US20100236282A1 - Refrigerant compressor - Google Patents

Refrigerant compressor Download PDF

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Publication number
US20100236282A1
US20100236282A1 US12/374,725 US37472508A US2010236282A1 US 20100236282 A1 US20100236282 A1 US 20100236282A1 US 37472508 A US37472508 A US 37472508A US 2010236282 A1 US2010236282 A1 US 2010236282A1
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refrigerant
oil
viscosity
compression chamber
compressor
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US12/374,725
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Yoichiro Nakamura
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Panasonic Intellectual Property Management Co Ltd
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Panasonic Corp
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Publication of US20100236282A1 publication Critical patent/US20100236282A1/en
Assigned to PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. reassignment PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PANASONIC CORPORATION
Assigned to PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. reassignment PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. CORRECTIVE ASSIGNMENT TO CORRECT THE ERRONEOUSLY FILED APPLICATION NUMBERS 13/384239, 13/498734, 14/116681 AND 14/301144 PREVIOUSLY RECORDED ON REEL 034194 FRAME 0143. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: PANASONIC CORPORATION
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008Lubricant compositions compatible with refrigerants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/02Lubrication
    • F04B39/0215Lubrication characterised by the use of a special lubricant
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • C10M2203/065Well-defined aromatic compounds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/2805Esters used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/02Viscosity; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09Characteristics associated with water
    • C10N2020/097Refrigerants
    • C10N2020/101Containing Hydrofluorocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09Characteristics associated with water
    • C10N2020/097Refrigerants
    • C10N2020/103Containing Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/30Refrigerators lubricants or compressors lubricants

Definitions

  • the present invention relates to a refrigerant compressor.
  • Patent Document 1 The conventional refrigerant compressor disclosed in Patent Document 1 is described as follows with reference to FIG. 2 showing a longitudinal sectional view of the refrigerant compressor.
  • the refrigerant compressor includes hermetic container 1 , which is filled with refrigerant 2 and stores refrigerant oil 3 at its bottom.
  • Hermetic container 1 accommodates electrically-driven element 6 and reciprocating compressing element 7 driven by electrically-driven element 6 .
  • Electrically-driven element 6 includes stator 4 and rotor 5 .
  • Refrigerant 2 is made of R600a, which is a hydrocarbon refrigerant.
  • Compressing element 7 is described in detail as follows.
  • Compressing element 7 includes crankshaft 8 .
  • Crankshaft 8 includes main shaft 9 to which rotor 5 is fixedly fitted, and eccentric shaft 10 is eccentric to main shaft 9 .
  • Crankshaft 8 is also provided at its bottom with lubrication pump 11 for lifting refrigerant oil 3 .
  • Compressing element 7 further includes cylinder block 12 .
  • Cylinder block 12 includes a nearly cylindrical compression chamber 13 , and bearing 14 for supporting main shaft 9 .
  • Compressing element 7 further includes piston 15 loosely fitted into compression chamber 13 .
  • Piston 15 is connected to eccentric shaft 10 via piston pin 16 by connecting rod 17 , which is a connection means.
  • the end face of compression chamber 13 is tightly sealed by valve plate 18 .
  • Compressing element 7 further includes head 19 forming an unillustrated high-pressure chamber. Head 19 is fixed on the other side of compression chamber 13 with respect to valve plate 18 .
  • Hermetic container 1 further includes muffler 20 sandwiched between valve plate 18 and head 19 .
  • Hermetic container 1 further includes suction tube 21 and discharge tube 22 which are fixed thereto and connected to an unillustrated refrigeration cycle.
  • Suction tube 21 guides refrigerant 2 into hermetic container 1 , and discharge tube 22 sends refrigerant 2 to the refrigeration cycle.
  • the refrigerant compressor thus structured has the following operation and effects.
  • An unillustrated commercial power supply supplies power to electrically-driven element 6 so as to rotate rotor 5 of electrically-driven element 6 , thereby rotating crankshaft 8 .
  • eccentric shaft 10 performs eccentric movement, allowing connecting rod 17 as the connection means to drive piston 15 via piston pin 16 .
  • Refrigerant 2 is guided into hermetic container 1 through suction tube 21 via an unillustrated suction reed from the refrigeration cycle. Refrigerant 2 is then suctioned through muffler 20 and continuously compressed in compression chamber 13 . Refrigerant 2 thus compressed is discharged via an unillustrated discharge valve and sent through discharge tube 22 to the refrigeration cycle.
  • refrigerant oil 3 is pumped by lubrication pump 11 of crankshaft 8 so as to lubricate sliding portions such as main shaft 9 and piston 15 .
  • refrigerant oil 3 having viscosity of less than 8 mm 2 /s at 40° C. so as to have a low friction loss in sliding portions of the refrigerant compressor, such as between compression chamber 13 and piston 15 and between crankshaft 8 and bearing 14 .
  • refrigerant oil 3 has viscosity as low as less than 8 mm 2 /s at 40° C. and therefore a sufficient amount thereof cannot be held between compression chamber 13 and piston 15 . This causes refrigerant 2 to leak from the gap between compression chamber 13 and piston 15 , thereby increasing leakage loss.
  • the leakage of refrigerant 2 from the gap between compression chamber 13 and piston 15 can be decreased by reducing the gap.
  • too small a gap causes the outer wall of piston 15 and the inner wall of compression chamber 13 to be brought into contact with each other and to be abraded when compressed refrigerant 2 has caused an increase of the ambient temperature.
  • Patent Document 1 Japanese Patent Unexamined Publication No. S62-059695
  • the refrigerant compressor of the present invention includes a hermetic container storing refrigerant oil; an electrically-driven element; and a compressing element driven by the electrically-driven element.
