US20070137815A1 - Smooth low density paperboard - Google Patents
Smooth low density paperboard Download PDFInfo
- Publication number
- US20070137815A1 US20070137815A1 US11/313,544 US31354405A US2007137815A1 US 20070137815 A1 US20070137815 A1 US 20070137815A1 US 31354405 A US31354405 A US 31354405A US 2007137815 A1 US2007137815 A1 US 2007137815A1
- Authority
- US
- United States
- Prior art keywords
- paperboard product
- paperboard
- grams per
- fibers
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000011087 paperboard Substances 0.000 title claims abstract description 93
- 239000000835 fiber Substances 0.000 claims abstract description 64
- 238000005259 measurement Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 239000003431 cross linking reagent Substances 0.000 description 17
- 235000013877 carbamide Nutrition 0.000 description 12
- 238000003490 calendering Methods 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- -1 methylolated ureas Chemical class 0.000 description 9
- 229920001131 Pulp (paper) Polymers 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000000123 paper Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 239000011121 hardwood Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000003672 ureas Chemical class 0.000 description 3
- LGJMYGMNWHYGCB-UHFFFAOYSA-N 4,5-dihydroxy-1,3-dimethylimidazolidin-2-one Chemical compound CN1C(O)C(O)N(C)C1=O LGJMYGMNWHYGCB-UHFFFAOYSA-N 0.000 description 2
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- CEGRHPCDLKAHJD-UHFFFAOYSA-N 1,1,1-propanetricarboxylic acid Chemical compound CCC(C(O)=O)(C(O)=O)C(O)=O CEGRHPCDLKAHJD-UHFFFAOYSA-N 0.000 description 1
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 1
- YORGLSZZMFADAJ-UHFFFAOYSA-N 1,3-dihydroxy-1,3-dimethylurea Chemical compound CN(O)C(=O)N(C)O YORGLSZZMFADAJ-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZMGMDXCADSRNCX-UHFFFAOYSA-N 5,6-dihydroxy-1,3-diazepan-2-one Chemical class OC1CNC(=O)NCC1O ZMGMDXCADSRNCX-UHFFFAOYSA-N 0.000 description 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical group FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 235000005018 Pinus echinata Nutrition 0.000 description 1
- 241001236219 Pinus echinata Species 0.000 description 1
- 235000017339 Pinus palustris Nutrition 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- MIGNWTQKRPNYLP-UHFFFAOYSA-N but-2-ene-2,3-diol urea Chemical compound NC(=O)N.OC(=C(C)O)C MIGNWTQKRPNYLP-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000021268 hot food Nutrition 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/02—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
- D21F11/04—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type paper or board consisting on two or more layers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
Abstract
A paperboard product has at least two or three plies. One of the plies has at least 25% by weight bulky cellulosic fibers. Another of the plies is an outer ply and has an outer surface having a Parker PrintSurf measurement of between 3 and 6μ when measured at 10 kg/cm2 using a soft backing surface. The paperboard product has a density no greater than 0.5 grams per cubic centimeter. An embodiment has a caliper in the range of 0.4 and 1.2 mm. An embodiment has a basis weight in the range of 200 to 500 grams per square meter. A method for making the paperboard product by passing the web through a soft nip calender and an extended nip calender which can be a shoe calender under conditions which provide the surface and density properties.
Description
- This invention relates generally to a low density paperboard containing bulky fibers and having a smooth surface. The invention also relates to calendering the paperboard to achieve these results.
- Hot foods, particularly hot liquids, are commonly served and consumed in disposable containers. These containers are made from a variety of materials including paperboard and foamed polymeric sheet material. One of the least expensive sources of paperboard material is cellulose fibers. Cellulose fibers are employed to produce excellent paperboards for the production of hot cups, paper plates, and other food and beverage containers. Conventional paperboard produced from cellulosic fibers, however, is relatively dense, and therefore, transmits heat more readily than, for example, foamed polymeric sheet material. Thus, hot liquids are typically served in double cups or in cups containing multiple plies of conventional paperboard.
