US20090161054A1 - Method for Forming Multiple Alignment Films on a Substrate and Pixel Structure of a Liquid Crystal Display - Google Patents
Method for Forming Multiple Alignment Films on a Substrate and Pixel Structure of a Liquid Crystal Display Download PDFInfo
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- US20090161054A1 US20090161054A1 US12/250,337 US25033708A US2009161054A1 US 20090161054 A1 US20090161054 A1 US 20090161054A1 US 25033708 A US25033708 A US 25033708A US 2009161054 A1 US2009161054 A1 US 2009161054A1
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
Definitions
- the present invention provides the pixel structure of a liquid crystal display (LCD) and a forming method thereof.
- the pixel structure has multiple distinct alignment films and the forming method thereof.
- a twisted nematic (TN) type LCD basically comprises an upper and a lower conductive glass substrates, a nematic liquid crystal layer injected between the substrates, two polarizers disposed on the outer surfaces of the two substrates respectively, and alignment films coated on the conductive glass substrates with very fine trenches formed therein by rubbing.
- the fluidity of the liquid crystal molecules tends to align the molecules along the trench direction.
- the trenches in the alignment films of the upper and the lower conductive glass substrates differ from each other by 90°.
- the liquid crystal molecules when filled into the trenches of the upper and the lower substrates, the liquid crystal molecules will be aligned along the trench directions, with the liquid crystal molecules in the middle subjected to the smaller binding force. Those molecules closer to the trenches of the substrates are subjected to a larger binding force. In general, the liquid crystal molecules will be aligned at a twisted angle of 90°.
- the light entering the liquid crystal element propagates with the polarization that changes according to the twisted direction of the liquid crystal molecules. Because the upper and lower polarizers have the same directions as the upper and lower alignment films respectively, the light is transmitted through the liquid crystal elements to provide brightness. In contrast, when a voltage is applied, the liquid crystal molecules are aligned towards a direction in which the electric field is applied and are consequently aligned perpendicularly to the alignment films. In this case, the light will not be able to transmit through the second polarizer, thus yielding darkness. Such alternate bright and dark statuses may be used for display purposes.
- protrusions are used to cause the liquid crystal molecules to present a pre-tilt angle in a stationary alignment status, so that when applied with a voltage, the liquid crystal molecules will tilt towards various orientations rapidly.
- the light from the back light source can be transmitted through rapidly after applying the voltage to shorten the display response time remarkably.
- the protrusions lead to a change in the orientation of the liquid crystal molecules, the liquid crystal molecules may reinforce each other when the LCD is viewed from different angles, thus obtaining an enlarged viewing angle range.
- the glass substrates are coated with an alignment material to provide a certain alignment effect.
- the rubbing alignment method may provide alignment in only one single direction, gray-scale inversion tends to occur at particular viewing angles.
- the color is washed out at large viewing angles, resulting in a significantly degraded chroma viewed by a viewer at large viewing angles.
- the pixel structure comprises a plurality of pixel units arranged in arrays.
- Each of the pixel units comprises a first substrate, a second substrate, two first alignment films and two second alignment films.
- the second substrate is disposed opposite to the first substrate.
- the two first alignment films are respectively disposed on the first substrate and the second substrate, and the two second alignment films are also respectively disposed on the first substrate and the second substrate.
- the first alignment films are formed from an alignment material different from that of the second alignment films.
- Each of the first alignment films is disposed substantially opposite to one of the second alignment films.
- Another objective of this invention is to provide a method for forming multiple alignment films on a substrate, wherein the substrate comprises a plurality of pixel areas arranged in arrays.
- the method comprises the following steps: forming a plurality of trenches on the substrate to divide each of the pixel areas into two sub-pixel areas; forming a first alignment film on one of the two sub-pixel areas; and forming a second alignment film on the other sub-pixel area in such a way that for two adjacent pixel areas in at least one portion of the substrate, the first alignment films of the two adjacent pixel areas are disposed adjacent to each other.
- the second alignment films of the two adjacent pixel areas are also disposed adjacent to each other.
- Yet a further objective of this invention is to provide a method for forming multiple alignment films on a substrate, wherein the substrate comprises a plurality of pixel areas arranged in arrays.
- the method comprises the following steps: forming a plurality of trenches on the substrate to divide each of the pixel areas into two sub-pixel areas; forming a first alignment film on one of the two sub-pixel areas; and forming a second alignment film on the other sub-pixel area in such a way that for two adjacent pixel areas in at least one portion of the substrate, the first alignment film of one pixel area is disposed adjacent to the second alignment film of the other pixel area.
- FIG. 1 depicts an example in which this invention is applied to a CF glass substrate of the LCD in an embodiment
- FIGS. 2A , 2 B, 2 C and 2 D depict a manufacturing process flow for forming alignment films on a substrate
- FIG. 3 depicts an example in which this invention is applied to a TFT glass substrate of an LCD
- FIGS. 4A and 4B are schematic views of pixel units with different alignment film arrangements in the pixel structure of an LCD in accordance with this invention respectively;
- FIGS. 5A and 5B depict a plurality of pixel units arranged in arrays on a substrate of an LCD in accordance with this invention respectively.
- FIGS. 6A , 6 B, 6 C and 6 D are schematic views of different alignment film arrangements on the CF and TFT substrates in an LCD of this invention respectively.
- FIG. 1 illustrates a partial view of a pixel structure in a TFT-LCD.
- the pixel structure comprises a plurality of pixel units arranged in arrays, e.g., a plurality of pixel units arranged in arrays as shown in FIG. 4A and FIG. 4B .
- the portion of the pixel structure illustrated comprises a first substrate 100 , a second substrate 200 and a photo-resist spacer (PS) 300 interposed between the first substrate 100 and the second substrate 200 .
- PS photo-resist spacer
- the first substrate 100 and the second substrate 200 are correspondingly disposed with a liquid crystal layer 400 of the LCD filled in a gap between the first substrate 100 and second substrate 200 .
- the first substrate 100 can be a CF glass substrate
- the second substrate 200 can be a TFT glass substrate.
