US20130037556A1 - Packaging for a tea pouch - Google Patents
Packaging for a tea pouch Download PDFInfo
- Publication number
- US20130037556A1 US20130037556A1 US13/521,021 US201113521021A US2013037556A1 US 20130037556 A1 US20130037556 A1 US 20130037556A1 US 201113521021 A US201113521021 A US 201113521021A US 2013037556 A1 US2013037556 A1 US 2013037556A1
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- United States
- Prior art keywords
- layer
- coextrusion
- packaging
- vinyl alcohol
- ethylene vinyl
- Prior art date
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- Abandoned
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/327—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
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- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
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- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
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- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/546—Flexural strength; Flexion stiffness
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7244—Oxygen barrier
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7248—Odour barrier
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31739—Nylon type
- Y10T428/31743—Next to addition polymer from unsaturated monomer[s]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31895—Paper or wood
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
- Y10T428/3192—Next to vinyl or vinylidene chloride polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Definitions
- This disclosure relates to packaging and, in particular, to packaging for use in a tea pouch.
- Packaging particularly for perishable items such as tea, is subject to many demands.
- the packaging for tea pouches must be capable of providing an oxygen and aroma barrier to prevent the tea contained within the pouch from spoiling and losing flavor before the pouch is open.
- the packaging should be workable in such a way that the packaging can be quickly placed around the tea bag using machinery.
- the packaging must run well in packaging machines, such as those made by Industria Macchine Automatiche (IMA), which run at line speeds of up to 400 bags/min.
- IMA Industria Macchine Automatiche
- the temperature and pressure must be sufficiently high (typically in the range of 160° C. to 180° C. and 70 psi) to quickly form the seal in the brief amount of time that the packaging machine affords.
- the sealant resin on the inside of the tea pouch may squeeze out of the periphery of the pouch. The squeezed out resin builds up on the heat seal jaws resulting in excessive waste of material and requiring periodic downtime to clean the machine.
- Aluminum foil gives the paper-based pouch structure excellent barrier properties as well as stiffness and deadfold properties which translate to good efficiencies on the high speed packaging machines.
- aluminum foil has a very large carbon footprint and is expensive. Aluminum foil prices can swing up and down based on the energy costs associated with the production of thin aluminum foil and the sealant resin used on foil pouches is comparatively expensive when compared to other resins.
- PVDC polyvinylidene chloride
- the packaging includes an ethylene vinyl alcohol (EVOH) layer which is directly attached to a paper substrate.
- EVOH ethylene vinyl alcohol
- the EVOH layer can be formed as part of an asymmetrical coextrusion with a two resin capable coextruder, which makes the packaging inexpensive to produce.
- EVOH has conventionally been considered unsuitable for this type of packaging because in order to prevent degradation of the EVOH, the EVOH needed to be sandwiched between layers including moisture barriers such as LDPE (low density poly ethylene).
- LDPE low density poly ethylene
- Conventional EVOH coextrusion has been done using a symmetrical three resin, five layer design such as LDPE-Tie.
- Resin-EVOH-Tie Resin-LDPE The LDPE and Tie Resin materials are extruded separately and directed into a feedblock device that splits them both into two separate layers on each side of the EVOH layer. When extrusion coated onto paper, the inner LDPE and Tie Resin layers would be disposed between the paper and EVOH.
- a packaging for a tea pouch includes a paper substrate and a coextrusion including an ethylene vinyl alcohol layer.
- the ethylene vinyl alcohol layer is directly attached to the paper substrate. Since the melting point of EVOH (178 degrees C.) is greater than the commonly used set-point temperatures of the heat seal jaws (160 degrees C. to 170 degrees C.), the EVOH layer does not melt and does not squeeze out. All of the heat put into the structure can go into melting just the sealant layer or layers.
- the ethylene vinyl alcohol layer may be directly attached to the paper substrate along a paper substrate—ethylene vinyl alcohol layer interface.
- the coextrusion may include a tie resin and a sealant resin as a blend or as separate layers.
- the coextrusion further includes a tie sealant resin blend (TSRB) layer on the side of the ethylene vinyl alcohol layer not directly attached to the paper substrate.
- TSRB tie sealant resin blend
- the coextrusion includes a tie resin layer and a sealant layer.
- the tie resin layer is disposed at least in part between the ethylene vinyl alcohol layer and the sealant layer.
- the paper substrate may include cellulosic fibers and various types of paper may be suitable for use as the substrate.
- a polymeric barrier layer may be attached to a side of the paper substrate that is not directly attached to the coextrusion.
- Another paper layer may be attached to the polymeric barrier layer such that the polymeric barrier layer is sandwiched between the paper substrate and the other paper layer.
- this polymeric barrier layer may be polyethylene or polypropylene.
- the paper substrate and/or the polymeric barrier layer may have a treated surface.
- the treated surface can promote adhesion of the ethylene vinyl alcohol layer to the paper substrate and/or the polymeric barrier layer to the paper layers.
- Such treatments could potentially include flame treatment, liquid priming, or corona treatment.
- a coextrusion face of the packaging may be heat sealable to another coextrusion face of the packaging without substantial amounts of squeeze out at a rate of 400 units/minute or higher in a packaging machine, such as those made by Industria Macchine Automatiche (IMA).
- IMA Industria Macchine Automatiche
- the ethylene vinyl alcohol layer may have a melting temperature (178 degrees C.) in excess of a sealant layer (90 to 100 degrees C.) of the coextrusion containing a tie resin.
- the coextrusion may be formable using a two resin capable coextruder and may be asymmetrical.
- most EVOH extrusions are symmetrical and include moisture barrier layers on both sides of the EVOH, as the barrier properties of EVOH can degrade when exposed to humidity levels above 85% RH.
- symmetric coextrusions of EVOH can require multiple coextruders or coextruders capable of extruding more than two resins. This has made conventional symmetrical coextrusions of EVOH very costly to produce.
- the ethylene vinyl alcohol layer may include ethylene in a range of 24 to 48 mole percent, and preferably 35 mole percent ethylene.
- a method of making packaging for a tea pouch includes providing a paper substrate, extruding a coextrusion including a layer of ethylene vinyl alcohol, and attaching the coextrusion onto the paper substrate such that the layer of ethylene vinyl alcohol is directly attached to the paper substrate.
- the method may further include the step of treating a surface of the paper substrate to be attached to the layer of ethylene vinyl alcohol before attaching the coextrusion, thereby promoting adhesion between the paper substrate and the coextrusion.
- the treatment may include flame treating, liquid priming, and/or corona treating the surface.
- the coextrusion includes a layer of tie sealant resin blend (TSRB) coextruded with the layer of ethylene vinyl alcohol. If a blend is coextruded with the ethylene vinyl alcohol, then the extrusion step may be performed with a two resin capable extruder. In other forms, the coextrusion may include a layer of tie resin and a separate layer of sealant coextruded with the layer of ethylene vinyl alcohol. In either of these forms, the coextrusion may be asymmetrical.
