US2484014A - Production of artificial fibers - Google Patents
Production of artificial fibers Download PDFInfo
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- US2484014A US2484014A US724138A US72413847A US2484014A US 2484014 A US2484014 A US 2484014A US 724138 A US724138 A US 724138A US 72413847 A US72413847 A US 72413847A US 2484014 A US2484014 A US 2484014A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
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- Cellulose as shown by Meyer (Brochemlsche Zeitschrift, 214,253-281, 1929) is a linear superpolymer, 1. e., a superpolymer in which the crystalline regions or micelles comprising molecular chains or bundles of molecular chains show a high degree of orientation along fiber axis. Although in viscose, the crystallites or micelles are randomly dispersed and oriented in all directions or agglomerated into small gellike masses, they tend to reorient themselves in the direction of the fiber axis during spinning.
- the physical strength of fibers of regenerated cellulose depends upon the ratio of crsytalline portions to amorphous portions, homogeneity at all portions of the fibers, and the degree to which the crystalline portions are reoriented with respect to the fiber axis. It is known that stretching-of freshly spun fibers comprising partially regenerated cel-, lulose improves the crystallinity and orientation of the crystallites along the fiber axis, with improvement in the tenacity of the fibers.
- regenerated cellulose fibers obtained by conventional procedures are not homogeneous and do not show maximum uniform crystallite orientation consistent with good extensibility, even after being subjected to strong stretching while in the gel state in which they are initially obtained.
- the fibres are manufactured by extruding viscose through a spinneret into an acid coagulating and regenerating bath, and continuously withdrawing the fibers formed by the action of the bath away .from the spinneret face and to the exterior ofthe bath for eventual after-treatment and purification.
- the fibers undergo a series of changes due to various chemical processes such asdehydration, dexanthation of the cellulose xanthate, etc., which proceed more or less simultaneously.
- the fibers are withdrawn from the bath in the form of a gel comprising partially regenerated cellulose, dependence being placed upon diffusion of the acid carried from the bath through the skin initially set up on the fibers in the bath about a still fluid core to efiect complete regeneration of the cellulose at all portions of the fiber crosssection.
- the rate of diffusion of the adhering acid to the interior of the fiber, and the uniformity of such diffusion controls the rate at which the xanthate groups are split off and the uniformity of the dexanthation at any given moment, which in turn controls the speed with which the fibers are finally set up, with formation of hydroxyl-to-hydroxyl bonds between the cellulose molecules.
- the speed with which the hydroxyl-to-hydroxyl bonds are formed effects the degree to which the molecules are reoriented with respect to the fiber axis, since, obviously, when such bonds have been formed, the crystallites are less free to undergo molecular rotations and align themselves along the fiber 'axis.
- One-object of the present invention is to pro vide a method of manufacturing artificial fibers which exhibit a high degree of micellar orientation with respect to the fiber axis. Another object is to provide a method of manufacturing regenerated cellulose fibers from viscose characterized by maximum uniform tenacity consistent with sufilcient extensibility to render the fibers suitable for commercial purposes. A further object is to provide a method of manufacturing regenerated cellulose fibers from viscose which permits a greater measure of control over the changes which take place in the freshly formed fibers, before they are finally set up, to yield more homogeneous and uniform fibers, and the delivery of the fibres in the more homogeneous condition to the after-treatment stages.
- the pulsations may be ofvarying duration, andthe pulses may beof varying width.- For example,
- the oscillations may have a frequency of, say, 500 kc. and the periods of operation and non-operation of the oscillator may 5 be of 0.001 second duration each, to produce, dur-. ing each second, 500 pulses consisting of 500 vibrations, or 250,000 cycles, each .pulse having awidth'of 0.001 second.
- the difluslon rate is accelerated as compared to the rate at which it proceeds normally, it is uniform at all portions of the fiber, and under the conditions of the invention, by appropriate choice of the frequency and magnitude of the waves, the duration of exposure of the fibers to the pulsating field and the stage in the manufacture at which the sound wave radiations are applied, the rate of dexanthation may be controlled to the extent'that the fibers are stretched while the cellulose is only partially dexanthated under which conditions optimum orientation of the crystallites is realized.
- the fibers may be given a predetermined after-stretch, as measured, for
- the cellulose by differential in godet speeds, and acceleration or dexanthation may be so controlled that, during the after-stretching step, the cellulose is only partially dexanthated, the dexantha- 'tion being completed, however, soon after the "fibers leave the after-stretching zone, and the regeneration of the cellulose, or only a shortened pressional wave beam produced by the 'transducer.
- the concave face of the converging lens may be either cylindrical or spherical depending on whether it is desired to focus the waves along lines or at points.
- the lens may be formed of that the wave trains are returned and reinforce each other back through the lines or points of focus of the waves, whereby the intensity of the sound wave vibrations to which the fibers are exposed as they pass through the focal point or along the lines of focus of the beam, is increased.
- the reflector may be made of any suitable metal, for example stainless steel.
- the sound waves may be applied either directly or indirectly to the fibers, threads, or yarns, at all stages in their manufacture, from the time of their formation to just prior to subjecting them to the usual after-treatingprocesses, or at any one or more of such stages. Further, it is within the scope of this invention to subject the fibers, while they are in the form of a gel comprising partially regenerated cellulose, simultaneously or successively to the action of a pulsating field of sound waves having different frequencies within the range stated and of different magnitudes.
- the fibers may be subjected to the action of the pulsating sound waves concurrently with their formation in the spinning bath, as they proceed through the bath, before, during, or after subjecting them to after-stretching, after collection in the form of a wound package or other thread mass and during storage of the mass to permit complete regeneration of the cellulose by the adhering spinning bath, as they proceed to a thread storage, thread-advancing reel, which may also be a stretching reel, or as they are advanced over such a reel.
- the waves may be applied in any direction. with respect to the direction of travel of the thread, as for instance in a direction parallel to the direction of travel, or transversely thereof.
- the sound waves are applied to the fibers in a direction at right angles to the direction of travel of the fibers.
- the freshly spun fibers may be passed through the pulsating high frequency sound wave field prior to final setting up thereof, set up, with or without after-stretching thereof, and, at a subsequent stage, brought to unplasticized condition and after-stretched, if desired.
- the transducer may be of the piezo-electric crystal, magnetostrictive, or electromagnetic type.
