US2655453A - Manifold sheet having a crushresistant transfer film - Google Patents
Manifold sheet having a crushresistant transfer film Download PDFInfo
- Publication number
- US2655453A US2655453A US283989A US28398952A US2655453A US 2655453 A US2655453 A US 2655453A US 283989 A US283989 A US 283989A US 28398952 A US28398952 A US 28398952A US 2655453 A US2655453 A US 2655453A
- Authority
- US
- United States
- Prior art keywords
- film
- sheet
- marking
- manifold
- crushresistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/025—Applications of microcapsules not provided for in other subclasses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/1243—Inert particulate additives, e.g. protective stilt materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31768—Natural source-type polyamide [e.g., casein, gelatin, etc.]
- Y10T428/31772—Next to cellulosic
- Y10T428/31775—Paper
Definitions
- This invention relates to a manifold sheet having a crush-resistant rupturable film containing printing fluid, and more particularly pertains to such in which minute particles of hard, solid. inert material are scattered in the film to prevent the crushing of it by broadly applied pressures encountered in storage or in ordinary handling as distinguished from the local- 1y applied pressures of printing or writing.
- manifold sheets in print ing or marking operations, they are commonly stacked in a pile or bound together in some manner which brings each film surface in contact with an under sheet on which a copy is to be made.
- the hard, solid particles are scattered evenlyand widely throughout the film so as to prevent the film from being crushed by the aforesaid broad- 1y applied sort of pressure which is encountered in such storage or handling.
- the drawing is a diagrammatic representation, on a large scale, of the record material of the invention.
- This invention is particularly useful in connection with the kind of manifold sheets which contain microscopic marking-fluid inclusions in a rupturable film, such as are disclosed in United States Patent No. 2,374,862, which issued on the application of Barrett K. Green, and United States Patent No. 2,548,366, which issued on the application of Barrett K. Green and this applicant, Robert W. Sandberg.
- Those patents disclose manifold paper having on one side thereof a film, derived from a hydrophilic colloid material, having dispersed therein fluid droplets or inclusions containing marking material, or fluid droplets of marking fluid itself.
- the present invention is to prevent such an occurrence by providing throughout such a film a dispersion of hard, rounded, bead-like particles of inert solid material of such average diameter, and spaced apart in the film, so that storage and handling pressures supplied to broad areas of the sheets of a stack, so made, will not smudge the underlying sheets, yet will not prevent transfer of printing fluid to underlying sheets by the relatively great printing or writing pressures locally applied.
- the relatively large pressure of 100 pounds or more per square inch encountered at points of printing pressure or on lines of scribing or at places of other marking pressure is sufficient to deform the sheet so the film will be ruptured between the hard inert particles.
- particles of an average diameter of one to three times the thickness of the film on a sheet used in a quantity equal to /2% to 10% of the volume of the film, but preferably from 2% to 5% thereof, will give the necessary spacing to insure generally applied pressures applied to film will not crush it and, yet will not interfere with printing or marking sensitivity of the sheet. For instance, falling within the ranges noted above, in a film. of .025
- marking dyes and ink materials may be men tioned glass beads, rounded white silica sand, casein particles and vinyl acetate polymer material particles.
- Each of these materials may be obtained in globular form or as well rounded beads or particles, such globularity or roundness being preferred so the film will have a smooth surface texture rather than a sandpaper surface texture.
- a sheet of paper .075 of a millimeter thick is coated so as to leave a dry film .025 of a millimeter thick with a coating made and applied in the following manner-one part, by weight, of animal gelatin, having an iso-electric point of pH 8 and a jelly strength of 275 grams as measured by the Bloom gelometer is mixed with three parts, by weight, of water heated to 150 degrees Fahrenheit.
- the solution of crystal violet lactone and the methane compound is made by dissolving one and one-half parts, by weight, of crystal violet lactone and one and one-half parts, by weight of the methane compound in 97 parts, by weight, of chlorinated diphenyl, which has a chlorine content averaging. 48% by weight.
- This solution is heated to the temperature of the gelatin solution before it is added thereto and emulsified.
- the emulsion with the glass beads therein is applied to the paper, while still hot, or if allowed to cool, after reheat ing to 150 degrees Fahrenheit and is dried either under normal atmospheric conditions or by artificial means such as a hot air blast or a drying drum such as is commonly used in paper coating machines.
- the coating is applied in such thickness that, upon drying, the gelatin film will be approximately .025 millimeter in thickness.
- the glass beads will be spaced about five diameters apart on the average and will protrude more or less from the surface of the film and act to prevent any substantial contact between it and an underlying sheet in a stack of such sheets, until printing or writing pressures are applied, whereupon the type or marking instrument, being of small dimensions with respect to its contact with the paper surface will distort the paper so that the gelatin film will be ruptured locally and the film-enclosed droplets of printing fluid will escape onto the underlying receiving sheet.
- Crystal violet lactone may be made by the process described in United States Letters Patent Re. 23,024, which is a re-issue of a patent which issued on the original application of Clyde S. Adams.
- the crystal violet lactone in the chlorinated diphenyl when applied to a paper sheet sensitized by being coated with exposed particles 1 4 of attapulgite clay, will turn to a dark blue color, as is disclosed in the aforesaid United States Patent 2,548,366, which issued on the application of Barrett K. Green and this applicant, Robert W. Sandberg.
- dye-stuffs such as analine dyes, oily pigmented inks, etc. may be used for the internal phase of the above emulsion to provide fiuid inclusions of ink instead of a colorless colorrea'ctant such as is provided by the use of crystal violet lactone.
- the type of marking fluid used in the film is not a critical factor in the invention and further examples of marking fluids or compounds will not be given here.
- Patent 2,374,362 which as before mentioned, issued on the application of Barrett K. Green, for manifold record material in which the film has inclusions of oily marking fluids containing such coloring or marking ingredients as carbon black and Sudan IV dye.
- the particle material may be sprinkled on the surface of a coating of the film-forming material while still wet whereby it may sink and be embedded or implanted by virtue of its weight.
- paper is the preferred and most widely used web material for use in making transfer or manifold sheets
- pliable films of nonfibrous cellulose derivatives and synthetic resins also may be used.
- the invention also is applicable to hot-melt types of manifolding transfer coating, such as ordinary wax carbon paper coatings by sprinkling the material over the surface of a coated sheet while the coating is in a melted condition.
- Record material including, in combination, a paper sheet; and a coating on the sheet including a film of hydrophilic colloid material rupturable by printing pressures and having dispersed therein a profusion of microscopic droplets of printing fluid and, also having dispersed in that part of the film not occupied by the droplets a plurality of beads of hard inert material having a diameter of from one to three times the thickness of the film and being spaced apart in the film a distance equal to about five times the average particle diameter, said particles constituting per cent. to 10 per cent. of the solids of the film by volume.
Description
Oct. 13, 1953 R. w. SANDBERG 2,655,453
MANIFOLD SHEET HAVING A CRUSH-RESISTANT TRANSFER FILM Filed April 23, 1952 HYDROPHILIG COLLOID FILM INVENTOR ROBERT W. SANDBERG HIS ATTORNEYS Patented Oct. 13, 1953 UNITED STATES PATENT OFFICE,
MANIFOLD SHEET HAVING A CRUSH- RESISTANT TRANSFER FILM Application April 23, 1952, Serial No. 283,989
1 Claim.
This invention relates to a manifold sheet having a crush-resistant rupturable film containing printing fluid, and more particularly pertains to such in which minute particles of hard, solid. inert material are scattered in the film to prevent the crushing of it by broadly applied pressures encountered in storage or in ordinary handling as distinguished from the local- 1y applied pressures of printing or writing. Be fore the use of such manifold sheets in print ing or marking operations, they are commonly stacked in a pile or bound together in some manner which brings each film surface in contact with an under sheet on which a copy is to be made. In the product of this invention the hard, solid particles are scattered evenlyand widely throughout the film so as to prevent the film from being crushed by the aforesaid broad- 1y applied sort of pressure which is encountered in such storage or handling.
