US20130081770A1

US20130081770A1 - Method for manufacturing eco-friendly inorganic paper

Info

Publication number: US20130081770A1
Application number: US13/249,226
Authority: US
Inventors: Chun-Teng Huang; Chun-Ming Huang
Original assignee: Individual
Current assignee: Individual
Priority date: 2011-09-29
Filing date: 2011-09-29
Publication date: 2013-04-04

Abstract

A method is provided for manufacturing eco-friendly inorganic paper, which has a composition comprising inorganic glass powder that is greater than 51% but not greater than 75%, 25-40 wt % bonding substance comprising polypropylene (PP) (comprising mixture of polylactic acid (PLA) or PP and polyethylene (PE)), and 1-5 wt % assisting agents, through a process of continuous compression molding that includes step one to step six. As such, the paper so made, after being disposed of can be subjected to incineration of the constituent of PP, which is of a minor fraction, so as not to generate high temperature, smoke, and toxicant gases and to allow the inorganic powdery residuals of the incineration to be returnable to the earth and the nature.

Description

TECHNICAL FIELD OF THE INVENTION

The present invention generally relates to a method for manufacturing eco-friendly inorganic paper, and especially paper having a paper composition containing greater than 51% but not greater than 75% inorganic glass powder, 25-40 wt % bonding substance comprising polypropylene (PP) (comprising a mixture of polylactic acid (PLA) or PP and polyethylene (PE)) and 1-5 wt % assisting agents and is made with a continuous compression molding process, whereby the paper so made, after being disposed of, is recyclable regeneration and only consumes PP, which is of a small fraction, in incineration and combustion so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the inorganic glass powders that are of a major fraction to return to the earth and the nature after combustion.

DESCRIPTION OF THE PRIOR ART

The paper consumption of most countries of the worlds is millions of tons. The victim is the supplier of pulp, namely trees. Further, the disposed paper products and the subsequent environmental-protection processing requires quite an expense for environmental protection. Thus, in view of the limited natural resources and the future constraint of limiting lumbering operations, synthetic paper is a promising solution for such an issue and this is also a breakthrough for handling carbon release for environmental conservation and peripheral pollution.
Various types of synthetic paper are available in the international market, which usually comprises polypropylene (PP) as the primary constituent mixed with minor amount of mineral powders or rock powders to be made in the form of single-layer or multi-layer structure. The manufacturing process often employs a conventional formula of thin-film plastic products. The manufacture is done with a single layer or multiple layer co-extrusion through a flat nozzle of a shaping mold to form a thin sheet. The paper sheet, which is subjected to longitudinal stretching, receives additional sheets bonded to opposite surfaces thereof or laminated therewith, and is then further subjected lateral stretching. The synthetic paper so made is a multi-layer synthetic paper, which comprises a core layer that is stretched in two directions and surface layers that are stretched in only one direction.
The synthetic paper, either single-layered or multi-layered, which is made by subjecting a paper sheet first to longitudinal stretching and then lateral stretching, has a surface that shows bi-directional extendibility. The synthetic paper so made, although being advantageous in certain respects, is still of great difference from the performance of pulp paper. Disadvantages of the synthetic paper include: poor foldability, great difference between longitudinal tearability and lateral tearability, or excessive or insufficient tearability. Further, the synthetic paper that is made of a primary constituent of PP is not oxidized and decomposed in the nature in a short period of time after being disposed, so that it does not help in reducing secondary pollution. Further, the cost for manufacturing the synthetic paper is much higher than regular pulp paper. Due to such drawbacks, the synthetic paper has been of no appealing and attraction to the consumers and has not been widely used in the market.