- Fig. 1 is an elevation, partly in section, of apparatus suitable for carrying out one modification of the invention
- Fig. 2 is an elevation, partly in section, of apparatus suitable for carrying out another modicells, each constituting an individual unit of the spinning machine, one cell being shown;
- Fig. is a perspective view of a difi'erent embodiment of the invention.
- viscose is extruded through spinneret 2, positioned in vessel 3 containing the spinning bath 4, the spinneret being arranged to spin generally vertically upwardly to the godets 5 and 6, which are driven (by means not shown) at different peripheral speeds for imparting a predetermined stretch to the fibers.
- a pulsed generator I (which may be of conventional type) is supported above the level of the bath, in a bracket 8, secured to the side of the spinning machine, and associated with the generator is a transmission tube 9, which may itself be a transducer of the type aforesaid, or provide a support for the transducer.
- the tube is provided with a slot or groove in through which the thread travels to the godets, the tube thus serving not only to transmit the pulsating high frequency sound vibrations to the threads or fibers, but also as a guide for controlling the thread as it proceeds to the lowermost godet, and for remov-- ing excess coagulating liquid from the thread.
- the thread is passed around godet 5, over a guide 5a, and thence over godet 6.
- the fibers, threads or yarns leaving the spinning bath are thus subjected to the pulsating high frequency sound wavesas they enter the stretching zone.
- Figure 3 illustrates an embodiment of the invention in accordance with which the fibers or yarns are subjected to the pulsating compressional waves simultaneously with stretching thereof. As shown, there is provided a trough. I2
- Compartment I4 is supplied with a plasticizing liquid for the fibers, for instance, hot water or hot dilute acid, through pipe I6.
- the liquid discharges through pipe II from the overflow chamber formed adjacent one end of compartment It by the overflow I8.
- Compartment It contains a body of oil in which is supported a transducer II of the piezo-electric crystal type, the crystal being energized by a pulsed generator 20 supported below the trough.
- a reflector 23 is supported in compartment I4 below the level of the bath, and the crystal, spherical lens. and reflector are spaced away from each other at relative distances such that the system is tuned in resonance.
- the beam of compressional waves travelling from the crystal is directed by the lens 22 and converged to a focal point 24, as shown in dotted lines.
- the rays passing through the focal point impinge uponthe spherical reflector 23 and are turned back by the reflector to their point of convergence, so that the wave energies are concentrated at the point of focus 24.
- the fibers are passed into the liquid in compartment I4 over the guide roll I I, wrapped one or more times around the driven roller Ila, immersed in the liquid, and then around the driven roller I2a and are withdrawn from the bath over the guide roll I2.
- Rollers Ila and I'2 a are driven at different peripheral speeds to impart a predetermined stretch to the fibers passing therebetween.
- the fibers travelling from roll Ila to roll I2a pass through the focal point 24 and are thus simultaneously stretched and exposed to the action of the concentrated pulsated sound waves. It will be readily understood that one or both of rolls Na and i211 may be replaced by threadadvancing reels.
- FIG. 4 which is illustrative of an arrangement for subjecting the fibers to the effects of pulsed high frequency sound waves concurrently with their formation, there is shown one unit of a spinning machine comprising a spinning tank oriother similar container for the spinning bath which, it will be understood, is divided into a plurality of compartments or troughs separated by partitions and each accommodating a single spinneret and provided with suitable means for introducing fresh spinning bath into each trough and removing the spent liquid, each compartment or'cell being provided with at least one associated compressional wave producing and directing system comprising a sound producer, a compressional wave lens, and a compressional wave reflector.
- each spinning cell is divided into two chambers 25 and 26 by electric crystal type, the crystal being adapted to translate high frequency electric oscillations produced by a generator 32 into compressional waves as will be understood.
- a spherical compressional wave reflector 33 is supported in chamber 25 by means of a bracket 25a.
- the beam of high frequency compressional waves is directed by lens 28 to a focal point .31.
- the focal point may be immediately adjacent the face of the spinneret or at a distance removed therefrom, or the spinneret may be positioned in the point of focus of the concentrated pulsating sound waves.
- the rays, passing through the focal point are returned, by the reflector 33, as they impinge thereon, and concentrated at the focal point 34, through which the freshly formed fibers pass as they are drawn through the spinning bath.
- more than one compressional wave producing and directing system each comprising a transducer, a compressional wave lens, and a compressional wave reflector may be provided at spaced points along the length of the cell, so that the freshly formed fibers are drawn through more than one point of focus. of the concentrated pulsating high frequency sound waves as they are drawn through the bath.
- Fig. 5 differs from thatshown in Fig. 4, in that the pianoconcave compressional wave lens 28 has a concave face of cylindrical shape and itself constitutes the liquid-tight partition between compartments 25 and 26 of the spinning cell.
- the reflector 33 is also cylindrical.
- the compressional wave beam is focused and concentrated along a line in the path of travel of the fibers or threads through the spinning bath.
- more than one compressional wave directing and concentrating system comprising a transducer, 9.
- cylindrical compressional wave lens, and a cylindrical compressional wave reflector may be provided, to provide a plurality of lines of focus and concentration of the sound waves.
- the invention is not limited to the manufacture of fibers of regenerated cellulose from viscose, or to the manufacture of fibers from fiberforming solutions by wet spinning methods, but may be practiced in the manufacture of fibers of different chemical constitution from various fiber-forming materials.
- fibers of regenerated proteins may be subjected to pulsating high frequency sound waves while they are in the plastic condition in which they are initially obtained, to assist in the agglomeration of polypeptide chains into parallel bundles, as occurs in the manufacture of fibers from solutions of casein, for example.
- the invention is also of advantage in the manufacture of fibers from solutions of cellulose esters, such as cellulose acetate, by either the dry or wet spinning methods.
- Cellulose acetate fibers obtained by spinning the solution of the ester into an evaporative atmosphere, such as heated air or other fluid medium, and while still in the plastic condition in which they are obtained initially, or such fibers obtained by spinning the solution into a setting bath which may comprise, for instance, an aqueous salt solution, hydrocarbons, or oils, etc. may be subjected to the pulsating high frequency sound waves, for the obtention of fibers having enhanced tenacity by virtue of improved micellar orientation.
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at some time between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path and through a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second, said beam of waves being focused in a definite predetermined direction to a single point .on the path of the fibers.
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at some time between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path and through a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second, said beam of waves being focused in a predetermined definite direction to a line on the path of the fibers.
- Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, and drawing the fibers thus formed through the setting bath, the beam of sound waves being focused in a definite predetermined direction on the path of the fibers through the bath so that the sound wave rays pass transversely through the fibers.
- Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, and drawing the fibers thus formedthrough the setting bath, the beam of sound waves being focused in a definite predetermined direction to a single point on the path of the fibers through the bath so that the rays of the sound wave beam pass transversely through the fibers.
- viscose which comprises extruding the vbcose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose; and drawing the fibers thus formed through the setting bath, the beam of sound waves being focused in a definite predetermined direction to a line on the path of the fibers through the bath so that the rays of the sound wave beam pass transversely through the fibers.
- Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, ad- Jacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction on the path of the fibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly. through the same point on the path of the fibers and perpendicularly through the fibers.
- Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, adjacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction on a single point on the path of the fibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly through said point on the path of the fibers and transversely through the fibers.
- Method of manufacturing artificial fibers from viscose which comprises extruding the viscose throu h a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, adjacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction in a line on the path of thefibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly through the same point in the line on the path of the fibers and perpendicularly through the fibers.
- a machine for manufacturing artificial fibers comprising, in combination, a vessel containing a setting medium for a fiber-forming material, means for extruding a fiber-forming material into the setting medium, means for drawing the fibers formed in the setting medium through the medium in a predetermined path, means for producing a pulsating beam of sound .waves having a frequency of at-least 1000 cycles per second in the setting medium, and a compressional wave lens disposed between the means for producing the beam of sound waves and the fibers, for focusing the beam of sound waves ina definite, predetermined direction on the path of the fibers 14.
- a machine for manufacturing a ificiai fibers comprising in combination a vessel contalning a setting medium fora fibereforming material, means for extruding a fiber -forming material into the setting medium, means for drawing the fibers formed in the setting medium 10 through the medium in a predetermined path, means for producing a beam of sound waves having a frequency of at least 1000 cycles per second in the setting medium, and a piano-concave compressional lens the curved face of which is a spherical surface disposed between the means for producing the beam of sound waves and the fibers, for focusing the beam of sound waves in'a definite predetermined direction to a single point on the path of the fibers through the setting medium.
- a machine for manufacturing artificial fibers comprising in combination a vessel containing a setting medium for a fiber-forming material, means for extruding a fiber-forming material into the setting medium, means for drawin the fibers formed in the setting medium through the medium in a predetermined path, means for producing a beam of sound waves having a frequency of at least 1000 cycles per second in the setting medium, and a piano-concave compressional lens the curved face of which is a cylindrical surface disposed between the means for producing the beam of sound waves and the fibers for focusing the beam of sound waves in a definite predetermined direction to a line on the path of the fibers through the setting medium.
- a machine for manufacturing artificial fibers which comprises in combination a container, a plano-concave compressional wave lens extending longitudinally of the container and separating the container into two liquid-tight compartments, a setting medium for a fiberforming material in one of the compartments, a body of oil in the other of the compartments, a piezo-electric crystal supported in the body of oil, means for energizing the crystal to produce a beam of pulsating high frequency sound waves.
- a compressional wave reflector tuned in resonance with the lens and crystal and supported in the setting medium, means supported in the setting medium for extruding a fiber-forming material into the medium, and means for drawing the fibers formed in the medium in a predetermined path through the medium between the lens and reflector and in a direction at a right angle to the beam of sound waves produced by the crystal, and through the site of focus of the focused and reflected sound waves.
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at sometime between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path, and through a beam of pulsating sound waves having a frequency of 250,000 cycles per second, each pulse having a width of 0.001 second, said beam being focused and reflected back in a definite predetermined direction to a focal site on the path of the fibers.
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,'
- a method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,
Description
1949- L.-E. PETERSON AL 2,484,014
PRODUCTION OF ARTIFICIAL FIBERS Filed Jan. 24, 1947 INVENTORS. LEROY ER/C PETERSON J/DNEY, LEONARD DART Patented Oct. 11, 1949 PRODUCTION OF ARTIFICIAL FIBERS Leroy Eric Peterson and Sidney Leonard Dart,
Chester, Pa., assignors to American Viscose Corporation, Wilmington, DeL, a corporation oi Delaware Application January 24, 1947, Serial No. 724,138
20 Claims. (Cl. 18-64) This invention relates to improvements in the manufacture of artificial fibers from solutions of fiber-forming materials.
While the invention may be practiced with advantage in connection with the manufacture of articial fibers from solutions of fiber-forming materials of various types, it will be described in detail in connection with the manufacture of regenerated cellulose fibers from viscose by the wet spinning method, byway of specific exemplification. 1
Cellulose, as shown by Meyer (Brochemlsche Zeitschrift, 214,253-281, 1929) is a linear superpolymer, 1. e., a superpolymer in which the crystalline regions or micelles comprising molecular chains or bundles of molecular chains show a high degree of orientation along fiber axis. Although in viscose, the crystallites or micelles are randomly dispersed and oriented in all directions or agglomerated into small gellike masses, they tend to reorient themselves in the direction of the fiber axis during spinning. According to modern concepts, the physical strength of fibers of regenerated cellulose depends upon the ratio of crsytalline portions to amorphous portions, homogeneity at all portions of the fibers, and the degree to which the crystalline portions are reoriented with respect to the fiber axis. It is known that stretching-of freshly spun fibers comprising partially regenerated cel-, lulose improves the crystallinity and orientation of the crystallites along the fiber axis, with improvement in the tenacity of the fibers. However, regenerated cellulose fibers obtained by conventional procedures are not homogeneous and do not show maximum uniform crystallite orientation consistent with good extensibility, even after being subjected to strong stretching while in the gel state in which they are initially obtained.
In accordance with conventional procedures, the fibres are manufactured by extruding viscose through a spinneret into an acid coagulating and regenerating bath, and continuously withdrawing the fibers formed by the action of the bath away .from the spinneret face and to the exterior ofthe bath for eventual after-treatment and purification.
During the spinning operation and concomitantly with conversion of the freshly formed highly plastic or gel-like fibers to the form in which they are finally set up, the fibers undergo a series of changes due to various chemical processes such asdehydration, dexanthation of the cellulose xanthate, etc., which proceed more or less simultaneously. While the fibers are undergoing such changes, and the molecules are more or less in a state of flux, a number of factors arise which interfere with the freedom of the crystallites to satisfy their natural tendency to reorient themselves in the direction of the fiber axis, as for instance, the stresses and strains which tend to develop in the molecular structure during the spinning operation, the difficulty of controlling the rate at which dexanthation proceeds at all portions of the fiber cross-section, and at all points along the fiber length, with regeneration of the cellulose, and doubtless other factors, as well.
