US2103587A - Ornamentation of textile fabrics - Google Patents
Ornamentation of textile fabrics Download PDFInfo
- Publication number
- US2103587A US2103587A US2103587DA US2103587A US 2103587 A US2103587 A US 2103587A US 2103587D A US2103587D A US 2103587DA US 2103587 A US2103587 A US 2103587A
- Authority
- US
- United States
- Prior art keywords
- fabric
- resin
- embossed
- textile fabrics
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 76
- 239000004753 textile Substances 0.000 title description 14
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 32
- 229920005989 resin Polymers 0.000 description 22
- 239000011347 resin Substances 0.000 description 22
- 239000004202 carbamide Substances 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 229920000297 Rayon Polymers 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 229920002955 Art silk Polymers 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000005755 formation reaction Methods 0.000 description 10
- 230000002401 inhibitory effect Effects 0.000 description 10
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229920003002 synthetic resin Polymers 0.000 description 8
- 239000000057 synthetic resin Substances 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 6
- 230000002378 acidificating Effects 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000004049 embossing Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000004627 regenerated cellulose Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- -1 aliphatic amino compound Chemical class 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 239000001117 sulphuric acid Substances 0.000 description 4
- IVNZBWNBYXERPK-DZGBHZPSSA-K trisodium;(8Z)-7-oxo-8-[(4-sulfonatonaphthalen-1-yl)hydrazinylidene]naphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N\N=C3/C(=O)C=CC=4C=C(C=C(C=43)S([O-])(=O)=O)S(=O)(=O)[O-])=CC=C(S([O-])(=O)=O)C2=C1 IVNZBWNBYXERPK-DZGBHZPSSA-K 0.000 description 4
- SOAAGHDAWFEEPP-JZJYNLBNSA-N (4Z)-4-[(2,4-dimethylphenyl)hydrazinylidene]-3-oxonaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N\N=C/1C2=CC=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C\1=O SOAAGHDAWFEEPP-JZJYNLBNSA-N 0.000 description 2
- 239000005695 Ammonium acetate Substances 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N Diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 229960004011 Methenamine Drugs 0.000 description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N Polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 2
- KIEOKOFEPABQKJ-UHFFFAOYSA-N Sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N Thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- 229940043376 ammonium acetate Drugs 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N cyanoguanidine Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- OLVNAWLXZDRGPL-QXCCSOORSA-L disodium;(6Z)-4-amino-3-[[4-[4-[(2,4-diaminophenyl)diazenyl]phenyl]phenyl]diazenyl]-5-oxo-6-(phenylhydrazinylidene)naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC=3C=C(C(=N\NC=4C=CC=CC=4)/C(=O)C=3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 OLVNAWLXZDRGPL-QXCCSOORSA-L 0.000 description 2
- FTZLWXQKVFFWLY-UHFFFAOYSA-L disodium;2,5-dichloro-4-[3-methyl-5-oxo-4-[(4-sulfonatophenyl)diazenyl]-4H-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].[Na+].CC1=NN(C=2C(=CC(=C(Cl)C=2)S([O-])(=O)=O)Cl)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FTZLWXQKVFFWLY-UHFFFAOYSA-L 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000000717 retained Effects 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/56—Condensation products or precondensation products prepared with aldehydes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- This invention relates to the ornamentation of textile fabrics composed of natural cellulosic fibres, such as cotton, or regenerated cellulose artiflcial silk, but not to fabrics composed of cellu- 5 lose acetate or other cellulose esters or of animal fibres, such as wool.
- the process is concerned with such fabrics when treated with materials or components which lead to the formation of an insoluble resin of theamido-formaldehyde group.
- the object of the present invention is to pro vide for the production of valuable pattern effects upon fabrics which have been treated as before 20 described.
- Our invention comprises a process for producing pattern effects on textile fabrics comprising applying to selectedareas of said fabric a reagent inhibiting the formation of the synthetic resin, before or after impregnating the fabric with materials or components which lead to thefor'mation of a synthetic resin of the ammo-formaldehyde group, heating resin in theparts of the fabric not so treated, and
- Our invention further comprises the application to the fabric in selected areas of any one-or more of the nitrogenous compounds hereinafter indicated for the prevention of the formation of the insoluble resin of the ammo-formaldehyde group in such areas.
- Our invention further comprises applying to a dyed or undyed textile fabric a dyestuif which will not normally give dyeings fast to washing upon that fabric before, simultaneously with or subsequently to the impregnation step with the resin components or materials but prior to the heating step specified.