- Low density insulating paperboard contains fibers which have the purpose of reducing the temperature drop across the paperboard. The paperboard would be made into a container which maintains the heat of the contained product and has an outer surface which is at a temperature that can be handled without discomfort. The materials within the insulating paperboard may by their nature be lumpy and not smooth. This can provide a surface that is not smooth and may be difficult to use for some types of printing.
- It is desirable to have a low density paperboard that has a smooth surface because the containers are used by retail outlets that desire to have a business name and logo on the container. The outlets may also wish to have a statement about the temperature of the contained product. A smooth surface is more useful for printing.
- A concern is how to maintain a low density board while providing a smooth surface. Will the pressures required to obtain a smooth surface increase the density unacceptably?
- An embodiment of this invention is a paperboard that has a low density and a surface that is smooth. Another embodiment of this invention is a process for manufacturing a paperboard having a low density and a surface that is smooth.
- Low density insulating paperboard may be in two or more plies. At least one of the plies contains both regular chemical bleached, semi-bleached or unbleached pulp fibers and bulky fibers. Bulky fibers give the ply insulative qualities because they provide bulk to the ply and create a lower density ply. The purpose of these bulky fibers is to provide a greater temperature drop across the thickness of the paperboard than would be provided if bulky fibers were not used. Another of the plies is a surface ply which does not contain bulky fibers and has a smooth outer surface.
- Bulky fibers can be mechanically produced or can be produced by crosslinking the cellulosic fibers. The bulky fibers create a rough surface on the paperboard. It is necessary to smooth the surface of the paperboard while maintaining the low density of the paperboard. In an embodiment of the invention at least one surface of the paperboard is smooth. In an embodiment of the invention at least one surface of the paperboard has a Parker PrintSurf measurement of between 3 and 6μ at 10S where 10 indicates a clamp force of 10 kilograms and S indicates the use of a soft backing to the tested paperboard.
- Paperboard of the present invention may have a broad set of characteristics. In one embodiment its basis weight can range from 200 grams per square meter to 500 grams per square meter. In another embodiment its basis weight can range from 250 grams per square meter to 400 grams per square meter. In another embodiment the basis weight of the paperboard is equal to or greater than 250 grams per square meter. To achieve the insulating characteristics of the present invention, the paperboard may have a density of less than 0.5 g/cc. In another embodiment the density may be from 0.3 g/cc to 0.45 g/cc. In another embodiment the density may be from 0.35 g/cc to 0.40 g/cc. In an embodiment of the present invention the caliper of the paperboard is in the range of 0.4 to 1.2 mm after calendering.
-
FIG. 1 is a schematic cross-sectional view of a two-ply paperboard. -
FIG. 2 is a schematic cross-sectional view of a three-ply paperboard - The paperboard of the present invention has at least two plies.
FIG. 1 illustrates a two-ply construction in which paperboard 10 hasplies FIG. 2 illustrates a three-ply construction in which thepaperboard 20 has plies 22, 24 and 26. While the paperboard of the present invention may employ synthetic fibers, it would usually comprise all or substantially all cellulosic fibers. - The
plies - The
plies - Chemically crosslinked cellulosic fibers are suitable for use as the bulky fibers in paperboard. Any one of a number of crosslinking agents and crosslinking catalysts, if necessary, can be used to provide the crosslinked fibers to be included in the layer. The following is a representative list of useful crosslinking agents and catalysts.
- Suitable urea-based crosslinking agents include substituted ureas, such as methylolated ureas, methylolated cyclic ureas, methylolated lower alkyl cyclic ureas, methylolated dihydroxy cyclic ureas, dihydroxy cyclic ureas, and lower alkyl substituted cyclic ureas. Specific urea-based crosslinking agents include dimethyldihydroxy urea (DMDHU, 1,3-dimethyl-4,5-dihydroxy-2-imidazolidinone), dimethyloldihydroxyethylene urea (DMDHEU, 1,3-dihydroxymethyl-4,5-dihydroxy-2-imidazolidinone), dimethylol urea (DMU, bis[N-hydroxymethyl]urea), dihydroxyethylene urea (DHEU, 4,5-dihydroxy-2-imidazolidinone), dimethylolethylene urea (DMEU, 1,3-dihydroxymethyl-2-imidazolidinone), and dimethyldihydroxyethylene urea (DMeDHEU or DDI, 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone).