Under usual manufacturing conditions, the fibers are withdrawn from the bath in the form of a gel comprising partially regenerated cellulose, dependence being placed upon diffusion of the acid carried from the bath through the skin initially set up on the fibers in the bath about a still fluid core to efiect complete regeneration of the cellulose at all portions of the fiber crosssection. The rate of diffusion of the adhering acid to the interior of the fiber, and the uniformity of such diffusion controls the rate at which the xanthate groups are split off and the uniformity of the dexanthation at any given moment, which in turn controls the speed with which the fibers are finally set up, with formation of hydroxyl-to-hydroxyl bonds between the cellulose molecules. Apparently, the speed with which the hydroxyl-to-hydroxyl bonds are formed effects the degree to which the molecules are reoriented with respect to the fiber axis, since, obviously, when such bonds have been formed, the crystallites are less free to undergo molecular rotations and align themselves along the fiber 'axis.
period, than occurs at other portions, which ap l.
parently is one factor leading to lack of homogeneity in the final fibers and their failure to show the maximum uniform crystallinity and crystallite orientation consistent with goodextensibility, which theoretically should be effected by the stretching to which the fibers are subjected during their production.
One-object of the present invention is to pro vide a method of manufacturing artificial fibers which exhibit a high degree of micellar orientation with respect to the fiber axis. Another object is to provide a method of manufacturing regenerated cellulose fibers from viscose characterized by maximum uniform tenacity consistent with sufilcient extensibility to render the fibers suitable for commercial purposes. A further object is to provide a method of manufacturing regenerated cellulose fibers from viscose which permits a greater measure of control over the changes which take place in the freshly formed fibers, before they are finally set up, to yield more homogeneous and uniform fibers, and the delivery of the fibres in the more homogeneous condition to the after-treatment stages.
In accordance with the present invention, freshly formed artificial fibers are passed, at any time prior to final setting up thereof, that is,
while they are in the highly plastic condition in which they are obtained initially and before final setting of the molecular structure, in the sound waves having a frequency in the range of about 1000 to.several billion'-'cycl"es-.lper'second,
herein called high frequency sound waves. The pulsations may be ofvarying duration, andthe pulses may beof varying width.- For example,
when the transducer employed for transmitting the sound. waves 1.to the fibers, iswenergized through a pulsed oscillator, in accordance with this invention, the oscillations may have a frequency of, say, 500 kc. and the periods of operation and non-operation of the oscillator may 5 be of 0.001 second duration each, to produce, dur-. ing each second, 500 pulses consisting of 500 vibrations, or 250,000 cycles, each .pulse having awidth'of 0.001 second.
. I 'fthe preferred embodiment-of the invention the fibers. .are exposed to the pulsating sound waves in a liquid medium which maybe the spinning bath. or a 'stretching bath or cascade, and
'a' converging compressionalwave-lens ofplanoconcave type is disposed in the path of the com-- spinning bath or soon after their withdrawal from the bath and while they are in the acidmoist condition, it is possible to control the rate of diffusion of the acid through the fibers so that it is uniform at all portions of the fiber, with consequent uniform control of the rate at which dexanthation and regeneration of the cellulose proceeds to completion, thus insuring that. before final setting up of the fibers, the crystaliites are uniformly free to align themselves in the direction of the fiber axis. The high frequency sound wave radiations have the effect of accelerating the rate of diflusion of the bath to the interior of the fibers. However, although the difluslon rate is accelerated as compared to the rate at which it proceeds normally, it is uniform at all portions of the fiber, and under the conditions of the invention, by appropriate choice of the frequency and magnitude of the waves, the duration of exposure of the fibers to the pulsating field and the stage in the manufacture at which the sound wave radiations are applied, the rate of dexanthation may be controlled to the extent'that the fibers are stretched while the cellulose is only partially dexanthated under which conditions optimum orientation of the crystallites is realized. In addition to the jet stretch to which the fibers are subjected incidental to withdrawal thereof from the spinning bath, the fibers may be given a predetermined after-stretch, as measured, for
- example, by differential in godet speeds, and acceleration or dexanthation may be so controlled that, during the after-stretching step, the cellulose is only partially dexanthated, the dexantha- 'tion being completed, however, soon after the "fibers leave the after-stretching zone, and the regeneration of the cellulose, or only a shortened pressional wave beam produced by the 'transducer. The concave face of the converging lens may be either cylindrical or spherical depending on whether it is desired to focus the waves along lines or at points. The lens may be formed of that the wave trains are returned and reinforce each other back through the lines or points of focus of the waves, whereby the intensity of the sound wave vibrations to which the fibers are exposed as they pass through the focal point or along the lines of focus of the beam, is increased. The reflector may be made of any suitable metal, for example stainless steel.
By subjecting the freshly formed highly plastic or gel-like fibers to the pulsating high frequency sound waves, it is possible to exercise control over the various processes which take place prior to final setting up of the fibers, and to radically influence the molecular structure of the final fibers, with material improvement in their physi cal properties. Thus, under the influence of the extremely rapidly alternating waves of compression and rarefaction to which fibers comprising partially regenerated cellulose are subjected,
storage period for that purpose. By uniformly controlling the rate of diffusion of the acid to all-'portions'of the fiber cross-section, and the rapidity with which the fibers are finally set up, it is possible to control the degree of reorientation of the crystallites with respect to the fiber axis within the limits in which maximum uniform increase in the tenacity of the fibers is obtained without embrittlement of the fibers.
The sound waves may be applied either directly or indirectly to the fibers, threads, or yarns, at all stages in their manufacture, from the time of their formation to just prior to subjecting them to the usual after-treatingprocesses, or at any one or more of such stages. Further, it is within the scope of this invention to subject the fibers, while they are in the form of a gel comprising partially regenerated cellulose, simultaneously or successively to the action of a pulsating field of sound waves having different frequencies within the range stated and of different magnitudes.
The fibers may be subjected to the action of the pulsating sound waves concurrently with their formation in the spinning bath, as they proceed through the bath, before, during, or after subjecting them to after-stretching, after collection in the form of a wound package or other thread mass and during storage of the mass to permit complete regeneration of the cellulose by the adhering spinning bath, as they proceed to a thread storage, thread-advancing reel, which may also be a stretching reel, or as they are advanced over such a reel. when the pulsating high frequency sound wave field is established in the path of a thread proceeding fromone stage to another, as from the spinning bath to a stretching zone, or from one thread handling device to another, as between godets or between a thread handling godet and a stretching reel, the waves may be applied in any direction. with respect to the direction of travel of the thread, as for instance in a direction parallel to the direction of travel, or transversely thereof. Preferably, however, the sound waves are applied to the fibers in a direction at right angles to the direction of travel of the fibers.
The freshly spun fibers may be passed through the pulsating high frequency sound wave field prior to final setting up thereof, set up, with or without after-stretching thereof, and, at a subsequent stage, brought to unplasticized condition and after-stretched, if desired.
The transducer may be of the piezo-electric crystal, magnetostrictive, or electromagnetic type.
The accompanying drawing will serve to illustrate various specific embodiments of the invention. In the drawing.
Fig. 1 is an elevation, partly in section, of apparatus suitable for carrying out one modification of the invention;
Fig. 2 is an elevation, partly in section, of apparatus suitable for carrying out another modicells, each constituting an individual unit of the spinning machine, one cell being shown; and
Fig. is a perspective view of a difi'erent embodiment of the invention.
Referring to Figure 1, viscose is extruded through spinneret 2, positioned in vessel 3 containing the spinning bath 4, the spinneret being arranged to spin generally vertically upwardly to the godets 5 and 6, which are driven (by means not shown) at different peripheral speeds for imparting a predetermined stretch to the fibers. A pulsed generator I (which may be of conventional type) is supported above the level of the bath, in a bracket 8, secured to the side of the spinning machine, and associated with the generator is a transmission tube 9, which may itself be a transducer of the type aforesaid, or provide a support for the transducer. The tube is provided with a slot or groove in through which the thread travels to the godets, the tube thus serving not only to transmit the pulsating high frequency sound vibrations to the threads or fibers, but also as a guide for controlling the thread as it proceeds to the lowermost godet, and for remov-- ing excess coagulating liquid from the thread. The thread is passed around godet 5, over a guide 5a, and thence over godet 6. The fibers, threads or yarns leaving the spinning bath are thus subjected to the pulsating high frequency sound wavesas they enter the stretching zone.
In Figure 2, a different arrangement is illustrated, the pulsed generator I supported in bracket 8 being mounted on the side of the spinning machine so that the thread is subjected to the pulsating sound waves as it proceeds from the stretching zone. In Figure 2 the spinneret 2 is positioned for horizontal spinning.
Figure 3 illustrates an embodiment of the invention in accordance with which the fibers or yarns are subjected to the pulsating compressional waves simultaneously with stretching thereof. As shown, there is provided a trough. I2
comprising a compartment I4 and a compartment of reduced length IS, the compartments being separated from one another by a liquid-tight diaphragm 2 I, a portion of which comprises a pianoconcave compressional wave lens 22 the curved face of which is a spherical surface. Compartment I4 is supplied with a plasticizing liquid for the fibers, for instance, hot water or hot dilute acid, through pipe I6. The liquid discharges through pipe II from the overflow chamber formed adjacent one end of compartment It by the overflow I8. Compartment It contains a body of oil in which is supported a transducer II of the piezo-electric crystal type, the crystal being energized by a pulsed generator 20 supported below the trough. A reflector 23 is supported in compartment I4 below the level of the bath, and the crystal, spherical lens. and reflector are spaced away from each other at relative distances such that the system is tuned in resonance. The beam of compressional waves travelling from the crystal is directed by the lens 22 and converged to a focal point 24, as shown in dotted lines. The rays passing through the focal point impinge uponthe spherical reflector 23 and are turned back by the reflector to their point of convergence, so that the wave energies are concentrated at the point of focus 24. The fibers are passed into the liquid in compartment I4 over the guide roll I I, wrapped one or more times around the driven roller Ila, immersed in the liquid, and then around the driven roller I2a and are withdrawn from the bath over the guide roll I2. Rollers Ila and I'2 a are driven at different peripheral speeds to impart a predetermined stretch to the fibers passing therebetween. The fibers travelling from roll Ila to roll I2a pass through the focal point 24 and are thus simultaneously stretched and exposed to the action of the concentrated pulsated sound waves. It will be readily understood that one or both of rolls Na and i211 may be replaced by threadadvancing reels. With reference to Fig. 4 which is illustrative of an arrangement for subjecting the fibers to the effects of pulsed high frequency sound waves concurrently with their formation, there is shown one unit of a spinning machine comprising a spinning tank oriother similar container for the spinning bath which, it will be understood, is divided into a plurality of compartments or troughs separated by partitions and each accommodating a single spinneret and provided with suitable means for introducing fresh spinning bath into each trough and removing the spent liquid, each compartment or'cell being provided with at least one associated compressional wave producing and directing system comprising a sound producer, a compressional wave lens, and a compressional wave reflector. As shown in Fig. 4, each spinning cell is divided into two chambers 25 and 26 by electric crystal type, the crystal being adapted to translate high frequency electric oscillations produced by a generator 32 into compressional waves as will be understood. A spherical compressional wave reflector 33 is supported in chamber 25 by means of a bracket 25a. The beam of high frequency compressional waves is directed by lens 28 to a focal point .31. The focal point may be immediately adjacent the face of the spinneret or at a distance removed therefrom, or the spinneret may be positioned in the point of focus of the concentrated pulsating sound waves. The rays, passing through the focal point are returned, by the reflector 33, as they impinge thereon, and concentrated at the focal point 34, through which the freshly formed fibers pass as they are drawn through the spinning bath. It will be understood that more than one compressional wave producing and directing system, each comprising a transducer, a compressional wave lens, and a compressional wave reflector may be provided at spaced points along the length of the cell, so that the freshly formed fibers are drawn through more than one point of focus. of the concentrated pulsating high frequency sound waves as they are drawn through the bath.
The arrangement illustrated in Fig. 5 differs from thatshown in Fig. 4, in that the pianoconcave compressional wave lens 28 has a concave face of cylindrical shape and itself constitutes the liquid-tight partition between compartments 25 and 26 of the spinning cell. The reflector 33 is also cylindrical. In this embodiment of the invention, the compressional wave beam is focused and concentrated along a line in the path of travel of the fibers or threads through the spinning bath. Again, more than one compressional wave directing and concentrating system comprising a transducer, 9. cylindrical compressional wave lens, and a cylindrical compressional wave reflector may be provided, to provide a plurality of lines of focus and concentration of the sound waves.
