|Publication number||US2293810 A|
|Publication date||25 Aug 1942|
|Filing date||22 Jun 1938|
|Priority date||22 Jun 1938|
|Publication number||US 2293810 A, US 2293810A, US-A-2293810, US2293810 A, US2293810A|
|Inventors||Domm Elgin Carleton|
|Original Assignee||Nat Standard Co|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (20), Classifications (9)|
|External Links: USPTO, USPTO Assignment, Espacenet|
Aug. 25, 1942. E. c. DoMM ELECTROPLATING STAINLESS STEEL Filed June 22, 1938 Patented Aug. 25, 1942 ELEcTaoPLa'rING STAINLESS s'rEnL Elgin Carletonv Domm, Niles, Mich., assignorto National-Standard Company, a corporation of Michigan 3 Claims.
This invention relates to a process-for producing adherent electro-coatings yupon stainless steel. This process has'heretofore proved extremely dimcult, and no method known by which an adherent coating can be obtainedupon a. stainless steel surface.` This is particularly true of coatings upon objects such as wires. l
By means of the present inyention it is possible to plate stainless steel, particularly of v the austenitic or 18-8 type, with a metal, for example copper, in a uniform adherent coating Iof any desired thickness.
This invention is primarily applicable to the "Y drawing of stainless steel wires of the 18-8 type or other high tensile strength materials particularly those including substantial percentages of chromium. Wires of this type are extremely diilicult to draw and the drawingfis considerably easier if a uniformly distributedV lubricant can be provided on the wire.
In accordance with this invention, the wire is continuously cleaned and coated with an adherent lubricating metal such as copper and is then drawn with the copper on'lt, after which the copper coating is removed. The drawing diagrammatically illustrates the sequence of steps.
and is appropriately legended.
Figure 1 and Figure 2 representk consecutive operations, the wire passing from the right hand portion of Figure 1 to the left hand portion of Figure 2. The apparatus comprises a reel l from which a wire 2 passes first through a sulphuric acid bath 3, then through a hydrochloric acid cleaning bath 4; then through a sulphuric acid deoxidizing bath 5 from which it is passed through cloths 6 soaked in sodiumcarbon'ate to through more cloths 8 soaked in sodium carbonate solution to a. copper plating bath 9. The wire is then drawn through the dies l0 and Il after which it is decoppered in the decoppering bath I2.
An example of the invention will be given in connection with stainless steel wire containing approximately 18% chromium and 8% nickel and having a tensile strength of approximately 200,000 lbs. per square inch. However, other stainless steel types, including stainless steel without nickel, for example, that having approximately 17% chromium and no nickel, are satisfactory.
The wire which has been annealed and is cov ered with scale is first cleaned to remove the scale, which may be accomplished by passing it continuously through a cleaning solution. This `a sodium carbonate neutralizing bath 1; then 'Y is preferably an acidbathK in which the-wire is made the anode for an electrical circuit. The preferred bath is approximately a 10% solution of sulfuric acid at room temperature and a'direct current is employed using the wire as the anode.
While a wide range-of current density may be employed, Ihave found 75 amperes per square foot most suitable. A reaction time of about one minute is sufficient und'er these conditions.
The wire then enters a 10% solution of hydrochloric acid at room temperature, and remains therein for about 20 seconds. It is then Washed in cold running water, and again enters a 10% sulfuric acidv bath at room temperature. In thisr bath the wire is the cathode and=a current density of about 30 amperes per square foot is employed. Under these conditions a 30 second reaction time is satisfactory.
This bath removes oxygen from the wire by generating nascent hydrogen in contact therewith. After this treatment oxygen is excluded at all times from vthe wire until plating is complete.
The oxide-free wire is then passed into a plating bath. In practice this is preferably accomplished by enclosing the wire in a cloth wetted with sodium carbonate solution while passing from the deoxidizing bath to a neutralizing bath and similarly protecting it while passing from the neutralizing bath to the plating bath.
The preferred neutralizing solution is sodium carbonate with a concentration of about 8 ounces of crystals of commercial sodium carbonate per gallon of water. The bath is preferably kept warm (about FJ. The cloths are kept wetted with sodium carbonate solution of the same concentration as the bath. The make-up water added to the cloths to replace that lost by evaporation should be warm, in order to insure relative freedom of thel .water from air. 'I'he process is sensitive enough that if ordinary cold water is added as make-up, the adherence of the resulting coating will be adversely affected.
Other neutralizing solutions may be employed in the bath -or other liquids maybe employed on the cloths, the function being to keep the wires free from air.
From the neutralizing bath the wires pass through the cloths to a plating bath which, for copper, preferably comprises a copper-cyanide plating solution. A preferable solution comprises 35 grams per liter of metallic copper, approximately 25'grams per liter of free-sodium-cyanide, approximately l0 grams per liter of sodium carbonate, 5 grams per liter of thiosulfate. The
bat-h is kept warm, `but the sodium thiosulfate also assists in keeping the bath free from oxygen.
A satisfactory current density is 30 amperes to .043 inch in diameter. Larger amounts are satisfactory but increase expense.