- Suitable crosslinking agents also include dialdehydes such as C2-C8 dialdehydes (e.g., glyoxal), C2-C8 dialdehyde acid analogs having at least one aldehyde group, and oligomers of these aldehyde and dialdehyde acid analogs. Other suitable crosslinking agents include aldehyde and urea-based formaldehyde addition products, glyoxal adducts of ureas and glyoxal/cyclic urea adducts.
- Other suitable crosslinking agents include carboxylic acid crosslinking agents such as polycarboxylic acids. Polycarboxylic acid crosslinking agents include citric acid, propane tricarboxylic acid, and butane tetracarboxylic acid) and catalysts. C2-C9 polycarboxylic acids that contain at least three carboxyl groups (e.g., citric acid and oxydisuccinic acid) are also suitable as crosslinking agents.
- Polymeric polycarboxylic acids are also suitable crosslinking agents. Polyacrylic acid and related copolymers may be used as crosslinking agents. Polymaleic acid may be used as a crosslinking agent.
- Specific suitable polycarboxylic acid crosslinking agents include citric acid, tartaric acid, malic acid, succinic acid, glutaric acid, citraconic acid, itaconic acid, tartrate monosuccinic acid, maleic acid, polyacrylic acid, polymethacrylic acid, polymaleic acid, polymethylvinylether-co-maleate copolymer, polymethylvinylether-co-itaconate copolymer, copolymers of acrylic acid, and copolymers of maleic acid.
- Suitable crosslinking catalysts can include acidic salts, such as ammonium chloride, ammonium sulfate, aluminum chloride, magnesium chloride, magnesium nitrate, and alkali metal salts of phosphorous-containing acids. In one embodiment, the crosslinking catalyst is sodium hypophosphite.
- The crosslinking agent is applied to the cellulosic fibers as they are being produced in an amount sufficient to affect intrafiber crosslinking. The amount applied to the cellulosic fibers may be from about 1% to about 25% by weight based on the total weight of fibers. In one embodiment, crosslinking agent in an amount from about 4% to about 6% by weight based on the total weight of fibers. Mixtures or blends of crosslinking agents and catalysts can also be used.
- The insulative fibers may also be mechanically pulped fibers, thermomechanical pulped fibers, chemithermomechanically pulped fibers or combinations of these.
- Insulating fibers, for the most part, are not smooth. They often are curled and twisted. They have a tendency to provide an uneven surface to the low density insulative paperboard.
- In addition to fibrous materials, the paperboard of the invention may optionally include a binding agent. Suitable binding agents are soluble in, dispersible in, or form a suspension in water. Suitable binding agents include those agents commonly used in the paper industry to impart wet and dry tensile and tearing strength to such products. Suitable wet strength agents include cationic modified starch having nitrogen-containing groups (e.g.,. amino groups), such as those available from National Starch and Chemical Corp., Bridgewater, N.J.; latex; wet strength resins, such as polyamide-epichlorohydrin resin (e.g., KYMENE 557LX, Hercules, Inc., Wilmington, Del.), and polyacrylamide resin (see, e.g., U.S. Pat. No. 3,556,932 and also the commercially available polyacrylamide marketed by American Cyanamid Co., Stanford, Conn., under the trade name PAREZ 631 NC); urea formaldehyde and melamine formaldehyde resins; and polyethylenimine resins. A general discussion on wet strength resins utilized in the paper field, and generally applicable in the present invention, can be found in TAPPI monograph series No. 29, “Wet Strength in Paper and Paperboard”, Technical Association of the Pulp and Paper Industry (New York, 1965).
- Other suitable binding agents include starch, modified starch, polyvinyl alcohol, polyvinyl acetate, polyethylene/acrylic acid copolymer, acrylic acid polymers, polyacrylate, polyacrylamide, polyamine, guar gum, oxidized polyethylene, polyvinyl chloride, polyvinyl chloride/acrylic acid copolymers, acrylonitrile/butadiene/styrene copolymers, and polyacrylonitrile. Many of these will be formed into latex polymers for dispersion or suspension in water.
