US20090236095A1 - Method of cementing gas or oil pipeline and hydraulic cement slurry - Google Patents
Method of cementing gas or oil pipeline and hydraulic cement slurry Download PDFInfo
- Publication number
- US20090236095A1 US20090236095A1 US12/441,249 US44124907A US2009236095A1 US 20090236095 A1 US20090236095 A1 US 20090236095A1 US 44124907 A US44124907 A US 44124907A US 2009236095 A1 US2009236095 A1 US 2009236095A1
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- US
- United States
- Prior art keywords
- silica
- cement
- microfine
- cement slurry
- hydraulic cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices, or the like
- E21B33/138—Plastering the borehole wall; Injecting into the formation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
- C09K8/467—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices, or the like
- E21B33/14—Methods or devices for cementing, for plugging holes, crevices, or the like for cementing casings into boreholes
Definitions
- the present invention is concerned with the cementation of steel pipes or other structures in oil and gas well such as casings and liners.
- a cement slurry In the cementation of oil wells, a cement slurry is usually pumped down into a casing and placed into the annular space between the outside of the casing and wall of the well.
- the two most important purposes of the cementation process are to prevent the transport of gas and liquid between subterranean formations and to tie up and support the casing pipe.
- the cement In addition to sealing oil, gas and water producing formations, the cement also protects the casing against corrosion, and prevents gas- or oil-blow-outs as the cement slurry seals the well very quickly and impermeably.
- SR strength-retrogression
- Strength-retrogression is easily identified through a quick and early compressive-strength decrease and set-cement permeability increase over time at temperature above 110 deg C. When no decrease of compressive strength and no increase in set-cement permeability can be observed, it is then concluded that no strength-retrogression is taking place.
- BWOC cement
- liquid suspension of silica have been commercialised as an alternative to completely dry-blending operations. These liquid additives have proven effective in preventing SR when used at an equivalent 35% BWOC total silica. They have shown some advantages over dry-blending operations, especially in offshore or remote operations when only the deepest casings/liners require the use of silica to stabilise the Portland cement or other.
- the well temperatures lie in the range 100° C. to 150° C. It has been observed by the present inventors that at these well temperatures, a different approach to the use of silica as a cement slurry additive can be adopted.
- a method of cementing a casing of an oil or gas pipeline to a surrounding well wall which comprises forming an hydraulic cement slurry, deploying the slurry in the annulus between the pipeline casing and the surrounding well wall, and allowing the cement to set; in which the cement slurry is formed by mixing together an hydraulic cement, 12 to 24% of silica based on the weight of cement, and water; the silica comprising of 1 ⁇ 3 to 2 ⁇ 3 microfine silica and 2 ⁇ 3 to 1 ⁇ 3 silica flour.
- the silica is in the form of an aqueous suspension of microfine silica and silica flour.
- microfine silica particles used in this invention are of amorphous nature such as microsilica, but could also be crystalline.
- silica in the form of a liquid suspension
- the use of dry silica flour is avoided, mixing dry ingredients is avoided, a single component (namely the aqueous silica suspension) only need be transported and stored, and the volume that needs to be transported and stored is minimised in circumstances where storage availability is at a premium.
- the total silica represents 15 to 20% by weight of cement.
- microsilica used in the specification and claims of this application is particulate, amorphous SiO 2 obtained from a process in which silica (quartz) is reduced to SiO-gas and the reduction product is oxidised in vapour phase to form amorphous silica.
- Microsilica may contain at least 70% by weight silica (SiO 2 ) and has a specific density of 2.1-2.3 g/cm 3 and a surface area of 15-40 m 2 /g.
- the primary particles are substantially spherical and have an average size of about 0.15 ⁇ m.
- Microsilica is preferably obtained as a co-product in the production of silicon or silicon alloys in electric reduction furnaces. In these processes large quantities of microsilica are formed.
- the microsilica is recovered in conventional manner using baghouse filters or other collection apparatus.
- microfine crystalline silica used in the specification and claims of this application is particulate crystalline silica having a D50 of maximum 10 ⁇ m and preferably a D50 of about 3 ⁇ m.
- Silica flour is simply ground crystalline silica with a mean particle size of about 25 ⁇ m.
- a standard cement slurry without silica was mixed, cast and cured at 150 deg C.
- Compressive strength was measured and set-cement permeability were measured. The results are shown in Table 1 and in FIG. 1 . As can be seen SR is rapidly occurring after 9 hrs as shown in FIG. 1 .
- microfine silica particle in the liquid silica blend can be of amorphous or crystalline origins.