The drawing is a diagrammatic representation, on a large scale, of the record material of the invention.
In the manifolding art it is customary to provide two or more base web sheets each having, at least on one surface of the sheet, a film of transferable marking material or a film containing transferable marking material, so that printing or other marking pressures will transfer the marking material to an underlying sheet. Such printing or marking pressures are ordinarily very great, amounting to 100 pounds or more per square inch where the type or marking instrument is applied. This contrasts with the much lower average pressure encountered in storage where a maximum of 20 pounds per square inch may be expected.
This invention is particularly useful in connection with the kind of manifold sheets which contain microscopic marking-fluid inclusions in a rupturable film, such as are disclosed in United States Patent No. 2,374,862, which issued on the application of Barrett K. Green, and United States Patent No. 2,548,366, which issued on the application of Barrett K. Green and this applicant, Robert W. Sandberg. Those patents disclose manifold paper having on one side thereof a film, derived from a hydrophilic colloid material, having dispersed therein fluid droplets or inclusions containing marking material, or fluid droplets of marking fluid itself. When such sheets are stored in a stack under pressure or otherwise are subjected to prolonged heavy pressure the film, being made of easily rupturable material such as gelatin, may break down and release part of the fluid. This will cause discoloration or smudging of the adjacent sheet in the stack. The present invention is to prevent such an occurrence by providing throughout such a film a dispersion of hard, rounded, bead-like particles of inert solid material of such average diameter, and spaced apart in the film, so that storage and handling pressures supplied to broad areas of the sheets of a stack, so made, will not smudge the underlying sheets, yet will not prevent transfer of printing fluid to underlying sheets by the relatively great printing or writing pressures locally applied. The relatively large pressure of 100 pounds or more per square inch encountered at points of printing pressure or on lines of scribing or at places of other marking pressure is sufficient to deform the sheet so the film will be ruptured between the hard inert particles.
It has been found that particles of an average diameter of one to three times the thickness of the film on a sheet, used in a quantity equal to /2% to 10% of the volume of the film, but preferably from 2% to 5% thereof, will give the necessary spacing to insure generally applied pressures applied to film will not crush it and, yet will not interfere with printing or marking sensitivity of the sheet. For instance, falling within the ranges noted above, in a film. of .025
of a millimeter thick, rounded, bead-like spacage, in the film.
Among the materials which are hard, solid, inert as to ordinary film-forming materials, marking dyes and ink materials, and which are preferred as crush-resistant fillers because of their whiteness or lack of color, may be men tioned glass beads, rounded white silica sand, casein particles and vinyl acetate polymer material particles. Each of these materials may be obtained in globular form or as well rounded beads or particles, such globularity or roundness being preferred so the film will have a smooth surface texture rather than a sandpaper surface texture.
Falling within the practical range, as to size, are particles which will pass a size 230 mesh United States standard sieve, and be retained on a size 325 mesh United States standard sieve. Smaller particles may be used, but they, preferably, should notbe less in diameter than the intended film thickness, although they may be 3 greater in diameter than the film thickness by a factor of 3.
As an example, in making such manifold material, a sheet of paper .075 of a millimeter thick is coated so as to leave a dry film .025 of a millimeter thick with a coating made and applied in the following manner-one part, by weight, of animal gelatin, having an iso-electric point of pH 8 and a jelly strength of 275 grams as measured by the Bloom gelometer is mixed with three parts, by weight, of water heated to 150 degrees Fahrenheit. Into four parts, by weight, of gelatin solution there is dispersed, or emulsified, three parts, by weight, of a colorless solution of crystal violet lactone, which is 3,3-bis(p-dimethylaminophenyl) -6-dimethylamino phthalide, mixed with an equal weight of bis(p-dimethylaminophenyl) methane.