- The insulative fibers may be blended with other cellulosic fibers which have lesser insulative properties. Although available from other sources, these other fibers are derived primarily from wood pulp. Suitable wood pulp fibers for use with the invention can be obtained from well-known chemical processes such as the kraft and sulfite processes, with or without subsequent bleaching. The preferred pulp fiber is produced by chemical methods. Recycled or secondary wood pulp fibers, and bleached and unbleached wood pulp fibers can be used. Softwoods and hardwoods can be used. Details of the selection of wood pulp fibers are well known to those skilled in the art. These fibers are commercially available from a number of companies, including Weyerhaeuser Company, the assignee of the present invention. For example, suitable cellulose fibers produced from southern pine that are usable with the present invention are available from Weyerhaeuser Company under the designations CF416, NF405, PL416, FR516, and NB416. These are the same fibers that would be used in
plies - Paperboard of the present invention may have a broad set of characteristics. In one embodiment its basis weight can range from 200 grams per square meter to 500 grams per square meter. In another embodiment its basis weight can range from 250 grams per square meter to 400 grams per square meter. In another embodiment the basis weight of the paperboard is equal to or greater than 250 grams per square meter. To achieve the insulating characteristics of the present invention, the paperboard may have a density of less than 0.5 g/cc. In another embodiment the density may be from 0.3 g/cc to 0.45 g/cc. In another embodiment the density may be from 0.35 g/cc to 0.40 g/cc.
- In a two-ply structure, for example, the first ply may contain 100% non-bulky fibers by weight while the second ply may in one embodiment contain from 25% to 100% bulky fibers by weight and in another embodiment from 30% to 70% bulky fibers by weight. In a three-ply layer, for example, the bottom and top plies may comprise 100% of non-bulky fibers by weight while the middle ply contains in one embodiment from about 25% to about 100% bulky fiber by weight and in another embodiment from about 30% to about 70% bulky fibers by weight.
- In each of these embodiments it is desired to have a surface which is smooth and printable. The surface would have a Parker PrintSurf (TAPPI Test Method T 555 om-04) of between 3 and 6μ at a clamping pressure of 10 kg/cm2 and using a soft backing sheet.
- It is understood that TAPPI test method T-555 is a recognized method of measuring surface smoothness. It is also understood that Collaborative Testing Services, Inc., 21331 Gentry Drive, Sterling, Va. 20166 has over the years checked variations in the readings among a population of Parker PrintSurf test machines using a clamping pressure of 10 kg/cm and a standard test sample and have found variations of as much as ÷1μ from a mean measurement. Therefore the measurement of between 3 and 6μ as used here and in the claims is a mean measurement and the actual measurement would be between 3 and 6μ±1μ.
- The paperboard of the present invention can be formed using conventional papermaking machines including, for example, Rotoformer, Fourdrinier, inclined wire Delta former, and twin-wire forming machines.
- A multi-ply paperboard may be made by using multiple headboxes arranged sequentially in a wet-forming process, or by a baffled headbox having the capacity of receiving and then laying multiple pulp furnishes. In a multi-ply construction the printing surface ply may be of other fibers and the non printing ply of a two ply construction or a middle ply of a three or more ply construction may be of insulative fibers or a blend of insulative fibers and other fibers.
- Multilayer liquid packaging board basestock can be formed on a papermachine capable of producing multilayer product. The papermachine can be a conventional Fourdrinier machine fitted with multiple head boxes. Each of the plies would be placed on the Fourdrinier machine by one of the headboxes to form a multiply web. Vacuum would be applied to remove water from the web. The web would then be pressed in a conventional press section to remove additional water.
- The paperboard web would then be dried. The dried web may then optionally pass through a size press of the puddle or metering type, or a blade coater, where additional chemicals may be applied to the web.
- Materials that can be added at the size press are starch, polyvinyl alcohol, pigments such as calcium carbonate or clay, or lubricants that are compatible with the starch and other binders. The web then passes through another dryer section.
