US20070138326A1 - Automatic microfluidic fragrance dispenser - Google Patents

Automatic microfluidic fragrance dispenser Download PDF

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US20070138326A1
US20070138326A1 US11/312,911 US31291105A US2007138326A1 US 20070138326 A1 US20070138326 A1 US 20070138326A1 US 31291105 A US31291105 A US 31291105A US 2007138326 A1 US2007138326 A1 US 2007138326A1
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fragrance
microfluidic circuit
group
solid
fluid
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US11/312,911
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Zhiyu Hu
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/02Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
    • A61L9/03Apparatus therefor
    • A61L9/035Apparatus therefor emanating multiple odours
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/20Poisoning, narcotising, or burning insects
    • A01M1/2022Poisoning or narcotising insects by vaporising an insecticide
    • A01M1/2027Poisoning or narcotising insects by vaporising an insecticide without heating
    • A01M1/2038Holders or dispensers for pressurized insecticide, e.g. pressurized vessels, cans
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/20Poisoning, narcotising, or burning insects
    • A01M1/2022Poisoning or narcotising insects by vaporising an insecticide
    • A01M1/2027Poisoning or narcotising insects by vaporising an insecticide without heating
    • A01M1/2044Holders or dispensers for liquid insecticide, e.g. using wicks
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/20Poisoning, narcotising, or burning insects
    • A01M1/2022Poisoning or narcotising insects by vaporising an insecticide
    • A01M1/2061Poisoning or narcotising insects by vaporising an insecticide using a heat source
    • A01M1/2077Poisoning or narcotising insects by vaporising an insecticide using a heat source using an electrical resistance as heat source
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • A61L9/145Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes air-liquid contact processes, e.g. scrubbing

Definitions

  • the invention pertains to apparatus and methods for dispensing fragrances and more particularly to wearable microfluidic dispensers for releasing controlled amounts of fragrance compounds at controlled intervals.
  • Fragrances and perfumes can be applied onto skin, clothes or other objects for releasing scent and odor.
  • These application methods have been around for centuries. The main disadvantages of these methods include: 1. The scent concentration generally is too strong right after the application then it becomes weaker over the time. The user has no control of scent concentration level over time. 2.
  • Many perfume/cologne are designed in such a way once they are applied onto skin the user's body heat acts like a vaporizer or scent dispenser to promote the circulation of odor.
  • fragment includes any natural or synthetic volatile compounds, solutions, or mixtures that have some intended olfactory effect in humans or animals.
  • the effect may be conscious, as in the case of perfume or cologne, or subconscious, as in the case of pheromones.
  • the compounds may be relatively undetectable by the user yet have desired masking effects against the olfactory senses of animals. Examples include so-called insect repellents as well as scent masking agents for hunters.
  • a further class of fragrances for which the present invention may be used includes various scented agents to which medicinal effects have been attributed, i.e., so-called “aromatherapy” agents.
  • Perfume is the term applied to a strong alcoholic solution of odorants, as opposed to weaker solvents such as toilet waters and eaux de cologne.
  • Colognes, eaux de toilette, eaux de perfume, and other “dilute perfumes” have a concentrate content of 3% to 8% prepared in a 75° to 90° alcohol solution. They contain perfume oil, water (the presence of water generally increases the persistence of odors on the skin), and alcohol.
  • Perfumes generally cover a range of 10% to 35% concentrate with an alcoholic strength between 85° and 95°. A higher perfume concentration does not mean higher strength and tenacity; too high a concentration causes the fragrance to be dull and non-diffusing. It has been known for some time that perfumes that had lasting success had similar or identical evaporation behaviors.
  • Natural odorants in perfumery are generally classified into seven categories: 1. Concrete Oils or “natural flower oils”: Flowers, leaves, and roots are subjected to extraction by hydrocarbon solvents, which dissolve the waxes containing the odorous principles from the flowers. The concrete of the flowers has the appearance of solid wax and is insoluble in water and alcohol. It is possible to dissolve it by mixing in 95° alcohol for about a month. Odorous products of the flower are then obtained. 2. Absolute Oils: Obtained by extracting concretes with alcohol, then eliminating the alcohol at reduced pressure. The product obtained is soluble in alcohol and has the consistency of honey. 3. Essential Oils: Derived from a distillation process applied to flowers, leaves, stalks, herbs, roots, and certain fruits. They are the most widely used of all natural perfumery materials.
  • Synthetic products used in perfumery include the following: 1. Aldehydes, esters, ethers, ketones, and lactones. 2. Methyl heptin carbonate (MHC), a potent alkyne carbonate used with restraint and discrimination, has a fresh, penetrating odor used as an odorant of green, violet-leaf fragrances, when used in 5% dilution gives excellent, long-lasting effects in violet gardenia, freesia, and other perfumes. 3. Phenylacetaldehyde gives a pungent green odor used as constituent of spring flower perfumes, but is somewhat unstable. 4.
  • Dimethyl acetal gives a characteristically green odor suggesting fresh wet foliage, useful in woody, mossy, and certain floral types, and is probably the most frequently used acetal in perfumery. 5.
  • Ethyl methyl phenyl glycidate is the chief component of artificial strawberry compounds. 6.
  • Acetates are most profusely used of all the esters; the most important class of synthetic odorants produced is the aliphatic aldehydes.
  • dispensers suitable for fragrances have been known for many years. These include the familiar pump-type spray bottles and the gas-powered or “aerosol” cans. Both of these applicators dispense a stream or mist of liquid droplets on demand.
  • a pump-type dispenser may be refillable or the pump head may be interchangeable among different reservoir bottles. Aerosol cans are most often disposable once the contents are exhausted.
  • Other devices include a container with a porous wick that generally resembles a felt-tip pen and may be uncapped and dabbed on the user's skin at desired intervals.
  • the dispenser consists of a capped, cylindrical vial filled with an absorbent material and having a small hole in the cap, through which the fragrance escapes by natural evaporation.
  • room fresheners Stationary devices that dispense fragrance into the air are broadly referred to as “room fresheners”. These may be substantially passive devices in which the desired fragrance is released by evaporation from a porous wick (see Compton et al., U.S. Pat. No. 4,323,193) or from a hydrogel (see Lanzet, U.S. Pat. No. 2,927,055; Graiver et al., U.S. Pat. No. 4,891,389). The evaporation rate may be controlled by manually opening or closing the device, by raising the wick, and so on. These devices may alternatively contain fans, heating elements, etc. to enhance or control the release of the selected fragrance.
  • a further class of fragrance dispensing devices includes systems for releasing fragrances, detergents, etc. into a lavatory.
  • Various means have been described for controlling the release of these generally liquid substances to minimize waste.
  • Such means include installing infrared detectors to actuate the device each time a user approaches or leaves (see, for example, Shieh, U.S. Pat. No. 5,377,363), electrical switches or hydraulic valves to actuate the device when the lavatory is flushed, and other means (see, for example, Stone, U.S. Pat. No. 6,694,534).
  • Objects of the present invention include the following: providing an apparatus and method for releasing small, controlled amounts of volatile compounds; providing a wearable fragrance dispenser that releases one or more selected fragrances in the vicinity of the wearer at selected rates or selected intervals; providing a wearable fragrance dispenser that also serves the aesthetic function of jewelry; providing a fragrance dispenser that may be concealed on the person; providing a means for dispensing selected fragrance compounds near the user without depositing the fragrance directly on the skin or clothing; and, providing a means of dispensing controlled doses of aromatherapy agents.
  • an apparatus for dispensing fragrances comprises: a fluid reservoir containing a selected fragrance; a solid-state microfluidic circuit to control the release of the fragrance from the reservoir; a solid state switching device configured to actuate the microfluidic circuit according to a selected program; and, a power supply configured to provide electric power to operate the switching device and the microfluidic circuit.
  • a method of dispensing fragrances comprises the steps of: providing a fluid reservoir containing a selected fragrance; providing a solid-state microfluidic circuit configured to dispense the fragrance from said reservoir at a selected rate; providing a solid-state switching device configured to actuate the microfluidic circuit for a selected duration at selected times; and, providing a power supply sufficient to operate the switching device and the microfluidic circuit, whereby the fragrance may be withdrawn from the reservoir for vaporization into the surrounding air at a selected rate.
  • a method of dispensing fragrances comprises the steps of: providing a fluid reservoir containing a selected fragrance, the fragrance having aromatherapeutic attributes; providing a solid-state microfluidic circuit configured to dispense the fragrance from the reservoir at a selected rate; providing a solid-state switching device configured to actuate the microfluidic circuit for a selected duration at selected times; and, providing a power supply sufficient to operate the switching device and the microfluidic circuit, whereby the fragrance may be withdrawn from the reservoir at a selected rate for vaporization into the surrounding air.
  • FIG. 1 is a schematic diagram of one embodiment of the present invention, in which a solid-state microfluidic device dispenses a fragrance from a fluid reservoir.
  • FIG. 2 is a schematic diagram of an embodiment of the invention in which the components of a fragrance-dispensing device are contained within a protective housing.
  • FIG. 3 is a schematic diagram of an embodiment of the invention having a plurality of fluid reservoirs, each containing a separate fragrance.
  • FIG. 4 is a schematic diagram of an embodiment of the invention adapted to be worn as a pendant.
  • the invention contains a fluid reservoir holding a desired fragrance in liquid form.
  • the liquid may include such ingredients as essential oils, natural or synthetic odor compounds, esters, phenols, etc., along with solvents or diluents such as water, alcohol, etc.
  • the fluid reservoir is connected to a microfluidic control element including one or more micromachined channels through which the fluid may be pumped in order to release the scent.
  • a conventional solid-state controller is provided to actuate the microfluidic control element at selected intervals in order to maintain the desired level of fragrance release.
  • a battery or other conventional power source (such as a photovoltaic cell) is provided to drive the various elements.
  • a decorative housing unit may be provided to carry the cartridge, thereby doubling as an item of jewelry such as a necklace, brooch, hair clip, or the like.
  • the battery and/or solid-state controller may be contained in the housing unit, thereby minimizing the cost of the disposable cartridge element, and in that case the housing unit will contain electrodes that engage corresponding contacts on the cartridge.
  • Various conventional means such as keyways, etc., may be used to ensure that the electrodes and contacts maintain the necessary alignment to engage properly.
  • Some exemplary categories of fluid dispensing technology include: Pin transfer, needle dispensing, jetting, and spraying.
  • Pin transfer uses a pin that is dipped into a reservoir of fluid. The fluid is transferred to the part by touching the pin to surface of the part.
  • Needle dispensing is one of the more common methods used in automated fluid dispensing. Material is extruded through a needle that is held close to the surface of a part. As the needle is pulled away, the fluid is held to the board by gravity and surface tension.
  • a variety of devices can be used to extrude the material through the needle: auger pumps, pneumatic pumps, or piston pumps.
  • Needle dispensing devices may include valves to control the flow of very low viscosity fluids. Material viscosity from 1 cp (e.g., water) to over 1,000,000 cp (e.g., thick grease) can be dispensed with needles.
  • 1 cp e.g., water
  • 1,000,000 cp e.g., thick grease
  • Jet dispensing energizes a specific quantity of fluid such that the kinetic energy of the fluid is used to break the fluid stream from the nozzle.
  • Viscosities of 1 cp (e.g., water) to over 100,000 cp (e.g., surface mount adhesives) can be jetted with various mechanisms.
  • Complex fluid rheology is an important factor in the suitability of a fluid for jetting. Picoliter volumes of low viscosity materials are widely used in printing technology; however, fluids used in these applications are generally limited to specially formulated inks. Jetting of materials likely to be used for MEMs assemblies, such as adhesives, find a practical limitation of approximately 3 nanoliters and larger. Diameters of approximately 250 ⁇ m are possible. Many of the limitations of solid content and filler size of needle dispensing apply to jetting.
  • Jetting fluids can provide some unique advantages.
  • the energy for breaking the fluid from the nozzle comes from the kinetic energy of the fluid. Jetting is less sensitive to the gap between the nozzle and the part.
  • the fluid stream from a jet can be as small as 100 ⁇ m in diameter, allowing fluid to be deposited in areas that it is not possible to place a needle.
  • Dot Dispensing Large deposits of fluid can be made with relative ease, so the discussion here will focus on the practical lower limits available commercially. With pin transfer, fluid deposits of ⁇ 1 nanoliter and 100 ⁇ m in diameter are possible with many adhesives. The stability of the processes are difficult to control since the amount of fluid deposited can vary as fluid characteristics change. The process requires open containers of fluid.
  • Fragrant liquid 11 is contained within reservoir 12 .
  • a microfluidic device 13 receives liquid 11 from reservoir 12 .
  • a control circuit 14 receives power from power source 15 , which may be a battery, photocell, or other suitable device, and applies an actuating signal to microfluidic device 13 through conductors 17 .
  • the actuating signal causes microfluidic device 13 to dispense a small droplet 16 of the fragrant liquid.
  • the droplet 16 is dispensed to the surface of the device for evaporation, rather than forcefully ejected as would be the case in a typical ink-jet printer head.
  • An ink-jet printer head may consume as much as 12 W of power. Simple dispensing, rather than forceful ejection, requires significantly less energy and is therefore more suited to a small, battery-powered device.
  • Skilled artisans may construct the inventive device by routine engineering practices using a number of suitable components, including the following: Suzuki et al. (Sensors and Actuators B 2002, 86, pp. 242-250) have described a micropump system, which could pump liquid at a rate of 2 nl per second with a 1.2 V bias and 0.1 mA current or 0.12 mW. A small fluidic reservoir could easily be attached to the micropump using conventional adhesives. Tsai et al. (J. of Microelectromechanical Systems 2002, 11[6], pp.
  • thermal-bubble micronozzle-diffuser pump which is able to pump a very large volume of liquid at a rate of 4 ⁇ 5 gl/min when the driving pulse is 250 ⁇ 400 Hz and duty cycle of 5 ⁇ 10% with a power consumption of about 0.5 W.
  • the average power consumption is only 50 mW.
  • Commercially available “coin” lithium batteries e.g., BRxxxx and CRxxxx series, Panasonic Corp.
  • the invention overcomes a fundamental limitation of prior fragrance dispensing approaches, viz., that a particular fragrance might include several components with differing rates of evaporation.
  • a dispenser that relies on evaporation from a small orifice (as disclosed in U.S. Pat. No. 4,785,642) or one that relies on evaporation from a gel body (as described in U.S. Pat. No. 2,927,055) will invariably display some effect of differential evaporation.
  • the composition of the fragrant material remaining in the reservoir will therefore tend to change somewhat with time and the perceived fragrance will change with it.
  • a very small volume of liquid is withdrawn from the reservoir and completely converted to vapor before a second volume of fluid is withdrawn.
  • the bulk composition of the liquid remaining in the reservoir does not change with time and the fragrance is therefore more uniform.
  • microfluidic devices that may be used to carry out Applicant's invention.
  • Channels of the appropriate size may be etched into glass or silicon and various strategies may be used to pump the fluid, including local heating, electroosmotic effects, piezoelectric actuation, etc.
  • Familiar examples of practical applications of microfluidic devices include ink-jet printers and various small-scale chemical reaction devices (see, for example, Ramsey, U.S. Pat. No. 5,858,195).
  • Hansen, et al. Current Opinion in Structural Biology 2003, 13, pp. 538-544
  • Barry, et al. Journal of Nanobiotechnology 2004, 2, pp.
  • a microfabricated electrokinetic pump is disclosed by Corbin, et al. in U.S. Pat. No. 6,881,039.
  • a pump and passive check valve is disclosed by Dai, et al. in U.S. Pat. No. 6,874,999.
  • a method of building peristaltic micropumps using polydimethylsiloxane multilayer soft lithography is described by Goulpeau, et al. ( Journal of Applied Physics 2005, 98, #044914).
  • An electrokinetic pump for pumping a liquid including a pumping body having a plurality of narrow, short and straight pore apertures for channeling the liquid through the body is described by Corbin, et al. in U.S. Pat. No.
  • the device preferably operates in a mode that avoids the forceful ejection of droplets (in contrast to the operation of an ink-jet printer, for example).
  • Various elements may therefore be provided to help convert the pumped fluid to vapor.
  • a porous layer may be disposed on an outside surface of the device; the microfluidic element may pump the fluid to this porous layer, from which it will evaporate in a controlled manner.
  • a heating element may optionally be provided, preferably as an integral part of the microfluidic device.
  • microfluidic device preferably for a selected duration at some selected time interval.
  • This is preferably done using a small integrated circuit that contains at least a timing function and a switching function, and, preferably, a memory function.
  • ASIC application specific integrated circuit
  • FPGA field-programmable gate array
  • appropriate time and drive signal could be provided by a microcontroller such as MAXIM (Dallas Semiconductor, Dallas, Tex.) DS80xx, DS87xx or DS89xx series. Some of these chips have a built-in memory and can be programmed by users. Other examples of suitable microcontrollers are Texas Instruments MSPxx series and Motorola MC68xx series chips.
  • the device has a single operating mode, wherein once activated by the user the device simply releases fragrance at regular intervals over a predefined time scale.
  • a more sophisticated device can be constructed, whose operating parameters may be user-programmed over some range.
  • Such user programming may be as simple as a small multiposition switch (e.g., low-medium-high) that can select either greater or lesser duration of the individual actuations or shorter or longer times between actuations.
  • a continuous user-programmable controller may be used. This controller may further contain visual indicators such as LED elements or an LCD display to indicate various operating states.
  • the device may be adapted to interact with a base station (through a temporary electrical connection, wireless data link, or the like) from which it may download a more complicated operating profile.
  • a means such as a vent or check valve in order to allow air to enter the reservoir 12 to compensate for the volume of fragrant liquid 11 being removed therefrom.
  • a mechanical check valve and air passage may be fabricated as one component on the microfluidic device 13 or other conventional venting means may be employed. It will be appreciated that in some instances it may be practical to pressurize the reservoir 12 in which case the microfluidic device 13 may be simplified to employ a valve rather than an active pumping mechanism.
  • FIG. 1 The components indicated schematically in FIG. 1 may be combined within a housing in order to provide a small, self-contained, and relatively robust unit as shown schematically in FIG. 2 .
  • An outer housing 21 is provided, which contains spring mounted battery 15 ′, control circuit 14 , reservoir 12 , and fragrance 11 .
  • the solid-state fluidic device 13 is located under reservoir 12 and is protected by a mesh 28 , which serves to protect the surface of the device from damage while allowing the vaporized fragrance to escape.
  • the mesh may further provide a decorative function if desired.
  • the invention may also be adapted to dispense more than one fragrance as shown generally at 30 in FIG. 3 .
  • Three separate reservoirs 12 ′ contain fluids 11 ′, 11 ′′, and 11 ′′′.
  • the device may be configured so that one multichannel solid state microfluidic device 13 ′ (driven by control circuit 14 ) receives fluids from each of the reservoirs 12 ′.
  • the microfluidic device 13 ′ may be controlled to dispense individual fragrances 11 ′, 11 ′′, and 11 ′′′ selectively at various times, to dispense them as separate droplets at the same time, or to blend them in selected ratios and dispense droplets of the resulting blended composition.
  • the components may be contained within housing 21 and protective mesh 28 , as in the previous example.
  • one housing unit may be configured to accept several dispensing cartridges 20 , each with its own microfluidic device 13 .
  • the cartridges may be substantially self-contained, i.e., have individual power supply 15 and control circuit 14 .
  • the housing unit may contain a single power supply 15 with electrical contacts to engage each of the dispensing cartridges 20 .
  • the housing unit may further contain a single microprocessor or switching device 14 with electrical contacts to engage each of the microfluidic devices 13 .
  • any suitable power source may be used, including photovoltaic cells, capacitive storage elements, and others.
  • the device may also be provided with a wire, cable, plug, or jack arrangement in order to accept power from a larger external power source. This may be useful, for example, in a device intended for use in an automobile, wherein power may be supplied via a wire in the auto's electrical system.
  • the actuating signal from control circuit 14 may be delivered to microfluidic device 13 via a hard-wired connection or via a wireless link using any conventional wireless protocol.
  • the housing unit is intended to be a permanent piece of fine or costume jewelry, in which the wearer may replace the fragrance-dispensing unit when it is used up, or to select a different fragrance.
  • the housing unit may be worn for its decorative value even when fragrance is not being dispensed.
  • the housing unit may provide a degree of mechanical protection to the cartridge, particularly in the case where the fluid reservoir is a small glass vial.
  • fragrance dispenser 41 is adapted with a chain 42 , allowing it to be worn as a necklace.
  • dispenser 41 may be adapted to be attached to, or integral with, other personal items such as a pin, brooch, hair clip, wristwatch, telephone handset, and so on.
  • the housing unit may be provided with various conventional means for attachment to the body or clothing of the user; these means can include chains, hooks, pins, dips, and the like.
  • the entire unit may be designed to be fairly unobtrusive during use. This might be advantageous, for example, in applications where the device is dispensing pheromones, masking agents, insect repellents, and the like.
  • the unit may also be configured to fit in a user's shirt pocket, to accommodate a larger fluid reservoir, larger battery, etc., as might be desired for steady, long-term use by outdoorsmen or the military.
  • the device is configured so that it can be worn on the person.
  • the device may easily be deployed in other uses and locations. For example, it may be placed in the ventilation system of an automobile, the air outlet of an air conditioner, or other convenient location where the user desires to have a controlled release of fragrance at selected time intervals.
  • perfumes, colognes, and other fragrant products are typically mixtures or solutions of numerous chemical compounds along with solvents and other additives.
  • inventive device may be used for dispensing any and all such mixtures, blends, solutions, or dispersions as are familiar to those skilled in the art of fragrance production and use.
  • the apparatus includes several fluid reservoirs, each of the individual fluids will, in turn, frequently be a mixture or solution in its own right but it may, in some cases, be a substantially pure component or concentrate.
  • aromatherapy describes a branch of holistic or “traditional” medicine wherein various healing attributes are associated with particular aromas.
  • the practice of treating physical or mental problems by the inhalation of specific aromas has been carried out since ancient times and anecdotal evidence among practitioners in the art identifies dozens of fragrances purported to have some value in aromatherapy [see, for example V. A. Worwood, The Complete Book of Essential Oils and Aromatherapy , New World Library, 1991].
  • the materials typically used include essential oils or extracts of various plants, flowers, herbs, etc.
  • the inventive device may be used to dispense fragrances for aromatherapy treatment.
  • Individual fragrances or combinations of fragrances may be selected by the user or prescribed by an aromatherapy practitioner, who may also recommend frequency or duration of treatment, etc.
  • the inventive device offers the advantage that the aromatherapeutic agent is dispensed efficiently directly in the vicinity of the user, rather than dispersed into the air to fill a room, for example.
  • Some examples of materials that have been offered for aromatherapy include the following: angelica root, anise, Peru balsam, basil, bay, bay laurel, beeswax, bergamot, mint bergamot, bois-de-rose, boronia, cajeput, cardamom, carrot seed, cedarwood, chamomile, cinnamon, citronella, clary sage, clove bud, coriander, cypress, dill, elemi, eucalyptus, fennel, fir needle, frankincense, galbanum, geranium, rose geranium, ginger, grapefruit, helichrysum, hyssop, immortelle, jasmine, juniper berry, kanuka, lavender, lavendin, lemon, lemon grass, lime, linden blossom, mandarin, manuka, marjoram, may chang, myrrh, myrtle, neroli, niaouli
  • Aromatherapy products also frequently make use of solvents, such as water or alcohol, as well as “carrier oils” such as sweet almond, apricot kernel, avocado, borage, cocoa butter, evening primrose, grapeseed, hazelnut, jojoba, kukui, macadamia nut, olive, peanut, pecan, rose hip, sesame, shea butter, and sunflower.
  • solvents such as water or alcohol
  • carrier oils such as sweet almond, apricot kernel, avocado, borage, cocoa butter, evening primrose, grapeseed, hazelnut, jojoba, kukui, macadamia nut, olive, peanut, pecan, rose hip, sesame, shea butter, and sunflower.

Abstract

A method and apparatus for dispensing fragrance into the air in the vicinity of the user comprises a liquid reservoir and a solid-state microfluidic controller actuated by a solid-state switching device. The microfluidic device is designed to vaporize or pump the fragrant material into the air and thereby release a scent under the manipulation of an electrical circuit, which is preferably battery powered. The entire device consisting of fluid reservoir, pump or valve, power supply, and electronic controls, is preferably small enough to be conveniently attached to clothing or worn by the user. The device may further be contained in a substantially decorative housing and worn like jewelry. The device may be pre-programmed to dispense automatically according to a preset cycle, or it may be adjustable or programmable to some degree by the user.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The invention pertains to apparatus and methods for dispensing fragrances and more particularly to wearable microfluidic dispensers for releasing controlled amounts of fragrance compounds at controlled intervals.
  • 2. Description of Related Art
  • Fragrances and perfumes can be applied onto skin, clothes or other objects for releasing scent and odor. There are two basic techniques for perfume application. One is to directly apply perfume/cologne liquid or concentrate onto the targeted subject. Another is to pump through a dispenser that vaporizes the perfume via a fan or atomizes the liquid perfume into many very small mist droplets by compressed air flow. These application methods have been around for centuries. The main disadvantages of these methods include: 1. The scent concentration generally is too strong right after the application then it becomes weaker over the time. The user has no control of scent concentration level over time. 2. Many perfume/cologne are designed in such a way once they are applied onto skin the user's body heat acts like a vaporizer or scent dispenser to promote the circulation of odor. The problem is that same perfume/cologne might react differently on the people's skins, altering the scent and, in some cases, causing irritation or allergic reactions. 3. To change the scent from one perfume to another, one needs to remove the first and apply the new perfume. This might be impractical because of the time constraints or restrictions of social circumstances. 4. Chemicals such as alcohol or aldehyde often are preferred choice of solvent and they are also the odor carrier of perfume as they evaporate. But they could also cause skin irritation and other problems. For example, the odor of these chemicals might interfere with the scent of perfume.
  • As used herein, the term “fragrance” includes any natural or synthetic volatile compounds, solutions, or mixtures that have some intended olfactory effect in humans or animals. The effect may be conscious, as in the case of perfume or cologne, or subconscious, as in the case of pheromones. The compounds may be relatively undetectable by the user yet have desired masking effects against the olfactory senses of animals. Examples include so-called insect repellents as well as scent masking agents for hunters. A further class of fragrances for which the present invention may be used includes various scented agents to which medicinal effects have been attributed, i.e., so-called “aromatherapy” agents.
  • Perfume is the term applied to a strong alcoholic solution of odorants, as opposed to weaker solvents such as toilet waters and eaux de cologne. Colognes, eaux de toilette, eaux de parfum, and other “dilute perfumes” have a concentrate content of 3% to 8% prepared in a 75° to 90° alcohol solution. They contain perfume oil, water (the presence of water generally increases the persistence of odors on the skin), and alcohol. Perfumes generally cover a range of 10% to 35% concentrate with an alcoholic strength between 85° and 95°. A higher perfume concentration does not mean higher strength and tenacity; too high a concentration causes the fragrance to be dull and non-diffusing. It has been known for some time that perfumes that had lasting success had similar or identical evaporation behaviors.
  • Natural odorants in perfumery are generally classified into seven categories: 1. Concrete Oils or “natural flower oils”: Flowers, leaves, and roots are subjected to extraction by hydrocarbon solvents, which dissolve the waxes containing the odorous principles from the flowers. The concrete of the flowers has the appearance of solid wax and is insoluble in water and alcohol. It is possible to dissolve it by mixing in 95° alcohol for about a month. Odorous products of the flower are then obtained. 2. Absolute Oils: Obtained by extracting concretes with alcohol, then eliminating the alcohol at reduced pressure. The product obtained is soluble in alcohol and has the consistency of honey. 3. Essential Oils: Derived from a distillation process applied to flowers, leaves, stalks, herbs, roots, and certain fruits. They are the most widely used of all natural perfumery materials. Some oxidation-prone essential oils are treated on production site with traces of antioxidants. 4. Essential Oils Obtained by Expression: Citrus fruits yield essential oil by squeezing the peels. 5. Isolates etc. from Essential Oils: These products are midway between natural and synthetic products. 6. Natural Odorants as Tinctures: Some natural products are used in the form of tinctures by mixing in 95° alcohol for a period of time. Examples include animal musk, ambergris, civet, castoreum, root, and oakmoss. 7. Balsams and Resins: Resin materials found on trees and plants are extracted with different solvents.
  • Synthetic products used in perfumery include the following: 1. Aldehydes, esters, ethers, ketones, and lactones. 2. Methyl heptin carbonate (MHC), a potent alkyne carbonate used with restraint and discrimination, has a fresh, penetrating odor used as an odorant of green, violet-leaf fragrances, when used in 5% dilution gives excellent, long-lasting effects in violet gardenia, freesia, and other perfumes. 3. Phenylacetaldehyde gives a pungent green odor used as constituent of spring flower perfumes, but is somewhat unstable. 4. Dimethyl acetal gives a characteristically green odor suggesting fresh wet foliage, useful in woody, mossy, and certain floral types, and is probably the most frequently used acetal in perfumery. 5. Ethyl methyl phenyl glycidate is the chief component of artificial strawberry compounds. 6. Acetates are most profusely used of all the esters; the most important class of synthetic odorants produced is the aliphatic aldehydes.
  • Several types of dispensers suitable for fragrances have been known for many years. These include the familiar pump-type spray bottles and the gas-powered or “aerosol” cans. Both of these applicators dispense a stream or mist of liquid droplets on demand. A pump-type dispenser may be refillable or the pump head may be interchangeable among different reservoir bottles. Aerosol cans are most often disposable once the contents are exhausted. Other devices include a container with a porous wick that generally resembles a felt-tip pen and may be uncapped and dabbed on the user's skin at desired intervals. Yet another approach for controlled release of a fragrance or insect repellent involves an adhesive patch to be worn by the user, the patch having a multilayer structure intended to release a scent at a controlled rate (see Fischel-Ghodsian, U.S. Pat. No. 5,071,704).
  • An article of jewelry containing a refillable fragrance dispenser is disclosed by Chin, et al. in U.S. Pat. No. 4,785,642. The dispenser consists of a capped, cylindrical vial filled with an absorbent material and having a small hole in the cap, through which the fragrance escapes by natural evaporation.
  • Stationary devices that dispense fragrance into the air are broadly referred to as “room fresheners”. These may be substantially passive devices in which the desired fragrance is released by evaporation from a porous wick (see Compton et al., U.S. Pat. No. 4,323,193) or from a hydrogel (see Lanzet, U.S. Pat. No. 2,927,055; Graiver et al., U.S. Pat. No. 4,891,389). The evaporation rate may be controlled by manually opening or closing the device, by raising the wick, and so on. These devices may alternatively contain fans, heating elements, etc. to enhance or control the release of the selected fragrance.
  • A further class of fragrance dispensing devices includes systems for releasing fragrances, detergents, etc. into a lavatory. Various means have been described for controlling the release of these generally liquid substances to minimize waste. Such means include installing infrared detectors to actuate the device each time a user approaches or leaves (see, for example, Shieh, U.S. Pat. No. 5,377,363), electrical switches or hydraulic valves to actuate the device when the lavatory is flushed, and other means (see, for example, Stone, U.S. Pat. No. 6,694,534).
  • OBJECTS AND ADVANTAGES
  • Objects of the present invention include the following: providing an apparatus and method for releasing small, controlled amounts of volatile compounds; providing a wearable fragrance dispenser that releases one or more selected fragrances in the vicinity of the wearer at selected rates or selected intervals; providing a wearable fragrance dispenser that also serves the aesthetic function of jewelry; providing a fragrance dispenser that may be concealed on the person; providing a means for dispensing selected fragrance compounds near the user without depositing the fragrance directly on the skin or clothing; and, providing a means of dispensing controlled doses of aromatherapy agents. These and other objects and advantages of the invention will become apparent from consideration of the following specification, read in conjunction with the drawings.
  • SUMMARY OF THE INVENTION
  • According to one aspect of the invention, an apparatus for dispensing fragrances comprises: a fluid reservoir containing a selected fragrance; a solid-state microfluidic circuit to control the release of the fragrance from the reservoir; a solid state switching device configured to actuate the microfluidic circuit according to a selected program; and, a power supply configured to provide electric power to operate the switching device and the microfluidic circuit.
  • According to another aspect of the invention, a method of dispensing fragrances comprises the steps of: providing a fluid reservoir containing a selected fragrance; providing a solid-state microfluidic circuit configured to dispense the fragrance from said reservoir at a selected rate; providing a solid-state switching device configured to actuate the microfluidic circuit for a selected duration at selected times; and, providing a power supply sufficient to operate the switching device and the microfluidic circuit, whereby the fragrance may be withdrawn from the reservoir for vaporization into the surrounding air at a selected rate.
  • According to another aspect of the invention, a method of dispensing fragrances comprises the steps of: providing a fluid reservoir containing a selected fragrance, the fragrance having aromatherapeutic attributes; providing a solid-state microfluidic circuit configured to dispense the fragrance from the reservoir at a selected rate; providing a solid-state switching device configured to actuate the microfluidic circuit for a selected duration at selected times; and, providing a power supply sufficient to operate the switching device and the microfluidic circuit, whereby the fragrance may be withdrawn from the reservoir at a selected rate for vaporization into the surrounding air.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The drawings accompanying and forming part of this specification are included to depict certain aspects of the invention. A clearer conception of the invention, and of the components and operation of systems provided with the invention, will become more readily apparent by referring to the exemplary, and therefore non-limiting embodiments illustrated in the drawing figures, wherein like numerals (if they occur in more than one view) designate the same elements. The features in the drawings are not necessarily drawn to scale.
  • FIG. 1 is a schematic diagram of one embodiment of the present invention, in which a solid-state microfluidic device dispenses a fragrance from a fluid reservoir.
  • FIG. 2 is a schematic diagram of an embodiment of the invention in which the components of a fragrance-dispensing device are contained within a protective housing.
  • FIG. 3 is a schematic diagram of an embodiment of the invention having a plurality of fluid reservoirs, each containing a separate fragrance.
  • FIG. 4 is a schematic diagram of an embodiment of the invention adapted to be worn as a pendant.
  • DETAILED DESCRIPTION OF THE INVENTION
  • In its most general form, the invention contains a fluid reservoir holding a desired fragrance in liquid form. The liquid may include such ingredients as essential oils, natural or synthetic odor compounds, esters, phenols, etc., along with solvents or diluents such as water, alcohol, etc. The fluid reservoir is connected to a microfluidic control element including one or more micromachined channels through which the fluid may be pumped in order to release the scent. A conventional solid-state controller is provided to actuate the microfluidic control element at selected intervals in order to maintain the desired level of fragrance release. A battery or other conventional power source (such as a photovoltaic cell) is provided to drive the various elements.
  • The foregoing components are preferably combined into a low-cost, substantially self-contained device or cartridge that may be disposable when the liquid is exhausted. A decorative housing unit may be provided to carry the cartridge, thereby doubling as an item of jewelry such as a necklace, brooch, hair clip, or the like. In this embodiment, the battery and/or solid-state controller may be contained in the housing unit, thereby minimizing the cost of the disposable cartridge element, and in that case the housing unit will contain electrodes that engage corresponding contacts on the cartridge. Various conventional means such as keyways, etc., may be used to ensure that the electrodes and contacts maintain the necessary alignment to engage properly.
  • Some exemplary categories of fluid dispensing technology include: Pin transfer, needle dispensing, jetting, and spraying. Pin transfer uses a pin that is dipped into a reservoir of fluid. The fluid is transferred to the part by touching the pin to surface of the part. Needle dispensing is one of the more common methods used in automated fluid dispensing. Material is extruded through a needle that is held close to the surface of a part. As the needle is pulled away, the fluid is held to the board by gravity and surface tension. A variety of devices can be used to extrude the material through the needle: auger pumps, pneumatic pumps, or piston pumps.
  • Needle dispensing devices may include valves to control the flow of very low viscosity fluids. Material viscosity from 1 cp (e.g., water) to over 1,000,000 cp (e.g., thick grease) can be dispensed with needles.
  • Jet dispensing energizes a specific quantity of fluid such that the kinetic energy of the fluid is used to break the fluid stream from the nozzle. Viscosities of 1 cp (e.g., water) to over 100,000 cp (e.g., surface mount adhesives) can be jetted with various mechanisms. Complex fluid rheology is an important factor in the suitability of a fluid for jetting. Picoliter volumes of low viscosity materials are widely used in printing technology; however, fluids used in these applications are generally limited to specially formulated inks. Jetting of materials likely to be used for MEMs assemblies, such as adhesives, find a practical limitation of approximately 3 nanoliters and larger. Diameters of approximately 250 μm are possible. Many of the limitations of solid content and filler size of needle dispensing apply to jetting.
  • Jetting fluids can provide some unique advantages. The energy for breaking the fluid from the nozzle comes from the kinetic energy of the fluid. Jetting is less sensitive to the gap between the nozzle and the part. The fluid stream from a jet can be as small as 100 μm in diameter, allowing fluid to be deposited in areas that it is not possible to place a needle.
  • Dot Dispensing: Large deposits of fluid can be made with relative ease, so the discussion here will focus on the practical lower limits available commercially. With pin transfer, fluid deposits of <1 nanoliter and 100 μm in diameter are possible with many adhesives. The stability of the processes are difficult to control since the amount of fluid deposited can vary as fluid characteristics change. The process requires open containers of fluid.
  • EXAMPLE
  • The basic elements of the invention are shown schematically at 10 in FIG. 1. Fragrant liquid 11 is contained within reservoir 12. A microfluidic device 13 receives liquid 11 from reservoir 12. A control circuit 14 receives power from power source 15, which may be a battery, photocell, or other suitable device, and applies an actuating signal to microfluidic device 13 through conductors 17. The actuating signal causes microfluidic device 13 to dispense a small droplet 16 of the fragrant liquid.
  • As shown in FIG. 1, it is preferable that the droplet 16 is dispensed to the surface of the device for evaporation, rather than forcefully ejected as would be the case in a typical ink-jet printer head. An ink-jet printer head may consume as much as 12 W of power. Simple dispensing, rather than forceful ejection, requires significantly less energy and is therefore more suited to a small, battery-powered device.
  • Skilled artisans may construct the inventive device by routine engineering practices using a number of suitable components, including the following: Suzuki et al. (Sensors and Actuators B 2002, 86, pp. 242-250) have described a micropump system, which could pump liquid at a rate of 2 nl per second with a 1.2 V bias and 0.1 mA current or 0.12 mW. A small fluidic reservoir could easily be attached to the micropump using conventional adhesives. Tsai et al. (J. of Microelectromechanical Systems 2002, 11[6], pp. 665-671) have described a thermal-bubble micronozzle-diffuser pump which is able to pump a very large volume of liquid at a rate of 4˜5 gl/min when the driving pulse is 250˜400 Hz and duty cycle of 5˜10% with a power consumption of about 0.5 W. When the system operates at 3 Hz pulse excitation frequency and the duty cycle of 5%, the average power consumption is only 50 mW. Commercially available “coin” lithium batteries (e.g., BRxxxx and CRxxxx series, Panasonic Corp.) have a power capacity up to 1000 mAh with a weight of a few grams that could provide enough power to operate the micropump continuously for more than one and half years.
