-NAMED MEANS INCLUDING A MASK SUPPORTING MEMBER MOUNTED FOR MOVEMENT ALONG THE INCLINED SURFACE LATERALLY OF THE PATH OF THE STRIP, AND MEANS FOR MOUNTING THE MASK ON THE MASK SUPPORTING MEMBER INCLUDING MEANS FOR VERTICALLY ADJUSTING THE MASK WITH RESPECT TO THE MASK SUPPORTING MEMBER.
US196589A 1950-11-20 1950-11-20 Apparatus for reduction of heavy edge coating in electroplating Expired - Lifetime US2690424A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US196589A US2690424A (en) 1950-11-20 1950-11-20 Apparatus for reduction of heavy edge coating in electroplating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US196589A US2690424A (en) 1950-11-20 1950-11-20 Apparatus for reduction of heavy edge coating in electroplating

Publications (1)

Publication Number Publication Date
US2690424A true US2690424A (en) 1954-09-28

Family

ID=22726000

Family Applications (1)

Application Number Title Priority Date Filing Date
US196589A Expired - Lifetime US2690424A (en) 1950-11-20 1950-11-20 Apparatus for reduction of heavy edge coating in electroplating

Country Status (1)

Country Link
US (1) US2690424A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963760A (en) * 1957-09-30 1960-12-13 Samuel L Cohn Slide fastener and treatment thereof
US3445371A (en) * 1966-06-15 1969-05-20 Nat Steel Corp Anode structure for continuous strip electroplating
US3855083A (en) * 1973-06-13 1974-12-17 United States Steel Corp Method for the uniform electroplating of sheet and strip
US4183799A (en) * 1978-08-31 1980-01-15 Production Machinery Corporation Apparatus for plating a layer onto a metal strip
US20070227632A1 (en) * 2003-12-23 2007-10-04 Corus Staal Bv Metal Strip Electroplating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2086226A (en) * 1934-10-25 1937-07-06 Du Pont Plating apparatus
US2399254A (en) * 1943-05-20 1946-04-30 Nat Steel Corp Electroplating
US2461556A (en) * 1943-04-01 1949-02-15 Carnegie Illinois Steel Corp Method and apparatus for the electrolytic coating of metal strip

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2086226A (en) * 1934-10-25 1937-07-06 Du Pont Plating apparatus
US2461556A (en) * 1943-04-01 1949-02-15 Carnegie Illinois Steel Corp Method and apparatus for the electrolytic coating of metal strip
US2399254A (en) * 1943-05-20 1946-04-30 Nat Steel Corp Electroplating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963760A (en) * 1957-09-30 1960-12-13 Samuel L Cohn Slide fastener and treatment thereof
US3445371A (en) * 1966-06-15 1969-05-20 Nat Steel Corp Anode structure for continuous strip electroplating
US3855083A (en) * 1973-06-13 1974-12-17 United States Steel Corp Method for the uniform electroplating of sheet and strip
US4183799A (en) * 1978-08-31 1980-01-15 Production Machinery Corporation Apparatus for plating a layer onto a metal strip
US20070227632A1 (en) * 2003-12-23 2007-10-04 Corus Staal Bv Metal Strip Electroplating

Similar Documents

Publication Publication Date Title
DE102012012990B4 (en) Surface treatment system and workpiece support support
DE10153171B4 (en) Method and device for the electrolytic treatment of parts in continuous systems
US2544510A (en) Apparatus and method for plating strips
US6309517B1 (en) Apparatus for inline plating
US2554943A (en) Electroplating apparatus
EP1419290B1 (en) Segmented counterelectrode for an electrolytic treatment system
US2399254A (en) Electroplating
EP1573094B1 (en) Device and method for electrolytically treating an at least superficially electrically conducting work piece
EP1007766A2 (en) Device and method for evening out the thickness of metal layers on electrical contact points on items that are to be treated
US2690424A (en) Apparatus for reduction of heavy edge coating in electroplating
US4267024A (en) Electrolytic coating of strip on one side only
US2312452A (en) Method and apparatus for continuously electroplating metallic strip
US2382018A (en) Apparatus for electroplating
US6120671A (en) Method and apparatus for electrolytic pickling a metallic strip
US4505785A (en) Method for electroplating steel strip
US3445371A (en) Anode structure for continuous strip electroplating
JPS6348956B2 (en)
JP6367664B2 (en) Partial plating method and apparatus
US2742417A (en) Apparatus for electroplating
US2776939A (en) Anode and method of continuous plating
US3729390A (en) Electrotinning process to prevent plating on the cathode contact roll
KR102065220B1 (en) Electroplating apparatus with edge mask
US7449089B2 (en) Conveyorized plating line and method for electrolytically metal plating a workpiece
US4548685A (en) Process for electrolytically removing metal deposit from a non-plated surface of a single surface-plated metal strip
JPH06306695A (en) Equipment for continuously electropoplating metallic strip and method for controlling coating weight in width direction