- When bulky fibers are used in paperboard in accordance with the present invention, it has been found that the paperboard exiting the papermaking machine can be compressed to varying degrees. In one embodiment of the present invention the caliper of the paperboard is in the range of 0.4 to 1.2 mm after calendering.
- Following the size press treatment and drying, the paperboard is passed through a calender station. In the calender station the paperboard is calendered first with a soft nip calender and then with an extended nip or shoe calender.
- In soft nip calendering the web is pressed against a hot surface in a nip by a roll that has a resilient cover. The resilient cover gives the paper a longer dwell time in the nip compared to hard steel nips and also allows the smoothness and gloss development to occur at relatively uniform density across the width of the paper. In the soft nip calender the paperboard will be exposed to a heated surface having a temperature of 120° C. to 160° C. and be under a linear load of 40 to 150 N/mm.
- Extended nip calendering uses an endless band/belt over a backing roll to provide support for the paper web that is pressed against a heated cylinder. A variation to this concept, shoe calendering, uses a shoe instead of a roll as a backing for the paperboard. The backing shoe provides longer nip widths and hence an increased dwell time. In either configuration the nip would have a width of 6 to 12 cm for best results. In the calender the paperboard will be exposed to a heated surface having a temperature of 180° C. to 250° C. and be under a linear load of 100 to 300 N/mm.
- In the following examples, the paperboard was formed at a forming pilot facility, and calendered at a calendering pilot facility. The paperboard was three-ply having bulky fiber in the center ply. The paperboard had 20% of its fiber in each of the outer plies and 60% of its fiber in the center ply. The bulky fiber was 50% of the weight of the center ply. The bulky fiber was chemically intrafiber crosslinked cellulose fiber which used bleached chemical cellulosic wood pulp as its starting material. The fiber in the outer plies and the remainder of the fiber in the center ply was bleached chemical cellulosic wood pulp.
Top Basis Calendered Softnip Softnip Shoe Shoe PPS weight Caliper Temp Load Temp Load 10S Ex. g/m2 mm ° C. N/mm ° C. N/mm μ 1 392 1.12 140 60 210 150 5.43 2 392 1.12 140 60 210 250 4.24 3 392 1.09 140 120 210 150 5.22 4 392 1.09 140 120 210 250 4.06 - The foregoing invention has been described in conjunction with a preferred diment and various alterations and variations thereof. One of ordinary skill will be to substitute equivalents in the disclosed invention without departing from the broad pts imparted herein. It is therefore intended that the present invention be limited by the definition contained in the appended claims
Claims (18)
1. A paperboard product comprising at least two plies
said paperboard product having a density no greater that 0.5 grams per cubic centimeter,
one of said plies comprising a least 25% by weight bulky cellulosic fibers,
another of said plies being an outer ply and having an outer surface having a Parker PrintSurf measurement of between 3 and 6μ when measured at 10 kg/cm2 using a soft backing surface.
2. The paperboard product of claim 1 in which said paperboard product has a caliper in the range of 0.4 and 1.2 mm.
3. The paperboard product of claim 1 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
4. The paperboard product of claim 1 in which the density of said paperboard product is between 0.3 and 0.45 grams per cubic centimeter.
5. The paperboard product of claim 4 in which said paperboard product has a caliper in the range of 0.4 and 1.2 mm.
6. The paperboard product of claim 4 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
7. The paperboard product of claim 1 in which the density of said paperboard product is between 0.35 and 0.4 grams per cubic centimeter.
8. The paperboard product of claim 7 in which said paperboard product has a caliper in the range of 0.4 and 1.2 mm.
9. The paperboard product of claim 7 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
10. The paperboard product of claim 1 further comprising at least three plies, and said one of said plies comprises a center ply.
11. The paperboard product of claim 10 in which said paperboard product has a caliper of 0.4 and 1.2 mm.
12. The paperboard product of claim 10 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
13. The paperboard product of claim 10 in which the density of said paperboard product is between 0.3 and 0.45 grams per cubic centimeter.