- TSRB tie sealant resin blend
- the paper substrate may be further modified by attaching a polymeric layer and another paper layer to a side of the paper substrate not attached to the coextrusion such that the polymeric layer is sandwiched between the paper substrate and the other paper layer thereby forming an improved barrier to moisture that could degrade the ethylene vinyl alcohol.
- a tea pouch may be made using a packaging of the type described herein.
- the tea pouch includes at least one ply of packaging comprising a paper substrate and a coextrusion with an ethylene vinyl alcohol layer in which the ethylene vinyl alcohol layer is directly attached to the paper substrate and the coextrusion further has a tie resin and a sealant.
- a seal is formed about at least a portion of the periphery of the tea pouch to form an inner volume for storage of a tea product. This seal is formed by the application of heat and pressure to the at least one ply of packaging.
- the packaging of this tea pouch may be further defined to have the features described above or disclosed hereafter.
- FIGS. 1 through 4 are four exemplary embodiments of packaging for tea pouches
- FIG. 5 is a schematic illustrating a method of making packaging for tea pouches
- FIG. 6 is a plan view of an exemplary tea pouch.
- FIG. 7 is a cross-sectional view taken through line 6 - 6 of FIG. 6 .
- Ethylene vinyl alcohol is an extrudable resin that has excellent oxygen, flavor, and aroma barrier properties.
- EVOH resins and packaging materials have been used for several decades as meat and cheese film wrappers and its barrier properties with respect to oxygen, grease, oil, flavor additives, and aroma are well understood.
- EVOH when exposed to humidity levels of 85% or higher, the barrier properties of EVOH degrade.
- EVOH is typically extruded in a multi-layer coextrusion in which specialized tie resins are used to adhere the EVOH to outer polyolefin layers that protect the EVOH from humidity.
- a five layer coextrusion of EVOH may include LDPE-Tie Resin-EVOH-Tie Resin-LDPE.
- the LDPE layers protect the EVOH layer from exposure to moisture and, hence, degradation.
- EVOH cannot be extruded as a separate thin film. When melted, EVOH becomes fluid very quickly. Thus, EVOH has traditionally required the above-described five layer structure not only to maintain barrier properties, but also to provide adjacent structural layers (such as polyethylene) to support the coextrusion of the EVOH.
- EVOH has excellent barrier properties
- EVOH has heretofore been considered unsuitable as a barrier layer in some paper based applications.
- Production of EVOH has required extrusion machines capable of coextruding more than two resins. Such machines are very expensive and not as common as those extruding only two resins.
- a heat sealed paper packaging product incorporating EVOH would have unacceptably high levels of “squeeze out” during packaging as a result of the melting of the various LDPE barrier layers and tie resins. As mentioned above, squeeze out results in the build up of polymeric material on the packaging machine components which requires costly downtime to clean.
- a “-” is used to indicate layers that are coextruded with one another and a “/” is used to indicate layers that are separated attached to one another (for example, by lamination).
- FIGS. 1 through 4 a number of the packaging structures that may be used for the tea pouch stock are disclosed including:
- a packaging 100 includes a paper substrate 102 and a coextrusion 104 including an ethylene vinyl alcohol layer 106 and a tie sealant resin blend layer 108 .
- the ethylene vinyl alcohol layer 106 of the coextrusion 104 is directly attached to the paper substrate 102 along a paper substrate—ethylene vinyl alcohol layer interface 110 .
- a packaging 200 again includes a paper substrate 202 with a coextrusion 204 .
- the coextrusion 204 includes an ethylene vinyl alcohol layer 206 , a tie resin layer 212 , and a sealant layer 214 .
- the ethylene vinyl alcohol layer 206 is directly attached to the paper substrate 202 along a paper substrate—ethylene vinyl alcohol layer interface 210 .
- the other layers are arranged such that the tie resin layer 212 is sandwiched between the ethylene vinyl alcohol layer 206 and the sealant layer 214 .
- the sealant layer 214 is disposed such that it is on an attachment face (i.e., a face that will be attached to another face of the packaging) when the packaging is heat sealed to form a tea pouch.
- FIG. 3 is generally similar to FIG. 1 and FIG. 4 is generally similar to FIG. 2 , except that in FIGS. 3 and 4 an additional polymeric barrier layer 316 or 416 and another paper layer 318 or 418 are attached to the other side of the paper substrate 302 or 402 , respectively.
- the EVOH coextrusion is asymmetrical in all forms, unlike the LDPE-Tie Resin-EVOH-Tie Resin-LDPE structures which have been previously produced.
- the EVOH is directly attached to a paper layer, the elimination of the tie resin-LDPE layers on the left side of the EVOH (of the listed structures) reduce the amount of squeeze out that is likely to occur during heat seal in an IMA machine or the like.
- the paper substrate may serve as a barrier to moisture to protect the EVOH layer.
- the thickness of the EVOH layer may be increased in comparison to the EVOH layer thickness in a standard symmetrical coextrusion.
- an interpaper layer of a polymeric barrier layer such as polyethylene or polypropylene may be employed.
- the third and fourth structures have the best barrier properties for both water vapor transmission and oxygen transmission.
- using two thinner layers of paper is more expensive.
- the laminate resin layer would preferably be high density polyethylene (HDPE), polypropylene (PP), or another material with a high melting point polymeric material to prevent squeeze-out issues.
- EVOH melts at a much higher temperature than the TSRB (EVOH melts at around 178 degrees C., while the TSRB melts in the range of 90-100 degrees C. depending on the blend). Accordingly, the EVOH itself also resists squeeze out when heat seal jaws of the packaging machines are set at 160 degrees C.
- the tea pouch packaging has a structure of 35#PAPER/4#EVOH-7#TSRB (#/ream based on 3,000 ft 2 ream size).
- the 35#/ream PAPER may be Kraft paper with a machine glaze type finish and bleached white color.
- the paper may be flame treated for good adhesion of the 4#EVOH-7#TSRB coextrusion to the paper.
- the 4#EVOH-7#TSRB layers are coextruded from a single die.
- the EVOH may be 35 mol % ethylene EVOH (available as EVAL C109B) and the TSRB may be 50% POP (polyolefin plastomer, available as DOW PT1450), 25% tie resin (such as ADMER AT1000A), and 25% LDPE (low-density polyethylene, available as CHEVRON 4517).
- POP polyolefin plastomer, available as DOW PT1450
- 25% tie resin such as ADMER AT1000A
- LDPE low-density polyethylene
- the packaging for the tea pouch made according to structure ( 2 ) above may have a structure of 35#PAPER/4#EVOH-1.5#Tie Resin-5.5#Sealant.
