US20070248819A1 - Cellulosic Fibre of the Lyocell Type - Google Patents
Cellulosic Fibre of the Lyocell Type Download PDFInfo
- Publication number
- US20070248819A1 US20070248819A1 US10/560,834 US56083404A US2007248819A1 US 20070248819 A1 US20070248819 A1 US 20070248819A1 US 56083404 A US56083404 A US 56083404A US 2007248819 A1 US2007248819 A1 US 2007248819A1
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- United States
- Prior art keywords
- fibre
- fibres
- titre
- ratio
- dtex
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
Definitions
- the present invention relates to a cellulosic fibre of the Lyocell type.
- Fibres of the Lyocell type are produced by a solvent spinning process, wherein the cellulose is directly dissolved in an organic solvent without the formation of a derivative and the solution is spun. Such fibres are also referred to as “solvent-spun” fibres.
- “Lyocell” is the generic name allocated by BISFA (The International Bureau for the Standardization of man made fibers) for cellulose fibres which are produced by dissolving cellulose in an organic solvent without the formation of a derivative and extruding fibres from said solution by means of a dry-wet spinning process or a melt-blown process.
- An organic solvent is thereby understood to be a mixture of an organic chemical and water. At present, N-methyl-morpholine-N-oxide is used as an organic solvent on a commercial scale.
- the solution of the cellulose is usually extruded by means of a forming tool, whereby it is moulded. Via an air gap, the moulded solution gets into a precipitation bath, where the moulded body is obtained by precipitating the solution. The moulded body is washed and optionally dried after further treatment steps.
- a process for the production of Lyocell fibres is described, for instance, in U.S. Pat. No. 4,246,221. Lyocell fibres are distinguished by a high tensile strength, a high wet-modulus and a high loop strength.
- EP 0 494 851 describes a process for the manufacture of Lyocell fibres, wherein the draft (the ratio of the drawing-off speed of the filament, divided by the nozzle-hole discharge speed) amounts to 1 at the most, or in particular is smaller than 1, respectively.
- the present invention relates to a fibre of the Lyocell type which is characterized in that the ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk amounts to 2.2 or less.
- the ratio V amounts to 2.0 or less, particularly preferably to 1.8 or less. Furthermore, the ratio V should preferably not amount to less that 1.
- the fibre according to the invention exhibits a titre of 6 to 25 dtex.
- the titre of the fibre depends in particular on the drawing-off speed or on the ratio of the drawing-off speed to the speed at which the spinning dope is discharged from the spinneret, respectively.
- the fibre according to the invention is preferably provided in the form of a staple fibre.
- Fibres according to the invention are preferably produced by means of a process wherein the draft assumes a value of more than 1.
- the fibre according to the invention in particular when having a higher titre of 12 dtex, 15 dtex or more, is excellently suitable for applications in carpets, textile flooring materials, wall linings and/or decoration materials.
- the carpets today on the market are produced largely from the synthetic fibres polyamide and polypropylene and from wool. Mixtures of wool with polyamide and polypropylene are used as well. Fibres such as polyacrylonitrile, polyester and cotton play a secondary role.
- viscose fibres having a higher titre were also used for carpets besides cotton.
- the viscose fibre was completely eliminated from this field.
- carpets are used because of a higher living comfort in comparison with smooth floors. For areas subject to less strain, velour carpets according to the tufting method are usually used. For areas subject to higher mechanical strain, loop or felt carpets are used.
- a disadvantage of synthetic fibres and wool is their electrostatic charge. Tensions of 7-9 kV are measured in standardized walk tests. Only by appropriate measures, such as by furnishing the fibres with antistatic agents or by incorporating conductive fibres in the carpet structure, an antistatic effect can be achieved and the tension during the walk test can be reduced to below 3 kV. Another problem associated with wool is an infestation by moths, making it necessary that the carpets be treated with toxic insecticides.
- Polypropylene on the other hand, has, as a material for carpets, the disadvantage that the fibre is not colourable and printable, whereby only a limited colour palette can be achieved by spin dyeing.
- Lyocell fibres are not infested by moths and therefore require no additional furnishing. Lyocell fibres can be dyed by techniques known per se for cellulose fibres and therefore render possible various colour variations.