14. The paperboard product of claim 13 in which said paperboard product has a caliper in the range of 0.4 and 1.2 mm.
15. The paperboard product of claim 13 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
16. The paperboard product of claim 10 in which the density of said paperboard product is between 0.35 and 0.4 grams per cubic centimeter.
17. The paperboard of claim 16 in which said paperboard product has a caliper in the range of 0.4 and 1.2 mm.
18. The paperboard product of claim 16 in which said paperboard product has a basis weight in the range of 200 to 500 grams per square meter.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/313,544 US20070137815A1 (en) | 2005-12-20 | 2005-12-20 | Smooth low density paperboard |
SE0602471A SE0602471L (en) | 2005-12-20 | 2006-11-21 | Process for the production of low density board with smooth surface |
JP2006333949A JP2007169870A (en) | 2005-12-20 | 2006-12-12 | Method for making smooth low density paperboard |
FI20061134A FI20061134A (en) | 2005-12-20 | 2006-12-19 | Process for producing a uniform, low density carton |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/313,544 US20070137815A1 (en) | 2005-12-20 | 2005-12-20 | Smooth low density paperboard |
Publications (1)
Publication Number | Publication Date |
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US20070137815A1 true US20070137815A1 (en) | 2007-06-21 |
Family
ID=37623758
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/313,544 Abandoned US20070137815A1 (en) | 2005-12-20 | 2005-12-20 | Smooth low density paperboard |
Country Status (4)
Country | Link |
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US (1) | US20070137815A1 (en) |
JP (1) | JP2007169870A (en) |
FI (1) | FI20061134A (en) |
SE (1) | SE0602471L (en) |
Cited By (5)
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US20070151687A1 (en) * | 2005-12-30 | 2007-07-05 | Halabisky Donald D | Insulating paperboard |
US20070215301A1 (en) * | 2006-03-17 | 2007-09-20 | Weyerhaeuser Co. | Method for making a low density multi-ply paperboard with high internal bond strength |
WO2015036932A1 (en) | 2013-09-13 | 2015-03-19 | Stora Enso Oyj | Multiply paperboard |
WO2015036930A1 (en) * | 2013-09-13 | 2015-03-19 | Stora Enso Oyj | Multiply Paperboard |
CN107849823A (en) * | 2015-05-22 | 2018-03-27 | 因文特亚有限公司 | For the couch board for producing the method for couch board and obtaining |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070151687A1 (en) * | 2005-12-30 | 2007-07-05 | Halabisky Donald D | Insulating paperboard |
US20070215301A1 (en) * | 2006-03-17 | 2007-09-20 | Weyerhaeuser Co. | Method for making a low density multi-ply paperboard with high internal bond strength |
WO2015036932A1 (en) | 2013-09-13 | 2015-03-19 | Stora Enso Oyj | Multiply paperboard |
WO2015036930A1 (en) * | 2013-09-13 | 2015-03-19 | Stora Enso Oyj | Multiply Paperboard |
CN104452477A (en) * | 2013-09-13 | 2015-03-25 | 斯托拉恩索公司 | Multiply paperboard |
CN104452417A (en) * | 2013-09-13 | 2015-03-25 | 斯托拉恩索公司 | Multiply Paperboard |
CN112575618A (en) * | 2013-09-13 | 2021-03-30 | 斯托拉恩索公司 | Multilayer paperboard |
CN107849823A (en) * | 2015-05-22 | 2018-03-27 | 因文特亚有限公司 | For the couch board for producing the method for couch board and obtaining |
EP3298196A4 (en) * | 2015-05-22 | 2018-12-19 | Innventia AB | Process for the production of multi-layer paperboard and multi-layer paperboard obtained |
Also Published As
Publication number | Publication date |
---|---|
SE0602471L (en) | 2007-06-21 |
FI20061134A (en) | 2007-06-21 |
JP2007169870A (en) | 2007-07-05 |
FI20061134A0 (en) | 2006-12-19 |
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Owner name: WEYERHAEUSER COMPANY, WASHINGTON Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SHEARER, DWAYNE M.;REEL/FRAME:017508/0861 Effective date: 20051219 |
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STCB | Information on status: application discontinuation |
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