- the packaging for the tea pouch made according to structures ( 3 ) and ( 4 ) in which two papers are laminated together may have a total paper basis weight of 30#/ream (3,000 ft 2 ) and a lamination polymer basis weight of 6#/ream.
- the two paper layers may each have a separate basis weight of 15#/ream, although they might be uneven or differently distributed.
- the total weight basis and thickness of the structures are substantially the same. It is contemplated that as the intermediate lamination polymer is a polymeric barrier layer to moisture, then the EVOH basis weight may be reduced to 3#/ream since there is additional protection to humidity on the paper side.
- the paper may be a type having a machine glazed (MG) or a machine finished (MF) type finish, may be of a white or a natural color, and may be of a Kraft, ground wood, recycled, or sulfite furnish. Clay coated paper may also be used.
- the paper may include laminations of one or more layers of paper or include a PET, Nylon, OPP, or PLA film laminated to the paper.
- the basis weight of the paper substrate can range from 10#/ream to 60#/ream.
- EVOH is available in 24% ethylene to 48% ethylene content. It is contemplated that any amount of ethylene content might be used or selected based on the desired properties of the barrier or for appropriate economy. Generally speaking, the lower the ethylene content, the better the aroma and oxygen barrier. It is contemplated that the basis weight of the EVOH layer may be in the range of 0.1#/3,000 ft 2 to 10.0#/3,000 ft 2 .
- the TSRB may have a tie resin content from 10 wt % to 80 wt % and a polyethylene content from 20 wt % to 90 wt %.
- the tie resin may be an anhydride modified LDPE based adhesive resin concentrates such as ADMER AT1000A or DUPONT BYNEL 41E170.
- the polyethylene sealant resin may be LDPE, MDPE, HDPE, LLDPE, POP, mLLDPE and blends thereof, and copolymers of PE such as, for example: EVA, IONOMER, EAA, EMAA, EMAC, EnBA, and the like.
- TSRB can be further modified with slip, antiblock, or color concentrates depending upon customer needs.
- the particular tie sealant resin blend selected may be tweaked to minimize the amount of squeeze out that occurs during heat sealing at high temperatures and pressures, while simultaneously maximizing the quality of the seal.
- the basis weight of the TSRB layer may be in the range of 1.0#/3,000 ft 2 to 20.0#/3,000 ft 2 and modified to provide enough TSRB material to form a robust seal without including so much material so as to induce squeeze out.
- EVOH is not extruded as its own single layer, but needs to be coextruded with the TSRB.
- Another suitable alternative is to extrude an asymmetric three layer coextrusion, such as in the second and fourth structures, in which the tie and sealant resins are not blended.
- a benefit of using the TSRB instead of the three layer coextrusion is that a three resin capable coextruder is not required.
- a line 500 for making the packaging is disclosed.
- the line 500 illustrated is suitable for making any of the structures ( 1 )-( 4 ) listed above.
- segments of the line 500 may be eliminated or not used based on the desired structure of the final product.
- the line 500 includes two sections.
- the first section provides the paper substrate layer or forms a laminate including the paper layers with the polymeric barrier layer disposed there between.
- the second section then applies the EVOH coextrusion to the substrate.
- the first section of the line 500 is shown for the preparation of structures shown in FIGS. 3 and 4 , which include a paper/polymeric barrier layer/paper lamination.
- paper is separately unrolled from a main substrate roll 502 and an auxillary substrate roll 504 and fed toward an extrusion laminator 506 which inserts the polymeric barrier layer between the two paper layers.
- the paper from the main substrate roll 502 is fed past a treater 508 such as a flame treater or a corona treater that treats the surface of the paper from the main substrate roll 502 such that the polymeric barrier layer created at the extrusion laminator 506 will adhere well to the paper layer.
- a treater 508 such as a flame treater or a corona treater that treats the surface of the paper from the main substrate roll 502 such that the polymeric barrier layer created at the extrusion laminator 506 will adhere well to the paper layer.
- the paper from the auxiliary substrate roll 504 is fed past a treater 509 such as a flame treater or a corona treater that treats the surface of the paper from the auxiliary substrate roll 504 such that the polymeric barrier layer created at the extrusion laminator 506 will also adhere well to this paper layer.
- a treater 509 such as a flame treater or a corona treater that treats the surface of the paper from the auxiliary substrate roll 504 such that the polymeric barrier layer created at the extrusion laminator 506 will also adhere well to this paper layer.
- the paper layers meet at a nip point at which point the polymeric barrier layer is inserted between the paper layers.
- the nip point occurs between a rubber nip roll 510 and a chill roll 512 .
- the paper layers approach the nip point from different angles and in the space between where the paper layers meet and at a location above the nip point, a die 514 supplies a molten resin A (which may be, for example, polyethylene or polypropylene) as a melt curtain between the paper layers.
- a molten resin A which may be, for example, polyethylene or polypropylene
- This molten resin A is pressed between the paper layers at the nip point, is cooled to form a paper/polymeric barrier layer/paper structure found in FIGS. 3 and 4 , and exits the extrusion laminator 506 .
- the line 500 is shown including the extrusion laminator 506 for the formation of the paper/polymeric barrier layer/paper structure of structures ( 3 ) or ( 4 ), that if the structures ( 1 ) or ( 2 ) are being formed then the extrusion laminator 506 may be eliminated and the first section of the line 500 could simply be a main substrate roll that unrolls to provide the paper substrate.
- the substrate may then be optionally fed past a treater 516 that treats the surface of the paper substrate for better adhesion to the coextrusion further down the line 500 .
- the treater 516 may incorporate a flame treatment, liquid priming, or a corona treatment to prepare the surface of the paper substrate.
- a coextrusion coater 518 applies or coats the paper substrate with the EVOH coextrusion to form the packaging.
- the paper substrate is fed between a rubber nip roll 520 and a chill roll 522 .
- a feedblock 524 of the coextruder 526 receives molten EVOH and at least one other molten resin B and/or C.
- the molten TSRB is also fed into the feedblock 524 (as B, with no C resin being fed) and a two layer coextrusion of EVOH-TSRB is extruded by the die 528 proximate the nip point such that the EVOH layer side contacts the paper substrate.
- the coextruder 526 may be only a two resin capable coextruder.
- the feedblock 524 receives both a molten tie resin (as B) and a molten sealant (as C) and the die 528 extrudes an EVOH-Tie-Sealant coextrusion such that the EVOH layer is applied to the paper substrate.
- the packaging is wound up on a product wind-up roll 530 .
- an exemplary tea pouch 600 is illustrated that has been made by heat sealing a ply of the paper/EVOH-TSRB packaging 100 .
- the tea pouch 600 is formed by folding a single ply of the packaging in half at a fold line 602 such that the TSRB layer 108 on either side of the fold line 602 face one another and a tea bag 604 is disposed between the two halves.