SUMMARY OF THE INVENTION

In view of the previously discussed problems of the conventional technology, the present invention aims to provide a method for manufacturing eco-friendly inorganic paper, which uses inorganic glass powders in order to overcome the problem that a conventional synthetic paper that is made of a primary constituent of PP cannot be oxidized and decomposed in the nature in a short period of time after being disposed of and thus cannot reduce secondary pollution, as well as the problem that the conventional synthetic paper must be made with a much higher cost than the regular pulp paper and is not economically efficient.
An objective of the present invention is to provide a method for manufacturing eco-friendly inorganic paper, of which the composition comprises greater than 51% and not greater than 75% inorganic glass powders, 25-40 wt % bonding substance comprising polypropylene (PP) (comprising a mixture of polylactic acid (PLA) or PP and polyethylene (PE)), and 1-5 wt % assisting agents and is made with a single-layer continuous compression molding process, which comprises the following steps:
Step one: constituents of the composition are automatically fed and mixed according to the ratios of the constituents;
Step two: continuous mixture and stirring are performed to realize uniform mixture of the compositional constituents;
Step three: combined pressing is performed to cause bi-directional extension of the compositional constituents to form a sheet in a bonded condition;
Step four: the sheet is passed through a high density squeezing machine for further mixing and pressing of the sheet;
Step five: a five-roller compression and extension machine is used to compress and extend the sheet so as to realize bi-directional extension in both lateral and longitudinal directions;
Step six: a cooling and shaping machine is used to perform continuous compression and extension on the sheet to induce further bi-directional extension in both lateral and longitudinal direction in order to control thickness of the sheet;
Step seven: a roll-winding machine is used to automatically roll the sheet up; and
Step eight: a trimming machine is used to trim the sheet into a planar piece of paper of a desired size.
In this process, if the desired form of final paper product is a roll, then the eighth step can be omitted. The paper made in this way, after being used, can be recycled for regeneration and only the constituent of PP, which is of a minor fraction, will be consumed in combustion, so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the inorganic glass powders that are of a major fraction to return to the earth and the nature after incineration or combustion, making the present invention perfectly fit to the requirement of environmental protection.
It is noted here that the inorganic glass powder used in the composition according to the present invention is made of disposed glass articles, especially glass articles made of glass, so that it has the features of containing a single, generally pure constituent without major impurity. Thus, after the glass articles are ground to fine glass powders as a raw material, it also contains a single, generally pure constituent, this being a readily-controllable raw material and easy access of the material and helpful in handling environmental protection issue of disposed glass articles.
Another objective of the present invention is to provide a method for manufacturing eco-friendly inorganic paper, which has a ratio between longitudinal tensile strength and lateral tensile strength of 1:1 to 1:2, or 2:1 to 1:1, or 1:2 to 1:3 and a ratio between longitudinal tear strength and lateral tear strength of 1:1 to 1:2, or 2:1 to 1:1, or 1:2 to 1:3, and comprises a primary constituent of not greater than 75 wt % inorganic glass powders, which is subjected to grinding to be in a powdery form, together with 25-40 wt % bonding substance comprising polypropylene (PP) (comprising a mixture of polylactic acid (PLA) or PP and polyethylene (PE)), and 1-5 wt % assisting agents (comprising solid softening agent, activating agent, promoter, aging prevention agent, scorch prevention agent, bonding agent, heat resisting agent, initiator agent, polymerization catalyst, dispersing agent, emulsifying agent, plasticizer, heat/light stabilizer, fire retardant, mold release agent, decomposable substances (which can be starch (such as soybean powder, corn meal, casaval meal and the likes)), chitin, polycaprolactone, modifier aromatic polyesters, and the likes).
A further objective of the present invention is to provide a method for manufacturing eco-friendly inorganic paper, wherein the paper so made shows improved characteristics over the regular pulp paper in respect of foldability, stiffness, levelability, opaqueness, glossiness, and writability of ball pen, pencil, and water-based pens, and printing resolution, and has longitudinal and lateral tear strengths and tensile strength close to the regular pulp paper, and also shows the characteristics of water resistance, improved strength, perforation resistance, wear resistances, fold resistance, and vermin-eating resistance.
Yet a further objective of the present invention is to provide a method for manufacturing eco-friendly inorganic paper, wherein depending upon the assisting agents used, the paper so made can be classified as (1) biodegradable material, which is decomposed in the nature by microorganisms into carbon dioxide and water; (2) photo-degradable material, which can be decomposed by exposure to ultraviolet components contained in the sun light to break main chains of large molecules of the material to be decomposed; and (3) oxidation decomposable material, which is decomposed through oxidation of the constituent materials thereof with oxygen to form oxides.
Thus, the disposed paper can be returned to the earth, generates no toxicant gas or cause water pollution, so as to completely meet the requirement for environmental protection.
The foregoing objectives and summary provide only a brief introduction to the present invention. To fully appreciate these and other objects of the present invention as well as the invention itself, all of which will become apparent to those skilled in the art, the following detailed description of the invention and the claims should be read in conjunction with the accompanying drawings. Throughout the specification and drawings identical reference numerals refer to identical or similar parts.
Many other advantages and features of the present invention will become manifest to those versed in the art upon making reference to the detailed description and the accompanying sheets of drawings in which a preferred structural embodiment incorporating the principles of the present invention is shown by way of illustrative example.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view showing a compression and extension paper making device according to the present invention.