- Lyocell fibres having a higher titre and a balanced ratio V are their higher flexural stiffness as compared to other cellulose fibres such as, for example, viscose.
- spinning was conducted through nozzle holes having a diameter of 100 ⁇ m; in order to produce fibres with a higher titre, spinning was conducted through nozzle holes having a diameter of 160 ⁇ m.
- the ratio V was determined by dividing FFk (cN/tex) by FDk (%).
- Table 2 illustrates the high flexural stiffness of fibres of the Lyocell type as compared to viscose fibres.
- the flexural stiffness is determined according to a method developed by the applicant.
- the measured value is indicated as a titre-based ratio of the gradient of force to path across a linear measuring range.
- a conditioned fibre is clamped horizontally into a clamping bar and is cut with a device to a length of exactly 5 mm. Via an electric drive, the clamping bar is moved upward at a constant speed. In doing so, the fibre is pressed against a sensor plate which is adapted to a force transducer. The stiffer a fibre, the higher the measured force.
Abstract
The invention relates to a cellulosic fibre of the Lyocell type, which is characterized in that the ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk amounts to 2.2 or less.
Description
- The present invention relates to a cellulosic fibre of the Lyocell type.
- Fibres of the Lyocell type are produced by a solvent spinning process, wherein the cellulose is directly dissolved in an organic solvent without the formation of a derivative and the solution is spun. Such fibres are also referred to as “solvent-spun” fibres. “Lyocell” is the generic name allocated by BISFA (The International Bureau for the Standardization of man made fibers) for cellulose fibres which are produced by dissolving cellulose in an organic solvent without the formation of a derivative and extruding fibres from said solution by means of a dry-wet spinning process or a melt-blown process. An organic solvent is thereby understood to be a mixture of an organic chemical and water. At present, N-methyl-morpholine-N-oxide is used as an organic solvent on a commercial scale.
- In said process, the solution of the cellulose is usually extruded by means of a forming tool, whereby it is moulded. Via an air gap, the moulded solution gets into a precipitation bath, where the moulded body is obtained by precipitating the solution. The moulded body is washed and optionally dried after further treatment steps. A process for the production of Lyocell fibres is described, for instance, in U.S. Pat. No. 4,246,221. Lyocell fibres are distinguished by a high tensile strength, a high wet-modulus and a high loop strength.
- In a publication “Lyocell—eine vielseitige cellulosische Faser” in the Lenzinger Berichte 75/96 it is mentioned without any further details that carpets and carpet backs constitute possibilities of application for Lyocell fibres.
- In a lecture by W. Feilmair et al. “Funktionalität von Lenzing Lyocell® in Heimtextilien” at the 5th International Symposium “Alternative Cellulose—Herstellen, Verfahren, Eigenschaften” in Rudolstadt 2002, a fibre of the Lyocell type having a titre of 6.7 dtex and a cutting length of 60 mm is described.
-
EP 0 494 851 describes a process for the manufacture of Lyocell fibres, wherein the draft (the ratio of the drawing-off speed of the filament, divided by the nozzle-hole discharge speed) amounts to 1 at the most, or in particular is smaller than 1, respectively. - Conventional fibres of the Lyocell type exhibit a ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk (measured and calculated in accordance with the methods described below in greater detail) of clearly more than 2.2.
- Surprisingly, it has now been found that it is possible to provide a Lyocell fibre whose ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk is below 2.2.
- Accordingly, the present invention relates to a fibre of the Lyocell type which is characterized in that the ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk amounts to 2.2 or less.
- Preferably, the ratio V amounts to 2.0 or less, particularly preferably to 1.8 or less. Furthermore, the ratio V should preferably not amount to less that 1.
- Preferably, the fibre according to the invention exhibits a titre of 6 to 25 dtex.
- Surprisingly, it has been shown that a balanced ratio between FFk and Fdk is achievable in particular during the manufacture of Lyocell fibres having a higher titre.
- It is known to a person skilled in the art that the titre of the fibre depends in particular on the drawing-off speed or on the ratio of the drawing-off speed to the speed at which the spinning dope is discharged from the spinneret, respectively.
- It has now been found that, during the manufacture of fibres having a higher titre, a decrease in the ratio between FFk and FdK is observed as the titre increases. Said effect becomes apparent in particular as from a titre of 6 dtex. Extra low ratios V can be achieved when producing fibres having a titre of 7 dtex or more, in particular 12 dtex or more, and preferably 15 dtex or more.
- The fibre according to the invention is preferably provided in the form of a staple fibre.
- Fibres according to the invention are preferably produced by means of a process wherein the draft assumes a value of more than 1.
- It has been found that the fibre according to the invention, in particular when having a higher titre of 12 dtex, 15 dtex or more, is excellently suitable for applications in carpets, textile flooring materials, wall linings and/or decoration materials.
- The carpets today on the market are produced largely from the synthetic fibres polyamide and polypropylene and from wool. Mixtures of wool with polyamide and polypropylene are used as well. Fibres such as polyacrylonitrile, polyester and cotton play a secondary role.
- Up until the mid-60ies, viscose fibres having a higher titre (f.i. 17 dtex) were also used for carpets besides cotton. However, due to the development of synthetic fibres and their advantages in terms of mechanical resilience, the viscose fibre was completely eliminated from this field.
- Various demands are made on carpets. Carpets are used because of a higher living comfort in comparison with smooth floors. For areas subject to less strain, velour carpets according to the tufting method are usually used. For areas subject to higher mechanical strain, loop or felt carpets are used.
- A disadvantage of synthetic fibres and wool is their electrostatic charge. Tensions of 7-9 kV are measured in standardized walk tests. Only by appropriate measures, such as by furnishing the fibres with antistatic agents or by incorporating conductive fibres in the carpet structure, an antistatic effect can be achieved and the tension during the walk test can be reduced to below 3 kV. Another problem associated with wool is an infestation by moths, making it necessary that the carpets be treated with toxic insecticides. Polypropylene, on the other hand, has, as a material for carpets, the disadvantage that the fibre is not colourable and printable, whereby only a limited colour palette can be achieved by spin dyeing.
- Surprisingly, it has turned out that it is feasible to produce tufting carpets exhibiting excellent mechanical properties from Lyocell fibres having a higher titre of, f.i., 15 dtex, especially in combination with synthetic fibres. In comparison with carpets made from synthetic fibres and/or wool, carpets made from Lyocell fibres exhibit an inherently antistatic behaviour. In the above-mentioned standardized walk tests, the tension is in the range of less than 1 kV.
- As opposed to wool, Lyocell fibres are not infested by moths and therefore require no additional furnishing. Lyocell fibres can be dyed by techniques known per se for cellulose fibres and therefore render possible various colour variations.
- Another favourable property of Lyocell fibres having a higher titre and a balanced ratio V is their higher flexural stiffness as compared to other cellulose fibres such as, for example, viscose.
- In a continuously operating pilot plant for the manufacture of cellulose fibres of the Lyocell type, a cellulose solution having a cellulose content of about 13% (pulp manufacturer: Bacell) was spun through nozzles in a manner known per se and the final titre of the fibres was changed by adjusting the draft ratio (=drawing-off speed of the filament/nozzle-hole discharge speed, in each case in m/min).
- In order to produce fibres with a titre of up to about 3.25, spinning was conducted through nozzle holes having a diameter of 100 μm; in order to produce fibres with a higher titre, spinning was conducted through nozzle holes having a diameter of 160 μm.
- According to the “Testing methods viscose, modal, lyocell and acetate staple fibres and tows” as published by BISFA, the fibre strength in the conditioned state FFk (cN/tex) as well as the fibre elongation in the conditioned state FDk (%) were determined in each case from the obtained fibres.
- From the values for FFk and FDk evaluated in this way, the ratio V was determined by dividing FFk (cN/tex) by FDk (%).
- The following table 1 contains a summary of test parameters and obtained results.