- a U-shaped seal 606 is then formed around a portion of the periphery 608 of the tea pouch 600 by use of heat and pressure from a packaging machine such as the IMA machine above to seal the two TSRB layers 106 together.
- the seal 606 and the fold line 602 completely surround the tea bag 604 such that the tea bag 604 is entirely contained with an inner volume 610 of the tea pouch 600 .
- tea pouch is shown formed from a single ply of packaging which has been folded and a portion of the periphery has been heat sealed, it should be appreciated that two separate plies of packaging could be sealed around their entire periphery to establish the inner volume for receiving the tea bag such that no fold is required. Additionally, while a tea pouch formed from the paper/EVOH-TSRB structure has been illustrated in FIGS. 6 and 7 , it will be appreciated that any structures ( 1 )-( 4 ) could be sealed (either at the TSRB surface or sealant surface) under heat and pressure to make the tea pouch.
Abstract
Description
- This patent application claims priority to U.S. provisional patent application Ser. No. 61/296,321 titled “Packaging Materials” and filed on Jan. 19, 2010. The full contents of that application is incorporated by reference as if set forth in its entirety herein.
- Not applicable.
- This disclosure relates to packaging and, in particular, to packaging for use in a tea pouch.
- Packaging, particularly for perishable items such as tea, is subject to many demands. For example, the packaging for tea pouches must be capable of providing an oxygen and aroma barrier to prevent the tea contained within the pouch from spoiling and losing flavor before the pouch is open. At the same time, however, the packaging should be workable in such a way that the packaging can be quickly placed around the tea bag using machinery.
- The packaging must run well in packaging machines, such as those made by Industria Macchine Automatiche (IMA), which run at line speeds of up to 400 bags/min. At these high line speeds, to form a heat seal, the temperature and pressure must be sufficiently high (typically in the range of 160° C. to 180° C. and 70 psi) to quickly form the seal in the brief amount of time that the packaging machine affords. Unfortunately, at these temperatures and pressures, the sealant resin on the inside of the tea pouch may squeeze out of the periphery of the pouch. The squeezed out resin builds up on the heat seal jaws resulting in excessive waste of material and requiring periodic downtime to clean the machine.
- Traditionally, aluminum foil or metallized films have been employed in tea pouch packaging. Aluminum foil gives the paper-based pouch structure excellent barrier properties as well as stiffness and deadfold properties which translate to good efficiencies on the high speed packaging machines. However, aluminum foil has a very large carbon footprint and is expensive. Aluminum foil prices can swing up and down based on the energy costs associated with the production of thin aluminum foil and the sealant resin used on foil pouches is comparatively expensive when compared to other resins.
- Although polymeric substitutes for Al foil or metallized films have been considered, many polymers are more prone to the squeeze out described above and present other environmental and usability concerns. One alternative to foil based packaging, PVDC (polyvinylidene chloride), has been considered as a barrier layer or as a coating on films. However, the use of PVDC is highly regulated and/or banned in many countries due to environmental concerns upon incineration. Additionally, many users complain that packaging made with oriented films is difficult to tear open, even when notches are provided on the tea pouch to initiate a tear.
- Hence, there is a continuing need for an improved packaging that maintains product freshness without presenting cost, processing, or post-use concerns.
- Packaging for a tea pouch, a method of making such packaging, and a tea pouch made from such packaging is disclosed. The packaging includes an ethylene vinyl alcohol (EVOH) layer which is directly attached to a paper substrate. In some preferred forms, the EVOH layer can be formed as part of an asymmetrical coextrusion with a two resin capable coextruder, which makes the packaging inexpensive to produce.
- As will be described in more detail below, EVOH has conventionally been considered unsuitable for this type of packaging because in order to prevent degradation of the EVOH, the EVOH needed to be sandwiched between layers including moisture barriers such as LDPE (low density poly ethylene). Conventional EVOH coextrusion has been done using a symmetrical three resin, five layer design such as LDPE-Tie. Resin-EVOH-Tie Resin-LDPE. The LDPE and Tie Resin materials are extruded separately and directed into a feedblock device that splits them both into two separate layers on each side of the EVOH layer. When extrusion coated onto paper, the inner LDPE and Tie Resin layers would be disposed between the paper and EVOH. When formed into a tea pouch and heat sealed, heat is applied to the paper side, thus the inner LDPE and Tie Resin layers must melt before the outer LDPE and Tie Resin layers. This premature melting of the inner polymeric layers makes the structure prone to excessive amounts of squeeze-out. This collected material would need to be cleaned from the jaws and require frequent downtime.
- A packaging for a tea pouch is disclosed. The packaging includes a paper substrate and a coextrusion including an ethylene vinyl alcohol layer. The ethylene vinyl alcohol layer is directly attached to the paper substrate. Since the melting point of EVOH (178 degrees C.) is greater than the commonly used set-point temperatures of the heat seal jaws (160 degrees C. to 170 degrees C.), the EVOH layer does not melt and does not squeeze out. All of the heat put into the structure can go into melting just the sealant layer or layers.
- In some forms, the ethylene vinyl alcohol layer may be directly attached to the paper substrate along a paper substrate—ethylene vinyl alcohol layer interface. The coextrusion may include a tie resin and a sealant resin as a blend or as separate layers. In one form, the coextrusion further includes a tie sealant resin blend (TSRB) layer on the side of the ethylene vinyl alcohol layer not directly attached to the paper substrate. In another form, on a side of the ethylene vinyl alcohol layer not directly attached to the substrate, the coextrusion includes a tie resin layer and a sealant layer. In this form, the tie resin layer is disposed at least in part between the ethylene vinyl alcohol layer and the sealant layer.
- The paper substrate may include cellulosic fibers and various types of paper may be suitable for use as the substrate. To provide an improved moisture barrier and to prevent the degradation of the ethylene vinyl alcohol layer, a polymeric barrier layer may be attached to a side of the paper substrate that is not directly attached to the coextrusion. Another paper layer may be attached to the polymeric barrier layer such that the polymeric barrier layer is sandwiched between the paper substrate and the other paper layer. In some forms, this polymeric barrier layer may be polyethylene or polypropylene.
- The paper substrate and/or the polymeric barrier layer may have a treated surface. The treated surface can promote adhesion of the ethylene vinyl alcohol layer to the paper substrate and/or the polymeric barrier layer to the paper layers. Such treatments could potentially include flame treatment, liquid priming, or corona treatment.
- A coextrusion face of the packaging may be heat sealable to another coextrusion face of the packaging without substantial amounts of squeeze out at a rate of 400 units/minute or higher in a packaging machine, such as those made by Industria Macchine Automatiche (IMA). The ethylene vinyl alcohol layer may have a melting temperature (178 degrees C.) in excess of a sealant layer (90 to 100 degrees C.) of the coextrusion containing a tie resin. By reducing the amount of squeeze out, the packaging can be run through packaging machines at higher speeds with less machine downtime being need to clean heat seal jaws or other tool parts.
