US20070004304A1 - Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method - Google Patents

Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method Download PDF

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Publication number
US20070004304A1
US20070004304A1 US11/452,320 US45232006A US2007004304A1 US 20070004304 A1 US20070004304 A1 US 20070004304A1 US 45232006 A US45232006 A US 45232006A US 2007004304 A1 US2007004304 A1 US 2007004304A1
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United States
Prior art keywords
fibers
nonwoven
microfibers
strengthened
spun
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/452,320
Inventor
Luder Gerking
Gerold Fleissner
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Individual
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Individual
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7687382&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20070004304(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Priority to US11/452,320 priority Critical patent/US20070004304A1/en
Publication of US20070004304A1 publication Critical patent/US20070004304A1/en
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • D01D4/02Spinnerettes
    • D01D4/025Melt-blowing or solution-blowing dies
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/098Melt spinning methods with simultaneous stretching
    • D01D5/0985Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H18/00Needling machines
    • D04H18/04Needling machines with water jets
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/016Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the fineness
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • D04H5/03Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling by fluid jet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/614Strand or fiber material specified as having microdimensions [i.e., microfiber]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/614Strand or fiber material specified as having microdimensions [i.e., microfiber]
    • Y10T442/62Including another chemically different microfiber in a separate layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/614Strand or fiber material specified as having microdimensions [i.e., microfiber]
    • Y10T442/621Including other strand or fiber material in a different layer not specified as having microdimensions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/614Strand or fiber material specified as having microdimensions [i.e., microfiber]
    • Y10T442/626Microfiber is synthetic polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/696Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]

Definitions

  • DE-A-199 29 709 teaches a fiber production method in which, from a polymer melt of only one certain polymer, filaments are spun from a plurality of spinning apertures and the spun filaments are drawn by substantially cold gas streams accelerated to high velocity by an accelerating nozzle such as a Laval nozzle and, due to further production conditions, each fiber receives before solidification an internal hydrostatic pressure that is higher than the ambient gas pressure so that each fiber cracks in the longitudinal direction and splits up into a plurality of fine endless filaments. These endless microfibers can then be progressively laid to form a nonwoven of arbitrary width.
  • the filaments are very fine, having an average diameter of roughly 2 ⁇ m and being essentially endless even at this diameter. Because they are not stretched by a hot air stream as in the melt-blowing method, they undergo no thermal damage and have high strength.
  • the filaments can be produced from any polymer but also from solutions according to the Lyocell method.
  • split fibers are also microfibers. They arise from filaments spun from a plurality of polymers and subsequently split, for example by water jets. This microfiber production method is, however, more expensive.
  • the idea of the invention is to effect this by hydrodynamic needling. This is especially effective here because these very thin endless fibers so produced can easily be displaced by water-needling and, despite their endlessness, entangled with nearby fibers.
  • the result is an abrasion-resistant product; this is still the case when the nonwoven fabric has become wet.
  • the product is not only abrasion-resistant but also displays no pilling effect, because entangled endless fibers are involved and these, in the case of normal endless fibers, have a longitudinal strength that makes them difficult to displace with water.

