US20090025784A1 - Thermal spray for solar concentrator fabrication - Google Patents

Thermal spray for solar concentrator fabrication Download PDF

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Publication number
US20090025784A1
US20090025784A1 US11/782,605 US78260507A US2009025784A1 US 20090025784 A1 US20090025784 A1 US 20090025784A1 US 78260507 A US78260507 A US 78260507A US 2009025784 A1 US2009025784 A1 US 2009025784A1
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United States
Prior art keywords
optical element
solar cell
spraying
onto
thermal
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Abandoned
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US11/782,605
Inventor
Hing Wah Chan
John S. Fitch
Michael C. Weisberg
David G. Duff
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Palo Alto Research Center Inc
Solfocus Inc
Sol Focus Inc
Original Assignee
Palo Alto Research Center Inc
Sol Focus Inc
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Priority to US11/782,605 priority Critical patent/US20090025784A1/en
Application filed by Palo Alto Research Center Inc, Sol Focus Inc filed Critical Palo Alto Research Center Inc
Assigned to PALO ALTO RESEARCH CENTER INCORPORATED reassignment PALO ALTO RESEARCH CENTER INCORPORATED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DUFF, DAVID G., FITCH, JOHN S., WEISBERG, MICHAEL C.
Assigned to SOLFOCUS, INC. reassignment SOLFOCUS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHAN, HING WAH
Priority to PCT/US2008/050791 priority patent/WO2008097688A1/en
Priority to EP08727546A priority patent/EP2115787A1/en
Priority to AU2008214229A priority patent/AU2008214229A1/en
Priority to JP2009548352A priority patent/JP2010518255A/en
Publication of US20090025784A1 publication Critical patent/US20090025784A1/en
Assigned to NEW ENTERPRISE ASSOCIATES 12 LIMITED PARTNERSHIP, AS COLLATERAL AGENT reassignment NEW ENTERPRISE ASSOCIATES 12 LIMITED PARTNERSHIP, AS COLLATERAL AGENT SECURITY AGREEMENT Assignors: SOLFOCUS, INC.
Priority to US12/841,823 priority patent/US20100294364A1/en
Assigned to SOLFOCUS, INC. reassignment SOLFOCUS, INC. RELEASE OF SECURITY INTEREST AT REEL/FRAME 023973/0826 Assignors: NEW ENTERPRISE ASSOCIATES 12 LIMITED PARTNERSHIP
Assigned to CPV SOLAR LLC C/O HARPER CONSTRUCTION COMPANY, INC. reassignment CPV SOLAR LLC C/O HARPER CONSTRUCTION COMPANY, INC. SECURITY AGREEMENT Assignors: SOLFOCUS, INC.
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0547Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/0556Disposition
    • H01L2224/05568Disposition the whole external layer protruding from the surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/05573Single external layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13099Material
    • H01L2224/131Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/13101Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of less than 400°C
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16151Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/16221Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/16225Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/16237Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation the bump connector connecting to a bonding area disposed in a recess of the surface of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/10Bump connectors ; Manufacturing methods related thereto
    • H01L24/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L24/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/10Bump connectors ; Manufacturing methods related thereto
    • H01L24/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L24/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/00014Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor

Definitions

  • Some embodiments generally relate to the collection and concentration of solar radiation. More specifically, embodiments may relate to systems to efficiently fabricate solar radiation collectors.
  • a concentrating solar radiation collector may convert received solar radiation (i.e., sunlight) into a concentrated beam and direct the concentrated beam onto a small photovoltaic cell.
  • the cell in turn, converts the photons of the received beam into electrical current.
  • a concentrating solar collector may include reflective material for directing received solar radiation, conductive material to carry electrical current generated from the solar radiation, and/or insulative material to isolate various conductors from one another. Fabrication of a solar radiation collector using one or more of these materials may be unsuitably complex and costly.
  • conventional techniques for depositing these materials may include evaporating or sputtering within an established vacuum.
  • Thin film lithographic techniques are employed to create desired patterns and features in the deposited materials. Such techniques require photoresist deposition, masking, UV exposure, and subsequent etching for each layer of material.
  • Thin film lithography may provide geometrically accuracy but entails significant expense.
  • some aspects provide a method, means and/or process steps to thermal spray a first material onto an optical element, and to couple a solar cell to the optical element.
  • Thermal spraying the first material may include spraying a molten metal powder onto the optical element.
  • spraying the molten metal powder onto the optical element may include placing a stencil on the optical element and spraying a molten metal powder onto the stencil and the optical element.
