US20100025256A1 - Surface treatment method for housing - Google Patents
Surface treatment method for housing Download PDFInfo
- Publication number
- US20100025256A1 US20100025256A1 US12/504,768 US50476809A US2010025256A1 US 20100025256 A1 US20100025256 A1 US 20100025256A1 US 50476809 A US50476809 A US 50476809A US 2010025256 A1 US2010025256 A1 US 2010025256A1
- Authority
- US
- United States
- Prior art keywords
- housing
- surface treatment
- treatment method
- electrolyte
- electroplating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C25D3/06—Electroplating: Baths therefor from solutions of chromium from solutions of trivalent chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/36—Pretreatment of metallic surfaces to be electroplated of iron or steel
Abstract
Description
- 1. Technical Field
- The present disclosure relates to a surface treatment method for housings, especially to an electroplating method for metal housings.
- 2. Description of Related Art
- A typical surface treatment method now for portable electronic devices' housings is electroplating. Commonly, the housing is electroplated to form a trivalent chromium coating on its surface to present high gloss appearance and enhance abrasion resistance. To enhance the bonding between the trivalent chromium coating and the housing, the housing is electroplated with a nickel coating prior to the forming of the chromium coating. However, the nickel coating and the whole process of electroplating with nickel are not environmentally friendly because the nickel or nickel iron contained in the electrolyte is toxic.
- Therefore, there is room for improvement within the art.
- Many aspects of the surface treatment method for housing can be better understood with reference to the following drawing. The emphasis of the drawing is placed upon clearly illustrating the principles of the surface treatment for housing.
- The figure is a flow chart of an exemplary embodiment of a surface treatment method for a housing.
- Referring to the FIG, a surface treatment method for a housing may include the steps S10 to S50.
- In step S10, a metal housing is provided. The metal housing may be made of, e.g., stainless steel or copper. The metal housing may be a mobile phone, a digital camera, a personal digital assistant, or a note book computer's housing. The metal housing may also be a housing of a container.
- In step S20, the metal housing is pretreated. The pre-treating step may comprise one or more of the following: degreasing, electrochemical cleaning, and acid treating the housing.
- The degreasing process may be carried out by dipping the housing in a degreasing solution for about 5-15 minutes. The mass concentration of the degreasing agent is about 150-200 grams per liter (g/L). The temperature of the degreasing solution is about 55-65° C.
- After the degreasing process, the housing is removed from the degreasing solution to be electrochemically cleaned. Electrochemical cleaning the housing may be carried out in a first electrolyte. The first electrolyte may contain a sodium hydroxide component in a mass concentration of about 100-200 g/L and an activating agent(s) component in a mass concentration of about 40-80 g/L. The activating agent(s) may be dodecyl sulfonic acid sodium salt. The temperature of the first electrolyte is about 55-65° C. The electric current density through the first electrolyte is about 1-5 A/dm2. Electrochemically cleaning the housing may last for about 4-10 minutes. The electrochemical cleaning step can further remove lipids adhering to the housing and smudges.
- After the electrochemical cleaning process, the housing is dipped in a sulfuric acid solution for about 1-5 minutes to remove the residual basic liquid adhering to the housing's surface. The concentration by volume of the sulfuric acid in the solution is about 50-80 ml/L. The temperature of the sulfuric acid solution is about 20-30° C. After the acid treatment, the housing is water washed; in this embodiment the housing is water washed three times.
- In step S30, the housing is electroplated to form a hexavalent chromium coating on its surface. Electroplating the housing to form the hexavalent chromium coating may be carried out in a second electrolyte, with the metalized surface of the housing being a cathode, and a stannum (Sn) plumbum (Pb) alloy anode being provided and immersed in the second electrolyte. The second electrolyte may contain a chromium acid (H2CrO4) component in a mass concentration of about 240-350 g/L and a sulfuric acid component in a mass concentration of about 2-4 g/L. The second electrolyte may further contain additive agent(s), such as fluoride. The additive agent(s) may improve the forming of the hexavalent chromium coating on the surface of the housing. The mass concentration of the additive agent(s) in the second electrolyte is about 5-10 g/L. The electric current density through the second electrolyte is about 10-30 A/dm2. Electroplating the housing with the hexavalent chromium coating may last for about 1-15 minutes. The hexavalent chromium coating bonds well with the housing because of having similar properties as copper or stainless steel. After the electroplating, the housing is bathed in water.
- In step S40, the housing is electroplated to form a trivalent chromium coating on the hexavalent chromium coating. Electroplating the housing to form the trivalent chromium coating may be carried out in a third electrolyte, with the metalized surface of the housing being a cathode, and a iridium (Ir) tantalum (Ta) alloy anode being provided and immersed in the third electrolyte. The third electrolyte may contain a chromium sulphate (Cr2(SO4)3) component in a mass concentration of about 240-300 g/L, and a boric acid component in a mass concentration of about 70-90 g/L. The third electrolyte may further contain additive agent(s) such as bromide and formate. The mass concentration of the bromide in the third electrolyte is about 15-20 g/L, and the mass concentration of the formate is about 70-90 g/L. The mass concentration of the trivalent chromium iron in the third electrolyte is about 3-10 g/L. The electric current density through the third electrolyte is about 5-15 A/dm2. Electroplating the housing with the trivalent chromium coating may last for about 1-15 minutes. The trivalent chromium coating bond well with the hexavalent chromium coating for the two coatings are all contain the chromium element. The trivalent chromium coating being formed on the hexavalent chromium coating prevents the problem that the trivalent chromium coating is tend to split for directly formed on the surface of the housing.