- Our invention further comprises the step, in the process above described, of subjecting the fabric after impregnating with the resin mate- 50 rials or components and drying but before heating, to a mechanical treatment for the production of an embossed, glazed, schreinered or other desired effect thereby.
- the fabrio may be so treated in the manner it! previously described, as to produce both perma- Apnlication January
- oo Printers Associa- February diphenylamine and m-aminopheno1. may be produced from formaldehyde and urea or allied compounds-such as thiourea and dicyanodiamide.
- Example 2 A viscose artificial silk fabric previously dyed with 6% Chlorazol Black E (CO1. Ind. N0. 581) is impregnated with the solution of Example 1, printed with a paste containing of piperidine, glazed in a friction calender and heat treated as in Example 1. After washing and soaping it is found that the glazed effect has only been retained in the unprinted parts.
- Chlorazol Black E CO1. Ind. N0. 581
- Example 3 England a British I A cotton warp-viscose artificial silk weft fabric is impregnated with a solution of an early inter- 2 mediate condensation product of urea and formaldehyde containing 8% Acid Scarlet 43 (C01. Ind. No. '19) and an acidic catalyst. After drying the fabric is printed with a paste containing 20% hexamethylene tetramine, dried, embossed and heat treated as in Example 1. The result after washing and soaping is a white flat pattern on'a red embossed ground.
- Example 4 with the solution of Example 1, printed with a paste containing 26% urea and 6% Indigosol Scarlet HB (Col. 1nd. Suppl. p. 43), dried, embossed and heated as in Example 1.
- the Indigosol is then developed as usual by a passage in a solution of sodium bichrcmate and sulphuric acid, followed by rinsing and soaping. The result is a red flat pattern on a white embossed ground.
- Example 5 A viscose artificial silk fabric is impregnated with a solution of an early intermediate condenof urea and formaldehyde containing 2.5% Lissamine Fast Yellow 2G (Col. Ind. No. 639) and an acidic catalyst. After dryi'ng the fabric is printed with a paste containing 26% urea and 5% Soledon Brilliant Purple RR (Col. Ind. Suppl. p. 52) dried, embossed and heated as in Example 1. The Soledon is then developed as usual by a passage in a solution of sodium bichromate and sulphuric acid, followed by rinsing and scoping. The result is a violet fiat pattern on a yellow embossed ground.
- Example 6 A cotton warp-viscose artificial'silk weft fabric is impregnated with the solution of Example 1, printed with a paste containing 25% ammonium acetate, dried, heated for seconds at 200 C., washed and dyed with 2% Benzo Fast Scarlet 488 (Col. Ind. No. 32'! After washing and drying it is found that the printed portions have dyed to a deep red while the ground is only slightly tinted.
- Example 7 A viscose artificial silk fabric is impregnated with the solution of Example 1, printed in a well spaced pattern with a paste containing 25% urea, overprinted in a cover pattern with a paste containing 2.5% Acid Scarlet 4R (Col. Ind. No. .79), embossed and heated as in Example 1. After washing and soaping the spaced pattern appears white and flat on an embossed ground, part of which is coloured red by the cover pattern.
- Example 8 A viscose artificial silk fabric is printed in a well spaced pattern with a paste containing 25% urea, dried, overprinted in a cover pattern with a paste containing 10% (on urea) of a ureaformaldehyde condensate, and acidic catalyst, and 2.5% Acid Scarlet 4R (Col. Ind. No. '79) dried, embossed and heat treated as in result is similar to that of Example '1, except that not only the colour but also the embossing is limited to the unresisted'parts of the cover pattern.
- the invention includes fabrics treated by the processes hereinbefore described.
- a process for producing pattern effects on textile fabrics which comprises applying to the fabric composed of natural or regenerated cellulose unreacted components of a synthetic resin of the amide-formaldehyde group and treating the fabric in selected areas with a reagent which inhibits the formation of said resin, heating the fabric to form the resin on the fabric in those portions thereof not treated with the inhibiting agent and then washing out of the selected areas the unreacted resin components and inhibiting agent.
- a process for producing pattern effects on textile fabrics which comprises-applying to the fabric composed of natural or regenerated cellulose unreacted components of a synthetic resin of the amide-formaldehyde group and treating the fabric in selected areas with a reagent which inhibits the formation of said resin, drying the the nitrogenous compounds of the group consisting of a heterocyclic base; an aldehyde-ammonia condensation product; an ammonium salt; an acid amide; an aliphatic amino compound; an aromatic amino compound.
Description
Patented Dec. 28, 1937 PATENT OFFlGE f ORNAMENTATION F TEXTILE FABRICS Louis Amede Lantz, and William company no Drawing.
rial No. 60,52
21,, 1935 I 4 Claims.