  • thermal spraying the first material includes powder coating a polymer onto the optical element.
  • a reflective material is deposited on a substantially-transparent core, an insulator is deposited on the reflective material, and thermal spraying the first material includes spraying a molten metal powder onto the insulator.
  • an optical element a thermal-sprayed material disposed on the optical element, and a solar cell coupled to the optical element.
  • the thermal-sprayed material may comprise a hardened metal powder.
  • the optical element may comprise an aperture from which light may pass out of the optical element, an electrical contact of the solar cell is coupled to the hardened metal powder, and an optically-active area of the solar cell is aligned with the aperture.
  • the thermal-sprayed material may comprise a polymer.
  • the optical element may comprise a substantially-transparent core, a reflective material disposed on the substantially-transparent core, and an insulator disposed on the reflective material, wherein the thermal-sprayed material is disposed on the insulator.
  • the insulator may include a powder-coated polymer.
  • FIG. 1 is a flow diagram of a method according to some embodiments.
  • FIG. 2A is a perspective view of a portion of an optical element and conductive material according to some embodiments.
  • FIG. 2B is a cross-sectional view of a portion of an optical element and conductive material according to some embodiments.
  • FIG. 3A is a perspective view of a portion of an optical element and a solar cell coupled thereto according to some embodiments.
  • FIG. 3B is a perspective view of a portion of an optical element and a solar cell coupled thereto according to some embodiments.
  • FIG. 4 is a flow diagram of a method according to some embodiments.
  • FIG. 5A is a perspective view of a transparent optical element according to some embodiments.
  • FIG. 5B is a cross-sectional view of a transparent optical element according to some embodiments.
  • FIG. 6A is a perspective view of a transparent optical element with reflective material disposed thereon according to some embodiments.
  • FIG. 6B is a cross-sectional view of a transparent optical element with reflective material disposed thereon according to some embodiments.
  • FIG. 7A is a perspective view of an optical element with an electrical isolator disposed thereon according to some embodiments.
  • FIG. 7B is a cross-sectional view of an optical element with an electrical isolator disposed thereon according to some embodiments.
  • FIG. 8A is a perspective view of an optical element with conductive material disposed thereon according to some embodiments.
  • FIG. 8B is a cross-sectional view of an optical element with conductive material disposed thereon according to some embodiments.
  • FIG. 9 is a cross-sectional view of an optical element and a solar cell according to some embodiments.
  • FIG. 1 is a flow diagram of process 100 according to some embodiments. Process 100 may be performed by any combination of machine, hardware, software and manual means.
  • a first material is thermal sprayed onto an optical element.
  • the first material may comprise any material that is capable of being thermally-sprayed.
  • Thermal spraying the first material may include heating a powder to a molten state and spraying the molten powder onto the optical element. The molten powder then cools on the optical element to produce a solid layer of material.
  • a stencil may be applied to the optical element before spraying the molten powder onto the optical element. The first material is therefore deposited in a pattern defined by the stencil.
  • the thermal spraying may be performed using a known twin wire arc process in a case that the first material is a metal.
  • Plasma spray techniques may be employed at S 110 if the first material is a metal or a ceramic.
  • the first material may be powder coated onto the optical element at S 110 .
  • the term thermal spraying encompasses at least twin wire arcing, plasma spraying (e.g., hot, cold, assisted), and powder coating.
  • Thermal spraying the first material onto the optical element may comprise spraying the first material onto other material(s) already deposited on the optical element.
  • the optical element may be configured to manipulate and/or pass desired wavelengths of light.
  • the optical element may comprise any number of disparate materials and/or elements (e.g., lenses, reflective surfaces and optically-transparent portions).
  • FIG. 2A is a perspective view of apparatus 200 according to some embodiments
  • FIG. 2B is a cross-sectional view of apparatus 200 as shown in FIG. 2A
  • Apparatus 200 includes optical element 220 and conductive material 210 sprayed thereon according to some embodiments of S 110 .
  • FIGS. 2A and 2B show only a portion of apparatus 200 in order to illustrate that apparatus 200 may exhibit any suitable shape or size.
  • Conductive material 210 may comprise any combination of one or more currently- or hereafter-known conductors, including but not limited to copper, gold and nickel. A thickness of material 210 on optical element 220 might not be as uniform as shown in FIG. 2B .
  • a solar cell is coupled to the optical element at S 120 .
  • the coupling at S 120 may comprise coupling the solar cell to other material(s) already deposited on the optical element.
  • an electrical contact of the solar cell may be coupled to conductive material deposited on the optical element.