- The coextrusion may be formable using a two resin capable coextruder and may be asymmetrical. Notably, most EVOH extrusions are symmetrical and include moisture barrier layers on both sides of the EVOH, as the barrier properties of EVOH can degrade when exposed to humidity levels above 85% RH. However, symmetric coextrusions of EVOH can require multiple coextruders or coextruders capable of extruding more than two resins. This has made conventional symmetrical coextrusions of EVOH very costly to produce.
- To provide an effective barrier, the ethylene vinyl alcohol layer may include ethylene in a range of 24 to 48 mole percent, and preferably 35 mole percent ethylene.
- A method of making packaging for a tea pouch is also disclosed which includes providing a paper substrate, extruding a coextrusion including a layer of ethylene vinyl alcohol, and attaching the coextrusion onto the paper substrate such that the layer of ethylene vinyl alcohol is directly attached to the paper substrate.
- The method may further include the step of treating a surface of the paper substrate to be attached to the layer of ethylene vinyl alcohol before attaching the coextrusion, thereby promoting adhesion between the paper substrate and the coextrusion. Again, the treatment may include flame treating, liquid priming, and/or corona treating the surface.
- In one form, the coextrusion includes a layer of tie sealant resin blend (TSRB) coextruded with the layer of ethylene vinyl alcohol. If a blend is coextruded with the ethylene vinyl alcohol, then the extrusion step may be performed with a two resin capable extruder. In other forms, the coextrusion may include a layer of tie resin and a separate layer of sealant coextruded with the layer of ethylene vinyl alcohol. In either of these forms, the coextrusion may be asymmetrical.
- The paper substrate may be further modified by attaching a polymeric layer and another paper layer to a side of the paper substrate not attached to the coextrusion such that the polymeric layer is sandwiched between the paper substrate and the other paper layer thereby forming an improved barrier to moisture that could degrade the ethylene vinyl alcohol.
- A tea pouch may be made using a packaging of the type described herein. The tea pouch includes at least one ply of packaging comprising a paper substrate and a coextrusion with an ethylene vinyl alcohol layer in which the ethylene vinyl alcohol layer is directly attached to the paper substrate and the coextrusion further has a tie resin and a sealant. A seal is formed about at least a portion of the periphery of the tea pouch to form an inner volume for storage of a tea product. This seal is formed by the application of heat and pressure to the at least one ply of packaging.
- The packaging of this tea pouch may be further defined to have the features described above or disclosed hereafter.
- The foregoing and still other advantages of the invention will appear from the following description. In that description reference is made to the accompanying drawings which form a part hereof and in which there is shown by way of illustration preferred embodiments of the invention. These embodiments do not represent the full scope of the invention. Rather, the claims should be looked to in order to judge the full scope of the invention.
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FIGS. 1 through 4 are four exemplary embodiments of packaging for tea pouches; -
FIG. 5 is a schematic illustrating a method of making packaging for tea pouches; -
FIG. 6 is a plan view of an exemplary tea pouch; and -
FIG. 7 is a cross-sectional view taken through line 6-6 ofFIG. 6 . - Ethylene vinyl alcohol (EVOH) is an extrudable resin that has excellent oxygen, flavor, and aroma barrier properties. EVOH resins and packaging materials have been used for several decades as meat and cheese film wrappers and its barrier properties with respect to oxygen, grease, oil, flavor additives, and aroma are well understood.
- However, when exposed to humidity levels of 85% or higher, the barrier properties of EVOH degrade. To avoid this, EVOH is typically extruded in a multi-layer coextrusion in which specialized tie resins are used to adhere the EVOH to outer polyolefin layers that protect the EVOH from humidity. For example, a five layer coextrusion of EVOH may include LDPE-Tie Resin-EVOH-Tie Resin-LDPE. In this five layer structure, the LDPE layers protect the EVOH layer from exposure to moisture and, hence, degradation.
- It should further be appreciated that EVOH cannot be extruded as a separate thin film. When melted, EVOH becomes fluid very quickly. Thus, EVOH has traditionally required the above-described five layer structure not only to maintain barrier properties, but also to provide adjacent structural layers (such as polyethylene) to support the coextrusion of the EVOH.
- Although EVOH has excellent barrier properties, EVOH has heretofore been considered unsuitable as a barrier layer in some paper based applications. Production of EVOH has required extrusion machines capable of coextruding more than two resins. Such machines are very expensive and not as common as those extruding only two resins. Further, given the dual tie resin and polyolefin layers deemed necessary to protect each side of the EVOH from humidity, a heat sealed paper packaging product incorporating EVOH would have unacceptably high levels of “squeeze out” during packaging as a result of the melting of the various LDPE barrier layers and tie resins. As mentioned above, squeeze out results in the build up of polymeric material on the packaging machine components which requires costly downtime to clean.
- Disclosed below are structures for a paper-based substrate containing EVOH which avoid the problems of squeeze out and, in some structures, do not require complex coextrusion machinery configurations capable of forming coatings having more than two layers. As used herein, a “-” is used to indicate layers that are coextruded with one another and a “/” is used to indicate layers that are separated attached to one another (for example, by lamination).
- Now with reference to
FIGS. 1 through 4 , a number of the packaging structures that may be used for the tea pouch stock are disclosed including: -
- (1) PAPER/EVOH-TSRB COEX
- (2) PAPER/EVOH-TIE-SEALANT COEX
- (3) PAPER/(PE or PP)/PAPER/EVOH-TSRB COEX
- (4) PAPER/(PE or PP)/PAPER/EVOH-TIE-SEALANT COEX
As used herein, TSRB refers to a tie resin and sealant resin blend, whereas EVOH-TIE-SEALANT refers to three discrete separately formed layers of EVOH, tie resin (which is the resin designed to adhere the EVOH and the sealant layers together), and sealant. With respect to the figures, like reference numerals are used to describe like items in which the hundreds digit has been increased to correspond to the figure number (e.g., tie sealantresin blend layer 108 corresponds to tie sealant resin blend layer 308).