This invention relates to the ornamentation of textile fabrics composed of natural cellulosic fibres, such as cotton, or regenerated cellulose artiflcial silk, but not to fabrics composed of cellu- 5 lose acetate or other cellulose esters or of animal fibres, such as wool. The process is concerned with such fabrics when treated with materials or components which lead to the formation of an insoluble resin of theamido-formaldehyde group.
It is known to treat such fabrics in this manner for the purpose of giving permanency to embossing or like mechanically produced effects or finishes upon the fabric, or for giving permanency or fastness to relatively fugitivedyeings or to dyeings of dyestuffs which have little or no aflinity for these fabrics.
r The object of the present invention is to pro vide for the production of valuable pattern effects upon fabrics which have been treated as before 20 described.
Our invention comprises a process for producing pattern effects on textile fabrics comprising applying to selectedareas of said fabric a reagent inhibiting the formation of the synthetic resin, before or after impregnating the fabric with materials or components which lead to thefor'mation of a synthetic resin of the ammo-formaldehyde group, heating resin in theparts of the fabric not so treated, and
3 then washing out the resin components orniaterials and the inhibiting reagent from the selected areas.
Our invention further comprises the application to the fabric in selected areas of any one-or more of the nitrogenous compounds hereinafter indicated for the prevention of the formation of the insoluble resin of the ammo-formaldehyde group in such areas.
Our invention further comprises applying to a dyed or undyed textile fabric a dyestuif which will not normally give dyeings fast to washing upon that fabric before, simultaneously with or subsequently to the impregnation step with the resin components or materials but prior to the heating step specified.
Our invention further comprises the step, in the process above described, of subjecting the fabric after impregnating with the resin mate- 50 rials or components and drying but before heating, to a mechanical treatment for the production of an embossed, glazed, schreinered or other desired effect thereby.
The fabriomay be so treated in the manner it! previously described, as to produce both perma- Apnlication January Great Britain the fabric to form thesynthetlc' Alexander Lan M rrim Stuart Mill o land, assignors to The Call tion Limited, Manchester,
er, Manchester, En
oo Printers Associa- February diphenylamine and m-aminopheno1. may be produced from formaldehyde and urea or allied compounds-such as thiourea and dicyanodiamide.
'the parts in which the resin not been allowed to form.
Our invention will now be illustrated by the following examples:-
Ewample 1 and dried. The fabric is then passed through" the bowls of an embossing calender and subsequently heated for 50 seconds at 200 C. After washing and soaping the fabric shows a flat pat-,
tern on an embossed ground.
Example 2 A viscose artificial silk fabric previously dyed with 6% Chlorazol Black E (CO1. Ind. N0. 581) is impregnated with the solution of Example 1, printed with a paste containing of piperidine, glazed in a friction calender and heat treated as in Example 1. After washing and soaping it is found that the glazed effect has only been retained in the unprinted parts.
Example 3 England, a British I A cotton warp-viscose artificial silk weft fabric is impregnated with a solution of an early inter- 2 mediate condensation product of urea and formaldehyde containing 8% Acid Scarlet 43 (C01. Ind. No. '19) and an acidic catalyst. After drying the fabric is printed with a paste containing 20% hexamethylene tetramine, dried, embossed and heat treated as in Example 1. The result after washing and soaping is a white flat pattern on'a red embossed ground.
Example 4 with the solution of Example 1, printed with a paste containing 26% urea and 6% Indigosol Scarlet HB (Col. 1nd. Suppl. p. 43), dried, embossed and heated as in Example 1. The Indigosol is then developed as usual by a passage in a solution of sodium bichrcmate and sulphuric acid, followed by rinsing and soaping. The result is a red flat pattern on a white embossed ground.
Example 5 A viscose artificial silk fabric is impregnated with a solution of an early intermediate condenof urea and formaldehyde containing 2.5% Lissamine Fast Yellow 2G (Col. Ind. No. 639) and an acidic catalyst. After dryi'ng the fabric is printed with a paste containing 26% urea and 5% Soledon Brilliant Purple RR (Col. Ind. Suppl. p. 52) dried, embossed and heated as in Example 1. The Soledon is then developed as usual by a passage in a solution of sodium bichromate and sulphuric acid, followed by rinsing and scoping. The result is a violet fiat pattern on a yellow embossed ground.
Example 6 A cotton warp-viscose artificial'silk weft fabric is impregnated with the solution of Example 1, printed with a paste containing 25% ammonium acetate, dried, heated for seconds at 200 C., washed and dyed with 2% Benzo Fast Scarlet 488 (Col. Ind. No. 32'!) After washing and drying it is found that the printed portions have dyed to a deep red while the ground is only slightly tinted.