  • the compressing element includes a cylinder block having a cylindrical compression chamber and a cylindrical piston reciprocating in the compression chamber.
  • the compression chamber and the piston have a diameter difference in the range of not shorter than 4 ⁇ m to not longer than 15 ⁇ m.
  • the refrigerant oil has viscosity of 8 mm 2 /s or less at 40° C. and is prepared by mixing a first refrigerant oil having viscosity of less than 8 mm 2 /s at 40° C. with a second refrigerant oil having viscosity of 20 mm 2 /s or more at 40° C.
  • the refrigerant oil has a low viscosity resistance to make the friction loss small.
  • a sufficient amount of the refrigerant oil can be held between the compression chamber and the piston so as to have a low leakage loss of the refrigerant.
  • the diameter difference between the compression chamber and the piston can be optimized to prevent abrasion between them which is caused by their contact.
  • FIG. 1 is a longitudinal sectional view of a refrigerant compressor according to an embodiment of the present invention.
  • FIG. 2 is a longitudinal sectional view of a conventional refrigerant compressor.
  • FIG. 1 is a longitudinal sectional view of a refrigerant compressor according to the embodiment of the present invention.
  • refrigerant compressor 100 includes hermetic container 101 , which is filled with refrigerant 102 and stores refrigerant oil 103 at its bottom.
  • Refrigerant compressor 100 further includes electrically-driven element 106 and reciprocating compressing element 107 driven by electrically-driven element 106 .
  • Electrically-driven element 106 includes stator 104 and rotor 105 .
  • Compressing element 107 is described in detail as follows.
  • Compressing element 107 includes crankshaft 108 made of ferrous metal.
  • Crankshaft 108 includes main shaft 109 to which rotor 105 is fixedly fitted, and eccentric shaft 110 eccentric to main shaft 109 .
  • Crankshaft 108 is also provided at its bottom with lubrication pump 111 for lifting refrigerant oil 103 .
  • Compressing element 107 further includes cylinder block 112 .
  • Cylinder block 112 includes nearly cylindrical compression chamber 113 and bearing 114 for supporting main shaft 109 .
  • Compressing element 107 further includes piston 115 made of ferrous metal and loosely fitted into compression chamber 113 .
  • Piston 115 is connected to eccentric shaft 110 via piston pin 116 by connecting rod 117 , which is a connection means.
  • Valve plate 118 is made of laminated spring steel and forms valve member 120 composed of suction reed 119 for opening and closing an unillustrated suction port.
  • Compressing element 107 further includes head 121 which is fixed on the other side of compression chamber 113 with respect to valve plate 118 .
  • Hermetic container 101 further includes muffler 122 sandwiched between valve plate 118 and head 121 .
  • Muffler 122 is made of polybutylene terephthalate mixed with glass fiber.
  • Hermetic container 101 further includes suction tube 123 and discharge tube 124 which are fixed thereto and connected to an unillustrated refrigeration cycle.
  • Suction tube 123 guides refrigerant 102 into hermetic container 101 , and discharge tube 124 sends refrigerant 102 to the refrigeration cycle.
  • the refrigerant compressor thus structured has the following operation and effects.
  • An unillustrated commercial power supply supplies power to electrically-driven element 106 so as to rotate rotor 105 of electrically-driven element 106 , thereby rotating crankshaft 108 .
  • eccentric shaft 110 performs eccentric movement, allowing connecting rod 117 to drive piston 115 via piston pin 116 . This makes piston 115 reciprocate in compression chamber 113 .
  • Refrigerant 102 is guided into hermetic container 101 through suction tube 123 and then suctioned into compression chamber 113 through muffler 122 . Refrigerant 102 suctioned into compression chamber 113 is continuously compressed. Refrigerant 102 thus compressed is sent to the refrigeration cycle through discharge tube 124 . Refrigerant 102 sent to the refrigeration cycle is guided again into hermetic container 101 through suction tube 123 .
  • refrigerant oil 103 is pumped by lubrication pump 111 of crankshaft 108 so as to lubricate sliding portions such as main shaft 109 and piston 115 .
  • Table 1 shows the results of the efficiency analysis of refrigerant compressors having the same specification with piston 115 of a 30 mm outer diameter. The analysis is performed by changing the diameter differences between compression chamber 113 and piston 115 and using three types of refrigerant oils.
  • Refrigerant oil “A” is refrigerant oil 103 used in the refrigerant compressor according to the embodiment of the present invention.
  • Refrigerant oil “A” has viscosity of 8 mm 2 /s at 40° C. and is prepared by mixing mineral oil having viscosity of 7.5 mm 2 /s at 40° C. as a first refrigerant oil with 3 wt % of mineral oil having viscosity of 20 mm 2 /s at 40 C as a second refrigerant oil.
  • Refrigerant oil “B”, which is used to be compared with refrigerant oil “A”, is mineral oil having viscosity of 8 mm 2 /s at 40° C.
  • Refrigerant oil “C”, which is also used to be compared with refrigerant oil “A”, is mineral oil having viscosity of 10 mm 2 /s at 40° C.
  • the analysis is performed at a condensation temperature of 54.4° C. and an evaporation temperature of ⁇ 23.3° C.
  • the efficiencies of three refrigerant compressors are compared by using R600a as a refrigerant and by changing the diameter difference between compression chamber 113 and piston 115 in the range of not shorter than 4 ⁇ m to not longer than 18 ⁇ m.
  • Table 1 indicates that when the diameter difference between compression chamber 113 and piston 115 is in the range of not shorter than 4 ⁇ m to not longer than 18 ⁇ m, the efficiency of the compressor using refrigerant oil “B” made of only the mineral oil having viscosity of 8 mm 2 /s at 40° C. is equal to or less than that of the compressor using refrigerant oil “C” made of only the mineral oil having viscosity of 10 mm 2 /s at 40° C.