  • From the foregoing description it will be apparent that the invention overcomes a fundamental limitation of prior fragrance dispensing approaches, viz., that a particular fragrance might include several components with differing rates of evaporation. A dispenser that relies on evaporation from a small orifice (as disclosed in U.S. Pat. No. 4,785,642) or one that relies on evaporation from a gel body (as described in U.S. Pat. No. 2,927,055) will invariably display some effect of differential evaporation. The composition of the fragrant material remaining in the reservoir will therefore tend to change somewhat with time and the perceived fragrance will change with it. In the inventive device, a very small volume of liquid is withdrawn from the reservoir and completely converted to vapor before a second volume of fluid is withdrawn. Thus, the bulk composition of the liquid remaining in the reservoir does not change with time and the fragrance is therefore more uniform.
  • Various approaches exist for manufacturing microfluidic devices that may be used to carry out Applicant's invention. Channels of the appropriate size may be etched into glass or silicon and various strategies may be used to pump the fluid, including local heating, electroosmotic effects, piezoelectric actuation, etc. Familiar examples of practical applications of microfluidic devices include ink-jet printers and various small-scale chemical reaction devices (see, for example, Ramsey, U.S. Pat. No. 5,858,195). A general summary of microfluidic technology and devices is given by Hansen, et al. (Current Opinion in Structural Biology 2003, 13, pp. 538-544), and Barry, et al. (Journal of Nanobiotechnology 2004, 2, pp. 2-6), and Erickson et al. (Analytica Chimica Acta 2004, 5071, pp. 11-26), and Ziaie et al. (Advanced Drug Delivery Reviews 2004, 56[2], pp. 145-172) and Malek et al. (Microelectronics Journal 2004, 35[2], pp. 131-143), and Beebe et al. (Annual Review of Biomedical Engineering 2002, 4, pp. 261-286) and Darhuber (Annual Review of Fluid Mechanics 2005, 37, pp. 425455). A piston-type pump made by MEMS techniques is disclosed by Galambos, et al. in U.S. Pat. No. 6,886,916. A microfabricated electrokinetic pump is disclosed by Corbin, et al. in U.S. Pat. No. 6,881,039. A pump and passive check valve is disclosed by Dai, et al. in U.S. Pat. No. 6,874,999. A method of building peristaltic micropumps using polydimethylsiloxane multilayer soft lithography is described by Goulpeau, et al. (Journal of Applied Physics 2005, 98, #044914). An electrokinetic pump for pumping a liquid including a pumping body having a plurality of narrow, short and straight pore apertures for channeling the liquid through the body is described by Corbin, et al. in U.S. Pat. No. 6,881,039; and by Kopf-Sill, et al. in U.S. Pat. Nos. 6,524,790; 6,613,512; and 6,703,205. A method of building a dielectric pump to move fluids which have two dissimilar dielectric constants from an interface through microchannels is described by Vacca in U.S. Pat. No. 6,949,176. An apparatus and method for controlling the delivery of fluids and, in particular, to the delivery of fluids to a receptor is described by Kane, et al. in U.S. Pat. No. 6,109,717. Shawgo, et al. (Current Opinion in Solid State & Materials Science 2002, 6[4], pp. 329-334) described MEMS-based micropumps and their applications for drug delivery. Any or all of the foregoing microfluidic devices and methods may be suitable to use in implementing the present invention.
  • As noted, the device preferably operates in a mode that avoids the forceful ejection of droplets (in contrast to the operation of an ink-jet printer, for example). Various elements may therefore be provided to help convert the pumped fluid to vapor. For example, a porous layer may be disposed on an outside surface of the device; the microfluidic element may pump the fluid to this porous layer, from which it will evaporate in a controlled manner. Alternatively, a heating element may optionally be provided, preferably as an integral part of the microfluidic device.
  • As discussed in the foregoing example, it is necessary to provide a means for actuating the microfluidic device, preferably for a selected duration at some selected time interval. This is preferably done using a small integrated circuit that contains at least a timing function and a switching function, and, preferably, a memory function. Those skilled in the art will appreciate that many conventional circuits will be suitable for this device, which may be implemented as an application specific integrated circuit (ASIC) or as a field-programmable gate array (FPGA) or similar device and its associated software. The skilled artisan, by applying routine engineering principles, may therefore select the most appropriate control circuit 14 based on the choice of microfluidic device 13, cost and performance objectives, power consumption, and other considerations. For the control circuit 14, appropriate time and drive signal could be provided by a microcontroller such as MAXIM (Dallas Semiconductor, Dallas, Tex.) DS80xx, DS87xx or DS89xx series. Some of these chips have a built-in memory and can be programmed by users. Other examples of suitable microcontrollers are Texas Instruments MSPxx series and Motorola MC68xx series chips.
  • In order for the device to be small and simple to use, it is generally preferred that the device has a single operating mode, wherein once activated by the user the device simply releases fragrance at regular intervals over a predefined time scale. However, it will be appreciated that a more sophisticated device can be constructed, whose operating parameters may be user-programmed over some range. Such user programming may be as simple as a small multiposition switch (e.g., low-medium-high) that can select either greater or lesser duration of the individual actuations or shorter or longer times between actuations. In a more sophisticated design, a continuous user-programmable controller may be used. This controller may further contain visual indicators such as LED elements or an LCD display to indicate various operating states. Alternatively, the device may be adapted to interact with a base station (through a temporary electrical connection, wireless data link, or the like) from which it may download a more complicated operating profile.
  • In many instances it will be preferable to provide a means such as a vent or check valve in order to allow air to enter the reservoir 12 to compensate for the volume of fragrant liquid 11 being removed therefrom. A mechanical check valve and air passage may be fabricated as one component on the microfluidic device 13 or other conventional venting means may be employed. It will be appreciated that in some instances it may be practical to pressurize the reservoir 12 in which case the microfluidic device 13 may be simplified to employ a valve rather than an active pumping mechanism.
  • EXAMPLE
  • The components indicated schematically in FIG. 1 may be combined within a housing in order to provide a small, self-contained, and relatively robust unit as shown schematically in FIG. 2. An outer housing 21 is provided, which contains spring mounted battery 15′, control circuit 14, reservoir 12, and fragrance 11. The solid-state fluidic device 13 is located under reservoir 12 and is protected by a mesh 28, which serves to protect the surface of the device from damage while allowing the vaporized fragrance to escape. The mesh may further provide a decorative function if desired.
  • EXAMPLE
  • The invention may also be adapted to dispense more than one fragrance as shown generally at 30 in FIG. 3. Three separate reservoirs 12′ contain fluids 11′, 11″, and 11′″. As shown in FIG. 3, the device may be configured so that one multichannel solid state microfluidic device 13′ (driven by control circuit 14) receives fluids from each of the reservoirs 12′. It will be appreciated that the microfluidic device 13′ may be controlled to dispense individual fragrances 11′, 11″, and 11′″ selectively at various times, to dispense them as separate droplets at the same time, or to blend them in selected ratios and dispense droplets of the resulting blended composition. The components may be contained within housing 21 and protective mesh 28, as in the previous example.
  • It will be apparent to those skilled in the art that this embodiment may be implemented in many alternative configurations to achieve substantially the same purpose. For example, one housing unit may be configured to accept several dispensing cartridges 20, each with its own microfluidic device 13. The cartridges may be substantially self-contained, i.e., have individual power supply 15 and control circuit 14. Alternatively, the housing unit may contain a single power supply 15 with electrical contacts to engage each of the dispensing cartridges 20. The housing unit may further contain a single microprocessor or switching device 14 with electrical contacts to engage each of the microfluidic devices 13.
  • It will be further appreciated that although some exemplary devices are shown with an on-board battery as a preferred power source, any suitable power source may be used, including photovoltaic cells, capacitive storage elements, and others. The device may also be provided with a wire, cable, plug, or jack arrangement in order to accept power from a larger external power source. This may be useful, for example, in a device intended for use in an automobile, wherein power may be supplied via a wire in the auto's electrical system. Furthermore, the actuating signal from control circuit 14 may be delivered to microfluidic device 13 via a hard-wired connection or via a wireless link using any conventional wireless protocol.
  • It will be understood that in some instances the housing unit is intended to be a permanent piece of fine or costume jewelry, in which the wearer may replace the fragrance-dispensing unit when it is used up, or to select a different fragrance. In some cases, the housing unit may be worn for its decorative value even when fragrance is not being dispensed. Furthermore, it will be appreciated that the housing unit may provide a degree of mechanical protection to the cartridge, particularly in the case where the fluid reservoir is a small glass vial.
  • EXAMPLE
  • Illustrated schematically at 40 in FIG. 4 is an embodiment of the invention in which fragrance dispenser 41 is adapted with a chain 42, allowing it to be worn as a necklace. Similarly, dispenser 41 may be adapted to be attached to, or integral with, other personal items such as a pin, brooch, hair clip, wristwatch, telephone handset, and so on.
  • In other instances, it may be desirable to make the housing unit from very inexpensive materials so that the entire item is disposable once the fragrance has been completely dispensed. The housing unit may be provided with various conventional means for attachment to the body or clothing of the user; these means can include chains, hooks, pins, dips, and the like.
  • It will be further appreciated that in some applications the entire unit may be designed to be fairly unobtrusive during use. This might be advantageous, for example, in applications where the device is dispensing pheromones, masking agents, insect repellents, and the like. The unit may also be configured to fit in a user's shirt pocket, to accommodate a larger fluid reservoir, larger battery, etc., as might be desired for steady, long-term use by outdoorsmen or the military.
  • In the aforedescribed situations the device is configured so that it can be worn on the person. However, it will be appreciated that because the device is generally compact and self-contained, it may easily be deployed in other uses and locations. For example, it may be placed in the ventilation system of an automobile, the air outlet of an air conditioner, or other convenient location where the user desires to have a controlled release of fragrance at selected time intervals.