- the CF glass substrate 100 is coated with a color-resist 110 consisting of red, green, blue colors and/or other colors thereon, while the TFT glass substrate 200 comprises a number of pixel storage capacitors 210 spaced apart from each other. It should be noted that other elements irrelevant to this invention disposed on the first substrate 100 and the second substrate 200 are omitted from depiction.
- FIG. 1 is an example in which this invention is applied to a CF glass substrate in an LCD. It should be noted that, as will be appreciated by those of ordinary skill in the art, this invention may also be applied to a TFT glass substrate in an LCD, which is omitted from description herein.
- at least one first trench 130 with a width (w) and a length (l) is disposed on the color resist 110 of the first substrate 100 in a spaced-apart relation.
- the trench has a depth (d) substantially ranging from 0.5 micrometer ( ⁇ m) to 10 ⁇ m and a width (w) substantially ranging from 1 ⁇ l to 50 ⁇ m.
- the depth (d) and width (w) of the trench may vary according to the design or location of the trench in a pixel.
- the first trenches 130 spaced apart may further divide each pixel area of the entire pixel structure into two or more than two sub-pixel areas to facilitate the coating of different alignment film materials on each of the pixel areas.
- the different pre-tilt angles (not shown) will be obtained for liquid crystal molecules in each of the pixel areas, thus achieving a multi-domain division.
- the first trenches 130 are preferably arranged on the first substrate 100 at locations opposite to the pixel storage capacitors 210 on the second substrate 200 to mitigate the loss of the aperture ratio.
- a first alignment film 10 and a second alignment film 20 are disposed on the color resists 110 at both sides of each first trench 130 .
- the one of two alignment materials is selected from one of a group consisting of the following: a twisted nematic (TN) alignment material, a vertical alignment (VA) material and an in-plane switching (IPS) alignment material.
- TN twisted nematic
- VA vertical alignment
- IPS in-plane switching
- the first alignment film 10 and the second alignment film 20 may be either the same or different in terms of thickness, which ranges from about 100 angstroms ( ⁇ ) to 10,000 ⁇ . Because the first alignment material 10 and the second alignment material 20 are made of materials different from each other, each of the pixel areas in the LCD of this invention has different alignment film materials.
- the manufacturing process flow for forming the aforementioned pixel areas with different alignment films on the first substrate or the second substrate is shown.
- the first substrate 110 has a number of first trenches 130 formed thereon.
- the first trenches 130 are formed by leaving one or more additional black matrices in the color resists during the conventional process of forming a black matrix on the first substrate 100 , so no additional manufacturing process is required to form the first trenches 130 in this embodiment.
- the trenches with a width (w) and a length (l) are etched above the black matrix to form the first trenches 130 .
- the first trenches 130 divide each of the pixel areas on the first substrate 100 into the first sub-pixel area 140 and second sub-pixel area 150 , thus achieving a multi-domain division on the substrate.
- each of the trenches has a depth (d) substantially ranging from 0.5 ⁇ m to 10 ⁇ m and a width (w) substantially ranging from 1 ⁇ m to 50 ⁇ m.
- the depth (d) and width (w) of the trenches may vary according to the design or location of the trenches in the pixels.
- the coating of the same or different alignment materials on the individual pixel areas of the pixel structure through an inkjet printing process will be described in detail.
- the first alignment film is coated.
- the size and location of the ink drops are controlled in such a way so that the first alignment film material 10 is coated only on one side of the first trenches 130 .
- the second alignment film material 20 is coated on the other side of the trenches 130 , as shown in FIG. 2C .
- a single drying process is carried out to dry the second alignment film material 20 , as shown in FIG. 2D .
- the two alignment film materials may be coated respectively at first, and then a single drying process is carried out to form the first alignment film 10 and second alignment film 20 simultaneously.
- the invention is applied to a TFT glass substrate of an LCD.
- at least one second trench 230 is spaced apart and formed on the second substrate 200 .
- the second trenches 230 spaced apart may further divide each pixel area of the entire pixel structure on the TFT glass substrate into two or more sub-pixel areas to facilitate the coating of different alignment film materials on each of the pixel areas. As a result, the different pre-tilt angles will be obtained for liquid crystal molecules in each of the pixel areas.
- the second trench 230 is formed by etching a trench with a width (w) and a length (l) on an organic layer of the second substrate 200 when an opening 220 (e.g., a contact window) is made in the second substrate 200 to achieve a multi-domain division.
- the organic layer may be a transparent material used in the Ultra High Aperture (UHA) technology or a color resist used in the Color filter On Array (COA) technology.
- the trench substantially ranges from 0.5 ⁇ m to 10 ⁇ m in depth (d) and substantially ranges from 1 ⁇ m to 50 ⁇ m in width (w).
- the depth and width of the trenches may vary according to the design or location of the trenches in the pixels.
- the second trenches 230 are formed on the substrate concurrently when the opening is formed on the TFT glass substrate, no additional manufacturing process is required in this embodiment to form the trenches 230 .
- the trenches 230 are preferably arranged directly above the pixel storage capacitor 210 on the second substrate 200 to mitigate the loss of the aperture ratio. Since the second trenches 230 divide each of the pixel areas of the pixel structure on the second substrate 200 into two sub-pixel areas, the first alignment material 10 and the second alignment material 20 with a thickness ranging from about 100 ⁇ to 10,000 ⁇ may be coated on both sides of the second trenches 230 in a similar manner as described above to obtain different alignment film materials in each of the pixel areas.
- the second trenches 230 are preferably arranged at locations of the openings 220 , directly above the pixel storage capacitor 210 , to avoid the occupation of other locations on the TFT glass substrate as well as the consequent increase of the aperture ratio and light leakage.
- FIGS. 4A and 4B illustrate the pixel units with different alignment film arrangements in the pixel structure of an LCD, where the pixel structure comprises a plurality of pixel units arranged in arrays.
- Each of the pixel units comprises a first substrate 100 , a second substrate 200 , a liquid crystal layer 400 , first alignment films 10 and second alignment films 20 .
- the first substrate 100 and the second substrate 200 are disposed correspondingly with the liquid crystal layer 400 filled in a gap between the first substrate 100 and the second substrate 200 .
- the first alignment film 10 and the second alignment film 20 may be obtained by changing materials, thickness, surface conditions, rubbing directions or the like of the alignment films.
- the first substrate 100 in each of the pixel units, has at least one first trench (not shown) to separate the first alignment film 10 and the second alignment film 20 on the first substrate 100 .
- the second substrate 200 in each of the pixel units, has at least one second trench (not shown) to separate the first alignment film 10 and the second alignment film 20 on the second substrate 200 .
- each of the pixel areas on the first substrate 100 and the second substrate 200 in this embodiment has two sub-pixel areas.
- first alignment films 10 and two second alignment films 20 can be coated on the two sub-pixel areas of the first substrate 100 and the second substrate 200 respectively. Particularly, in each pixel area, each of the first alignment film 10 is disposed substantially opposite to one of the two second alignment films 20 .
- each of the first alignment films 10 is disposed substantially directly opposite to one of the two second alignment films 20 .
- each of the first alignment films 10 is disposed substantially obliquely opposite to one of the two second alignment films 20 .
- the different electric fields are generated on the left side and right side of each pixel area by using different alignment film arrangements on the first and the second substrates, which further results in different pre-tilt angles of liquid crystal molecules and helps to overcome the displaying problems suffered by different LCDs.
- each pixel area has both a first alignment film 10 and a second alignment film 20 on both the left side and the right side thereof, so equal voltage differences will be expected on both sides of each pixel area.
- Such an arrangement is particularly adapted to a TN type LCD to reduce the response time thereof by effectively increasing the pre-tilt angle of liquid crystal molecules in the liquid crystal layer.
- each pixel area is coated with a single kind of alignment material on either side thereof.
- the first substrate 100 and the second substrate 200 are both coated with the first alignment film 10 on the right side and both coated with the second alignment films 20 on the left side.
- Such an alignment film arrangement is particularly adapted to a VA type LCD. More specifically, the side of the pixel area exhibiting a larger voltage difference may help to shorten the response time by increasing the pre-tilt angle of the liquid crystal molecules in the liquid crystal layer. The other side exhibits a smaller voltage difference to avoid an excessively large pre-tilt angle of liquid crystal molecules therebetween, thereby, maintaining a certain level of transmittance in the display and preventing color wash-out at large viewing angles.
- FIGS. 5A and 5B show adjacent disposition relationships among a plurality of pixel units arranged in the arrays on the CF glass substrate or the TFT glass substrate of the LCD.
- each pixel unit 60 on the CF glass substrate or the TFT glass substrate is divided into two sub-pixel areas 62 by spacers 50 such as the first and/or the second trenches.
- Each of the sub-pixel areas 62 is then coated with the first alignment film 10 or second alignment film 20 through an inkjet printing process.
- a plurality of equally or unequally spaced spacers 50 are formed on the CF or the TFT substrate to divide each of the pixel areas into two sub-pixel areas. Then, a first alignment film 10 is formed on one of the two sub-pixel areas 62 . Finally, the second alignment film 20 is formed on the other sub-pixel area 62 in such a way that for every two adjacent pixel areas in at least a portion of the substrate, the first alignment films 10 of the two adjacent pixel areas are disposed adjacent to each other, like the second alignment films 20 thereof. That is, the first alignment films of adjacent pixel areas form a plurality of continuous first alignment film bands 12 . The second alignment films of adjacent pixel areas form a plurality of continuous second alignment film bands 22 , with the individual continuous first alignment film band 12 and the individual continuous second alignment film band 22 alternately disposed.
- a plurality of equally or unequally spaced spacers 50 are formed on the CF or the TFT substrate to divide each of the pixel areas into two sub-pixel areas. Then, a first alignment film 10 is formed on one of the two sub-pixel areas 62 . Finally, a second alignment film 20 is formed on the other sub-pixel area 62 in such a way that for two adjacent pixel areas in at least one portion of the substrate, the first alignment film 10 of one pixel area and the second alignment film 20 of the other pixel area are disposed adjacent to each other. That is, adjacent sub-pixel areas form a plurality of continuous first alignment film bands 12 and a plurality of continuous second alignment film bands 22 on the CF or the TFT substrate. In this case, every two continuous first alignment film bands 12 are disposed adjacent to each other like the every two continuous second alignment film bands 22 disposed adjacent to each other. Every two adjacent continuous first alignment film bands 12 and every two continuous second alignment film bands 22 are alternately disposed.
- FIGS. 5A and 5B several different implementations may be obtained by using the layouts shown in FIGS. 5A and 5B in combination with the alignment film arrangements between the first and the second substrates shown in FIGS. 4A and 4B , and will be described as follows.
- FIG. 6A illustrates an embodiment combining the arrangement of FIG. 4A and the layout of FIG. 5A .
- the first alignment films 10 on one substrate are substantially disposed directly opposite to the second alignment films 20 on the other substrate.
- the second alignment films 20 on the first substrate 100 are disposed adjacent to each other like the second alignment films 20 on the second substrate 200 . That is, the first alignment films 10 on one substrate are disposed directly opposite to the second alignment films 20 on the other substrate.
- the individual continuous first alignment film bands 12 and individual continuous second alignment film bands 22 are alternately disposed on each substrate.
- FIG. 6B illustrates an embodiment combining the arrangement of FIG. 4A and the layout of FIG. 5B .
- the first alignment films 10 on the first substrate 100 are disposed adjacent to each other, along with the first alignment films 10 on the second substrate 200 . That is, the first alignment films 10 on one substrate are disposed directly opposite to the second alignment films 20 on the other substrate, and every two adjacent continuous first alignment film bands 12 and every two adjacent continuous bands 22 are alternately disposed on each substrate.
- FIG. 6C illustrates an embodiment combining the arrangement of FIG. 4B and the layout of FIG. 5A .
- the first alignment films 10 on one substrate are substantially disposed obliquely opposite to the second alignment films 20 on the other substrate. Furthermore, the first alignment films 10 on the first substrate 100 are disposed adjacent to each other, along with the second alignment films 20 on the second substrate 200 . That is, the first alignment films 10 on one substrate are disposed obliquely opposite to the second alignment films 20 on the other substrate, and the individual continuous first alignment film bands 12 and individual continuous second alignment film bands 22 are alternately disposed on each substrate.
- FIG. 6D illustrates an embodiment combining the arrangement of FIG. 4B and the layout of FIG. 5B .
- the second alignment films 20 on the first substrate 100 are disposed adjacent to each other, along with the first alignment films 10 on the second substrate 200 . That is, the first alignment films 10 on one substrate are disposed obliquely opposite to the second alignment films 20 on the other substrate, and every two adjacent continuous bands 12 and every two adjacent continuous bands 22 are alternately disposed on each substrate.
- this invention divides each pixel area of the glass substrates in an LCD by using the multi-domain dividing technology without requiring any additional development and etching process.
- each of the pixel areas can be coated with different alignment film materials to obtain several variations of alignment film arrangement to improve the display performance of the LCD by affecting the pre-tilt angle of liquid crystal molecules in the liquid crystal layer.
Abstract
A method for forming the alignment films on the substrate and a pixel structure of a liquid crystal display are disclosed. The pixel structure comprises a plurality of pixel units arranged in arrays. Each of the pixel units comprises a first substrate, a second substrate, two first alignment films and two second alignment films. The first alignment film is different from the second alignment film. The second substrate is disposed opposite to the first substrate. The two first alignment films and the two second alignment films are individually disposed on the first substrate and the second substrate, while each of the first alignment films is disposed substantially opposite to one of the second alignment films. The method for forming the alignment films comprises the following steps: (1) forming a trench on the substrate to divide each of the pixel units into a first sub-pixel area and a second sub-pixel area, (2) forming the first alignment film on the first sub-pixel area of the substrate and then, (3) forming a second alignment film on the second sub-pixel area of the substrate at last.
Description
- This application claims priority to Taiwan Patent Application No. 096149269 filed on Dec. 21, 2007 the disclosures of which are incorporated herein by reference in their entirety.
- Not applicable.
- 1. Field of the Invention
- The present invention provides the pixel structure of a liquid crystal display (LCD) and a forming method thereof. In particular, the pixel structure has multiple distinct alignment films and the forming method thereof.
- 2. Descriptions of the Related Art
- Currently in common liquid crystal displays (LCDs), the alignment orientations of the liquid crystal molecules are altered by applying voltages externally to acquire varied optical characteristics. For example, a twisted nematic (TN) type LCD basically comprises an upper and a lower conductive glass substrates, a nematic liquid crystal layer injected between the substrates, two polarizers disposed on the outer surfaces of the two substrates respectively, and alignment films coated on the conductive glass substrates with very fine trenches formed therein by rubbing. The fluidity of the liquid crystal molecules tends to align the molecules along the trench direction. The trenches in the alignment films of the upper and the lower conductive glass substrates differ from each other by 90°. Consequently, when filled into the trenches of the upper and the lower substrates, the liquid crystal molecules will be aligned along the trench directions, with the liquid crystal molecules in the middle subjected to the smaller binding force. Those molecules closer to the trenches of the substrates are subjected to a larger binding force. In general, the liquid crystal molecules will be aligned at a twisted angle of 90°.
- When there is no voltage applied, the light entering the liquid crystal element propagates with the polarization that changes according to the twisted direction of the liquid crystal molecules. Because the upper and lower polarizers have the same directions as the upper and lower alignment films respectively, the light is transmitted through the liquid crystal elements to provide brightness. In contrast, when a voltage is applied, the liquid crystal molecules are aligned towards a direction in which the electric field is applied and are consequently aligned perpendicularly to the alignment films. In this case, the light will not be able to transmit through the second polarizer, thus yielding darkness. Such alternate bright and dark statuses may be used for display purposes.
- As another example, in a vertical alignment (VA) LCD, protrusions are used to cause the liquid crystal molecules to present a pre-tilt angle in a stationary alignment status, so that when applied with a voltage, the liquid crystal molecules will tilt towards various orientations rapidly. The light from the back light source can be transmitted through rapidly after applying the voltage to shorten the display response time remarkably. Furthermore, because the protrusions lead to a change in the orientation of the liquid crystal molecules, the liquid crystal molecules may reinforce each other when the LCD is viewed from different angles, thus obtaining an enlarged viewing angle range.
- In current thin-film transistor liquid crystal displays (LCD-TFTs), the glass substrates are coated with an alignment material to provide a certain alignment effect. However, since the rubbing alignment method may provide alignment in only one single direction, gray-scale inversion tends to occur at particular viewing angles. Moreover, in VA type LCDs, the color is washed out at large viewing angles, resulting in a significantly degraded chroma viewed by a viewer at large viewing angles.
- In an attempt to solve the aforementioned problems, some patents have proposed to pattern the alignment films by a development and etching process or to modify the alignment films with plasma. However, all of these methods require additional photo-resist coatings, exposures, development and etching, which not only increases the complexity of the manufacturing process, but also leads to lengthened processing time and increasing costs. In summary, it is highly desirable in the art to overcome the problems associated with the alignment of different alignment films by a simple manufacturing process.
- One objective of this invention is to provide a pixel structure for a thin-film transistor liquid crystal display (TFT-LCD). The pixel structure comprises a plurality of pixel units arranged in arrays. Each of the pixel units comprises a first substrate, a second substrate, two first alignment films and two second alignment films. The second substrate is disposed opposite to the first substrate. The two first alignment films are respectively disposed on the first substrate and the second substrate, and the two second alignment films are also respectively disposed on the first substrate and the second substrate. The first alignment films are formed from an alignment material different from that of the second alignment films. Each of the first alignment films is disposed substantially opposite to one of the second alignment films.
- Another objective of this invention is to provide a method for forming multiple alignment films on a substrate, wherein the substrate comprises a plurality of pixel areas arranged in arrays. The method comprises the following steps: forming a plurality of trenches on the substrate to divide each of the pixel areas into two sub-pixel areas; forming a first alignment film on one of the two sub-pixel areas; and forming a second alignment film on the other sub-pixel area in such a way that for two adjacent pixel areas in at least one portion of the substrate, the first alignment films of the two adjacent pixel areas are disposed adjacent to each other. The second alignment films of the two adjacent pixel areas are also disposed adjacent to each other.
- Yet a further objective of this invention is to provide a method for forming multiple alignment films on a substrate, wherein the substrate comprises a plurality of pixel areas arranged in arrays. The method comprises the following steps: forming a plurality of trenches on the substrate to divide each of the pixel areas into two sub-pixel areas; forming a first alignment film on one of the two sub-pixel areas; and forming a second alignment film on the other sub-pixel area in such a way that for two adjacent pixel areas in at least one portion of the substrate, the first alignment film of one pixel area is disposed adjacent to the second alignment film of the other pixel area.
- According to this invention, by performing a particular treatment to the glass substrates of an LCD, different alignment film materials are coated on different areas of the pixels without need of additional development and etching processes. Consequently, the gray-scale inversion in the TN mode LCD and the color wash-out at large viewing angles in a VA mode LCD are overcome, thus improving the display performance of the LCDs.
- The detailed technology and preferred embodiments implemented for the subject invention are described in the following paragraphs accompanying the appended drawings for people skilled in this field to well appreciate the features of the claimed invention.
-
FIG. 1 depicts an example in which this invention is applied to a CF glass substrate of the LCD in an embodiment; -
FIGS. 2A , 2B, 2C and 2D depict a manufacturing process flow for forming alignment films on a substrate; -
FIG. 3 depicts an example in which this invention is applied to a TFT glass substrate of an LCD; -
FIGS. 4A and 4B are schematic views of pixel units with different alignment film arrangements in the pixel structure of an LCD in accordance with this invention respectively; -
FIGS. 5A and 5B depict a plurality of pixel units arranged in arrays on a substrate of an LCD in accordance with this invention respectively; and -
FIGS. 6A , 6B, 6C and 6D are schematic views of different alignment film arrangements on the CF and TFT substrates in an LCD of this invention respectively. - According to this invention, by performing a particular treatment to the glass substrates in LCDs, e.g., by applying this invention to color the filter (CF) glass substrates and thin-film transistor (TFT) glass substrates, different alignment film materials are coated on different pixel areas to control the different pre-tilt angles of liquid crystal molecules in the pixel areas. This will be described in detail hereinafter.
-
FIG. 1 illustrates a partial view of a pixel structure in a TFT-LCD. The pixel structure comprises a plurality of pixel units arranged in arrays, e.g., a plurality of pixel units arranged in arrays as shown inFIG. 4A andFIG. 4B . The portion of the pixel structure illustrated comprises afirst substrate 100, asecond substrate 200 and a photo-resist spacer (PS) 300 interposed between thefirst substrate 100 and thesecond substrate 200. Thefirst substrate 100 and thesecond substrate 200 are correspondingly disposed with aliquid crystal layer 400 of the LCD filled in a gap between thefirst substrate 100 andsecond substrate 200. In this embodiment, thefirst substrate 100 can be a CF glass substrate, while thesecond substrate 200 can be a TFT glass substrate. TheCF glass substrate 100 is coated with a color-resist 110 consisting of red, green, blue colors and/or other colors thereon, while theTFT glass substrate 200 comprises a number ofpixel storage capacitors 210 spaced apart from each other. It should be noted that other elements irrelevant to this invention disposed on thefirst substrate 100 and thesecond substrate 200 are omitted from depiction. - The embodiment illustrated in
FIG. 1 is an example in which this invention is applied to a CF glass substrate in an LCD. It should be noted that, as will be appreciated by those of ordinary skill in the art, this invention may also be applied to a TFT glass substrate in an LCD, which is omitted from description herein. In this embodiment, at least onefirst trench 130 with a width (w) and a length (l) is disposed on the color resist 110 of thefirst substrate 100 in a spaced-apart relation. In practical applications, the trench has a depth (d) substantially ranging from 0.5 micrometer (μm) to 10 μm and a width (w) substantially ranging from 1 μl to 50 μm. However, the depth (d) and width (w) of the trench may vary according to the design or location of the trench in a pixel. Thefirst trenches 130 spaced apart may further divide each pixel area of the entire pixel structure into two or more than two sub-pixel areas to facilitate the coating of different alignment film materials on each of the pixel areas. As a result, the different pre-tilt angles (not shown) will be obtained for liquid crystal molecules in each of the pixel areas, thus achieving a multi-domain division. Furthermore, thefirst trenches 130 are preferably arranged on thefirst substrate 100 at locations opposite to thepixel storage capacitors 210 on thesecond substrate 200 to mitigate the loss of the aperture ratio. - In this invention, a
first alignment film 10 and asecond alignment film 20, made of two different alignment materials, are disposed on the color resists 110 at both sides of eachfirst trench 130. The one of two alignment materials is selected from one of a group consisting of the following: a twisted nematic (TN) alignment material, a vertical alignment (VA) material and an in-plane switching (IPS) alignment material. Furthermore, thefirst alignment film 10 and thesecond alignment film 20 may be either the same or different in terms of thickness, which ranges from about 100 angstroms (Å) to 10,000 Å. Because thefirst alignment material 10 and thesecond alignment material 20 are made of materials different from each other, each of the pixel areas in the LCD of this invention has different alignment film materials. - With reference to
FIGS. 2A to 2D , the manufacturing process flow for forming the aforementioned pixel areas with different alignment films on the first substrate or the second substrate is shown. As shown inFIG. 2A , thefirst substrate 110 has a number offirst trenches 130 formed thereon. Thefirst trenches 130 are formed by leaving one or more additional black matrices in the color resists during the conventional process of forming a black matrix on thefirst substrate 100, so no additional manufacturing process is required to form thefirst trenches 130 in this embodiment. Then, during a subsequent color resist etching process, the trenches with a width (w) and a length (l) are etched above the black matrix to form thefirst trenches 130. Thefirst trenches 130 divide each of the pixel areas on thefirst substrate 100 into thefirst sub-pixel area 140 andsecond sub-pixel area 150, thus achieving a multi-domain division on the substrate. In application, each of the trenches has a depth (d) substantially ranging from 0.5 μm to 10 μm and a width (w) substantially ranging from 1 μm to 50 μm. However, the depth (d) and width (w) of the trenches may vary according to the design or location of the trenches in the pixels. Hereinafter, the coating of the same or different alignment materials on the individual pixel areas of the pixel structure through an inkjet printing process will be described in detail. - Then, the first alignment film is coated. As shown in
FIG. 2B , the size and location of the ink drops are controlled in such a way so that the firstalignment film material 10 is coated only on one side of thefirst trenches 130. After the firstalignment film material 10 is dried, the secondalignment film material 20 is coated on the other side of thetrenches 130, as shown inFIG. 2C . Finally, a single drying process is carried out to dry the secondalignment film material 20, as shown inFIG. 2D . Alternatively, in practice, the two alignment film materials may be coated respectively at first, and then a single drying process is carried out to form thefirst alignment film 10 andsecond alignment film 20 simultaneously. - Next, as shown in
FIG. 3 , the invention is applied to a TFT glass substrate of an LCD. In this embodiment, at least onesecond trench 230 is spaced apart and formed on thesecond substrate 200. Thesecond trenches 230 spaced apart may further divide each pixel area of the entire pixel structure on the TFT glass substrate into two or more sub-pixel areas to facilitate the coating of different alignment film materials on each of the pixel areas. As a result, the different pre-tilt angles will be obtained for liquid crystal molecules in each of the pixel areas. - In the preferred example, the
second trench 230 is formed by etching a trench with a width (w) and a length (l) on an organic layer of thesecond substrate 200 when an opening 220 (e.g., a contact window) is made in thesecond substrate 200 to achieve a multi-domain division. The organic layer may be a transparent material used in the Ultra High Aperture (UHA) technology or a color resist used in the Color filter On Array (COA) technology. In application, the trench substantially ranges from 0.5 μm to 10 μm in depth (d) and substantially ranges from 1 μm to 50 μm in width (w). However, the depth and width of the trenches may vary according to the design or location of the trenches in the pixels. - It should be emphasized that because the
second trenches 230 are formed on the substrate concurrently when the opening is formed on the TFT glass substrate, no additional manufacturing process is required in this embodiment to form thetrenches 230. Additionally, as previously described, thetrenches 230 are preferably arranged directly above thepixel storage capacitor 210 on thesecond substrate 200 to mitigate the loss of the aperture ratio. Since thesecond trenches 230 divide each of the pixel areas of the pixel structure on thesecond substrate 200 into two sub-pixel areas, thefirst alignment material 10 and thesecond alignment material 20 with a thickness ranging from about 100 Å to 10,000 Å may be coated on both sides of thesecond trenches 230 in a similar manner as described above to obtain different alignment film materials in each of the pixel areas. To further mitigate the loss to the aperture ration, thesecond trenches 230 are preferably arranged at locations of theopenings 220, directly above thepixel storage capacitor 210, to avoid the occupation of other locations on the TFT glass substrate as well as the consequent increase of the aperture ratio and light leakage. - The processes involved in dividing each pixel area on the TFT glass substrate or the CF glass substrate into two or more sub-pixel areas by forming trenches has been described above. Hereinafter, further applications of the above descriptions will be set forth. For example, different arrangements of alignment films may be used on the TFT and CF glass substrates of an LCD to solve different displaying problems of different types of displays.
-
FIGS. 4A and 4B illustrate the pixel units with different alignment film arrangements in the pixel structure of an LCD, where the pixel structure comprises a plurality of pixel units arranged in arrays. Each of the pixel units comprises afirst substrate 100, asecond substrate 200, aliquid crystal layer 400,first alignment films 10 andsecond alignment films 20. Similar to those described above, thefirst substrate 100 and thesecond substrate 200 are disposed correspondingly with theliquid crystal layer 400 filled in a gap between thefirst substrate 100 and thesecond substrate 200. Thefirst alignment film 10 and thesecond alignment film 20 may be obtained by changing materials, thickness, surface conditions, rubbing directions or the like of the alignment films. In the description that follows, several specific applications of this invention will be described in detail with respect to the drawings. - The following description provides examples in which a multi-domain dividing process is performed on both the first and the second substrate. As shown in
FIG. 4A andFIG. 4B , thefirst substrate 100, in each of the pixel units, has at least one first trench (not shown) to separate thefirst alignment film 10 and thesecond alignment film 20 on thefirst substrate 100. Likewise, thesecond substrate 200, in each of the pixel units, has at least one second trench (not shown) to separate thefirst alignment film 10 and thesecond alignment film 20 on thesecond substrate 200. As a consequence, each of the pixel areas on thefirst substrate 100 and thesecond substrate 200 in this embodiment has two sub-pixel areas. During the subsequent alignment film coating process, twofirst alignment films 10 and twosecond alignment films 20 can be coated on the two sub-pixel areas of thefirst substrate 100 and thesecond substrate 200 respectively. Particularly, in each pixel area, each of thefirst alignment film 10 is disposed substantially opposite to one of the twosecond alignment films 20. - In more detail, in the example shown in
FIG. 4A , each of thefirst alignment films 10 is disposed substantially directly opposite to one of the twosecond alignment films 20. In contrast, in the example shown inFIG. 4B , each of thefirst alignment films 10 is disposed substantially obliquely opposite to one of the twosecond alignment films 20. In both examples, the different electric fields are generated on the left side and right side of each pixel area by using different alignment film arrangements on the first and the second substrates, which further results in different pre-tilt angles of liquid crystal molecules and helps to overcome the displaying problems suffered by different LCDs. - For instance, in the example shown in
FIG. 4A , each pixel area has both afirst alignment film 10 and asecond alignment film 20 on both the left side and the right side thereof, so equal voltage differences will be expected on both sides of each pixel area. Such an arrangement is particularly adapted to a TN type LCD to reduce the response time thereof by effectively increasing the pre-tilt angle of liquid crystal molecules in the liquid crystal layer. On the other hand, in the example shown inFIG. 4B , each pixel area is coated with a single kind of alignment material on either side thereof. For instance, in the pixel area shown inFIG. 4B , thefirst substrate 100 and thesecond substrate 200 are both coated with thefirst alignment film 10 on the right side and both coated with thesecond alignment films 20 on the left side. Hence, the electric fields resulting in unequal voltage differences will be expected on the left side and the right side of each pixel area. Such an alignment film arrangement is particularly adapted to a VA type LCD. More specifically, the side of the pixel area exhibiting a larger voltage difference may help to shorten the response time by increasing the pre-tilt angle of the liquid crystal molecules in the liquid crystal layer. The other side exhibits a smaller voltage difference to avoid an excessively large pre-tilt angle of liquid crystal molecules therebetween, thereby, maintaining a certain level of transmittance in the display and preventing color wash-out at large viewing angles. - Furthermore, when the multi-domain dividing technology of this invention is applied to the entire CF glass substrate or TFT glass substrate of an LCD, several possible alignment film layouts may be formed on the CF glass substrate or TFT glass substrate. For example,
