US20110136946A1

US20110136946A1 - Slurry compositions for ground improvement using blast-furnace slag cement and method of producing soil cement slurry by using same

Info

Publication number: US20110136946A1
Application number: US13/028,748
Authority: US
Inventors: Takao Kono; Toshio Yonezawa; Eiji Sato; Tomonori Yoshida; Mitsuo Kinoshita; Shinji Tamaki
Original assignee: Takao Kono; Toshio Yonezawa; Eiji Sato; Tomonori Yoshida; Mitsuo Kinoshita; Shinji Tamaki
Current assignee: Takemoto Oil and Fat Co Ltd
Priority date: 2009-06-09
Filing date: 2011-02-16
Publication date: 2011-06-09
Also published as: JPWO2010143630A1; TW201114721A; US8822567B2; CN102459510A; WO2010143630A1; CN102459510B; TWI465410B; KR20120026533A; US20130023606A1; JP5545678B2

Abstract

Slurry composition for ground improvement is obtained from cement, water and an admixture. The slurry composition cement is of a kind prepared by using blast-furnace slag cement of a specified type as the cement at a water/blast-furnace slag cement mass ratio of 40-250% and contains the admixture in an amount of 0.1-5 mass parts for 100 mass parts of the blast-furnace slag cement. The blast-furnace slag cement of the specified type contains blast-furnace slag fine particles with fineness 3000-13000 cm²/g in an amount of 60-80 mass % and portland cement in an amount of 20-40 mass % for a total of 100 mass %.

Description

This application is a continuation of International Application No. PCT/JP2010/059699, filed Jun. 8, 2010, priority being claimed on Japanese Patent Application 2009-138002 filed Jun. 9, 2009.

BACKGROUND OF THE INVENTION

This invention relates to slurry compositions for ground improvement using blast-furnace slag cement and a method of producing soil cement slurry by using such slurry compositions.
In recent years, the demand for reducing the emission rate of carbon dioxide and improving efficient energy consumption is becoming increasingly stronger. Under this condition, blast-furnace slag as by-product from steel mills is being effectively used as material for blast-furnace slag cement in the form of blast-furnace slag fine particles in mountain stationary construction, underground water stop construction and soft ground improvement construction works. Generally, when such a ground improvement work is carried out, cement slurry with a mixture of cementatious stabilizer and water (cement milk) is injected into the ground and a drilling and kneading machine is used to mix and stir it with the ground at the site, and blast-furnace slag cement is used here as the cementatious stabilizer. Blast-furnace slag cement is usually produced by mixing blast-furnace slag fine particles into normal portland cement and is usually divided according to the JIS-RS211 standard into the following three kinds, depending on the amount of the blast-furnace slag fine particles: Type A (over 5% to 30%), Type B (over 30% to 60%) and Type C (over 60% to 70%). Type B with a good balance in characteristics is usually used when actual ground improvement is done.
For ground improvement, Type B blast-furnace slag cement is normally mixed into 1 m³of ground at a rate of 100-400 kg, but since about 400 kg of carbon dioxide is emitted for producing 1 ton of Type B blast-furnace slag cement, this means that 40-160 kg of carbon dioxide is emitted for improving 1 m³of ground by using Type B blast-furnace slag cement, exclusive of the emission of carbon dioxide generated by the operation of construction machines, transportation of materials, etc. For this reason, in the field of carrying out ground improvement, there have been demands for the development of technology for suppressing the generation of carbon dioxide by using blast-furnace slag cement at a higher rate, while maintaining workability and the prerequisite that the ground to be improved gain the necessary strength.
The present invention relates to slurry compositions for ground improvement using blast-furnace slag cement that can respond to such demands, as well as a method of producing soil cement slurry using such compositions.
Regarding the effects of the conventional use of portland cement for ground improvement, it has been reported, for example, in “Manual for Ground Improvement by Cementatious Stabilizer” (1984) pages 42-44, edited by the Cement Association of Japan, that portland cement is alkaline because calcium hydroxide is generated when it comes into contact with water and, if it is used for ground improvement, the pH of the ground increases up to 10, adversely affecting the growth of plants, etc. and that, if portland cement is used for improving ground with low water content such as a loamy layer, it becomes easier for hexavalent chromium in the portland cement to elute, adversely affecting the environment. Besides the above, there have been proposals for the improvement of fluidity of cement slurry used for ground improvement such as those in Japanese Patent Publications Tokkai 11-256161, 2000-169209 and 2006-298726, as well as for hydraulic compositions using blast-furnace slag, etc. usable also for ground improvement such as those in Japanese Patent Publications Tokkai 62-158146, 63-2842, 1-208354, 10-114555 and 2002-241152, but there have been no detailed reports or proposals contributing to the reduction in emission of carbon dioxide.

SUMMARY OF THE INVENTION

It is therefore an object of this invention to provide slurry compositions for ground improvement capable of reducing the generation of carbon dioxide by using blast-furnace slag cement at a higher rate than being done at present such that the workability of ground improvement work is maintained and the ground would gain necessary strength, as well as a method of producing soil cement slurry using such compositions.
The inventors herein have discovered as a result of their diligent studies in view of the aforementioned object of the present invention that slurry compositions for ground improvement using together with an admixture a specified kind of blast-furnace slag cement containing blast-furnace slag fine particles at a higher rate and portland cement at a correspondingly lower rate, as well as a method of producing soil cement slurry using such compositions are correctly responsive to the object of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to slurry compositions for ground improvement, comprising at least cement, water and an admixture, the cement being blast-furnace slag cement comprising blast-furnace fine particles with fineness 3000-13000 cm²/g in an amount of 60-80 mass % and portland cement in an amount of 20-40 mass % so as to be together 100 mass %, the slurry compositions being produced by mixing water with this blast-furnace slag cement at a mass ratio of 40-250% and containing the admixture in an amount of 0.1-5 mass parts per 100 mass parts of this blast-furnace slag cement.
The present invention also relates to a method of producing soil cement slurry characterized as using slurry compositions for ground slurry using blast-furnace slag cement according to this invention at a rate of 300-1200 kg per 1 m³of ground.
A slurry composition for ground improvement using blast-furnace slag cement (hereinafter referred to as a slurry composition of this invention) is characterized as comprising at least cement, water and an admixture. The slurry composition of this invention uses blast-furnace slag cement of a special kind and such blast-furnace slag cement is characterized as containing blast-furnace slag fine particles with fineness 3000-13000 cm²/g in an amount of 60-80 mass % and portland cement in an amount of 20-40 mass % such that their total would be 100 mass % but those containing blast-furnace slag fine particles in an amount of 64-76 mass % and portland cement in an amount of 24-36 mass % such that their total would be 100 mass % are preferable.
Use is made of blast-furnace slag fine particles with fineness in the range of 3000-13000 cm²/g but those with fineness in the range of 3000-8000 cm²/g are preferable and those with fineness in the range of 3500-6500 cm²/g are more preferable. If those with fineness outside the range of 3000-13000 cm²/g are used, the fluidity of the prepared slurry composition may be poor or the resultant ground strength may be lowered. The fineness is herein expressed by the specific surface area by the blain method.
Use as portland cement is usually made of normal portland cement, high early strength portland cement or moderate heat portland cement, but multi-purpose normal portland cement is preferable.
For producing a slurry composition of this invention, the mass ratio of water to blast-furnace slag cement is adjusted to 40-250%, and more preferably to 45-230%. If this mass ratio is greater than 250%, the reduction in the ground strength becomes great. If this mass ratio is less than 40%, on the other hand, the fluidity of the soil cement slurry becomes too low. An admixture is used in a slurry composition of this invention in an amount of 0.1-5 mass parts per 100 mass parts of the blast-furnace slag cement. In the above, the mass ratio between water and blast-furnace cement is the number obtained as ((mass of water used)/(mass of blast-furnace cement used))×100.
Admixtures that may be used in the slurry compositions of this invention include those used in conventionally known kinds of soil cement. Examples of such admixture include fluidizers, hardening accelerators and defoamers.
There is no particular limitation on the fluidizers to be used but those comprising alkali metal salts of water soluble vinyl copolymers obtained by alkali hydrolysis of copolymer between α-olefin and anhydrous maleic acid and having mass averaged molecular weight (throughout herein, pullulan converted weight by gel-permeation chromatography method) of 2000-70000 are preferable and those comprising alkali metal salts of water soluble vinyl copolymers obtained by alkali hydrolysis of copolymer between isobutylene and anhydrous maleic acid are particular preferable.