- a cement containing 10% total silica BWOC originating from the liquid suspension of silica conatining 1 ⁇ 3 microsilica and 2 ⁇ 3 silica flour was mixed, cast and tested at 150 deg C.
Abstract
The present invention relates to a method of cementing a casing of an oil or gas pipeline to a surrounding well wall, where an hydraulic cement slurry is formed and the slurry is deployed in the annulus between the pipeline casing and the surrounding well wall. The cement slurry is formed by mixing together an hydraulic cement 12 to 24% of silica based on the weight of cement, and water; wherein the silica comprises ⅓ to ⅔ microfine silica and ⅔ to ⅓ silica flour. The invention further relates to a cement slurry for use in the method.
Description
- The present invention is concerned with the cementation of steel pipes or other structures in oil and gas well such as casings and liners.
- In the cementation of oil wells, a cement slurry is usually pumped down into a casing and placed into the annular space between the outside of the casing and wall of the well. The two most important purposes of the cementation process are to prevent the transport of gas and liquid between subterranean formations and to tie up and support the casing pipe. In addition to sealing oil, gas and water producing formations, the cement also protects the casing against corrosion, and prevents gas- or oil-blow-outs as the cement slurry seals the well very quickly and impermeably.
- At temperatures above 110° C., the hydration phases of set Portland cement undergo changes. This phenomenon is known as strength-retrogression (SR). This results in poorer isolation properties such as lower compressive-strength and higher set-cement permeability, and leads to a loss of zonal isolation as described in the oilfield cementing industry with possibility of liquid or gas influx from the formation into the well and across the different formations.
- Strength-retrogression is easily identified through a quick and early compressive-strength decrease and set-cement permeability increase over time at temperature above 110 deg C. When no decrease of compressive strength and no increase in set-cement permeability can be observed, it is then concluded that no strength-retrogression is taking place.
- For 50 years, companies have routinely added 35% by weight of cement (BWOC) of silica flour, with an average particle diameter of about 20-60 microns, to the cement to prevent SR from occurring (Journal of American concrete institute V27, No. 6, 678, February 1956).
- However, there are handling and storage difficulties associated with the use of dry-blends prepared with cement and dry silica flour, such as lack of spaces on the rigs or offshore platforms to accommodate several different dry-blends, contamination misuse, and the general difficulties associated with the preparation and handling of fine powders.
- More recently, liquid suspension of silica have been commercialised as an alternative to completely dry-blending operations. These liquid additives have proven effective in preventing SR when used at an equivalent 35% BWOC total silica. They have shown some advantages over dry-blending operations, especially in offshore or remote operations when only the deepest casings/liners require the use of silica to stabilise the Portland cement or other.
- Unfortunately, a limitation that was identified early in its use was the relatively high concentration of liquid product that was required to equate to the 35% BWOC total silica. This meant that a large volume of liquid additives had to be transported and mixed during the cementing operation. This is particularly significant in the case of offshore drilling rigs, where deck and storage space can be extremely limited.
- There is thus storage problems both with different dry materials and with liquid additives.
- It is therefore an object of the present invention to provide a means for reducing SR in the cement used for oil and gas pipelines, in particular, for offshore wells.
- It is a further object to avoid the need to store and mix dry powders to form cement slurries, and also to minimise the volume of any cement slurry additives brought to the rig.
- Often, in the case of offshore wells, the well temperatures lie in the range 100° C. to 150° C. It has been observed by the present inventors that at these well temperatures, a different approach to the use of silica as a cement slurry additive can be adopted.
- According to the invention, therefore, there is provided a method of cementing a casing of an oil or gas pipeline to a surrounding well wall, which comprises forming an hydraulic cement slurry, deploying the slurry in the annulus between the pipeline casing and the surrounding well wall, and allowing the cement to set; in which the cement slurry is formed by mixing together an hydraulic cement, 12 to 24% of silica based on the weight of cement, and water; the silica comprising of ⅓ to ⅔ microfine silica and ⅔ to ⅓ silica flour.
- According to a preferred embodiment of the invention the silica is in the form of an aqueous suspension of microfine silica and silica flour.
- The preferred microfine silica particles used in this invention are of amorphous nature such as microsilica, but could also be crystalline.
- It has been found by the inventors that by adopting a combination of microfine silica particles and silica flour, preferably in the form of an aqueous suspension, in a cement slurry for use in wells with temperatures in the range 110° C. to 150° C., the amount of silica can be significantly reduced, while still preventing SR from occurring in the cement.