FIGS. 5A and 5B show adjacent disposition relationships among a plurality of pixel units arranged in the arrays on the CF glass substrate or the TFT glass substrate of the LCD. Here, eachpixel unit 60 on the CF glass substrate or the TFT glass substrate is divided into twosub-pixel areas 62 byspacers 50 such as the first and/or the second trenches. Each of thesub-pixel areas 62 is then coated with thefirst alignment film 10 orsecond alignment film 20 through an inkjet printing process. - For example, as shown in
FIG. 5A , a plurality of equally or unequally spacedspacers 50 are formed on the CF or the TFT substrate to divide each of the pixel areas into two sub-pixel areas. Then, afirst alignment film 10 is formed on one of the twosub-pixel areas 62. Finally, thesecond alignment film 20 is formed on theother sub-pixel area 62 in such a way that for every two adjacent pixel areas in at least a portion of the substrate, thefirst alignment films 10 of the two adjacent pixel areas are disposed adjacent to each other, like thesecond alignment films 20 thereof. That is, the first alignment films of adjacent pixel areas form a plurality of continuous firstalignment film bands 12. The second alignment films of adjacent pixel areas form a plurality of continuous secondalignment film bands 22, with the individual continuous firstalignment film band 12 and the individual continuous secondalignment film band 22 alternately disposed. - As another example shown in
FIG. 5B , a plurality of equally or unequally spacedspacers 50 are formed on the CF or the TFT substrate to divide each of the pixel areas into two sub-pixel areas. Then, afirst alignment film 10 is formed on one of the twosub-pixel areas 62. Finally, asecond alignment film 20 is formed on theother sub-pixel area 62 in such a way that for two adjacent pixel areas in at least one portion of the substrate, thefirst alignment film 10 of one pixel area and thesecond alignment film 20 of the other pixel area are disposed adjacent to each other. That is, adjacent sub-pixel areas form a plurality of continuous firstalignment film bands 12 and a plurality of continuous secondalignment film bands 22 on the CF or the TFT substrate. In this case, every two continuous firstalignment film bands 12 are disposed adjacent to each other like the every two continuous secondalignment film bands 22 disposed adjacent to each other. Every two adjacent continuous firstalignment film bands 12 and every two continuous secondalignment film bands 22 are alternately disposed. - Furthermore, several different implementations may be obtained by using the layouts shown in
FIGS. 5A and 5B in combination with the alignment film arrangements between the first and the second substrates shown inFIGS. 4A and 4B , and will be described as follows. -
FIG. 6A illustrates an embodiment combining the arrangement ofFIG. 4A and the layout ofFIG. 5A . Thefirst alignment films 10 on one substrate are substantially disposed directly opposite to thesecond alignment films 20 on the other substrate. Furthermore, thesecond alignment films 20 on thefirst substrate 100 are disposed adjacent to each other like thesecond alignment films 20 on thesecond substrate 200. That is, thefirst alignment films 10 on one substrate are disposed directly opposite to thesecond alignment films 20 on the other substrate. The individual continuous firstalignment film bands 12 and individual continuous secondalignment film bands 22 are alternately disposed on each substrate. -
FIG. 6B illustrates an embodiment combining the arrangement ofFIG. 4A and the layout ofFIG. 5B . In addition to thefirst alignment films 10 that are disposed directly opposite to thesecond alignment films 20 on the other substrate, thefirst alignment films 10 on thefirst substrate 100 are disposed adjacent to each other, along with thefirst alignment films 10 on thesecond substrate 200. That is, thefirst alignment films 10 on one substrate are disposed directly opposite to thesecond alignment films 20 on the other substrate, and every two adjacent continuous firstalignment film bands 12 and every two adjacentcontinuous bands 22 are alternately disposed on each substrate. -
FIG. 6C illustrates an embodiment combining the arrangement ofFIG. 4B and the layout ofFIG. 5A . Thefirst alignment films 10 on one substrate are substantially disposed obliquely opposite to thesecond alignment films 20 on the other substrate. Furthermore, thefirst alignment films 10 on thefirst substrate 100 are disposed adjacent to each other, along with thesecond alignment films 20 on thesecond substrate 200. That is, thefirst alignment films 10 on one substrate are disposed obliquely opposite to thesecond alignment films 20 on the other substrate, and the individual continuous firstalignment film bands 12 and individual continuous secondalignment film bands 22 are alternately disposed on each substrate. -
FIG. 6D illustrates an embodiment combining the arrangement ofFIG. 4B and the layout ofFIG. 5B . In addition to thefirst alignment films 10 that are substantially disposed obliquely opposite to thesecond alignment films 20 on the other substrate, thesecond alignment films 20 on thefirst substrate 100 are disposed adjacent to each other, along with thefirst alignment films 10 on thesecond substrate 200. That is, thefirst alignment films 10 on one substrate are disposed obliquely opposite to thesecond alignment films 20 on the other substrate, and every two adjacentcontinuous bands 12 and every two adjacentcontinuous bands 22 are alternately disposed on each substrate. - In conclusion, this invention divides each pixel area of the glass substrates in an LCD by using the multi-domain dividing technology without requiring any additional development and etching process. As a result, each of the pixel areas can be coated with different alignment film materials to obtain several variations of alignment film arrangement to improve the display performance of the LCD by affecting the pre-tilt angle of liquid crystal molecules in the liquid crystal layer.
- The above disclosure is related to the detailed technical contents and inventive features thereof. People skilled in this field may proceed with a variety of modifications and replacements based on the disclosures and suggestions of the invention as described without departing from the characteristics thereof. Nevertheless, although such modifications and replacements are not fully disclosed in the above descriptions, they have substantially been covered in the following claims as appended.
Claims (24)
1. A method for forming multiple alignment films on a substrate, the substrate comprising a plurality of pixel areas arranged in arrays, the method comprising the steps of:
forming a trench on the substrate to divide each of the pixel areas into a first sub-pixel area and a second sub-pixel area;
forming a first alignment film on the first sub-pixel area on the substrate; and
forming a second alignment film on the second sub-pixel area on the substrate.
2. The method as claimed in claim 1 , wherein the substrate includes a color filter substrate.
3. The method as claimed in claim 1 , wherein the substrate includes an array substrate.
4. The method as claimed in claim 1 , wherein both the steps of forming the first alignment film and the second alignment film include a step of inkjet printing.
5. The method as claimed in claim 1 , wherein the step of forming the trench comprises forming the trench with a depth substantially between 0.5 and 10 micrometers and a width substantially between 1 and 50 micrometers.
6. The method as claimed in claim 1 , wherein the steps of forming the first alignment film and the second alignment film comprise the step of forming the first alignment films adjacent to each other and the second alignment films adjacent to each other in at least one portion of two adjacent pixel units on the substrate.
7. The method as claimed in claim 1 , wherein the steps of forming the first alignment film and the second alignment film comprise the step of forming the first alignment film and the second alignment film adjacent to each other in at least one portion of two adjacent pixel units on the substrate.
8. The method as claimed in claim 1 , wherein the steps of forming the first alignment film and the second alignment film are using different alignment materials.
9. A pixel structure of a liquid crystal display, comprising a plurality of pixel units arranged in arrays, each of the pixel units comprising:
a first substrate;
a second substrate, disposed corresponding to the first substrate;
two first alignment films, respectively disposed on the first substrate and the second substrate; and
two second alignment films, respectively disposed on the first substrate and the second substrate,
wherein each of the first alignment films is disposed substantially opposite to one of the second alignment films.
10. The pixel structure as claimed in claim 9 , wherein the first alignment film and the second alignment film have different alignment materials.
11. The pixel structure as claimed in claim 10 , wherein a material of one of the first alignment film and the second alignment film is selected from one of a group consisting of a twisted nematic (TN) alignment material, a vertical alignment (VA) material and a in-plane switching (IPS) alignment material.
12. The pixel structure as claimed in claim 9 , wherein the first alignment film and the second alignment film have different thicknesses.
13. The pixel structure as claimed in claim 9 , wherein the first alignment film is disposed substantially obliquely opposite to one of the second alignment films.
14. The pixel structure as claimed in claim 13 , wherein, the second alignment films, disposed on the first substrate in two adjacent pixel units of the arrays, are disposed adjacent to each other, and the first alignment films, disposed on the second substrate and in the two adjacent pixel units of the arrays, are disposed adjacent to each other.
15. The pixel structure as claimed in claim 13 , wherein the first alignment films, disposed on the first substrate in two adjacent pixel units of the arrays, are disposed adjacent to each other, and the second alignment films, disposed on the second substrate in the two adjacent pixel units of the arrays, are disposed adjacent to each other.
16. The pixel structure as claimed in claim 9 , wherein the first alignment film is disposed substantially directly opposite one of the second alignment films.
17. The pixel structure as claimed in claim 16 , wherein the first alignment films, disposed on the first substrate in two adjacent pixel units of the arrays, are disposed adjacent to each other, and the first alignment films, disposed on the second substrate in the two adjacent pixel units of the arrays, are disposed adjacent to each other.
18. The pixel structure as claimed in claim 16 , wherein the second alignment films, disposed on the first substrate in two adjacent pixel units of the arrays, are disposed adjacent to each other, and the second alignment films, disposed on the second substrate in the two adjacent pixel units of the arrays, are disposed adjacent to each other.
19. The pixel structure as claimed in claim 9 , further comprising at least one first trench and at least one second trench, wherein the at least one first trench is disposed on the first substrate and adapted to separate the first alignment film from the second alignment film on the first substrate, and the at least one second trench is disposed on the second substrate and adapted to separate the first alignment films from the second alignment films on the second substrate.
20. The pixel structure as claimed in claim 19 , wherein each of the at least one first trench and the at least one second trench has a depth substantially between 0.5 and 10 micrometers and a width substantially between 1 and 50 micrometers.
21. The pixel structure as claimed in claim 19 , wherein the second substrate further comprises at least one pixel storage capacitor, disposed opposite to the at least one first trench.
22. The pixel structure as claimed in claim 9 , further comprising a liquid crystal layer, disposed between the first substrate and the second substrate.
23. A pixel structure of a liquid crystal display, comprising a plurality of pixel units arranged in arrays, each of the pixel units having a first sub-pixel area and a second sub-pixel area, the pixel units comprising:
a first substrate;
a second substrate, disposed corresponding to the first substrate;
two first alignment films, respectively disposed on the first substrate and the second substrate of the first sub-pixel area; and
two second alignment films, respectively disposed on the first substrate and the second substrate of the second sub-pixel area, wherein the second alignment films are different from the first alignment films.
24. A pixel structure of a liquid crystal displayer, comprising a plurality of pixel units arranged in arrays, each of the pixel units having a first sub-pixel area and a second sub-pixel area, the pixel units comprising:
a first substrate;
a second substrate, disposed corresponding to the first substrate;
two first alignment films, respectively disposed on the first substrate of the first sub-pixel area and on the second substrate of the second sub-pixel area; and
two second alignment films, respectively disposed on the first substrate of the second sub-pixel area and on the second substrate of the first sub-pixel area, wherein the second alignment films are different from the first alignment films.
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US13/673,431 US8576364B2 (en) | 2007-12-21 | 2012-11-09 | Method for forming multiple alignment films on a substrate and pixel structure of a liquid crystal display |
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TW096149269A TWI372293B (en) | 2007-12-21 | 2007-12-21 | Method for forming multiple alignment films on a substrate and pixel structure of a liquid crystal display |
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US13/673,431 Active US8576364B2 (en) | 2007-12-21 | 2012-11-09 | Method for forming multiple alignment films on a substrate and pixel structure of a liquid crystal display |
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US8576364B2 (en) | 2013-11-05 |
TWI372293B (en) | 2012-09-11 |
TW200928523A (en) | 2009-07-01 |
US20130063689A1 (en) | 2013-03-14 |
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