  • refrigerant oil “B” has a low viscosity resistance to make the friction loss low.
  • the low viscosity of refrigerant oil “B” causes refrigerant oil “B” to flow out from the gap between compression chamber 113 and piston 115 . This reduces the sealing effect for the gap between compression chamber 113 and piston 115 , thereby causing a leakage of refrigerant 102 .
  • the reason for the high efficiency of the compressor using refrigerant oil “A” is considered as follows.
  • the mineral oil having viscosity as high as 20 mm 2 /s at 40° C. reduces the amount of refrigerant oil “A” flowing out from the gap between compression chamber 113 and piston 115 .
  • the low-viscosity oil reduces friction loss.
  • refrigerant oil 103 prevents a reduction in the sealing effect between compression chamber 113 and piston 115 .
  • Different refrigerant oils having viscosity of 8 mm 2 /s or less at 40° C. are prepared by mixing an oil having viscosity lower than 7.5 mm 2 /s at 40° C. as the first refrigerant oil with an oil having viscosity higher than 20 mm 2 /s at 40° C. as the second refrigerant oil. Then, these different refrigerant oils having viscosity of 8 mm 2 /s or less at 40° C. are used to analyze the efficiencies of compressors. As a result, these refrigerant oils having viscosity of 8 mm 2 /s or less at 40° C. have similar effects to refrigerant oil “A” which is superior to refrigerant oils “B” and “C”.
  • compression chamber 113 and piston 115 sliding along each other can be abraded, causing an increase in the gap between them. Even so, the oil-sealing effect for the sliding portion between compression chamber 113 and piston 115 can be secured to maintain high efficiency.
  • the first refrigerant oil having viscosity of less than 8 mm 2 /s at 40° C. is mineral oil.
  • the first refrigerant oil may be ester oil or hard alkyl benzene oil.
  • the second refrigerant oil having viscosity of 20 mm 2 /s or more at 40° C. is mineral oil.
  • the second refrigerant oil may be ester oil, hard alkyl benzene oil, a poly- ⁇ -olefin oil, or a polyalkylene glycol oil.
  • Refrigerant compressors in which the diameter difference between compression chamber 113 and piston 115 is set to 15 ⁇ m are operated for 500 hours at a condensation temperature of 54.4° C. and an evaporation temperature of ⁇ 23.3° C.
  • refrigerant oil “B” having viscosity of 8 mm 2 /s at 40° C.
  • oligomer that seems to have been extracted from muffler 122 has been observed on valve member 120 .
  • no deposits such as oligomer or oil sludge have been observed in the refrigerant compressor using refrigerant oil “A” which is a mixture of mineral oil having viscosity of 7.5 mm 2 /s at 40° C. as the first refrigerant oil, and 3 wt % or more of mineral oil having viscosity of 20 mm 2 /s at 40° C. as the second refrigerant oil.
  • the reason for this is considered as follows.
  • the mineral oil having viscosity of 20 mm 2 /s at 40° C. reduces the evaporation of refrigerant oil 103 , thereby preventing oligomer or oil sludge from remaining on valve member 120 , which is raised to high temperature.
  • the weight percentage of the second refrigerant oil is made greater than 3 wt % so as to further reduce the evaporation, thereby increasing the effect of preventing the deposition of oligomer on valve member 120 .
  • Different refrigerant oils having viscosity of 8 mm 2 /s or less at 40° C. are prepared by mixing an oil having viscosity lower than 7.5 mm 2 /s at 40° C. as the first refrigerant oil and an oil having viscosity higher than 20 mm 2 /s at 40° C. as the second refrigerant oil. Then, these different refrigerant oils having viscosity of 8 mm 2 /s or less at 40° C. have been tested and found that no deposits such as oligomer or oil sludge are observed when the content of the second refrigerant oil is 3 wt % or more.
  • refrigerant oil “A” which is a mixture of mineral oil having viscosity of less than 8 mm 2 /s at 40° C. and 3 wt % or more of an oil having viscosity of 20 mm 2 /s or more at 40° C.
  • R134a which is an HFC refrigerant
  • R600a which is an HC refrigerant
  • refrigerant oil of the present invention having ester oil, mineral oil, or hard alkyl benzene oil as base oil so as to test their compatibility.
  • Table 2 indicates that all the combinations between the refrigerants and the refrigerant oils show good results, causing no oil sludge or other deposits.
  • a reliable refrigerant compressor can be achieved by combining either an HFC refrigerant or an HC refrigerant with refrigerant oil having ester oil, mineral oil, or hard alkyl benzene oil as base oil without degradation of the refrigerant oil.
  • ester oil mineral oil, and hard alkyl benzene oil to obtain the same effect.
  • Refrigerant oil 103 may be added with an antioxidant to prevent degradation of refrigerant oil 103 when exposed to a high-temperature high-humidity environment during storage, thereby achieving a reliable refrigerant compressor.
  • Refrigerant oil 103 may be added with an extreme-pressure additive such as tricresyl phosphate that undergoes a chemical reaction to form a film on a metal surface. This reduces the abrasion of the sliding portions, thereby achieving a reliable refrigerant compressor.
  • an extreme-pressure additive such as tricresyl phosphate that undergoes a chemical reaction to form a film on a metal surface. This reduces the abrasion of the sliding portions, thereby achieving a reliable refrigerant compressor.
  • Refrigerant oil 103 may be added with an oil agent that can absorb a metal physically or chemically, such as higher fatty acid, higher alcohol, or a compound having an ester group.
  • an oil agent that can absorb a metal physically or chemically, such as higher fatty acid, higher alcohol, or a compound having an ester group.
  • the addition of such an oil agent can reduce the deposition of oligomer onto the metal surface if the oligomer is extracted from muffler 122 , thereby reducing the blockage of the passage of refrigerant 102 in the refrigeration cycle. This results in a reliable refrigerant compressor.
  • the efficient and reliable refrigerant compressor according to the embodiment of the present invention is achieved by setting the diameter difference between compression chamber 113 and piston 115 to the range of not shorter than 4 ⁇ m to not longer than 15 ⁇ m, and by using refrigerant oil 103 having viscosity of 8 mm 2 /s or less at 40° C.
  • Refrigerant oil 103 is a mixture of the first refrigerant oil having viscosity of less than 8 mm 2 /s at 40° C. and the second refrigerant oil having viscosity of 20 mm 2 /s or more at 40° C.
  • the refrigerant compressor of the present invention has high efficiency and therefore is applicable to a device having a refrigeration cycle.

Abstract

A refrigerant compressor includes a hermetic container storing refrigerant oil an electrically-driven element and a compressing element driven by the electrically-driven element. The compressing element includes a cylinder block having a cylindrical compression chamber and a cylindrical piston reciprocating in the compression chamber. The compression chamber and the piston have a diameter difference in the range of not shorter than 4 μm to not longer than 15 μm. The refrigerant oil has viscosity of 8 mm2/s or less at 40° C. and is prepared by mixing a first refrigerant oil having viscosity of less than 8 mm2/s at 40° C. with a second refrigerant oil having viscosity of 20 mm2/s or more at 40° C.

Description

    TECHNICAL FIELD
  • The present invention relates to a refrigerant compressor.
  • BACKGROUND ART
  • In recent years, the efficiency of refrigerant compressors has been improved by using a low-viscosity refrigerant oil so as to reduce the input (see, for example, Patent Document 1 shown below).
  • The conventional refrigerant compressor disclosed in Patent Document 1 is described as follows with reference to FIG. 2 showing a longitudinal sectional view of the refrigerant compressor.
  • As shown in FIG. 2, the refrigerant compressor includes hermetic container 1, which is filled with refrigerant 2 and stores refrigerant oil 3 at its bottom. Hermetic container 1 accommodates electrically-driven element 6 and reciprocating compressing element 7 driven by electrically-driven element 6. Electrically-driven element 6 includes stator 4 and rotor 5. Refrigerant 2 is made of R600a, which is a hydrocarbon refrigerant.
  • Compressing element 7 is described in detail as follows.
  • Compressing element 7 includes crankshaft 8. Crankshaft 8 includes main shaft 9 to which rotor 5 is fixedly fitted, and eccentric shaft 10 is eccentric to main shaft 9. Crankshaft 8 is also provided at its bottom with lubrication pump 11 for lifting refrigerant oil 3.
  • Compressing element 7 further includes cylinder block 12. Cylinder block 12 includes a nearly cylindrical compression chamber 13, and bearing 14 for supporting main shaft 9.
  • Compressing element 7 further includes piston 15 loosely fitted into compression chamber 13. Piston 15 is connected to eccentric shaft 10 via piston pin 16 by connecting rod 17, which is a connection means. The end face of compression chamber 13 is tightly sealed by valve plate 18.
  • Compressing element 7 further includes head 19 forming an unillustrated high-pressure chamber. Head 19 is fixed on the other side of compression chamber 13 with respect to valve plate 18. Hermetic container 1 further includes muffler 20 sandwiched between valve plate 18 and head 19.
  • Hermetic container 1 further includes suction tube 21 and discharge tube 22 which are fixed thereto and connected to an unillustrated refrigeration cycle. Suction tube 21 guides refrigerant 2 into hermetic container 1, and discharge tube 22 sends refrigerant 2 to the refrigeration cycle.
  • The refrigerant compressor thus structured has the following operation and effects.
  • An unillustrated commercial power supply supplies power to electrically-driven element 6 so as to rotate rotor 5 of electrically-driven element 6, thereby rotating crankshaft 8. As a result, eccentric shaft 10 performs eccentric movement, allowing connecting rod 17 as the connection means to drive piston 15 via piston pin 16. This makes piston 15 reciprocate in compression chamber 13. Refrigerant 2 is guided into hermetic container 1 through suction tube 21 via an unillustrated suction reed from the refrigeration cycle. Refrigerant 2 is then suctioned through muffler 20 and continuously compressed in compression chamber 13. Refrigerant 2 thus compressed is discharged via an unillustrated discharge valve and sent through discharge tube 22 to the refrigeration cycle.
  • During these operations, refrigerant oil 3 is pumped by lubrication pump 11 of crankshaft 8 so as to lubricate sliding portions such as main shaft 9 and piston 15.
  • In the conventional refrigerant compressor, it has been attempted to achieve high efficiency by using refrigerant oil 3 having viscosity of less than 8 mm2/s at 40° C. so as to have a low friction loss in sliding portions of the refrigerant compressor, such as between compression chamber 13 and piston 15 and between crankshaft 8 and bearing 14.
  • In the conventional refrigerant compressor, however, refrigerant oil 3 has viscosity as low as less than 8 mm2/s at 40° C. and therefore a sufficient amount thereof cannot be held between compression chamber 13 and piston 15. This causes refrigerant 2 to leak from the gap between compression chamber 13 and piston 15, thereby increasing leakage loss.
  • The leakage of refrigerant 2 from the gap between compression chamber 13 and piston 15 can be decreased by reducing the gap. However, too small a gap causes the outer wall of piston 15 and the inner wall of compression chamber 13 to be brought into contact with each other and to be abraded when compressed refrigerant 2 has caused an increase of the ambient temperature.
  • Patent Document 1: Japanese Patent Unexamined Publication No. S62-059695
  • SUMMARY OF THE INVENTION
  • The refrigerant compressor of the present invention includes a hermetic container storing refrigerant oil; an electrically-driven element; and a compressing element driven by the electrically-driven element. The compressing element includes a cylinder block having a cylindrical compression chamber and a cylindrical piston reciprocating in the compression chamber. The compression chamber and the piston have a diameter difference in the range of not shorter than 4 μm to not longer than 15 μm. The refrigerant oil has viscosity of 8 mm2/s or less at 40° C. and is prepared by mixing a first refrigerant oil having viscosity of less than 8 mm2/s at 40° C. with a second refrigerant oil having viscosity of 20 mm2/s or more at 40° C.
  • In the refrigerant compressor, the refrigerant oil has a low viscosity resistance to make the friction loss small. At the same time, a sufficient amount of the refrigerant oil can be held between the compression chamber and the piston so as to have a low leakage loss of the refrigerant. Furthermore, the diameter difference between the compression chamber and the piston can be optimized to prevent abrasion between them which is caused by their contact. These features result in an efficient and reliable refrigerant compressor.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a longitudinal sectional view of a refrigerant compressor according to an embodiment of the present invention.
  • FIG. 2 is a longitudinal sectional view of a conventional refrigerant compressor.
  • REFERENCE MARKS IN THE DRAWINGS
      • 100 refrigerant compressor
      • 101 hermetic container
      • 102 refrigerant
      • 103 refrigerant oil
      • 106 electrically-driven element
      • 107 compressing element
      • 112 cylinder block
      • 113 compression chamber
      • 115 piston
    DETAILED DESCRIPTION OF PREFERRED EMBODIMENT
  • An embodiment of the present invention is described as follows with reference to drawings. Note that the present invention is not limited to this embodiment.
  • EMBODIMENT
  • FIG. 1 is a longitudinal sectional view of a refrigerant compressor according to the embodiment of the present invention.
  • As shown in FIG. 1, refrigerant compressor 100 includes hermetic container 101, which is filled with refrigerant 102 and stores refrigerant oil 103 at its bottom. Refrigerant compressor 100 further includes electrically-driven element 106 and reciprocating compressing element 107 driven by electrically-driven element 106. Electrically-driven element 106 includes stator 104 and rotor 105.
  • Compressing element 107 is described in detail as follows.
  • Compressing element 107 includes crankshaft 108 made of ferrous metal. Crankshaft 108 includes main shaft 109 to which rotor 105 is fixedly fitted, and eccentric shaft 110 eccentric to main shaft 109. Crankshaft 108 is also provided at its bottom with lubrication pump 111 for lifting refrigerant oil 103. Compressing element 107 further includes cylinder block 112. Cylinder block 112 includes nearly cylindrical compression chamber 113 and bearing 114 for supporting main shaft 109.
  • Compressing element 107 further includes piston 115 made of ferrous metal and loosely fitted into compression chamber 113. Piston 115 is connected to eccentric shaft 110 via piston pin 116 by connecting rod 117, which is a connection means.
  • The end face of compression chamber 113 is tightly sealed by valve plate 118. Valve plate 118 is made of laminated spring steel and forms valve member 120 composed of suction reed 119 for opening and closing an unillustrated suction port.
  • Compressing element 107 further includes head 121 which is fixed on the other side of compression chamber 113 with respect to valve plate 118. Hermetic container 101 further includes muffler 122 sandwiched between valve plate 118 and head 121.
  • Muffler 122 is made of polybutylene terephthalate mixed with glass fiber.
  • Hermetic container 101 further includes suction tube 123 and discharge tube 124 which are fixed thereto and connected to an unillustrated refrigeration cycle. Suction tube 123 guides refrigerant 102 into hermetic container 101, and discharge tube 124 sends refrigerant 102 to the refrigeration cycle.
  • The refrigerant compressor thus structured has the following operation and effects.
  • An unillustrated commercial power supply supplies power to electrically-driven element 106 so as to rotate rotor 105 of electrically-driven element 106, thereby rotating crankshaft 108. As a result, eccentric shaft 110 performs eccentric movement, allowing connecting rod 117 to drive piston 115 via piston pin 116. This makes piston 115 reciprocate in compression chamber 113.
  • Refrigerant 102 is guided into hermetic container 101 through suction tube 123 and then suctioned into compression chamber 113 through muffler 122. Refrigerant 102 suctioned into compression chamber 113 is continuously compressed. Refrigerant 102 thus compressed is sent to the refrigeration cycle through discharge tube 124. Refrigerant 102 sent to the refrigeration cycle is guided again into hermetic container 101 through suction tube 123.
  • During these operations, refrigerant oil 103 is pumped by lubrication pump 111 of crankshaft 108 so as to lubricate sliding portions such as main shaft 109 and piston 115.
  • The following is a description, with reference to Table 1, of the relation between the diameter difference between compression chamber 113 and piston 115, the type of refrigerant oil, and the efficiency of the compressor.
  • Table 1 shows the results of the efficiency analysis of refrigerant compressors having the same specification with piston 115 of a 30 mm outer diameter. The analysis is performed by changing the diameter differences between compression chamber 113 and piston 115 and using three types of refrigerant oils.
  • Refrigerant oil “A” is refrigerant oil 103 used in the refrigerant compressor according to the embodiment of the present invention. Refrigerant oil “A” has viscosity of 8 mm2/s at 40° C. and is prepared by mixing mineral oil having viscosity of 7.5 mm2/s at 40° C. as a first refrigerant oil with 3 wt % of mineral oil having viscosity of 20 mm2/s at 40 C as a second refrigerant oil.