- Particularly with the use of silica in the form of a liquid suspension, the use of dry silica flour is avoided, mixing dry ingredients is avoided, a single component (namely the aqueous silica suspension) only need be transported and stored, and the volume that needs to be transported and stored is minimised in circumstances where storage availability is at a premium.
- Preferably, the total silica represents 15 to 20% by weight of cement.
- At levels of silica of 10% BWOC and less, the suppression of SR is not effective, particularly at higher temperatures, while at temperatures above 150° C. it becomes necessary to use silica levels above 25% of BWOC.
- The term “microsilica” used in the specification and claims of this application is particulate, amorphous SiO2 obtained from a process in which silica (quartz) is reduced to SiO-gas and the reduction product is oxidised in vapour phase to form amorphous silica. Microsilica may contain at least 70% by weight silica (SiO2) and has a specific density of 2.1-2.3 g/cm3 and a surface area of 15-40 m2/g. The primary particles are substantially spherical and have an average size of about 0.15 μm. Microsilica is preferably obtained as a co-product in the production of silicon or silicon alloys in electric reduction furnaces. In these processes large quantities of microsilica are formed. The microsilica is recovered in conventional manner using baghouse filters or other collection apparatus.
- The term “microfine crystalline silica” used in the specification and claims of this application is particulate crystalline silica having a D50 of maximum 10 μm and preferably a D50 of about 3 μm.
- Silica flour is simply ground crystalline silica with a mean particle size of about 25 μm.
- The invention will now be illustrated in more detail in the following non-limiting Examples.
- A standard cement slurry without silica was mixed, cast and cured at 150 deg C.
- Compressive strength was measured and set-cement permeability were measured. The results are shown in Table 1 and in
FIG. 1 . As can be seen SR is rapidly occurring after 9 hrs as shown inFIG. 1 . -
TABLE 1 Set-cement permeability measurements of cement without silica cured at 150 deg C. Temperature Sample # Composition during cement set Permeability Cement without 150 deg C. High, typically of the silica order of 10 mD - Cement with 35% BWOC dry silica flour was mixed, cast and tested for compressive strength and permeability at 150 deg. C. The results are shown in Table 2. As expected no SR occurred with addition of 35% BWOC.
-
TABLE 2 Cubes (48 hr) UCA Strength At 150 deg C. C.S. (psi) psi @ 48 Hr 35% Silica Flour 8503 3633 35% Silica Flour 8946 -
Set-cement permeability measurements Temperature Air Sample # Composition during cement set Permeability 5 35% BWOC silica flour 175 deg C. 0.000838 mD From 35% BWOC silica flour 150 deg C. 0.004 mD literature - Cement+35% silica BWOC originating from a liquid suspension of ⅓ microsilica and ⅔ silica flour was mixed, cast and tested at 150 deg C.
- The results are shown in Table 3 and in
FIG. 2 . -
TABLE 3 Cubes (48 hr) UCA Strength At 150 deg C. C.S. (psi) psi @ 48 Hr 35% BWOC MBHT 8078 4069 35% BWOC MBHT 9197 - From
FIG. 2 it can be seen that CS increases to a value of more than 2000 psi and stays at this level. No strength retrogression can be observed. This was expected as the cement had conventional silica content of 35 BWOC. - A cement containing 17% BWOC total silica from the liquid suspension of silica containing ⅓ microsilica and ⅔ silica flour was mixed cast, cured and tested at 150 deg C. The air permeability and compressive strength was measured at intervals for a time period of one year. The results are shown in Table 4.
-
TABLE 4 Curing time at 150 deg C. 3 weeks 3 months 6 months 1 year Klinkenberg air 0.092 0.00082 0.00028 0.00036 permeability mD Compressive — 4630 6230 — Strength PSI NOTE Air permeability is of several orders higher than water permeability. ref. Paper: “Klinkenberg effect for gas permeability and its comparison to water permeability for porous sedimentary rocks” - W. Tanikawa and T. Shimamoto. - No sign of SR has occurred after 1 year at 150 deg C. Set-cement permeability remains low and CS remains high. Examination of the samples after one year showed a very low porosity and very fine pores making the cement very well suited for sealing well bores having a bottom temperature of up to 150 deg. C.
- It was surprising that SR could be prevented by the use of about half of the amount of silica compared to conventional practice.
- A cement containing 17% BWOC total silica originating from a liquid suspension of silica prepared with ⅔rd microsilica and ⅓rd silica flour was mixed, cast and tested at 150 deg. C.
- As shown in
FIG. 3 no sign of SR appears after 15 days curing at 150 deg C. showing that a liquid blend with this ratio of microsilica to silica flour is effectively preventing SR. - A cement containing 17% BWOC originating from liquid suspension of silica prepared with ⅓ microfine crystalline silica with a D50 of 3 μm and ⅔ silica flour was mixed, cast and tested at 150 deg. C.
- As can be seen from
FIG. 4 no sign of SR occurs after 1 week curing at 150 deg C. The microfine silica particle in the liquid silica blend can be of amorphous or crystalline origins. - A cement containing 10% total silica BWOC originating from the liquid suspension of silica conatining ⅓ microsilica and ⅔ silica flour was mixed, cast and tested at 150 deg C.
- As can be seen from
FIG. 5 , clear signs of SR occurs after 24 hrs at 150 deg. C. when only 10% BWOC total silica from the liquid suspension of silica is used. A minimum silica content is needed to effectively prevent SR.
Claims (10)
1. A method of cementing a casing of an oil or gas pipeline to a surrounding well wall, which comprises forming an hydraulic cement slurry, deploying the slurry in the annulus between the pipeline casing and the surrounding well wall, and allowing the cement to set; in which the cement slurry is formed by mixing together an hydraulic cement, 12 to 24% of silica based on the weight of cement, and water; wherein the silica comprises ⅓ to ⅔ microfine silica and ⅔ to ⅓ silica flour.
2. A method as claimed in claim 1 , in which the silica is in the form of an aqueous suspension of microfine silica and silica flour.
3. A method as claimed in claim 1 , in which the microfine silica and silica flour are added separately.
4. A method as claimed in claim 1 , in which the microfine silica is microsilica, microfine crystalline silica, colloidal silica or mixtures thereof.
5. A method as claimed in claim 4 , in which the microfine crystalline silica has a D50 of maximum 10 μm.
6. A method as claimed in claim 1 , in which the silica represents 15 to 20% by weight of cement.
7. An hydraulic cement slurry for use in the cementation of gas or oil wells having a bottom temperature of between 100 and 150° C., comprising: an hydraulic cement, 12 to 24 of silica based on the weight of cement and water wherein the silica comprises ⅓ to ⅔ microfine silica and ⅔ to ⅓ silica flour.
8. An hydraulic cement slurry as claimed in claim 7 , in which the silica comprises an aqueous suspension of microfine silica and silica flour.
9. An hydraulic cement slurry as claimed in claim 7 , in which the microfine silica is microsilica, microfine crystalline silica, colloidal silica or mixtures thereof.
10. An hydraulic cement slurry as claimed in claim 9 , in which the microfine crystalline silica has a D50 of maximum 10 μm.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20064174 | 2006-09-15 | ||
NO20064174A NO327763B1 (en) | 2006-09-15 | 2006-09-15 | Procedure for cementing gas and oil wells and cement slurry |
PCT/NO2007/000306 WO2008033027A1 (en) | 2006-09-15 | 2007-08-29 | Method of cementing gas or oil pipeline and hydraulic cement slurry |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NO2007/000306 A-371-Of-International WO2008033027A1 (en) | 2006-09-15 | 2007-08-29 | Method of cementing gas or oil pipeline and hydraulic cement slurry |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/157,953 Continuation US20160340246A1 (en) | 2006-09-15 | 2016-05-18 | Method of cementing gas or oil pipeline |
Publications (1)
Publication Number | Publication Date |
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US20090236095A1 true US20090236095A1 (en) | 2009-09-24 |
Family
ID=39184000
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/441,249 Abandoned US20090236095A1 (en) | 2006-09-15 | 2007-08-29 | Method of cementing gas or oil pipeline and hydraulic cement slurry |
US15/157,953 Abandoned US20160340246A1 (en) | 2006-09-15 | 2016-05-18 | Method of cementing gas or oil pipeline |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/157,953 Abandoned US20160340246A1 (en) | 2006-09-15 | 2016-05-18 | Method of cementing gas or oil pipeline |
Country Status (15)
Country | Link |
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US (2) | US20090236095A1 (en) |
EP (1) | EP2061857B1 (en) |
CN (2) | CN104405335A (en) |
AT (1) | ATE526380T1 (en) |
AU (1) | AU2007295181B2 (en) |
BR (1) | BRPI0716721B1 (en) |
CA (1) | CA2662941C (en) |
DK (1) | DK2061857T3 (en) |