TABLE 1 Spinning Dia- FFk mass meter absolute Ratio cellulose nozzle Draft Titre FFk FDk (cN/tex* V (FFk/ (%) [μm] ratio (dtex) (cN/tex) (%) dtex) FDk) 12.0 100 17 0.92 45.7 16.6 42 2.75 13.0 100 13 1.30 41 15.2 53 2.70 13.0 100 9 1.71 37.6 14.8 64 2.54 13.5 100 5 3.17 33.8 12.6 107 2.68 13 0 160 13 3.25 37.5 12.8 122 2.93 13.5 160 7 5.73 29.1 11.4 167 2.55 13.7 160 2.7 13.00 30.8 14.3 400 2.15 13.5 160 2.6 15.70 27.6 14 433 1.97 13.5 160 2.1 17.20 31.2 15.1 537 2.07 13.5 160 1.8 19.20 30.6 16.7 588 1.83 - Table 1 makes evident that, as from a titre of 6 dtex, the ratio V assumes values of 2.2 or less.
- This is also apparent in particular from
FIG. 1 wherein the results are graphically represented in accordance with Table 1. - One reason for the decrease in the ratio V in case of higher fibre titres could be that the evaluated fibre elongation of the fibres decreases virtually linearly down to a titre of about 6 dtex but increases in case of higher titres.
- This is illustrated in
FIG. 2 wherein the absolute fibre strength “FFk absolute” (FFk multiplied by the respective fibre titre) and the fibre elongation FDk are plotted against the fibre titre. Whereas the absolute fibre strength increases linearly with an increasing titre, the fibre elongation at first decreases with an increasing titre in order to rise again with higher titres. - Table 2 illustrates the high flexural stiffness of fibres of the Lyocell type as compared to viscose fibres.
- The flexural stiffness is determined according to a method developed by the applicant. The measured value is indicated as a titre-based ratio of the gradient of force to path across a linear measuring range.
- For implementation, a conditioned fibre is clamped horizontally into a clamping bar and is cut with a device to a length of exactly 5 mm. Via an electric drive, the clamping bar is moved upward at a constant speed. In doing so, the fibre is pressed against a sensor plate which is adapted to a force transducer. The stiffer a fibre, the higher the measured force.
- Due to a lack of calibration possibilities, no effective force is indicated for calculating the flexural stiffness. It is, however, possible to conduct a relative comparison of fibres within a certain measuring range. In doing so, the gradient in a linear measuring range of the measured force per path is calculated and related to the titre of the fibre.
TABLE 2 Bending gradient/ dtex Titre (dtex) Lyocell Viscose 1.3 0.03 3.3 0.12 0.06 5.0 0.11 6.7 0.22 13.6 0.52 17.0 0.31
Claims (9)
1. A cellulo sic fibre of the Lyocell type, characterized in that the ratio V of the strength of the fibre in the conditioned state FFk to the fibre elongation in the conditioned state Fdk amounts to 2.2 or less.
2. A fibre according to claim 1 , wherein the ratio V amounts to 2.0 or less.
3. A fibre according to claim 1 , wherein the ratio V amounts to 1.8 or less.
4. A fibre according to claim 1 , wherein the ratio V amounts to at least 1.
5. A fibre according to claim 1 , wherein the titre of the fibre amounts to 6 to 25 dtex.
6. A fibre according to claim 5 , wherein the titre of the fibre amounts to 6.5 dtex or more.
7. A fibre according to claim 5 , wherein the titre of the fibre amounts to 12 dtex or more, preferably to 15 dtex or more.
8. A fibre according to claim 1 in the form of a staple fibre.
9. The use of a fibre according to claim 1 in carpets, textile flooring materials, wall linings and/or decoration materials.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0001604U AT6807U1 (en) | 2004-01-13 | 2004-01-13 | CELLULOSIC FIBER OF THE LYOCELL GENERATION |
ATGM16/2004 | 2004-01-13 | ||
PCT/AT2004/000441 WO2005068693A1 (en) | 2004-01-13 | 2004-12-15 | Lyocell-type cellulose fibre |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070248819A1 true US20070248819A1 (en) | 2007-10-25 |
Family
ID=31892467
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/560,834 Abandoned US20070248819A1 (en) | 2004-01-13 | 2004-12-15 | Cellulosic Fibre of the Lyocell Type |
Country Status (10)
Country | Link |
---|---|
US (1) | US20070248819A1 (en) |
EP (1) | EP1704271B1 (en) |
JP (1) | JP4638882B2 (en) |
KR (1) | KR101225557B1 (en) |
CN (1) | CN100558949C (en) |
AT (2) | AT6807U1 (en) |
DE (1) | DE502004007639D1 (en) |
DK (1) | DK1704271T3 (en) |
TW (1) | TWI325449B (en) |
WO (1) | WO2005068693A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040178142A1 (en) * | 2002-01-31 | 2004-09-16 | Koslow Evan E. | Integrated paper comprising fibrillated fibers and active particles immobilized therein |
US20110223398A1 (en) * | 2010-03-09 | 2011-09-15 | Valley Forge Fabrics, Inc. | Upholstery and Wall Panel Weight Woven Fabrics |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3674452A1 (en) * | 2018-12-28 | 2020-07-01 | Lenzing Aktiengesellschaft | Spinneret, method of heating a spinneret and lyocell process |
CN115058810A (en) * | 2022-04-05 | 2022-09-16 | 山东超越纺织有限公司 | Compact siro spinning process for modal, double-resistant acrylic fibers and mulberry silk fibers |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4246221A (en) * | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
US5189152A (en) * | 1990-07-16 | 1993-02-23 | Lenzing Aktiengesellschaft | Cellulose solution in water and nmmo |
US5216144A (en) * | 1990-12-07 | 1993-06-01 | Lenzing Aktiengesellschaft | Method of producing shaped cellulosic articles |
US5252284A (en) * | 1991-01-09 | 1993-10-12 | Lenzing Aktiengesellschaft | Method of producing shaped cellulosic articles |
US5543101A (en) * | 1993-07-08 | 1996-08-06 | Lenzing Aktiengesellschaft | Process of making cellulose fibres |
US5863478A (en) * | 1996-03-04 | 1999-01-26 | Lenzing Aktiengesellschaft | Process for the manufacture of cellulose fibres |
US5928973A (en) * | 1997-09-29 | 1999-07-27 | American Nonwovens Corporation | Nonwoven needlepunch fabric and articles produced therefrom |
US6210801B1 (en) * | 1996-08-23 | 2001-04-03 | Weyerhaeuser Company | Lyocell fibers, and compositions for making same |
US6235392B1 (en) * | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
US6706237B2 (en) * | 1996-08-23 | 2004-03-16 | Weyerhaeuser Company | Process for making lyocell fibers from pulp having low average degree of polymerization values |
US20050225002A1 (en) * | 2002-09-03 | 2005-10-13 | Johann Manner | Cellulose fiber |
US20060035053A1 (en) * | 2002-09-16 | 2006-02-16 | Dieter Eichinger | Blanket, in particular quilt |
US20070105469A1 (en) * | 2003-07-21 | 2007-05-10 | Lenzing Aktiengesellschaft | Use of a lyocell-type staple fibre as a padding fibre |
US20080233821A1 (en) * | 2005-08-26 | 2008-09-25 | Lenzing Aktiengesellschaft | Cellulosic Molded Body, Method For Manufacturing It and Use Thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT395862B (en) * | 1991-01-09 | 1993-03-25 | Chemiefaser Lenzing Ag | METHOD FOR PRODUCING A CELLULOSIC MOLDED BODY |
GB9404547D0 (en) * | 1994-03-09 | 1994-04-20 | Courtaulds Fibres Holdings Ltd | Fibre production process |
JP2000226720A (en) | 1999-02-04 | 2000-08-15 | Kuraray Co Ltd | Cellulose yarn having controlled fibrillation and its production |
JP3937216B2 (en) * | 2002-03-18 | 2007-06-27 | 東洋紡績株式会社 | Method for producing cellulose molded body |