The invention is not limited to the manufacture of fibers of regenerated cellulose from viscose, or to the manufacture of fibers from fiberforming solutions by wet spinning methods, but may be practiced in the manufacture of fibers of different chemical constitution from various fiber-forming materials. Thus, fibers of regenerated proteins may be subjected to pulsating high frequency sound waves while they are in the plastic condition in which they are initially obtained, to assist in the agglomeration of polypeptide chains into parallel bundles, as occurs in the manufacture of fibers from solutions of casein, for example.
The invention is also of advantage in the manufacture of fibers from solutions of cellulose esters, such as cellulose acetate, by either the dry or wet spinning methods. Cellulose acetate fibers obtained by spinning the solution of the ester into an evaporative atmosphere, such as heated air or other fluid medium, and while still in the plastic condition in which they are obtained initially, or such fibers obtained by spinning the solution into a setting bath which may comprise, for instance, an aqueous salt solution, hydrocarbons, or oils, etc., may be subjected to the pulsating high frequency sound waves, for the obtention of fibers having enhanced tenacity by virtue of improved micellar orientation.
Modifications andvariations may be made in the specific procedures described herein, without 8 departing from the spirit and scope of the invention as defined by the appended claims.
We claim:
1. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,
advancing the fibers, at some time between extrusion of thefiber-forming material and final setting of the fibers, in a predetermined path and through a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second, said beamof waves being focused in a definite, predetermined direction on the path of the fibers.
2. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at some time between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path and through a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second, said beam of waves being focused in a definite predetermined direction to a single point .on the path of the fibers.
3. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at some time between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path and through a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second, said beam of waves being focused in a predetermined definite direction to a line on the path of the fibers.
4. The method of claim 1, wherein the fiberforming material is viscose.
5. The method of claim 2, wherein the fiberforming material is viscose.
6. The method of claim 3, wherein the fiberforming material is viscose.
'7. Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, and drawing the fibers thus formed through the setting bath, the beam of sound waves being focused in a definite predetermined direction on the path of the fibers through the bath so that the sound wave rays pass transversely through the fibers.
8. Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, and drawing the fibers thus formedthrough the setting bath, the beam of sound waves being focused in a definite predetermined direction to a single point on the path of the fibers through the bath so that the rays of the sound wave beam pass transversely through the fibers.
from viscose which comprises extruding the vbcose through a spinneret into a focused beam of pulsating sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose; and drawing the fibers thus formed through the setting bath, the beam of sound waves being focused in a definite predetermined direction to a line on the path of the fibers through the bath so that the rays of the sound wave beam pass transversely through the fibers.
10. Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, ad- Jacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction on the path of the fibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly. through the same point on the path of the fibers and perpendicularly through the fibers.
11. Method of manufacturing artificial fibers from viscose which comprises extruding the viscose through a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, adjacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction on a single point on the path of the fibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly through said point on the path of the fibers and transversely through the fibers.
12. Method of manufacturing artificial fibers from viscose which comprises extruding the viscose throu h a spinneret into a focused beam of pulsating high frequency sound waves having a frequency of at least 1000 cycles per second maintained in an acid setting bath for the viscose, adjacent the spinneret, and drawing the fibers thus formed through the setting bath, the beam of sound rays being focused in a definite predetermined direction in a line on the path of thefibers and reflected back to the site of focus so that any given ray of the sound wave beam passes repeatedly through the same point in the line on the path of the fibers and perpendicularly through the fibers.
13. A machine for manufacturing artificial fibers comprising, in combination, a vessel containing a setting medium for a fiber-forming material, means for extruding a fiber-forming material into the setting medium, means for drawing the fibers formed in the setting medium through the medium in a predetermined path, means for producing a pulsating beam of sound .waves having a frequency of at-least 1000 cycles per second in the setting medium, and a compressional wave lens disposed between the means for producing the beam of sound waves and the fibers, for focusing the beam of sound waves ina definite, predetermined direction on the path of the fibers 14. A machine for manufacturing a ificiai fibers comprising in combination a vessel contalning a setting medium fora fibereforming material, means for extruding a fiber -forming material into the setting medium, means for drawing the fibers formed in the setting medium 10 through the medium in a predetermined path, means for producing a beam of sound waves having a frequency of at least 1000 cycles per second in the setting medium, and a piano-concave compressional lens the curved face of which is a spherical surface disposed between the means for producing the beam of sound waves and the fibers, for focusing the beam of sound waves in'a definite predetermined direction to a single point on the path of the fibers through the setting medium.
15. A machine for manufacturing artificial fibers comprising in combination a vessel containing a setting medium for a fiber-forming material, means for extruding a fiber-forming material into the setting medium, means for drawin the fibers formed in the setting medium through the medium in a predetermined path, means for producing a beam of sound waves having a frequency of at least 1000 cycles per second in the setting medium, and a piano-concave compressional lens the curved face of which is a cylindrical surface disposed between the means for producing the beam of sound waves and the fibers for focusing the beam of sound waves in a definite predetermined direction to a line on the path of the fibers through the setting medium.
16. A machine for manufacturing artificial fibers which comprises in combination a container, a plano-concave compressional wave lens extending longitudinally of the container and separating the container into two liquid-tight compartments, a setting medium for a fiberforming material in one of the compartments, a body of oil in the other of the compartments, a piezo-electric crystal supported in the body of oil, means for energizing the crystal to produce a beam of pulsating high frequency sound waves. a compressional wave reflector tuned in resonance with the lens and crystal and supported in the setting medium, means supported in the setting medium for extruding a fiber-forming material into the medium, and means for drawing the fibers formed in the medium in a predetermined path through the medium between the lens and reflector and in a direction at a right angle to the beam of sound waves produced by the crystal, and through the site of focus of the focused and reflected sound waves.
17. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers, advancing the fibers, at sometime between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path, and through a beam of pulsating sound waves having a frequency of 250,000 cycles per second, each pulse having a width of 0.001 second, said beam being focused and reflected back in a definite predetermined direction to a focal site on the path of the fibers.
18. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,'
advancingthe fibers, at sometime between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path, and through a beam of pulsating sound waves having a frequency of 250,000 cycles per second, each pulse having a width of 0.001 second, said setting of the fibers, in a predetermined path,
and through a beam of pulsating sound waves having a frequency 01' 250,000 cycles per second, each pulse having a width of 0.001 second, said waves being applied transversely of the fibers and the sound wave beam being focused and refiected back to a single point on the path of the fibers so that each ray of the beam passes repeatedly through said point and transversely through the fibers.