EA (1) | EA013320B1 (en) |
EG (1) | EG25452A (en) |
ES (1) | ES2369107T3 (en) |
MX (1) | MX2009002400A (en) |
MY (1) | MY154007A (en) |
NO (1) | NO327763B1 (en) |
WO (1) | WO2008033027A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160280981A1 (en) * | 2015-03-24 | 2016-09-29 | Schlumberger Technology Corporation | Compositions and methods for well cementing |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO334970B1 (en) * | 2011-06-01 | 2014-08-11 | Elkem As | cement Compositions |
CN110590212B (en) * | 2019-09-25 | 2021-12-07 | 嘉华特种水泥股份有限公司 | Admixture for oil well cement for low-temperature well cementation |
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US5049596A (en) * | 1987-06-25 | 1991-09-17 | Somar Corporation | Epoxy resin based powder coating composition with mixed filler including microfine silica |
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US20050166802A1 (en) * | 2004-01-29 | 2005-08-04 | Matula Gary W. | Grout compositions having high thermal conductivities and methods of using the same |
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NO158499C (en) * | 1985-09-03 | 1988-09-21 | Elkem As | HYDRAULIC CEMENT SUSPENSION. |
NO165673C (en) * | 1987-11-16 | 1991-03-20 | Elkem As | HYDRAULIC CEMENT SUSPENSION. |
NO167649C (en) * | 1989-04-10 | 1993-07-06 | Norske Stats Oljeselskap | PROCEDURE FOR THE ADDITION OF SILICIDE OXIDE IN A HYDRAULIC CEMENT SUSPENSION |
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AU3486197A (en) * | 1996-06-27 | 1998-01-14 | Bj Services Company, U.S.A. | Lightweight thermally stable cement compositions and method of use |
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2006
- 2006-09-15 NO NO20064174A patent/NO327763B1/en not_active IP Right Cessation
-
2007
- 2007-08-29 MX MX2009002400A patent/MX2009002400A/en active IP Right Grant
- 2007-08-29 CN CN201410548808.3A patent/CN104405335A/en active Pending
- 2007-08-29 AU AU2007295181A patent/AU2007295181B2/en not_active Ceased
- 2007-08-29 EP EP07808620A patent/EP2061857B1/en not_active Not-in-force
- 2007-08-29 BR BRPI0716721A patent/BRPI0716721B1/en not_active IP Right Cessation
- 2007-08-29 ES ES07808620T patent/ES2369107T3/en active Active
- 2007-08-29 EA EA200970286A patent/EA013320B1/en not_active IP Right Cessation
- 2007-08-29 AT AT07808620T patent/ATE526380T1/en not_active IP Right Cessation
- 2007-08-29 CA CA2662941A patent/CA2662941C/en active Active
- 2007-08-29 US US12/441,249 patent/US20090236095A1/en not_active Abandoned
- 2007-08-29 DK DK07808620.4T patent/DK2061857T3/en active
- 2007-08-29 WO PCT/NO2007/000306 patent/WO2008033027A1/en active Application Filing
- 2007-08-29 CN CNA200780034043XA patent/CN101522854A/en active Pending
-
2009
- 2009-03-04 MY MYPI20090874A patent/MY154007A/en unknown
- 2009-03-11 EG EG2009030317A patent/EG25452A/en active
-
2016
- 2016-05-18 US US15/157,953 patent/US20160340246A1/en not_active Abandoned
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US1671104A (en) * | 1925-03-03 | 1928-05-29 | White S Dental Mfg Co | Dental cement |
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US20160280981A1 (en) * | 2015-03-24 | 2016-09-29 | Schlumberger Technology Corporation | Compositions and methods for well cementing |
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CA2662941C (en) | 2012-06-26 |
AU2007295181A1 (en) | 2008-03-20 |
AU2007295181B2 (en) | 2011-10-06 |
NO327763B1 (en) | 2009-09-21 |
BRPI0716721A2 (en) | 2013-09-03 |
CN101522854A (en) | 2009-09-02 |
CA2662941A1 (en) | 2008-03-20 |
CN104405335A (en) | 2015-03-11 |
NO20064174L (en) | 2008-03-17 |
WO2008033027A1 (en) | 2008-03-20 |
DK2061857T3 (en) | 2011-10-24 |
MX2009002400A (en) | 2009-03-20 |
EA013320B1 (en) | 2010-04-30 |
EP2061857A4 (en) | 2010-07-28 |
BRPI0716721B1 (en) | 2017-03-21 |
US20160340246A1 (en) | 2016-11-24 |
ES2369107T3 (en) | 2011-11-25 |
EG25452A (en) | 2012-01-09 |
EP2061857B1 (en) | 2011-09-28 |
ATE526380T1 (en) | 2011-10-15 |
EP2061857A1 (en) | 2009-05-27 |
EA200970286A1 (en) | 2009-08-28 |
MY154007A (en) | 2015-04-30 |
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