  • Refrigerant oil “B”, which is used to be compared with refrigerant oil “A”, is mineral oil having viscosity of 8 mm2/s at 40° C.
  • Refrigerant oil “C”, which is also used to be compared with refrigerant oil “A”, is mineral oil having viscosity of 10 mm2/s at 40° C.
  • The analysis is performed at a condensation temperature of 54.4° C. and an evaporation temperature of −23.3° C. The efficiencies of three refrigerant compressors are compared by using R600a as a refrigerant and by changing the diameter difference between compression chamber 113 and piston 115 in the range of not shorter than 4 μm to not longer than 18 μm.
  • TABLE 1
    diameter difference
    between compression
    chamber and piston (μm)
    refrigerant oil 4 8 10 12 15 18
    refrigerant oil “A”
    (the present invention)
    refrigerant oil “B” Δ Δ Δ Δ Δ Δ
    refrigerant oil “C” standard
    Note:
    ◯ indicates the compressor efficiency is higher than in the case of refrigerant oil “C”, and
    Δ indicates the compressor efficiency is equal to or less than in the case of refrigerant oil “C”.
  • Table 1 indicates that when the diameter difference between compression chamber 113 and piston 115 is in the range of not shorter than 4 μm to not longer than 18 μm, the efficiency of the compressor using refrigerant oil “B” made of only the mineral oil having viscosity of 8 mm2/s at 40° C. is equal to or less than that of the compressor using refrigerant oil “C” made of only the mineral oil having viscosity of 10 mm2/s at 40° C.
  • The reason for the low efficiency of the compressor using refrigerant oil “B” is considered as follows. Refrigerant oil “B” has a low viscosity resistance to make the friction loss low. However, the low viscosity of refrigerant oil “B” causes refrigerant oil “B” to flow out from the gap between compression chamber 113 and piston 115. This reduces the sealing effect for the gap between compression chamber 113 and piston 115, thereby causing a leakage of refrigerant 102.
  • On the other hand, the compressor using refrigerant oil “A”, which is refrigerant oil 103 used in the refrigerant compressor according to the embodiment of the present invention, has a higher efficiency than the compressor using refrigerant oil “C” when the diameter difference between compression chamber 113 and piston 115 is in the range of not shorter than 4 μm to not longer than 15 μm.
  • The reason for the high efficiency of the compressor using refrigerant oil “A” is considered as follows. The mineral oil having viscosity as high as 20 mm2/s at 40° C. reduces the amount of refrigerant oil “A” flowing out from the gap between compression chamber 113 and piston 115. On the other hand, the low-viscosity oil reduces friction loss. In addition, refrigerant oil 103 prevents a reduction in the sealing effect between compression chamber 113 and piston 115.
  • Although detailed results are not available, the following has been performed. Different refrigerant oils having viscosity of 8 mm2/s or less at 40° C. are prepared by mixing an oil having viscosity lower than 7.5 mm2/s at 40° C. as the first refrigerant oil with an oil having viscosity higher than 20 mm2/s at 40° C. as the second refrigerant oil. Then, these different refrigerant oils having viscosity of 8 mm2/s or less at 40° C. are used to analyze the efficiencies of compressors. As a result, these refrigerant oils having viscosity of 8 mm2/s or less at 40° C. have similar effects to refrigerant oil “A” which is superior to refrigerant oils “B” and “C”.
  • Thus, setting the diameter difference between compression chamber 113 and piston 115 to the range of not shorter than 4 μm to not longer than 15 μm prevents abrasion between compression chamber 113 and piston 115 which is caused when the gap between them is too small. Furthermore, the refrigerant oil having a low viscosity prevents friction loss, and the second refrigerant oil prevents a decrease in the sealing effect between compression chamber 113 and piston 115. These features result in an efficient refrigerant compressor.
  • Particularly when a refrigerant compressor has been operated for a long time, compression chamber 113 and piston 115 sliding along each other can be abraded, causing an increase in the gap between them. Even so, the oil-sealing effect for the sliding portion between compression chamber 113 and piston 115 can be secured to maintain high efficiency.
  • When a low-viscosity oil having viscosity of less than 8 mm2/s at 40° C. is used as the first refrigerant oil in order to reduce the friction loss in sliding portions or other portions, it is possible to use a high-viscosity oil having viscosity of 20 mm2/s or more at 40° C. as the second refrigerant oil to obtain the same effect as refrigerant oil “A”. It goes without saying that there are numerous viscosity combinations and numerous mixing ratios between the first and second refrigerant oils.
  • In the refrigerant compressor according to the embodiment of the present invention, the first refrigerant oil having viscosity of less than 8 mm2/s at 40° C. is mineral oil. Alternatively, the first refrigerant oil may be ester oil or hard alkyl benzene oil.
  • In the refrigerant compressor according to the embodiment of the present invention, the second refrigerant oil having viscosity of 20 mm2/s or more at 40° C. is mineral oil. Alternatively, the second refrigerant oil may be ester oil, hard alkyl benzene oil, a poly-α-olefin oil, or a polyalkylene glycol oil.
  • Refrigerant compressors in which the diameter difference between compression chamber 113 and piston 115 is set to 15 μm are operated for 500 hours at a condensation temperature of 54.4° C. and an evaporation temperature of −23.3° C. As a result, in the refrigerant compressor using refrigerant oil “B” having viscosity of 8 mm2/s at 40° C., oligomer that seems to have been extracted from muffler 122 has been observed on valve member 120. On the other hand, no deposits such as oligomer or oil sludge have been observed in the refrigerant compressor using refrigerant oil “A” which is a mixture of mineral oil having viscosity of 7.5 mm2/s at 40° C. as the first refrigerant oil, and 3 wt % or more of mineral oil having viscosity of 20 mm2/s at 40° C. as the second refrigerant oil.
  • The reason for this is considered as follows. The mineral oil having viscosity of 20 mm2/s at 40° C. reduces the evaporation of refrigerant oil 103, thereby preventing oligomer or oil sludge from remaining on valve member 120, which is raised to high temperature.
  • In addition, the weight percentage of the second refrigerant oil is made greater than 3 wt % so as to further reduce the evaporation, thereby increasing the effect of preventing the deposition of oligomer on valve member 120.
  • Although detailed results are not available, the following has been performed. Different refrigerant oils having viscosity of 8 mm2/s or less at 40° C. are prepared by mixing an oil having viscosity lower than 7.5 mm2/s at 40° C. as the first refrigerant oil and an oil having viscosity higher than 20 mm2/s at 40° C. as the second refrigerant oil. Then, these different refrigerant oils having viscosity of 8 mm2/s or less at 40° C. have been tested and found that no deposits such as oligomer or oil sludge are observed when the content of the second refrigerant oil is 3 wt % or more.
  • Thus, a reliable compressor causing no deposition of oligomer onto the valve member and other portions can be provided by using refrigerant oil “A” which is a mixture of mineral oil having viscosity of less than 8 mm2/s at 40° C. and 3 wt % or more of an oil having viscosity of 20 mm2/s or more at 40° C.
  • Next, the compatibility between refrigerants and refrigerant oils of the present invention are described as follows with reference to Table 2. R134a which is an HFC refrigerant and R600a which is an HC refrigerant are aged in hermetic container 101 for 14 days at 140° C. with refrigerant oil of the present invention having ester oil, mineral oil, or hard alkyl benzene oil as base oil so as to test their compatibility.
  • TABLE 2
    refrigerant
    R134a R600a
    refrigerant ester mineral hard ester mineral hard
    oil oil oil alkyl oil oil alkyl
    benzene benzene
    oil oil
    degradation no degradation
    of refrigerant
    oil
  • Table 2 indicates that all the combinations between the refrigerants and the refrigerant oils show good results, causing no oil sludge or other deposits.
  • In other words, a reliable refrigerant compressor can be achieved by combining either an HFC refrigerant or an HC refrigerant with refrigerant oil having ester oil, mineral oil, or hard alkyl benzene oil as base oil without degradation of the refrigerant oil.
  • Alternatively, it is possible to mix ester oil, mineral oil, and hard alkyl benzene oil to obtain the same effect.
  • Refrigerant oil 103 may be added with an antioxidant to prevent degradation of refrigerant oil 103 when exposed to a high-temperature high-humidity environment during storage, thereby achieving a reliable refrigerant compressor.
  • Refrigerant oil 103 may be added with an extreme-pressure additive such as tricresyl phosphate that undergoes a chemical reaction to form a film on a metal surface. This reduces the abrasion of the sliding portions, thereby achieving a reliable refrigerant compressor.
  • Refrigerant oil 103 may be added with an oil agent that can absorb a metal physically or chemically, such as higher fatty acid, higher alcohol, or a compound having an ester group. The addition of such an oil agent can reduce the deposition of oligomer onto the metal surface if the oligomer is extracted from muffler 122, thereby reducing the blockage of the passage of refrigerant 102 in the refrigeration cycle. This results in a reliable refrigerant compressor.
  • As described hereinbefore, the efficient and reliable refrigerant compressor according to the embodiment of the present invention is achieved by setting the diameter difference between compression chamber 113 and piston 115 to the range of not shorter than 4 μm to not longer than 15 μm, and by using refrigerant oil 103 having viscosity of 8 mm2/s or less at 40° C. Refrigerant oil 103 is a mixture of the first refrigerant oil having viscosity of less than 8 mm2/s at 40° C. and the second refrigerant oil having viscosity of 20 mm2/s or more at 40° C.
  • INDUSTRIAL APPLICABILITY
  • As described above, the refrigerant compressor of the present invention has high efficiency and therefore is applicable to a device having a refrigeration cycle.
  • REFERENCE MARKS IN THE DRAWINGS
      • 100 refrigerant compressor
      • 101 hermetic container
      • 102 refrigerant
      • 103 refrigerant oil
      • 106 electrically-driven element
      • 107 compressing element
      • 112 cylinder block
      • 113 compression chamber
      • 115 piston

Claims (6)

1. A refrigerant compressor comprising:
a hermetic container storing refrigerant oil;
an electrically-driven element; and
a compressing element driven by the electrically-driven element, the compressing element including a cylinder block having a cylindrical compression chamber and a cylindrical piston reciprocating in the compression chamber, wherein
the compression chamber and the piston have a diameter difference in a range of not shorter than 4 μm to not longer than 15 μm, and
the refrigerant oil has viscosity of not more than 8 mm2/s at 40° C. and is prepared by mixing a first refrigerant oil having viscosity of less than 8 mm2/s at 40° C. with a second refrigerant oil having viscosity of not less than 20 mm2/s at 40° C.
2. The refrigerant compressor of claim 1, wherein
the refrigerant oil contains the second refrigerant oil of not less than 3 wt %.
3. The refrigerant compressor of claim 1, wherein
a refrigerant to be compressed in the compression chamber is one of an HFC refrigerant and an HC refrigerant, and
the refrigerant oil contains one of ester oil, mineral oil, and hard alkyl benzene oil as base oil.
4. The refrigerant compressor of claim 1, wherein
an antioxidant is added to the refrigerant oil.
5. The refrigerant compressor of claim 1, wherein
an extreme-pressure additive is added to the refrigerant oil.
6. The refrigerant compressor of claim 1, wherein
an oil agent is added to the refrigerant oil.
US12/374,725 2007-09-10 2008-04-10 Refrigerant compressor Abandoned US20100236282A1 (en)

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Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3538357A (en) * 1968-01-12 1970-11-03 Maurice Barthalon Fluid circulating apparatus for reciprocating machines
US3542495A (en) * 1965-09-24 1970-11-24 Maurice Barthalon Reciprocating electric motor
US4624630A (en) * 1984-03-08 1986-11-25 Mitsubishi Denki Kabushiki Kaisha Differential pressure lubrication system for rolling piston compressor
US5273410A (en) * 1989-12-28 1993-12-28 Kabushiki Kaisha Toshiba Compressor exhibiting an iron sulfide wear surface
US5458643A (en) * 1991-03-29 1995-10-17 Kyocera Corporation Artificial intervertebral disc
US5469777A (en) * 1994-07-05 1995-11-28 Ford Motor Company Piston assembly having abradable coating
US5548973A (en) * 1994-04-28 1996-08-27 Kabushiki Kaisha Toshiba Sealed type compressor and refrigerating cycle
US5653909A (en) * 1994-11-30 1997-08-05 Mitsubishi Denki Kabushiki Kaisha Refrigerating machine oil composition for use with HFC refrigerant
US5950451A (en) * 1996-12-19 1999-09-14 Samsung Electronics Co., Ltd. Reciprocating refrigerant compressor
US20020077255A1 (en) * 1988-12-06 2002-06-20 Yasuhiro Kawaguchi Lubricating oil for refrigerator with compressor
US20020077701A1 (en) * 2000-12-15 2002-06-20 Kuslich Stephen D. Annulus-reinforcing band
US20020193262A1 (en) * 1999-11-18 2002-12-19 Takashi Kaimai Lubricating oil composition for refrigerating machine, working fluid, and refrigerating machine
US6667285B1 (en) * 1999-05-10 2003-12-23 New Japan Chemical Co., Ltd. Lubricating oil for refrigerator, hydraulic fluid composition for refrigerator and method for lubricating of refrigerator
US7045490B2 (en) * 2000-07-24 2006-05-16 Nippon Oil Corporation Refrigerating machine oil composition
US20060216176A1 (en) * 2003-11-17 2006-09-28 Bitzer Kuehlmaschinenbau Gmbh Refrigerant compressor for motor vehicles
US20060265075A1 (en) * 2003-04-14 2006-11-23 Daniel Baumgartner Intervertebral implant
US20080174043A1 (en) * 2007-01-19 2008-07-24 Spinemedica Corporation Methods and systems for forming implants with selectively exposed mesh for fixation and related implants

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5527372A (en) * 1978-08-18 1980-02-27 Matsushita Refrig Co Refrigerator oil
JPS6162596A (en) * 1984-09-03 1986-03-31 Nippon Oil & Fats Co Ltd Oil for freezer
JPH09208980A (en) * 1996-02-02 1997-08-12 Nippon Oil Co Ltd Refrigerating machine oil composition and fluid composition for refrigerating machine
JP2002031059A (en) * 2000-07-17 2002-01-31 Zexel Valeo Climate Control Corp Reciprocating refrigerant compressor
US6777367B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
CN1928362A (en) * 2005-09-08 2007-03-14 松下电器产业株式会社 Refrigerant compressor, cooling system and refrigerator

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542495A (en) * 1965-09-24 1970-11-24 Maurice Barthalon Reciprocating electric motor
US3538357A (en) * 1968-01-12 1970-11-03 Maurice Barthalon Fluid circulating apparatus for reciprocating machines
US4624630A (en) * 1984-03-08 1986-11-25 Mitsubishi Denki Kabushiki Kaisha Differential pressure lubrication system for rolling piston compressor
US20020077255A1 (en) * 1988-12-06 2002-06-20 Yasuhiro Kawaguchi Lubricating oil for refrigerator with compressor
US5273410A (en) * 1989-12-28 1993-12-28 Kabushiki Kaisha Toshiba Compressor exhibiting an iron sulfide wear surface
US5458643A (en) * 1991-03-29 1995-10-17 Kyocera Corporation Artificial intervertebral disc
US5548973A (en) * 1994-04-28 1996-08-27 Kabushiki Kaisha Toshiba Sealed type compressor and refrigerating cycle
US5469777A (en) * 1994-07-05 1995-11-28 Ford Motor Company Piston assembly having abradable coating
US5653909A (en) * 1994-11-30 1997-08-05 Mitsubishi Denki Kabushiki Kaisha Refrigerating machine oil composition for use with HFC refrigerant
US5950451A (en) * 1996-12-19 1999-09-14 Samsung Electronics Co., Ltd. Reciprocating refrigerant compressor
US6667285B1 (en) * 1999-05-10 2003-12-23 New Japan Chemical Co., Ltd. Lubricating oil for refrigerator, hydraulic fluid composition for refrigerator and method for lubricating of refrigerator
US20020193262A1 (en) * 1999-11-18 2002-12-19 Takashi Kaimai Lubricating oil composition for refrigerating machine, working fluid, and refrigerating machine
US7045490B2 (en) * 2000-07-24 2006-05-16 Nippon Oil Corporation Refrigerating machine oil composition
US20020077701A1 (en) * 2000-12-15 2002-06-20 Kuslich Stephen D. Annulus-reinforcing band
US20060265075A1 (en) * 2003-04-14 2006-11-23 Daniel Baumgartner Intervertebral implant
US20060216176A1 (en) * 2003-11-17 2006-09-28 Bitzer Kuehlmaschinenbau Gmbh Refrigerant compressor for motor vehicles
US20080174043A1 (en) * 2007-01-19 2008-07-24 Spinemedica Corporation Methods and systems for forming implants with selectively exposed mesh for fixation and related implants

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