  • Such a coupling may form an electrical and a mechanical interconnection between the conductive material and the solar cell.
  • Various flip-chip bonding techniques may be employed in some embodiments to couple an electrical contact of the solar cell to conductive material deposited on the optical element.
  • FIG. 3A is a perspective view of apparatus 200 after S 120 according to some embodiments.
  • FIG. 3B is a cross-sectional view corresponding to FIG. 3A .
  • Solder bumps 305 of solar cell 300 are coupled to conductive material 210 .
  • Solder bumps 305 may also be respectively coupled to unshown terminals of solar cell 300 .
  • Solar cell 300 may comprise a solar cell (e.g., a III-V cell, II-VI cell, etc.) for receiving photons from optical element 220 and generating electrical charge carriers in response thereto.
  • a solar cell e.g., a III-V cell, II-VI cell, etc.
  • some embodiments include an opening through dielectric conductive material 210 through which solar cell 300 may receive light from optical element 220 .
  • FIG. 4 is a flow diagram of process 400 according to some embodiments. Process 400 may be performed by any combination of machine, hardware, software and manual means.
  • Process 400 begins at S 410 , at which an optical element is obtained.
  • the optical element may be composed of any suitable material or combination of materials.
  • the optical element may be created using any combination of devices and systems that is or becomes known.
  • FIG. 5A is a perspective view of optical element 500 created at S 410 according to some embodiments
  • FIG. 5B is a cross-sectional view of element 500
  • Optical element 500 may be molded from low-iron glass at S 410 using known methods. Alternatively, separate pieces may be glued or otherwise coupled together to form element 500 .
  • Optical element 500 may comprise an element of a solar concentrator according to some embodiments.
  • Element 500 includes convex surface 510 , pedestal 520 , and concave surface 530 . The purposes of each portion of element 500 during operation according to some embodiments will become evident from the description below.
  • a reflective material is deposited on the optical element at S 420 .
  • the reflective material may be intended to create one or more mirrored surfaces. Any suitable reflective material may be used, taking into account factors such as but not limited to the wavelengths of light to be reflected, bonding of the reflective material to the optical element, and cost.
  • the reflective material may include a mirror coating, a dielectric enhancement coating, and/or a protective dielectric or polymer paint coating.
  • the reflective material may be deposited by sputtering or other physical vapor deposition, liquid deposition, etc.
  • FIGS. 6A and 6B show perspective and cross-sectional views, respectively, of optical element 500 after some embodiments of S 420 .
  • Reflective material 540 is deposited on convex surface 510 and concave surface 530 .
  • Reflective material 540 may comprise sputtered silver or aluminum.
  • the vertical and horizontal surfaces of pedestal 520 may be masked at S 420 such that reflective material 540 is not deposited thereon, or otherwise treated to remove any reflective material 540 that is deposited thereon.
  • a polymer is powder-coated onto the optical element.
  • the polymer may comprise an electrical insulator, and the powder-coating may proceed according to any method that is or becomes known.
  • the polymer may act as a mechanical buffer layer between the reflective material and conductive material. This buffer layer can also be deposited by other means such as spraying, dipping or lamination.
  • other suitable insulators such as any dielectrics, polyester, epoxy and polyurethane are powder-coated onto the optical element at S 430 .
  • S 430 Some embodiments of S 430 are depicted in FIGS. 7A and 7B .
  • Polymer 550 is deposited on convex surface 510 or, more particularly, on reflective material 540 .
  • S 615 may be executed such that polymer 550 is not deposited on the vertical and horizontal surfaces of pedestal 520 .
  • polymer 550 is not deposited on concave surface 530 (i.e., on reflective material 540 deposited on concave surface 530 ).
  • a stencil is placed on the optical element at S 440 and a molten metal powder is sprayed on the stencil and the optical element at S 450 .
  • the stencil may comprise a mechanical, hard or soft tooling.
  • the stencil may cover portions of the previously-deposited polymer that are not to receive the molten metal powder.
  • the molten metal powder may be composed of any combination of one or more metals (e.g., nickel, copper).
  • FIG. 8A is a perspective view and FIG. 8B is a cross-sectional view of optical element 500 after S 450 according to some embodiments.
  • Conductive material 560 covers pedestal 520 and portions of insulator 550 .
  • Conductive material 570 is also sprayed at S 450 and also covers portions of insulator 550 .
  • a stencil in the shape of the illustrated gap between conductive material 560 and conductive material 570 was placed at S 440 . The gap may facilitate electrical isolation between conductive material 560 and conductive material 570 .