  • As noted earlier, perfumes, colognes, and other fragrant products are typically mixtures or solutions of numerous chemical compounds along with solvents and other additives. It will be understood that the inventive device may be used for dispensing any and all such mixtures, blends, solutions, or dispersions as are familiar to those skilled in the art of fragrance production and use. In the embodiment described in the foregoing examples, it will be understood that when the apparatus includes several fluid reservoirs, each of the individual fluids will, in turn, frequently be a mixture or solution in its own right but it may, in some cases, be a substantially pure component or concentrate.
  • The term aromatherapy describes a branch of holistic or “traditional” medicine wherein various healing attributes are associated with particular aromas. The practice of treating physical or mental problems by the inhalation of specific aromas has been carried out since ancient times and anecdotal evidence among practitioners in the art identifies dozens of fragrances purported to have some value in aromatherapy [see, for example V. A. Worwood, The Complete Book of Essential Oils and Aromatherapy, New World Library, 1991]. The materials typically used include essential oils or extracts of various plants, flowers, herbs, etc.
  • EXAMPLE
  • The inventive device may be used to dispense fragrances for aromatherapy treatment. Individual fragrances or combinations of fragrances may be selected by the user or prescribed by an aromatherapy practitioner, who may also recommend frequency or duration of treatment, etc. In this application, the inventive device offers the advantage that the aromatherapeutic agent is dispensed efficiently directly in the vicinity of the user, rather than dispersed into the air to fill a room, for example.
  • Some examples of materials that have been offered for aromatherapy include the following: angelica root, anise, Peru balsam, basil, bay, bay laurel, beeswax, bergamot, mint bergamot, bois-de-rose, boronia, cajeput, cardamom, carrot seed, cedarwood, chamomile, cinnamon, citronella, clary sage, clove bud, coriander, cypress, dill, elemi, eucalyptus, fennel, fir needle, frankincense, galbanum, geranium, rose geranium, ginger, grapefruit, helichrysum, hyssop, immortelle, jasmine, juniper berry, kanuka, lavender, lavendin, lemon, lemon grass, lime, linden blossom, mandarin, manuka, marjoram, may chang, myrrh, myrtle, neroli, niaouli, nutmeg, oakmoss, olibanum, bitter orange, sweet orange, oregano, palmarosa, parsley, patchouli, black pepper, peppermint, pettigrain, Scotch pine, ravensera, rose, rosemary, rosewood, sandalwood, spearmint, spikenard, spruce, tagetes, tangerine, tea tree, thyme, tobacco, tuberose, vanilla, vetiver, violet leaf, yarrow, and ylang-ylang. Many literature sources advise caution in using these materials because many essential oils, in concentrated form, can be toxic, irritating to the skin and mucous membranes, or allergenic. The present invention affords a particular advantage in the administration of such aromas because the method of dispensing the material effectively precludes direct contact of the fluid with the user's skin, eyes, or mucous membranes.
  • Aromatherapy products also frequently make use of solvents, such as water or alcohol, as well as “carrier oils” such as sweet almond, apricot kernel, avocado, borage, cocoa butter, evening primrose, grapeseed, hazelnut, jojoba, kukui, macadamia nut, olive, peanut, pecan, rose hip, sesame, shea butter, and sunflower.

Claims (20)

1. An apparatus for dispensing fragrances comprising:
a fluid reservoir containing a selected fragrance;
a solid-state microfluidic circuit to control the release of said fragrance from said reservoir;
a solid state switching device configured to actuate said microfluidic circuit according to a selected program; and,
a power supply configured to provide electric power to operate said switching device and said microfluidic circuit.
2. The apparatus of claim 1 wherein said selected program comprises a preset schedule of actuations at selected intervals of time.
3. The apparatus of claim 1 wherein at least one parameter of said selected program is adjustable by the user.
4. The apparatus of claim 1 wherein said solid state switching device comprises a device selected from the group consisting of: application specific integrated circuits and field-programmable gate arrays.
5. The apparatus of claim 1 wherein said microfluidic circuit comprises a device selected from the group consisting of: piston pumps, electrokinetic pumps, peristaltic pumps, dielectric pumps, valves, check valves, nozzles, heaters, and micromachined fluid channels.
6. The apparatus of claim 1 wherein said power supply comprises a device selected from the group consisting of: batteries and photovoltaic devices.
7. The apparatus of claim 1 wherein said fragrance comprises a substance selected from the group consisting of: essential oils, natural plant extracts, natural animal extracts, synthetic esters, pheromones, and insect repellents.
8. The apparatus of claim 1 wherein said fluid reservoir comprises a plurality of individual chambers, each containing a different selected fragrance, and said microfluidic circuit is adapted to selectably withdraw fluid from said individual chambers.
9. The apparatus of claim 8 wherein said microfluidic circuit is adapted to withdraw fluids from at least two of said individual chambers and blend said fluids in a selected ratio whereby a selected fragrance blend is dispensed.
10. The apparatus of claim 1 further comprising a decorative housing adapted to allow said apparatus to be worn by the user.
11. A method of dispensing fragrances comprising the steps of:
providing a fluid reservoir containing a selected fragrance;
providing a solid-state microfluidic circuit configured to dispense said fragrance from said reservoir at a selected rate;
providing a solid-state switching device configured to actuate said microfluidic circuit for a selected duration at selected times; and,
providing a power supply sufficient to operate said switching device and said microfluidic circuit, whereby said fragrance may be withdrawn from said reservoir at a selected rate for vaporization into the surrounding air.
12. The method of claim 11 wherein said solid state switching device comprises a device selected from the group consisting of: application specific integrated circuits and field-programmable gate arrays.
13. The method of claim 11 wherein said microfluidic circuit comprises a device selected from the group consisting of: piston pumps, electrokinetic pumps, peristaltic pumps, dielectric pumps, valves, check valves, nozzles, heaters, and micromachined fluid channels.
14. The method of claim 11 wherein said power supply comprises a device selected from the group consisting of: batteries and photovoltaic devices.
15. The method of claim 11 wherein said fragrance comprises a substance selected from the group consisting of: essential oils, natural plant extracts, natural animal extracts, synthetic esters, pheromones, and insect repellents
16. The method of claim 11 wherein said fluid reservoir containing said fragrance is pressurized to an internal pressure greater than atmospheric and said microfluidic device contains a valve for controllably releasing said pressurized fluid.
17. A method of dispensing fragrances comprising the steps of:
providing a fluid reservoir containing a selected fragrance, said fragrance having aromatherapeutic attributes;
providing a solid-state microfluidic circuit configured to dispense said fragrance from said reservoir at a selected rate;
providing a solid-state switching device configured to actuate said microfluidic circuit for a selected duration at selected times; and,
providing a power supply sufficient to operate said switching device and said microfluidic circuit, whereby said fragrance may be withdrawn from said reservoir at a selected rate for vaporization into the surrounding air.
18. The method of claim 17 wherein said aromatherapeutic fragrance comprises an essential oil selected from the group consisting of: angelica root, anise, Peru balsam, basil, bay, bay laurel, beeswax, bergamot, mint bergamot, bois-de-rose, boronia, cajeput, cardamom, carrot seed, cedarwood, chamomile, cinnamon, citronella, clary sage, clove bud, coriander, cypress, dill, elemi, eucalyptus, fennel, fir needle, frankincense, galbanum, geranium, rose geranium, ginger, grapefruit, helichrysum, hyssop, immortelle, jasmine, juniper berry, kanuka, lavender, lavendin, lemon, lemon grass, lime, linden blossom, mandarin, manuka, marjoram, may chang, myrrh, myrtle, neroli, niaouli, nutmeg, oakmoss, olibanum, bitter orange, sweet orange, oregano, palmarosa, parsley, patchouli, black pepper, peppermint, pettigrain, Scotch pine, ravensera, rose, rosemary, rosewood, sandalwood, spearmint, spikenard, spruce, tagetes, tangerine, tea tree, thyme, tobacco, tuberose, vanilla, vetiver, violet leaf, yarrow, and ylang-ylang.
19. The method of claim 17 wherein said aromatherapeutic fragrance further contains a carrier oil selected from the group consisting of: sweet almond, apricot kernel, avocado, borage, cocoa butter, evening primrose, grapeseed, hazelnut, jojoba, kukui, macadamia nut, olive, peanut, pecan, rose hip, sesame, shea butter, and sunflower.
20. The method of claim 17 wherein said aromatherapeutic fragrance further contains a solvent selected from the group consisting of: water, alcohols, and ketones.
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Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070199952A1 (en) * 2004-10-12 2007-08-30 Carpenter M S Compact spray device
US20080092282A1 (en) * 2006-10-13 2008-04-24 Florian Altmann Unit-dose dispenser
US20080277411A1 (en) * 2007-05-10 2008-11-13 Rene Maurice Beland Actuator cap for a spray device
US20090261178A1 (en) * 2006-12-18 2009-10-22 Yehuda Ivri Subminiature thermoelectric fragrance dispenser
US20100168529A1 (en) * 2008-12-30 2010-07-01 Searete Llc, A Limited Liability Corporation Of The State Of Delaware Methods and systems for presenting an inhalation experience
US20100286803A1 (en) * 2004-12-01 2010-11-11 Jenny Tillotson System and method for dispensing fluid in response to a sensed property
US7837065B2 (en) 2004-10-12 2010-11-23 S.C. Johnson & Son, Inc. Compact spray device
US20110095044A1 (en) * 2009-10-26 2011-04-28 Gene Sipinski Dispensers and Functional Operation and Timing Control Improvements for Dispensers
WO2012107472A1 (en) 2011-02-09 2012-08-16 Scope Fluidics Sp. Z O.O. System for dispensing volatile substances
US20120247613A1 (en) * 2011-03-28 2012-10-04 Fawzi Behbehani Vending Machine for Selected Blends of Perfumes
US20130015258A1 (en) * 2011-07-13 2013-01-17 Mark Boyles Aromatic Adhesive-Backed Tab and Method of Using Same
US8381951B2 (en) 2007-08-16 2013-02-26 S.C. Johnson & Son, Inc. Overcap for a spray device
US8387827B2 (en) 2008-03-24 2013-03-05 S.C. Johnson & Son, Inc. Volatile material dispenser
US8469244B2 (en) 2007-08-16 2013-06-25 S.C. Johnson & Son, Inc. Overcap and system for spraying a fluid
US8556122B2 (en) 2007-08-16 2013-10-15 S.C. Johnson & Son, Inc. Apparatus for control of a volatile material dispenser
US8747735B2 (en) 2012-04-27 2014-06-10 Gregg S. Homer Electronic scent generator
WO2014123817A1 (en) * 2013-02-06 2014-08-14 Massachusetts Institute Of Technology Sustained release delivery devices
US20150122261A1 (en) * 2012-06-06 2015-05-07 Smiths Medical International Limited Respiratory therapy apparatus
US9108782B2 (en) 2012-10-15 2015-08-18 S.C. Johnson & Son, Inc. Dispensing systems with improved sensing capabilities
WO2016098114A1 (en) * 2014-12-17 2016-06-23 Agan Aroma & Fine Chemicals Ltd. System and method for releasing flavor
US20180043048A1 (en) * 2016-07-27 2018-02-15 Rami Sidawi Fragrance dispenser having a disposable piezoelectric cartridge with a snap-in bottle containing aromatic liquid
US10034987B2 (en) 2016-10-06 2018-07-31 Spdi Holdings, Inc. Essential oils diffuser
WO2019025763A1 (en) * 2017-07-29 2019-02-07 Sensory Design & Technology Ltd Liquid dispensing system creating and maintaining a personalised bubble with a defined radius and concentration
US20190070329A1 (en) * 2016-11-02 2019-03-07 The Procter & Gamble Company Volatile composition dispenser having an air pump and a method of delivering a volatile composition to an evaporative surface using the same
US20190105615A1 (en) * 2016-07-26 2019-04-11 Prolitec Inc. Air treatment appliance
US10426862B2 (en) 2016-10-06 2019-10-01 Spdi Holdings, Inc. Diffusing apparatus and methods
JP2020176133A (en) * 2016-06-02 2020-10-29 ロレアル System for dispensing cosmetic product
US10919059B2 (en) 2016-10-06 2021-02-16 Spdi Holdings, Inc. Diffusing apparatus and methods
US11957816B2 (en) * 2018-11-05 2024-04-16 The Procter & Gamble Company Volatile composition dispenser having an air pump and a method of delivering a volatile composition to an evaporative surface using the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9715223B2 (en) 2013-07-10 2017-07-25 Scentair Technologies, Llc Bias setting in a scent delivery system
IL231686A (en) * 2014-03-24 2016-04-21 Shmuel Ur Automatic scent selection
WO2016205555A1 (en) * 2015-06-16 2016-12-22 Video Plus Print Company Multi-sensory presentation device
WO2018108585A1 (en) * 2016-12-16 2018-06-21 Noustique Perfumes, S.L. Fragrance cartridge and fragrance mixer
US20200077767A1 (en) * 2016-12-16 2020-03-12 Noustique Perfumes, S.L. Dispensing a fragrance blend
WO2019050803A1 (en) * 2017-09-07 2019-03-14 University Of North Texas Systems and methods for copper etch rate monitoring and control
WO2019083820A1 (en) * 2017-10-25 2019-05-02 Xinova, LLC Microdispensing wearable device
US20200268115A1 (en) * 2017-10-25 2020-08-27 Xinova, LLC Microdispensing jewelry
WO2022032107A1 (en) * 2020-08-06 2022-02-10 Strassburger Daniel J Wearable fragrance dispensing devices

Citations (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2927055A (en) * 1958-09-05 1960-03-01 Airkem Inc Air treating gel and method of preparing the same
US3987935A (en) * 1975-11-17 1976-10-26 The Raymond Lee Organization, Inc. Perfume dispenser
US4006841A (en) * 1974-07-24 1977-02-08 Girair Hagop Alticosalian Perfume dispenser
US4323193A (en) * 1979-11-07 1982-04-06 The Procter & Gamble Company Wick-type slow diffusion dispenser
US4549674A (en) * 1982-03-09 1985-10-29 Alticosalian Girair H Perfume dispenser
US4785642A (en) * 1987-01-13 1988-11-22 Eric Chiao Shih Decorative clip with perfume dispenser
US4891939A (en) * 1987-12-04 1990-01-09 Tecnomare S.P.A. System for the cryogenic processing and storage of combustion products of heat engines
US4964570A (en) * 1989-11-24 1990-10-23 William Haiduk Perfume dispenser
US5071704A (en) * 1990-06-13 1991-12-10 Fischel Ghodsian Fariba Device for controlled release of vapors and scents
US5377363A (en) * 1994-03-09 1995-01-03 Shieh; Snoopy Automatic lavatory detergent and perfume dispenser
US5586694A (en) * 1994-12-14 1996-12-24 Fragrance Systems International, Inc. Perfume applicator with replaceable cartridges
US5820792A (en) * 1997-02-24 1998-10-13 Lin; Hsi Huang Perfume dispenser
US6015094A (en) * 1997-05-09 2000-01-18 Por; Sze Pik Vehicle Perfume Dispenser
US6109717A (en) * 1997-05-13 2000-08-29 Sarnoff Corporation Multi-element fluid delivery apparatus and methods
US6145241A (en) * 1997-11-07 2000-11-14 Okuno; Yoshitoshi Electric insecticidal apparatus
US6267297B1 (en) * 1999-10-12 2001-07-31 Waterbury Companies, Inc. Programmable dispenser
US6290103B1 (en) * 1998-09-15 2001-09-18 Lir-Usa Manufacturing Co., Inc. Collapsible cap mechanism for shielding pump actuator and liquid material-dispensing container including the same
US6398381B1 (en) * 2000-07-18 2002-06-04 Wen Yung Tseng Wind-driven perfume dispenser capable of producing different light patterns
US6524790B1 (en) * 1997-06-09 2003-02-25 Caliper Technologies Corp. Apparatus and methods for correcting for variable velocity in microfluidic systems
US6540079B1 (en) * 1998-10-13 2003-04-01 Valois S.A. Product packaging under film-sealed shell
US6554203B2 (en) * 2000-08-30 2003-04-29 Ing. Erich Pfeiffer Gmbh Smart miniature fragrance dispensing device for multiple ambient scenting applications and environments
US6694534B2 (en) * 2002-03-04 2004-02-24 Earlyn W. Stone Toilet ventilation system
US6802460B2 (en) * 2002-03-05 2004-10-12 Microflow Engineering Sa Method and system for ambient air scenting and disinfecting based on flexible, autonomous liquid atomizer cartridges and an intelligent networking thereof
US6808683B2 (en) * 2001-09-25 2004-10-26 Cytonome, Inc. Droplet dispensing system
US6874999B2 (en) * 2002-08-15 2005-04-05 Motorola, Inc. Micropumps with passive check valves
US6881039B2 (en) * 2002-09-23 2005-04-19 Cooligy, Inc. Micro-fabricated electrokinetic pump
US6886916B1 (en) * 2003-06-18 2005-05-03 Sandia Corporation Piston-driven fluid-ejection apparatus
US20050127206A1 (en) * 2003-12-10 2005-06-16 Xerox Corporation Device and system for dispensing fluids into the atmosphere
US6949176B2 (en) * 2001-02-28 2005-09-27 Lightwave Microsystems Corporation Microfluidic control using dielectric pumping
US7152758B2 (en) * 2004-08-17 2006-12-26 Avago Technologies Wireless Ip (Singapore) Pte. Ltd. Scented material dispense system for a hand-held device

Patent Citations (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2927055A (en) * 1958-09-05 1960-03-01 Airkem Inc Air treating gel and method of preparing the same
US4006841A (en) * 1974-07-24 1977-02-08 Girair Hagop Alticosalian Perfume dispenser
US3987935A (en) * 1975-11-17 1976-10-26 The Raymond Lee Organization, Inc. Perfume dispenser
US4323193A (en) * 1979-11-07 1982-04-06 The Procter & Gamble Company Wick-type slow diffusion dispenser
US4549674A (en) * 1982-03-09 1985-10-29 Alticosalian Girair H Perfume dispenser
US4785642A (en) * 1987-01-13 1988-11-22 Eric Chiao Shih Decorative clip with perfume dispenser
US4891939A (en) * 1987-12-04 1990-01-09 Tecnomare S.P.A. System for the cryogenic processing and storage of combustion products of heat engines
US4964570A (en) * 1989-11-24 1990-10-23 William Haiduk Perfume dispenser
US5071704A (en) * 1990-06-13 1991-12-10 Fischel Ghodsian Fariba Device for controlled release of vapors and scents
US5377363A (en) * 1994-03-09 1995-01-03 Shieh; Snoopy Automatic lavatory detergent and perfume dispenser
US5586694A (en) * 1994-12-14 1996-12-24 Fragrance Systems International, Inc. Perfume applicator with replaceable cartridges
US5820792A (en) * 1997-02-24 1998-10-13 Lin; Hsi Huang Perfume dispenser
US6015094A (en) * 1997-05-09 2000-01-18 Por; Sze Pik Vehicle Perfume Dispenser
US6109717A (en) * 1997-05-13 2000-08-29 Sarnoff Corporation Multi-element fluid delivery apparatus and methods
US6703205B2 (en) * 1997-06-09 2004-03-09 Caliper Technologies Corp. Apparatus and methods for correcting for variable velocity in microfluidic systems
US6524790B1 (en) * 1997-06-09 2003-02-25 Caliper Technologies Corp. Apparatus and methods for correcting for variable velocity in microfluidic systems
US6613512B1 (en) * 1997-06-09 2003-09-02 Caliper Technologies Corp. Apparatus and method for correcting for variable velocity in microfluidic systems
US6145241A (en) * 1997-11-07 2000-11-14 Okuno; Yoshitoshi Electric insecticidal apparatus
US6290103B1 (en) * 1998-09-15 2001-09-18 Lir-Usa Manufacturing Co., Inc. Collapsible cap mechanism for shielding pump actuator and liquid material-dispensing container including the same
US6540079B1 (en) * 1998-10-13 2003-04-01 Valois S.A. Product packaging under film-sealed shell
US6267297B1 (en) * 1999-10-12 2001-07-31 Waterbury Companies, Inc. Programmable dispenser
US6398381B1 (en) * 2000-07-18 2002-06-04 Wen Yung Tseng Wind-driven perfume dispenser capable of producing different light patterns
US6554203B2 (en) * 2000-08-30 2003-04-29 Ing. Erich Pfeiffer Gmbh Smart miniature fragrance dispensing device for multiple ambient scenting applications and environments
US6949176B2 (en) * 2001-02-28 2005-09-27 Lightwave Microsystems Corporation Microfluidic control using dielectric pumping
US6808683B2 (en) * 2001-09-25 2004-10-26 Cytonome, Inc. Droplet dispensing system
US6694534B2 (en) * 2002-03-04 2004-02-24 Earlyn W. Stone Toilet ventilation system
US6802460B2 (en) * 2002-03-05 2004-10-12 Microflow Engineering Sa Method and system for ambient air scenting and disinfecting based on flexible, autonomous liquid atomizer cartridges and an intelligent networking thereof
US6874999B2 (en) * 2002-08-15 2005-04-05 Motorola, Inc. Micropumps with passive check valves
US6881039B2 (en) * 2002-09-23 2005-04-19 Cooligy, Inc. Micro-fabricated electrokinetic pump
US6886916B1 (en) * 2003-06-18 2005-05-03 Sandia Corporation Piston-driven fluid-ejection apparatus
US20050127206A1 (en) * 2003-12-10 2005-06-16 Xerox Corporation Device and system for dispensing fluids into the atmosphere
US7152758B2 (en) * 2004-08-17 2006-12-26 Avago Technologies Wireless Ip (Singapore) Pte. Ltd. Scented material dispense system for a hand-held device

Cited By (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8061562B2 (en) 2004-10-12 2011-11-22 S.C. Johnson & Son, Inc. Compact spray device
US9457951B2 (en) 2004-10-12 2016-10-04 S. C. Johnson & Son, Inc. Compact spray device
US10011419B2 (en) 2004-10-12 2018-07-03 S. C. Johnson & Son, Inc. Compact spray device
US20070199952A1 (en) * 2004-10-12 2007-08-30 Carpenter M S Compact spray device
US8887954B2 (en) 2004-10-12 2014-11-18 S.C. Johnson & Son, Inc. Compact spray device
US8678233B2 (en) 2004-10-12 2014-03-25 S.C. Johnson & Son, Inc. Compact spray device
US8342363B2 (en) 2004-10-12 2013-01-01 S.C. Johnson & Son, Inc. Compact spray device
US7837065B2 (en) 2004-10-12 2010-11-23 S.C. Johnson & Son, Inc. Compact spray device
US8091734B2 (en) 2004-10-12 2012-01-10 S.C. Johnson & Son, Inc. Compact spray device
US7954667B2 (en) 2004-10-12 2011-06-07 S.C. Johnson & Son, Inc. Compact spray device
US11027303B2 (en) 2004-12-01 2021-06-08 Sensory Design & Technology Ltd. System and method for dispensing fluid in response to a sensed property
US20100286803A1 (en) * 2004-12-01 2010-11-11 Jenny Tillotson System and method for dispensing fluid in response to a sensed property
US9675987B2 (en) 2004-12-01 2017-06-13 Jenny Tillotson System and method for dispensing fluid in response to a sensed property
US20080092282A1 (en) * 2006-10-13 2008-04-24 Florian Altmann Unit-dose dispenser
US20090261178A1 (en) * 2006-12-18 2009-10-22 Yehuda Ivri Subminiature thermoelectric fragrance dispenser
US7673820B2 (en) 2006-12-18 2010-03-09 Yehuda Ivri Subminiature thermoelectric fragrance dispenser
US8746504B2 (en) 2007-05-10 2014-06-10 S.C. Johnson & Son, Inc. Actuator cap for a spray device
US20080277411A1 (en) * 2007-05-10 2008-11-13 Rene Maurice Beland Actuator cap for a spray device
US8590743B2 (en) 2007-05-10 2013-11-26 S.C. Johnson & Son, Inc. Actuator cap for a spray device
US9061821B2 (en) 2007-08-16 2015-06-23 S.C. Johnson & Son, Inc. Apparatus for control of a volatile material dispenser
US8381951B2 (en) 2007-08-16 2013-02-26 S.C. Johnson & Son, Inc. Overcap for a spray device
US8469244B2 (en) 2007-08-16 2013-06-25 S.C. Johnson & Son, Inc. Overcap and system for spraying a fluid
US8556122B2 (en) 2007-08-16 2013-10-15 S.C. Johnson & Son, Inc. Apparatus for control of a volatile material dispenser
US8387827B2 (en) 2008-03-24 2013-03-05 S.C. Johnson & Son, Inc. Volatile material dispenser
US9089622B2 (en) 2008-03-24 2015-07-28 S.C. Johnson & Son, Inc. Volatile material dispenser
US20100168529A1 (en) * 2008-12-30 2010-07-01 Searete Llc, A Limited Liability Corporation Of The State Of Delaware Methods and systems for presenting an inhalation experience
US8668115B2 (en) 2009-10-26 2014-03-11 S.C. Johnson & Son, Inc. Functional operation and timing control improvements for dispensers
US8459499B2 (en) 2009-10-26 2013-06-11 S.C. Johnson & Son, Inc. Dispensers and functional operation and timing control improvements for dispensers
US20110095044A1 (en) * 2009-10-26 2011-04-28 Gene Sipinski Dispensers and Functional Operation and Timing Control Improvements for Dispensers
WO2012107472A1 (en) 2011-02-09 2012-08-16 Scope Fluidics Sp. Z O.O. System for dispensing volatile substances
US8490873B2 (en) * 2011-03-28 2013-07-23 Fawzi Behbehani Vending machine for selected blends of perfumes
US20120247613A1 (en) * 2011-03-28 2012-10-04 Fawzi Behbehani Vending Machine for Selected Blends of Perfumes
US20130015258A1 (en) * 2011-07-13 2013-01-17 Mark Boyles Aromatic Adhesive-Backed Tab and Method of Using Same
US10583215B2 (en) 2011-07-13 2020-03-10 Beekley Corporation Aromatic adhesive-backed tab and method of using same
US9855360B2 (en) * 2011-07-13 2018-01-02 Beekley Corporation Aromatic adhesive-backed tab and method of using same
US8747735B2 (en) 2012-04-27 2014-06-10 Gregg S. Homer Electronic scent generator
US20150122261A1 (en) * 2012-06-06 2015-05-07 Smiths Medical International Limited Respiratory therapy apparatus
US9108782B2 (en) 2012-10-15 2015-08-18 S.C. Johnson & Son, Inc. Dispensing systems with improved sensing capabilities
WO2014123817A1 (en) * 2013-02-06 2014-08-14 Massachusetts Institute Of Technology Sustained release delivery devices
WO2016098115A1 (en) * 2014-12-17 2016-06-23 Agan Aroma & Fine Chemicals Ltd. System and method for releasing edible material
WO2016098114A1 (en) * 2014-12-17 2016-06-23 Agan Aroma & Fine Chemicals Ltd. System and method for releasing flavor
CN106999972A (en) * 2014-12-17 2017-08-01 阿甘芳香和精细化工有限公司 System and method for discharging fragrance
US10869944B2 (en) 2014-12-17 2020-12-22 Agan Aroma & Fine Chemicals Ltd. System and method for releasing edible material
US10512706B2 (en) 2014-12-17 2019-12-24 Agan Aroma & Fine Chemicals Ltd. System and method for releasing flavor
JP2020176133A (en) * 2016-06-02 2020-10-29 ロレアル System for dispensing cosmetic product
US11052356B2 (en) * 2016-07-26 2021-07-06 Prolitec Inc. Air treatment appliance
US20190105615A1 (en) * 2016-07-26 2019-04-11 Prolitec Inc. Air treatment appliance
US20180043048A1 (en) * 2016-07-27 2018-02-15 Rami Sidawi Fragrance dispenser having a disposable piezoelectric cartridge with a snap-in bottle containing aromatic liquid
US10675373B2 (en) * 2016-07-27 2020-06-09 Newmarket Concepts, Llc Fragrance dispenser having a disposable piezoelectric cartridge with a snap-in bottle containing aromatic liquid
US10918812B2 (en) 2016-10-06 2021-02-16 Spdi Holdings, Inc. Essential oils diffuser
US10426862B2 (en) 2016-10-06 2019-10-01 Spdi Holdings, Inc. Diffusing apparatus and methods
US10919059B2 (en) 2016-10-06 2021-02-16 Spdi Holdings, Inc. Diffusing apparatus and methods
US10034987B2 (en) 2016-10-06 2018-07-31 Spdi Holdings, Inc. Essential oils diffuser
US20190070329A1 (en) * 2016-11-02 2019-03-07 The Procter & Gamble Company Volatile composition dispenser having an air pump and a method of delivering a volatile composition to an evaporative surface using the same
US20200211703A1 (en) * 2017-07-29 2020-07-02 Sensory Design & Technology Ltd Liquid dispensing system creating and maintaining a personalized bubble with a defined radius and concentration
WO2019025763A1 (en) * 2017-07-29 2019-02-07 Sensory Design & Technology Ltd Liquid dispensing system creating and maintaining a personalised bubble with a defined radius and concentration
US11957816B2 (en) * 2018-11-05 2024-04-16 The Procter & Gamble Company Volatile composition dispenser having an air pump and a method of delivering a volatile composition to an evaporative surface using the same

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