Abstract

A strengthened nonwoven is made at least in part of spun microfibers that are strengthened by hydrodynamic needling, alone or together with other fibers such as also staple fibers and/or endless fibers. The microfibers are spun from a polymer melt of only one certain polymer from a plurality of spinning apertures, and the spun filaments are drawn by gas streams accelerated to high velocity by an accelerating nozzle such as a Laval nozzle and, due to further production conditions, each fiber receives before solidification an internal hydrostatic pressure that is higher than the ambient gas pressure so that each fiber cracks in the longitudinal direction and splits up into a plurality of fine endless filaments.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application is a continuation application of U.S. application Ser. No. 10/479,851, filed Dec. 8, 2003, the contents of which are incorporated herein by reference.
  • DE-A-199 29 709 teaches a fiber production method in which, from a polymer melt of only one certain polymer, filaments are spun from a plurality of spinning apertures and the spun filaments are drawn by substantially cold gas streams accelerated to high velocity by an accelerating nozzle such as a Laval nozzle and, due to further production conditions, each fiber receives before solidification an internal hydrostatic pressure that is higher than the ambient gas pressure so that each fiber cracks in the longitudinal direction and splits up into a plurality of fine endless filaments. These endless microfibers can then be progressively laid to form a nonwoven of arbitrary width.
  • This fiber production method has significant advantages over the prior art involving the melt-blowing method, with which microfibers are also produced. The filaments are very fine, having an average diameter of roughly 2 μm and being essentially endless even at this diameter. Because they are not stretched by a hot air stream as in the melt-blowing method, they undergo no thermal damage and have high strength. The filaments can be produced from any polymer but also from solutions according to the Lyocell method.
  • So-called split fibers are also microfibers. They arise from filaments spun from a plurality of polymers and subsequently split, for example by water jets. This microfiber production method is, however, more expensive.
  • The necessity exists of strengthening the microfibers produced as defined at the outset.
  • The idea of the invention is to effect this by hydrodynamic needling. This is especially effective here because these very thin endless fibers so produced can easily be displaced by water-needling and, despite their endlessness, entangled with nearby fibers. The result is an abrasion-resistant product; this is still the case when the nonwoven fabric has become wet. The product is not only abrasion-resistant but also displays no pilling effect, because entangled endless fibers are involved and these, in the case of normal endless fibers, have a longitudinal strength that makes them difficult to displace with water.
  • The application of hydrodynamic needling in this field is already known in several cases. With regard to melt-blown fibers, reference is made to EP-A-0 333 228; with regard to split fibers, to U.S. Pat. No. 4,233,349. In the present case, the application of water needling is especially advantageous because the product can be tightly needled with water jets in spite of the endless fibers so that no pilling effect occurs in the subsequent use of the strengthened nonwoven. The nonwoven fabric has a soft and quite uniform surface, and can therefore be used with great advantage for many applications in industry.

Claims (2)

1. Strengthened nonwoven consisting at least in part of microfibers
a) that are spun from a polymer melt of only one certain polymer from a plurality of spinning apertures and the spun filaments are drawn by gas streams accelerated to high velocity by an accelerating nozzle such as a Laval nozzle and, due to further production conditions, each fiber receives before solidification an internal hydrostatic pressure that is higher than the ambient gas pressure so that each fiber cracks in the longitudinal direction and splits up into a plurality of fine endless filaments
b) and are strengthened by hydrodynamic needling, alone or together with other fibers such as also staple fibers and/or endless fibers.
2. Nonwoven according to claim 1 wherein the microfibers are laid onto a support ply made of more-stable chemical fibers and serve as a parting ply for a wood pulp ply laid onto the microfibers.
US11/452,320 2001-06-07 2006-06-14 Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method Abandoned US20070004304A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/452,320 US20070004304A1 (en) 2001-06-07 2006-06-14 Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10127471A DE10127471A1 (en) 2001-06-07 2001-06-07 Fixed nonwoven, at least partially of micro-fine continuous fusible polymer filaments, has longitudinally split melt spun filaments laid across the material width and bonded by water jets
DE10127471.8 2001-06-07
PCT/EP2002/006075 WO2002099176A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced
US10/479,851 US20040222556A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced
US11/452,320 US20070004304A1 (en) 2001-06-07 2006-06-14 Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
PCT/EP2002/006075 Division WO2002099176A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced
US10/479,851 Division US20040222556A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced

Publications (1)

Publication Number Publication Date
US20070004304A1 true US20070004304A1 (en) 2007-01-04

Family

ID=7687382

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/479,851 Abandoned US20040222556A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced
US11/452,320 Abandoned US20070004304A1 (en) 2001-06-07 2006-06-14 Method for producing a strengthened nonwoven from at least partly microfine endless fibers and nonwoven according to this method

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US10/479,851 Abandoned US20040222556A1 (en) 2001-06-07 2002-06-04 Method for producing bonded non-wovens from at least partially microfine continuous fibres and non-wovens thereby produced

Country Status (9)