  • Aperture 565 may comprise an exit window for light entering element 500 .
  • the stencil placed at S 440 may also define aperture 565 .
  • Such a stencil may comprise a mechanical, a liquid or a solid mask which is removed (i.e., peeled or dissolved) after S 450 .
  • Conductive materials 560 and 570 appear to extend to a uniform height above element 500 , this height need not be uniform. Conductive materials 560 and 570 may create a conductive path for electrical current generated by a photovoltaic (solar) cell coupled to element 500 . Conductive material 560 and conductive material 570 may also, as described in U.S. Patent Application Publication No. 2006/0231133, electrically link solar cells of adjacent solar concentrators in a solar concentrator array.
  • An electrical contact of a solar cell is coupled to the metal sprayed onto the optical element at S 460 .
  • the electrical contact may comprise a solder bump, and any number of intermediate conductive elements such as various layers of bonding pads may be used to couple the electrical contact to the exposed portion.
  • Coupling the electrical contact to the metal may comprise any flip-chip bonding techniques that are or become known.
  • the electrical contact may be placed on the metal using a pick-and-place machine, and the optical element and solar cell may be placed in a reflow oven to melt and subsequently cool the electrical contact.
  • FIG. 9 shows solder bumps 910 of solar cell 900 coupled to conductive material 560 .
  • Window 920 of solar cell 900 covers an optically-active area of solar cell 900 .
  • solder bumps 910 are coupled to conductive material 560 in some embodiments such that the optically-active area is aligned with aperture 565 .
  • Apparatus 500 of FIG. 9 may generally operate in accordance with the description of aforementioned U.S. Patent Application Publication No. 2006/0231133.
  • solar rays enter surface 598 and are reflected by reflective material 540 disposed on convex surface 510 .
  • the rays are reflected toward reflective material 540 on concave surface 530 , and are thereafter reflected toward aperture 565 .
  • the reflected rays pass through aperture 565 and are received by window 920 of solar cell 900 .
  • window 920 of solar cell 900 Those skilled in the art of optics will recognize that combinations of one or more other surface shapes may be utilized to concentrate solar rays onto a solar cell.
  • Solar cell 900 receives a substantial portion of the photon energy received at surface 598 and generates electrical current in response to the received photon energy.
  • the electrical current may be passed to external circuitry (and/or to similar serially-connected apparatuses) through conductive material 560 and conductive material 570 .
  • solar cell 900 may also comprise an electrical contact electrically coupled to conductive material 570 . Such a contact would exhibit a polarity opposite to the polarity of the contacts to which solder bumps 910 are coupled.

Abstract

A system may include an optical element, a thermal-sprayed material disposed on the optical element, and a solar cell coupled to the optical element. Some aspects provide thermal spraying of a first material onto an optical element, and coupling of a solar cell to the optical element. Thermal spraying the first material may include spraying a molten metal powder onto the optical element.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • The present application claims priority to U.S. Provisional Patent Application Ser. No. 60/899,150, filed on Feb. 2, 2007 and entitled “Concentrated Photovoltaic Energy Designs”, the contents of which are incorporated herein by reference for all purposes.
  • BACKGROUND
  • 1. Field
  • Some embodiments generally relate to the collection and concentration of solar radiation. More specifically, embodiments may relate to systems to efficiently fabricate solar radiation collectors.
  • 2. Brief Description
  • A concentrating solar radiation collector may convert received solar radiation (i.e., sunlight) into a concentrated beam and direct the concentrated beam onto a small photovoltaic cell. The cell, in turn, converts the photons of the received beam into electrical current.
  • U.S. Patent Application Publication No. 2006/0231133 describes several types of concentrating solar collectors. As described therein, a concentrating solar collector may include reflective material for directing received solar radiation, conductive material to carry electrical current generated from the solar radiation, and/or insulative material to isolate various conductors from one another. Fabrication of a solar radiation collector using one or more of these materials may be unsuitably complex and costly.
  • For example, conventional techniques for depositing these materials may include evaporating or sputtering within an established vacuum. Thin film lithographic techniques are employed to create desired patterns and features in the deposited materials. Such techniques require photoresist deposition, masking, UV exposure, and subsequent etching for each layer of material. Thin film lithography may provide geometrically accuracy but entails significant expense.
  • SUMMARY
  • To address at least the foregoing, some aspects provide a method, means and/or process steps to thermal spray a first material onto an optical element, and to couple a solar cell to the optical element. Thermal spraying the first material may include spraying a molten metal powder onto the optical element. Moreover, spraying the molten metal powder onto the optical element may include placing a stencil on the optical element and spraying a molten metal powder onto the stencil and the optical element.
  • In some aspects, thermal spraying the first material includes powder coating a polymer onto the optical element. According to still other aspects, a reflective material is deposited on a substantially-transparent core, an insulator is deposited on the reflective material, and thermal spraying the first material includes spraying a molten metal powder onto the insulator.
  • In other aspects, provided are an optical element, a thermal-sprayed material disposed on the optical element, and a solar cell coupled to the optical element. The thermal-sprayed material may comprise a hardened metal powder. In further aspects, the optical element may comprise an aperture from which light may pass out of the optical element, an electrical contact of the solar cell is coupled to the hardened metal powder, and an optically-active area of the solar cell is aligned with the aperture.
  • The thermal-sprayed material may comprise a polymer. Additionally or alternatively, the optical element may comprise a substantially-transparent core, a reflective material disposed on the substantially-transparent core, and an insulator disposed on the reflective material, wherein the thermal-sprayed material is disposed on the insulator. Further to the foregoing aspect, the insulator may include a powder-coated polymer.
  • The claims are not limited to the disclosed embodiments, however, as those in the art can readily adapt the description herein to create other embodiments and applications.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The construction and usage of embodiments will become readily apparent from consideration of the following specification as illustrated in the accompanying drawings, in which like reference numerals designate like parts.
  • FIG. 1 is a flow diagram of a method according to some embodiments.
  • FIG. 2A is a perspective view of a portion of an optical element and conductive material according to some embodiments.
  • FIG. 2B is a cross-sectional view of a portion of an optical element and conductive material according to some embodiments.
  • FIG. 3A is a perspective view of a portion of an optical element and a solar cell coupled thereto according to some embodiments.
  • FIG. 3B is a perspective view of a portion of an optical element and a solar cell coupled thereto according to some embodiments.
  • FIG. 4 is a flow diagram of a method according to some embodiments.
  • FIG. 5A is a perspective view of a transparent optical element according to some embodiments.
  • FIG. 5B is a cross-sectional view of a transparent optical element according to some embodiments.
  • FIG. 6A is a perspective view of a transparent optical element with reflective material disposed thereon according to some embodiments.
  • FIG. 6B is a cross-sectional view of a transparent optical element with reflective material disposed thereon according to some embodiments.
  • FIG. 7A is a perspective view of an optical element with an electrical isolator disposed thereon according to some embodiments.
  • FIG. 7B is a cross-sectional view of an optical element with an electrical isolator disposed thereon according to some embodiments.
  • FIG. 8A is a perspective view of an optical element with conductive material disposed thereon according to some embodiments.
  • FIG. 8B is a cross-sectional view of an optical element with conductive material disposed thereon according to some embodiments.
  • FIG. 9 is a cross-sectional view of an optical element and a solar cell according to some embodiments.
  • DETAILED DESCRIPTION
  • The following description is provided to enable any person in the art to make and use the described embodiments and sets forth the best mode contemplated for carrying out some embodiments. Various modifications, however, will remain readily apparent to those in the art.
  • FIG. 1 is a flow diagram of process 100 according to some embodiments. Process 100 may be performed by any combination of machine, hardware, software and manual means.
  • Initially, at S110, a first material is thermal sprayed onto an optical element. The first material may comprise any material that is capable of being thermally-sprayed. Thermal spraying the first material may include heating a powder to a molten state and spraying the molten powder onto the optical element. The molten powder then cools on the optical element to produce a solid layer of material. In some embodiments, a stencil may be applied to the optical element before spraying the molten powder onto the optical element. The first material is therefore deposited in a pattern defined by the stencil.
  • The thermal spraying may be performed using a known twin wire arc process in a case that the first material is a metal. Plasma spray techniques may be employed at S110 if the first material is a metal or a ceramic. Moreover, if the first material is a polymer (e.g., polyester, epoxy, polyurethane, etc.), the first material may be powder coated onto the optical element at S110. Accordingly, the term thermal spraying encompasses at least twin wire arcing, plasma spraying (e.g., hot, cold, assisted), and powder coating.
  • Thermal spraying the first material onto the optical element may comprise spraying the first material onto other material(s) already deposited on the optical element. According to some embodiments, the optical element may be configured to manipulate and/or pass desired wavelengths of light. The optical element may comprise any number of disparate materials and/or elements (e.g., lenses, reflective surfaces and optically-transparent portions).
  • FIG. 2A is a perspective view of apparatus 200 according to some embodiments, and FIG. 2B is a cross-sectional view of apparatus 200 as shown in FIG. 2A. Apparatus 200 includes optical element 220 and conductive material 210 sprayed thereon according to some embodiments of S110. FIGS. 2A and 2B show only a portion of apparatus 200 in order to illustrate that apparatus 200 may exhibit any suitable shape or size.
  • Conductive material 210 may comprise any combination of one or more currently- or hereafter-known conductors, including but not limited to copper, gold and nickel. A thickness of material 210 on optical element 220 might not be as uniform as shown in FIG. 2B.
  • A solar cell is coupled to the optical element at S120. The coupling at S120 may comprise coupling the solar cell to other material(s) already deposited on the optical element. For example, an electrical contact of the solar cell may be coupled to conductive material deposited on the optical element. Such a coupling may form an electrical and a mechanical interconnection between the conductive material and the solar cell. Various flip-chip bonding techniques may be employed in some embodiments to couple an electrical contact of the solar cell to conductive material deposited on the optical element.
  • FIG. 3A is a perspective view of apparatus 200 after S120 according to some embodiments. FIG. 3B is a cross-sectional view corresponding to FIG. 3A. Solder bumps 305 of solar cell 300 are coupled to conductive material 210. Solder bumps 305 may also be respectively coupled to unshown terminals of solar cell 300.
  • Solar cell 300 may comprise a solar cell (e.g., a III-V cell, II-VI cell, etc.) for receiving photons from optical element 220 and generating electrical charge carriers in response thereto. In this regard, some embodiments include an opening through dielectric conductive material 210 through which solar cell 300 may receive light from optical element 220.
  • FIG. 4 is a flow diagram of process 400 according to some embodiments. Process 400 may be performed by any combination of machine, hardware, software and manual means.
  • Process 400 begins at S410, at which an optical element is obtained. The optical element may be composed of any suitable material or combination of materials. The optical element may be created using any combination of devices and systems that is or becomes known.
  • FIG. 5A is a perspective view of optical element 500 created at S410 according to some embodiments, and FIG. 5B is a cross-sectional view of element 500. Optical element 500 may be molded from low-iron glass at S410 using known methods. Alternatively, separate pieces may be glued or otherwise coupled together to form element 500. Optical element 500 may comprise an element of a solar concentrator according to some embodiments.
  • Element 500 includes convex surface 510, pedestal 520, and concave surface 530. The purposes of each portion of element 500 during operation according to some embodiments will become evident from the description below.
  • A reflective material is deposited on the optical element at S420. The reflective material may be intended to create one or more mirrored surfaces. Any suitable reflective material may be used, taking into account factors such as but not limited to the wavelengths of light to be reflected, bonding of the reflective material to the optical element, and cost. In some embodiments, the reflective material may include a mirror coating, a dielectric enhancement coating, and/or a protective dielectric or polymer paint coating. The reflective material may be deposited by sputtering or other physical vapor deposition, liquid deposition, etc.
  • FIGS. 6A and 6B show perspective and cross-sectional views, respectively, of optical element 500 after some embodiments of S420. Reflective material 540 is deposited on convex surface 510 and concave surface 530. Reflective material 540 may comprise sputtered silver or aluminum. The vertical and horizontal surfaces of pedestal 520 may be masked at S420 such that reflective material 540 is not deposited thereon, or otherwise treated to remove any reflective material 540 that is deposited thereon.
  • Next, at S430, a polymer is powder-coated onto the optical element. The polymer may comprise an electrical insulator, and the powder-coating may proceed according to any method that is or becomes known. The polymer may act as a mechanical buffer layer between the reflective material and conductive material. This buffer layer can also be deposited by other means such as spraying, dipping or lamination. According to some embodiments, other suitable insulators such as any dielectrics, polyester, epoxy and polyurethane are powder-coated onto the optical element at S430.
  • Some embodiments of S430 are depicted in FIGS. 7A and 7B. Polymer 550 is deposited on convex surface 510 or, more particularly, on reflective material 540. S615 may be executed such that polymer 550 is not deposited on the vertical and horizontal surfaces of pedestal 520. According to the illustrated embodiment, polymer 550 is not deposited on concave surface 530 (i.e., on reflective material 540 deposited on concave surface 530).
  • Returning to process 400, a stencil is placed on the optical element at S440 and a molten metal powder is sprayed on the stencil and the optical element at S450. The stencil may comprise a mechanical, hard or soft tooling. The stencil may cover portions of the previously-deposited polymer that are not to receive the molten metal powder. The molten metal powder may be composed of any combination of one or more metals (e.g., nickel, copper).
  • FIG. 8A is a perspective view and FIG. 8B is a cross-sectional view of optical element 500 after S450 according to some embodiments. Conductive material 560 covers pedestal 520 and portions of insulator 550. Conductive material 570 is also sprayed at S450 and also covers portions of insulator 550. A stencil in the shape of the illustrated gap between conductive material 560 and conductive material 570 was placed at S440. The gap may facilitate electrical isolation between conductive material 560 and conductive material 570.
  • Aperture 565 may comprise an exit window for light entering element 500. The stencil placed at S440 may also define aperture 565. Such a stencil may comprise a mechanical, a liquid or a solid mask which is removed (i.e., peeled or dissolved) after S450.
  • Although conductive materials 560 and 570 appear to extend to a uniform height above element 500, this height need not be uniform. Conductive materials 560 and 570 may create a conductive path for electrical current generated by a photovoltaic (solar) cell coupled to element 500. Conductive material 560 and conductive material 570 may also, as described in U.S. Patent Application Publication No. 2006/0231133, electrically link solar cells of adjacent solar concentrators in a solar concentrator array.
  • An electrical contact of a solar cell is coupled to the metal sprayed onto the optical element at S460. The electrical contact may comprise a solder bump, and any number of intermediate conductive elements such as various layers of bonding pads may be used to couple the electrical contact to the exposed portion. Coupling the electrical contact to the metal may comprise any flip-chip bonding techniques that are or become known. For example, the electrical contact may be placed on the metal using a pick-and-place machine, and the optical element and solar cell may be placed in a reflow oven to melt and subsequently cool the electrical contact.
  • FIG. 9 shows solder bumps 910 of solar cell 900 coupled to conductive material 560. Window 920 of solar cell 900 covers an optically-active area of solar cell 900. Accordingly, solder bumps 910 are coupled to conductive material 560 in some embodiments such that the optically-active area is aligned with aperture 565.
  • Apparatus 500 of FIG. 9 may generally operate in accordance with the description of aforementioned U.S. Patent Application Publication No. 2006/0231133. With reference to FIG. 9, solar rays enter surface 598 and are reflected by reflective material 540 disposed on convex surface 510. The rays are reflected toward reflective material 540 on concave surface 530, and are thereafter reflected toward aperture 565. The reflected rays pass through aperture 565 and are received by window 920 of solar cell 900. Those skilled in the art of optics will recognize that combinations of one or more other surface shapes may be utilized to concentrate solar rays onto a solar cell.
  • Solar cell 900 receives a substantial portion of the photon energy received at surface 598 and generates electrical current in response to the received photon energy. The electrical current may be passed to external circuitry (and/or to similar serially-connected apparatuses) through conductive material 560 and conductive material 570. In this regard, solar cell 900 may also comprise an electrical contact electrically coupled to conductive material 570. Such a contact would exhibit a polarity opposite to the polarity of the contacts to which solder bumps 910 are coupled.
  • The several embodiments described herein are solely for the purpose of illustration. Embodiments may include any currently or hereafter-known versions of the elements described herein. Therefore, persons in the art will recognize from this description that other embodiments may be practiced with various modifications and alterations.

Claims (19)

1. A method comprising:
thermal spraying a first material onto an optical element; and
coupling a solar cell to the optical element.
2. A method according to claim 1, wherein thermal spraying the first material comprises spraying a molten metal powder onto the optical element.
3. A method according to claim 2, wherein spraying the molten metal powder onto the optical element comprises:
placing a stencil on the optical element; and
spraying a molten metal powder onto the stencil and the optical element.
4. A method according to claim 3, further comprising:
removing the stencil to expose an aperture from which light may pass out of the optical element,
wherein coupling the solar cell to the optical element comprises:
coupling an electrical contact of the solar cell to the first material to align an optically-active area of the solar cell with the aperture.
5. A method according to claim 3, wherein the stencil comprises a mechanical, hard or soft tooling.
6. A method according to claim 1, wherein thermal spraying the first material comprises powder coating a polymer onto the optical element.
7. A method according to claim 1, further comprising:
depositing a reflective material on a substantially-transparent core; and
depositing an insulator on the reflective material;
wherein thermal spraying the first material comprises spraying a molten metal powder onto the insulator.
8. A method according to claim 7, wherein depositing the insulator comprises powder coating a polymer onto the reflective material.