FIG. 2 is a schematic view showing an automatic metering machine according to the present invention.

FIG. 3 is a schematic view showing an automatic stirring and mixing machine according to the present invention.

FIG. 4 is a schematic view showing a combined sheet forming machine according to the present invention.

FIG. 5 is a schematic view showing a high-density squeezing machine according to the present invention.

FIG. 6 is a schematic view showing a five-roller compression and extension machine according to the present invention.

FIG. 7 is a schematic view showing a cooling and shaping machine according to the present invention.

FIG. 8 is a schematic view showing an automatic roll-winding machine according to the present invention.

FIG. 9 is a schematic view showing a trimming machine according to the present invention.

FIG. 10 is a schematic view showing a dual-side coating machine according to the present invention.

FIG. 11 is a schematic view showing an automatic leveling machine according to the present invention.

FIG. 12 is a schematic view showing a front surface coating machine according to the present invention.

FIG. 13 is a schematic view showing a dry type baking oven according to the present invention.

FIG. 14 is a schematic view showing a back surface coating machine according to the present invention.

FIG. 15 is a schematic view showing a paper rolling machine according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The following descriptions are exemplary embodiments only, and are not intended to limit the scope, applicability or configuration of the invention in any way. Rather, the following description provides a convenient illustration for implementing exemplary embodiments of the invention. Various changes to the described embodiments may be made in the function and arrangement of the elements described without departing from the scope of the invention as set forth in the appended claims.
Referring to FIGS. 1-9, the present invention provides a method for manufacturing eco-friendly inorganic paper, which has a composition comprising not great than 75 wt % inorganic glass powder that is subjected to grinding to be in a powdery form as a primary constituent, together with 25-40 wt % polypropylene (PP) bonding substance, which comprises a mixture of polylactic acid (PLA) or PP and polyethylene (PE), and 1-5 wt % assisting agents. The material of PP used may comprise a combination of PP and low density PE, ethylene vinyl acetate (EVA), and PLA. The assisting agents may include one or more of coupling agent, slipping agent (dispersing agent), anti-static agent, solid softening agent, activating agent, promoter, aging prevention agent, scorch prevention agent, bonding agent, heat resisting agent, initiator agent, polymerization catalyst, dispersing agent, emulsifying agent, plasticizer, heat/light stabilizer, fire retardant, and mold release agent. The coupling agent may include di(dioctyl phosphate)ethylene and/or β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane). The slipping agent may include gelatin and/or methyl cellulose. The anti-static agent may include octadecyldiethanolaminc.
In the previously discussed method for manufacturing eco-friendly inorganic paper, the composition of the eco-friendly inorganic paper uses not great than 75 wt % inorganic glass powder that is subjected to grinding to be in a powdery form as the primary constituent that can be directly deposited into a compression and extension paper making device 10. (Trimmed residuals may also be directly fed back to the machine for compression and extension, so that no waste may be generated.) The compression and extension paper making device 10 comprises an automatic metering machine 11, an automatic stirring and mixing machine 12, a combined sheet forming machine 13, a high-density squeezing machine 14, a five-roller compression and extension machine 15, a cooling and shaping machine 16, an automatic roll-winding machine 17, and a trimming machine 18. The manufacturing method comprises the following steps:
Step one: the automatic metering machine 11 performs automatic feeding and mixing of the constituents of the composition according to the ratios of the constituents to be then supplied to the automatic stirring and mixing machine 12;
Step two: the automatic stirring and mixing machine 12 performs continuous mixture and stirring of the composition to realize uniform mixture of the compositional constituents;
Step three: the well mixed composition is then directly fed to the combined sheet forming machine 13 to be subjected to combined pressing so as to cause bi-directional extension of the compositional constituents and uniform rubbing and kneading to form a sheet of the compositional constituents in a bonded condition;
Step four: the uniformly rubbed and kneaded sheet is passed through the high density squeezing machine 14 for further mixing and pressing the sheet, so as to provide the sheet with proper hardness and proper tension;
Step five: the five-roller compression and extension machine 15 is used for reversely turning and shaping the sheet and to realize bi-directional extension of the sheet in both lateral and longitudinal directions;
Step six: the cooling and shaping machine 16 is used to perform continuous compression and extension on the sheet to induce further bi-directional extension of the sheet in both lateral and longitudinal direction and to control thickness of the sheet;