- After electroplating, the housing is again bathed in water.
- In step S50, the housing is subjected to neutralization treatment. The neutralization treatment is carried out by dipping the housing in a neutralization solution for about 1-3 minutes to remove any residual electrolyte adhering to the housing. The neutralization solution includes a sulfuric acid component in a concentration by volume of about 20-50 ml/L, and an oxydol component in a concentration by volume of about 50-100 ml/L. The temperature of the neutralization solution is about 20-30° C. After receiving neutralization treatment, the housing is bathed once more in water.
- The surface treatment method for housing described above forms a hexavalent chromium coating on the surface of the housing prior to forming the trivalent chromium coating, which prevents the tendency of the trivalent chromium coating to split when directly formed on the surface of the housing, and enhances the bonding between the trivalent chromium and the housing. The two chromium coatings can further enhance the rigidity of the housing and make the housing present more glossy appearance, thus producing better protected parts of the housing. Moreover, the two coatings do not contain nickel and so are more environmentally friendly.
- It is believed that the present embodiment and its advantages will be understood from the foregoing description, and it will be apparent that various changes may be made thereto without departing from the spirit and scope of the disclosure or sacrificing all of its advantages, the examples hereinbefore described merely being preferred or exemplary embodiment of the disclosure.
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810303201.3 | 2008-07-30 | ||
CN200810303201A CN101638801A (en) | 2008-07-30 | 2008-07-30 | Method for processing surface of shell |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100025256A1 true US20100025256A1 (en) | 2010-02-04 |
Family
ID=41327686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/504,768 Abandoned US20100025256A1 (en) | 2008-07-30 | 2009-07-17 | Surface treatment method for housing |
Country Status (3)
Country | Link |
---|---|
US (1) | US20100025256A1 (en) |
EP (1) | EP2157212A3 (en) |
CN (1) | CN101638801A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100048300A1 (en) * | 2008-08-19 | 2010-02-25 | Capio Oliver R | Audience-condition based media selection |
US20170073991A1 (en) * | 2010-12-10 | 2017-03-16 | Hayward Industries, Inc. | Power Supplies For Pool And Spa Equipment |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3042592A (en) * | 1959-06-05 | 1962-07-03 | Gen Dev Corp | Power supply for chromium plating |
US3414492A (en) * | 1965-12-14 | 1968-12-03 | Corillium Corp | Chromium plating process |
US4022703A (en) * | 1975-01-14 | 1977-05-10 | Produits Chimiques Ugine Kuhlmann | Stabilization of hydrogen peroxide in acid baths for cleaning metals |
US5110035A (en) * | 1990-02-01 | 1992-05-05 | Westinghouse Electric Corp. | Method for improving the solderability of corrosion resistant heat exchange tubing |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2038361B (en) * | 1978-11-11 | 1983-08-17 | Ibm | Trivalent chromium plating bath |
DE19529843A1 (en) * | 1995-08-12 | 1997-02-13 | Marco Santini | Galvanic chrome plating process |
ATE507328T1 (en) * | 2006-10-24 | 2011-05-15 | Wolf-Dieter Franz | GRAY CHROME SURFACES |
CN101555614B (en) * | 2008-04-11 | 2011-03-30 | 深圳富泰宏精密工业有限公司 | Plastic surface galvanizing method |
-
2008
- 2008-07-30 CN CN200810303201A patent/CN101638801A/en active Pending
-
2009
- 2009-07-17 US US12/504,768 patent/US20100025256A1/en not_active Abandoned
- 2009-07-22 EP EP09166155.3A patent/EP2157212A3/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3042592A (en) * | 1959-06-05 | 1962-07-03 | Gen Dev Corp | Power supply for chromium plating |
US3414492A (en) * | 1965-12-14 | 1968-12-03 | Corillium Corp | Chromium plating process |
US4022703A (en) * | 1975-01-14 | 1977-05-10 | Produits Chimiques Ugine Kuhlmann | Stabilization of hydrogen peroxide in acid baths for cleaning metals |
US5110035A (en) * | 1990-02-01 | 1992-05-05 | Westinghouse Electric Corp. | Method for improving the solderability of corrosion resistant heat exchange tubing |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100048300A1 (en) * | 2008-08-19 | 2010-02-25 | Capio Oliver R | Audience-condition based media selection |
US20170073991A1 (en) * | 2010-12-10 | 2017-03-16 | Hayward Industries, Inc. | Power Supplies For Pool And Spa Equipment |
Also Published As
Publication number | Publication date |
---|---|
EP2157212A3 (en) | 2014-03-12 |
CN101638801A (en) | 2010-02-03 |
EP2157212A2 (en) | 2010-02-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SHENZHEN FUTAIHONG PRECISION INDUSTRY CO., LTD.,CH Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SU, JONG-YI;CHEN, CHENG-SHIN;WANG, REN-NING;AND OTHERS;REEL/FRAME:022969/0437 Effective date: 20090620 Owner name: FIH (HONG KONG) LIMITED,HONG KONG Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SU, JONG-YI;CHEN, CHENG-SHIN;WANG, REN-NING;AND OTHERS;REEL/FRAME:022969/0437 Effective date: 20090620 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |