US20060160707A1 - Aluminum metal machining fluid lubricating concentrate - Google Patents

Aluminum metal machining fluid lubricating concentrate Download PDF

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Publication number
US20060160707A1
US20060160707A1 US11/038,637 US3863705A US2006160707A1 US 20060160707 A1 US20060160707 A1 US 20060160707A1 US 3863705 A US3863705 A US 3863705A US 2006160707 A1 US2006160707 A1 US 2006160707A1
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Prior art keywords
weight
blended
lubricating fluid
concentrate
aluminum
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US11/038,637
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C. Gigel
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Assigned to RAYFIELD, STEVEN E. reassignment RAYFIELD, STEVEN E. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GIGEL, C. MATTHIAS
Publication of US20060160707A1 publication Critical patent/US20060160707A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/022Well-defined aliphatic compounds saturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/024Well-defined aliphatic compounds unsaturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/44Boron free or low content boron compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles
    • C10N2050/011Oil-in-water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A concentrate particularly suitable for aluminum machining containing: alkenylsuccinic acid derivative, sodium hydroxide salt; ether carboxylate; alkyl benzene sodium sulfate; fatty alcohol polyglycol ether; tall oil fatty acid having about 18 carbon atoms; trimethyl propylene; butylcarbitol; (44%) potassium hydroxide; and blended with about 50% by weight of a mineral oil and added to water to form a working composition.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to lubricant fluids used in metal machining. More particularly, it refers to a fluid lubricant concentrate for use in the machining of aluminum products.
  • 2. Description of the Prior Art
  • U.S. Pat. No. 5,668,093 describes the use of alkenylsuccinic acid half-amides used in metal working liquids. In addition, the preparation of alkenylsuccinic anhydride used as a starting material to make the alkenylsuccinic acid half-amides are well known. Although the alkenylsuccinic acid half-amides are now known generally as metal working liquids, each type of metal requires specific concentrates for optimum results. A major problem of prior art cutting fluids is that they alter the substrate surface chemistry of aluminum substrates. They also have poor water break characteristics resulting in incomplete coating of the substrate by the cutting fluid and the retention of contaminants on the substrate surface following cleaning, including water beads.
  • Aluminum, a soft metal requires greater lubrication during machining operations than steel, cast iron and other ferrous metal alloys. In addition, the lubricant needs to be non-hazardous, free from foaming, blendable with mineral oil, have a compatible pH above 8.0, and not stain or discolor the aluminum.
  • SUMMARY OF THE INVENTION
  • The present invention provides a solution to the prior art need by providing a machining lubricant for aluminum products that is not hazardous, environmentally friendly, free from foaming, blendable with mineral oil, having a compatible pH above 8.0, boron and amine free and will not corrode, stain or discolor aluminum. The machining lubricant of this invention is a clear emulsion which turns opal when diluted with water. The ingredients are:
      • alkenysuccinic half-amide derivative, sodium hydroxide salt;
      • ether carboxylate;
      • alkylbenzene sodium sulfate;
      • fatty alcohol polyglycol ether;
      • tall oil fatty acid;
      • trimethyl propylene;
      • butylcarbitol; and
      • potassium hydroxide;
        all blendable with mineral oil.
  • The concentrate is mixed with water prior to use in an aluminum machining operation.
  • DETAILED DESCRIPTION OF THE INVENTION
  • The concentrate of this invention is useful for various applications in the metal working of aluminum. These applications include heavy machining cutting, stamping, drilling, forming and ban saw cutting. The active ingredients are blendable with mineral oil to form the concentrate. The working composition contains less than 5% by weight of the concentrate in tap water. This composition removes chips instantly from a threading operation from the threading tool and the resulting threaded product without affecting the diameter of the product. The composition is boron free and will not corrode, stain or discolor aluminum. The active ingredients form a clear emulsion when blended with mineral oil, but turns opal in color when blended with water.
  • The concentrate contains the following eight active ingredients in specific weight percents totaling 100, which are blended with about 50% by weight mineral oil:
      • 18-25 alkenylsuccinic acid derivative, sodium hydroxide salt (commercially known as HOSFACOR 3928, and containing about twenty-eight carbon atoms);
      • 3-7 ether carboxylate;
      • 12-16 alkyl benzene sodium sulfate;
      • 15-18 fatty alcohol polyglycol ether;
      • 6-12 tall oil fatty acid having about 18 carbon atoms;
      • 8-15 trimethyl propylene;
      • 4-7 butylcarbitol; and
      • 12-16 potassium hydroxide (44% concentration).
  • A bactericide can be added to increase pot life.
  • A preferred concentrate contains the following active ingredients at a weight percent of about:
      • 22 alkenylsuccinic acid derivative, sodium hydroxide salt (HOSFACOR 3928);
      • 3 ether carboxylate;
      • 14 alkyl benzene sodium sulfate;
      • 18 fatty alcohol polyglycol ether;
      • 10 tall oil fatty acid having about 18 carbon atoms;
      • 13 trimethyl propylene;
      • 6 butyl carbitol; and
      • 14 potassium hydroxide (44% concentrate).
  • The above active ingredients are blended with 50% by weight of any conventional mineral oil. Especially, those having a naphthalene or paraffin base can be blended with the active ingredients to form a clear liquid concentrate. Further blending with water is employed in most machining operations using less than 5% by weight of concentrate in tap water.
  • Known cutting fluids do not suggest the use of the unique combination of materials in the cutting fluids of the present invention which achieve outstanding performance results when used in machining aluminum.
  • The following percent by weight of concentrate is mixed with tap water to form the working compositions in the indicated operations:
    OPERATION % BY WEIGHT CONCENTRATE
    Grinding 2.5 to 3.5
    Cutting 3.0
    Drilling 3.0
    Tapping 4.0 to 5.0
    CNC 3.0 to 4.0
  • Equivalent ingredients can be substituted for the above enumerated ingredients to create a substantially equivalent functional concentrate, in substantially the same way and with substantially the same results.

Claims (6)

1. An aluminum machining lubricating fluid concentrate comprising about 50% by weight of a mineral oil blended with 100% by weight of the following:
18-25 alkenylsuccinic acid derivative, sodium hydroxide salt;
3-7 ether carboxylate;
12-16 alkyl benzene sodium sulfate;
15-18 fatty alcohol polyglycol ether;
6-12 tall oil fatty acid having about 18 carbon atoms;
8-15 trimethyl propylene;
4-7 butylcarbitol; and
12-16 potassium hydroxide (44% concentration).
2. The aluminum machining lubricating fluid concentrate according to claim 1, blended with water to form a metal working composition.
3. An aluminum machining lubricating fluid composition according to claim 2, containing a bacteriacide and defoaming agent.
4. An aluminum machining lubricating fluid concentrate consisting by weight percent of:
18-25 a salt of an alkenylsuccinic acid derivative, sodium hydroxide salt;
3-7 ether carboxylate;
12-16 alkyl benzene sodium sulfate;
15-18 fatty alcohol polyglycol ether;
6-12 tall oil fatty acid having about 18 carbon atoms;
8-15 trimethyl propylene;
4-7 butylcarbitol;
12-16 potassium hydroxide (44% concentration);
and blended with about 50% by weight of a mineral oil.
5. An aluminum machining lubricating fluid concentrate consisting by weight percent about:
22 a sodium hydroxide salt of an alkenylsuccinic acid derivative;
3 ether carboxylate;
14 alkyl benzene sodium sulfate;
18 fatty alcohol polyglycol ether;
10 tall oil fatty acid having about 18 carbon atoms;
13 trimethyl propylene;
6 butylcarbitol;
14 potassium hydroxide (44% concentration);
and blended with about 50% by weight of a mineral oil.
6. The aluminum machining lubricating fluid concentrate according to claim 5, blended at less than 5% by weight of concentrate in water to form a working composition.
US11/038,637 2005-01-19 2005-01-19 Aluminum metal machining fluid lubricating concentrate Abandoned US20060160707A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060261054A1 (en) * 2005-05-19 2006-11-23 Lincoln Global, Inc. Cored welding electrode and methods for manufacturing the same
US20110036579A1 (en) * 2009-08-11 2011-02-17 Baker Hughes Incorporated Water-Based Mud Lubricant Using Fatty Acid Polyamine Salts and Fatty Acid Esters
CN105670752A (en) * 2016-01-13 2016-06-15 黑龙江华安精益计量技术研究院有限公司 Reference substance for calibrating emulsion concentration meter
CN110951532A (en) * 2019-12-23 2020-04-03 苏州铱诺化学材料有限公司 Water-based stamping oil for aluminum fins and preparation method thereof