Examples of preferable fluidizers further include those comprising alkali metal salts of polyacrylic acid with mass averaged molecular weight of 1500-50000 and they can be used in combination with the aforementioned alkali metal salt of water soluble vinyl copolymer. The amount of aforementioned fluidizers to be used is preferably 0.1-4 mass parts to 100 mass parts of blast-furnace slag cement, and more preferably 0.3-3 mass parts.
Examples of hardening accelerator include alkali metal carbonates such as sodium carbonate, potassium carbonate and lithium carbonate. Among these, sodium carbonate is preferable from economic reasons. These hardening accelerators are used for improving the strength manifestation characteristic of the ground hardener obtained by injecting a slurry composition of this invention into ground, drilling and stirring. The amount of hardening accelerator to be used is preferably 0.3-4 mass parts, and more preferably 0.5-3 mass parts, for 100 mass parts of blast-furnace slag cement.
There is no particular limitation on the defoamer to be used but those of polyalkylene glycol monoalkenyl (or alkyl)ether, modified polydimethyl siloxane and trialkyl phosphate can be mentioned. For economic reasons and from the point of view of the degree of manifestation of effects, however, defoamers comprising polyalkylene glycol monoalkenyl ether are preferable. A defoamer is used for eliminating the trouble of foaming when the slurry composition of this invention is produced and also for controlling the air to be dragged in when the slurry composition is injected into the ground for drilling and stirring to thereby improve the strength manifestation of the ground hardener. The amount of defoamer to be used is preferably 0.001-0.1 mass parts, and more preferably 0.002-0.01 mass parts, for 100 mass parts of blast-furnace slag cement.
Slurry compositions of this invention can be prepared by a known method. For example, they may be prepared by a method of mixing specified amounts of blast-furnace slag cement, water and admixture by placing them into a mixer and kneading them together. At this moment, additive materials such as bentonite and fibers and additive agents such as setting retarders and hardening accelerators may be added, if necessary, within the limit of not adversely affecting the effects of this invention.
In a method of fluidizing the soil cement slurry of this invention, soil cement slurry is produced by mixing a slurry composition of this invention described above with ground according to the required fluidity of the soil cement slurry and strength of the ground hardener. At this moment, the slurry composition of this invention is used in an amount of 300-1200 kg, and preferably 400-1100 kg, per 1 m³of ground.
The present invention has the effect of suppressing the emission of carbon dioxide and controlling the lowering in fluidity of prepared soil cement slurry with time by using blast-furnace slag cement of a specified kind as a cement material together with an admixture in ground improvement such that superior workability can be maintained and the ground hardener can be allowed to manifest necessary strength at the same time.
In what follows, the invention will be explained in terms of some examples but these examples are not intended to limit the scope of the invention. In the following examples, unless otherwise explained, “%” means “mass %”, and “parts” means “mass parts”.

Part 1

Preparation of Fluidizer as Admixture

After water 145 g and 30% caustic soda 470 g were placed in a flask equipped with a stirrer, copolymer of isobutylene and anhydrous maleic acid (isobam 600 (tradename) produced by Kuraray) 395 g was gradually added with stirring while the internal temperature was maintained at 60° C. to obtain alkali metal salt of copolymer by hydrolysis. This was analyzed by using GPC (gel-permeation chromatography) method and found to be sodium salt (p-1) of water soluble vinyl copolymer comprising sodium salt of copolymer of isobutylene and anhydrous maleic acid and having mass averaged molecular weight of 23000. By similar methods, fluidizers (p-2) and (p-3) were prepared.
The fluidizers, hardening accelerators and defoamers used as admixtures in this invention, inclusive of the fluidizers described above, are shown together in Table 1.