The solution of crystal violet lactone and the methane compound is made by dissolving one and one-half parts, by weight, of crystal violet lactone and one and one-half parts, by weight of the methane compound in 97 parts, by weight, of chlorinated diphenyl, which has a chlorine content averaging. 48% by weight. This solution is heated to the temperature of the gelatin solution before it is added thereto and emulsified. To this emulsion, while still hot, is added threetenths part, by weight, of glass beads having an average particle size of about .044 millimeter, that is to say, those that will be retained on a 325 mesh .screen, specified above, but which will pass a size 230 sieve screen. The emulsion with the glass beads therein is applied to the paper, while still hot, or if allowed to cool, after reheat ing to 150 degrees Fahrenheit and is dried either under normal atmospheric conditions or by artificial means such as a hot air blast or a drying drum such as is commonly used in paper coating machines. The coating is applied in such thickness that, upon drying, the gelatin film will be approximately .025 millimeter in thickness. The glass beads will be spaced about five diameters apart on the average and will protrude more or less from the surface of the film and act to prevent any substantial contact between it and an underlying sheet in a stack of such sheets, until printing or writing pressures are applied, whereupon the type or marking instrument, being of small dimensions with respect to its contact with the paper surface will distort the paper so that the gelatin film will be ruptured locally and the film-enclosed droplets of printing fluid will escape onto the underlying receiving sheet.
Crystal violet lactone may be made by the process described in United States Letters Patent Re. 23,024, which is a re-issue of a patent which issued on the original application of Clyde S. Adams. The crystal violet lactone in the chlorinated diphenyl, when applied to a paper sheet sensitized by being coated with exposed particles 1 4 of attapulgite clay, will turn to a dark blue color, as is disclosed in the aforesaid United States Patent 2,548,366, which issued on the application of Barrett K. Green and this applicant, Robert W. Sandberg.
Other dye-stuffs, such as analine dyes, oily pigmented inks, etc. may be used for the internal phase of the above emulsion to provide fiuid inclusions of ink instead of a colorless colorrea'ctant such as is provided by the use of crystal violet lactone. The type of marking fluid used in the film is not a critical factor in the invention and further examples of marking fluids or compounds will not be given here. However, reference is again made to Patent 2,374,362, which as before mentioned, issued on the application of Barrett K. Green, for manifold record material in which the film has inclusions of oily marking fluids containing such coloring or marking ingredients as carbon black and Sudan IV dye.
Although not as efficient in evenly dispersing the particle material, as is the method of mixing it in with the solution of the film-forming material, the particle material may be sprinkled on the surface of a coating of the film-forming material while still wet whereby it may sink and be embedded or implanted by virtue of its weight.
Although paper is the preferred and most widely used web material for use in making transfer or manifold sheets, pliable films of nonfibrous cellulose derivatives and synthetic resins also may be used.
The invention also is applicable to hot-melt types of manifolding transfer coating, such as ordinary wax carbon paper coatings by sprinkling the material over the surface of a coated sheet while the coating is in a melted condition.
What is claimed is:
Record material including, in combination, a paper sheet; and a coating on the sheet including a film of hydrophilic colloid material rupturable by printing pressures and having dispersed therein a profusion of microscopic droplets of printing fluid and, also having dispersed in that part of the film not occupied by the droplets a plurality of beads of hard inert material having a diameter of from one to three times the thickness of the film and being spaced apart in the film a distance equal to about five times the average particle diameter, said particles constituting per cent. to 10 per cent. of the solids of the film by volume.
ROBERT W. SANDBERG.