- Looking first at
FIG. 1 , the layers of structure (1) listed above are illustrated. InFIG. 1 , apackaging 100 includes apaper substrate 102 and acoextrusion 104 including an ethylenevinyl alcohol layer 106 and a tie sealantresin blend layer 108. The ethylenevinyl alcohol layer 106 of thecoextrusion 104 is directly attached to thepaper substrate 102 along a paper substrate—ethylene vinylalcohol layer interface 110. - Turning now to
FIG. 2 , structure (2) is illustrated which is similar to structure (1), but in which the tie sealant resin blend layer has been replaced by separate tie resin and sealant layers. InFIG. 2 , apackaging 200 again includes apaper substrate 202 with acoextrusion 204. However, in structure (2), thecoextrusion 204 includes an ethylenevinyl alcohol layer 206, atie resin layer 212, and asealant layer 214. The ethylenevinyl alcohol layer 206 is directly attached to thepaper substrate 202 along a paper substrate—ethylene vinylalcohol layer interface 210. The other layers are arranged such that thetie resin layer 212 is sandwiched between the ethylenevinyl alcohol layer 206 and thesealant layer 214. Accordingly, thesealant layer 214 is disposed such that it is on an attachment face (i.e., a face that will be attached to another face of the packaging) when the packaging is heat sealed to form a tea pouch. - Now with reference to
FIGS. 3 and 4 , apackaging 300 and apackaging 400 are illustrated which correspond to structures (3) and (4) listed above.FIG. 3 is generally similar toFIG. 1 andFIG. 4 is generally similar toFIG. 2 , except that inFIGS. 3 and 4 an additionalpolymeric barrier layer paper layer paper substrate - Looking at the structures above, it can be seen that the EVOH coextrusion is asymmetrical in all forms, unlike the LDPE-Tie Resin-EVOH-Tie Resin-LDPE structures which have been previously produced. As the EVOH is directly attached to a paper layer, the elimination of the tie resin-LDPE layers on the left side of the EVOH (of the listed structures) reduce the amount of squeeze out that is likely to occur during heat seal in an IMA machine or the like. At least to some extent, the paper substrate may serve as a barrier to moisture to protect the EVOH layer.
- To further prevent degradation of the EVOH layer, the thickness of the EVOH layer may be increased in comparison to the EVOH layer thickness in a standard symmetrical coextrusion. Additionally, as in
FIGS. 3 and 4 , an interpaper layer of a polymeric barrier layer such as polyethylene or polypropylene may be employed. The third and fourth structures have the best barrier properties for both water vapor transmission and oxygen transmission. However, using two thinner layers of paper is more expensive. The laminate resin layer would preferably be high density polyethylene (HDPE), polypropylene (PP), or another material with a high melting point polymeric material to prevent squeeze-out issues. - Notably, all other known EVOH paper structures to date have employed a layer of polyethylene resin between the paper and the EVOH resin. Because this polyethylene layer will melt and flow under the high seal pressure conditions, the known structures would have squeeze-out issues, or if the seal temperature and pressure are lowered to avoid squeeze out, then the packaged product would have weaker seal integrity. Additionally, as EVOH is typically processed to have tie resin and LDPE on either side as a moisture barrier, the extrusion equipment to produce a five layer coextrusion is typically more costly than that to produce a two layer coextrusion. At least the first and third structures described above can be produced with only a two resin capable coextruder.
- It is also noted that EVOH melts at a much higher temperature than the TSRB (EVOH melts at around 178 degrees C., while the TSRB melts in the range of 90-100 degrees C. depending on the blend). Accordingly, the EVOH itself also resists squeeze out when heat seal jaws of the packaging machines are set at 160 degrees C.
- In one preferred form for the packaging of a tea pouch, the tea pouch packaging has a structure of 35#PAPER/4#EVOH-7#TSRB (#/ream based on 3,000 ft2 ream size). The 35#/ream PAPER may be Kraft paper with a machine glaze type finish and bleached white color. The paper may be flame treated for good adhesion of the 4#EVOH-7#TSRB coextrusion to the paper. The 4#EVOH-7#TSRB layers are coextruded from a single die. The EVOH may be 35 mol % ethylene EVOH (available as EVAL C109B) and the TSRB may be 50% POP (polyolefin plastomer, available as DOW PT1450), 25% tie resin (such as ADMER AT1000A), and 25% LDPE (low-density polyethylene, available as CHEVRON 4517). The exact percentages of the constituent components may be varied depending on the temperatures, times, and pressures used to form the heat seal and the quality of the seal desired.
- In another exemplary form, the packaging for the tea pouch made according to structure (2) above may have a structure of 35#PAPER/4#EVOH-1.5#Tie Resin-5.5#Sealant.
- In still another exemplary alternative form, the packaging for the tea pouch made according to structures (3) and (4) in which two papers are laminated together may have a total paper basis weight of 30#/ream (3,000 ft2) and a lamination polymer basis weight of 6#/ream. In this form, the two paper layers may each have a separate basis weight of 15#/ream, although they might be uneven or differently distributed. By having 30#/ream in the paper layers and 6#/ream of the lamination polymer, the total weight basis and thickness of the structures are substantially the same. It is contemplated that as the intermediate lamination polymer is a polymeric barrier layer to moisture, then the EVOH basis weight may be reduced to 3#/ream since there is additional protection to humidity on the paper side.
- Although a preferred tea pouch structure is described above, this structure should not be construed as limiting. Some examples of variations to the structure are provided below which, again, are for purpose of example only and should not be construed as limiting.
- It is contemplated that the paper may be a type having a machine glazed (MG) or a machine finished (MF) type finish, may be of a white or a natural color, and may be of a Kraft, ground wood, recycled, or sulfite furnish. Clay coated paper may also be used. The paper may include laminations of one or more layers of paper or include a PET, Nylon, OPP, or PLA film laminated to the paper. The basis weight of the paper substrate can range from 10#/ream to 60#/ream.
- Although EVOH with 35% ethylene content is believed to provide the best barrier results, EVOH is available in 24% ethylene to 48% ethylene content. It is contemplated that any amount of ethylene content might be used or selected based on the desired properties of the barrier or for appropriate economy. Generally speaking, the lower the ethylene content, the better the aroma and oxygen barrier. It is contemplated that the basis weight of the EVOH layer may be in the range of 0.1#/3,000 ft2 to 10.0#/3,000 ft2.
- The TSRB may have a tie resin content from 10 wt % to 80 wt % and a polyethylene content from 20 wt % to 90 wt %. The tie resin may be an anhydride modified LDPE based adhesive resin concentrates such as ADMER AT1000A or DUPONT BYNEL 41E170. The polyethylene sealant resin may be LDPE, MDPE, HDPE, LLDPE, POP, mLLDPE and blends thereof, and copolymers of PE such as, for example: EVA, IONOMER, EAA, EMAA, EMAC, EnBA, and the like. TSRB can be further modified with slip, antiblock, or color concentrates depending upon customer needs.
- The particular tie sealant resin blend selected may be tweaked to minimize the amount of squeeze out that occurs during heat sealing at high temperatures and pressures, while simultaneously maximizing the quality of the seal. The basis weight of the TSRB layer may be in the range of 1.0#/3,000 ft2 to 20.0#/3,000 ft2 and modified to provide enough TSRB material to form a robust seal without including so much material so as to induce squeeze out.
- In order to achieve a thin and stable coating layer, EVOH is not extruded as its own single layer, but needs to be coextruded with the TSRB. Another suitable alternative is to extrude an asymmetric three layer coextrusion, such as in the second and fourth structures, in which the tie and sealant resins are not blended. Of course, a benefit of using the TSRB instead of the three layer coextrusion is that a three resin capable coextruder is not required.
- Now with reference to
FIG. 5 , aline 500 for making the packaging is disclosed. Theline 500 illustrated is suitable for making any of the structures (1)-(4) listed above. One of ordinary skill in the art will readily appreciate, however, that segments of theline 500 may be eliminated or not used based on the desired structure of the final product. - The
line 500 includes two sections. The first section provides the paper substrate layer or forms a laminate including the paper layers with the polymeric barrier layer disposed there between. The second section then applies the EVOH coextrusion to the substrate. - In the form shown, the first section of the
line 500 is shown for the preparation of structures shown inFIGS. 3 and 4 , which include a paper/polymeric barrier layer/paper lamination. In this form, paper is separately unrolled from amain substrate roll 502 and anauxillary substrate roll 504 and fed toward anextrusion laminator 506 which inserts the polymeric barrier layer between the two paper layers. On the way to theextrusion laminator 506, the paper from themain substrate roll 502 is fed past atreater 508 such as a flame treater or a corona treater that treats the surface of the paper from themain substrate roll 502 such that the polymeric barrier layer created at theextrusion laminator 506 will adhere well to the paper layer. Likewise, the paper from theauxiliary substrate roll 504 is fed past atreater 509 such as a flame treater or a corona treater that treats the surface of the paper from theauxiliary substrate roll 504 such that the polymeric barrier layer created at theextrusion laminator 506 will also adhere well to this paper layer. - At the
extrusion laminator 506, the paper layers meet at a nip point at which point the polymeric barrier layer is inserted between the paper layers. The nip point occurs between a rubber niproll 510 and achill roll 512. The paper layers approach the nip point from different angles and in the space between where the paper layers meet and at a location above the nip point, adie 514 supplies a molten resin A (which may be, for example, polyethylene or polypropylene) as a melt curtain between the paper layers. This molten resin A is pressed between the paper layers at the nip point, is cooled to form a paper/polymeric barrier layer/paper structure found inFIGS. 3 and 4 , and exits theextrusion laminator 506. - It should be appreciated that while the
line 500 is shown including theextrusion laminator 506 for the formation of the paper/polymeric barrier layer/paper structure of structures (3) or (4), that if the structures (1) or (2) are being formed then theextrusion laminator 506 may be eliminated and the first section of theline 500 could simply be a main substrate roll that unrolls to provide the paper substrate. - Regardless of whether the substrate is a single paper layer or a paper/polymeric barrier layer/paper laminate structure, the substrate may then be optionally fed past a
treater 516 that treats the surface of the paper substrate for better adhesion to the coextrusion further down theline 500. Again, thetreater 516 may incorporate a flame treatment, liquid priming, or a corona treatment to prepare the surface of the paper substrate. - In the second portion of the
line 500, acoextrusion coater 518 applies or coats the paper substrate with the EVOH coextrusion to form the packaging. In thecoextrusion coater 518, the paper substrate is fed between a rubber niproll 520 and achill roll 522. Afeedblock 524 of thecoextruder 526 receives molten EVOH and at least one other molten resin B and/or C. If an EVOH-TSRB coextrusion is being formed, then the molten TSRB is also fed into the feedblock 524 (as B, with no C resin being fed) and a two layer coextrusion of EVOH-TSRB is extruded by thedie 528 proximate the nip point such that the EVOH layer side contacts the paper substrate. In this form, thecoextruder 526 may be only a two resin capable coextruder. If an EVOH-Tie-Sealant coextrusion is being formed, then in addition to the molten EVOH thefeedblock 524 receives both a molten tie resin (as B) and a molten sealant (as C) and thedie 528 extrudes an EVOH-Tie-Sealant coextrusion such that the EVOH layer is applied to the paper substrate. After exiting thecoextrusion coater 518, the packaging is wound up on a product wind-up roll 530. - Now with reference to
FIGS. 6 and 7 , anexemplary tea pouch 600 is illustrated that has been made by heat sealing a ply of the paper/EVOH-TSRB packaging 100. Thetea pouch 600 is formed by folding a single ply of the packaging in half at afold line 602 such that theTSRB layer 108 on either side of thefold line 602 face one another and atea bag 604 is disposed between the two halves. AU-shaped seal 606 is then formed around a portion of theperiphery 608 of thetea pouch 600 by use of heat and pressure from a packaging machine such as the IMA machine above to seal the twoTSRB layers 106 together. Theseal 606 and thefold line 602 completely surround thetea bag 604 such that thetea bag 604 is entirely contained with aninner volume 610 of thetea pouch 600. - While a tea pouch is shown formed from a single ply of packaging which has been folded and a portion of the periphery has been heat sealed, it should be appreciated that two separate plies of packaging could be sealed around their entire periphery to establish the inner volume for receiving the tea bag such that no fold is required. Additionally, while a tea pouch formed from the paper/EVOH-TSRB structure has been illustrated in
FIGS. 6 and 7 , it will be appreciated that any structures (1)-(4) could be sealed (either at the TSRB surface or sealant surface) under heat and pressure to make the tea pouch. - While specific embodiments of the present invention has been shown, various modifications falling within the breadth and scope of the invention will be apparent to one skilled in the art. Thus, the following claims should be looked to in order to understand the full scope of the invention.