	TABLE 1

	Type	Details

Fluidizer	p-1	Sodium salt of water soluble vinyl copolymer of
		isobutylene and anhydrous maleic acid with mass
		averaged molecular weight = 23000
	p-2	Potassium salt of water soluble vinyl copolymer of
		isobutylene and anhydrous maleic acid with mass
		averaged molecular weight = 65000
	p-3	Sodium salt of water soluble vinyl copolymer of
		diisobutylene and anhydrous maleic acid with mass
		averaged molecular weight = 34000
	p-4	Sodium salt of polyacrylic acid with mass averaged
		molecular weight = 21000
	p-5	Mixture of (p-1) and (p-4) at mass ratio of 2/1
Hardening	c-1	Sodium carbonate
accelerator	c-2	Potassium carbonate
Defoamer	d-1	Polyalkylene glycol monoalkenyl ether defoamer
		(AFK-2 (tradename) produced by Takemoto Yushi)

Part 2

Preparation of Blast-Furnace Slag Cement

Blast-furnace slag fine particles and portland cement were used under the conditions shown in Table 2 to obtain blast-furnace slag cement (S-1)-(S-4) and (R-1)-(R-3).

TABLE 2

Blast-furnace slag cement

	Mixture of blast-furnace slag fine particles and
	portland cement (total of 100 mass parts)

	Blast-furnace slag
	fine particles		Portland cement

Type	Type	Ratio (%)	Type	Ratio (%)

S-1	sg-1	70	pc-1	30
S-2	sg-1	75	pc-1	25
S-3	sg-2	65	pc-1	35
S-4	sg-1	70	pc-2	30
R-1	sg-1	85	pc-1	15
R-2	sg-1	45	pc-1	55
R-3	sg-3	30	pc-1	70

In Table 2:
sg-1: Blast-furnace slag fine particles with fineness 4100 cm²/g
sg-2: Blast-furnace slag fine particles with fineness 5900 cm²/g
sg-3: Blast-furnace slag fine particles with fineness 1020 cm²/g
pc-1: Normal portland cement
pc-2: High early strength portland cement

Part 3

Preparation of Slurry Compositions for Ground Improvement

Test Examples 1-8 and Comparison Examples 1-6

Specified amounts of blast-furnace slag cement shown in Table 2 and kneading water (faucet water) were placed in a forced mixing pan-type mixer under conditions shown in Table 3 and specified amounts of fluidizer, hardening accelerator and defoamer shown in Table 1 as admixtures were also placed inside to be kneaded together to prepare each example of slurry composition for ground improvement.

	TABLE 3

	Slurry compositions for ground improvement

	Ratio of slurry
	composition
	(total = 100%)

	Mass ratio	Blast-
	(%) of	furnace		Admixtures

	water/blast-	slag cement	Water	Fluidizer	Hardening	Deformer
	furnace	(type/used	(used	(type/used	accelerator	(type/used
	slag cement	amount	amount	amount	(type/used	amount
Type	(%)	(%))	(%))	(%))	amount (%))	(%))

TE-1	SL-1	200	S-1/33.3	66.7	p-1/0.4	c-1/2.5	d-1/0.005
TE-2	SL-2	200	S-2/33.3	66.7	p-2/0.4	c-1/2.5	d-1/0.005
TE-3	SL-3	200	S-3/33.3	66.7	p-3/0.4	c-1/2.5	d-1/0.005
TE-4	SL-4	200	S-1/33.3	66.7	p-4/0.4	c-2/2.5	d-1/0.005
TE-5	SL-5	100	S-1/50	50	p-5/1.8	c-1/1.5	d-1/0.003
TE-6	SL-6	100	S-3/50	50	p-1/1.8	c-2/1.5	d-1/0.003
TE-7	SL-7	50	S-2/66.7	33.3	p-1/2.5	c-1/1.0	d-1/0.002
TE-8	SL-8	50	S-4/66.7	33.3	p-1/2.5	c-2/1.0	d-1/0.002
CE-1	RSL-1	200	R-1/33.3	66.7	p-1/0.4	c-1/2.5	d-1/0.005
CE-2	RSL-2	200	R-2/33.3	66.7	p-2/0.4	c-1/2.5	d-1/0.005
CE-3	RSL-3	200	R-3/33.3	66.7	p-3/0.4	c-1/2.5	d-1/0.005
CE-4	RSL-4	100	S-1/50	50	—	—	—
CE-5	RSL-5	100	R-2/50	50	p-1/1.8	c-2/1.5	d-1/0.003
CE-6	RSL-6	200	S-1/33.3	66.7	p-1/0.4	c-1/0.05	d-1/0.005
CE-7	RSL-7	200	S-3/33.3	66.7	p-1/0.4	—	—
CE-8	RSL-8	200	*1/33.3	66.7	p-1/0.4	—	—