20. A method of manufacturing artificial fibers from an organic polymeric fiber-forming material capable of being formed into fibers which exhibit crystallinity, which comprises extruding a solution of the fiber-forming material into a setting medium to form initially plastic fibers,
advancing the fibers, at some time between extrusion of the fiber-forming material and final setting of the fibers, in a predetermined path, and through a beam of pulsating sound waves having a frequency of 250,000 cycles per second, each pulse having a width of 0.001'second, said waves being applied at a right angle to the fibers and the sound wave beam being focused and reflected back to a line onthe path of the fibers so that each ray of the beam passes repeatedly through the same point on said line and perpendicularly through the fibers.
LEROY ERIC PETERSON. SIDNEY LEONARD DART.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS OTHER REFERENCES Chimie 8: Industrie, vol. 55, #4, April 1946, pp. 263-268.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US724138A US2484014A (en) | 1947-01-24 | 1947-01-24 | Production of artificial fibers |
GB35040/47A GB652744A (en) | 1947-01-24 | 1947-12-31 | Production of artificial fibers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US652744XA | 1947-01-24 | 1947-01-24 | |
US724138A US2484014A (en) | 1947-01-24 | 1947-01-24 | Production of artificial fibers |
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Publication Number | Publication Date |
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US2484014A true US2484014A (en) | 1949-10-11 |
Family
ID=26745415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US724138A Expired - Lifetime US2484014A (en) | 1947-01-24 | 1947-01-24 | Production of artificial fibers |
Country Status (2)
Country | Link |
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US (1) | US2484014A (en) |
GB (1) | GB652744A (en) |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2784119A (en) * | 1953-09-17 | 1957-03-05 | Libbey Owens Ford Glass Co | Ultrasonic cleaning of curved surfaces, and apparatus therefor |
US2800682A (en) * | 1954-02-23 | 1957-07-30 | American Viscose Corp | Piezoelectric tube for applying liquid to running strands |
US2802476A (en) * | 1954-06-10 | 1957-08-13 | Detrex Corp | Cleaning apparatus |
US2802758A (en) * | 1954-06-10 | 1957-08-13 | Detrex Corp | Method of cleaning |
US2834359A (en) * | 1954-08-04 | 1958-05-13 | Detrex Chem Ind | Cleaning apparatus |
US2845077A (en) * | 1956-08-02 | 1958-07-29 | Branson Instr | Ultrasonic cleaning apparatus |
US2852417A (en) * | 1954-06-17 | 1958-09-16 | Detrex Corp | Cleaning method and apparatus |
US2863075A (en) * | 1953-12-15 | 1958-12-02 | Francis J Fry | Ultrasonic transducer |
US2883310A (en) * | 1954-07-01 | 1959-04-21 | Libbey Owens Ford Glass Co | Surface cleaning apparatus and method |
US2888939A (en) * | 1955-03-14 | 1959-06-02 | Nitsche Karl Paul Wolfgang | Apparatus for cleaning or similar treatment of metallic articles |
US2896646A (en) * | 1954-05-05 | 1959-07-28 | Bendix Aviat Corp | Machine for vibration treatment of surfaces |
US2980123A (en) * | 1955-11-14 | 1961-04-18 | Jerome H Lemelson | Ultrasonic apparatus |
US2987068A (en) * | 1956-05-01 | 1961-06-06 | Branson Instr | Apparatus for ultrasonic cleaning |
US2993373A (en) * | 1956-09-18 | 1961-07-25 | Kritz Jack | Ultrasonic flowmeters and transducers therefor |
US2998823A (en) * | 1956-05-15 | 1961-09-05 | Libbey Owens Ford Glass Co | Apparatus for cleaning surfaces |
US3001769A (en) * | 1959-02-27 | 1961-09-26 | Phillips Mfg Company | Ultrasonic degreaser |
US3002731A (en) * | 1956-11-15 | 1961-10-03 | Gen Motors Corp | Apparatus for ultrasonic cleaning |
US3066686A (en) * | 1960-05-10 | 1962-12-04 | Bendix Corp | Sonic treating apparatus |
US3084020A (en) * | 1956-05-30 | 1963-04-02 | Rene Ruegg | Method of treating knitted superpoly-amide textile fabric with an aqueous phenol bath subjected to ultra-sonic waves and fabric produced thereby |
US3161702A (en) * | 1962-01-04 | 1964-12-15 | St Regis Paper Co | Process for rendering polymeric surface adherent to a coating |
US3525243A (en) * | 1967-06-15 | 1970-08-25 | Gulton Ind Inc | Wire cleaning apparatus |
US3688527A (en) * | 1970-07-13 | 1972-09-05 | Stam Instr | Apparatus for cleaning resilient webs |
US4324751A (en) * | 1979-11-05 | 1982-04-13 | Fiber Associates, Incorporated | Process for preparing viscose rayon |
US4597921A (en) * | 1984-07-26 | 1986-07-01 | Northern Telecom Limited | Provision of plastic insulation upon an electrical conductor |
US5244607A (en) * | 1992-07-23 | 1993-09-14 | E. I. Du Pont De Nemours And Company | Quenching and coagulation of filaments in an ultrasonic field |
US5617887A (en) * | 1994-06-27 | 1997-04-08 | Shibano; Yoshihide | Ultrasonic cleaning apparatus |
US5801106A (en) * | 1996-05-10 | 1998-09-01 | Kimberly-Clark Worldwide, Inc. | Polymeric strands with high surface area or altered surface properties |
US6020277A (en) * | 1994-06-23 | 2000-02-01 | Kimberly-Clark Corporation | Polymeric strands with enhanced tensile strength, nonwoven webs including such strands, and methods for making same |
US6315215B1 (en) | 1995-12-21 | 2001-11-13 | Kimberly-Clark Worldwide, Inc. | Apparatus and method for ultrasonically self-cleaning an orifice |
US6395216B1 (en) | 1994-06-23 | 2002-05-28 | Kimberly-Clark Worldwide, Inc. | Method and apparatus for ultrasonically assisted melt extrusion of fibers |