After the wires have been coated with copper they may be passed directly to the drawing dies and may be reduced in thickness as desired. A
powdered sodium stearate lubricant is used in the dies, in addition to the copper. With a copper coating applied as herein described, the wires may be drawn practically as many passes as desired. For example, drawing from l to 5 passes is quite satisfactory.
After the drawing operation, the copper may be removed, if desired, from the wire in any de- `sirable manner. The preferred manner is to \pass it through a copper cyanide bath of the type herein described for plating and simply reversing the current. be annealed and cleaned. Y
The foregoing detailed description has been given for clear-ness of understanding only, and no unnecessary limitations should be understood therefrom, but the appended claims should be construed as` broadly as \,permissible in view of the prior art.
l. In the continuous plating of stainless steel wire, the steps of passing a chromium-containing stainless steel Wire continuously through a bath of dilute sulfuric acid while maintaining the wirel as the anode of an electric current, clean- The wire may then again ing the wire and then passing it through a bath of dilute sulfuric acid while maintaining the'wire as the cathode of an electric circuit, maintaining the contact and electric current under conditions to generate nascent hydrogen until the Wire has become adaptable for plating during passage through the bath, and removing the stainless steel wire continuously from the bath to an alkaline cyanide copper `plating bath while preventing access of air thereto, by passing the wire continuously through. a fabric wetted with an aqueous solution of sodium carbonate during the entire distance from the acid bath to the plating bath.
2. In the continuous plating of stainless steel wire, the steps of passing a chromium-containing stainless steel wire continuously through a bath of dilute sulfuric acid while maintaining the wire as the anode of an electric circuit, cleaning the wire and then passing it through a bath of dilute sulfuric acid while maintaining the wire as the cathode of an electric circuit, maintaining the contact and electric current under conditions to generate nascent hydrogen until the wire has become adaptable for plating during passage through the bath, and removing the stainless steel wire continuously from the bath to an alkaline cyanide copper plating bath while preventing access of air thereto, by passing the wire continuously while wetted with an aqueous solution of an alkaline salt during the entire distance from the acid bath to the plating bath.
3. The method as set forth in claim 2, in which the wire is passed from the acid bath to the plating bath through fabrics wetted with the alkaline salt.
ELGIN CARLETON DOMM.
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US2445372 *||26 Apr 1945||20 Jul 1948||American Steel & Wire Co||Process of copper coating stainless steel|
|US2491126 *||28 Jul 1945||13 Dec 1949||Emi Ltd||Method of electroplating on chromium or chromium-iron alloys|
|US2517907 *||5 Jan 1945||8 Aug 1950||Conmar Prod Corp||Apparatus for electrotreating metal slide fasteners|
|US2528717 *||11 Oct 1944||7 Nov 1950||Clements Batcheller||Method of electroplating stainless steels and irons|
|US2546447 *||15 May 1945||27 Mar 1951||American Steel & Wire Co||Art of drawing fine steel wire|
|US2560534 *||12 Jul 1946||17 Jul 1951||Nat Standard Co||Method of operating a continuous electroplating system|
|US2603593 *||8 Jan 1946||15 Jul 1952||Electeodepositiqn of metaiis|
|US2742691 *||18 Apr 1950||24 Apr 1956||Ohio Commw Eng Co||Method of making corrosion resistant clad steel|
|US2762763 *||13 Jul 1951||11 Sep 1956||Nat Standard Co||Process and apparatus for simultaneously drawing and plating wire|
|US2776255 *||7 Jul 1955||1 Jan 1957||Rockwell Spring & Axle Co||Method of making formed, plated articles|
|US2856334 *||1 Nov 1955||14 Oct 1958||Tiarco Corp||Chromium plating|
|US2859161 *||13 Jun 1957||4 Nov 1958||Cornell Dubilier Electric||Contaminating ion removal|
|US2947080 *||29 Jan 1953||2 Aug 1960||Leonard W Kates||Method for making fuel elements|
|US2947676 *||29 Jan 1952||2 Aug 1960||John L Zambrow||Method of making wire fuel elements|
|US3055087 *||7 Jun 1954||25 Sep 1962||Union Carbide Corp||Carbonyl metal plated product|
|US3074857 *||18 Nov 1958||22 Jan 1963||Aluminium Walzwerke Singen||Method and apparatus for producing dielectric layer on the surface of an aluminum foil|
|US3676322 *||6 Jan 1970||11 Jul 1972||Furukawa Electric Co Ltd||Apparatus and method for continuous production of electrolytically treated wires|
|US5296127 *||6 Aug 1992||22 Mar 1994||Saunders William T||Composite-coated flat-rolled sheet metal manufacture|
|US5927131 *||20 Mar 1997||27 Jul 1999||Shin-Etsu Handotai Co., Ltd.||Method of manufacturing wire for use in a wire saw and wire for use in a wire saw|
|US6418994||11 Jul 1997||16 Jul 2002||Michelin Recherche Et Technique S.A.||Tire having a stainless steel carcass reinforcement|
|U.S. Classification||205/138, 205/218, 428/935, 205/222, 428/685|
|Cooperative Classification||C25D5/36, Y10S428/935|