In Table 3:
TE: Test Example
CE: Comparison Example
Type of Blast-furnace slag cement: As described in Table 2
Types of fluidizers, hardening accelerators and defoamers: As described in Table 1
Used amounts of fluidizers, hardening accelerators and defoamers: Mass parts of solid component per 100 mass parts of blast-furnace slag cement
*1: Type B blast-furnace slag cement (density = 3.04 g/cm³; blain value = 3850 cm²/g)

Part 4

Preparation and Evaluation of Soil Cement Slurry

Test Examples 9-16 and Comparison Examples 7-12

Soil cement slurry was prepared by using each example of slurry compositions for ground improvement prepared in Part 3 and evaluated as follows. The injected amount of slurry compositions for 1 m³of ground improvement was determined such that the target uni-axial compressive strength at material age of 28 days would be over 5N/mm². A specified amount of each slurry composition for ground improvement prepared in Part 3 was firstly placed in a hobart mixer and then ground with the physical characteristics shown in Table 4 (mixture of cohesive soil obtained by digging ground and silica sand at mass ratio of 3/1) was added and mixed together to obtain the samples of soil cement slurry shown in Table 5. Conditions for preparation of each sample are also shown in Table 5.

TABLE 4

Mass per		Particle density	Fraction of particles in
volume	Water content	in mixed soil	mixed soil (%)

(kg/m³)	(%)	(g/cm₃)	Cohesive soil	Silica sand

1812	38.6	1.082	66.7	33.3

Evaluation of Physical Characteristics of Prepared Soil Cement Slurry

For each example of soil cement slurry prepared, the flow value immediately after the mixing with kneading, the flow value 90 minutes after the mixing with kneading, the air content and the uni-axial compressive strength were obtained as follows and the results are shown together in Table 5. Their emission rates of carbon dioxide are also shown.
Flow values: Flow tests were carried out both immediately and 90 minutes after the mixing with kneading and flow values after elevation difference (mm) were measured 15 times according to JIS-RS201.
Air content: Obtained according to JIS-A6201 (1977).
Uni-axial compression strength test: Compressive strength (N/mm²) at material age of 28 days was measured on molded articles obtained by using a mold with diameter 50 mm×height 100 mm according to JIS-A1108.

	TABLE 5

	Details of soil cement slurry

	Slurry
	composition		Content		Evaluated physical characteristics

	for ground		of blast-	Emmitted	Flow value
	improvement	Injection	furnace	amount of	(mm)		Uni-axial

	Injected	rate	slag	carbon		90	Air	compressive
	amount	(volume	cement	dioxide	Right	minutes	content	strength
Type	(kg)	%)	(kg)	(kg)	after	later	(%)	(N/mm²)