Step seven: the roll-winding machine 17 is used to automatically roll the paper sheet up in the form of a paper roll; and
Step eight: the trimming machine 18 is used to trim the paper sheet into a planar piece of paper of a desired size.
According to the method for manufacturing eco-friendly inorganic paper of the present invention, the following categories can be made depending upon the assisting agents used:
(1) Biodegradable material, which is decomposed in the nature by microorganisms into carbon dioxide and water;
(2) Photo-degradable material, which can be decomposed by exposure to ultraviolet components contained in the sun light to break main chains of large molecules of the material to be decomposed; and
(3) Oxidation decomposable material, which is decomposed through oxidation of the constituent materials thereof with oxygen to form oxides. Thus, any disposed paper can be recycled for regeneration and only the constituent of PP, which is of a minor fraction, will be consumed in combustion, so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the natural inorganic minerals that are of a major fraction to return to the earth and the nature after combustion, making the present invention perfectly fit to the requirement of environmental protection.
Further, in the method for manufacturing eco-friendly inorganic paper according to the present invention, the five-roller compression and extension machine 15 used in the fifth step is operated by employing high temperature compression and extension and the temperature employed can be adjusted according to the characteristics of the composition formula so as to effectively realize melting, mixture, and bi-directional extension of the composition. The cooling and shaping machine 16 used in the sixth step is adjustable for compression time according to the desired thickness and product property. In the previous process, if the desired form of final paper product is a paper roll, then the eighth step can be omitted.
Further, according to paper thickness and property, the eco-friendly inorganic paper made according to the manufacturing method of the present invention can be used, after further and proper processing, to make monthly calendar, almanac, hanging scroll, map, notebook, instruction leaflet, business log, letter paper, book, commercial marks, poster, label, various hand-carrying bags, wrapping paper, art and craft material, wall paper, surface cover for woven bag, release paper, heat-sealing package bag, backing adhesive label paper, surface bonding material, atlas, self-adhesive mark, shopping bag, various hand bags, wall paper, newspaper and loose leaf paper, shinning paper, and education material.
Referring to FIGS. 10-15, the eco-friendly inorganic paper according to the present invention can be processed to form a coating layer on a surface thereof, and the coating can be formed of a water-based solution or an oil-based solution. For the case where a water-based solution is used to form the coating, the composition of the water-based coating solution may comprise acrylic resin, isoprophy alcohol, polyvinyl alcohol, clay, anti-static agent, 28% ammonia liquor, pure water, and vinyl acetate. A dual-side coating machine 20 is used to deposit a non-coated paper sheet into an automatic leveling machine 21 to have the sheet dragged and leveled for subsequent performance of corona treatment, whereby the two surfaces of the paper sheet, after being treated with high voltage discharging, form a plurality of tiny voids, which help improving bonding force for the coating applied to the surface (the surface treatment being selectively thermal fusion coating, fluent spraying, flame spraying, plasma spraying, and electrostatic spraying). The paper sheet is conveyed to a front surface coating machine 22 for initial coating, and then the paper sheet is conveyed to a dry type baking oven 23 to have the surfaces thereof dried for subsequent coating on the opposite surface. A back surface coating machine 24 uses a plurality of spraying nozzles to control the amount of coating solution sprayed and realize coating on the opposite surface. The paper sheet is then conveyed to the dry type baking oven 23 to dry the coated surface, whereby under the condition of being heated, the coated surface of the paper sheet can be quickly dried and shows a shining face on the paper surface.
Further, for frosting treatment of the coated surface of the paper sheet, a frosting roller is employed to compress the paper sheet so that the dried smooth coated surface of the paper sheet is converted into a frosted surface. Then, a paper rolling machine 25 is used to roll up the coated paper sheet into a paper roll.
It will be understood that each of the elements described above, or two or more together may also find a useful application in other types of methods differing from the type described above.
While certain novel features of this invention have been shown and described and are pointed out in the annexed claim, it is not intended to be limited to the details above, since it will be understood that various omissions, modifications, substitutions and changes in the forms and details of the device illustrated and in its operation can be made by those skilled in the art without departing in any way from the spirit of the present invention.