Claims (38)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/521,021 US20130037556A1 (en) | 2010-01-19 | 2011-01-18 | Packaging for a tea pouch |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US29632110P | 2010-01-19 | 2010-01-19 | |
PCT/US2011/021535 WO2011090936A1 (en) | 2010-01-19 | 2011-01-18 | Packaging for a tea pouch |
US13/521,021 US20130037556A1 (en) | 2010-01-19 | 2011-01-18 | Packaging for a tea pouch |
Publications (1)
Publication Number | Publication Date |
---|---|
US20130037556A1 true US20130037556A1 (en) | 2013-02-14 |
Family
ID=44307158
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/521,021 Abandoned US20130037556A1 (en) | 2010-01-19 | 2011-01-18 | Packaging for a tea pouch |
US13/521,019 Active 2034-07-04 US9610755B2 (en) | 2010-01-19 | 2011-01-18 | Packaging and method of making packaging |
US15/477,492 Abandoned US20170259546A1 (en) | 2010-01-19 | 2017-04-03 | Packaging and method of making packaging |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
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US13/521,019 Active 2034-07-04 US9610755B2 (en) | 2010-01-19 | 2011-01-18 | Packaging and method of making packaging |
US15/477,492 Abandoned US20170259546A1 (en) | 2010-01-19 | 2017-04-03 | Packaging and method of making packaging |
Country Status (3)
Country | Link |
---|---|
US (3) | US20130037556A1 (en) |
CA (2) | CA2797763A1 (en) |
WO (2) | WO2011090934A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9610755B2 (en) | 2010-01-19 | 2017-04-04 | Prolamina Midwest Corporation | Packaging and method of making packaging |
US10315837B2 (en) * | 2012-04-17 | 2019-06-11 | Ima Industries S.R.L. | Device for sealing an overwrap envelope |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103329300B (en) * | 2011-03-30 | 2016-05-04 | 海洋王照明科技股份有限公司 | Substrate and preparation method thereof and use the organic electroluminescence device of this substrate |
ITMI20111692A1 (en) * | 2011-09-20 | 2013-03-21 | Fattoria La Vialla Di Gianni Anton Io E Bandino L | PACKAGING FOR FOOD IN THE FORM OF A BAG OR ENVELOPE |
US20160122116A1 (en) * | 2014-10-29 | 2016-05-05 | Sonoco Development, Inc | Extrusion Laminate Mineral Oil Barrier |
EP3230173A4 (en) * | 2014-12-08 | 2018-05-16 | Entegris, Inc. | Film with improved flex crack resistance |
WO2018165116A1 (en) * | 2017-03-06 | 2018-09-13 | Evergreen Packaging, Inc. | Extrusion coated paper for flexible packaging |
DE102020123123A1 (en) | 2020-09-04 | 2022-03-10 | Koehler Innovation & Technology Gmbh | Packing with paper material |
US11827397B2 (en) | 2021-06-17 | 2023-11-28 | Evergreen Packaging Llc | Multilayer paperboard pouch and method of making the same using conventional bag-making equipment (CBME) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040245138A1 (en) * | 2001-10-15 | 2004-12-09 | Tapani Penttinen | Package lid, method for manufacturing the same and package sealed with the lid |
US20090324861A1 (en) * | 2006-07-27 | 2009-12-31 | Stora Enso Oyi | Polymer-coated heat-sealable packaging material and a sealed package manufactured thereof |
US7794804B2 (en) * | 1998-08-27 | 2010-09-14 | Cryovac, Inc. | Oxygen scavenging packaging |
US20130040155A1 (en) * | 2010-01-19 | 2013-02-14 | Prolamina Midwest Corporation | Packaging and method of making packaging |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4701360A (en) * | 1986-05-16 | 1987-10-20 | International Paper Company | Heat sealable barrier material for improved juice packaging (EVOH) |
US5059459A (en) * | 1989-05-17 | 1991-10-22 | Westvaco Corporation | Paperboard laminate |
EP0750573A4 (en) | 1994-03-24 | 1997-09-03 | Union Camp Corp | Flip side box with moisture barrier |
US5679422A (en) * | 1995-01-25 | 1997-10-21 | American National Can Company | Coextruded film for chub packages |
DE69729763T2 (en) * | 1996-02-28 | 2004-12-09 | Cryovac, Inc. | Packaging film for cheese |
ES2386666T3 (en) * | 1998-10-07 | 2012-08-24 | Kuraray Co., Ltd. | Multilayer structure and process to produce it |
US6383589B1 (en) * | 1999-03-29 | 2002-05-07 | Pechiney Plastic Packaging, Inc. | Multilayer plastic structures, containers made therefrom, and methods of making the structures |
US6479154B1 (en) * | 1999-11-01 | 2002-11-12 | Kimberly-Clark Worldwide, Inc. | Coextruded, elastomeric breathable films, process for making same and articles made therefrom |
US6521312B1 (en) * | 2000-11-28 | 2003-02-18 | Loparex, Inc. | Multilayered film structures and methods of making and using the same |
US8043674B2 (en) * | 2001-02-22 | 2011-10-25 | Exxonmobil Oil Corporation | Sealable packaging structures and applications related thereto |
US6974447B2 (en) * | 2001-04-17 | 2005-12-13 | Baxter International Inc. | High gas barrier receptacle and closure assembly |
JP3828861B2 (en) | 2002-12-03 | 2006-10-04 | 東京製紙株式会社 | Laminated body and paper container and package using the same |
US20060172143A1 (en) * | 2003-07-23 | 2006-08-03 | Breese David R | Extrusion coating process and coated substrates having improved heat seal properties |
US7318498B2 (en) * | 2004-04-06 | 2008-01-15 | Azdel, Inc. | Decorative interior sound absorbing panel |
ES2633237T3 (en) * | 2004-04-08 | 2017-09-20 | Dow Global Technologies Llc | Multi-component structures that have improved adhesion between components |
WO2007062391A2 (en) * | 2005-11-22 | 2007-05-31 | Triton Systems, Inc. | Multilayer flame retardant barrier films and fabrics |
-
2011
- 2011-01-18 CA CA2797763A patent/CA2797763A1/en not_active Abandoned
- 2011-01-18 US US13/521,021 patent/US20130037556A1/en not_active Abandoned
- 2011-01-18 US US13/521,019 patent/US9610755B2/en active Active
- 2011-01-18 WO PCT/US2011/021533 patent/WO2011090934A1/en active Application Filing
- 2011-01-18 WO PCT/US2011/021535 patent/WO2011090936A1/en active Application Filing
- 2011-01-18 CA CA2797570A patent/CA2797570A1/en not_active Abandoned
-
2017
- 2017-04-03 US US15/477,492 patent/US20170259546A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7794804B2 (en) * | 1998-08-27 | 2010-09-14 | Cryovac, Inc. | Oxygen scavenging packaging |
US20040245138A1 (en) * | 2001-10-15 | 2004-12-09 | Tapani Penttinen | Package lid, method for manufacturing the same and package sealed with the lid |
US20090324861A1 (en) * | 2006-07-27 | 2009-12-31 | Stora Enso Oyi | Polymer-coated heat-sealable packaging material and a sealed package manufactured thereof |
US20130040155A1 (en) * | 2010-01-19 | 2013-02-14 | Prolamina Midwest Corporation | Packaging and method of making packaging |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9610755B2 (en) | 2010-01-19 | 2017-04-04 | Prolamina Midwest Corporation | Packaging and method of making packaging |
US10315837B2 (en) * | 2012-04-17 | 2019-06-11 | Ima Industries S.R.L. | Device for sealing an overwrap envelope |
Also Published As
Publication number | Publication date |
---|---|
WO2011090934A1 (en) | 2011-07-28 |
CA2797570A1 (en) | 2011-07-28 |
US20130040155A1 (en) | 2013-02-14 |
US9610755B2 (en) | 2017-04-04 |
CA2797763A1 (en) | 2011-07-28 |
US20170259546A1 (en) | 2017-09-14 |
WO2011090936A1 (en) | 2011-07-28 |
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