Example 7 A viscose artificial silk fabric is impregnated with the solution of Example 1, printed in a well spaced pattern with a paste containing 25% urea, overprinted in a cover pattern with a paste containing 2.5% Acid Scarlet 4R (Col. Ind. No. .79), embossed and heated as in Example 1. After washing and soaping the spaced pattern appears white and flat on an embossed ground, part of which is coloured red by the cover pattern.
Example 8 A viscose artificial silk fabric is printed in a well spaced pattern with a paste containing 25% urea, dried, overprinted in a cover pattern with a paste containing 10% (on urea) of a ureaformaldehyde condensate, and acidic catalyst, and 2.5% Acid Scarlet 4R (Col. Ind. No. '79) dried, embossed and heat treated as in result is similar to that of Example '1, except that not only the colour but also the embossing is limited to the unresisted'parts of the cover pattern.
The invention includes fabrics treated by the processes hereinbefore described.
What we claim is:-
1. A process for producing pattern effects on textile fabrics which comprises applying to the fabric composed of natural or regenerated cellulose unreacted components of a synthetic resin of the amide-formaldehyde group and treating the fabric in selected areas with a reagent which inhibits the formation of said resin, heating the fabric to form the resin on the fabric in those portions thereof not treated with the inhibiting agent and then washing out of the selected areas the unreacted resin components and inhibiting agent.
2. The process claimed in claim 1 wherein the inhibiting agent is applied to the fabric in a dye printing paste. I
3. A process for producing pattern effects on textile fabrics which comprises-applying to the fabric composed of natural or regenerated cellulose unreacted components of a synthetic resin of the amide-formaldehyde group and treating the fabric in selected areas with a reagent which inhibits the formation of said resin, drying the the nitrogenous compounds of the group consisting of a heterocyclic base; an aldehyde-ammonia condensation product; an ammonium salt; an acid amide; an aliphatic amino compound; an aromatic amino compound.
LOUIS mm.
ER LANG MORRISON. WILLIAM STUART m.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2103587A true US2103587A (en) | 1937-12-28 |
Family
ID=3429137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2103587D Expired - Lifetime US2103587A (en) | Ornamentation of textile fabrics |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2103587A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2743190A (en) * | 1952-05-13 | 1956-04-24 | Bancroft & Sons Co J | Method for producing effects on fabrics |
| US2777186A (en) * | 1953-12-21 | 1957-01-15 | Heberlein Patent Corp | Process for the production of permanent locally goffered effects and products therefrom |
| US2899263A (en) * | 1949-08-15 | 1959-08-11 | Eneurea | |
| US2936209A (en) * | 1957-12-16 | 1960-05-10 | Optical Gaging Prod Inc | Process for marking thermoplastic surfaces and resultant product |
| US3125403A (en) * | 1964-03-17 | New colouration process | ||
| US3986824A (en) * | 1973-05-30 | 1976-10-19 | Quikoton S.A. | Process for the manufacture of a dyed sheet-like textile structure |
| US4029831A (en) * | 1975-06-19 | 1977-06-14 | Masonite Corporation | Method of making a multi-gloss panel |
| US20060081164A1 (en) * | 2004-10-20 | 2006-04-20 | Neustat Paula S | Antiquing whole cloth quilt fabric |
-
0
- US US2103587D patent/US2103587A/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3125403A (en) * | 1964-03-17 | New colouration process | ||
| US2899263A (en) * | 1949-08-15 | 1959-08-11 | Eneurea | |
| US2743190A (en) * | 1952-05-13 | 1956-04-24 | Bancroft & Sons Co J | Method for producing effects on fabrics |
| US2777186A (en) * | 1953-12-21 | 1957-01-15 | Heberlein Patent Corp | Process for the production of permanent locally goffered effects and products therefrom |
| US2936209A (en) * | 1957-12-16 | 1960-05-10 | Optical Gaging Prod Inc | Process for marking thermoplastic surfaces and resultant product |
| US3986824A (en) * | 1973-05-30 | 1976-10-19 | Quikoton S.A. | Process for the manufacture of a dyed sheet-like textile structure |
| US4029831A (en) * | 1975-06-19 | 1977-06-14 | Masonite Corporation | Method of making a multi-gloss panel |
| US20060081164A1 (en) * | 2004-10-20 | 2006-04-20 | Neustat Paula S | Antiquing whole cloth quilt fabric |
| US7140313B2 (en) * | 2004-10-20 | 2006-11-28 | Neustat Paula S | Antiquing whole cloth quilt fabric |
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