Claims

I claim:

1. A method for manufacturing eco-friendly inorganic paper, which has a composition comprising not greater than 75 wt % inorganic glass powder that is subjected to grinding to be in a powdery form as a primary constituent, together with 25-40 wt % polypropylene (PP), which comprises a mixture of polylactic acid (PLA) or PP and polyethylene (PE)), and 1-5 wt % assisting agents, wherein the composition is directly deposited into a compression and extension paper making device, which comprises an automatic metering machine, an automatic stirring and mixing machine, a combined sheet forming machine, a high-density squeezing machine, a five-roller compression and extension machine, and a cooling and shaping machine, the method comprising the following steps:

step one: the automatic metering machine performs automatic feeding and mixing of the constituents of the composition according to the ratios of the constituents to be then supplied to the automatic stirring and mixing machine;

step two: the automatic stirring and mixing machine performs continuous mixture and stirring of the composition to realize uniform mixture of the compositional constituents;

step three: the well mixed composition is then directly fed to the combined sheet forming machine to be subjected to combined pressing so as to cause bi-directional extension of the compositional constituents and uniform rubbing and kneading to form a sheet of the compositional constituents in a bonded condition;

step four: the uniformly rubbed and kneaded sheet is passed through the high density squeezing machine for further mixing and pressing the sheet, so as to provide the sheet with proper hardness and proper tension;

step five: the five-roller compression and extension machine is used for reversely turning and shaping the sheet and to realize bi-directional extension of the sheet in both lateral and longitudinal directions; and

step six: the cooling and shaping machine is used to perform continuous compression and extension on the sheet to induce further bi-directional extension of the sheet in both lateral and longitudinal direction and to control thickness of the sheet.

2. The method according to claim 1, wherein the compression and extension paper making device further comprises an automatic roll-winding machine and a trimming machine, whereby the sheet formed in step six is wound by using the automatic roll-winding machine and the trimmed to a planar piece of paper of desired size by the trimming machine.

3. The method according to claim 1, wherein the five-roller compression and extension machine of step five is operated by employing high temperature compression and extension and the temperature employed is adjustable according to the characteristics of the composition of the paper so as to effectively realize melting, mixture, and bi-directional extension of the composition of mineral paper.

4. The method according to claim 1, wherein the cooling and shaping machine of step six is adjustable for compression time according to desired thickness and product property of the paper.

5. The method according to claim 1, wherein the sheet formed in step six is further subjected to surface coating of an oil-based coating solution.

6. The method according to claim 1, wherein the sheet formed in step six is further subjected to surface coating of a water-based coating solution through use of a dual-side coating machine to deposit a non-coated paper sheet into an automatic leveling machine to have the sheet dragged and leveled for subsequent performance of corona treatment, whereby two surfaces of the paper sheet, after being treated with high voltage discharging, form a plurality of tiny voids, which help improving bonding force for the coating applied to the surface (the surface treatment being selectively thermal fusion coating, fluent spraying, flame spraying, plasma spraying, and electrostatic spraying); the paper sheet is conveyed to a front surface coating machine for initial coating, and then the paper sheet is conveyed to a dry type baking oven to have the surfaces thereof dried for subsequent coating on the opposite surface; a back surface coating machine uses a plurality of spraying nozzles to control the amount of coating solution sprayed and realize coating on the opposite surface; and the paper sheet is then conveyed to the dry type baking oven to dry the coated surface, whereby under the condition of being heated, the coated surface of the paper sheet is quickly dried and shows a shining face on the paper surface.