References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,550,470 Green Apr. 24, 1951 2,555,319 Cross June 5, 1951
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US283989A US2655453A (en) | 1952-04-23 | 1952-04-23 | Manifold sheet having a crushresistant transfer film |
GB7179/53A GB732284A (en) | 1952-04-23 | 1953-03-16 | Transfer material |
DEN6999A DE945454C (en) | 1952-04-23 | 1953-04-05 | Recording material and process for its manufacture |
FR1076021D FR1076021A (en) | 1952-04-23 | 1953-04-21 | Material for inscriptions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US283989A US2655453A (en) | 1952-04-23 | 1952-04-23 | Manifold sheet having a crushresistant transfer film |
Publications (1)
Publication Number | Publication Date |
---|---|
US2655453A true US2655453A (en) | 1953-10-13 |
Family
ID=23088425
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US283989A Expired - Lifetime US2655453A (en) | 1952-04-23 | 1952-04-23 | Manifold sheet having a crushresistant transfer film |
Country Status (4)
Country | Link |
---|---|
US (1) | US2655453A (en) |
DE (1) | DE945454C (en) |
FR (1) | FR1076021A (en) |
GB (1) | GB732284A (en) |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2711375A (en) * | 1951-08-24 | 1955-06-21 | Ncr Co | Pressure sensitive manifold sheet |
US2961334A (en) * | 1957-06-04 | 1960-11-22 | Little Inc A | Positive printing, pressure-sensitive material and method of making it |
US3063864A (en) * | 1959-09-28 | 1962-11-13 | Ipswich Processes Inc | Material for receiving inscriptions and method of making |
US3260612A (en) * | 1961-07-14 | 1966-07-12 | Eastman Kodak Co | Thermographic recording process and heat-sensitive elements therefor |
US3389007A (en) * | 1962-07-20 | 1968-06-18 | Oda Ryohei | Record transfer sheet material, method of making and composition |
US3413168A (en) * | 1967-05-03 | 1968-11-26 | Minnesota Mining & Mfg | Adhesive bonding method permitting precise positioning |
US3539344A (en) * | 1967-05-31 | 1970-11-10 | Eastman Kodak Co | Photographic elements having protective bead coatings |
US3617334A (en) * | 1968-11-08 | 1971-11-02 | Ncr Co | Pressure-sensitive sheet material |
US3844816A (en) * | 1971-05-12 | 1974-10-29 | Plywood Champion Papers Inc | Grafted, polymeric microcapsular system |
US3852092A (en) * | 1972-06-05 | 1974-12-03 | J Patterson | Thermally responsive elastic membrane |
US3924767A (en) * | 1971-09-30 | 1975-12-09 | Dart Ind Inc | Plastic coated containers having embedded friction reducing particles |
US3955025A (en) * | 1973-10-02 | 1976-05-04 | Fuji Photo Film Co., Ltd. | Pressure-sensitive copying sheet |
US3955026A (en) * | 1973-10-02 | 1976-05-04 | Fuji Photo Film Co., Ltd. | Pressure-sensitive recording sheet |
US4056648A (en) * | 1975-06-16 | 1977-11-01 | Denbyware Limited | Transfers |
US4103053A (en) * | 1976-04-09 | 1978-07-25 | Myron Barehas | Pressure sensitive laminate and method of forming same |
US4150187A (en) * | 1975-09-02 | 1979-04-17 | Columbia Ribbon And Carbon Manufacturing Co., Inc. | Transfer elements and process |
JPS5468307A (en) * | 1977-11-11 | 1979-06-01 | Mitsubishi Paper Mills Ltd | Selffcoupling pressureesensitive recording paper |
EP0005024A1 (en) * | 1978-04-25 | 1979-10-31 | Appleton Papers Inc. | Sheet materials |
US4362566A (en) * | 1977-03-10 | 1982-12-07 | Rudolf Hinterwaldner | One-component hardenable substances stable to storage and activatable by mechanical and/or physical forces and method of producing, activating and applying same |