9. A method according to claim 7, wherein depositing the reflective material comprises physical vapor deposition of the reflective material onto the substantially-transparent core.
10. A method according to claim 7, wherein thermal spraying the first material comprises:
placing a stencil on the insulator; and
spraying a molten metal powder onto the stencil and the insulator.
11. A method according to claim 1, wherein thermal spraying the first material onto the optical element comprises:
placing a stencil on the optical element; and
spraying the first material onto the stencil and the optical element.
12. A method according to claim 1, wherein coupling the solar cell to the optical element comprises coupling an electrical contact of the solar cell to the first material to align an optically-active area of the solar cell with an aperture from which light may pass out of the optical element.
13. An apparatus comprising:
an optical element;
a thermal-sprayed material disposed on the optical element; and
a solar cell coupled to the optical element.
14. An apparatus according to claim 13, wherein the thermal-sprayed material comprises a hardened metal powder.
15. An apparatus according to claim 14, wherein:
the optical element comprises an aperture from which light may pass out of the optical element,
an electrical contact of the solar cell is coupled to the hardened metal powder, and
an optically-active area of the solar cell is aligned with the aperture.
16. An apparatus according to claim 13, wherein the thermal-sprayed material comprises a polymer.
17. An apparatus according to claim 13, wherein the optical element comprises:
a substantially-transparent core;
a reflective material disposed on the substantially-transparent core; and
an insulator disposed on the reflective material,
wherein the thermal-sprayed material is disposed on the insulator.
18. An apparatus according to claim 17, wherein the insulator comprises a powder-coated polymer.
19. An apparatus according to claim 13, wherein:
the optical element comprises an aperture from which light may pass out of the optical element,
an electrical contact of the solar cell is coupled to the thermal-sprayed material, and
an optically-active area of the solar cell is aligned with the aperture.
US11/782,605 2007-02-02 2007-07-24 Thermal spray for solar concentrator fabrication Abandoned US20090025784A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US11/782,605 US20090025784A1 (en) 2007-02-02 2007-07-24 Thermal spray for solar concentrator fabrication
PCT/US2008/050791 WO2008097688A1 (en) 2007-02-02 2008-01-10 Thermal spray for solar concentrator fabrication
EP08727546A EP2115787A1 (en) 2007-02-02 2008-01-10 Thermal spray for solar concentrator fabrication
AU2008214229A AU2008214229A1 (en) 2007-02-02 2008-01-10 Thermal spray for solar concentrator fabrication
JP2009548352A JP2010518255A (en) 2007-02-02 2008-01-10 Thermal spraying for solar concentrator manufacturing
US12/841,823 US20100294364A1 (en) 2007-02-02 2010-07-22 Thermal Spray For Solar Concentrator Fabrication

Applications Claiming Priority (2)

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US89915007P 2007-02-02 2007-02-02
US11/782,605 US20090025784A1 (en) 2007-02-02 2007-07-24 Thermal spray for solar concentrator fabrication

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US11/782,605 Abandoned US20090025784A1 (en) 2007-02-02 2007-07-24 Thermal spray for solar concentrator fabrication
US11/782,359 Abandoned US20090025789A1 (en) 2007-02-02 2007-07-24 Alignment of optical element and solar cell
US11/782,376 Abandoned US20080185039A1 (en) 2007-02-02 2007-07-24 Conductor fabrication for optical element
US11/782,609 Abandoned US20080186593A1 (en) 2007-02-02 2007-07-24 Metal trace fabrication for optical element
US12/841,823 Abandoned US20100294364A1 (en) 2007-02-02 2010-07-22 Thermal Spray For Solar Concentrator Fabrication
US12/909,488 Active 2028-03-06 US8389851B2 (en) 2007-02-02 2010-10-21 Metal trace fabrication for optical element
US13/586,794 Active US8624102B2 (en) 2007-02-02 2012-08-15 Metal trace fabrication for optical element

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US11/782,376 Abandoned US20080185039A1 (en) 2007-02-02 2007-07-24 Conductor fabrication for optical element
US11/782,609 Abandoned US20080186593A1 (en) 2007-02-02 2007-07-24 Metal trace fabrication for optical element
US12/841,823 Abandoned US20100294364A1 (en) 2007-02-02 2010-07-22 Thermal Spray For Solar Concentrator Fabrication
US12/909,488 Active 2028-03-06 US8389851B2 (en) 2007-02-02 2010-10-21 Metal trace fabrication for optical element
US13/586,794 Active US8624102B2 (en) 2007-02-02 2012-08-15 Metal trace fabrication for optical element

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