US6450417B1 (en) | 1995-12-21 | 2002-09-17 | Kimberly-Clark Worldwide Inc. | Ultrasonic liquid fuel injection apparatus and method |
US6543700B2 (en) | 2000-12-11 | 2003-04-08 | Kimberly-Clark Worldwide, Inc. | Ultrasonic unitized fuel injector with ceramic valve body |
US6663027B2 (en) | 2000-12-11 | 2003-12-16 | Kimberly-Clark Worldwide, Inc. | Unitized injector modified for ultrasonically stimulated operation |
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US1699615A (en) * | 1926-08-03 | 1929-01-22 | Toshiya Iwasaki | Process for manufacturing artificial silk and other filaments by applying electric current |
US1672943A (en) * | 1927-01-15 | 1928-06-12 | Jackson John Grant | Method of producing filamentary material |
US2036752A (en) * | 1930-11-13 | 1936-04-07 | Herzog Reginald Oliver | Producing artificial structures, such as artificial silk, bands or the like, from viscose |
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Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2784119A (en) * | 1953-09-17 | 1957-03-05 | Libbey Owens Ford Glass Co | Ultrasonic cleaning of curved surfaces, and apparatus therefor |
US2863075A (en) * | 1953-12-15 | 1958-12-02 | Francis J Fry | Ultrasonic transducer |
US2800682A (en) * | 1954-02-23 | 1957-07-30 | American Viscose Corp | Piezoelectric tube for applying liquid to running strands |
US2896646A (en) * | 1954-05-05 | 1959-07-28 | Bendix Aviat Corp | Machine for vibration treatment of surfaces |
US2802476A (en) * | 1954-06-10 | 1957-08-13 | Detrex Corp | Cleaning apparatus |
US2802758A (en) * | 1954-06-10 | 1957-08-13 | Detrex Corp | Method of cleaning |
US2852417A (en) * | 1954-06-17 | 1958-09-16 | Detrex Corp | Cleaning method and apparatus |
US2883310A (en) * | 1954-07-01 | 1959-04-21 | Libbey Owens Ford Glass Co | Surface cleaning apparatus and method |
US2834359A (en) * | 1954-08-04 | 1958-05-13 | Detrex Chem Ind | Cleaning apparatus |
US2888939A (en) * | 1955-03-14 | 1959-06-02 | Nitsche Karl Paul Wolfgang | Apparatus for cleaning or similar treatment of metallic articles |
US2980123A (en) * | 1955-11-14 | 1961-04-18 | Jerome H Lemelson | Ultrasonic apparatus |
US2987068A (en) * | 1956-05-01 | 1961-06-06 | Branson Instr | Apparatus for ultrasonic cleaning |
US2998823A (en) * | 1956-05-15 | 1961-09-05 | Libbey Owens Ford Glass Co | Apparatus for cleaning surfaces |
US3084020A (en) * | 1956-05-30 | 1963-04-02 | Rene Ruegg | Method of treating knitted superpoly-amide textile fabric with an aqueous phenol bath subjected to ultra-sonic waves and fabric produced thereby |
US2845077A (en) * | 1956-08-02 | 1958-07-29 | Branson Instr | Ultrasonic cleaning apparatus |
US2993373A (en) * | 1956-09-18 | 1961-07-25 | Kritz Jack | Ultrasonic flowmeters and transducers therefor |
US3002731A (en) * | 1956-11-15 | 1961-10-03 | Gen Motors Corp | Apparatus for ultrasonic cleaning |
US3001769A (en) * | 1959-02-27 | 1961-09-26 | Phillips Mfg Company | Ultrasonic degreaser |
US3066686A (en) * | 1960-05-10 | 1962-12-04 | Bendix Corp | Sonic treating apparatus |
US3161702A (en) * | 1962-01-04 | 1964-12-15 | St Regis Paper Co | Process for rendering polymeric surface adherent to a coating |
US3525243A (en) * | 1967-06-15 | 1970-08-25 | Gulton Ind Inc | Wire cleaning apparatus |
US3688527A (en) * | 1970-07-13 | 1972-09-05 | Stam Instr | Apparatus for cleaning resilient webs |
US4324751A (en) * | 1979-11-05 | 1982-04-13 | Fiber Associates, Incorporated | Process for preparing viscose rayon |
US4597921A (en) * | 1984-07-26 | 1986-07-01 | Northern Telecom Limited | Provision of plastic insulation upon an electrical conductor |
US5244607A (en) * | 1992-07-23 | 1993-09-14 | E. I. Du Pont De Nemours And Company | Quenching and coagulation of filaments in an ultrasonic field |
US6020277A (en) * | 1994-06-23 | 2000-02-01 | Kimberly-Clark Corporation | Polymeric strands with enhanced tensile strength, nonwoven webs including such strands, and methods for making same |
US6395216B1 (en) | 1994-06-23 | 2002-05-28 | Kimberly-Clark Worldwide, Inc. | Method and apparatus for ultrasonically assisted melt extrusion of fibers |
US5617887A (en) * | 1994-06-27 | 1997-04-08 | Shibano; Yoshihide | Ultrasonic cleaning apparatus |
US6315215B1 (en) | 1995-12-21 | 2001-11-13 | Kimberly-Clark Worldwide, Inc. | Apparatus and method for ultrasonically self-cleaning an orifice |
US6450417B1 (en) | 1995-12-21 | 2002-09-17 | Kimberly-Clark Worldwide Inc. | Ultrasonic liquid fuel injection apparatus and method |
US6659365B2 (en) | 1995-12-21 | 2003-12-09 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid fuel injection apparatus and method |
US5801106A (en) * | 1996-05-10 | 1998-09-01 | Kimberly-Clark Worldwide, Inc. | Polymeric strands with high surface area or altered surface properties |
US6543700B2 (en) | 2000-12-11 | 2003-04-08 | Kimberly-Clark Worldwide, Inc. | Ultrasonic unitized fuel injector with ceramic valve body |
US6663027B2 (en) | 2000-12-11 | 2003-12-16 | Kimberly-Clark Worldwide, Inc. | Unitized injector modified for ultrasonically stimulated operation |
US20040016831A1 (en) * | 2000-12-11 | 2004-01-29 | Jameson Lee Kirby | Method of retrofitting an unitized injector for ultrasonically stimulated operation |
US6880770B2 (en) | 2000-12-11 | 2005-04-19 | Kimberly-Clark Worldwide, Inc. | Method of retrofitting an unitized injector for ultrasonically stimulated operation |
Also Published As
Publication number | Publication date |
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GB652744A (en) | 1951-05-02 |
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