US4376151A (en) * | 1981-06-29 | 1983-03-08 | Moore Business Forms, Inc. | Pressure threshold adhesive |
US4541830A (en) * | 1982-11-11 | 1985-09-17 | Matsushita Electric Industrial Co., Ltd. | Dye transfer sheets for heat-sensitive recording |
US4657541A (en) * | 1984-06-07 | 1987-04-14 | Terumo Kabushiki Kaisha | Medical instrument |
US5002924A (en) * | 1989-10-05 | 1991-03-26 | The Standard Register Company | Carbonless copy paper coating containing microencapsulated load bearers |
US6423379B1 (en) | 1993-06-09 | 2002-07-23 | Charles Ewing | Method of making an artistic medium |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1232347A (en) * | 1968-03-28 | 1971-05-19 | ||
DE2743800C3 (en) * | 1977-09-29 | 1980-04-03 | Feldmuehle Ag, 4000 Duesseldorf | Pressure-sensitive recording material and coating slip for its production |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2550470A (en) * | 1948-07-13 | 1951-04-24 | Ncr Co | Pressure sensitive record material |
US2555319A (en) * | 1943-04-19 | 1951-06-05 | Minnesota Mining & Mfg | Bead coated tympan sheet |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE640311C (en) * | 1934-07-26 | 1936-12-30 | Erwin O Haberfeld | Carbonless paper |
GB428010A (en) * | 1934-08-18 | 1935-05-03 | Autographic Register Co | Improvements in or relating to transfer devices and method of preparing same |
-
1952
- 1952-04-23 US US283989A patent/US2655453A/en not_active Expired - Lifetime
-
1953
- 1953-03-16 GB GB7179/53A patent/GB732284A/en not_active Expired
- 1953-04-05 DE DEN6999A patent/DE945454C/en not_active Expired
- 1953-04-21 FR FR1076021D patent/FR1076021A/en not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2555319A (en) * | 1943-04-19 | 1951-06-05 | Minnesota Mining & Mfg | Bead coated tympan sheet |
US2550470A (en) * | 1948-07-13 | 1951-04-24 | Ncr Co | Pressure sensitive record material |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2711375A (en) * | 1951-08-24 | 1955-06-21 | Ncr Co | Pressure sensitive manifold sheet |
US2961334A (en) * | 1957-06-04 | 1960-11-22 | Little Inc A | Positive printing, pressure-sensitive material and method of making it |
US3063864A (en) * | 1959-09-28 | 1962-11-13 | Ipswich Processes Inc | Material for receiving inscriptions and method of making |
US3260612A (en) * | 1961-07-14 | 1966-07-12 | Eastman Kodak Co | Thermographic recording process and heat-sensitive elements therefor |
US3389007A (en) * | 1962-07-20 | 1968-06-18 | Oda Ryohei | Record transfer sheet material, method of making and composition |
US3413168A (en) * | 1967-05-03 | 1968-11-26 | Minnesota Mining & Mfg | Adhesive bonding method permitting precise positioning |
US3539344A (en) * | 1967-05-31 | 1970-11-10 | Eastman Kodak Co | Photographic elements having protective bead coatings |
US3617334A (en) * | 1968-11-08 | 1971-11-02 | Ncr Co | Pressure-sensitive sheet material |
US3844816A (en) * | 1971-05-12 | 1974-10-29 | Plywood Champion Papers Inc | Grafted, polymeric microcapsular system |
US3924767A (en) * | 1971-09-30 | 1975-12-09 | Dart Ind Inc | Plastic coated containers having embedded friction reducing particles |
US3852092A (en) * | 1972-06-05 | 1974-12-03 | J Patterson | Thermally responsive elastic membrane |
US3955026A (en) * | 1973-10-02 | 1976-05-04 | Fuji Photo Film Co., Ltd. | Pressure-sensitive recording sheet |
US3955025A (en) * | 1973-10-02 | 1976-05-04 | Fuji Photo Film Co., Ltd. | Pressure-sensitive copying sheet |