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2210140A (en) * 1931-11-06 1940-08-06 Colbeth Ivor Milton Lubricant and process of producing it
US3657126A (en) * 1970-04-17 1972-04-18 Aluminum Co Of America Oil and water-base lubricant: that, as to improvements in oil and water-base lubricants
US3909429A (en) * 1973-03-08 1975-09-30 Continental Oil Co Cutting oil composition
US4218329A (en) * 1978-08-28 1980-08-19 Koh Kook Wha Cooling and lubricating fluid for metal working
US4414121A (en) * 1981-12-14 1983-11-08 Shell Oil Company Aqueous lubricating compositions
US4781849A (en) * 1987-05-21 1988-11-01 Aluminum Company Of America Lyotropic liquid crystal metalworking lubricant composition
US4882077A (en) * 1988-03-09 1989-11-21 W. R. Grace & Co.-Conn. Metalworking fluid
US4956110A (en) * 1985-06-27 1990-09-11 Exxon Chemical Patents Inc. Aqueous fluid
US5614482A (en) * 1995-02-27 1997-03-25 Parker Sales, Inc. Lubricant composition for treatment of non-ferrous metals and process using same
US5668093A (en) * 1991-02-26 1997-09-16 Hoechst Aktiengesellschaft Use of alkenylsuccinic acid half-amides
US5706684A (en) * 1995-10-03 1998-01-13 Cincinnati Milacron Inc. Metalworking process
US5716917A (en) * 1996-09-24 1998-02-10 Cincinnati Milacron Inc. Machining fluid composition and method of machining
US6602833B1 (en) * 1998-09-07 2003-08-05 Ab Chem Dimension Mechanical working in the presence of a metal containing copper or aluminum

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2210140A (en) * 1931-11-06 1940-08-06 Colbeth Ivor Milton Lubricant and process of producing it
US3657126A (en) * 1970-04-17 1972-04-18 Aluminum Co Of America Oil and water-base lubricant: that, as to improvements in oil and water-base lubricants
US3909429A (en) * 1973-03-08 1975-09-30 Continental Oil Co Cutting oil composition
US4218329A (en) * 1978-08-28 1980-08-19 Koh Kook Wha Cooling and lubricating fluid for metal working
US4414121A (en) * 1981-12-14 1983-11-08 Shell Oil Company Aqueous lubricating compositions
US4956110A (en) * 1985-06-27 1990-09-11 Exxon Chemical Patents Inc. Aqueous fluid
US4781849A (en) * 1987-05-21 1988-11-01 Aluminum Company Of America Lyotropic liquid crystal metalworking lubricant composition
US4882077A (en) * 1988-03-09 1989-11-21 W. R. Grace & Co.-Conn. Metalworking fluid
US5668093A (en) * 1991-02-26 1997-09-16 Hoechst Aktiengesellschaft Use of alkenylsuccinic acid half-amides
US5614482A (en) * 1995-02-27 1997-03-25 Parker Sales, Inc. Lubricant composition for treatment of non-ferrous metals and process using same
US5706684A (en) * 1995-10-03 1998-01-13 Cincinnati Milacron Inc. Metalworking process
US5716917A (en) * 1996-09-24 1998-02-10 Cincinnati Milacron Inc. Machining fluid composition and method of machining
US6602833B1 (en) * 1998-09-07 2003-08-05 Ab Chem Dimension Mechanical working in the presence of a metal containing copper or aluminum

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060261054A1 (en) * 2005-05-19 2006-11-23 Lincoln Global, Inc. Cored welding electrode and methods for manufacturing the same
US8519303B2 (en) * 2005-05-19 2013-08-27 Lincoln Global, Inc. Cored welding electrode and methods for manufacturing the same
US20110036579A1 (en) * 2009-08-11 2011-02-17 Baker Hughes Incorporated Water-Based Mud Lubricant Using Fatty Acid Polyamine Salts and Fatty Acid Esters
US8413745B2 (en) 2009-08-11 2013-04-09 Baker Hughes Incorporated Water-based mud lubricant using fatty acid polyamine salts and fatty acid esters
US9340722B2 (en) 2009-08-11 2016-05-17 Baker Hughes Incorporated Water-based mud lubricant using fatty acid polyamine salts and fatty acid esters
CN105670752A (en) * 2016-01-13 2016-06-15 黑龙江华安精益计量技术研究院有限公司 Reference substance for calibrating emulsion concentration meter
CN110951532A (en) * 2019-12-23 2020-04-03 苏州铱诺化学材料有限公司 Water-based stamping oil for aluminum fins and preparation method thereof

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