TE-9	SL-1	1031	80	344	82	226	214	0.6	6.0
TE-10	SL-2	1031	80	344	68	229	226	0.5	6.3
TE-11	SL-3	1031	80	344	96	221	207	0.5	6.4
TE-12	SL-4	1031	80	344	82	223	212	0.6	6.0
TE-13	SL-5	688	46	344	82	227	214	0.6	9.1
TE-14	SL-6	688	46	344	96	224	213	0.6	9.0
TE-15	SL-7	416	29	344	68	231	215	0.5	13.3
TE-16	SL-8	416	29	344	82	236	218	0.5	12.7
CE-9	RSL-1	1031	80	344	41	208	163	0.6	3.2
CE-10	RSL-2	1031	80	344	151	215	142	0.6	2.8
CE-11	RSL-3	1031	80	344	192	220	121	0.6	5.3
CE-12	RSL-4	1031	46	344	82	136	105	2.8	4.2
CE-13	RSL-5	1031	46	344	151	225	164	0.9	5.5
CE-14	RSL-6	1031	80	344	82	210	153	1.2	4.6
CE-15	RSL-7	1031	80	344	96	202	125	3.2	3.8
CE-16	RSL-8	1031	80	344	137	223	162	3.7	4.7

In Table 5:
Test Example
Comparison Example
Injected amount: Injected amount (kg) of slurry composition for ground improvement per 1 m³
Injection rate: Rate of injection (volume %) of slurry composition for ground improvement per 1 m³
Content of blast-furnace slag cement: Content of blast-furnace slag cement (kg) per 1 m³
Emitted amount of carbon dioxide: Amount of carbon dioxide (kg) emitted for improving 1 m³as calculated from the amount of portland cement used

As can be understood from Table 5, each example of soil cement slurry is characterized by a small amount of carbon dioxide for improving 1 m³of ground as compared with conventionally used Comparison Example 16 which employs Type B blast-furnace slag cement. Moreover, excellent fluidity and fluidity maintaining characteristics with flow values less than 200 mm are obtainable, and sufficiently satisfactory results in target uni-axial compressive strength is attained.

Claims

1. A slurry composition for ground improvement, said slurry composition comprising cement, water and an admixture, and being prepared by using water and blast-furnace slag cement as said cement at a water/blast-furnace slag cement mass ratio of 40-250% and containing said admixture in an amount of 0.1-5 mass parts for 100 mass parts of said blast-furnace slag cement, said blast-furnace slag cement comprising blast-furnace slag fine particles with fineness 3000-13000 cm²/g in an amount of 60-80 mass % and portland cement in an amount of 20-40 mass % for a total of 100 mass %.

2. The slurry composition for ground improvement of claim 1 wherein said blast-furnace slag fine particles have fineness 3500-6500 cm²/g.

3. The slurry composition for ground improvement of claim 2 wherein said portland cement is normal portland cement.

4. The slurry composition for ground improvement of claim 2 wherein said blast-furnace slag cement comprises said blast-furnace slag fine particles in an amount of 64-76 mass % and said portland cement in an amount of 24-36 mass % for a total of 100 mass %.

5. The slurry composition for ground improvement of claim 4 wherein said admixture at least partially includes a hardening accelerator comprising an alkali metal carbonate salt.

6. The slurry composition for ground improvement of claim 5 wherein said admixture at least partially includes a defoamer comprising polyalkylene glycol monoalkenyl ether.

7. The slurry composition for ground improvement of claim 6 wherein said admixture at least partially includes a fluidizer comprising an alkali metal salt of water soluble vinyl copolymer obtained by alkali hydrolysis of copolymer of α-olefin and anhydrous maleic acid and having mass averaged molecular weight of 2000-70000.

8. The slurry composition for ground improvement of claim 6 wherein said admixture at least partially includes a fluidizer comprising an alkali metal salt of polyacrylic acid having mass averaged molecular weight of 1500-50000.

9. The slurry composition for ground improvement of claim 7 wherein water and said blast-furnace slag cement are used at a mass ratio of 45-230%.

10. The slurry composition for ground improvement of claim 8 wherein water and said blast-furnace slag cement are used at a mass ratio of 45-230%.

11. A method of preparing soil cement slurry, said method comprising the step of using the slurry composition for ground improvement of claim 9 in an amount of 300-1200 kg per 1 m³of ground.

12. A method of preparing soil cement slurry, said method comprising the step of using the slurry composition for ground improvement of claim 10 in an amount of 300-1200 kg per 1 m³of ground.