US4056648A (en) * | 1975-06-16 | 1977-11-01 | Denbyware Limited | Transfers |
US4150187A (en) * | 1975-09-02 | 1979-04-17 | Columbia Ribbon And Carbon Manufacturing Co., Inc. | Transfer elements and process |
US4103053A (en) * | 1976-04-09 | 1978-07-25 | Myron Barehas | Pressure sensitive laminate and method of forming same |
US4362566A (en) * | 1977-03-10 | 1982-12-07 | Rudolf Hinterwaldner | One-component hardenable substances stable to storage and activatable by mechanical and/or physical forces and method of producing, activating and applying same |
JPS5468307A (en) * | 1977-11-11 | 1979-06-01 | Mitsubishi Paper Mills Ltd | Selffcoupling pressureesensitive recording paper |
JPS5847998B2 (en) * | 1977-11-11 | 1983-10-26 | 三菱製紙株式会社 | Self-coloring pressure-sensitive recording paper |
EP0005024A1 (en) * | 1978-04-25 | 1979-10-31 | Appleton Papers Inc. | Sheet materials |
US4376151A (en) * | 1981-06-29 | 1983-03-08 | Moore Business Forms, Inc. | Pressure threshold adhesive |
US4541830A (en) * | 1982-11-11 | 1985-09-17 | Matsushita Electric Industrial Co., Ltd. | Dye transfer sheets for heat-sensitive recording |
US4657541A (en) * | 1984-06-07 | 1987-04-14 | Terumo Kabushiki Kaisha | Medical instrument |
US5002924A (en) * | 1989-10-05 | 1991-03-26 | The Standard Register Company | Carbonless copy paper coating containing microencapsulated load bearers |
US6423379B1 (en) | 1993-06-09 | 2002-07-23 | Charles Ewing | Method of making an artistic medium |
Also Published As
Publication number | Publication date |
---|---|
FR1076021A (en) | 1954-10-21 |
GB732284A (en) | 1955-06-22 |
DE945454C (en) | 1956-07-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2655453A (en) | Manifold sheet having a crushresistant transfer film | |
US4010038A (en) | Process for producing microcapsules | |
US3020171A (en) | Pressure-sensitive record and transfer sheet material | |
US4230743A (en) | Process for producing pressure-sensitive copying paper | |
US5698296A (en) | Business document having security features | |
US3516845A (en) | Record sheet sensitized with salt modified kaolin-phenolic material | |
US3738857A (en) | Pressure-sensitive record sheet and method of making | |
US3625736A (en) | Pressure-sensitive copying unit containing granular resinous material and method of making | |
US3955026A (en) | Pressure-sensitive recording sheet | |
US4046404A (en) | Carbonless paper for use in electrostatographic copiers | |
JPH06183139A (en) | Pressure sensitive recording material | |
DE2919521C2 (en) | Recording material for use in a pressure-sensitive copier system | |
SE427917B (en) | SIGNATURE RECEIVING SHEET INTENDED TO BE USED IN PRINTING COPYING SYSTEMS | |
DE2513526A1 (en) | METHOD OF PRESSURE MEASUREMENT | |
US4070508A (en) | Recording method comprising reacting cellulose fiber with a basic color former | |
US3914470A (en) | Capsule-carrying sheets or webs | |
US4226442A (en) | Water insensitive image receptor coating | |
DE60103135T2 (en) | TWO-WAY SELF-TAGING PAPER CONTAINING HOLLOW MICROBALLS | |
JP2535383B2 (en) | Tamper-proof pressure sensitive copy sheet | |
US3617410A (en) | Pressure-sensitive recording sheet and method of making | |
US4460199A (en) | Microcapsule coated sheet for pressure sensitive copying paper | |
CA1309251C (en) | Self-contained pressure-sensitive carbonless recording sheet having anti-scuff protective overcoating | |
JPS6097886A (en) | Pressure-sensitive recording sheet | |
JPH03247484A (en) | Stilt material and pressure sensitive layer therewith | |
JPS6257518B2 (en) |