-
2004
- 2004-01-13 AT AT0001604U patent/AT6807U1/en not_active IP Right Cessation
- 2004-12-15 KR KR1020057023877A patent/KR101225557B1/en active IP Right Grant
- 2004-12-15 WO PCT/AT2004/000441 patent/WO2005068693A1/en active IP Right Grant
- 2004-12-15 DE DE502004007639T patent/DE502004007639D1/en active Active
- 2004-12-15 US US10/560,834 patent/US20070248819A1/en not_active Abandoned
- 2004-12-15 CN CNB2004800166143A patent/CN100558949C/en not_active Expired - Fee Related
- 2004-12-15 JP JP2006548029A patent/JP4638882B2/en not_active Expired - Fee Related
- 2004-12-15 EP EP04802004A patent/EP1704271B1/en active Active
- 2004-12-15 AT AT04802004T patent/ATE401435T1/en active
- 2004-12-15 DK DK04802004T patent/DK1704271T3/en active
-
2005
- 2005-01-05 TW TW094100281A patent/TWI325449B/en not_active IP Right Cessation
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4246221A (en) * | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
US5189152A (en) * | 1990-07-16 | 1993-02-23 | Lenzing Aktiengesellschaft | Cellulose solution in water and nmmo |
US5216144A (en) * | 1990-12-07 | 1993-06-01 | Lenzing Aktiengesellschaft | Method of producing shaped cellulosic articles |
US5252284A (en) * | 1991-01-09 | 1993-10-12 | Lenzing Aktiengesellschaft | Method of producing shaped cellulosic articles |
US5543101A (en) * | 1993-07-08 | 1996-08-06 | Lenzing Aktiengesellschaft | Process of making cellulose fibres |
US5863478A (en) * | 1996-03-04 | 1999-01-26 | Lenzing Aktiengesellschaft | Process for the manufacture of cellulose fibres |
US6706237B2 (en) * | 1996-08-23 | 2004-03-16 | Weyerhaeuser Company | Process for making lyocell fibers from pulp having low average degree of polymerization values |
US6210801B1 (en) * | 1996-08-23 | 2001-04-03 | Weyerhaeuser Company | Lyocell fibers, and compositions for making same |
US6235392B1 (en) * | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
US7067444B2 (en) * | 1996-08-23 | 2006-06-27 | Weyerhaeuser Company | Lyocell nonwoven fabric |
US5928973A (en) * | 1997-09-29 | 1999-07-27 | American Nonwovens Corporation | Nonwoven needlepunch fabric and articles produced therefrom |
US20050225002A1 (en) * | 2002-09-03 | 2005-10-13 | Johann Manner | Cellulose fiber |
US20060035053A1 (en) * | 2002-09-16 | 2006-02-16 | Dieter Eichinger | Blanket, in particular quilt |
US20070105469A1 (en) * | 2003-07-21 | 2007-05-10 | Lenzing Aktiengesellschaft | Use of a lyocell-type staple fibre as a padding fibre |
US20080233821A1 (en) * | 2005-08-26 | 2008-09-25 | Lenzing Aktiengesellschaft | Cellulosic Molded Body, Method For Manufacturing It and Use Thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040178142A1 (en) * | 2002-01-31 | 2004-09-16 | Koslow Evan E. | Integrated paper comprising fibrillated fibers and active particles immobilized therein |
US7655112B2 (en) * | 2002-01-31 | 2010-02-02 | Kx Technologies, Llc | Integrated paper comprising fibrillated fibers and active particles immobilized therein |
US8613363B2 (en) | 2002-01-31 | 2013-12-24 | Kx Technologies Llc | Integrated paper comprising fibrillated fibers and active agents immobilized therein |
US20110223398A1 (en) * | 2010-03-09 | 2011-09-15 | Valley Forge Fabrics, Inc. | Upholstery and Wall Panel Weight Woven Fabrics |
Also Published As
Publication number | Publication date |
---|---|
CN100558949C (en) | 2009-11-11 |
WO2005068693A1 (en) | 2005-07-28 |
DE502004007639D1 (en) | 2008-08-28 |
CN1806070A (en) | 2006-07-19 |
ATE401435T1 (en) | 2008-08-15 |
AT6807U1 (en) | 2004-04-26 |
KR101225557B1 (en) | 2013-01-24 |
DK1704271T3 (en) | 2008-10-27 |
JP2007517993A (en) | 2007-07-05 |
KR20060114628A (en) | 2006-11-07 |
EP1704271B1 (en) | 2008-07-16 |
TW200526828A (en) | 2005-08-16 |
TWI325449B (en) | 2010-06-01 |
EP1704271A1 (en) | 2006-09-27 |
JP4638882B2 (en) | 2011-02-23 |
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