Country Link
US (2) US20040222556A1 (en)
EP (1) EP1402099B1 (en)
JP (1) JP2004527673A (en)
CN (1) CN1330813C (en)
AT (1) ATE311493T1 (en)
DE (2) DE10127471A1 (en)
DK (1) DK1402099T3 (en)
ES (1) ES2254689T3 (en)
WO (1) WO2002099176A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20030805A1 (en) 2003-04-17 2004-10-18 Orlandi Spa NON-FABRIC BASED ON EXPLODED FIBERS OR MULTI-COMPONENT FIBERS SPLITTABLE.
DE10322460B4 (en) * 2003-05-16 2007-02-08 Corovin Gmbh Method and apparatus for producing a spunbonded web of filaments of broken fibers, filaments of broken fibers and nonwoven web
DE102006012052A1 (en) * 2006-03-08 2007-09-13 Lüder GERKING Spinning device for producing fine threads by splicing
AT505621B1 (en) * 2007-11-07 2009-03-15 Chemiefaser Lenzing Ag METHODS FOR PRODUCING A WATER-IRRADIZED PRODUCT CONTAINING CELLULOSIC FIBERS
DE102009005387A1 (en) 2009-01-21 2010-07-22 Fleissner Gmbh Composite non-woven, useful as filtration medium, comprises nanofibers bonded to supporting non-woven by fiber entanglements created by water-jet needling
DE102009010935A1 (en) 2009-02-27 2010-10-14 Fleissner Gmbh Nonwoven composite for filter medium, comprises layers of support non-woven having fibers and/or filament, and/or further layers applied on the support layer, where a layer of microfibers and/or nanofibers is present on the support layer
JP6614450B2 (en) * 2016-05-11 2019-12-04 パナソニックIpマネジメント株式会社 Nonwoven fabric and sound absorbing material
DE102016010163A1 (en) * 2016-08-25 2018-03-01 Carl Freudenberg Kg Technical packaging material

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US4233349A (en) * 1979-03-26 1980-11-11 E. I. Du Pont De Nemours And Company Suede-like product and process therefor
US4970104A (en) * 1988-03-18 1990-11-13 Kimberly-Clark Corporation Nonwoven material subjected to hydraulic jet treatment in spots
US5137600A (en) * 1990-11-01 1992-08-11 Kimberley-Clark Corporation Hydraulically needled nonwoven pulp fiber web
US5328759A (en) * 1991-11-01 1994-07-12 Kimberly-Clark Corporation Process for making a hydraulically needled superabsorbent composite material and article thereof
US5573841A (en) * 1994-04-04 1996-11-12 Kimberly-Clark Corporation Hydraulically entangled, autogenous-bonding, nonwoven composite fabric
US5970583A (en) * 1997-06-17 1999-10-26 Firma Carl Freudenberg Nonwoven lap formed of very fine continuous filaments
US6800226B1 (en) * 1999-06-24 2004-10-05 Gerking Lueder Method and device for the production of an essentially continous fine thread

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Publication number Priority date Publication date Assignee Title
US4233349A (en) * 1979-03-26 1980-11-11 E. I. Du Pont De Nemours And Company Suede-like product and process therefor
US4970104A (en) * 1988-03-18 1990-11-13 Kimberly-Clark Corporation Nonwoven material subjected to hydraulic jet treatment in spots
US5137600A (en) * 1990-11-01 1992-08-11 Kimberley-Clark Corporation Hydraulically needled nonwoven pulp fiber web
US5328759A (en) * 1991-11-01 1994-07-12 Kimberly-Clark Corporation Process for making a hydraulically needled superabsorbent composite material and article thereof
US5573841A (en) * 1994-04-04 1996-11-12 Kimberly-Clark Corporation Hydraulically entangled, autogenous-bonding, nonwoven composite fabric
US5970583A (en) * 1997-06-17 1999-10-26 Firma Carl Freudenberg Nonwoven lap formed of very fine continuous filaments
US6800226B1 (en) * 1999-06-24 2004-10-05 Gerking Lueder Method and device for the production of an essentially continous fine thread

Also Published As

Publication number Publication date
CN1330813C (en) 2007-08-08
JP2004527673A (en) 2004-09-09
WO2002099176A1 (en) 2002-12-12
DE50205125D1 (en) 2006-01-05
US20040222556A1 (en) 2004-11-11
ES2254689T3 (en) 2006-06-16
CN1513070A (en) 2004-07-14
DE10127471A1 (en) 2002-12-12
EP1402099A1 (en) 2004-03-31
EP1402099B1 (en) 2005-11-30
DK1402099T3 (en) 2006-03-27
ATE311493T1 (en) 2005-12-15

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